Coal serves not only as a crucial energy resource but also as a significant reservoir of critical metal elements,including Lithium(Li),Gallium(Ga),Germanium(Ge),and rare earth elements(REE).This paper provides a syste...Coal serves not only as a crucial energy resource but also as a significant reservoir of critical metal elements,including Lithium(Li),Gallium(Ga),Germanium(Ge),and rare earth elements(REE).This paper provides a systematic review of the enrichment characteristics,occurrence modes,and comprehensive utilization potential of these critical metals in coal.Globally,the distribution of these metal resources exhibits significant regional heterogeneity.While the concentration in most coals falls below industrial cut-off grades,anomalous enrichment in specific coal basins results in Li,Ga,Ge,and REE concentrations far exceeding global averages,highlighting their considerable potential as unconventional metal deposits.The occurrence modes of these metals are diverse:Li is primarily hosted in mineral phases;Ga exists in inorganic,organic,and complex forms;Ge shows a strong association with organic matter;and REE are mainly present in adsorbed/isomorphic forms within clay minerals,while also displaying organic affinity.Direct extraction of metals from raw coal is often cost-prohibitive;effective recovery is therefore more feasible when integrated with coal processing.Metals are further enriched in solid wastes such as coal gangue,fly ash,and bottom ash,from which recovery is more economically and technically viable.Current comprehensive utilization primarily employs integrated mineral processing-hydrometallurgy approaches.Future research should focus on elucidating the precise occurrence forms of metals in coal and solid wastes,optimizing pre-treatment methods,and selecting effective activators and leachants.Advancing the synergistic extraction and green recovery of multiple associated resources from coal and its by-products is essential for achieving high-value,comprehensive utilization of coal-based resources.展开更多
The pervasive accumulation of plastic waste exacerbates environmental degradation and undermines resource circularity.Selective thermal catalysis emerges as a transformative pathway for valorizing waste plastics into ...The pervasive accumulation of plastic waste exacerbates environmental degradation and undermines resource circularity.Selective thermal catalysis emerges as a transformative pathway for valorizing waste plastics into value-added chemicals,yet persistent challenges in catalytic activity and product selectivity demand systematic resolution.This review decodes cutting-edge advances in thermal depolymerization by converging two critical dimensions:atomic-scale active site engineering-where rational design of coordination features and interfacial architectures regulates C-C cleavage energetics and intermediate adsorption-and macromolecular-scale manipulation of polymer transient states-leveraging nanoconfinement effects,chain folding dynamics,and thermal fragmentation to accelerate conversion kinetics.We further highlight breakthroughs in operando char-acterization techniques that resolve time-evolving reaction coordinates across catalytic systems.By establishing multiscale structure-activity relationships linking catalyst configurations to polymer dynamics,this analysis derives design paradigms for next-generation upcycling systems.These principles enable economically viable,industrially scalable plastic valorization while charting a strategic trajectory toward carbon-circular economies.展开更多
Traditional polymeric photocatalysts are typically constructed using aromatic building blocks to enhanceπ-conjugation.However,their inherent hydrophobicity and rigid structure lead to poor dispersibility in aqueous s...Traditional polymeric photocatalysts are typically constructed using aromatic building blocks to enhanceπ-conjugation.However,their inherent hydrophobicity and rigid structure lead to poor dispersibility in aqueous solutions,resulting in significant optical losses and exciton recombination.In this study,two series of six novel polymer photocatalysts(FLUSO,FLUSO-PEG10,FLUSO-PEG30;CPDTSO,CPDTSO-PEG10,CPDTSO-PEG30)are designed and synthesized by incorporating the hydrophilic,non-conjugated polyethylene glycol(PEG)chain,into both the main and side chains of polymers.By precisely optimizing the ratio of hydrophilic PEG segments,the water dispersibility is significantly improved while the light absorption capability of the polymer photocatalysts is well maintained.The experimental results confirm that the optimized FLUSO-PEG10 exhibits excellent photocatalytic hydrogen evolution rate,reaching up to 33.9 mmol/(g·h),which is nearly three times higher than that of fullyπ-conjugated counterparts.Water contact angles and particle size analyses reveal that incorporating non-conjugated segments into the main chains enhances the capacitance of the polymer/water interface and reduces particle aggregation,leading to improved photocatalyst dispersion and enhanced charge generation.展开更多
Considering the special features of dynamic environment economic dispatch of power systems with high dimensionality,strong coupling,nonlinearity,and non-convexity,a GA-DE multi-objective optimization algorithm based o...Considering the special features of dynamic environment economic dispatch of power systems with high dimensionality,strong coupling,nonlinearity,and non-convexity,a GA-DE multi-objective optimization algorithm based on dual-population pseudo-parallel genetic algorithm-differential evolution is proposed in this paper.The algorithm is based on external elite archive and Pareto dominance,and it adopts the cooperative co-evolution mechanism of differential evolution and genetic algorithm.Average entropy and cubic chaoticmapping initialization strategies are proposed to increase population diversity.In the proposed method,we analyze the distribution of neighboring solutions and apply a new Pareto solution set pruning approach.Unlike traditional models,this work takes the transmission losses as an optimization target and overcomes complex model constraints through a dynamic relaxation constraint approach.To solve the uncertainty caused by integrating wind and photovoltaic energy in power system scheduling,a multi-objective dynamic environment economical dispatch model is set up that takes the system spinning reserve and network highest losses into account.In this paper,the DE algorithm is improved to form the DGAGE algorithm for the objective optimization of the overall power system,The DE algorithm part of DGAGE is combined with the JAYA algorithm to form the system scheduling HDJ algorithm for multiple energy sources connected to the grid.The effectiveness of the proposed method is demonstrated using CEC2022 and CEC2005 test functions,showing robust optimization performance.Validation on a classical 10-unit system confirms the feasibility of the proposed algorithm in addressing power system scheduling issues.This approach provides a novel solution for dynamic power dispatch systems.展开更多
The electrocatalytic reduction of nitrate to ammonia(NO_(3)^(−)RR)offers a sustainable alternative to energy-intensive industrial NH3 synthesis.Tandem catalysis has shown promise in overcoming the multi-step complexit...The electrocatalytic reduction of nitrate to ammonia(NO_(3)^(−)RR)offers a sustainable alternative to energy-intensive industrial NH3 synthesis.Tandem catalysis has shown promise in overcoming the multi-step complexity of NO_(3)^(−)RR,yet challenges remain in optimizing performance and elucidating tandem mechanisms.Herein,we report a Cu@Co/CoFe-P tandem electrocatalyst featuring a phosphorus-doped heterostructure with dual active sites(Cu-P and Co/CoFe-P).This catalyst achieves an exceptional NH_(3)yield of 175.40 mg h^(−1)cm^(−2)and a record-high current density exceeding 2 A cm^(−2),with the electro-synthesized NH3 directly converted into NH4Cl.In situ spectroscopic analysis and density functional theory(DFT)calculations reveal a novel desorption-reactivation tandem mechanism:(1)the Cu-P domain preferentially reduces NO_(3)^(−)to*NO_(2),which desorbs as stable NO_(2)^(−);(2)the Co/CoFe-P domain subsequently reactivates NO_(2)^(−),and converts it efficiently into NH3.Moreover,phosphorus doping enhances*H supply,while Fe alloying with Co promotes NO_(2)^(−)hydrogenation,ensuring an efficient and synchronized tandem pathway for NO_(3)^(−)RR.The proposed*NO_(2)desorption-reactivation mechanism deepens the understanding of NO_(3)^(−)RR tandem process,thereby paving the way for designing more efficient tandem electrocatalysts.展开更多
