A corrosion discoloration model for copper-nickel alloys in Cl^(−)environments was established using CIE-Lab,UV-VIS absorption spectroscopy,X-ray diffraction,and X-ray photoelectron spectroscopy.The corrosion discolor...A corrosion discoloration model for copper-nickel alloys in Cl^(−)environments was established using CIE-Lab,UV-VIS absorption spectroscopy,X-ray diffraction,and X-ray photoelectron spectroscopy.The corrosion discoloration process and the corresponding main corrosion products can be summarized as follows:silver-white(Cu+Ni)→green(NiO)→reddishbrown(NiO+Cu_(2)O)→black(NiO+Cu_(2)O+CuO).Density functional theory was employed to explain the corrosion process of copper-nickel alloys and the detrimental effect of Cl^(−).The results indicate that adsorbates preferentially bind to nickel,leading to the preferential formation of NiO,which imparts a green appearance to the surface.Furthermore,the difficulty in forming nickel cation vacancies and the higher diffusion barrier for nickel inhibit the migration of species within the oxide layer.Notably,nickel also suppresses carrier migration within the oxide layer,reducing the charge transfer rate.In contrast,the promotion of corrosion by Cl^(−)is primarily attributed to the reduction in surface work function and the formation energy of cation vacancies.展开更多
Research on the ecohydrological processes of terrestrial plants is a frontier field comprising ecology,hydrology and global change research,yielding the key theoretical foundations of ecohydrology.In karst areas,due t...Research on the ecohydrological processes of terrestrial plants is a frontier field comprising ecology,hydrology and global change research,yielding the key theoretical foundations of ecohydrology.In karst areas,due to its unique geological background,the karst landscape is strongly developed,with high bedrock exposure,high permeability,fragmented soils,shallow soils,and high spatial heterogeneity,resulting in very limited water storage for plant uptake and growth in rock fissures and shallow soils.Therefore,water conditions are an important ecological factor influencing plant growth.To comprehensively understand the current progress and development trends in plant water use research focusing on karst areas,this paper uses the VOSviewer software to analyze the literature on plant water use in karst areas between 1984 and 2022.The results showed that:(1)Research on plant water use in karst areas has developed rapidly worldwide,and the number of relevant studies in the literature have increased year by year,which together means that it is attracting more and more attention.(2)The investigation of plant water sources,geological background of karst areas,seasonal arid tropical climates,the relationship betweenδ13C values and plant water use efficiency,karst plant water use in karst savannas and subtropical areas,and ecosystems under climate change yields the knowledge base in this field.(3)Most studies in this area focus on the division of water sources of plants in karst areas,the methods of studying the water use sources of plants,and the water use strategies and efficiency of plants.(4)Future research will focus on how plant water use in karst areas is influenced by Earth’s critical zones,climate change,and ecohydrological separation.These studies will provide a key scientific basis for guiding ecological restoration and promoting sustainable development in karst areas.展开更多
Seasonal precipitation has always been a key focus of climate prediction.As a dynamic-statistical combined method,the existing observational constraint correction establishes a regression relationship between the nume...Seasonal precipitation has always been a key focus of climate prediction.As a dynamic-statistical combined method,the existing observational constraint correction establishes a regression relationship between the numerical model outputs and historical observations,which can partly predict seasonal precipitation.However,solving a nonlinear problem through linear regression is significantly biased.This study implements a nonlinear optimization of an existing observational constrained correction model using a Light Gradient Boosting Machine(LightGBM)machine learning algorithm based on output from the Beijing National Climate Center Climate System Model(BCC-CSM)and station observations to improve the prediction of summer precipitation in China.The model was trained using a rolling approach,and LightGBM outperformed Linear Regression(LR),Extreme Gradient Boosting(XGBoost),and Categorical Boosting(CatBoost).Using parameter tuning to optimize the machine learning model and predict future summer precipitation using eight different predictors in BCC-CSM,the mean Anomaly Correlation Coefficient(ACC)score in the 2019–22 summer precipitation predictions was 0.17,and the mean Prediction Score(PS)reached 74.The PS score was improved by 7.87%and 6.63%compared with the BCC-CSM and the linear observational constraint approach,respectively.The observational constraint correction prediction strategy with LightGBM significantly and stably improved the prediction of summer precipitation in China compared to the previous linear observational constraint solution,providing a reference for flood control and drought relief during the flood season(summer)in China.展开更多
Surface deformation calculations due to environmental loading typically rely on the Preliminary Reference Earth Model(PREM),which assumes a homogeneous and isotropic Earth structure,leading to noticeable errors.To enh...Surface deformation calculations due to environmental loading typically rely on the Preliminary Reference Earth Model(PREM),which assumes a homogeneous and isotropic Earth structure,leading to noticeable errors.To enhance accuracy,the high-precision crustal model CRUST 1.0 is used to refine calculations of regional surface deformation caused by hydrological and non-tidal atmospheric loading.The improved model is applied to 27 Global Navigation Satellite System(GNSS)reference stations in the first phase of the Crustal Movement Observation Network of China(CMONOC),considering their geographical locations.Green's functions are employed to compute surface deformation at each site.Results indicate relative discrepancies of 11.78%and 14.14%for non-tidal atmospheric and hydrological loading compared to PREM,with vertical deformation differences reaching an average of 18.95%.Additionally,the distinct spatial distribution characteristics of the relative differences in each direction indicate that the improved RPREM model is more responsive to the mass variations derived from Gravity Recovery and Climate Experiment(GRACE).The results suggest that the improved PRREM model demonstrates higher sensitivity to loading variations than the PREM model.Utilizing the enhanced method of calculating surface deformation through the utilization of Green's function at the site could effectively reduce the calculation error caused by regional structure,leading to enhanced uniformity and isotropy of PREM.展开更多
The Urumqi foreland thrust tectonic belt exhibits complex geological structures and strong seismicity.Imaging its shallow crustal structure is of great significance for understanding its tectonic mechanism and seismog...The Urumqi foreland thrust tectonic belt exhibits complex geological structures and strong seismicity.Imaging its shallow crustal structure is of great significance for understanding its tectonic mechanism and seismogenic environment.We obtained a high-resolution S-wave velocity model of the shallow crust at depths of 0–8 km using ambient noise tomography applied to data from a dense seismic array.Sediments are generally thinner in the southeast and thicker in the northwest,with a maximum thickness of more than 8 km.Variations in the velocity structure near the Xishan,Wanyaogou,and Yamalike faults indicate that their formation was related to differences in the physical properties on either side of the fault.In addition,the faults exhibit thrusting of the low-velocity sides towards the high-velocity sides.In the study area,earthquakes rarely occur at depths of less than 3 km and are mostly concentrated in the high-velocity zone in the southern part.Below 3 km depth,more earthquakes were observed,mainly distributed near faults or in relatively high-velocity areas in the southern part.This suggests that high-velocity structures are more prone to stress accumulation,resulting in earthquakes.At 6–8 km depth,the densely distributed earthquakes in the northwestern part of the Bogda mountains are well-aligned with the northwest-oriented low-velocity zone observed in this study,suggesting that this weak zone likely controls seismicity in this area.展开更多
Influenza A virus(IAV) has a wide host range,including wild birds,poultry,various mammals,and even humans(Xu et al.2024).Currently,two subtypes of canine influenza virus(CIV),H3N8 and H3N2,are primarily circulating in...Influenza A virus(IAV) has a wide host range,including wild birds,poultry,various mammals,and even humans(Xu et al.2024).Currently,two subtypes of canine influenza virus(CIV),H3N8 and H3N2,are primarily circulating in dogs.The H3N8 CIV was introduced from horses into dogs in 2004(Crawford et al.2005),while the H3N2 CIV originated from chickens in Asia in 2007(Song et al.2008).In China,H3N2 is the predominant CIV subtype,with a prevalence rate of up to 5.63% in the canine population,as reported by Chen et al.(2023).CIV infection typically manifests with symptoms such as coughing,sneezing,runny nose,and fever but is rarely fatal.However,co-infection with other pathogens(e.g.,Streptococcus,Mycoplasma or canine parainfluenza virus) can exacerbate symptoms and lead to lethal outcomes(Yondo et al.2023).展开更多
