T he ecological footprint of China's provinces is calculated in this pap er. In general, China's development is not sustainable because its ecological footprint is beyond its bio-capacity. The sustainability s...T he ecological footprint of China's provinces is calculated in this pap er. In general, China's development is not sustainable because its ecological footprint is beyond its bio-capacity. The sustainability status of each pr ovince in China is presented. Ulanowicz's development capacity formula w as introduced to discuss the relationship of development and ecological footprin t's diversity. The diversity of ecological impacts is related to the e fficiency with which an economy uses the source and sink services of the environment and, in this view, should be a factor in economic output. Developme nt capacity, calculated from the ecological footprint and its diversity , is used to examine the relationship of economic output with the st ructure of the ecological footprint. China and its provinces are prese nted as a case study to investigate this relationship. The analysis s hows that footprint capacity is significant in predicting economic outp ut. Increasing the ecological footprint's diversity is presented as another way to increase development capacity.展开更多
The study employs slope, aspect, relief degree of land surface, land use, vegetation index, hydrology and climate, as evaluation indexes to set up the Human Settlements Environmental Index （HEI） model to evaluate th...The study employs slope, aspect, relief degree of land surface, land use, vegetation index, hydrology and climate, as evaluation indexes to set up the Human Settlements Environmental Index （HEI） model to evaluate the environmental suitability for human settlements in the Shiyang River Basin. By using GIS spatial analysis technology, such as spatial overlay analysis, buffer analysis and density analysis, the environmental suitability of the human set- tlement spatial situation and spatial pattern are established to analyze their spatial distribution The results show that the index of suitability for human settlements in the Shiyang River Basin is between 17.13 and 84.32. In general, suitability for human settlements decreases from the southwest to the northeast. Seen from an area pattern, the suitable region is mainly distributed in the Minqin oasis, Wuwei oasis and Changning basin, which are about 1080.01 km2 and account for 2.59% of the total area. Rather and comparatively suitable region is mainly distributed around the counties of Gulang, Yongchang and north of Tianzhu, which is about 1100.30 km2. The common suitable region is mainly distributed outside the counties of Yongchang, Jinchuan and most parts of Minqin County, which are about 23328.04 km2, accounting for 56.08% of the total area. The unsuitable region is mainly distributed upstream and to the north of the river, which is about 9937.60 km2, accounting for 23.89% of the total area. Meanwhile, the least suitable region is distributed around the Qilian Mountains, which are covered by snow and cold desert and lie in the intersecting area between the Tengger Desert and Badain Jaran Desert. The total area is about 6154.05 km2, accounting for 14.79% of the total area. Suitable regions for human habitation are mainly distributed around rivers in the form of ribbons and batches, while others are scattered. The distribution pattern is iden- tical to the residential spatial pattern. In addition, the relationships between HEI and other factors have been analyzed. There is a clear logarithmic correlation between the residential environment and population, that is, the correlation coefficient between the evaluation valueand population density reaches 0.851. There is also a positive correlation between the residential environment and economy, which reaches an evaluation value of 0.845 between the residential environment and GDP. Results also show that the environment is out of bearing with the existing population in Shiyang River Basin. Spatial distribution of population is pro- foundly affected by severe environmental problems, such as the expanded deserts, the hilly terrain and the changing climate. Surface water shortage and slow economic growth are bot- tlenecks for suitable human settlement in the Shiyang River Basin. Combining these prob- lems with planning for construction of new country and the exploitation of local land, some residential areas should be relocated to improve the residential environment.展开更多
