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Mechanism of enhancing NH_(3)-SCR performance of Mn-Ce/AC catalyst by the structure regulation of activated carbon with calcite in coal
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作者 NIU Jian LI Yuhang +4 位作者 BAI Baofeng WEN Chaolu LI Linbo ZHANG Huirong GUO Shaoqing 《燃料化学学报(中英文)》 北大核心 2026年第1期69-79,共11页
To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content ... To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced. 展开更多
关键词 CALCITE activated carbon structure Mn-Ce/AC catalyst NH_(3)-SCR performance
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Accumulation of cadmium and copper by female Oxya chinensis (Orthopera: Acridoidea) in soil-plant-insect system 被引量:7
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作者 LI Li-jun LIU Xue-mei +5 位作者 DUAN Yi-hao GUO Ya-ping CHENG Bin GUO Jun XI Yu-ying MA En-bo 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2006年第2期341-346,共6页
One purpose of this research is to present accumulation of cadmium (Cd) and copper (Cu) by female Oxya chinensis (Orthopera: Acridoidea) in a simulated soil-plant-insect ecosystem treated with Cd. Fourth-instar... One purpose of this research is to present accumulation of cadmium (Cd) and copper (Cu) by female Oxya chinensis (Orthopera: Acridoidea) in a simulated soil-plant-insect ecosystem treated with Cd. Fourth-instar nymphs of O. chinensis had been fed on wheat (Triticurn aestivum) seedlings contaminated with Cd and Cu for one month. In the ecosystem, the Cd concentration in wheat seedlings rose greatly with the increasing of Cd in the soil, but the Cu concentration in wheat seedlings was not found elevated. There was a highly significant difference(P〈0.05) in Cd concentrations of wheat seedlings and not any significant difference(P〉0.05) in Cu concentrations of wheat seedlings. The Cd and Cu concentration in different body part-head, thorax, abdomen, and hind femur, varied under different Cd concentrations in soil. There were significant differences (P〈0.05) in the four parts of Cd and Cu accumulations with all treatments. The order of Cd accumulation was thorax 〉abdomen 〉head 〉hind femur and the Cu was abdomen 〉thorax 〉 head〉hind femur. The results indicated that Cd and Cu were accumulated from the soil to grasshoppers through the plant; that is to say, Cd and Cu in environment could be transported to animal or human via food chain. 展开更多
关键词 ACCUMULATION cadmium(Cd) copper(Cu) grasshopper(Oxya chinensisi) soil-plant-insect ecosystem
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Integrated Fertilization Regimes Boost Heavy Metals Accumulation and Biomass of Sedum alfredii Hance 被引量:3
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作者 Kangning Zhou Yingying Zhang +4 位作者 Jiasen Wu Chunying Dou Zihao Ye Zhengqian Ye Weijun Fu 《Phyton-International Journal of Experimental Botany》 SCIE 2021年第4期1217-1232,共16页
The hyperaccumulator Sedum alfredii Hance(S.alfredii)may be employed for zinc(Zn)and cadmium(Cd)-polluted soil remediation.However,the low phytoremediation efficiency,related to the low biomass production,limits its u... The hyperaccumulator Sedum alfredii Hance(S.alfredii)may be employed for zinc(Zn)and cadmium(Cd)-polluted soil remediation.However,the low phytoremediation efficiency,related to the low biomass production,limits its use with that purpose.In this experiment,nitrogen(N),phosphorus(P),and potassium(K)fertilizers,and organic manure were applied to investigate the phytoremediation ability of S.alfredii.Hydroponic and pot experiments were conducted using Zn-Cd polluted soil.The hydroponic experiment indicated that appropriate fertilizer application could increase(p<0.05)the amount of accumulated Zn and Cd in S.alfredii.When N supply ranged from 0.5 to 2.5 mmol L^(−1),it could improve growth and accumulation of Zn and Cd in whole plants of S.alfredii.The 1 mmol L^(−1) N was an optimal N dosage for shoot biomass production and Cd accumulation in shoots,while the 2.5 mmol L^(−1) was an optimal N dosage for Zn accumulation in shoots.Both low(<0.05 mmol L^(−1))and high(>0.8 mmol L^(−1))P supply decreased growth,and Zn/Cd accumulation in whole plants of the studied species.The 0.1 mmol L^(−1) P was an optimal dosage for S.alfredii biomass production and Zn/Cd accumulation in shoots.The supply levels within the range from 0.3 to 1 mmol L^(−1) K could significantly improve the biomass production of S.alfredii and its capability to accumulate Zn and Cd in the biomass.The 0.5 mmol L^(−1) K was an optimal dosage for the whole biomass production and Zn accumulation in shoots,while the 1 mmol L^(−1) was an optimal K dosage for Zn accumulation in shoots,which was 17.2%higher than the control.Moreover,the soil pot experiment showed that the combination of organic(fermented manure)and inorganic fertilizers made significant effects on the Zn and Cd-polluted soil remediation by S.alfredii.These effects varied,however,with the application of different proportions of N,P,K and organic matter.The Zn accumulation by S.alfredii reached the highest efficiency ability under the highest fertilizer mixing rate(N:50 mg kg^(−1),P:40 mg kg^(−1),K:100 mg kg^(−1),organic matter:1%).Even more,S.alfredii showed the strongest ability to accumulate Cd with a lower fertilizer mixing rate(N:25mg kg^(−1),P:20mg kg^(−1),K:50 mg kg^(−1),organic matter:0.5%). 展开更多