The widely distributed loess deposits in the Yellow River Basin exhibit unique engineering geological characteristics.The variations in their thickness and stratigraphic structure significantly amplify ground motion p...The widely distributed loess deposits in the Yellow River Basin exhibit unique engineering geological characteristics.The variations in their thickness and stratigraphic structure significantly amplify ground motion parameters,directly influencing the regional seismic hazard risk level.This study methodically conducted on-site studies and observations of building collapses and damages resulting from seismic amplification effects,using the Wenchuan M_(S)8.0 earthquake as a case study.Comprehensive experimental and numerical simulation studies were carried out.A large-scale shaking table test was performed,and numerical models for 14 different loess sites types were established.Various types of seismic waves were incorporated into these models for systematic numerical simulation calculations.The research reveals the mechanisms by which loess deposit thickness and stratigraphic structure in the Yellow River Basin affect seismic ground motion amplification.The results indicate that as the epicentral distance increases,the peak ground motion shows a marked attenuation trend,with the horizontal component attenuating substantially faster than the vertical component.As the overlying loess layer thickness increases from 50 to 100 m,the seismic intensity may escalate by 3−4 degrees,and the peak acceleration may amplify by 1.5−2.2 times.With the augmentation of loess deposit thickness and the proliferation of soil layers,both the peak acceleration response spectrum and the characteristic period demonstrate an upward tendency,exhibiting slight fluctuations contingent upon the seismic wave type.展开更多
Coral reefs worldwide are losing their species diversity and ecosystem function under threats from global warming and anthropogenic activities.In this study,we investigated the diversity and current state of scleracti...Coral reefs worldwide are losing their species diversity and ecosystem function under threats from global warming and anthropogenic activities.In this study,we investigated the diversity and current state of scleractinian corals surrounding the Qizhou Archipelago.A total of 87 species of scleractinian corals,belonging to 29 genera and 12 families,were found across ten survey sites.The family Merulinidae exhibited the highest species richness(39 species and 12 genera),followed by Acroporidae(15 species and 3genera).The living coral coverage was 16.9%±10.3%(mean±SD)and ranged from 4.6%to 35.1%,which varied significantly.Massive corals such as Porites lutea,Porites lobata,Montipora nodosa,and Favites abdita were dominant species.The recruitment rate of coral larvae was(1.20±0.97)ind/m^(2)(mean±SD).In addition,we constructed an ecological vulnerability assessment system and evaluated the ecological vulnerability of scleractinian corals surrounding the Qizhou Archipelago.The results showed that scleractinian corals at Gouluanpaoshi(GLPS)and Duifan(DF)were highly vulnerable,whereas those on other islands had low to medium vulnerability.In general,the scleractinian corals surrounding the Qizhou Archipelago show low to medium levels of ecological vulnerability.Identifying severely afflicted areas and developing effective methods to manage coral reefs in these regions are crucial.展开更多
Insight into the carbon turnover in soil aggregates and density fractions is essential for reducing the uncertainty in estimating carbon pools on the Tibetan Plateau,and how they vary with land use type is unclear.In ...Insight into the carbon turnover in soil aggregates and density fractions is essential for reducing the uncertainty in estimating carbon pools on the Tibetan Plateau,and how they vary with land use type is unclear.In this study,the effect of land use type on carbon storage and fractionation was quantified based on organic carbon and its ^(13)C abundance at the microscale of soil aggregates and density fractions in Tibetan alpine ecosystems.The sequence of soil aggregate destruction in the land use types of plantation(13.1%)<shrubland(32.7%)<grassland(47.9%)<farmland(61.8%)shows that plantations strengthen the soil structure.Plantation land had a greater contribution of light fraction organic carbon(28.3%)but a lower contribution of mineral-associated organic carbon(40.6%)to the carbon stock compared to farmland(13.5 and 70.3%).Interestingly,plantation land enhanced the aggregational differentiation of organic carbon and ^(13)C in each density fraction,whereas no such phenomenon existed in the soil organic carbon.Carbon isotope analyses revealed that carbon transfer in the plantation land occurred from the light fraction in macroaggregates(–24.9‰)to the mineral-associated fraction in microaggregates(–19.9‰).When compared to the other three land use types,the low transferability of carbon in aggregates and density fractions in plantation land provides a stable carbon pool for the Tibetan Plateau.This study shows that plantations can mitigate global climate change by slowing carbon transfer and increasing carbon storage at the microscale of aggregates and density fractions in alpine regions.展开更多
Excessive levels of Fluoride(F−)and Cadmium(Cd)in drinking groundwater may pose health risks.This study assessed the health risks associated with F−and Cd contamination in rural drinking groundwater sources in Wutai C...Excessive levels of Fluoride(F−)and Cadmium(Cd)in drinking groundwater may pose health risks.This study assessed the health risks associated with F−and Cd contamination in rural drinking groundwater sources in Wutai County,Shanxi Province,China,to support population health protection,water resource management,and environmental decision-making.Groundwater samples were collected and analyzed,and a Human Health Risk Model(HHRA)was applied to evaluate groundwater quality.The results showed that both contents of F−and Cd in groundwater exceeded the Class III limits of China's national groundwater quality standard(GB/T 14848—2024).Fluoride levels met the Class V threshold,with enrichment area mainly located in the east part of the study area.Cadmium levels reached Class IV,with elevated concentrations primarily observed in the western and northwestern regions.Correlation analysis revealed that F−showed weak or no correlation with other measured substances,indicating independent sources.Health risk assessment results indicated that F−poses potential health risks to rural residents,while cadmium,due to its relatively low concentrations,does not currently present a significant health risk.Among different demographic groups,the health risk levels of F−exposure followed the order:Infants>children>adult females>adult males.The findings highlight that fluoride is the primary contributor to health risks associated with groundwater consumption in the study area.Strengthened monitoring and prevention of F−contamination are urgently needed.This research provides a scientific basis for the prevention and control of fluoride pollution in groundwater and offers practical guidance for safeguarding drinking water safety in rural China.展开更多
Cyperus esculentus(C.esculentus),a desert-adapted plant species with both ecological and economic value,has been widely cultivated in northern China's sandy regions.However,limited studies have investigated the pe...Cyperus esculentus(C.esculentus),a desert-adapted plant species with both ecological and economic value,has been widely cultivated in northern China's sandy regions.However,limited studies have investigated the performance of composite shelterbelts that integrate C.esculentus.This study systematically evaluated five shelterbelt models—Populus euphratica(P.euphratica),P.euphratica–C.esculentus composite,P.euphratica–nylon net–C.esculentus composite,Tamarix chinensis(T.chinensis),and T.chinensis–C.esculentus composite—using wind tunnel experiments and field observations.Sediment flux was measured at a normalized downwind distance(x/h)of 5,where x refers to the distance from the front edge(upwind side)of the shelterbelt for upwind measurements,and the distance from the rear edge(downwind side)for downwind measurements,and h represents the canopy height.Wind velocity was measured at x/h of–2,–1,1,2,3,5,and 7,and sand flux was measured at x/h=5,under initial wind velocities of 8.0 and 12.0 m/s.The results indicated that the P.euphratica–nylon net–C.esculentus composite was the most effective in reducing wind velocity,followed by the P.euphratica–C.esculentus composite.In contrast,the P.euphratica and T.chinensis exhibited relatively weaker wind reduction capabilities.Regarding sand flux,under moderate wind velocity(8.0 m/s),both the P.euphratica–C.esculentus composite and P.euphratica–nylon net–C.esculentus composite demonstrated the lowest sand flux values.However,under high wind velocity(12.0 m/s),the P.euphratica–nylon net–C.esculentus composite significantly outperformed the other shelterbelt models in sand retention,highlighting its superior windbreak and sand fixation efficacy.Field observations further validated the windbreak and sand fixation effects of C.esculentus.Comparisons between the bare sand plot and C.esculentus plot within protective forests demonstrated that planting C.esculentus can provide substantial ecological benefits in windbreak and sand-fixation.These findings,reinforced by field observations,strengthen the wind tunnel experiment results and highlight the critical role of C.esculentus in enhancing the performance of composite shelterbelts for desert ecological restoration.展开更多