The flotation separation of argentite from sphalerite using ammonium dibutyl dithiophosphate(ADD)was studied.Molecular simulation(MS)calculation shows that ADD is chemisorbed on argentite and sphalerite surface in the...The flotation separation of argentite from sphalerite using ammonium dibutyl dithiophosphate(ADD)was studied.Molecular simulation(MS)calculation shows that ADD is chemisorbed on argentite and sphalerite surface in the form of S—P bond.The ADD adsorption on argentite and sphalerite surface in Ag^(+)system was revealed by ICP,Zeta potential and XPS analyses.It is shown that the dissolved Ag^(+)from argentite surface can be absorbed on sphalerite surface in the form of silver hydroxide,and AgOH hydrophilic colloid prevents the adsorption of ADD on sphalerite surface.The ADD adsorption on argentite and sphalerite surface in the pulp containing silver and zinc ions was revealed by adsorption capacity and surface wettability analyses.It is shown that the combined Zn(OH)_(2) and AgOH hydrophilic colloid leads to greater ADD adsorption capacity on argentite surface and stronger surface hydrophobicity than sphalerite.Flotation tests demonstrate that ADD enables efficient separation of argentite from sphalerite in the pulp containing silver and zinc ions.展开更多
This study investigated the heterogeneous responses of organic matter(OM)in highly-to over-mature source rocks during thermal maturation.An integrated analysis was conducted on the Raman spectroscopic and geochemical ...This study investigated the heterogeneous responses of organic matter(OM)in highly-to over-mature source rocks during thermal maturation.An integrated analysis was conducted on the Raman spectroscopic and geochemical signatures of shales from the Lower Silurian Longmaxi Formation and the Lower Cambrian Qiongzhusi Formation,as well as anthracites from the Lower Permian Shanxi–Formation and the Upper Carboniferous Taiyuan Formation(collectively referred to as the Shanxi Taiyuan Formations).Additionally,burial and thermal evolution modeling was employed to support the analysis.A systematic assessment of Raman spectral parameters(e.g.,the positions and intensity ratio of the D and G bands)revealed robust correlations between the thermal history patterns of source rocks and molecular structural evolution parameters.The subsequent mechanistic quantification demonstrated that the maturation state of the source rocks was subjected to the hierarchical control of three principal factors:Peak heating temperature,the duration of sustained thermal intensity,and effective maturation duration.In addition,comparative analyses demonstrated that the anthracites attained higher structural ordering under sustained thermal conditions.This contrasts with the disordered carbon matrices observed in the intermittently heated shales.Raman spectroscopy further revealed broader variations in the D and G band intensities of the Longmaxi Formation compared to the Qiongzhusi Formation.This difference is associated with their different thermal histories.The thermal burial histories confirm that shales in the Longmaxi Formation underwent thermal exposure at lower peak temperatures over a shorter duration compared to those in the Qiongzhusi Formation.Finally,this study established a maturity calibration model for over-mature source rocks through a systematic correlation between Raman peak height ratios(R_(D/G))and vitrinite reflectance(R_(o)).展开更多
Rural domestic sewage treatment is critical for environmental protection.This study defines the spatial pattern of villages from the perspective of rural sewage treatment and develops an integrated decision-making sys...Rural domestic sewage treatment is critical for environmental protection.This study defines the spatial pattern of villages from the perspective of rural sewage treatment and develops an integrated decision-making system to propose a sewage treatment mode and scheme suitable for local conditions.By considering the village spatial layout and terrain factors,a decision tree model of residential density and terrain type was constructed with accuracies of 76.47%and 96.00%,respectively.Combined with binary classification probability unit regression,an appropriate sewage treatment mode for the village was determined with 87.00%accuracy.The Analytic Hierarchy Process(AHP),combined with the Technique for Order Preference(TOPSIS)by Similarity to an Ideal Solution model,formed the basis for optimal treatment process selection under different emission standards.Verification was conducted in 542 villages across three counties of the Inner Mongolia Autonomous Region,focusing on the standard effluent effect(0.3773),low investment cost(0.3196),and high standard effluent effect(0.5115)to determine the best treatment process for the same emission standard under different needs.The annual environmental and carbon emission benefits of sewage treatment in these villages were estimated.This model matches village density,geographic feature,and social development level,and provides scientific support and a theoretical basis for rural sewage treatment decision-making.展开更多
Tafoni are a type of cavernous weathering features widespread in different climate zones around the world,but their origin has not been fully understood.Little attention was paid on tafoni in conglomerates.Danxiashan ...Tafoni are a type of cavernous weathering features widespread in different climate zones around the world,but their origin has not been fully understood.Little attention was paid on tafoni in conglomerates.Danxiashan UNESCO Global Geopark,located within the subtropic humid region of South China,has a landscape of large tafoni that occur on cliffs of red conglomerates.Both the Dinosaur Rock and Pagoda Peak of the geopark were selected to investigate the formation mechanisms of tafoni in conglomerates.During the field investigation,the size,rock hardness,and the external and internal meteorology of tafoni were measured and tested.The texture and composition of rock samples were observed,and the ion chromatography experiments were performed as well.Results show that tafoni have well ellipsoidal openings.Clasts of the conglomerates are largely sub-rounded and poorly sorted,and the cement is dominantly composed of calcite and iron oxide.The hardness of the lips is almost equal to that of the columns,and both are slightly higher than the backwalls.Compared with the external intense environmental changes,the interior of the tafoni is characterized by smaller temperature and relative humidity ranges and windless condition.Therefore,the porous and permeable conglomerates provide favorable lithology for tafoni development,and the micro-environment within the caverns is conducive to improving water utilization efficiency and enhancing salt weathering.The salts mainly consist of sulfates and nitrates,which might be derived from frequent raining,water evaporation and red beds as well.Consequently,tafoni are the result of the synergistic effects by multiple factors,rather than a single mechanism.展开更多
