At present, the layering technology of water injection wells in Shengli Offshore Oilfield suffers from poor sealing, wear and tear of rubber parts, and corrosion and perforation of tubing, which seriously affect the n...At present, the layering technology of water injection wells in Shengli Offshore Oilfield suffers from poor sealing, wear and tear of rubber parts, and corrosion and perforation of tubing, which seriously affect the normal production of oil wells. To this end, the efficient stratification technology of water injection wells is studied, which has the control of all hydraulic control systems in addition to the water distributor. Hydraulic control washable annular safety packer, one-time pressure, permanent locking;hydraulic control forcibly opens and closes the well washing channel to avoid polluting the marine ecological environment. The double-sealing structure design of the hydraulic-controlled repeating packer effectively expands the axial sealing area. The hydraulically controlled two-way well flushing valve realizes forward and reverse well flushing and improves well flushing efficiency. The connection between the hydraulic control system and the ground hydraulic control cabinet realizes the remote control of the underground hydraulic control tool by the office computer terminal system, reduces the labor intensity of post-maintenance, and solves the problem of operating safety for on-site personnel. By the end of 2020, the high-efficiency stratification technology of water injection wells had been applied in more than 140 wells in Chengdao Oilfield, and the longest validity period had reached 7.6 years. The overall practical life of the pipe string could effectively meet the 5-year efficient development requirements.展开更多
Accurate diagnosis of liquid loading in gas wells is hindered by inconsistent criteria for identifying the critical liquid-loading condition and by reliance on subjective observation during the development of physical...Accurate diagnosis of liquid loading in gas wells is hindered by inconsistent criteria for identifying the critical liquid-loading condition and by reliance on subjective observation during the development of physical models.To address this issue,controlled laboratory experiments were conducted to investigate pressure fluctuations in gas–liquid two-phase flow under different flow regimes,with the aim of establishing a quantitative criterion to identify such critical conditions.High-frequency pressure signals were collected and analyzed using complementary ensemble empirical mode decomposition(CEEMD).Characteristic parameters describing slug flow,annular flow,and the critical liquid-loading condition were extracted accordingly,including signal variance,intrinsic mode function energy entropy,and kurtosis.The results demonstrate that the critical liquid-loading state exhibits distinctive pressure fluctuation features compared with slug and annular flow regimes.Evidence is provided that,by integrating statistical indicators with fractal-based analysis,the proposed method enables reliable identification of the critical liquid-loading condition.展开更多
Oxygen-reducing air flooding is a low-permeability reservoir recovery technology with safety and low-cost advantages.However,in the process of air injection and drive,carbon in the air is oxidized through the crude oi...Oxygen-reducing air flooding is a low-permeability reservoir recovery technology with safety and low-cost advantages.However,in the process of air injection and drive,carbon in the air is oxidized through the crude oil reservoir to generate CO_(2),and this can cause serious corrosion in the recovery well.In this study,experiments on the corrosion of J55 tubular steel in a fluid environment with coexisting O_(2)and CO_(2)in an autoclave are presented.In particular,a weight loss method and a 3D morphometer were used to determine the average and the local corrosion rate.The corrosion surface morphology and composition were also measured by means of scanning electron microscopy(SEM)and an X-ray diffractometer(XRD).The corrosion pattern and morphological characteristics of J55 steel were analyzed in the O2/CO_(2)environment for different degrees of oxygen-reduction.As made evident by the experimental results,the corrosion products were mainly ferrous carbonate and iron oxide.In general,air injection increases the degree of oxygen reduction,from oxygen corrosion characteristics to CO_(2)corrosion-based characteristics.As a result,the corrosion product film becomes denser,and the corrosion rate is lower.展开更多
CO_(2)flooding enhanced oil recovery(CO_(2)-EOR)represents a significant technology in the low permeability reservoir.With the fractures and heterogeneity in low permeability reservoirs,CO_(2)-EOR is susceptible to pe...CO_(2)flooding enhanced oil recovery(CO_(2)-EOR)represents a significant technology in the low permeability reservoir.With the fractures and heterogeneity in low permeability reservoirs,CO_(2)-EOR is susceptible to pessimistic gas channeling.Consequently,there is a need to develop conformance control materials that can be used in CO_(2)-EOR.Herein,to address the challenges of low strength and poor stability of polymer gel in high temperature and low permeability reservoirs,a new organic/metal ion composite crosslinking polymer gel(AR-Gel)is reported,which is formed by low hydrolysis and medium to high molecular weight polymer(CX-305),organic crosslinking agent(phenolic resin),and aluminium citrate(AI(Ⅲ)).The crosslinking of AI(Ⅲ)with carboxyl group and organic/metal ion double crosslinking can construct a more complex and stable polymer gel structure on the basis of traditional chemical crosslinking,to cope with the harsh conditions such as high temperature.The structure-activity relationship of AR-Gel was revealed by rheology behavior and micro-morphology.The applicability of AR-Gel in reservoir was investigated,as was its strength and stability in supercritical CO_(2).The anti-gas channeling and enhanced oil recovery of AR-Gel were investigated using low permeability fractured cores,and the field process parameters were provided.The gel can be used to meet supercritical CO_(2)reservoirs at 110℃and 20,000 mg/L salinity,with long-term stability over 60 days.The plugging rate of AR-Gel for fractured co re was 97%,with subsequent CO_(2)flooding re sulting in an enhanced oil recovery by 34.5%.ARGel can effectively control CO_(2)gas channeling and enhanced oil recovery.It offers a new material with high strength and temperature resistance,which is particularly beneficial in the CO_(2)flooding for the conformance control of oil field.展开更多
In this study,we propose a constraint learning strategy based on interpretability analysis to improve the convergence and accuracy of the enriched physics-informed neural network(EPINN),which is applied to simulate tw...In this study,we propose a constraint learning strategy based on interpretability analysis to improve the convergence and accuracy of the enriched physics-informed neural network(EPINN),which is applied to simulate two-phase flow in heterogeneous porous media.Specifically,we first analyze the layerwise outputs of EPINN,and identify the distinct functions across layers,including dimensionality adjustment,pointwise construction of non-equilibrium potential,extraction of high-level features,and the establishment of long-range dependencies.Then,inspired by these distinct modules,we propose a novel constraint learning strategy based on regularization approaches,which improves neural network(NN)learning through layer-specific differentiated updates to enhance cross-timestep generalization.Since different neu ral network layers exhibit varying sensitivities to global generalization and local regression,we decrease the update frequency of layers more sensitive to local learning under this constraint learning strategy.In other words,the entire neural network is encouraged to extract more generalized features.The superior performance of the proposed learning strategy is validated through evaluations on numerical examples with varying computational complexities.Post hoc analysis reveals that gradie nt propagation exhibits more pronounced staged characte ristics,and the partial differential equation(PDE)residuals are more uniformly distributed under the constraint guidance.Interpretability analysis of the adaptive constraint process suggests that maintaining a stable information compression mode facilitates progressive convergence acceleration.展开更多