关键词 Sedum alfredii Hance ZINC CADMIUM PHYTOREMEDIATION fertilizer application
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Effects of Autoclaving and Mercuric Chloride Sterilization on PAHs Dissipation in a Two-Liquid-Phase Soil Slurry 被引量:1
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作者 WANG Cong-Ying WANG Fang +5 位作者 WANG Tao YANG Xing-Lun BIAN Yong-Rong F. O. KENGARA LI Zeng-Bo JIANG Xin 《Pedosphere》 SCIE CAS CSCD 2011年第1期56-64,共9页
A two-liquid-phase (TLP) soil slurry system was employed to quantify the efficiencies of autoclaving and mercuric chloride sterilization in the dissipation of polycyclic aromatic hydrocaxbons (PAHs). The fates of ... A two-liquid-phase (TLP) soil slurry system was employed to quantify the efficiencies of autoclaving and mercuric chloride sterilization in the dissipation of polycyclic aromatic hydrocaxbons (PAHs). The fates of 11 PAHs (naphthalene, fluorene, phenanthrene, anthracene, fluoranthene, pyrene, benzo(a)anthracene, benzo(a)pyrene, benzo(b)fluoranthene, benzo(k)fluoranthene, dibenzo(a, h)anthracene) were recorded over 113 days of incubation. No microorganisms were detected in the HgC12-sterilized soil slurries during the whole incubation period, indicating very effective sterilization. However, about 2% 36% losses of PAHs were observed in the HgCl2- sterilized slurry. In contrast to the HgCl2-sterilized soil slurry, some microorganisms survived in the autoclaved soil slurries. Moreover, significant biodegradiation of 6 PAHs (naphthalene, fluorene, phenanthrene, anthracene, fluoranthene and pyrene) was observed in the autoclaved soil slurries. This indicated that biodegradation results of PAHs in the soil slurries, calculated on basis of the autoclaved control, would be underestimated. It could be concluded that the sterilization efficiency and effectiveness of HgCl2 on soil slurry was much higher than those of autoclaving at 121 ℃ for 45 rain. 展开更多
关键词 adsorption aqueous solubility biodegradation MICROORGANISMS octanol-water partition coefficient
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Diurnal and seasonal variations in carbon fluxes in bamboo forests during the growing season in Zhejiang province, China 被引量:3
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作者 Liang Chen Yuli Liu +5 位作者 Guomo Zhou Fangjie Mao Huaqiang Du Xiaojun Xu Pingheng Li Xuejian Li 《Journal of Forestry Research》 SCIE CAS CSCD 2019年第2期657-668,共12页
Bamboo forest is an important forest type in subtropical China and is characterized by fast growth and high carbon sequestration capacity. However, the dynamics of carbon fluxes during the fast growing period of bambo... Bamboo forest is an important forest type in subtropical China and is characterized by fast growth and high carbon sequestration capacity. However, the dynamics of carbon fluxes during the fast growing period of bamboo shoots and their correlation with environment factors are poorly understood. We measured carbon dioxide exchange and climate variables using open-path eddy covariance methods during the 2011 growing season in a Moso bamboo forest(MB, Phyllostchys edulis) and a Lei bamboo forest(LB, Phyllostachys violascens) in Zhejiang province,China. The bamboo forests were carbon sinks during the growing season. The minimum diurnal net ecosystem exchange(NEE) at MB and LB sites were-0.64 and-0.66 mg C m^(-2) s^(-1), respectively. The minimum monthly NEE, ecosystem respiration(RE), and gross ecosystem exchange(GEE) were-99.3 ± 4.03, 76.2 ±2.46, and^(-1)91.5 ± 4.98 g C m^(-2) month^(-1), respectively,at MB site, compared with-31.8 ± 3.44, 70.4 ± 1.41,and^(-1)57.9 ± 4.86 g C m^(-2) month^(-1), respectively, at LB site. Maximum RE was 92.1 ± 1.32 g C m^(-2) month^(-1) at MB site and 151.0 ± 2.38 g C m^(-2) month^(-1) at LB site.Key control factors varied by month during the growing season, but across the whole growing season, NEE and GEE at both sites showed similar trends in sensitivities to photosynthetic active radiation and vapor pressure deficit,and air temperature had the strongest correlation with RE at both sites. Carbon fluxes at LB site were more sensitive to soil water content compared to those at MB site. Both onyear(years when many new shoots are produced) and offyear(years when none or few new shoots are produced)should be studied in bamboo forests to better understand their role in global carbon cycling. 展开更多
关键词 Bamboo forest EDDY COVARIANCE CARBON fluxes CARBON SEQUESTRATION