Based on the carrying capacity of the resources and the environment,this article defines the connotation of the land multifunctional space(LMFS)from three aspects,ecological protection,agricultural production and urba...Based on the carrying capacity of the resources and the environment,this article defines the connotation of the land multifunctional space(LMFS)from three aspects,ecological protection,agricultural production and urban construction,in the new era of land space planning system.Moreover,a framework is constructed for the coordinated development of the multi-functional oriented space to match the use of land space(ULS)with the supply of resources and environment(SRE).Based on this,the technology and methods of comprehensive evaluation,dominance recognition,and matching relationship division functions of the use of land space(FULS)and functions of the supply of resources and environment(FSRE)are discussed.The advantageous functions of the use of land space(AFULS)and advantageous functions of the supply of resources and environment(AFSRE)are also identified in the study area.A LMFS coordinated development system integrating“function position-comprehensive partition-regulation strategy”is proposed.Through the empirical study of Shandong province,we found that,first,the FULS of ecological protection space in the province is mainly found in high value areas,and the FSRE is mainly in low value areas,which has certain complementarity in the space.The FULS of agricultural production space is mainly observed in high value areas,the FSRE is mainly in middle value areas,and the spatial distribution is balanced and staggered.The FULS of the urban construction space and the FSRE are mainly in middle values areas,and the spatial distribution is basically similar.Second,the FULS in the study area is dominated by the single advantage of agricultural production and urban construction,while the FSRE has a relatively balanced distribution of the advantages of ecological protection,single agricultural production and compound advantages of agricultural production and urban construction,and urban construction and ecological protection.The matching between the two is mainly at high and middle levels.Specifically,70%of the province’s land space still has a certain development and utilization potential,and 30%of ULS intensity is close to or exceeds the resource and environment carrying capacity.Third,considering the comprehensive impact of resource endowment,social and economic development and policy and institutional environment on different matching relationships,this paper constructs the land spatial development strategic pattern of“two screens-seven regions-multicore”positioning and“four regions-eight categories”hierarchical area of Shandong at the macro level,and puts forward a differentiated land space development strategy.展开更多
A novel environmental friendly wheat seed coating agent was prepared from the natural polymer,biological pesticide,microfertilizer,microelements and other additives.The laboratory and field test results showed that it...A novel environmental friendly wheat seed coating agent was prepared from the natural polymer,biological pesticide,microfertilizer,microelements and other additives.The laboratory and field test results showed that it could enhance the yield up to 16% and reduce its input cost to 1/6 as compared with the conventional wheat seed coating agent.It is safe without causing any pollution and would have significant economic and environmental benefits.展开更多
The exploitation of coal resources inevitably affects, to different degrees, arable land resources and impacts the socio-economic development in mining areas. Therefore it is of great practical importance to probe the...The exploitation of coal resources inevitably affects, to different degrees, arable land resources and impacts the socio-economic development in mining areas. Therefore it is of great practical importance to probe the rules of the effect from coal resource exploration on arable land. Suitable and effective measures to compensate for damaged to and loss of arable land resources should be taken on the basis of carrying out green mining and reducing damage to limited arable land resources. We have used GIS in simulating the effect of coal resource exploration on arable land. In light of our simulation of the space-time spectrum, the effect is analyzed. Given the socio-economic development conditions of a mining area, specified rational amounts and opportunities for compensation to arable land in mining areas are explored. Finally, from a policy perspective, relevant proposals for rational arable land resource compensation are proposed to facilitate the coordinated development between coal resource exploitation and socio-economy development in mining areas.展开更多
1.Introduction In recent years,China has carried out an extensive preventative battle against air,water,and soil pollution,and the nation’s environmental quality-as reflected by conventional pollutant indicators—has...1.Introduction In recent years,China has carried out an extensive preventative battle against air,water,and soil pollution,and the nation’s environmental quality-as reflected by conventional pollutant indicators—has significantly improved.At the same time,the issue of emerging contaminants(ECs)is beginning to receive increasing attention.ECs generally refer to newly discovered or noticeable pollutants that pose risks to the ecological environment or human health.Either they have not been included in environmental management,or existing management measures are insufficient to effectively prevent and control their risks.The ECs of greatest concern generally include persistent organic pollutants(POPs),endocrine-disrupting chemicals(EDCs),pharmaceuticals and personal care products(PPCPs),and microplastics.These four categories of ECs are not entirely separate,as they interrelate with each other(Fig.1).Chemical production and product usage are the main sources of ECs.China is the world’s largest producer and consumer of bulk chemicals,and the production value of China’s chemical industry is predicted to reach 50%of the global total by 2030[1].Scientific control of ECs based on their environmental risk assessment is a necessary way to support the prevention and legal governance of ECs.展开更多
Through denoting each expert as an agent and viewing a multiple criteria decision-making as a synthesis problem of aggregating experts＇ ratings, a multi-agent blind model （MABM） is developed for regional eco-enviro...Through denoting each expert as an agent and viewing a multiple criteria decision-making as a synthesis problem of aggregating experts＇ ratings, a multi-agent blind model （MABM） is developed for regional eco-environmental quality assessment. In this model, the ratings of the evaluated object under an index, given by expert group, are first utilized to construct a series of blind numbers. In general, each index will correspond to different blind numbers. On the basis of aggregating index weights, the rank score in the form of a blind number is obtained for the evaluated object. Then, by means of calculating expected value of the above blind number, its rank score is further converted into a crisp value. By way of comparing the expected value with classification standards, eco-environmental quality of the evaluated sample could he identified successfully in the end. As a case, the MABM is used to evaluate the eco-environmental quality of Chaohu Lake basin. Study result shows that the MABM is a useful model for regional eco-environmental quality assessment.展开更多
Solidification/stabilization （S/S） is one of the most effective methods of dealing with heavy metal contaminated soils. The effects of cyclic wetting and drying on solidified/stabilized contaminated soils were inves...Solidification/stabilization （S/S） is one of the most effective methods of dealing with heavy metal contaminated soils. The effects of cyclic wetting and drying on solidified/stabilized contaminated soils were investigated. A series of test program, unconfined compressive strength （UCS） test, TCLP leaching test and scanning electron microscopy （SEM） test, were performed on lead and zinc contaminated soils solidified/stabilized by fly ash. Test results show that UCS and the leaching characteristics of heavy metal ions of S/S contaminated soils are significantly improved with the increase of fly ash content. UCS of S/S soils firstly increases with the increase of the times of drying and wetting cycles, after reaching the peak, it decreases with it. When the pollutant content is lower （1 000 mg/kg）, the TCLP concentration first slightly decreases under cyclic drying and wetting, then increases, but the change is minor. The TCLP concentration is higher under a high pollutant content of 5 000 mg/kg, and increases with the increase of the times of drying and wetting cycles. The results of scanning electron microscopy （SEM） test are consistent with UCS tests and TCLP leaching tests, which reveals the micro-mechanism of the variations of engineering properties of stabilized contaminated soils after drying and wetting cycles.展开更多