During oil displacement,surfactants often encounter challenges such as emulsion instability and channeling,which can compromise their efficiency.To address these issues,polymer microspheres were synthesized via revers...During oil displacement,surfactants often encounter challenges such as emulsion instability and channeling,which can compromise their efficiency.To address these issues,polymer microspheres were synthesized via reverse microemulsion polymerization using acrylamide,2-methyl-2-acrylamidopropane sulfonic acid,and stearyl methacrylate as monomers,with N,N-methylenebisacrylamide as the crosslinker.The microspheres were then combined with sodium alkyl alcohol polyoxyethylene ether carboxylate to enhance emulsion stability and expand the swept volume of surfactant.A stable reverse microemulsion system was prepared using the maximum water solubilization rate as the indicator,and microspheres were synthesized based on this system.The ability of the microspheres to enhance emulsion stability was systematically evaluated.The plugging performance and enhanced oil recovery(EOR)efficiency of the microsphere/surfactant composite system were assessed through core seepage and oil displacement experiments.The experimental results demonstrated that microspheres were successfully prepared in a water-in-oil reverse microemulsion system with a solubilization rate of 42%.The emulsion stability was evaluated under an oil-to-water ratio of 7:3,a temperature of 80℃,and a salinity of 44,592 mg/L,by manually shaking the test tube five times.It was observed that the complete phase separation time of the emulsion increased from 10 to 120 min after the addition of microspheres.Under different permeability conditions(100×10^(-3),300×10^(-3),500×10^(-3)μm^(2)),the recovery efficiency of the composite system increased by 4.5%,8.3%,and 4.8%,respectively,compared to a single surfactant system.The microspheres developed in this study enhanced emulsion stability and increased the swept volume of surfactant within the formation,significantly boosting its oil recovery efficiency.展开更多
Casing deformation is a widespread problem in a certain block of Jiaoshiba Shale Gas Field in Sichuan Basin,China,and it severely limits the development benefits of shale gas in that block.Based on the spatiotemporal ...Casing deformation is a widespread problem in a certain block of Jiaoshiba Shale Gas Field in Sichuan Basin,China,and it severely limits the development benefits of shale gas in that block.Based on the spatiotemporal characteristics of block formation,fracture development,and casing deformation occurrence,this paper employs an integrated geological—engineering research approach to identify the primary mechanisms governing casing deformation within the block and proposes countermeasures to prevent such deformation.The present research indicates the following findings:(1)The block has undergone multiple phases of tectonic superposition,with fracture development serving as the geological factor causing casing deformation.(2)Fracturing activation constitutes the engineering factor causing casing deformation,with 4 mm of formation slip inducing deformation.(3)The fracture activation risk map shows that Class Ⅰ and Class Ⅱ fractures account for 73.36%of the total recorded in the block.Within the most susceptible Class I risk zone,the critical activation pressure increment for fracturing operations ranges from 13.43 MPa to 13.99 MPa.Based on the distribution of casing failure risk zones identified in the fracture activation risk map,this paper proposes relevant technical countermeasures for preventing casing failure from three perspectives:shale gas well location deployment,drilling techniques,and fracturing techniques.These measures provide robust support for safeguarding the integrity of casing systems within the studied block.展开更多
Polymer microspheres are one type of particle gel with swelling property,and the particle size is distributed between nanometer and micron.Because of the good variability and migration characteristics,polymer microsph...Polymer microspheres are one type of particle gel with swelling property,and the particle size is distributed between nanometer and micron.Because of the good variability and migration characteristics,polymer microspheres are widely used as conformance control agents,especially in fractured reservoirs.However,in the application process,the matching between polymer microspheres and the size of reservoir fractures remains insufficiently studied,leading to prevalent blind applications and low utilization efficiency.Based on polymer microspheres with different elastic modulus(23.6-715 Pa)prepared in the laboratory,the swelling dynamics of polymer microspheres were established according to their swelling ratio data under different reservoir temperatures(20-80℃).The fracture plate model was used to simulate the fractured reservoir,the matching mechanism of polymer microspheres in the model was studied.Applying this model and equation pt=kG′+m,we further investigated the quantitative relationship between threshold pressure and elastic modulus of polymer microspheres in the fracture plate model in the migration process.The swelling ratio of polymer microspheres showed that the polymer microspheres absorbed water quickly in the early stage and gradually slowed down in the later stage.The characteristics of the early stage were simulated by Fickian equation and those of the later stage were simulated by Schott equation.A new swelling kinetic equation of polymer microspheres was established considering the whole swelling characteristics.The diameter/width ratio was used as an evaluation index,the matching property results showed that under the experimental conditions,the migration modes of microspheres in the fracture plate model were straight-through passage,deformable passage,and blockage.Under the same elastic modulus,the smaller the fracture aperture,the higher the threshold pressure.At the same fracture aperture,the threshold pressure increased with the increase in elastic modulus.Based on the obtained results,the value range of threshold pressure under different fracture apertures could be quantitatively predicted,and then the particle size and elastic modulus of the polymer microspheres for conformance control could be determined according to the reservoir fracture parameters.The blind use of polymer microspheres for conformance control agents should be avoided,the success rate of fractured reservoir of conformance control could be improved.The results of the study have experimental guidance for the conformance control scheme design of polymer microspheres.展开更多
To investigate the height growth of multi-cluster fractures during variable fluid-viscosity fracturing in a layered shale oil reservoir,a two-dimensional finite element method(FEM)-discrete fracture network(DFN)model ...To investigate the height growth of multi-cluster fractures during variable fluid-viscosity fracturing in a layered shale oil reservoir,a two-dimensional finite element method(FEM)-discrete fracture network(DFN)model coupled with flow,stress and damage is proposed.A traction-separation law is used to describe the mixed-mode response of the damaged adhesive fractures,and the cubic law is used to describe the fluid flow within the fractures.The rock deformation is controlled by the in-situ stress,fracture cohesion and fluid pressure on the hydraulic fracture surface.The coupled finite element equations are solved by the explicit time difference method.The effects of the fracturing treatment parameters including fluid viscosity,pumping rate and cluster spacing on the geometries of multifractures are investigated.The results show that variable fluid-viscosity injection can improve the complexity of the fracture network and height of the main fractures simultaneously.The pumping rate of15 m^(3)/min,variable fluid-viscosity of 3-9-21-36-45 mPa s with a cluster spacing of 7.5 m is the ideal treatment strategy.The field application shows that the peak daily production of the application well with the optimized injection procedu re of variable fluid-viscosity fracturing is 171 tons(about 2.85 times that of the adjacent well),which is the highest daily production record of a single shale oil well in China,marking a strategic breakthrough of commercial shale oil production in the Jiyang Depression,Shengli Oilfield.The variable fluid-viscosity fracturing technique is proved to be very effective for improving shale oil production.展开更多
To fully exploit the technical advantages of the large-depth and high-precision artificial source electromagnetic method in the complex structure area of southern Sichuan and compensate for the shortcomings of the con...To fully exploit the technical advantages of the large-depth and high-precision artificial source electromagnetic method in the complex structure area of southern Sichuan and compensate for the shortcomings of the conventional electromagnetic method in exploration depth,precision,and accuracy,the large-depth and high-precision wide field electromagnetic method is applied to the complex structure test area of the Luochang syncline and Yuhe nose anticline in the southern Sichuan.The advantages of the wide field electromagnetic method in detecting deep,low-resistivity thin layers are demonstrated.First,on the basis of the analysis of physical property data,a geological–geoelectric model is established in the test area,and the wide field electromagnetic method is numerically simulated to analyze and evaluate the response characteristics of deep thin shale gas layers on wide field electromagnetic curves.Second,a wide field electromagnetic test is conducted in the complex structure area of southern Sichuan.After data processing and inversion imaging,apparent resistivity logging data are used for calibration to develop an apparent resistivity interpretation model suitable for the test area.On the basis of the results,the characteristics of the electrical structure change in the shallow longitudinal formation of 6 km are implemented,and the transverse electrical distribution characteristics of the deep shale gas layer are delineated.In the prediction area near the well,the subsequent data verification shows that the apparent resistivity obtained using the inversion of the wide field electromagnetic method is consistent with the trend of apparent resistivity revealed by logging,which proves that this method can effectively identify the weak response characteristics of deep shale gas formations in complex structural areas.This experiment,it is shown shows that the wide field electromagnetic method with a large depth and high precision can effectively characterize the electrical characteristics of deep,low-resistivity thin layers in complex structural areas,and a new set of low-cost evaluation technologies for shale gas target layers based on the wide field electromagnetic method is explored.展开更多