Seasonal cycles are essential components of weather and climatic systems. This study utilized observational data from a meteorological station on an island in the South China Sea from 1961 to 2020, along with ERA5 rea...Seasonal cycles are essential components of weather and climatic systems. This study utilized observational data from a meteorological station on an island in the South China Sea from 1961 to 2020, along with ERA5 reanalysis data, to explore the variations in seasonal cycles and thermal comfort characteristics on the island. The observational data revealed that the onset of summer on the island occurred earlier each year, whereas the onset of autumn was gradually delayed,leading to an increase in the duration of summer. Urbanization had played an important role in elevating local temperatures and extending the duration of summer. The thermal comfort index exhibited a clear upward trend annually, reflecting a shift towards warmer and less comfortable conditions due to urbanization. From 1961 to 2020, the annual average thermal comfort index indicated that 36 years(60%) were characterized by hot discomfort, and 24 years(40%) were within the comfortable range. The number of comfortable days per year on the island exhibited a declining trend. Urbanization markedly influenced the thermal comfort levels on the island, contributing to an annual increase in the number of hot discomfort days. However, the reanalysis data did not reflect the actual observed changes in the comfort characteristics on the island.展开更多
The Yingxiu-Beichuan fault zone(YBFZ)has long been active and experienced repeated large earthquakes.The physicochemical properties of the deep fault zone(>1000 m)are the key to understanding the deformation mechan...The Yingxiu-Beichuan fault zone(YBFZ)has long been active and experienced repeated large earthquakes.The physicochemical properties of the deep fault zone(>1000 m)are the key to understanding the deformation mechanism of large earthquakes.This study uses rock magnetic,microstructural,and geochemical analyses of representative samples exposed in FZ1681 within the Wenchuan Earthquake Fault Scientific Drilling borehole 2(WFSD-2)cores.Fault gouge and fault breccia have higher magnetic susceptibility values than wall rocks,and they contain abundant paramagnetic minerals and small quantities of magnetite and monoclinic pyrrhotite.The magnetite and monoclinic pyrrhotite in the fault gouge were mainly formed by coseismic frictional heating,indicating that large earthquakes with frictional heating temperatures of~500-900℃once occurred in the YBFZ.The seismogenic and coseismic environment was reducing with a relatively high sulfur content.The monoclinic pyrrhotite in the fault breccia was formed mainly by low-temperature hydrothermal fluid.This indicates that the fault zone experienced reducing and low-temperature(<400℃)hydrothermal fluid with a relatively high sulfur content after the earthquake.The YBFZ,which experiences frequent large earthquakes,is weakly oxidizing environment at different depths,but the effect of the low-temperature hydrothermal fluid is weaker at depth.展开更多
Changes in the soil environment induced by major global changes in climate are affecting carbon emissions in cold-temperate coniferous forests.A randomized block experiment simulating warming,rainfall increase and nit...Changes in the soil environment induced by major global changes in climate are affecting carbon emissions in cold-temperate coniferous forests.A randomized block experiment simulating warming,rainfall increase and nitrogen addition in a Larix gmelinii forest was carried out to study the effects on soil carbon,nitrogen,and CO_(2)flux during the thawing,growing,and freezing periods.Our study found that warming(0-2.0℃)increased soil organic carbon(SOC)and total nitrogen(STN),dissolved organic carbon(DOC)and dissolved organic nitrogen(DON),and microbial biomass carbon(MBC)and microbial biomass nitrogen(MBN).Warming played a direct role in regulating soil CO_(2)emissions,stimulated microbial and plant root respiration and soil CO_(2)flux rapidly increased.Rainfall increase initially increased soil carbon and nitrogen,but a 30%increase in mean annual rainfall caused losses of SOC,STN,DOC,and DON,while MBC and MBN accumulated.Soil CO_(2)emissions were regulated by MBC after an increase in rainfall,excess moisture inhibited microbial activity,and soil CO_(2)flux showed a trend of R2(20%rainfall increase)>R1(10%rainfall increase)>CK(control)>R3(30%rainfall increase).The addition of nitrogen increased SOC,STN,DOC,DON,MBC and MBN.Soil CO_(2)flux progressively decreased with nitrogen inputs(2.5,5.0 and 10.0 g m^(-2)a^(-1)),as more N intensified plant-microbe competition.Nitrogen addition indirectly regulated soil CO_(2)emissions by altering SOC and STN,with MBC and MBN acting as secondary regulators.The results highlight the role of cold-temperate coniferous forest soils in predicting carbon-climate feedback in high-latitude forest permafrost regions.展开更多
Rapid urbanization in China has led to spatial antagonism between urban development and farmland protection and ecological security maintenance.Multi-objective spatial collaborative optimization is a powerful method f...Rapid urbanization in China has led to spatial antagonism between urban development and farmland protection and ecological security maintenance.Multi-objective spatial collaborative optimization is a powerful method for achieving sustainable regional development.Previous studies on multi-objective spatial optimization do not involve spatial corrections to simulation results based on the natural endowment of space resources.This study proposes an Ecological Security-Food Security-Urban Sustainable Development(ES-FS-USD)spatial optimization framework.This framework combines the non-dominated sorting genetic algorithm II(NSGA-II)and patch-generating land use simulation(PLUS)model with an ecological protection importance evaluation,comprehensive agricultural productivity evaluation,and urban sustainable development potential assessment and optimizes the territorial space in the Yangtze River Delta(YRD)region in 2035.The proposed sustainable development(SD)scenario can effectively reduce the destruction of landscape patterns of various land-use types while considering both ecological and economic benefits.The simulation results were further revised by evaluating the land-use suitability of the YRD region.According to the revised spatial pattern for the YRD in 2035,the farmland area accounts for 43.59%of the total YRD,which is 5.35%less than that in 2010.Forest,grassland,and water area account for 40.46%of the total YRD—an increase of 1.42%compared with the case in 2010.Construction land accounts for 14.72%of the total YRD—an increase of 2.77%compared with the case in 2010.The ES-FS-USD spatial optimization framework ensures that spatial optimization outcomes are aligned with the natural endowments of land resources,thereby promoting the sustainable use of land resources,improving the ability of spatial management,and providing valuable insights for decision makers.展开更多
Reservoir-induced landslides in China's Three Gorges Reservoir area are prone to tensile cracks due to the influenceof their own weight and fluctuationsin water levels.The presence of cracks indicates that the ten...Reservoir-induced landslides in China's Three Gorges Reservoir area are prone to tensile cracks due to the influenceof their own weight and fluctuationsin water levels.The presence of cracks indicates that the tensile stress in the area has exceeded the tensile strength of the soil,leading to local instability.To explore the impact of tensile failure behavior on the stability and failure modes of reservoir landslides,the Huangtupo Riverside Slump#1 is taken as a case study.By considering local tensile failure,potential tensile cracks are incorporated into the analysis via the limit equilibrium method and reliability theory.The reliability of landslides under different tensile failure scenarios is quantified.Strain-softening characteristics of the soil are combined to further analyze the failure transmission path of the landslide.Finally,these potential failure modes were validated through physical model tests.The results show that cracks developing at rear positions reduce the stability of the slope and increase the probability of instability.During the destruction process,retrogressive failures with multiple sliding surfaces are likely to occur.However,tensile failure at the forefront reduces the likelihood of an individual slide mass descending.Progressive failure results in both regular and skip transmission patterns.Additionally,cracks and water level changes can also lead to shifts in the positions of the most dangerous blocks.Therefore,in practical landslide analysis and prevention,it is necessary to consider local tensile damage and identify potential tensile crack locations in advance to optimize prevention measures and accurately evaluate landslide risk.展开更多