Geomechanical parameters are complex and uncertain.In order to take this complexity and uncertainty into account,a probabilistic back-analysis method combining the Bayesian probability with the least squares support v...Geomechanical parameters are complex and uncertain.In order to take this complexity and uncertainty into account,a probabilistic back-analysis method combining the Bayesian probability with the least squares support vector machine(LS-SVM) technique was proposed.The Bayesian probability was used to deal with the uncertainties in the geomechanical parameters,and an LS-SVM was utilized to establish the relationship between the displacement and the geomechanical parameters.The proposed approach was applied to the geomechanical parameter identification in a slope stability case study which was related to the permanent ship lock within the Three Gorges project in China.The results indicate that the proposed method presents the uncertainties in the geomechanical parameters reasonably well,and also improves the understanding that the monitored information is important in real projects.展开更多
In the context of global degradation and loss of natural wetlands,waterbirds have been increasingly using artificial wetlands as alternative habitats.However,waterbirds are facing various threats in these artificial w...In the context of global degradation and loss of natural wetlands,waterbirds have been increasingly using artificial wetlands as alternative habitats.However,waterbirds are facing various threats in these artificial wetlands,due to dramatic environmental changes induced by anthropogenic activities.Exploring the effects of these changes on the temporal dynamics of the waterbird communities can help understand how waterbirds adapt to environmental changes and thus formulate effective management and conservation plans.In this study,we carried out field surveys on waterbirds and environmental factors across 20 subsidence wetlands created by underground coal mining in the Huainan coal mining area in the breeding seasons of 2016 and 2021.We predicted that the waterbird assemblages(i.e.,number of individuals,species richness,Shannon-Wiener diversity,Pielou evenness and species composition) differed between the two years,and that these differences were correlated with the temporal changes in environmental factors.Across the surveyed wetlands,we recorded 26 waterbird species in 2016 and 23 in 2021.For individual wetlands,the number of waterbird individuals and species richness increased by 71.6% and 20.1%,respectively,over the five years,with no changes in Shannon-Wiener diversity and Pielou evenness.The overall increase in the number of bird individuals was mainly caused by an increase in vegetation gleaners and gulls that adapt well to anthropogenic activities.The species composition was significantly different between the two years,which was mainly caused by changes in the number of individuals of dominant species under influence of changes in human activities.For most wetlands,the temporal pairwiseβ-diversities could be explained by species turnover rather than nestedness,probably due to high mobility of waterbird species and dramatic changes in local environments.Our study suggests that waterbird communities could respond to environmental changes in subsidence wetlands,providing important implications for waterbird conservation in human-dominated artificial wetlands.展开更多
Based on Remote Sensing （RS）, Geographic Information System （GIS）, and combining Principal Component Analysis, this paper designed a numerical integrated evaluation model for mountain eco-environment on the base ...Based on Remote Sensing （RS）, Geographic Information System （GIS）, and combining Principal Component Analysis, this paper designed a numerical integrated evaluation model for mountain eco-environment on the base of grid scale. Using this model, we evaluated the mountain eco-environmental quality in a case study area-the upper reaches of Minjiang River, and achieved a good result, which accorded well with the real condition. The study indicates that, the integrated evaluation model is suitable for multi-layer spatial factor computation, effectively lowing man＇s subjective influence in the evaluation process; treating the whole river basin as a system, the model shows full respect to the circulation of material and energy, synthetically embodies the determining impact of such natural condition as water-heat and landform, as well as human interference in natural eco-system; the evaluation result not only clearly presents mountainous vertical distribution features of input factors, but also provides a scientific and reliable thought for quantitatively evaluating mountain eco-environment.展开更多
Bandgap engineering through single-atom site binding on semiconducting photocatalyst can boost the intrinsic activity,selectivity,carrier separation,and electron transport.Here,we report a mixed-valence Ag(0)and Ag(I)...Bandgap engineering through single-atom site binding on semiconducting photocatalyst can boost the intrinsic activity,selectivity,carrier separation,and electron transport.Here,we report a mixed-valence Ag(0)and Ag(I)single atoms co-decorated semiconducting chalcopyrite quantum dots(Ag/CuFeS_(2)QDs)photocatalyst.It demonstrates efficient photocatalytic performances for specific organic dye(rhodamine B,denoted as RhB)as well as inorganic dye(Cr(VI))removal in water under natural sunlight irradiation.The RhB degradation and Cr(VI)removal efficiencies by Ag/CuFeS_(2)QDs were 3.55 and 6.75 times higher than those of the naked CuFeS_(2)QDs at their optimal pH conditions,respectively.Besides,in a mixture of RhB and Cr(VI)solution under neutral condition,the removal ratio has been elevated from 30.2%to 79.4%for Cr(VI),and from 95.2%to 97.3%for RhB degradation by using Ag/CuFeS_(2)QDs after 2 h sunlight illumination.The intrinsic mechanism for the photocatalytic performance improvement is attributed to the narrow bandgap of the single-atomic Ag(I)anchored CuFeS_(2)QDs,which engineers the electronic structure as well as expands the optical light response range.Significantly,the highly active Ag(0)/CuFeS_(2)and Ag(I)/CuFeS_(2)effectively improve the separation efficiency of the carriers,thus enhancing the photocatalytic performances.This work presents a highly efficient single atom/QDs photocatalyst,constructed through bandgap engineering via mixed-valence single noble metal atoms binding on semiconducting QDs.It paves the way for developing high-efficiency single-atom photocatalysts for complex pollutions removal in dyeing wastewater environment.展开更多
Studied the content and distribution of 18 environmental hazardous trace elementsin the lignite, fatty coal, anthracite and its burnt products by combustion simulatingexpriment in the one-dismensinal boiler.The transf...Studied the content and distribution of 18 environmental hazardous trace elementsin the lignite, fatty coal, anthracite and its burnt products by combustion simulatingexpriment in the one-dismensinal boiler.The transformations and concentration of 18 traceelements during different coal combustion were discussed.The results show that there aresome content distribution of 18 hazardous trace elements in every burnt product, but thelaw of concentration and dispersion of every trace element during different coal combustionis very different.Experiment results indicate that the transformation and concentrationof trace elements during coal combustion are related to the element contents and occur-rencesof trace elements in raw coal, but are also affected by some man-made factorssuch as the combustion method of boiler, combustion temperature and atmosphere, thetype of precipitators and so on.展开更多
基金supported by the Key Support Project of Regional Innovation and Development Joint Fund of the National Natural Science Foundation of China(No.U24A2095).