Oxidation of cyclohexene under 1 atmospheric pressure of molecular oxygen at 70C in the absence of solvent catalyzed by PAMAM-SA-M (Where PAMAM = polyamidoamine; SA = salicyaldehyde; M = metal ions Fe3+, Co2+, Ni2+, M...Oxidation of cyclohexene under 1 atmospheric pressure of molecular oxygen at 70C in the absence of solvent catalyzed by PAMAM-SA-M (Where PAMAM = polyamidoamine; SA = salicyaldehyde; M = metal ions Fe3+, Co2+, Ni2+, Mn2+, Cu2+, Zn2+, respectively) dendrimers, afforded 2-cyclohexen-1-ol 1, 2-cyclohexen-1-one 2, 7-oxabicyclo [4,1,0] heptane 3 and 7-oxabicyl [4,1,0] heptan-2-one 4 as the major products. The factors that affect this reaction are also discussed.展开更多
By employing the reductive perturbation technique we derived a Kadomtsev-Petviashvili equation forunmagnetized dusty plasmas. It suggests that the nonlinear dust acoustic solitary waves with adiabatic variation of dus...By employing the reductive perturbation technique we derived a Kadomtsev-Petviashvili equation forunmagnetized dusty plasmas. It suggests that the nonlinear dust acoustic solitary waves with adiabatic variation of dustcharge are stable even there are some higher order transverse perturbatoins. There are only rarefactive solitary wavesfor this system which has been verified analytically in this paper.展开更多
A new analytical method is proposed for the determination of heroin based on a sequential perturbation caused by trace amounts of heroin in the Cu(Ⅱ)-catalyzed oscillating reaction between hydrogen peroxide and sodiu...A new analytical method is proposed for the determination of heroin based on a sequential perturbation caused by trace amounts of heroin in the Cu(Ⅱ)-catalyzed oscillating reaction between hydrogen peroxide and sodium thiocyanate in an alkaline medium with the aid of a continuous-flow stirred tank reactor(CSTR). The method relies on the linear relationship between the change in oscillation period of the system and the concentration of heroin, with a detecting limit of 4.0×10^(-7) mol/L. The calibration curve fits a linear equation very well when the concentration of heroin is in the range of 2.0×10^(-6)_1.2×10^(-5) mol/L(r=0.9971). This method features good precision(RSD=0.98%). The influences of temperature, injection point, flow rate and reaction variables on the oscillation period were investigated in detail and a possible mechanism of the performance of heroin in the Cu(Ⅱ)-catalyzed oscillating reaction system is also discussed. The proposed method opens a new avenue for the determination of heroin.展开更多
TiO_2 nanoparticles with different phases are prepared by hydrolysis oftitanium tetrabutoxide in the presence of HC1. The composition and microstructure of the resultingsamples are studied by XRD and TEM. These result...TiO_2 nanoparticles with different phases are prepared by hydrolysis oftitanium tetrabutoxide in the presence of HC1. The composition and microstructure of the resultingsamples are studied by XRD and TEM. These results show that the range of particle size of TiO_2 isfrom 20 to 30 nm. The mechanism of TiO_2 photocatalysis reaction has been discussed extensively.Photocatalytic activities of nanometer TiO_2 are also evaluated by degradation of the crystal violetsolution. Experimental results indicate that the synergistic action of H_2O_2 and ultrasonic wavegreatly enhances photo-catalytic reaction of TiO_2.展开更多
A new steroid named as Zhonghualiaoine I (1) was isolated from Polygonum nodosum Pers (Chinese name 揨honghualiao? Berberidaceae). Its structure was deduced on the basis of its spectral data.
Dy0.8Sr0.2FeO3 nano powder, a synthetic oxide, is made by sol-gel method from metal nitrate and diethylenetriaminepentaacetic acid (DTPA), and the processing parameters are optimized. The process of the preparation, t...Dy0.8Sr0.2FeO3 nano powder, a synthetic oxide, is made by sol-gel method from metal nitrate and diethylenetriaminepentaacetic acid (DTPA), and the processing parameters are optimized. The process of the preparation, thermal decomposition and the property of the powder are studied by TG-DTA, IR, TEM, and XRD. The diameter of the average grain is about 70 nm. This new technique can be used in the preparation and the studying of na'no materials in the complex oxide system.展开更多
This mini-review covers the literatures of the determination of gallium, indium, and thallium by instrumental analysis with computer-assisted searching over the period of 1994 to 2003. Some papers appearing in the ear...This mini-review covers the literatures of the determination of gallium, indium, and thallium by instrumental analysis with computer-assisted searching over the period of 1994 to 2003. Some papers appearing in the early of 2004 are also included. Because the rapid progress in the instrument has been made, these new papers are prioritized in selection in the similar papers. The contents are considered to be separation and preconcentration, spectrophotometry, spectrofluorimetry, electroanalyses, atomic absorption spectrometry, inductively coupled plasma-atomic emission spectrometry, inductively coupled plasma-mass spectrometry and so forth.展开更多