Phosphorus (P) is an essential nutrient element that is critical for plant growth and ecosystem functionality.The soil P cycle plays multiple roles,such as sustaining plant growth and productivity,regulating nutrient ...Phosphorus (P) is an essential nutrient element that is critical for plant growth and ecosystem functionality.The soil P cycle plays multiple roles,such as sustaining plant growth and productivity,regulating nutrient balance within ecosystems,and enhancing ecosystem adaptability and resilience.This cycle is influenced by factors such as the restoration approach and microbial community dynamics.However,the extent to which the restoration approach alters the P cycle in karst ecosystems and the underlying microbial mechanisms remain poorly understood.The P-cycle multifunctionality index (P-cycle MFI) serves as a comprehensive indicator for evaluating soil P cycle function,and it provides insights into changes in the P cycle between different restoration approaches.To investigate the shifts in soil P-cycle MFI and microbial mechanisms between different restoration approaches,we analyzed soil available P (AP),total P (TP),microbial biomass P (MBP),and the activities of acid phosphatase (ACP) and alkaline phosphatase (ALP).These data were used to calculate the P-cycle MFI by averaging the Z-scores between two restoration approaches(artificial restoration of forest (AF) and natural restoration of forest (NF)) and a control (cropland,CP) at six subtropical karst ecosystem sites in China.We also determined the soil organic carbon (SOC),exchangeable calcium (Ca) and magnesium (Mg),pH,bulk density (BD),microbial biomass C (MBC),and microbial biomass nitrogen (MBN),as well as the community structure,relative abundance,diversity indices,and co-occurrence networks of phoD-harboring bacteria.The results showed that the community structure of phoD-harboring bacteria varied significantly among AF,NF,and CP and across different temperature gradients.These bacteria exhibited increasing complexity and tightness in co-occurrence networks from CP to AF and then to NF,along with the ACP and ALP activities,but not the TP and AP contents.The P-cycle MFI values were significantly higher in NF compared to AF and CP,and the variation was significantly explained by restoration approach,temperature,MBC,MBN,SOC,exchangeable Ca,BD,community structure of phoD-harboring bacteria,and exchangeable Mg.Furthermore,natural restoration had a more substantial impact on the P-cycle MFI than temperature by enhancing SOC,microbial biomass,the complexity and co-occurrence network tightness of the phoD-harboring bacterial community structure,and ACP and ALP activities,but it reduced soil BD.The rare genera of phoD-harboring bacteria significantly influenced the variation of soil P-cycle MFI compared to the dominant genera.This study highlights the importance of rare genera of phoD-harboring bacteria in driving soil P-cycle multifunctionality in karst ecosystems,with natural restoration being more effective than artificial methods for enhancing soil organic matter and microbial community complexity.展开更多
Tajikistan contains the majority of Central Asia’s glaciers,which cover about 6.00%of the national territory;their rapid shrinkage poses a significant threat to regional water resource security.However,glacier monito...Tajikistan contains the majority of Central Asia’s glaciers,which cover about 6.00%of the national territory;their rapid shrinkage poses a significant threat to regional water resource security.However,glacier monitoring in Tajikistan was interrupted after 1991,creating a substantial gap in understanding the current state and temporal evolution of these glaciers.Based on glacier inventory data,in situ measurements,and published literature,this study examined the present status and recent variations of glaciers in Tajikistan through data integration and validation,literature collation and comparative analysis,and the application of Geographic Information System(GIS)spatial analysis techniques.As of 2023,Tajikistan possesses a total of 11,528 glaciers,encompassing an area of 7624.48(±305.58)km2.Small glaciers dominate in number,whereas large glaciers account for the majority of the total area.Over the past two decades,the glacier count has decreased by 2014,and the total area has decreased by 628.98 km2,corresponding to an average annual reduction rate of 0.33%.Regional shrinkage rates range from 4.10%to 22.28%.Glaciers have undergone accelerated mass loss during the past 20 a;only those on the northeastern Pamir Plateau exhibit a weak positive mass balance.Observations of typical monitored glaciers also reveal intensified melting and retreat,consistent with regional trends.In light of the recent acceleration of glacier shrinkage in Tajikistan,focused measures should be implemented to strengthen glacier monitoring,enhance public awareness of glacier preservation,and promote the sustainable development and utilization of glacier tourism.These findings bridge the knowledge gap regarding the spatiotemporal dynamics of Tajikistan’s glaciers over recent decades and provide essential data support for regional water resource management.展开更多
Understanding the spatial distributions and corresponding variation mechanisms of key soil nutrients in fragile karst ecosystems can assist in promoting sustainable development.However,due to the implementation of eco...Understanding the spatial distributions and corresponding variation mechanisms of key soil nutrients in fragile karst ecosystems can assist in promoting sustainable development.However,due to the implementation of ecological restoration initiatives such as land-use conversions,novel changes in the spatial characteristics of soil nutrients remain unknown.To address this gap,we explored nutrient variations and the drivers of the variation in the 0–15 cm topsoil layer using a regional-scale sampling method in a typical karst area in northwest Guangxi Zhuang Autonomous Region,Southwest China.Descriptive statistics,geostatistics,and spatial analysis were used to assess the soil nutrient variability.The results indicated that soil organic carbon(SOC),total nitrogen(TN),total phosphorus(TP),and total potassium(TK)concentrations showed moderate variations,with coefficients of variance being 0.60,0.60,0.71,and 0.72,respectively.Moreover,they demonstrated positive spatial autocorrelations,with global Moran's indices being 0.68,0.77,0.64,and 0.68,respectively.However,local Moran's index values were low,indicating large spatial variations in soil nutrients.The best-fitting semi-variogram models for SOC,TN,TP,and TK concentrations were spherical,Gaussian,exponential,and exponential,respectively.According to the classification criteria of the Second National Soil Census in China,SOC and TN concentrations were relatively sufficient,with the proportions of rich and very rich levels being up to 90.9 and 96.0%,respectively.TP concentration was in the mediumdeficient level,with the areas of medium and deficient levels accounting for 33.7 and 30.1%of the total,respectively.TK concentration was deficient,with the cumulative area of extremely deficient,very deficient,and deficient levels accounting for 87.6%of the total area.Consequently,the terrestrial ecosystems in the study area were more vulnerable to soil P and K than soil N deficiencies.Furthermore,variance partitioning analysis of the influencing factors showed that,except for the interactions,the single effect of other soil properties accounted more for soil nutrient variations than spatial and environmental variables.These results will aid in the future management of terrestrial ecosystems.展开更多
Freshwater scarcity is exacerbated by uneven distribution of limited freshwater resources and high energy costs of desalination technologies.Atmospheric water vapor,a vast and geographically unrestricted reservoir,cou...Freshwater scarcity is exacerbated by uneven distribution of limited freshwater resources and high energy costs of desalination technologies.Atmospheric water vapor,a vast and geographically unrestricted reservoir,could become a sustainable alternative.Sorption-based atmospheric water harvesting(SAWH)has emerged as an available solution,yet conventional desorption methods relying on energy-intensive electrical heating hinder its scalability.Herein,a photothermal hygroscopic sponge has been developed for solar-driven atmospheric water harvesting.The composites combine a malleable melamine sponge skeleton,lithium chloride as a hygroscopic agent,and hydrangea-like molybdenum disulfide as a photothermal component,forming a multiscale“pore-film”cross-linked structure by an eco-friendly immersion-freeze-drying method.The optimized sample achieves exceptional hygroscopic capacity(3.92 g/g at 90%RH)and freshwater production efficiency(87.77%),which is attributed to synergistic effects of porous skeleton based crosslinked structures and“pore-film”structures,and outstanding photothermal conversion efficiency of MoS2.The unique structure could stabilize LiCl to prevent leakage,increase mass transfer effectiveness of whole SWAH process,and enable flexibility for diverse applications.We carried out outdoor experiments to demonstrate a solar-driven water production rate of 4.22 L m-2 d-1 without external energy input.This work provides insights into sustainable freshwater generation and promotes green energy utilization in addressing global water scarcity.展开更多
基金supported by the Key Program of the National Natural Science Foundation of China(Grant No.51131007)the National Key Research and Development Program of China(Grant No.2021YFC2803102).