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An Arabidopsis mutant atcsr-2 exhibits high cadmium stress sensitivity involved in the restriction of H_2S emission 被引量:4
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作者 Ya-wei LI Ze-hua GONG +6 位作者 Yao MU Yi-xian ZHANG Zeng-jie QIAO Li-ping ZHANG Zhu-ping JIN Hua LI Yan-xi PEI 《Journal of Zhejiang University-Science B(Biomedicine & Biotechnology)》 SCIE CAS CSCD 2012年第12期1006-1014,共9页
The gene AtCSR encodes peptidyl-prolyl cis/trans isomerases (PPIases) that accelerate energetically unfavorable cis/trans isomerization of the peptide bond preceding proline production.In our studies,we found that AtC... The gene AtCSR encodes peptidyl-prolyl cis/trans isomerases (PPIases) that accelerate energetically unfavorable cis/trans isomerization of the peptide bond preceding proline production.In our studies,we found that AtCSR was associated with cadmium (Cd)-sensitive response in Arabidopsis.Our results show that AtCSR expression was triggered by Cd-stress in wild type Arabidopsis.The expression of some genes responsible for Cd2+ transportation into vacuoles was induced,and the expression of the iron-regulated transporter 1 (IRT1) related to Cd2+ absorption from the environment was not induced in wild type with Cd2+ treatment.The expression of Cd-transportation related genes was not in response to Cd-stress,whereas IRT expression increased dramatically in atcsr-2 with Cd2+ treatment.The expression of glutathione 1 (GSH1) was consistent with GSH being much lower in atcsr-2 in comparison with the wild type with Cd2+ treatment.Additionally,malondialdehyde (MDA),hydrogen peroxide,and Cd2+ contents,and activities of some antioxidative enzymes,differed between the wild type and atcsr-2.Hydrogen sulfide (H2S) has been confirmed as the third gas-transmitter over recent years.The findings revealed that the expression pattern of H2 S-releasing related genes and that of Cd-induced chelation and transportation genes matched well in the wild type and atcsr-2,and H2S could regulate the expression of the Cd-induced genes and alleviate Cd-triggered toxicity.Finally,one possible suggestion was given:down-regulation of atcsr-2,depending on H2S gas-transmitter not only weakened Cd2+ chelation,but also reduced Cd2+ transportation into vacuoles,as well as enhancing the Cd2+ assimilation,thus rendering atcsr-2 mutant sensitive to Cd-stress. 展开更多
关键词 AtCSR H2S gas-transmitter GLUTATHIONE Cadmium stress sensitivity
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Effects of pre-ozonation on organic matter removal by coagulation with IPF-PACl 被引量:2
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作者 LIU Hai-long WANG Dong-sheng +2 位作者 SHI Bao-you WANG Min TANG Hong-xiao 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2006年第3期453-458,共6页
Ozone plays an important role as a disinfectant and oxidant in potable water treatment practice and is increasingly being used as a pre-oxidant before coagulation. The purpose of this study is to obtain insight into t... Ozone plays an important role as a disinfectant and oxidant in potable water treatment practice and is increasingly being used as a pre-oxidant before coagulation. The purpose of this study is to obtain insight into the mechanisms that are operative in pre-ozonized coagulation. Effects ofpre-ozonation on organic matter removal during coagulation with IPF-PAC1 were investigated by using PDA (photometric disperse analysis), apparent molecular weight distribution and chemical fractionation. The dynamic formation of flocs during coagulation process was detected. Changes of aquatic organic matter (AOM) structure resulted from the influence of pre-ozonation were evaluated. Results show that dosage of O3 and characteristics of AOM are two of the major factors influencing the performance of O3 on coagulation. No significant coagulation-aid effect of O3 was observed for all experiments using either A1C13 or PAC1. On the contrary, with the application of pre-ozonation, the coagulation efficiency of A1C13 was significantly deteriorated, reflected by the retardation of floc formation, and the removal decreases of turbidity, DOC, and UV254. However, if PACl was used instead of AlCl3, the adverse effects of pre-ozonation were mitigated obviously, particularly when the O3 dosage was less than 0.69 (mg O3/mg TOC). The difference between removals of UV254, and DOC indicated that pre-ozonation greatly changed the molecular structure of AOM, but its capability of mineralization was not remarkable. Only 5% or so DOC was removed by pre-ozonation at 0.6--0.8 mg/L alone. Fractionation results showed that the organic products of pre-ozonation exhibited lower molecular weight and more hydrophilicity, which impaired the removal of DOC in the following coagulation process. 展开更多
关键词 natural organic matter (NOM) FRACTIONATION PRE-OZONATION PACL COAGULATION
