In this paper,a fusion model based on a long short-term memory(LSTM)neural network and enhanced search ant colony optimization(ENSACO)is proposed to predict the power degradation trend of proton exchange membrane fuel...In this paper,a fusion model based on a long short-term memory(LSTM)neural network and enhanced search ant colony optimization(ENSACO)is proposed to predict the power degradation trend of proton exchange membrane fuel cells(PEMFC).Firstly,the Shapley additive explanations(SHAP)value method is used to select external characteristic parameters with high contributions as inputs for the data-driven approach.Next,a novel swarm optimization algorithm,the enhanced search ant colony optimization,is proposed.This algorithm improves the ant colony optimization(ACO)algorithm based on a reinforcement factor to avoid premature convergence and accelerate the convergence speed.Comparative experiments are set up to compare the performance differences between particle swarm optimization(PSO),ACO,and ENSACO.Finally,a data-driven method based on ENSACO-LSTM is proposed to predict the power degradation trend of PEMFCs.And actual aging data is used to validate the method.The results show that,within a limited number of iterations,the optimization capability of ENSACO is significantly stronger than that of PSO and ACO.Additionally,the prediction accuracy of the ENSACO-LSTM method is greatly improved,with an average increase of approximately 50.58%compared to LSTM,PSO-LSTM,and ACO-LSTM.展开更多
The liquid cooling system(LCS)of fuel cells is challenged by significant time delays,model uncertainties,pump and fan coupling,and frequent disturbances,leading to overshoot and control oscillations that degrade tempe...The liquid cooling system(LCS)of fuel cells is challenged by significant time delays,model uncertainties,pump and fan coupling,and frequent disturbances,leading to overshoot and control oscillations that degrade temperature regulation performance.To address these challenges,we propose a composite control scheme combining fuzzy logic and a variable-gain generalized supertwisting algorithm(VG-GSTA).Firstly,a one-dimensional(1D)fuzzy logic controler(FLC)for the pump ensures stable coolant flow,while a two-dimensional(2D)FLC for the fan regulates the stack temperature near the reference value.The VG-GSTA is then introduced to eliminate steady-state errors,offering resistance to disturbances and minimizing control oscillations.The equilibrium optimizer is used to fine-tune VG-GSTA parameters.Co-simulation verifies the effectiveness of our method,demonstrating its advantages in terms of disturbance immunity,overshoot suppression,tracking accuracy and response speed.展开更多
The development of efficient and robust non-precious metal electrocatalyst to drive the sluggish hydrogen oxidation reaction(HOR)is the key to the practical application of anion exchange membrane fuel cells(AEMFC),whi...The development of efficient and robust non-precious metal electrocatalyst to drive the sluggish hydrogen oxidation reaction(HOR)is the key to the practical application of anion exchange membrane fuel cells(AEMFC),which relies on the rational regulation of intermediates’binding strength.Herein,we reported a simple strategy to manipulate the adsorption energy of OH^(∗)on electrocatalyst surface via engineering Ni/NbO_(x) heterostructures with manageable oxygen vacancy(Ov).Theoretical calculations confirm that the electronic effect between Ni and NbO_(x) could weaken the hydrogen adsorption on Ni,and the interfacial oxygen vacancy tailor hydroxide binding energy(OHBE).The optimized HBE and OHBE contribute to reduce formation energy of water during the alkaline HOR process.Furthermore,in situ Raman spectroscopy monitor the dynamic process that OH^(∗)adsorbed on oxygen vacancy and react with adjacent H^(∗)adsorbed Ni,confirming the vital role of OH^(∗)for alkaline HOR process.As a result,the optimal Ni/NbO_(x) exhibits a remarkable intrinsic activity with a specific activity of 0.036mA/cm^(2),which is 4-fold than that of pristine Ni counterpart and surpasses most non-precious electrocatalysts ever reported.展开更多
Degradation prediction of proton exchange membrane fuel cell(PEMFC)stack is of great significance for improving the rest useful life.In this study,a PEMFC system including a stack of 300 cells and subsystems has been ...Degradation prediction of proton exchange membrane fuel cell(PEMFC)stack is of great significance for improving the rest useful life.In this study,a PEMFC system including a stack of 300 cells and subsystems has been tested under semi-steady operations for about 931 h.Then,two different models are respectively established based on semi-empirical method and data-driven method to investigate the degradation of stack performance.It is found that the root mean square error(RMSE)of the semi-empirical model in predicting the stack voltage is around 1.0 V,while the predicted voltage has no local dynamic characteristics,which can only reflect the overall degradation trend of stack performance.The RMSE of short-term voltage degradation predicted by the DDM can be less than 1.0 V,and the predicted voltage has accurate local variation characteristics.However,for the long-term prediction,the error will accumulate with the iterations and the deviation of the predicted voltage begins to fluctuate gradually,and the RMSE for the long-term predictions can increase to 1.63 V.Based on the above characteristics of the two models,a hybrid prediction model is further developed.The prediction results of the semi-empirical model are used to modify the input of the data-driven model,which can effectively improve the oscillation of prediction results of the data-driven model during the long-term degradation.It is found that the hybrid model has good error distribution(RSEM=0.8144 V,R2=0.8258)and local performance dynamic characteristics which can be used to predict the process of long-term stack performance degradation.展开更多
基金Supported by the Major Science and Technology Project of Jilin Province(20220301010GX)the International Scientific and Technological Cooperation(20240402071GH).
