Catalytic reduction of nitrate over bimetallic catalysts has emerged as a technology for sustainable treatment of nitrate-containing groundwater.However,the structure of bimetallic has been much less investigated for ...Catalytic reduction of nitrate over bimetallic catalysts has emerged as a technology for sustainable treatment of nitrate-containing groundwater.However,the structure of bimetallic has been much less investigated for catalyst optimization.Herein,two main types of Pd-Cu bimetallic nanocrystal structures,heterostructure and intermetallic,were prepared and characterized using high-resolution transmission electron microscopy(HRTEM),X-ray diffraction(XRD),and X-ray photoelectron spectroscopy(XPS).The results show that two individual Pd and Cu nanocrystals with a mixed interface exist in the heterostructure nanocrystals,while Pd and Cu atoms are uniformly distributed across the intermetallic Pd-Cu nanocrystals.The catalytic nitrate reduction experiments were carried out in a semibatch reactor under constant hydrogen flow.The nitrate conversion rate of the heterostructure Pd-Cu nanocrystals supported onα-Al_(2)O_(3),γ-Al_(2)O_(3),SBA-15,and XC-72R exhibited 3.82-,6.76-,4.28-,2.44-fold enhancements relative to the intermetallic nanocrystals,and the nitrogen and nitrite were the main products for the heterostructure and intermetallic Pd-Cu nanocrystals,respectively.This indicates that the catalytic nitrate reduction over Pd-Cu catalyst is sensitive to the bimetallic structures of the catalysts,and heterostructure bimetallic nanocrystals exhibit better catalytic performances on both the activity and selectivity,which may provide new insights into the design and optimization of catalysts to improve catalytic activity and selectivity for nitrate reduction in water.展开更多
A total of 25 strains were isolated from the intestinal tract of Mystus macropterus. The inhibitory effects of extracellular enzyme activity to common aquat- ic pathogenic bacteria were screened. A probiotic DQHY -7 s...A total of 25 strains were isolated from the intestinal tract of Mystus macropterus. The inhibitory effects of extracellular enzyme activity to common aquat- ic pathogenic bacteria were screened. A probiotic DQHY -7 strain was isolated, and its safety was detected. DQHY -7 strain was preliminarily identified by mor- phological observation, and physiological and biochemical test. Research results showed that DQHY -7 strain had relatively strong production capacities of amylase, cellulase and protease, and could restrict the growth of Escherichia coli, Aeromonas hydrophila and Pseudomonas fluorescens. Results of acute toxicity test showed that 1. 0 × 108 CFU/mL DQHY -7 bacterial suspension showed no pathogenicity to M. macropterus. According to the colony growth pattern and physiological-bio- chemical characteristics of DQHY -7, the strain was identified to be Bacillus subtilis. Research results showed that DQHY -7 strain could be used as a new candi- date strain for feeding microecologicalagent.展开更多
This paper analyzes the performance and operation of ecologically-based production systems in the Atlantic Forest in southern Brazil in an integrated approach to their multifunctional characteristics and rural develop...This paper analyzes the performance and operation of ecologically-based production systems in the Atlantic Forest in southern Brazil in an integrated approach to their multifunctional characteristics and rural development. Nowadays the Atlantic Forest is considered the most threatenet biome, because of exploitation of their biological resources and unsuitable agricultural purposes. Banana cultivation is one of biggest commercial productions in atlantic south portion of forest, showing two different cropping systems： one using conventional management tehniques and other antagonistic, ecological based. The ecological system is compatible with the conservation of sustainable use of forests. The article presents a comparative analysis-diagnosis of major production and cultivation systems of banana, using the production systems approach, with evaluation of economic and technical indicators. The database is composed by 17 interviews conducted under field conditions in 2007. As a result, the technical and economic functioning of ecological systems demonstrate achieve economic efficiency, in general, higher than conventional systems. Furthermore, some key characteristics of ecological based systems focus on food production and income generation for farmers without harming areas of the Atlantic Forest, being in equilibrium with tropical dynamic and being an important instrument for the restoration of degraded ecosystems and for local development.展开更多
International Maize and Wheat Improvement Center （CIMMYT） and Kazakhstan collaborative activities on wheat improvement are focused in the following main areas： （1） wheat germplasm enhancement： Kazakhstan-Siberia...International Maize and Wheat Improvement Center （CIMMYT） and Kazakhstan collaborative activities on wheat improvement are focused in the following main areas： （1） wheat germplasm enhancement： Kazakhstan-Siberian Network on Wheat Improvement （KASIB） and Shuttle Breeding ＂Mexico-KASIB＂ Programs; （2） Conservation agriculture （CA） for wheat production and crop diversification. Nineteen breeding programs of Kazakhstan and Russia are united by KASIB Network and Shuttle Breeding. By 2014, more than 15,000 wheat lines and varieties were involved in breeding programs of Kazakhstan and Russia; 10 varieties were developed and released. The KASIB Network and Shuttle Breeding Program were recognized as one of the best example of the effective regional and international cooperation in Kazakhstan and Russia. In the beginning of 2000 CIMMYT, National Agricultural Research System, the Ministry of Agriculture, FAO, World Bank in cooperation with farmers initiated large-scale activities based on CA in Kazakhstan. Due the joint efforts, area under CA-based practices has been increasing from virtually none to an estimated area of 500,000 ha in 2007, 1,200,000 ha in 2008, 2,000,000 ha in 2014 with continued rapid increases in area. Kazakhstan is now included among the top ten countries with the largest areas under no-tillage in the world.展开更多
基金support from the National Natural Science Foundation of China(Nos.52370100,52000146,and 51978098)China Postdoctoral Science Foundation(No.2020M673351).