文摘A corrosion discoloration model for copper-nickel alloys in Cl^(−)environments was established using CIE-Lab,UV-VIS absorption spectroscopy,X-ray diffraction,and X-ray photoelectron spectroscopy.The corrosion discoloration process and the corresponding main corrosion products can be summarized as follows:silver-white(Cu+Ni)→green(NiO)→reddishbrown(NiO+Cu_(2)O)→black(NiO+Cu_(2)O+CuO).Density functional theory was employed to explain the corrosion process of copper-nickel alloys and the detrimental effect of Cl^(−).The results indicate that adsorbates preferentially bind to nickel,leading to the preferential formation of NiO,which imparts a green appearance to the surface.Furthermore,the difficulty in forming nickel cation vacancies and the higher diffusion barrier for nickel inhibit the migration of species within the oxide layer.Notably,nickel also suppresses carrier migration within the oxide layer,reducing the charge transfer rate.In contrast,the promotion of corrosion by Cl^(−)is primarily attributed to the reduction in surface work function and the formation energy of cation vacancies.
基金This work was supported by the National Key Research and Development Program of China(2021YFE0107100)Guangxi Key Research and Development Program(GuikeAB22035004)Guangxi Science and Technology Base and Talent Special Project(Guike AD20297090).
文摘Research on the ecohydrological processes of terrestrial plants is a frontier field comprising ecology,hydrology and global change research,yielding the key theoretical foundations of ecohydrology.In karst areas,due to its unique geological background,the karst landscape is strongly developed,with high bedrock exposure,high permeability,fragmented soils,shallow soils,and high spatial heterogeneity,resulting in very limited water storage for plant uptake and growth in rock fissures and shallow soils.Therefore,water conditions are an important ecological factor influencing plant growth.To comprehensively understand the current progress and development trends in plant water use research focusing on karst areas,this paper uses the VOSviewer software to analyze the literature on plant water use in karst areas between 1984 and 2022.The results showed that:(1)Research on plant water use in karst areas has developed rapidly worldwide,and the number of relevant studies in the literature have increased year by year,which together means that it is attracting more and more attention.(2)The investigation of plant water sources,geological background of karst areas,seasonal arid tropical climates,the relationship betweenδ13C values and plant water use efficiency,karst plant water use in karst savannas and subtropical areas,and ecosystems under climate change yields the knowledge base in this field.(3)Most studies in this area focus on the division of water sources of plants in karst areas,the methods of studying the water use sources of plants,and the water use strategies and efficiency of plants.(4)Future research will focus on how plant water use in karst areas is influenced by Earth’s critical zones,climate change,and ecohydrological separation.These studies will provide a key scientific basis for guiding ecological restoration and promoting sustainable development in karst areas.
基金jointly supported by the National Natural Science Foundation of China(Grant Nos.42122034,42075043,42330609)the Second Tibetan Plateau Scientific Expedition and Research program(2019QZKK0103)+2 种基金Key Talent Project in Gansu and Central Guidance Fund for Local Science and Technology Development Projects in Gansu(No.24ZYQA031)the Youth Innovation Promotion Association of Chinese Academy of Sciences(2021427)West Light Foundation of the Chinese Academy of Sciences(xbzg-zdsys-202215)。
文摘Seasonal precipitation has always been a key focus of climate prediction.As a dynamic-statistical combined method,the existing observational constraint correction establishes a regression relationship between the numerical model outputs and historical observations,which can partly predict seasonal precipitation.However,solving a nonlinear problem through linear regression is significantly biased.This study implements a nonlinear optimization of an existing observational constrained correction model using a Light Gradient Boosting Machine(LightGBM)machine learning algorithm based on output from the Beijing National Climate Center Climate System Model(BCC-CSM)and station observations to improve the prediction of summer precipitation in China.The model was trained using a rolling approach,and LightGBM outperformed Linear Regression(LR),Extreme Gradient Boosting(XGBoost),and Categorical Boosting(CatBoost).Using parameter tuning to optimize the machine learning model and predict future summer precipitation using eight different predictors in BCC-CSM,the mean Anomaly Correlation Coefficient(ACC)score in the 2019–22 summer precipitation predictions was 0.17,and the mean Prediction Score(PS)reached 74.The PS score was improved by 7.87%and 6.63%compared with the BCC-CSM and the linear observational constraint approach,respectively.The observational constraint correction prediction strategy with LightGBM significantly and stably improved the prediction of summer precipitation in China compared to the previous linear observational constraint solution,providing a reference for flood control and drought relief during the flood season(summer)in China.
基金supported by the National Natural Science Foundation of China(Grant 42204006)the Education Commission of Hubei Province of China(Grant D20232802)+1 种基金the Open Fund of Wuhan,Gravitationand Solid EarthTides,National Observationand Research Station(Grant WHYWZ202407)the Open Fund of Hubei Luojia Laboratory(Grant 230100020,230100019).
文摘Surface deformation calculations due to environmental loading typically rely on the Preliminary Reference Earth Model(PREM),which assumes a homogeneous and isotropic Earth structure,leading to noticeable errors.To enhance accuracy,the high-precision crustal model CRUST 1.0 is used to refine calculations of regional surface deformation caused by hydrological and non-tidal atmospheric loading.The improved model is applied to 27 Global Navigation Satellite System(GNSS)reference stations in the first phase of the Crustal Movement Observation Network of China(CMONOC),considering their geographical locations.Green's functions are employed to compute surface deformation at each site.Results indicate relative discrepancies of 11.78%and 14.14%for non-tidal atmospheric and hydrological loading compared to PREM,with vertical deformation differences reaching an average of 18.95%.Additionally,the distinct spatial distribution characteristics of the relative differences in each direction indicate that the improved RPREM model is more responsive to the mass variations derived from Gravity Recovery and Climate Experiment(GRACE).The results suggest that the improved PRREM model demonstrates higher sensitivity to loading variations than the PREM model.Utilizing the enhanced method of calculating surface deformation through the utilization of Green's function at the site could effectively reduce the calculation error caused by regional structure,leading to enhanced uniformity and isotropy of PREM.
基金supported by the Key Research and Development Program of the Xinjiang Uygur Autonomous Region(No.2020B03006-1)the National Natural Science Foundation of China(Nos.42304069,and 42102275).
文摘The Urumqi foreland thrust tectonic belt exhibits complex geological structures and strong seismicity.Imaging its shallow crustal structure is of great significance for understanding its tectonic mechanism and seismogenic environment.We obtained a high-resolution S-wave velocity model of the shallow crust at depths of 0–8 km using ambient noise tomography applied to data from a dense seismic array.Sediments are generally thinner in the southeast and thicker in the northwest,with a maximum thickness of more than 8 km.Variations in the velocity structure near the Xishan,Wanyaogou,and Yamalike faults indicate that their formation was related to differences in the physical properties on either side of the fault.In addition,the faults exhibit thrusting of the low-velocity sides towards the high-velocity sides.In the study area,earthquakes rarely occur at depths of less than 3 km and are mostly concentrated in the high-velocity zone in the southern part.Below 3 km depth,more earthquakes were observed,mainly distributed near faults or in relatively high-velocity areas in the southern part.This suggests that high-velocity structures are more prone to stress accumulation,resulting in earthquakes.At 6–8 km depth,the densely distributed earthquakes in the northwestern part of the Bogda mountains are well-aligned with the northwest-oriented low-velocity zone observed in this study,suggesting that this weak zone likely controls seismicity in this area.
基金supported by the National Key Research and Development Program of China (2021YFD1800200)the National Natural Science Foundation of China (32170539)。
文摘Influenza A virus(IAV) has a wide host range,including wild birds,poultry,various mammals,and even humans(Xu et al.2024).Currently,two subtypes of canine influenza virus(CIV),H3N8 and H3N2,are primarily circulating in dogs.The H3N8 CIV was introduced from horses into dogs in 2004(Crawford et al.2005),while the H3N2 CIV originated from chickens in Asia in 2007(Song et al.2008).In China,H3N2 is the predominant CIV subtype,with a prevalence rate of up to 5.63% in the canine population,as reported by Chen et al.(2023).CIV infection typically manifests with symptoms such as coughing,sneezing,runny nose,and fever but is rarely fatal.However,co-infection with other pathogens(e.g.,Streptococcus,Mycoplasma or canine parainfluenza virus) can exacerbate symptoms and lead to lethal outcomes(Yondo et al.2023).
基金supported by the Earthquake Science and Technology Spark Plan Project(No.XH23041C)The Natural Science Foundation of Gansu Province(No.22JR11RA090)Gansu Lanzhou Geophysics National Observation and Research Station(No.2021Y14).