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Least Square Finite Element Method for Viscous Splitting of Unsteady Incompressible Navier–Stokes Equations
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作者 SHUI Qing-xiang WANG Da-guo +1 位作者 HE Zhi-liang HUANG Jin 《China Ocean Engineering》 SCIE EI CSCD 2018年第4期490-500,共11页
In order to solve unsteady incompressible Navier–Stokes(N–S) equations, a new stabilized finite element method,called the viscous-splitting least square FEM, is proposed. In the model, the N–S equations are split i... In order to solve unsteady incompressible Navier–Stokes(N–S) equations, a new stabilized finite element method,called the viscous-splitting least square FEM, is proposed. In the model, the N–S equations are split into diffusive and convective parts in each time step. The diffusive part is discretized by the backward difference method in time and discretized by the standard Galerkin method in space. The convective part is a first-order nonlinear equation.After the linearization of the nonlinear part by Newton’s method, the convective part is also discretized by the backward difference method in time and discretized by least square scheme in space. C0-type element can be used for interpolation of the velocity and pressure in the present model. Driven cavity flow and flow past a circular cylinder are conducted to validate the present model. Numerical results agree with previous numerical results, and the model has high accuracy and can be used to simulate problems with complex geometry. 展开更多
关键词 unsteady incompressible N–S equations viscous splitting Newton's method least square finite element method driven cavity flow flow past a circular cylinder
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Plant enhanced degradation of phenanthrene in the contaminated soil
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作者 LIAO Min XIE Xiao-mei 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2006年第3期510-513,共4页
The degradative characteristics ofphenanthrene, microbial biomass carbon, plate counts ofheterotrophic bacteria and most probable number (MPN) of phenanthrene degraders in non-rhizosphere or rhizosphere soils with u... The degradative characteristics ofphenanthrene, microbial biomass carbon, plate counts ofheterotrophic bacteria and most probable number (MPN) of phenanthrene degraders in non-rhizosphere or rhizosphere soils with uninoculating or inoculating phenanthrene degraders were measured. At the initial concentration of 20 mg phenanthrene/kg soil, the half-lives of phenanthrene in uninoculated non-rhizosphere soil, uninoculated rhizosphere soil, inoculated non-rhizosphere soil, and inoculated rhizosphere soil were measured to be 81.5, 47.8, 15.1 and 6.4 d, respectively, and corresponding kinetic data fitted first-order kinetics. The highest degradation rate of phenanthrene was observed in inoculated rhizosphere soil. The degradative characteristics of phenanthrene were closely related to the effects of vegetation on soil microbial process. Vegetation could enhance the magnitude of rhizosphere microbial communities, microbial biomass content, and heterotrophic bacterial community, but barely influence those community components responsible for phenanthrene degradation. Results suggested that combination of vegetation and inoculation with degrading microorganisms of target organic contaminants was a better pathway to enhance degradation of the organic contaminants in soil. 展开更多
关键词 PHENANTHRENE BIOREMEDIATION DEGRADATION
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A hybrid method for tree-level forest planning
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作者 Yusen Sun Xingji Jin +1 位作者 Timo Pukkala Fengri Li 《Journal of Forestry Research》 2025年第5期125-138,共14页
Forest inventory is increasingly producing infor-mation on the locations and sizes of individual trees.This information can be acquired by airborne or terrestrial laser scanning or analyzing photogrammetric data.Howev... Forest inventory is increasingly producing infor-mation on the locations and sizes of individual trees.This information can be acquired by airborne or terrestrial laser scanning or analyzing photogrammetric data.However,all trees are seldom detected,especially in young,dense,or multi-layered stands.On the other hand,the complete size distributions of trees can be predicted with various methods,for instance,kNN data imputation in an area-based LiDAR inventory,predicting the parameters of a distribution func-tion from remote sensing data,field sampling,or using his-togram matching and calibration methods.The predicted distribution can be used to estimate the number and sizes of the non-detected trees.The study’s objective was to develop a method for forest planning that efficiently uses the avail-able tree-level data in management optimization.The study developed a two-stage hierarchical method for tree-level