The mechanically choked orifice plate (MCOP) is a new type of device for flow control by which choking conditionsfor incompressible fluids can be obtained with relatively small pressure losses. Given the lack of relev...The mechanically choked orifice plate (MCOP) is a new type of device for flow control by which choking conditionsfor incompressible fluids can be obtained with relatively small pressure losses. Given the lack of relevant results anddata in the literature, in the present study, we concentrate on the experimental determination of the flow coefficientfor the annular orifice, the pressure distribution in the MCOP, and the characteristics of the choked flow itself. Asconfirmed by the experimental results, the Reynolds number, the orifice plate thickness, the plug taper, and theeccentricity have an obvious influence on the aforementioned flow coefficient. The pressure drop in the MCOPis mainly generated near the orifice plate, and the pressure upstream of the orifice plate is slightly reduced in theflow direction, while the pressure downstream of the orifice plate displays a recovery trend. The choked flow rateof the MCOP can be adjusted by replacing the spring with a maximum flow control deviation of 4.91%.展开更多
The increasing energy demand has pushed oil and gas exploration and development limits to extremely challenging and harsher HTHP (High Temperature and High Pressure) environments. Maintaining wellbore integrity in the...The increasing energy demand has pushed oil and gas exploration and development limits to extremely challenging and harsher HTHP (High Temperature and High Pressure) environments. Maintaining wellbore integrity in these environments, particularly in HPHT reservoirs with corrosive gases, presents a significant challenge. Robust risk evaluation and mitigation strategies are required to address these reservoirs' safety, economic, and environmental uncertainties. This study investigates chemo-mechanical properties degradations of class G oil well cement blended with silica fume, liquid silica, and latex when exposed to high temperature (150 °C) and high partial pressure of CO_(2) saturated brine. The result shows that these admixtures surround the cement grains and fill the interstitial spaces between the cement particles to form a dense crystal system of C–S–H. Consequently, the cement's percentage of pore voids, permeability, and the content of alkali compounds reduce, resulting in increased resistance to CO_(2) corrosion. Liquid silica, a specially prepared silica suspension, is a more effective alternative to silica fume in protecting oil well cement against CO_(2) chemical degradation. Micro-indentation analysis shows a significant deterioration in the mechanical properties of the cement, including average elastic modulus and hardness, particularly in the outer zones in direct contact with corrosive fluids. This study highlights the significance of incorporating admixtures to mitigate the effects of CO_(2) corrosion in HPHT environments and provides a valuable technique for quantitatively evaluating the mechanical-chemical degradation of cement sheath.展开更多
In recent years,with the development of the social Internet of Things(IoT),all kinds of data accumulated on the network.These data,which contain a lot of social information and opinions.However,these data are rarely f...In recent years,with the development of the social Internet of Things(IoT),all kinds of data accumulated on the network.These data,which contain a lot of social information and opinions.However,these data are rarely fully analyzed,which is a major obstacle to the intelligent development of the social IoT.In this paper,we propose a sentence similarity analysis model to analyze the similarity in people’s opinions on hot topics in social media and news pages.Most of these data are unstructured or semi-structured sentences,so the accuracy of sentence similarity analysis largely determines the model’s performance.For the purpose of improving accuracy,we propose a novel method of sentence similarity computation to extract the syntactic and semantic information of the semi-structured and unstructured sentences.We mainly consider the subjects,predicates and objects of sentence pairs and use Stanford Parser to classify the dependency relation triples to calculate the syntactic and semantic similarity between two sentences.Finally,we verify the performance of the model with the Microsoft Research Paraphrase Corpus(MRPC),which consists of 4076 pairs of training sentences and 1725 pairs of test sentences,and most of the data came from the news of social data.Extensive simulations demonstrate that our method outperforms other state-of-the-art methods regarding the correlation coefficient and the mean deviation.展开更多
The production capacity of shale oil reservoirs after hydraulic fracturing is influenced by a complex interplay involving geological characteristics,engineering quality,and well conditions.These relationships,nonlinea...The production capacity of shale oil reservoirs after hydraulic fracturing is influenced by a complex interplay involving geological characteristics,engineering quality,and well conditions.These relationships,nonlinear in nature,pose challenges for accurate description through physical models.While field data provides insights into real-world effects,its limited volume and quality restrict its utility.Complementing this,numerical simulation models offer effective support.To harness the strengths of both data-driven and model-driven approaches,this study established a shale oil production capacity prediction model based on a machine learning combination model.Leveraging fracturing development data from 236 wells in the field,a data-driven method employing the random forest algorithm is implemented to identify the main controlling factors for different types of shale oil reservoirs.Through the combination model integrating support vector machine(SVM)algorithm and back propagation neural network(BPNN),a model-driven shale oil production capacity prediction model is developed,capable of swiftly responding to shale oil development performance under varying geological,fluid,and well conditions.The results of numerical experiments show that the proposed method demonstrates a notable enhancement in R2 by 22.5%and 5.8%compared to singular machine learning models like SVM and BPNN,showcasing its superior precision in predicting shale oil production capacity across diverse datasets.展开更多
The research on the multiphase flow characteristics of hydrate slurry is the key to implementing the risk prevention and control technology of hydrate slurry in deep-water oil and gas mixed transportation system.This ...The research on the multiphase flow characteristics of hydrate slurry is the key to implementing the risk prevention and control technology of hydrate slurry in deep-water oil and gas mixed transportation system.This paper established a geometric model based on the high-pressure hydrate slurry experimental loop.The model was used to carry out simulation research on the flow characteristics of gas-liquid-solid three-phase flow.The specific research is as follows:Firstly,the effects of factors such as slurry flow velocity,hydrate particle density,hydrate particle size,and hydrate volume fraction on the stratified smooth flow were specifically studied.Orthogonal test obtained particle size has the most influence on the particle concentration distribution.The slurry flow velocity is gradually increased based on stratified smooth flow.Various flow patterns were observed and their characteristics were analyzed.Secondly,increasing the slurry velocity to 2 m/s could achieve the slurry flow pattern of partial hydrate in the pipeline transition from stratified smooth flow to wavy flow.When the flow rate increases to 3 m/s,a violent wave forms throughout the entire loop.Based on wave flow,as the velocity increased to 4 m/s,and the flow pattern changed to slug flow.When the particle concentration was below 10%,the increase of the concentration would aggravate the slug flow trend;if the particle concentration was above 10%,the increase of the concentration would weaken the slug flow trend,the increase of particle density and liquid viscosity would weaken the tendency of slug flow.The relationship between the pressure drop gradients of several different flow patterns is:slug flow>wave flow>stratified smooth flow.展开更多
