Wind power is not only pollution free and renewable but is becoming more economical with technology development. The countries around the Arabian Gulf region are investing for wind powers both the land and in their ma...Wind power is not only pollution free and renewable but is becoming more economical with technology development. The countries around the Arabian Gulf region are investing for wind powers both the land and in their marine space. A detailed study on wind power resource in the Arabian Gulf is not available. This paper is on the wind energy resource availability over Arabian Gulf waters, covering 2300 grid points. The data available with Coastal Information System data base at Kuwait Institute for Scientific Research, Kuwait, from 1979 to 2015 is used. The probability density and power density were derived from these data source. Weibull probability density function has been fitted to the wind speed data and the wind power density was evaluated. The study is carried out at 10 m, 30 m and 50 m elevations. The central location of the Arabian Gulf has higher annual average wind speed, ranging from 6 to 8 m/s at 10 m elevation, 7 to 8 m/s at 30 m elevation and 8 to 9 m/s at 50 m elevation. The scale parameter “c” at central location of Arabian Gulf is found to range from 6 - 8 m/s for 10 m elevation, 7 - 8 m/s for 30 m elevation and 8 - 9 m/s for 50 m above sea level. The Weibull shape parameter k varies from 2.5 to 3 at the north and central of the Arabian Gulf. The annual mean wind power density over Arabian Gulf Waters is the highest in the central region of the Gulf. The power density at 10 m, 30 m and 50 m hub height varies between 200 to 300 w/m2, 200 to 300 w/m2 and more than 300 w/m2 respectively. It is attractive to install large scale wind power generation at the central region of the Arabian Gulf and at elevations of 30 m or 50 m, since this region lies in Class 2 category of the Wind Energy Resource Atlas of the United States. The wind power density is attractive especially in summer season around the central region location in Arabian Gulf (Saudi Arabia, Bahrain and Qatar), since high rate of power is used for air conditioning systems in summer.展开更多
Watermelon peel residues were used to produce a new biochar by dehydration method.The new biochar has undergone two methods of chemical modification and the effect of this chemical modification on its ability to adsor...Watermelon peel residues were used to produce a new biochar by dehydration method.The new biochar has undergone two methods of chemical modification and the effect of this chemical modification on its ability to adsorb Cr(VI)ions from aqueous solution has been investigated.Three biochars,Melon-B,Melon-BO-NH_(2) and Melon-BO-TETA,were made from watermelon peel via dehydration with 50%sulfuric acid to give Melon-B followed by oxidation with ozone and amination using ammonium hydroxide to give Melon-BO-NH_(2) or Triethylenetetramine(TETA)to give Melon-BO-TETA.The prepared biochars were characterized by BET,BJH,SEM,FT-IR,TGA,DSC and EDAX analyses.The highest removal percentage of Cr(VI)ions was 69%for Melon-B,98%for Melon-BO-NH_(2) and 99%for Melon-BO-TETA biochars of 100 mg·L^(−1) Cr(VI)ions initial concentration and 1.0 g·L^(−1) adsorbents dose.The unmodified biochar(Melon-B)and modified biochars(Melon-BO-NH_(2) and Melon-BO-TETA)had maximum adsorption capacities(Q_(m))of 72.46,123.46,and 333.33 mg·g^(−1),respectively.The amination of biochar reduced the pore size of modified biochar,whereas the surface area was enhanced.The obtained data of isotherm models were tested using different error function equations.The Freundlich,Tempkin and Langmuir isotherm models were best fitted to the experimental data of Melon-B,Melon-BO-NH_(2) and Melon-BO-TETA,respectively.The adsorption rate was primarily controlled by pseudo-second–order rate model.Conclusively,the functional groups interactions are important for adsorption mechanisms and expected to control the adsorption process.The adsorption for the Melon-B,Melon-BO-NH_(2) and Melon-BO-TETA could be explained for acid–base interaction and hydrogen bonding interaction.展开更多
While reliance on renewable energy resources has become a reality, there is still a need to deploy greener and more sustainable methods in order to achieve sustainable development goals. Indeed, green hydrogen is curr...While reliance on renewable energy resources has become a reality, there is still a need to deploy greener and more sustainable methods in order to achieve sustainable development goals. Indeed, green hydrogen is currently believed to be a reliable solution for global warming and the pollution challenges arising from fossil fuels, making it the resilient fuel of the future. However, the sustainability of green hydrogen technologies is yet to be achieved. In this context, generation of green hydrogen with the aid of deep eutectic solvents(DESs) as green mixtures has been demonstrated as a promising research area. This systematic review article covers green hydrogen generation through water splitting and biomass fermentation when DESs are utilized within the generation process. It also discusses the incorporation of DESs in fuel cell technologies. DESs can play a variety of roles such as solvent, electrolyte, or precursor;colloidal suspension and reaction medium;galvanic replacement, shape-controlling, decoration, or extractive agent;finally oxidant. These roles are relevant to several methods of green hydrogen generation, including electrocatalysis, photocatalysis, and fermentation. As such, it is of utmost importance to screen potential DES formulations and determine how they can function in and contribute throughout the green hydrogen mobility stages. The realization of super green hydrogen generation stands out as a pivotal milestone in our journey towards achieving a more sustainable form of development;DESs have great potential in making this milestone achievable. Overall, incorporating DESs in hydrogen generation constitutes a promising research area and offers potential scalability for green hydrogen production, storage,transport, and utilization.展开更多