文摘Coal serves not only as a crucial energy resource but also as a significant reservoir of critical metal elements,including Lithium(Li),Gallium(Ga),Germanium(Ge),and rare earth elements(REE).This paper provides a systematic review of the enrichment characteristics,occurrence modes,and comprehensive utilization potential of these critical metals in coal.Globally,the distribution of these metal resources exhibits significant regional heterogeneity.While the concentration in most coals falls below industrial cut-off grades,anomalous enrichment in specific coal basins results in Li,Ga,Ge,and REE concentrations far exceeding global averages,highlighting their considerable potential as unconventional metal deposits.The occurrence modes of these metals are diverse:Li is primarily hosted in mineral phases;Ga exists in inorganic,organic,and complex forms;Ge shows a strong association with organic matter;and REE are mainly present in adsorbed/isomorphic forms within clay minerals,while also displaying organic affinity.Direct extraction of metals from raw coal is often cost-prohibitive;effective recovery is therefore more feasible when integrated with coal processing.Metals are further enriched in solid wastes such as coal gangue,fly ash,and bottom ash,from which recovery is more economically and technically viable.Current comprehensive utilization primarily employs integrated mineral processing-hydrometallurgy approaches.Future research should focus on elucidating the precise occurrence forms of metals in coal and solid wastes,optimizing pre-treatment methods,and selecting effective activators and leachants.Advancing the synergistic extraction and green recovery of multiple associated resources from coal and its by-products is essential for achieving high-value,comprehensive utilization of coal-based resources.
基金supported by the Key Technologies Research and Development Program(2024YFC2909605)Black Soil Project of Shenyang Science and Technology Program(24-216-2-07)Fundamental Research Funds for the Central Universities(NO.N25BSS006).
文摘The pervasive accumulation of plastic waste exacerbates environmental degradation and undermines resource circularity.Selective thermal catalysis emerges as a transformative pathway for valorizing waste plastics into value-added chemicals,yet persistent challenges in catalytic activity and product selectivity demand systematic resolution.This review decodes cutting-edge advances in thermal depolymerization by converging two critical dimensions:atomic-scale active site engineering-where rational design of coordination features and interfacial architectures regulates C-C cleavage energetics and intermediate adsorption-and macromolecular-scale manipulation of polymer transient states-leveraging nanoconfinement effects,chain folding dynamics,and thermal fragmentation to accelerate conversion kinetics.We further highlight breakthroughs in operando char-acterization techniques that resolve time-evolving reaction coordinates across catalytic systems.By establishing multiscale structure-activity relationships linking catalyst configurations to polymer dynamics,this analysis derives design paradigms for next-generation upcycling systems.These principles enable economically viable,industrially scalable plastic valorization while charting a strategic trajectory toward carbon-circular economies.
文摘Traditional polymeric photocatalysts are typically constructed using aromatic building blocks to enhanceπ-conjugation.However,their inherent hydrophobicity and rigid structure lead to poor dispersibility in aqueous solutions,resulting in significant optical losses and exciton recombination.In this study,two series of six novel polymer photocatalysts(FLUSO,FLUSO-PEG10,FLUSO-PEG30;CPDTSO,CPDTSO-PEG10,CPDTSO-PEG30)are designed and synthesized by incorporating the hydrophilic,non-conjugated polyethylene glycol(PEG)chain,into both the main and side chains of polymers.By precisely optimizing the ratio of hydrophilic PEG segments,the water dispersibility is significantly improved while the light absorption capability of the polymer photocatalysts is well maintained.The experimental results confirm that the optimized FLUSO-PEG10 exhibits excellent photocatalytic hydrogen evolution rate,reaching up to 33.9 mmol/(g·h),which is nearly three times higher than that of fullyπ-conjugated counterparts.Water contact angles and particle size analyses reveal that incorporating non-conjugated segments into the main chains enhances the capacitance of the polymer/water interface and reduces particle aggregation,leading to improved photocatalyst dispersion and enhanced charge generation.
基金funded by the Major Humanities and Social Sciences Research Projects in Zhejiang Higher Education Institutions,grant number 2023QN131National Innovation Training Program Project in China,grant number 202410451009.
文摘Considering the special features of dynamic environment economic dispatch of power systems with high dimensionality,strong coupling,nonlinearity,and non-convexity,a GA-DE multi-objective optimization algorithm based on dual-population pseudo-parallel genetic algorithm-differential evolution is proposed in this paper.The algorithm is based on external elite archive and Pareto dominance,and it adopts the cooperative co-evolution mechanism of differential evolution and genetic algorithm.Average entropy and cubic chaoticmapping initialization strategies are proposed to increase population diversity.In the proposed method,we analyze the distribution of neighboring solutions and apply a new Pareto solution set pruning approach.Unlike traditional models,this work takes the transmission losses as an optimization target and overcomes complex model constraints through a dynamic relaxation constraint approach.To solve the uncertainty caused by integrating wind and photovoltaic energy in power system scheduling,a multi-objective dynamic environment economical dispatch model is set up that takes the system spinning reserve and network highest losses into account.In this paper,the DE algorithm is improved to form the DGAGE algorithm for the objective optimization of the overall power system,The DE algorithm part of DGAGE is combined with the JAYA algorithm to form the system scheduling HDJ algorithm for multiple energy sources connected to the grid.The effectiveness of the proposed method is demonstrated using CEC2022 and CEC2005 test functions,showing robust optimization performance.Validation on a classical 10-unit system confirms the feasibility of the proposed algorithm in addressing power system scheduling issues.This approach provides a novel solution for dynamic power dispatch systems.
基金supported financially by the Key Project of the National Ministry of Science and Technology (No.2022YFC3705005)the Open Foundation of Key Laboratory of Industrial Ecology and Environmental Engineering,MOE (KLIEEE-22-05)
文摘The electrocatalytic reduction of nitrate to ammonia(NO_(3)^(−)RR)offers a sustainable alternative to energy-intensive industrial NH3 synthesis.Tandem catalysis has shown promise in overcoming the multi-step complexity of NO_(3)^(−)RR,yet challenges remain in optimizing performance and elucidating tandem mechanisms.Herein,we report a Cu@Co/CoFe-P tandem electrocatalyst featuring a phosphorus-doped heterostructure with dual active sites(Cu-P and Co/CoFe-P).This catalyst achieves an exceptional NH_(3)yield of 175.40 mg h^(−1)cm^(−2)and a record-high current density exceeding 2 A cm^(−2),with the electro-synthesized NH3 directly converted into NH4Cl.In situ spectroscopic analysis and density functional theory(DFT)calculations reveal a novel desorption-reactivation tandem mechanism:(1)the Cu-P domain preferentially reduces NO_(3)^(−)to*NO_(2),which desorbs as stable NO_(2)^(−);(2)the Co/CoFe-P domain subsequently reactivates NO_(2)^(−),and converts it efficiently into NH3.Moreover,phosphorus doping enhances*H supply,while Fe alloying with Co promotes NO_(2)^(−)hydrogenation,ensuring an efficient and synchronized tandem pathway for NO_(3)^(−)RR.The proposed*NO_(2)desorption-reactivation mechanism deepens the understanding of NO_(3)^(−)RR tandem process,thereby paving the way for designing more efficient tandem electrocatalysts.