文摘The widely distributed loess deposits in the Yellow River Basin exhibit unique engineering geological characteristics.The variations in their thickness and stratigraphic structure significantly amplify ground motion parameters,directly influencing the regional seismic hazard risk level.This study methodically conducted on-site studies and observations of building collapses and damages resulting from seismic amplification effects,using the Wenchuan M_(S)8.0 earthquake as a case study.Comprehensive experimental and numerical simulation studies were carried out.A large-scale shaking table test was performed,and numerical models for 14 different loess sites types were established.Various types of seismic waves were incorporated into these models for systematic numerical simulation calculations.The research reveals the mechanisms by which loess deposit thickness and stratigraphic structure in the Yellow River Basin affect seismic ground motion amplification.The results indicate that as the epicentral distance increases,the peak ground motion shows a marked attenuation trend,with the horizontal component attenuating substantially faster than the vertical component.As the overlying loess layer thickness increases from 50 to 100 m,the seismic intensity may escalate by 3−4 degrees,and the peak acceleration may amplify by 1.5−2.2 times.With the augmentation of loess deposit thickness and the proliferation of soil layers,both the peak acceleration response spectrum and the characteristic period demonstrate an upward tendency,exhibiting slight fluctuations contingent upon the seismic wave type.
基金funded by the Scientific Research Foundation of Third Institute of Oceanography,Ministry of Natural Resources(Nos.2022024 and 2020006)the National Natural Science Foundation of China(No.42106143)。
文摘Coral reefs worldwide are losing their species diversity and ecosystem function under threats from global warming and anthropogenic activities.In this study,we investigated the diversity and current state of scleractinian corals surrounding the Qizhou Archipelago.A total of 87 species of scleractinian corals,belonging to 29 genera and 12 families,were found across ten survey sites.The family Merulinidae exhibited the highest species richness(39 species and 12 genera),followed by Acroporidae(15 species and 3genera).The living coral coverage was 16.9%±10.3%(mean±SD)and ranged from 4.6%to 35.1%,which varied significantly.Massive corals such as Porites lutea,Porites lobata,Montipora nodosa,and Favites abdita were dominant species.The recruitment rate of coral larvae was(1.20±0.97)ind/m^(2)(mean±SD).In addition,we constructed an ecological vulnerability assessment system and evaluated the ecological vulnerability of scleractinian corals surrounding the Qizhou Archipelago.The results showed that scleractinian corals at Gouluanpaoshi(GLPS)and Duifan(DF)were highly vulnerable,whereas those on other islands had low to medium vulnerability.In general,the scleractinian corals surrounding the Qizhou Archipelago show low to medium levels of ecological vulnerability.Identifying severely afflicted areas and developing effective methods to manage coral reefs in these regions are crucial.
基金financially supported by the National Natural Science Foundation of China (42477044,32171648 and U23A2017)the Hubei Provincial Science and Technology Program,China (2025AFD451 and 2022CFB030)。
文摘Insight into the carbon turnover in soil aggregates and density fractions is essential for reducing the uncertainty in estimating carbon pools on the Tibetan Plateau,and how they vary with land use type is unclear.In this study,the effect of land use type on carbon storage and fractionation was quantified based on organic carbon and its ^(13)C abundance at the microscale of soil aggregates and density fractions in Tibetan alpine ecosystems.The sequence of soil aggregate destruction in the land use types of plantation(13.1%)<shrubland(32.7%)<grassland(47.9%)<farmland(61.8%)shows that plantations strengthen the soil structure.Plantation land had a greater contribution of light fraction organic carbon(28.3%)but a lower contribution of mineral-associated organic carbon(40.6%)to the carbon stock compared to farmland(13.5 and 70.3%).Interestingly,plantation land enhanced the aggregational differentiation of organic carbon and ^(13)C in each density fraction,whereas no such phenomenon existed in the soil organic carbon.Carbon isotope analyses revealed that carbon transfer in the plantation land occurred from the light fraction in macroaggregates(–24.9‰)to the mineral-associated fraction in microaggregates(–19.9‰).When compared to the other three land use types,the low transferability of carbon in aggregates and density fractions in plantation land provides a stable carbon pool for the Tibetan Plateau.This study shows that plantations can mitigate global climate change by slowing carbon transfer and increasing carbon storage at the microscale of aggregates and density fractions in alpine regions.
基金supported by the Northeast Geological Science and Technology Innovation Center of China Geological Survey(Grant NO.QCJJ2022-43)the Natural Resources Comprehensive Survey Project(Grant Nos.DD20230470,DD20230508)the National Groundwater Monitoring Network Operation and Maintenance Program(Grant No.DD20251300109).
文摘Excessive levels of Fluoride(F−)and Cadmium(Cd)in drinking groundwater may pose health risks.This study assessed the health risks associated with F−and Cd contamination in rural drinking groundwater sources in Wutai County,Shanxi Province,China,to support population health protection,water resource management,and environmental decision-making.Groundwater samples were collected and analyzed,and a Human Health Risk Model(HHRA)was applied to evaluate groundwater quality.The results showed that both contents of F−and Cd in groundwater exceeded the Class III limits of China's national groundwater quality standard(GB/T 14848—2024).Fluoride levels met the Class V threshold,with enrichment area mainly located in the east part of the study area.Cadmium levels reached Class IV,with elevated concentrations primarily observed in the western and northwestern regions.Correlation analysis revealed that F−showed weak or no correlation with other measured substances,indicating independent sources.Health risk assessment results indicated that F−poses potential health risks to rural residents,while cadmium,due to its relatively low concentrations,does not currently present a significant health risk.Among different demographic groups,the health risk levels of F−exposure followed the order:Infants>children>adult females>adult males.The findings highlight that fluoride is the primary contributor to health risks associated with groundwater consumption in the study area.Strengthened monitoring and prevention of F−contamination are urgently needed.This research provides a scientific basis for the prevention and control of fluoride pollution in groundwater and offers practical guidance for safeguarding drinking water safety in rural China.
基金supported by the Xinjiang Key Research and Development Programme Project(2022B02040-2)the Tianshan Yingcai Program of Xinjiang Uygur Autonomous Region(2024TSYCLJ0028).
文摘Cyperus esculentus(C.esculentus),a desert-adapted plant species with both ecological and economic value,has been widely cultivated in northern China's sandy regions.However,limited studies have investigated the performance of composite shelterbelts that integrate C.esculentus.This study systematically evaluated five shelterbelt models—Populus euphratica(P.euphratica),P.euphratica–C.esculentus composite,P.euphratica–nylon net–C.esculentus composite,Tamarix chinensis(T.chinensis),and T.chinensis–C.esculentus composite—using wind tunnel experiments and field observations.Sediment flux was measured at a normalized downwind distance(x/h)of 5,where x refers to the distance from the front edge(upwind side)of the shelterbelt for upwind measurements,and the distance from the rear edge(downwind side)for downwind measurements,and h represents the canopy height.Wind velocity was measured at x/h of–2,–1,1,2,3,5,and 7,and sand flux was measured at x/h=5,under initial wind velocities of 8.0 and 12.0 m/s.The results indicated that the P.euphratica–nylon net–C.esculentus composite was the most effective in reducing wind velocity,followed by the P.euphratica–C.esculentus composite.In contrast,the P.euphratica and T.chinensis exhibited relatively weaker wind reduction capabilities.Regarding sand flux,under moderate wind velocity(8.0 m/s),both the P.euphratica–C.esculentus composite and P.euphratica–nylon net–C.esculentus composite demonstrated the lowest sand flux values.However,under high wind velocity(12.0 m/s),the P.euphratica–nylon net–C.esculentus composite significantly outperformed the other shelterbelt models in sand retention,highlighting its superior windbreak and sand fixation efficacy.Field observations further validated the windbreak and sand fixation effects of C.esculentus.Comparisons between the bare sand plot and C.esculentus plot within protective forests demonstrated that planting C.esculentus can provide substantial ecological benefits in windbreak and sand-fixation.These findings,reinforced by field observations,strengthen the wind tunnel experiment results and highlight the critical role of C.esculentus in enhancing the performance of composite shelterbelts for desert ecological restoration.