文摘In this paper,a fusion model based on a long short-term memory(LSTM)neural network and enhanced search ant colony optimization(ENSACO)is proposed to predict the power degradation trend of proton exchange membrane fuel cells(PEMFC).Firstly,the Shapley additive explanations(SHAP)value method is used to select external characteristic parameters with high contributions as inputs for the data-driven approach.Next,a novel swarm optimization algorithm,the enhanced search ant colony optimization,is proposed.This algorithm improves the ant colony optimization(ACO)algorithm based on a reinforcement factor to avoid premature convergence and accelerate the convergence speed.Comparative experiments are set up to compare the performance differences between particle swarm optimization(PSO),ACO,and ENSACO.Finally,a data-driven method based on ENSACO-LSTM is proposed to predict the power degradation trend of PEMFCs.And actual aging data is used to validate the method.The results show that,within a limited number of iterations,the optimization capability of ENSACO is significantly stronger than that of PSO and ACO.Additionally,the prediction accuracy of the ENSACO-LSTM method is greatly improved,with an average increase of approximately 50.58%compared to LSTM,PSO-LSTM,and ACO-LSTM.
基金Supported by the Major Science and Technology Project of Jilin Province(20220301010GX)the International Scientific and Technological Cooperation(20240402071GH).
文摘The liquid cooling system(LCS)of fuel cells is challenged by significant time delays,model uncertainties,pump and fan coupling,and frequent disturbances,leading to overshoot and control oscillations that degrade temperature regulation performance.To address these challenges,we propose a composite control scheme combining fuzzy logic and a variable-gain generalized supertwisting algorithm(VG-GSTA).Firstly,a one-dimensional(1D)fuzzy logic controler(FLC)for the pump ensures stable coolant flow,while a two-dimensional(2D)FLC for the fan regulates the stack temperature near the reference value.The VG-GSTA is then introduced to eliminate steady-state errors,offering resistance to disturbances and minimizing control oscillations.The equilibrium optimizer is used to fine-tune VG-GSTA parameters.Co-simulation verifies the effectiveness of our method,demonstrating its advantages in terms of disturbance immunity,overshoot suppression,tracking accuracy and response speed.
基金supported by Jilin Province Science and Technology Development Program(Nos.20200201001JC,20210502002ZP,20230101367JC,20220301011GX)Jilin Province Science and Technology Major Project(No.222648GX0105103875).
文摘The development of efficient and robust non-precious metal electrocatalyst to drive the sluggish hydrogen oxidation reaction(HOR)is the key to the practical application of anion exchange membrane fuel cells(AEMFC),which relies on the rational regulation of intermediates’binding strength.Herein,we reported a simple strategy to manipulate the adsorption energy of OH^(∗)on electrocatalyst surface via engineering Ni/NbO_(x) heterostructures with manageable oxygen vacancy(Ov).Theoretical calculations confirm that the electronic effect between Ni and NbO_(x) could weaken the hydrogen adsorption on Ni,and the interfacial oxygen vacancy tailor hydroxide binding energy(OHBE).The optimized HBE and OHBE contribute to reduce formation energy of water during the alkaline HOR process.Furthermore,in situ Raman spectroscopy monitor the dynamic process that OH^(∗)adsorbed on oxygen vacancy and react with adjacent H^(∗)adsorbed Ni,confirming the vital role of OH^(∗)for alkaline HOR process.As a result,the optimal Ni/NbO_(x) exhibits a remarkable intrinsic activity with a specific activity of 0.036mA/cm^(2),which is 4-fold than that of pristine Ni counterpart and surpasses most non-precious electrocatalysts ever reported.
基金supported by the National Key Research and Development Program of China(Grant No.SQ2021YFE011145)the Science and Technology Development Program of Jilin Province(Grant No.20200501010GX).
文摘Degradation prediction of proton exchange membrane fuel cell(PEMFC)stack is of great significance for improving the rest useful life.In this study,a PEMFC system including a stack of 300 cells and subsystems has been tested under semi-steady operations for about 931 h.Then,two different models are respectively established based on semi-empirical method and data-driven method to investigate the degradation of stack performance.It is found that the root mean square error(RMSE)of the semi-empirical model in predicting the stack voltage is around 1.0 V,while the predicted voltage has no local dynamic characteristics,which can only reflect the overall degradation trend of stack performance.The RMSE of short-term voltage degradation predicted by the DDM can be less than 1.0 V,and the predicted voltage has accurate local variation characteristics.However,for the long-term prediction,the error will accumulate with the iterations and the deviation of the predicted voltage begins to fluctuate gradually,and the RMSE for the long-term predictions can increase to 1.63 V.Based on the above characteristics of the two models,a hybrid prediction model is further developed.The prediction results of the semi-empirical model are used to modify the input of the data-driven model,which can effectively improve the oscillation of prediction results of the data-driven model during the long-term degradation.It is found that the hybrid model has good error distribution(RSEM=0.8144 V,R2=0.8258)and local performance dynamic characteristics which can be used to predict the process of long-term stack performance degradation.