基金the support from the National Key Research and Development Program of China (No. 2022YFC2904504)the Science and Technology Research Project of Jiangxi Provincial Department of Education, China (No. GJJ2200864)the Gansu Provincial Key Research and Development Project, China (No. 22YF7GA073)。
文摘The flotation separation of argentite from sphalerite using ammonium dibutyl dithiophosphate(ADD)was studied.Molecular simulation(MS)calculation shows that ADD is chemisorbed on argentite and sphalerite surface in the form of S—P bond.The ADD adsorption on argentite and sphalerite surface in Ag^(+)system was revealed by ICP,Zeta potential and XPS analyses.It is shown that the dissolved Ag^(+)from argentite surface can be absorbed on sphalerite surface in the form of silver hydroxide,and AgOH hydrophilic colloid prevents the adsorption of ADD on sphalerite surface.The ADD adsorption on argentite and sphalerite surface in the pulp containing silver and zinc ions was revealed by adsorption capacity and surface wettability analyses.It is shown that the combined Zn(OH)_(2) and AgOH hydrophilic colloid leads to greater ADD adsorption capacity on argentite surface and stronger surface hydrophobicity than sphalerite.Flotation tests demonstrate that ADD enables efficient separation of argentite from sphalerite in the pulp containing silver and zinc ions.
基金supported by the National Natural Science Foundation of China(42362022)the Open Fund of the Shaanxi Key Laboratory of Petroleum Accumulation Geology(PAG-202406)the Open Fund of the Mine Geology and Environment Academician and Expert Workstation(2024OITYSZJGZZ-005)。
文摘This study investigated the heterogeneous responses of organic matter(OM)in highly-to over-mature source rocks during thermal maturation.An integrated analysis was conducted on the Raman spectroscopic and geochemical signatures of shales from the Lower Silurian Longmaxi Formation and the Lower Cambrian Qiongzhusi Formation,as well as anthracites from the Lower Permian Shanxi–Formation and the Upper Carboniferous Taiyuan Formation(collectively referred to as the Shanxi Taiyuan Formations).Additionally,burial and thermal evolution modeling was employed to support the analysis.A systematic assessment of Raman spectral parameters(e.g.,the positions and intensity ratio of the D and G bands)revealed robust correlations between the thermal history patterns of source rocks and molecular structural evolution parameters.The subsequent mechanistic quantification demonstrated that the maturation state of the source rocks was subjected to the hierarchical control of three principal factors:Peak heating temperature,the duration of sustained thermal intensity,and effective maturation duration.In addition,comparative analyses demonstrated that the anthracites attained higher structural ordering under sustained thermal conditions.This contrasts with the disordered carbon matrices observed in the intermittently heated shales.Raman spectroscopy further revealed broader variations in the D and G band intensities of the Longmaxi Formation compared to the Qiongzhusi Formation.This difference is associated with their different thermal histories.The thermal burial histories confirm that shales in the Longmaxi Formation underwent thermal exposure at lower peak temperatures over a shorter duration compared to those in the Qiongzhusi Formation.Finally,this study established a maturity calibration model for over-mature source rocks through a systematic correlation between Raman peak height ratios(R_(D/G))and vitrinite reflectance(R_(o)).
基金supported by the Central Government Guiding Local Science and Technology Development Fund Project(No.2024SZY0343)the Joint Research Program for Ecological Conservation and High Quality Development of the Yellow River Basin(No.2022-YRUC-01-050205)+2 种基金the Higher Education Scientific Research Project of Inner Mongolia Autonomous Region(No.NJZZ23078)the project of Inner Mongolia"Prairie Talents"Engineering Innovation Entrepreneurship Talent Team,the Major Projects of Erdos Science and Technology(No.2022EEDSKJZDZX015)the Innovation Team of the Inner Mongolia Academy of Science and Technology(No.CXTD2023-01-016).
文摘Rural domestic sewage treatment is critical for environmental protection.This study defines the spatial pattern of villages from the perspective of rural sewage treatment and develops an integrated decision-making system to propose a sewage treatment mode and scheme suitable for local conditions.By considering the village spatial layout and terrain factors,a decision tree model of residential density and terrain type was constructed with accuracies of 76.47%and 96.00%,respectively.Combined with binary classification probability unit regression,an appropriate sewage treatment mode for the village was determined with 87.00%accuracy.The Analytic Hierarchy Process(AHP),combined with the Technique for Order Preference(TOPSIS)by Similarity to an Ideal Solution model,formed the basis for optimal treatment process selection under different emission standards.Verification was conducted in 542 villages across three counties of the Inner Mongolia Autonomous Region,focusing on the standard effluent effect(0.3773),low investment cost(0.3196),and high standard effluent effect(0.5115)to determine the best treatment process for the same emission standard under different needs.The annual environmental and carbon emission benefits of sewage treatment in these villages were estimated.This model matches village density,geographic feature,and social development level,and provides scientific support and a theoretical basis for rural sewage treatment decision-making.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.41962009,41772197)the Innovation Fund of East China University of Technology(Grant No.DHYC202007)。
文摘Tafoni are a type of cavernous weathering features widespread in different climate zones around the world,but their origin has not been fully understood.Little attention was paid on tafoni in conglomerates.Danxiashan UNESCO Global Geopark,located within the subtropic humid region of South China,has a landscape of large tafoni that occur on cliffs of red conglomerates.Both the Dinosaur Rock and Pagoda Peak of the geopark were selected to investigate the formation mechanisms of tafoni in conglomerates.During the field investigation,the size,rock hardness,and the external and internal meteorology of tafoni were measured and tested.The texture and composition of rock samples were observed,and the ion chromatography experiments were performed as well.Results show that tafoni have well ellipsoidal openings.Clasts of the conglomerates are largely sub-rounded and poorly sorted,and the cement is dominantly composed of calcite and iron oxide.The hardness of the lips is almost equal to that of the columns,and both are slightly higher than the backwalls.Compared with the external intense environmental changes,the interior of the tafoni is characterized by smaller temperature and relative humidity ranges and windless condition.Therefore,the porous and permeable conglomerates provide favorable lithology for tafoni development,and the micro-environment within the caverns is conducive to improving water utilization efficiency and enhancing salt weathering.The salts mainly consist of sulfates and nitrates,which might be derived from frequent raining,water evaporation and red beds as well.Consequently,tafoni are the result of the synergistic effects by multiple factors,rather than a single mechanism.