A new measurement device,consisting of swirling blades and capsule-shaped throttling elements,is proposed in this study to eliminate typical measurement errors caused by complex flow patterns in gas-liquid flow.The sw...A new measurement device,consisting of swirling blades and capsule-shaped throttling elements,is proposed in this study to eliminate typical measurement errors caused by complex flow patterns in gas-liquid flow.The swirling blades are used to transform the complex flow pattern into a forced annular flow.Drawing on the research of existing blockage flow meters and also exploiting the single-phase flow measurement theory,a formula is introduced to measure the phase-separated flow of gas and liquid.The formula requires the pressure ratio,Lockhart-Martinelli number(L-M number),and the gas phase Froude number.The unknown parameters appearing in the formula are fitted through numerical simulation using computational fluid dynamics(CFD),which involves a comprehensive analysis of the flow field inside the device from multiple perspectives,and takes into account the influence of pressure fluctuations.Finally,the measurement model is validated through an experimental error analysis.The results demonstrate that the measurement error can be maintained within±8%for various flow patterns,including stratified flow,bubble flow,and wave flow.展开更多
Continental shale oil reservoirs,characterized by numerous bedding planes and micro-nano scale pores,feature significantly higher stress sensitivity compared to other types of reservoirs.However,research on suitable s...Continental shale oil reservoirs,characterized by numerous bedding planes and micro-nano scale pores,feature significantly higher stress sensitivity compared to other types of reservoirs.However,research on suitable stress sensitivity characterization models is still limited.In this study,three commonly used stress sensitivity models for shale oil reservoirs were considered,and experiments on representative core samples were conducted.By fitting and comparing the data,the“exponential model”was identified as a characterization model that accurately represents stress sensitivity in continental shale oil reservoirs.To validate the accuracy of the model,a two-phase seepage mathematical model for shale oil reservoirs coupled with the exponential model was introduced.The model was discretely solved using the finite volume method,and its accuracy was verified through the commercial simulator CMG.The study evaluated the productivity of a typical horizontal well under different engineering,geological,and fracture conditions.The results indicate that considering stress sensitivity leads to a 13.57%reduction in production for the same matrix permeability.Additionally,as the fracture half-length and the number of fractures increase,and the bottomhole flowing pressure decreases,the reservoir stress sensitivity becomes higher.展开更多
Abstract:As an important component of the atmosphere,ammonia(NH_(3))plays a very important role in maintaining the balance of environment.However,it is also one of the most toxic gases that can cause damage to the hum...Abstract:As an important component of the atmosphere,ammonia(NH_(3))plays a very important role in maintaining the balance of environment.However,it is also one of the most toxic gases that can cause damage to the human respiratory system and mucous membranes even at low concentrations.As such,development of highly sensitive and selective NH_(3)sensors is of high significance for environmental monitoring and health maintenance.Herein,we have synthesized Au@Ag@Ag Cl core-shell nanoparticles(NPs)by oxidative etching and precipitating Au@Ag core-shell NPs using FeCl3 and further used them as optical probes for the colorimetric detection of NH_(3).The sensing mechanism is based on the fact that the etching of NH_(3)on AgCl and Ag shell leads to the variations of ingredients and core-to-shell ratio of the Au@Ag@AgCl NPs,thereby inducing noticeable spectral and color changes.By replacing the outmost layer of Ag with AgCl,not only is the stability of the sensor against oxygen significantly enhanced,but also is the sensitivity of the method improved.The method exhibits good linear relationship for the detection of NH_(3)from 0 to 5000 mmol/L with the limit of detection of 6.4 mmol/L.This method was successfully applied to the detection of simulated air polluted by NH_(3),indicating its practical applicability for environmental monitoring.This method shows great potential for on-site NH_(3)detection particularly in remote area,where a simple,fast,low-cost,and easy-to-handle method is highly desirable.展开更多
At present,methods for treating tertiary oil recovery wastewater via electro-coagulation are still in their early stage of development.In this study,a device for electro-coagulation wastewater treatment was built and ...At present,methods for treating tertiary oil recovery wastewater via electro-coagulation are still in their early stage of development.In this study,a device for electro-coagulation wastewater treatment was built and tested in an oil field.The effects that the initial pH value,electrode type,and connection mode have on the coagulation and separation effect were assessed by measuring the mass fraction and turbidity of oil.The results have shown that when the electro-coagulation method is used,the effectiveness of the treatment can be significantly increased in neutral pH conditions(pH=7),in acidic conditions,and in alkaline conditions.Compared to an Al electrode,the floc that is produced by an Fe electrode is smaller;thus,it does not easily coagulate and settle in a short time.Using the oil removal rate,turbidity removal rate and energy consumption as a basis to assess the performances,the results have demonstrated that the combined aluminum alloy iron composite electrode should be used as electrolytic electrode.展开更多
The Chinese Loess Plateau has long been plagued by severe soil erosion and water scarcity.In this study,we proposed a technique involving the combined use of polymer SH and ryegrass and evaluated its effectiveness in ...The Chinese Loess Plateau has long been plagued by severe soil erosion and water scarcity.In this study,we proposed a technique involving the combined use of polymer SH and ryegrass and evaluated its effectiveness in modifying the water-holding characteristics of loess on the Chinese Loess Plateau(Chinese loess).We analysed the volumetric water content and water potential of untreated loess,treated loess with single polymer SH,treated loess with single ryegrass,and treated loess with both polymer SH and ryegrass using the loess samples collected from the Chinese Loess Plateau in July 2023.Moreover,fractal theory was used to analyse the fractal characteristics of the soil structure,and wet disintegration tests were conducted to assess the structural stability of both untreated and treated loess samples.The results showed that the loess samples treated with both polymer SH and ryegrass presented much higher volumetric water content and water potential than the untreated loess samples and those treated only with ryegrass or polymer SH.Moreover,the planting density of ryegrass affected the combined technique,since a relatively low planting density(20 g/m2)was conducive to enhancing the water-holding capacity of Chinese loess.The fractal dimension was directly correlated with both volumetric water content and water potential of Chinese loess.Specifically,since loess treated with both polymer SH and ryegrass was more saturated with moisture,its water potential increased,thus improving its water-holding capacity and fractal dimension.The combined technique better resisted disintegration than ryegrass alone but had slightly less resistance than polymer SH alone.This study provides insight into soil reinforcement and soil water management using polymetric materials and vegetation on the Chinese Loess Plateau.展开更多
文摘At present, the layering technology of water injection wells in Shengli Offshore Oilfield suffers from poor sealing, wear and tear of rubber parts, and corrosion and perforation of tubing, which seriously affect the normal production of oil wells. To this end, the efficient stratification technology of water injection wells is studied, which has the control of all hydraulic control systems in addition to the water distributor. Hydraulic control washable annular safety packer, one-time pressure, permanent locking;hydraulic control forcibly opens and closes the well washing channel to avoid polluting the marine ecological environment. The double-sealing structure design of the hydraulic-controlled repeating packer effectively expands the axial sealing area. The hydraulically controlled two-way well flushing valve realizes forward and reverse well flushing and improves well flushing efficiency. The connection between the hydraulic control system and the ground hydraulic control cabinet realizes the remote control of the underground hydraulic control tool by the office computer terminal system, reduces the labor intensity of post-maintenance, and solves the problem of operating safety for on-site personnel. By the end of 2020, the high-efficiency stratification technology of water injection wells had been applied in more than 140 wells in Chengdao Oilfield, and the longest validity period had reached 7.6 years. The overall practical life of the pipe string could effectively meet the 5-year efficient development requirements.