management optimization for cases where only part of the trees is detected or measured individually.Cutting years and harvest rate curves for the non-detected trees are optimized at the higher level,and the cutting events of the detected trees are optimized at the lower level.The study used differ-ential evolution at the higher level and simulated annealing at the lower level.The method was tested and demonstrated in even-aged Larix olgensis plantations in the Heilongjiang province of China.The optimizations showed that optimiz-ing the harvest decisions at the tree level improves the profit-ability of management compared to optimizations in which only the dependence of thinning intensity on tree diameter is optimized.The approach demonstrated in this study pro-vides feasible options for tree-level forest planning based on LiDAR inventories.The method is immediately applicable to forestry practice,especially in plantations. 展开更多
关键词 Forest planning Simulated annealing Unmanned aerial vehicle(UAV) Laser scanning Larix olgensis Management optimization
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Eradication of Solenopsis invicta by pyriproxyfen at the Shihmen Reservoir in northern Taiwan
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作者 Ji-Sen Hwang 《Insect Science》 SCIE CAS CSCD 2009年第6期493-501,共9页
The aim of this study was to investigate the possibility of eradicating the red imported fire ant, Solenopsis invicta Buren, in the hot, humid and rainy conditions of northern Taiwan. Thirteen hectares of the Shihmen ... The aim of this study was to investigate the possibility of eradicating the red imported fire ant, Solenopsis invicta Buren, in the hot, humid and rainy conditions of northern Taiwan. Thirteen hectares of the Shihmen Reservoir have been infected with these ants, with a total of 1 578 mounds. Pyriproxyfen was applied at a rate of 2 kg/hectare each season, for a total of four seasons. Surveys using visual examination, bait traps, as well as the population index method showed that the brood, the reproductive ants, and the worker ants within the nests were all significantly reduced 1 month after the first application of pyriproxyfen. Four months after the initial application there were no more brood or reproductive ants. After 8 months there were no longer any active mounds left, and 12 months later there were no more worker ants. After monitoring for 1 more year, it was ascertained that the red imported fire ants were eradicated. The percentages of decrease after 2, 4 and 6 months of treatment were 57.4%, 80.5%, and 98.2%, respectively. 展开更多
关键词 ERADICATION insect growth regulator PYRIPROXYFEN red imported fire ant Solenopsis invicta
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The phytolith carbon sequestration in terrestrial ecosystems:the underestimated potential of bamboo forest
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作者 Xuekun Cheng Huiru Lv +5 位作者 Shuhan Liu Chong Li Pingheng Li Yufeng Zhou Yongjun Shi Guomo Zhou 《Ecological Processes》 SCIE EI CSCD 2023年第1期872-883,共12页
Background Terrestrial ecosystems contain significant carbon storage,vital to the global carbon cycle and climate change.Alterations in human production activities and environmental factors affect the stability of car... Background Terrestrial ecosystems contain significant carbon storage,vital to the global carbon cycle and climate change.Alterations in human production activities and environmental factors affect the stability of carbon storage in soil.Carbon sequestration in plant phytoliths offers a sustainable method for long-term carbon stabilization.Carbon occluded in phytoliths(PhytOC)is a kind of carbon that can be stable and not decomposed for a long time,so it is crucial to conduct more in-depth research on it.Results We undertook a meta-analysis on PhytOC across global terrestrial ecosystems,analyzing 60 articles,encapsulating 534 observations.We observed notable differences in phytolith and PhytOC contents across various ecosystems.Bamboo forest ecosystems exhibited the highest vegetation phytolith and PhytOC content,while soil phytolith content was most prominent in bamboo forests and PhytOC content in croplands.Human activities,such as grassland grazing,had a lesser impact on soil PhytOC transport than actions like cutting and tillage in croplands and forests.Our study separated bamboo ecosystems,analyzing their PhytOC content and revealing an underestimation of their carbon sink capacity.Conclusions Notwithstanding our findings,phytoliths’intricate environmental interactions warrant further exploration,crucial for refining ecosystem management and accurately estimating PhytOC stocks.This deepened understanding lays the foundation for studying phytoliths and the carbon sink dynamics. 展开更多
关键词 Carbon sequestration PHYTOLITHS PhytOC Terrestrial ecosystem Soil carbon
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