基金National Natural Science Foundation of China(U21A6001,42475077)Innovation Platform for Academicians of Hainan Province。
文摘Seasonal cycles are essential components of weather and climatic systems. This study utilized observational data from a meteorological station on an island in the South China Sea from 1961 to 2020, along with ERA5 reanalysis data, to explore the variations in seasonal cycles and thermal comfort characteristics on the island. The observational data revealed that the onset of summer on the island occurred earlier each year, whereas the onset of autumn was gradually delayed,leading to an increase in the duration of summer. Urbanization had played an important role in elevating local temperatures and extending the duration of summer. The thermal comfort index exhibited a clear upward trend annually, reflecting a shift towards warmer and less comfortable conditions due to urbanization. From 1961 to 2020, the annual average thermal comfort index indicated that 36 years(60%) were characterized by hot discomfort, and 24 years(40%) were within the comfortable range. The number of comfortable days per year on the island exhibited a declining trend. Urbanization markedly influenced the thermal comfort levels on the island, contributing to an annual increase in the number of hot discomfort days. However, the reanalysis data did not reflect the actual observed changes in the comfort characteristics on the island.
基金supported by the Deep Earth Probe and Mineral Resources Exploration-National Science and Technology Major Project(2024ZD1000500)the National Natural Science Foundation of China(42172262 and 42372266)+1 种基金the China Geological Survey(DD20240041)the Fundamental Research Funds of the Institute of Geomechanics(DZLXJK202516).
文摘The Yingxiu-Beichuan fault zone(YBFZ)has long been active and experienced repeated large earthquakes.The physicochemical properties of the deep fault zone(>1000 m)are the key to understanding the deformation mechanism of large earthquakes.This study uses rock magnetic,microstructural,and geochemical analyses of representative samples exposed in FZ1681 within the Wenchuan Earthquake Fault Scientific Drilling borehole 2(WFSD-2)cores.Fault gouge and fault breccia have higher magnetic susceptibility values than wall rocks,and they contain abundant paramagnetic minerals and small quantities of magnetite and monoclinic pyrrhotite.The magnetite and monoclinic pyrrhotite in the fault gouge were mainly formed by coseismic frictional heating,indicating that large earthquakes with frictional heating temperatures of~500-900℃once occurred in the YBFZ.The seismogenic and coseismic environment was reducing with a relatively high sulfur content.The monoclinic pyrrhotite in the fault breccia was formed mainly by low-temperature hydrothermal fluid.This indicates that the fault zone experienced reducing and low-temperature(<400℃)hydrothermal fluid with a relatively high sulfur content after the earthquake.The YBFZ,which experiences frequent large earthquakes,is weakly oxidizing environment at different depths,but the effect of the low-temperature hydrothermal fluid is weaker at depth.
基金funded by the Science and Technology Programme of Inner Mongolia Autonomous Region(Grant No.:2023YFDZ0026 and 2024KYPT0003)the 2024 Postgraduate Research and Innovation Programme of Inner Mongolia Agricultural University。
文摘Changes in the soil environment induced by major global changes in climate are affecting carbon emissions in cold-temperate coniferous forests.A randomized block experiment simulating warming,rainfall increase and nitrogen addition in a Larix gmelinii forest was carried out to study the effects on soil carbon,nitrogen,and CO_(2)flux during the thawing,growing,and freezing periods.Our study found that warming(0-2.0℃)increased soil organic carbon(SOC)and total nitrogen(STN),dissolved organic carbon(DOC)and dissolved organic nitrogen(DON),and microbial biomass carbon(MBC)and microbial biomass nitrogen(MBN).Warming played a direct role in regulating soil CO_(2)emissions,stimulated microbial and plant root respiration and soil CO_(2)flux rapidly increased.Rainfall increase initially increased soil carbon and nitrogen,but a 30%increase in mean annual rainfall caused losses of SOC,STN,DOC,and DON,while MBC and MBN accumulated.Soil CO_(2)emissions were regulated by MBC after an increase in rainfall,excess moisture inhibited microbial activity,and soil CO_(2)flux showed a trend of R2(20%rainfall increase)>R1(10%rainfall increase)>CK(control)>R3(30%rainfall increase).The addition of nitrogen increased SOC,STN,DOC,DON,MBC and MBN.Soil CO_(2)flux progressively decreased with nitrogen inputs(2.5,5.0 and 10.0 g m^(-2)a^(-1)),as more N intensified plant-microbe competition.Nitrogen addition indirectly regulated soil CO_(2)emissions by altering SOC and STN,with MBC and MBN acting as secondary regulators.The results highlight the role of cold-temperate coniferous forest soils in predicting carbon-climate feedback in high-latitude forest permafrost regions.
基金National Natural Science Foundation of China,No.42301470,No.52270185,No.42171389Capacity Building Program of Local Colleges and Universities in Shanghai,No.21010503300。
文摘Rapid urbanization in China has led to spatial antagonism between urban development and farmland protection and ecological security maintenance.Multi-objective spatial collaborative optimization is a powerful method for achieving sustainable regional development.Previous studies on multi-objective spatial optimization do not involve spatial corrections to simulation results based on the natural endowment of space resources.This study proposes an Ecological Security-Food Security-Urban Sustainable Development(ES-FS-USD)spatial optimization framework.This framework combines the non-dominated sorting genetic algorithm II(NSGA-II)and patch-generating land use simulation(PLUS)model with an ecological protection importance evaluation,comprehensive agricultural productivity evaluation,and urban sustainable development potential assessment and optimizes the territorial space in the Yangtze River Delta(YRD)region in 2035.The proposed sustainable development(SD)scenario can effectively reduce the destruction of landscape patterns of various land-use types while considering both ecological and economic benefits.The simulation results were further revised by evaluating the land-use suitability of the YRD region.According to the revised spatial pattern for the YRD in 2035,the farmland area accounts for 43.59%of the total YRD,which is 5.35%less than that in 2010.Forest,grassland,and water area account for 40.46%of the total YRD—an increase of 1.42%compared with the case in 2010.Construction land accounts for 14.72%of the total YRD—an increase of 2.77%compared with the case in 2010.The ES-FS-USD spatial optimization framework ensures that spatial optimization outcomes are aligned with the natural endowments of land resources,thereby promoting the sustainable use of land resources,improving the ability of spatial management,and providing valuable insights for decision makers.
基金supported by the Major Program of National Natural Science Foundation of China(Grant No.42090055)the National Key ScientificInstruments and Equipment Development Projects of China(Grant No.41827808)the National Nature Science Foundation of China(Grant No.42207216).
文摘Reservoir-induced landslides in China's Three Gorges Reservoir area are prone to tensile cracks due to the influenceof their own weight and fluctuationsin water levels.The presence of cracks indicates that the tensile stress in the area has exceeded the tensile strength of the soil,leading to local instability.To explore the impact of tensile failure behavior on the stability and failure modes of reservoir landslides,the Huangtupo Riverside Slump#1 is taken as a case study.By considering local tensile failure,potential tensile cracks are incorporated into the analysis via the limit equilibrium method and reliability theory.The reliability of landslides under different tensile failure scenarios is quantified.Strain-softening characteristics of the soil are combined to further analyze the failure transmission path of the landslide.Finally,these potential failure modes were validated through physical model tests.The results show that cracks developing at rear positions reduce the stability of the slope and increase the probability of instability.During the destruction process,retrogressive failures with multiple sliding surfaces are likely to occur.However,tensile failure at the forefront reduces the likelihood of an individual slide mass descending.Progressive failure results in both regular and skip transmission patterns.Additionally,cracks and water level changes can also lead to shifts in the positions of the most dangerous blocks.Therefore,in practical landslide analysis and prevention,it is necessary to consider local tensile damage and identify potential tensile crack locations in advance to optimize prevention measures and accurately evaluate landslide risk.