基金National Natural Science Foundation of China,No.42077434,No.41771560Shandong Provincial Institutions of Higher Learning“Youth Innovation Team Development Plan”Project,No.2019RWG016。
文摘Based on the carrying capacity of the resources and the environment,this article defines the connotation of the land multifunctional space(LMFS)from three aspects,ecological protection,agricultural production and urban construction,in the new era of land space planning system.Moreover,a framework is constructed for the coordinated development of the multi-functional oriented space to match the use of land space(ULS)with the supply of resources and environment(SRE).Based on this,the technology and methods of comprehensive evaluation,dominance recognition,and matching relationship division functions of the use of land space(FULS)and functions of the supply of resources and environment(FSRE)are discussed.The advantageous functions of the use of land space(AFULS)and advantageous functions of the supply of resources and environment(AFSRE)are also identified in the study area.A LMFS coordinated development system integrating“function position-comprehensive partition-regulation strategy”is proposed.Through the empirical study of Shandong province,we found that,first,the FULS of ecological protection space in the province is mainly found in high value areas,and the FSRE is mainly in low value areas,which has certain complementarity in the space.The FULS of agricultural production space is mainly observed in high value areas,the FSRE is mainly in middle value areas,and the spatial distribution is balanced and staggered.The FULS of the urban construction space and the FSRE are mainly in middle values areas,and the spatial distribution is basically similar.Second,the FULS in the study area is dominated by the single advantage of agricultural production and urban construction,while the FSRE has a relatively balanced distribution of the advantages of ecological protection,single agricultural production and compound advantages of agricultural production and urban construction,and urban construction and ecological protection.The matching between the two is mainly at high and middle levels.Specifically,70%of the province’s land space still has a certain development and utilization potential,and 30%of ULS intensity is close to or exceeds the resource and environment carrying capacity.Third,considering the comprehensive impact of resource endowment,social and economic development and policy and institutional environment on different matching relationships,this paper constructs the land spatial development strategic pattern of“two screens-seven regions-multicore”positioning and“four regions-eight categories”hierarchical area of Shandong at the macro level,and puts forward a differentiated land space development strategy.
基金supported by the Scientific and Tech-nological Project of Zhejiang Province,China (ZK-20061103)
文摘A novel environmental friendly wheat seed coating agent was prepared from the natural polymer,biological pesticide,microfertilizer,microelements and other additives.The laboratory and field test results showed that it could enhance the yield up to 16% and reduce its input cost to 1/6 as compared with the conventional wheat seed coating agent.It is safe without causing any pollution and would have significant economic and environmental benefits.
基金Project 50774080 supported by the National Natural Science Foundation of China
文摘The exploitation of coal resources inevitably affects, to different degrees, arable land resources and impacts the socio-economic development in mining areas. Therefore it is of great practical importance to probe the rules of the effect from coal resource exploration on arable land. Suitable and effective measures to compensate for damaged to and loss of arable land resources should be taken on the basis of carrying out green mining and reducing damage to limited arable land resources. We have used GIS in simulating the effect of coal resource exploration on arable land. In light of our simulation of the space-time spectrum, the effect is analyzed. Given the socio-economic development conditions of a mining area, specified rational amounts and opportunities for compensation to arable land in mining areas are explored. Finally, from a policy perspective, relevant proposals for rational arable land resource compensation are proposed to facilitate the coordinated development between coal resource exploitation and socio-economy development in mining areas.
基金supported by the Major Project of National Natural Science Foundation of China(52091544).
文摘1.Introduction In recent years,China has carried out an extensive preventative battle against air,water,and soil pollution,and the nation’s environmental quality-as reflected by conventional pollutant indicators—has significantly improved.At the same time,the issue of emerging contaminants(ECs)is beginning to receive increasing attention.ECs generally refer to newly discovered or noticeable pollutants that pose risks to the ecological environment or human health.Either they have not been included in environmental management,or existing management measures are insufficient to effectively prevent and control their risks.The ECs of greatest concern generally include persistent organic pollutants(POPs),endocrine-disrupting chemicals(EDCs),pharmaceuticals and personal care products(PPCPs),and microplastics.These four categories of ECs are not entirely separate,as they interrelate with each other(Fig.1).Chemical production and product usage are the main sources of ECs.China is the world’s largest producer and consumer of bulk chemicals,and the production value of China’s chemical industry is predicted to reach 50%of the global total by 2030[1].Scientific control of ECs based on their environmental risk assessment is a necessary way to support the prevention and legal governance of ECs.
基金Under the auspices of the Natural Science Foundation of Anhui Province (No. 050450303 )
文摘Through denoting each expert as an agent and viewing a multiple criteria decision-making as a synthesis problem of aggregating experts＇ ratings, a multi-agent blind model （MABM） is developed for regional eco-environmental quality assessment. In this model, the ratings of the evaluated object under an index, given by expert group, are first utilized to construct a series of blind numbers. In general, each index will correspond to different blind numbers. On the basis of aggregating index weights, the rank score in the form of a blind number is obtained for the evaluated object. Then, by means of calculating expected value of the above blind number, its rank score is further converted into a crisp value. By way of comparing the expected value with classification standards, eco-environmental quality of the evaluated sample could he identified successfully in the end. As a case, the MABM is used to evaluate the eco-environmental quality of Chaohu Lake basin. Study result shows that the MABM is a useful model for regional eco-environmental quality assessment.
基金Foundation item： Projects（41172273, 40802079, 51108288） supported by the National Natural Science Foundation of China Project（KLE-TJGE-B1106） supported by the Opening Fund of Key Laboratory of Geotechnical and Underground Engineering of Ministry of Education （Tongji University）, China
文摘Solidification/stabilization （S/S） is one of the most effective methods of dealing with heavy metal contaminated soils. The effects of cyclic wetting and drying on solidified/stabilized contaminated soils were investigated. A series of test program, unconfined compressive strength （UCS） test, TCLP leaching test and scanning electron microscopy （SEM） test, were performed on lead and zinc contaminated soils solidified/stabilized by fly ash. Test results show that UCS and the leaching characteristics of heavy metal ions of S/S contaminated soils are significantly improved with the increase of fly ash content. UCS of S/S soils firstly increases with the increase of the times of drying and wetting cycles, after reaching the peak, it decreases with it. When the pollutant content is lower （1 000 mg/kg）, the TCLP concentration first slightly decreases under cyclic drying and wetting, then increases, but the change is minor. The TCLP concentration is higher under a high pollutant content of 5 000 mg/kg, and increases with the increase of the times of drying and wetting cycles. The results of scanning electron microscopy （SEM） test are consistent with UCS tests and TCLP leaching tests, which reveals the micro-mechanism of the variations of engineering properties of stabilized contaminated soils after drying and wetting cycles.