文摘Wind power is not only pollution free and renewable but is becoming more economical with technology development. The countries around the Arabian Gulf region are investing for wind powers both the land and in their marine space. A detailed study on wind power resource in the Arabian Gulf is not available. This paper is on the wind energy resource availability over Arabian Gulf waters, covering 2300 grid points. The data available with Coastal Information System data base at Kuwait Institute for Scientific Research, Kuwait, from 1979 to 2015 is used. The probability density and power density were derived from these data source. Weibull probability density function has been fitted to the wind speed data and the wind power density was evaluated. The study is carried out at 10 m, 30 m and 50 m elevations. The central location of the Arabian Gulf has higher annual average wind speed, ranging from 6 to 8 m/s at 10 m elevation, 7 to 8 m/s at 30 m elevation and 8 to 9 m/s at 50 m elevation. The scale parameter “c” at central location of Arabian Gulf is found to range from 6 - 8 m/s for 10 m elevation, 7 - 8 m/s for 30 m elevation and 8 - 9 m/s for 50 m above sea level. The Weibull shape parameter k varies from 2.5 to 3 at the north and central of the Arabian Gulf. The annual mean wind power density over Arabian Gulf Waters is the highest in the central region of the Gulf. The power density at 10 m, 30 m and 50 m hub height varies between 200 to 300 w/m2, 200 to 300 w/m2 and more than 300 w/m2 respectively. It is attractive to install large scale wind power generation at the central region of the Arabian Gulf and at elevations of 30 m or 50 m, since this region lies in Class 2 category of the Wind Energy Resource Atlas of the United States. The wind power density is attractive especially in summer season around the central region location in Arabian Gulf (Saudi Arabia, Bahrain and Qatar), since high rate of power is used for air conditioning systems in summer.
文摘Watermelon peel residues were used to produce a new biochar by dehydration method.The new biochar has undergone two methods of chemical modification and the effect of this chemical modification on its ability to adsorb Cr(VI)ions from aqueous solution has been investigated.Three biochars,Melon-B,Melon-BO-NH_(2) and Melon-BO-TETA,were made from watermelon peel via dehydration with 50%sulfuric acid to give Melon-B followed by oxidation with ozone and amination using ammonium hydroxide to give Melon-BO-NH_(2) or Triethylenetetramine(TETA)to give Melon-BO-TETA.The prepared biochars were characterized by BET,BJH,SEM,FT-IR,TGA,DSC and EDAX analyses.The highest removal percentage of Cr(VI)ions was 69%for Melon-B,98%for Melon-BO-NH_(2) and 99%for Melon-BO-TETA biochars of 100 mg·L^(−1) Cr(VI)ions initial concentration and 1.0 g·L^(−1) adsorbents dose.The unmodified biochar(Melon-B)and modified biochars(Melon-BO-NH_(2) and Melon-BO-TETA)had maximum adsorption capacities(Q_(m))of 72.46,123.46,and 333.33 mg·g^(−1),respectively.The amination of biochar reduced the pore size of modified biochar,whereas the surface area was enhanced.The obtained data of isotherm models were tested using different error function equations.The Freundlich,Tempkin and Langmuir isotherm models were best fitted to the experimental data of Melon-B,Melon-BO-NH_(2) and Melon-BO-TETA,respectively.The adsorption rate was primarily controlled by pseudo-second–order rate model.Conclusively,the functional groups interactions are important for adsorption mechanisms and expected to control the adsorption process.The adsorption for the Melon-B,Melon-BO-NH_(2) and Melon-BO-TETA could be explained for acid–base interaction and hydrogen bonding interaction.
基金the Ministry of Higher Education,Research and Innovation(MoHERI)Oman for their support of this research through TRC block funding Grant no.:BFP/RGP/EBR/22/378。
文摘While reliance on renewable energy resources has become a reality, there is still a need to deploy greener and more sustainable methods in order to achieve sustainable development goals. Indeed, green hydrogen is currently believed to be a reliable solution for global warming and the pollution challenges arising from fossil fuels, making it the resilient fuel of the future. However, the sustainability of green hydrogen technologies is yet to be achieved. In this context, generation of green hydrogen with the aid of deep eutectic solvents(DESs) as green mixtures has been demonstrated as a promising research area. This systematic review article covers green hydrogen generation through water splitting and biomass fermentation when DESs are utilized within the generation process. It also discusses the incorporation of DESs in fuel cell technologies. DESs can play a variety of roles such as solvent, electrolyte, or precursor;colloidal suspension and reaction medium;galvanic replacement, shape-controlling, decoration, or extractive agent;finally oxidant. These roles are relevant to several methods of green hydrogen generation, including electrocatalysis, photocatalysis, and fermentation. As such, it is of utmost importance to screen potential DES formulations and determine how they can function in and contribute throughout the green hydrogen mobility stages. The realization of super green hydrogen generation stands out as a pivotal milestone in our journey towards achieving a more sustainable form of development;DESs have great potential in making this milestone achievable. Overall, incorporating DESs in hydrogen generation constitutes a promising research area and offers potential scalability for green hydrogen production, storage,transport, and utilization.