文摘Accurate diagnosis of liquid loading in gas wells is hindered by inconsistent criteria for identifying the critical liquid-loading condition and by reliance on subjective observation during the development of physical models.To address this issue,controlled laboratory experiments were conducted to investigate pressure fluctuations in gas–liquid two-phase flow under different flow regimes,with the aim of establishing a quantitative criterion to identify such critical conditions.High-frequency pressure signals were collected and analyzed using complementary ensemble empirical mode decomposition(CEEMD).Characteristic parameters describing slug flow,annular flow,and the critical liquid-loading condition were extracted accordingly,including signal variance,intrinsic mode function energy entropy,and kurtosis.The results demonstrate that the critical liquid-loading state exhibits distinctive pressure fluctuation features compared with slug and annular flow regimes.Evidence is provided that,by integrating statistical indicators with fractal-based analysis,the proposed method enables reliable identification of the critical liquid-loading condition.
基金Major national science and technology projects“Key Techniques for the Development of Low Abundance Tight Low Permeability Reservoirs”(2016ZX05048).
文摘Oxygen-reducing air flooding is a low-permeability reservoir recovery technology with safety and low-cost advantages.However,in the process of air injection and drive,carbon in the air is oxidized through the crude oil reservoir to generate CO_(2),and this can cause serious corrosion in the recovery well.In this study,experiments on the corrosion of J55 tubular steel in a fluid environment with coexisting O_(2)and CO_(2)in an autoclave are presented.In particular,a weight loss method and a 3D morphometer were used to determine the average and the local corrosion rate.The corrosion surface morphology and composition were also measured by means of scanning electron microscopy(SEM)and an X-ray diffractometer(XRD).The corrosion pattern and morphological characteristics of J55 steel were analyzed in the O2/CO_(2)environment for different degrees of oxygen-reduction.As made evident by the experimental results,the corrosion products were mainly ferrous carbonate and iron oxide.In general,air injection increases the degree of oxygen reduction,from oxygen corrosion characteristics to CO_(2)corrosion-based characteristics.As a result,the corrosion product film becomes denser,and the corrosion rate is lower.
基金project was supported by the Fund of State Key Laboratory of Deep Oil and Gas,China University of Petroleum(East China)(No.SKLDOG2024-ZYRC-06)Key Program of National Natural Science Foundation of China(52130401)+1 种基金National Natural Science Foundation of China(52104055,52374058)Shandong Provincial Natural Science Foundation,China(ZR2021ME171,ZR2024YQ043)。
文摘CO_(2)flooding enhanced oil recovery(CO_(2)-EOR)represents a significant technology in the low permeability reservoir.With the fractures and heterogeneity in low permeability reservoirs,CO_(2)-EOR is susceptible to pessimistic gas channeling.Consequently,there is a need to develop conformance control materials that can be used in CO_(2)-EOR.Herein,to address the challenges of low strength and poor stability of polymer gel in high temperature and low permeability reservoirs,a new organic/metal ion composite crosslinking polymer gel(AR-Gel)is reported,which is formed by low hydrolysis and medium to high molecular weight polymer(CX-305),organic crosslinking agent(phenolic resin),and aluminium citrate(AI(Ⅲ)).The crosslinking of AI(Ⅲ)with carboxyl group and organic/metal ion double crosslinking can construct a more complex and stable polymer gel structure on the basis of traditional chemical crosslinking,to cope with the harsh conditions such as high temperature.The structure-activity relationship of AR-Gel was revealed by rheology behavior and micro-morphology.The applicability of AR-Gel in reservoir was investigated,as was its strength and stability in supercritical CO_(2).The anti-gas channeling and enhanced oil recovery of AR-Gel were investigated using low permeability fractured cores,and the field process parameters were provided.The gel can be used to meet supercritical CO_(2)reservoirs at 110℃and 20,000 mg/L salinity,with long-term stability over 60 days.The plugging rate of AR-Gel for fractured co re was 97%,with subsequent CO_(2)flooding re sulting in an enhanced oil recovery by 34.5%.ARGel can effectively control CO_(2)gas channeling and enhanced oil recovery.It offers a new material with high strength and temperature resistance,which is particularly beneficial in the CO_(2)flooding for the conformance control of oil field.
基金supported by the National Key R&D Program of China(No.2023YFB4104200)the National Natural Science Foundation of China(Nos.52474067,52441411,52325402,52034010,and12131014)+2 种基金the Natural Science Foundation of Shandong Province,China(No.ZR2024ME005)Fundamental Research Funds for the Central Universities(Nos.25CX02025A and 21CX06031A)the Youth Innovation and Technology Support Program for Higher Education Institutions of Shandong Province,China(No.2022KJ070)。
文摘In this study,we propose a constraint learning strategy based on interpretability analysis to improve the convergence and accuracy of the enriched physics-informed neural network(EPINN),which is applied to simulate two-phase flow in heterogeneous porous media.Specifically,we first analyze the layerwise outputs of EPINN,and identify the distinct functions across layers,including dimensionality adjustment,pointwise construction of non-equilibrium potential,extraction of high-level features,and the establishment of long-range dependencies.Then,inspired by these distinct modules,we propose a novel constraint learning strategy based on regularization approaches,which improves neural network(NN)learning through layer-specific differentiated updates to enhance cross-timestep generalization.Since different neu ral network layers exhibit varying sensitivities to global generalization and local regression,we decrease the update frequency of layers more sensitive to local learning under this constraint learning strategy.In other words,the entire neural network is encouraged to extract more generalized features.The superior performance of the proposed learning strategy is validated through evaluations on numerical examples with varying computational complexities.Post hoc analysis reveals that gradie nt propagation exhibits more pronounced staged characte ristics,and the partial differential equation(PDE)residuals are more uniformly distributed under the constraint guidance.Interpretability analysis of the adaptive constraint process suggests that maintaining a stable information compression mode facilitates progressive convergence acceleration.