基金supported by the National Key Research and Development Program of China (2022YFF1300705)the Key Research and Development Project of Guangxi,China (Guike AB24010051)+1 种基金the National Natural Science Foundation of China (42261011,32271730 and U20A2011)the Central Public Welfare Research Institutes,Chinese Academy of Geological Sciences (2023020)。
文摘Phosphorus (P) is an essential nutrient element that is critical for plant growth and ecosystem functionality.The soil P cycle plays multiple roles,such as sustaining plant growth and productivity,regulating nutrient balance within ecosystems,and enhancing ecosystem adaptability and resilience.This cycle is influenced by factors such as the restoration approach and microbial community dynamics.However,the extent to which the restoration approach alters the P cycle in karst ecosystems and the underlying microbial mechanisms remain poorly understood.The P-cycle multifunctionality index (P-cycle MFI) serves as a comprehensive indicator for evaluating soil P cycle function,and it provides insights into changes in the P cycle between different restoration approaches.To investigate the shifts in soil P-cycle MFI and microbial mechanisms between different restoration approaches,we analyzed soil available P (AP),total P (TP),microbial biomass P (MBP),and the activities of acid phosphatase (ACP) and alkaline phosphatase (ALP).These data were used to calculate the P-cycle MFI by averaging the Z-scores between two restoration approaches(artificial restoration of forest (AF) and natural restoration of forest (NF)) and a control (cropland,CP) at six subtropical karst ecosystem sites in China.We also determined the soil organic carbon (SOC),exchangeable calcium (Ca) and magnesium (Mg),pH,bulk density (BD),microbial biomass C (MBC),and microbial biomass nitrogen (MBN),as well as the community structure,relative abundance,diversity indices,and co-occurrence networks of phoD-harboring bacteria.The results showed that the community structure of phoD-harboring bacteria varied significantly among AF,NF,and CP and across different temperature gradients.These bacteria exhibited increasing complexity and tightness in co-occurrence networks from CP to AF and then to NF,along with the ACP and ALP activities,but not the TP and AP contents.The P-cycle MFI values were significantly higher in NF compared to AF and CP,and the variation was significantly explained by restoration approach,temperature,MBC,MBN,SOC,exchangeable Ca,BD,community structure of phoD-harboring bacteria,and exchangeable Mg.Furthermore,natural restoration had a more substantial impact on the P-cycle MFI than temperature by enhancing SOC,microbial biomass,the complexity and co-occurrence network tightness of the phoD-harboring bacterial community structure,and ACP and ALP activities,but it reduced soil BD.The rare genera of phoD-harboring bacteria significantly influenced the variation of soil P-cycle MFI compared to the dominant genera.This study highlights the importance of rare genera of phoD-harboring bacteria in driving soil P-cycle multifunctionality in karst ecosystems,with natural restoration being more effective than artificial methods for enhancing soil organic matter and microbial community complexity.
基金supported by the National Key R&D Plan“Inter-governmental International Science&Technology Innovation Cooperation”Key Specialized Program,China(2025YFE0102800)the Program of the State Key Laboratory of Cryospheric Science and Frozen Soil Engineering,Chinese Academy of Sciences(CSFSE-ZZ-2403).
文摘Tajikistan contains the majority of Central Asia’s glaciers,which cover about 6.00%of the national territory;their rapid shrinkage poses a significant threat to regional water resource security.However,glacier monitoring in Tajikistan was interrupted after 1991,creating a substantial gap in understanding the current state and temporal evolution of these glaciers.Based on glacier inventory data,in situ measurements,and published literature,this study examined the present status and recent variations of glaciers in Tajikistan through data integration and validation,literature collation and comparative analysis,and the application of Geographic Information System(GIS)spatial analysis techniques.As of 2023,Tajikistan possesses a total of 11,528 glaciers,encompassing an area of 7624.48(±305.58)km2.Small glaciers dominate in number,whereas large glaciers account for the majority of the total area.Over the past two decades,the glacier count has decreased by 2014,and the total area has decreased by 628.98 km2,corresponding to an average annual reduction rate of 0.33%.Regional shrinkage rates range from 4.10%to 22.28%.Glaciers have undergone accelerated mass loss during the past 20 a;only those on the northeastern Pamir Plateau exhibit a weak positive mass balance.Observations of typical monitored glaciers also reveal intensified melting and retreat,consistent with regional trends.In light of the recent acceleration of glacier shrinkage in Tajikistan,focused measures should be implemented to strengthen glacier monitoring,enhance public awareness of glacier preservation,and promote the sustainable development and utilization of glacier tourism.These findings bridge the knowledge gap regarding the spatiotemporal dynamics of Tajikistan’s glaciers over recent decades and provide essential data support for regional water resource management.
基金supported by the National Natural Science Foundation of China(U2344201 and 42101316)the Natural Science Foundation of Hunan Province,China(2022JJ40866)the Outstanding Youth Project of Education Bureau of Hunan Province,China(20B613)。
文摘Understanding the spatial distributions and corresponding variation mechanisms of key soil nutrients in fragile karst ecosystems can assist in promoting sustainable development.However,due to the implementation of ecological restoration initiatives such as land-use conversions,novel changes in the spatial characteristics of soil nutrients remain unknown.To address this gap,we explored nutrient variations and the drivers of the variation in the 0–15 cm topsoil layer using a regional-scale sampling method in a typical karst area in northwest Guangxi Zhuang Autonomous Region,Southwest China.Descriptive statistics,geostatistics,and spatial analysis were used to assess the soil nutrient variability.The results indicated that soil organic carbon(SOC),total nitrogen(TN),total phosphorus(TP),and total potassium(TK)concentrations showed moderate variations,with coefficients of variance being 0.60,0.60,0.71,and 0.72,respectively.Moreover,they demonstrated positive spatial autocorrelations,with global Moran's indices being 0.68,0.77,0.64,and 0.68,respectively.However,local Moran's index values were low,indicating large spatial variations in soil nutrients.The best-fitting semi-variogram models for SOC,TN,TP,and TK concentrations were spherical,Gaussian,exponential,and exponential,respectively.According to the classification criteria of the Second National Soil Census in China,SOC and TN concentrations were relatively sufficient,with the proportions of rich and very rich levels being up to 90.9 and 96.0%,respectively.TP concentration was in the mediumdeficient level,with the areas of medium and deficient levels accounting for 33.7 and 30.1%of the total,respectively.TK concentration was deficient,with the cumulative area of extremely deficient,very deficient,and deficient levels accounting for 87.6%of the total area.Consequently,the terrestrial ecosystems in the study area were more vulnerable to soil P and K than soil N deficiencies.Furthermore,variance partitioning analysis of the influencing factors showed that,except for the interactions,the single effect of other soil properties accounted more for soil nutrient variations than spatial and environmental variables.These results will aid in the future management of terrestrial ecosystems.
基金supported by the National Key Research and Development Program of China(No.2022YFC3702800)the National Natural Science Foundation of China(Nos.22366008,22406032)the Guizhou Provincial Basic Research Program(Natural Science)(No.ZK(2023)045).
文摘Freshwater scarcity is exacerbated by uneven distribution of limited freshwater resources and high energy costs of desalination technologies.Atmospheric water vapor,a vast and geographically unrestricted reservoir,could become a sustainable alternative.Sorption-based atmospheric water harvesting(SAWH)has emerged as an available solution,yet conventional desorption methods relying on energy-intensive electrical heating hinder its scalability.Herein,a photothermal hygroscopic sponge has been developed for solar-driven atmospheric water harvesting.The composites combine a malleable melamine sponge skeleton,lithium chloride as a hygroscopic agent,and hydrangea-like molybdenum disulfide as a photothermal component,forming a multiscale“pore-film”cross-linked structure by an eco-friendly immersion-freeze-drying method.The optimized sample achieves exceptional hygroscopic capacity(3.92 g/g at 90%RH)and freshwater production efficiency(87.77%),which is attributed to synergistic effects of porous skeleton based crosslinked structures and“pore-film”structures,and outstanding photothermal conversion efficiency of MoS2.The unique structure could stabilize LiCl to prevent leakage,increase mass transfer effectiveness of whole SWAH process,and enable flexibility for diverse applications.We carried out outdoor experiments to demonstrate a solar-driven water production rate of 4.22 L m-2 d-1 without external energy input.This work provides insights into sustainable freshwater generation and promotes green energy utilization in addressing global water scarcity.