基金Projects(2013BAB02B01,2013BAB02B03)supported by the National Key Technologies R&D Program of ChinaProjects(41072224,41272347)supported by the National Natural Science Foundation of China
文摘Geomechanical parameters are complex and uncertain.In order to take this complexity and uncertainty into account,a probabilistic back-analysis method combining the Bayesian probability with the least squares support vector machine(LS-SVM) technique was proposed.The Bayesian probability was used to deal with the uncertainties in the geomechanical parameters,and an LS-SVM was utilized to establish the relationship between the displacement and the geomechanical parameters.The proposed approach was applied to the geomechanical parameter identification in a slope stability case study which was related to the permanent ship lock within the Three Gorges project in China.The results indicate that the proposed method presents the uncertainties in the geomechanical parameters reasonably well,and also improves the understanding that the monitored information is important in real projects.
基金the National Natural Science Foundation of China(grant 31970500 and 31770571)the Excellent Youth Project of the Anhui Natural Science Foundation(grant 2108085Y09)。
文摘In the context of global degradation and loss of natural wetlands,waterbirds have been increasingly using artificial wetlands as alternative habitats.However,waterbirds are facing various threats in these artificial wetlands,due to dramatic environmental changes induced by anthropogenic activities.Exploring the effects of these changes on the temporal dynamics of the waterbird communities can help understand how waterbirds adapt to environmental changes and thus formulate effective management and conservation plans.In this study,we carried out field surveys on waterbirds and environmental factors across 20 subsidence wetlands created by underground coal mining in the Huainan coal mining area in the breeding seasons of 2016 and 2021.We predicted that the waterbird assemblages(i.e.,number of individuals,species richness,Shannon-Wiener diversity,Pielou evenness and species composition) differed between the two years,and that these differences were correlated with the temporal changes in environmental factors.Across the surveyed wetlands,we recorded 26 waterbird species in 2016 and 23 in 2021.For individual wetlands,the number of waterbird individuals and species richness increased by 71.6% and 20.1%,respectively,over the five years,with no changes in Shannon-Wiener diversity and Pielou evenness.The overall increase in the number of bird individuals was mainly caused by an increase in vegetation gleaners and gulls that adapt well to anthropogenic activities.The species composition was significantly different between the two years,which was mainly caused by changes in the number of individuals of dominant species under influence of changes in human activities.For most wetlands,the temporal pairwiseβ-diversities could be explained by species turnover rather than nestedness,probably due to high mobility of waterbird species and dramatic changes in local environments.Our study suggests that waterbird communities could respond to environmental changes in subsidence wetlands,providing important implications for waterbird conservation in human-dominated artificial wetlands.
文摘Based on Remote Sensing （RS）, Geographic Information System （GIS）, and combining Principal Component Analysis, this paper designed a numerical integrated evaluation model for mountain eco-environment on the base of grid scale. Using this model, we evaluated the mountain eco-environmental quality in a case study area-the upper reaches of Minjiang River, and achieved a good result, which accorded well with the real condition. The study indicates that, the integrated evaluation model is suitable for multi-layer spatial factor computation, effectively lowing man＇s subjective influence in the evaluation process; treating the whole river basin as a system, the model shows full respect to the circulation of material and energy, synthetically embodies the determining impact of such natural condition as water-heat and landform, as well as human interference in natural eco-system; the evaluation result not only clearly presents mountainous vertical distribution features of input factors, but also provides a scientific and reliable thought for quantitatively evaluating mountain eco-environment.
基金financially supported by the National Natural Science Foundation of China(Nos.21777045,61875119)Distinguished Young Scholar Fund from Natural Science Funds of Guangdong Province,China(No.2020B151502094)+1 种基金the program for Professor of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning,Shanghai Rising-Star Program(No.19QA1404000)Shanghai Talent Development Fund.
文摘Bandgap engineering through single-atom site binding on semiconducting photocatalyst can boost the intrinsic activity,selectivity,carrier separation,and electron transport.Here,we report a mixed-valence Ag(0)and Ag(I)single atoms co-decorated semiconducting chalcopyrite quantum dots(Ag/CuFeS_(2)QDs)photocatalyst.It demonstrates efficient photocatalytic performances for specific organic dye(rhodamine B,denoted as RhB)as well as inorganic dye(Cr(VI))removal in water under natural sunlight irradiation.The RhB degradation and Cr(VI)removal efficiencies by Ag/CuFeS_(2)QDs were 3.55 and 6.75 times higher than those of the naked CuFeS_(2)QDs at their optimal pH conditions,respectively.Besides,in a mixture of RhB and Cr(VI)solution under neutral condition,the removal ratio has been elevated from 30.2%to 79.4%for Cr(VI),and from 95.2%to 97.3%for RhB degradation by using Ag/CuFeS_(2)QDs after 2 h sunlight illumination.The intrinsic mechanism for the photocatalytic performance improvement is attributed to the narrow bandgap of the single-atomic Ag(I)anchored CuFeS_(2)QDs,which engineers the electronic structure as well as expands the optical light response range.Significantly,the highly active Ag(0)/CuFeS_(2)and Ag(I)/CuFeS_(2)effectively improve the separation efficiency of the carriers,thus enhancing the photocatalytic performances.This work presents a highly efficient single atom/QDs photocatalyst,constructed through bandgap engineering via mixed-valence single noble metal atoms binding on semiconducting QDs.It paves the way for developing high-efficiency single-atom photocatalysts for complex pollutions removal in dyeing wastewater environment.
基金Supported by the National Natural Science Key Foundation of China(40133010)Natural Science Foundation of China of Anhui University of Science and Technology for ph.D to Research(DG414)
文摘Studied the content and distribution of 18 environmental hazardous trace elementsin the lignite, fatty coal, anthracite and its burnt products by combustion simulatingexpriment in the one-dismensinal boiler.The transformations and concentration of 18 traceelements during different coal combustion were discussed.The results show that there aresome content distribution of 18 hazardous trace elements in every burnt product, but thelaw of concentration and dispersion of every trace element during different coal combustionis very different.Experiment results indicate that the transformation and concentrationof trace elements during coal combustion are related to the element contents and occur-rencesof trace elements in raw coal, but are also affected by some man-made factorssuch as the combustion method of boiler, combustion temperature and atmosphere, thetype of precipitators and so on.