基金supported by the Natural Science Foundation of Shandong Province(ZR2021ME007)the National Natural Science Foundation in China(51574267)the Key Projects of China National Key Research and Development Plan(2019YFA0708703)。
文摘During oil displacement,surfactants often encounter challenges such as emulsion instability and channeling,which can compromise their efficiency.To address these issues,polymer microspheres were synthesized via reverse microemulsion polymerization using acrylamide,2-methyl-2-acrylamidopropane sulfonic acid,and stearyl methacrylate as monomers,with N,N-methylenebisacrylamide as the crosslinker.The microspheres were then combined with sodium alkyl alcohol polyoxyethylene ether carboxylate to enhance emulsion stability and expand the swept volume of surfactant.A stable reverse microemulsion system was prepared using the maximum water solubilization rate as the indicator,and microspheres were synthesized based on this system.The ability of the microspheres to enhance emulsion stability was systematically evaluated.The plugging performance and enhanced oil recovery(EOR)efficiency of the microsphere/surfactant composite system were assessed through core seepage and oil displacement experiments.The experimental results demonstrated that microspheres were successfully prepared in a water-in-oil reverse microemulsion system with a solubilization rate of 42%.The emulsion stability was evaluated under an oil-to-water ratio of 7:3,a temperature of 80℃,and a salinity of 44,592 mg/L,by manually shaking the test tube five times.It was observed that the complete phase separation time of the emulsion increased from 10 to 120 min after the addition of microspheres.Under different permeability conditions(100×10^(-3),300×10^(-3),500×10^(-3)μm^(2)),the recovery efficiency of the composite system increased by 4.5%,8.3%,and 4.8%,respectively,compared to a single surfactant system.The microspheres developed in this study enhanced emulsion stability and increased the swept volume of surfactant within the formation,significantly boosting its oil recovery efficiency.
文摘Casing deformation is a widespread problem in a certain block of Jiaoshiba Shale Gas Field in Sichuan Basin,China,and it severely limits the development benefits of shale gas in that block.Based on the spatiotemporal characteristics of block formation,fracture development,and casing deformation occurrence,this paper employs an integrated geological—engineering research approach to identify the primary mechanisms governing casing deformation within the block and proposes countermeasures to prevent such deformation.The present research indicates the following findings:(1)The block has undergone multiple phases of tectonic superposition,with fracture development serving as the geological factor causing casing deformation.(2)Fracturing activation constitutes the engineering factor causing casing deformation,with 4 mm of formation slip inducing deformation.(3)The fracture activation risk map shows that Class Ⅰ and Class Ⅱ fractures account for 73.36%of the total recorded in the block.Within the most susceptible Class I risk zone,the critical activation pressure increment for fracturing operations ranges from 13.43 MPa to 13.99 MPa.Based on the distribution of casing failure risk zones identified in the fracture activation risk map,this paper proposes relevant technical countermeasures for preventing casing failure from three perspectives:shale gas well location deployment,drilling techniques,and fracturing techniques.These measures provide robust support for safeguarding the integrity of casing systems within the studied block.
基金supported by the Fund of Shandong Provincial Natural Science Foundation,China(ZR2025MS783,ZR2024YQ043)the Fundamental Research Funds for the Central Universities(25CX02024A)+2 种基金National Natural Science Foundation of China(52374058)State Key Laboratory of Deep Oil and Gas,China University of Petroleum(East China)(No.SKLDOG2024-ZYRC-06)Natural Science Basic Research Program of Shaanxi(No.2023-JC-QN-0486).
文摘Polymer microspheres are one type of particle gel with swelling property,and the particle size is distributed between nanometer and micron.Because of the good variability and migration characteristics,polymer microspheres are widely used as conformance control agents,especially in fractured reservoirs.However,in the application process,the matching between polymer microspheres and the size of reservoir fractures remains insufficiently studied,leading to prevalent blind applications and low utilization efficiency.Based on polymer microspheres with different elastic modulus(23.6-715 Pa)prepared in the laboratory,the swelling dynamics of polymer microspheres were established according to their swelling ratio data under different reservoir temperatures(20-80℃).The fracture plate model was used to simulate the fractured reservoir,the matching mechanism of polymer microspheres in the model was studied.Applying this model and equation pt=kG′+m,we further investigated the quantitative relationship between threshold pressure and elastic modulus of polymer microspheres in the fracture plate model in the migration process.The swelling ratio of polymer microspheres showed that the polymer microspheres absorbed water quickly in the early stage and gradually slowed down in the later stage.The characteristics of the early stage were simulated by Fickian equation and those of the later stage were simulated by Schott equation.A new swelling kinetic equation of polymer microspheres was established considering the whole swelling characteristics.The diameter/width ratio was used as an evaluation index,the matching property results showed that under the experimental conditions,the migration modes of microspheres in the fracture plate model were straight-through passage,deformable passage,and blockage.Under the same elastic modulus,the smaller the fracture aperture,the higher the threshold pressure.At the same fracture aperture,the threshold pressure increased with the increase in elastic modulus.Based on the obtained results,the value range of threshold pressure under different fracture apertures could be quantitatively predicted,and then the particle size and elastic modulus of the polymer microspheres for conformance control could be determined according to the reservoir fracture parameters.The blind use of polymer microspheres for conformance control agents should be avoided,the success rate of fractured reservoir of conformance control could be improved.The results of the study have experimental guidance for the conformance control scheme design of polymer microspheres.
基金funded by the National Natural Science Foundation of China(Nos.52192622,51874253,U20A202)
文摘To investigate the height growth of multi-cluster fractures during variable fluid-viscosity fracturing in a layered shale oil reservoir,a two-dimensional finite element method(FEM)-discrete fracture network(DFN)model coupled with flow,stress and damage is proposed.A traction-separation law is used to describe the mixed-mode response of the damaged adhesive fractures,and the cubic law is used to describe the fluid flow within the fractures.The rock deformation is controlled by the in-situ stress,fracture cohesion and fluid pressure on the hydraulic fracture surface.The coupled finite element equations are solved by the explicit time difference method.The effects of the fracturing treatment parameters including fluid viscosity,pumping rate and cluster spacing on the geometries of multifractures are investigated.The results show that variable fluid-viscosity injection can improve the complexity of the fracture network and height of the main fractures simultaneously.The pumping rate of15 m^(3)/min,variable fluid-viscosity of 3-9-21-36-45 mPa s with a cluster spacing of 7.5 m is the ideal treatment strategy.The field application shows that the peak daily production of the application well with the optimized injection procedu re of variable fluid-viscosity fracturing is 171 tons(about 2.85 times that of the adjacent well),which is the highest daily production record of a single shale oil well in China,marking a strategic breakthrough of commercial shale oil production in the Jiyang Depression,Shengli Oilfield.The variable fluid-viscosity fracturing technique is proved to be very effective for improving shale oil production.