文摘Catalytic reduction of nitrate over bimetallic catalysts has emerged as a technology for sustainable treatment of nitrate-containing groundwater.However,the structure of bimetallic has been much less investigated for catalyst optimization.Herein,two main types of Pd-Cu bimetallic nanocrystal structures,heterostructure and intermetallic,were prepared and characterized using high-resolution transmission electron microscopy(HRTEM),X-ray diffraction(XRD),and X-ray photoelectron spectroscopy(XPS).The results show that two individual Pd and Cu nanocrystals with a mixed interface exist in the heterostructure nanocrystals,while Pd and Cu atoms are uniformly distributed across the intermetallic Pd-Cu nanocrystals.The catalytic nitrate reduction experiments were carried out in a semibatch reactor under constant hydrogen flow.The nitrate conversion rate of the heterostructure Pd-Cu nanocrystals supported onα-Al_(2)O_(3),γ-Al_(2)O_(3),SBA-15,and XC-72R exhibited 3.82-,6.76-,4.28-,2.44-fold enhancements relative to the intermetallic nanocrystals,and the nitrogen and nitrite were the main products for the heterostructure and intermetallic Pd-Cu nanocrystals,respectively.This indicates that the catalytic nitrate reduction over Pd-Cu catalyst is sensitive to the bimetallic structures of the catalysts,and heterostructure bimetallic nanocrystals exhibit better catalytic performances on both the activity and selectivity,which may provide new insights into the design and optimization of catalysts to improve catalytic activity and selectivity for nitrate reduction in water.
基金Supported by the Planning Project of Basic Scientific Research Funds of Chongqing(2012-esfc-jbky-00405)
文摘A total of 25 strains were isolated from the intestinal tract of Mystus macropterus. The inhibitory effects of extracellular enzyme activity to common aquat- ic pathogenic bacteria were screened. A probiotic DQHY -7 strain was isolated, and its safety was detected. DQHY -7 strain was preliminarily identified by mor- phological observation, and physiological and biochemical test. Research results showed that DQHY -7 strain had relatively strong production capacities of amylase, cellulase and protease, and could restrict the growth of Escherichia coli, Aeromonas hydrophila and Pseudomonas fluorescens. Results of acute toxicity test showed that 1. 0 × 108 CFU/mL DQHY -7 bacterial suspension showed no pathogenicity to M. macropterus. According to the colony growth pattern and physiological-bio- chemical characteristics of DQHY -7, the strain was identified to be Bacillus subtilis. Research results showed that DQHY -7 strain could be used as a new candi- date strain for feeding microecologicalagent.
文摘This paper analyzes the performance and operation of ecologically-based production systems in the Atlantic Forest in southern Brazil in an integrated approach to their multifunctional characteristics and rural development. Nowadays the Atlantic Forest is considered the most threatenet biome, because of exploitation of their biological resources and unsuitable agricultural purposes. Banana cultivation is one of biggest commercial productions in atlantic south portion of forest, showing two different cropping systems： one using conventional management tehniques and other antagonistic, ecological based. The ecological system is compatible with the conservation of sustainable use of forests. The article presents a comparative analysis-diagnosis of major production and cultivation systems of banana, using the production systems approach, with evaluation of economic and technical indicators. The database is composed by 17 interviews conducted under field conditions in 2007. As a result, the technical and economic functioning of ecological systems demonstrate achieve economic efficiency, in general, higher than conventional systems. Furthermore, some key characteristics of ecological based systems focus on food production and income generation for farmers without harming areas of the Atlantic Forest, being in equilibrium with tropical dynamic and being an important instrument for the restoration of degraded ecosystems and for local development.
文摘International Maize and Wheat Improvement Center （CIMMYT） and Kazakhstan collaborative activities on wheat improvement are focused in the following main areas： （1） wheat germplasm enhancement： Kazakhstan-Siberian Network on Wheat Improvement （KASIB） and Shuttle Breeding ＂Mexico-KASIB＂ Programs; （2） Conservation agriculture （CA） for wheat production and crop diversification. Nineteen breeding programs of Kazakhstan and Russia are united by KASIB Network and Shuttle Breeding. By 2014, more than 15,000 wheat lines and varieties were involved in breeding programs of Kazakhstan and Russia; 10 varieties were developed and released. The KASIB Network and Shuttle Breeding Program were recognized as one of the best example of the effective regional and international cooperation in Kazakhstan and Russia. In the beginning of 2000 CIMMYT, National Agricultural Research System, the Ministry of Agriculture, FAO, World Bank in cooperation with farmers initiated large-scale activities based on CA in Kazakhstan. Due the joint efforts, area under CA-based practices has been increasing from virtually none to an estimated area of 500,000 ha in 2007, 1,200,000 ha in 2008, 2,000,000 ha in 2014 with continued rapid increases in area. Kazakhstan is now included among the top ten countries with the largest areas under no-tillage in the world.