文摘To fully exploit the technical advantages of the large-depth and high-precision artificial source electromagnetic method in the complex structure area of southern Sichuan and compensate for the shortcomings of the conventional electromagnetic method in exploration depth,precision,and accuracy,the large-depth and high-precision wide field electromagnetic method is applied to the complex structure test area of the Luochang syncline and Yuhe nose anticline in the southern Sichuan.The advantages of the wide field electromagnetic method in detecting deep,low-resistivity thin layers are demonstrated.First,on the basis of the analysis of physical property data,a geological–geoelectric model is established in the test area,and the wide field electromagnetic method is numerically simulated to analyze and evaluate the response characteristics of deep thin shale gas layers on wide field electromagnetic curves.Second,a wide field electromagnetic test is conducted in the complex structure area of southern Sichuan.After data processing and inversion imaging,apparent resistivity logging data are used for calibration to develop an apparent resistivity interpretation model suitable for the test area.On the basis of the results,the characteristics of the electrical structure change in the shallow longitudinal formation of 6 km are implemented,and the transverse electrical distribution characteristics of the deep shale gas layer are delineated.In the prediction area near the well,the subsequent data verification shows that the apparent resistivity obtained using the inversion of the wide field electromagnetic method is consistent with the trend of apparent resistivity revealed by logging,which proves that this method can effectively identify the weak response characteristics of deep shale gas formations in complex structural areas.This experiment,it is shown shows that the wide field electromagnetic method with a large depth and high precision can effectively characterize the electrical characteristics of deep,low-resistivity thin layers in complex structural areas,and a new set of low-cost evaluation technologies for shale gas target layers based on the wide field electromagnetic method is explored.
基金the Foundation of the Educational Commission of Hubei Province of China[Grant No.Q20191310]。
文摘The mechanically choked orifice plate (MCOP) is a new type of device for flow control by which choking conditionsfor incompressible fluids can be obtained with relatively small pressure losses. Given the lack of relevant results anddata in the literature, in the present study, we concentrate on the experimental determination of the flow coefficientfor the annular orifice, the pressure distribution in the MCOP, and the characteristics of the choked flow itself. Asconfirmed by the experimental results, the Reynolds number, the orifice plate thickness, the plug taper, and theeccentricity have an obvious influence on the aforementioned flow coefficient. The pressure drop in the MCOPis mainly generated near the orifice plate, and the pressure upstream of the orifice plate is slightly reduced in theflow direction, while the pressure downstream of the orifice plate displays a recovery trend. The choked flow rateof the MCOP can be adjusted by replacing the spring with a maximum flow control deviation of 4.91%.
基金funded by National Natural Science Foundation Project(Grant No.52274015)Opening Project Fund of Materials Service Safety Assessment Facilities(MSAF-2021-102).
文摘The increasing energy demand has pushed oil and gas exploration and development limits to extremely challenging and harsher HTHP (High Temperature and High Pressure) environments. Maintaining wellbore integrity in these environments, particularly in HPHT reservoirs with corrosive gases, presents a significant challenge. Robust risk evaluation and mitigation strategies are required to address these reservoirs' safety, economic, and environmental uncertainties. This study investigates chemo-mechanical properties degradations of class G oil well cement blended with silica fume, liquid silica, and latex when exposed to high temperature (150 °C) and high partial pressure of CO_(2) saturated brine. The result shows that these admixtures surround the cement grains and fill the interstitial spaces between the cement particles to form a dense crystal system of C–S–H. Consequently, the cement's percentage of pore voids, permeability, and the content of alkali compounds reduce, resulting in increased resistance to CO_(2) corrosion. Liquid silica, a specially prepared silica suspension, is a more effective alternative to silica fume in protecting oil well cement against CO_(2) chemical degradation. Micro-indentation analysis shows a significant deterioration in the mechanical properties of the cement, including average elastic modulus and hardness, particularly in the outer zones in direct contact with corrosive fluids. This study highlights the significance of incorporating admixtures to mitigate the effects of CO_(2) corrosion in HPHT environments and provides a valuable technique for quantitatively evaluating the mechanical-chemical degradation of cement sheath.
基金supported by the Major Scientific and Technological Projects of CNPC under Grant ZD2019-183-006partially supported by the Shandong Provincial Natural Science Foundation,China under Grant ZR2020MF006partially supported by“the Fundamental Research Funds for the Central Universities”of China University of Petroleum(East China)under Grant 20CX05017A,18CX02139A.
文摘In recent years,with the development of the social Internet of Things(IoT),all kinds of data accumulated on the network.These data,which contain a lot of social information and opinions.However,these data are rarely fully analyzed,which is a major obstacle to the intelligent development of the social IoT.In this paper,we propose a sentence similarity analysis model to analyze the similarity in people’s opinions on hot topics in social media and news pages.Most of these data are unstructured or semi-structured sentences,so the accuracy of sentence similarity analysis largely determines the model’s performance.For the purpose of improving accuracy,we propose a novel method of sentence similarity computation to extract the syntactic and semantic information of the semi-structured and unstructured sentences.We mainly consider the subjects,predicates and objects of sentence pairs and use Stanford Parser to classify the dependency relation triples to calculate the syntactic and semantic similarity between two sentences.Finally,we verify the performance of the model with the Microsoft Research Paraphrase Corpus(MRPC),which consists of 4076 pairs of training sentences and 1725 pairs of test sentences,and most of the data came from the news of social data.Extensive simulations demonstrate that our method outperforms other state-of-the-art methods regarding the correlation coefficient and the mean deviation.
基金supported by the China Postdoctoral Science Foundation(2021M702304)Natural Science Foundation of Shandong Province(ZR20210E260).
文摘The production capacity of shale oil reservoirs after hydraulic fracturing is influenced by a complex interplay involving geological characteristics,engineering quality,and well conditions.These relationships,nonlinear in nature,pose challenges for accurate description through physical models.While field data provides insights into real-world effects,its limited volume and quality restrict its utility.Complementing this,numerical simulation models offer effective support.To harness the strengths of both data-driven and model-driven approaches,this study established a shale oil production capacity prediction model based on a machine learning combination model.Leveraging fracturing development data from 236 wells in the field,a data-driven method employing the random forest algorithm is implemented to identify the main controlling factors for different types of shale oil reservoirs.Through the combination model integrating support vector machine(SVM)algorithm and back propagation neural network(BPNN),a model-driven shale oil production capacity prediction model is developed,capable of swiftly responding to shale oil development performance under varying geological,fluid,and well conditions.The results of numerical experiments show that the proposed method demonstrates a notable enhancement in R2 by 22.5%and 5.8%compared to singular machine learning models like SVM and BPNN,showcasing its superior precision in predicting shale oil production capacity across diverse datasets.
基金supported by the National Natural Science Foundation of China(Grant No.52274061&52004039&51974037)China Postdoctoral Science Foundation(Grant No.2023T160717&2021M693908)+1 种基金The major project of universities affiliated to Jiangsu Province basic science(natural science)research(Grant No.21KJA440001)Jiangsu Qinglan Project,Changzhou Longcheng Talent Plan-Youth Science and Technology Talent Recruitment Project.
文摘The research on the multiphase flow characteristics of hydrate slurry is the key to implementing the risk prevention and control technology of hydrate slurry in deep-water oil and gas mixed transportation system.This paper established a geometric model based on the high-pressure hydrate slurry experimental loop.The model was used to carry out simulation research on the flow characteristics of gas-liquid-solid three-phase flow.The specific research is as follows:Firstly,the effects of factors such as slurry flow velocity,hydrate particle density,hydrate particle size,and hydrate volume fraction on the stratified smooth flow were specifically studied.Orthogonal test obtained particle size has the most influence on the particle concentration distribution.The slurry flow velocity is gradually increased based on stratified smooth flow.Various flow patterns were observed and their characteristics were analyzed.Secondly,increasing the slurry velocity to 2 m/s could achieve the slurry flow pattern of partial hydrate in the pipeline transition from stratified smooth flow to wavy flow.When the flow rate increases to 3 m/s,a violent wave forms throughout the entire loop.Based on wave flow,as the velocity increased to 4 m/s,and the flow pattern changed to slug flow.When the particle concentration was below 10%,the increase of the concentration would aggravate the slug flow trend;if the particle concentration was above 10%,the increase of the concentration would weaken the slug flow trend,the increase of particle density and liquid viscosity would weaken the tendency of slug flow.The relationship between the pressure drop gradients of several different flow patterns is:slug flow>wave flow>stratified smooth flow.
基金Supported By Open Fund of Hubei Key Laboratory of Oil and Gas Drilling and Production Engineering(Yangtze University),YQZC202309.
文摘A new measurement device,consisting of swirling blades and capsule-shaped throttling elements,is proposed in this study to eliminate typical measurement errors caused by complex flow patterns in gas-liquid flow.The swirling blades are used to transform the complex flow pattern into a forced annular flow.Drawing on the research of existing blockage flow meters and also exploiting the single-phase flow measurement theory,a formula is introduced to measure the phase-separated flow of gas and liquid.The formula requires the pressure ratio,Lockhart-Martinelli number(L-M number),and the gas phase Froude number.The unknown parameters appearing in the formula are fitted through numerical simulation using computational fluid dynamics(CFD),which involves a comprehensive analysis of the flow field inside the device from multiple perspectives,and takes into account the influence of pressure fluctuations.Finally,the measurement model is validated through an experimental error analysis.The results demonstrate that the measurement error can be maintained within±8%for various flow patterns,including stratified flow,bubble flow,and wave flow.
基金supported by the China Postdoctoral Science Foundation(2021M702304)Natural Science Foundation of Shandong Province(ZR2021QE260).
文摘Continental shale oil reservoirs,characterized by numerous bedding planes and micro-nano scale pores,feature significantly higher stress sensitivity compared to other types of reservoirs.However,research on suitable stress sensitivity characterization models is still limited.In this study,three commonly used stress sensitivity models for shale oil reservoirs were considered,and experiments on representative core samples were conducted.By fitting and comparing the data,the“exponential model”was identified as a characterization model that accurately represents stress sensitivity in continental shale oil reservoirs.To validate the accuracy of the model,a two-phase seepage mathematical model for shale oil reservoirs coupled with the exponential model was introduced.The model was discretely solved using the finite volume method,and its accuracy was verified through the commercial simulator CMG.The study evaluated the productivity of a typical horizontal well under different engineering,geological,and fracture conditions.The results indicate that considering stress sensitivity leads to a 13.57%reduction in production for the same matrix permeability.Additionally,as the fracture half-length and the number of fractures increase,and the bottomhole flowing pressure decreases,the reservoir stress sensitivity becomes higher.
基金supported by the Graduate Student Innovation Project of China University of Petroleum(East China)in 2020(No.YCX2020031)the financial support by the National Natural Science Foundation of China(Nos.21876206,21505157)+1 种基金the Fundamental Research Funds for the Central Universities(China University of Petroleum(East China),Nos.18CX02037A,20CX05015A)the Youth Innovation and Technology project of Universities in Shandong Province(No.2020KJC007)。
文摘Abstract:As an important component of the atmosphere,ammonia(NH_(3))plays a very important role in maintaining the balance of environment.However,it is also one of the most toxic gases that can cause damage to the human respiratory system and mucous membranes even at low concentrations.As such,development of highly sensitive and selective NH_(3)sensors is of high significance for environmental monitoring and health maintenance.Herein,we have synthesized Au@Ag@Ag Cl core-shell nanoparticles(NPs)by oxidative etching and precipitating Au@Ag core-shell NPs using FeCl3 and further used them as optical probes for the colorimetric detection of NH_(3).The sensing mechanism is based on the fact that the etching of NH_(3)on AgCl and Ag shell leads to the variations of ingredients and core-to-shell ratio of the Au@Ag@AgCl NPs,thereby inducing noticeable spectral and color changes.By replacing the outmost layer of Ag with AgCl,not only is the stability of the sensor against oxygen significantly enhanced,but also is the sensitivity of the method improved.The method exhibits good linear relationship for the detection of NH_(3)from 0 to 5000 mmol/L with the limit of detection of 6.4 mmol/L.This method was successfully applied to the detection of simulated air polluted by NH_(3),indicating its practical applicability for environmental monitoring.This method shows great potential for on-site NH_(3)detection particularly in remote area,where a simple,fast,low-cost,and easy-to-handle method is highly desirable.
文摘At present,methods for treating tertiary oil recovery wastewater via electro-coagulation are still in their early stage of development.In this study,a device for electro-coagulation wastewater treatment was built and tested in an oil field.The effects that the initial pH value,electrode type,and connection mode have on the coagulation and separation effect were assessed by measuring the mass fraction and turbidity of oil.The results have shown that when the electro-coagulation method is used,the effectiveness of the treatment can be significantly increased in neutral pH conditions(pH=7),in acidic conditions,and in alkaline conditions.Compared to an Al electrode,the floc that is produced by an Fe electrode is smaller;thus,it does not easily coagulate and settle in a short time.Using the oil removal rate,turbidity removal rate and energy consumption as a basis to assess the performances,the results have demonstrated that the combined aluminum alloy iron composite electrode should be used as electrolytic electrode.
基金supported by the Natural Science Foundation of Qinghai Province(2024-ZJ-987)the Natural Science Foundation of Qinghai University(2023-QGY-9).
文摘The Chinese Loess Plateau has long been plagued by severe soil erosion and water scarcity.In this study,we proposed a technique involving the combined use of polymer SH and ryegrass and evaluated its effectiveness in modifying the water-holding characteristics of loess on the Chinese Loess Plateau(Chinese loess).We analysed the volumetric water content and water potential of untreated loess,treated loess with single polymer SH,treated loess with single ryegrass,and treated loess with both polymer SH and ryegrass using the loess samples collected from the Chinese Loess Plateau in July 2023.Moreover,fractal theory was used to analyse the fractal characteristics of the soil structure,and wet disintegration tests were conducted to assess the structural stability of both untreated and treated loess samples.The results showed that the loess samples treated with both polymer SH and ryegrass presented much higher volumetric water content and water potential than the untreated loess samples and those treated only with ryegrass or polymer SH.Moreover,the planting density of ryegrass affected the combined technique,since a relatively low planting density(20 g/m2)was conducive to enhancing the water-holding capacity of Chinese loess.The fractal dimension was directly correlated with both volumetric water content and water potential of Chinese loess.Specifically,since loess treated with both polymer SH and ryegrass was more saturated with moisture,its water potential increased,thus improving its water-holding capacity and fractal dimension.The combined technique better resisted disintegration than ryegrass alone but had slightly less resistance than polymer SH alone.This study provides insight into soil reinforcement and soil water management using polymetric materials and vegetation on the Chinese Loess Plateau.