Luminescence study from the silicon oxide filmsembedded nm carbon particles (CSO) and nm silicon particles (SSO) is of great importance in integrated optoelectronics. The pioneering work on electroluminescence (EL) fr...Luminescence study from the silicon oxide filmsembedded nm carbon particles (CSO) and nm silicon particles (SSO) is of great importance in integrated optoelectronics. The pioneering work on electroluminescence (EL) from the SSO was reported bu Dimaria et al.展开更多
An rapid and efficient synthesis of 2, 4, 6-triarylpyridines is reported using substituted benzaldehydes, substituted acetophenones and ammonia as starting materials under microwave irradiation in the presence of PEG-...An rapid and efficient synthesis of 2, 4, 6-triarylpyridines is reported using substituted benzaldehydes, substituted acetophenones and ammonia as starting materials under microwave irradiation in the presence of PEG-400.展开更多
diketone type chelating ligands have high coordinative activity and selectivity, and are widely applied in analytical chemistry. In order to obtain profounder understanding to the properties of bis(4 acylpyrazolone ...diketone type chelating ligands have high coordinative activity and selectivity, and are widely applied in analytical chemistry. In order to obtain profounder understanding to the properties of bis(4 acylpyrazolone 5), A new 4 acylpyrazol 5 one derivative (H 2BPMPP) was syntheszed, which contains a heterocyclic ring between two 1 phenyl 3 methyl 4 acylpyrazol 5 one rings. The new compound was characterized by element analyses, UV, IR and 1H NMR spectra. The equilibrium of the keto enol tautomerism was studied. The results show that a lower dielectric constant of solvent favors the enol form which has a higher λ max . Due to special merits of paraffin wax, the solid liquid extraction behavior of Ce(Ⅲ) with molten paraffin wax as a diluent was also investigated at higher temperature. The value of the pH 1/2 was 3.19 and the value of log K ex was 3.467. The chemical composition of the complex was obtained by the slope analysis method.展开更多
Five ruthenium complexes such as Phen-Ru-Phen, Phen-Ru-Bipy, Phen-Ru-Quin, Quin-Ru-Quin and Bipy-Ru-Quin (where Phen=1, 10-phenanthroline, Quin=8-hydroxyquinoline, Bipy=2, 2′-bipyridine) were synthesized and used as ...Five ruthenium complexes such as Phen-Ru-Phen, Phen-Ru-Bipy, Phen-Ru-Quin, Quin-Ru-Quin and Bipy-Ru-Quin (where Phen=1, 10-phenanthroline, Quin=8-hydroxyquinoline, Bipy=2, 2′-bipyridine) were synthesized and used as catalysts for the oxidation of benzylic and primary aliphatic alcohols with iodosylbenzene as oxidant. The oxidations were carried out at room temperature, affording the corresponding aldehydes and ketones with high selectivity.展开更多
A novel, simple, rapid, sensitive and highly selective flow injection procedure for the spectrophotometric determination of chlorine dioxide in the presence of other chlorine species, viz,free chlorine, chlorite, chlo...A novel, simple, rapid, sensitive and highly selective flow injection procedure for the spectrophotometric determination of chlorine dioxide in the presence of other chlorine species, viz,free chlorine, chlorite, chlorate and hypochlorite, is developed. The method is based on the discoloration reaction between chlorine dioxide and chlorophenol red and can overcome the shortcomings existed in direct spectrophotometric determination for chlorine dioxide owing to the serious interference of free and combined chlorine. The procedure gave a linear calibration graph over the range 0—0.71 mg/L of chlorine dioxide. With a detection limit of 0.024 mg/L and a sample throughput of 60 samples/h.展开更多
An efficient poly(ethylene glycol) (PEG)-supported liquid-phase parallel approach to di(aryloxyacetyl)thiosemicarbazides is described. PEG-bound phenol reacted with chloroacetic acid to afford PEG-bound phenyloxyaceti...An efficient poly(ethylene glycol) (PEG)-supported liquid-phase parallel approach to di(aryloxyacetyl)thiosemicarbazides is described. PEG-bound phenol reacted with chloroacetic acid to afford PEG-bound phenyloxyacetic acid, which was readily converted into corresponding phenyloxyacetyl chloride. Subsequent nucleophilic substitution with ammonium thiocyanate followed by addition of aryloxyacetic acid hydrazides gave PEG-bound di(aryloxyacetyl)thiosemi-carbazides, which were easily cleaved to give the resulting library of 1-aryloxyacetyl-4-(4'-methoxylcarbonylphenyloxyacetyl)thiosemicarbazides in good to high yield and high purity.展开更多
基金National Natural Science Foundation of China, No.40235053 No.40201019
文摘T he ecological footprint of China's provinces is calculated in this pap er. In general, China's development is not sustainable because its ecological footprint is beyond its bio-capacity. The sustainability status of each pr ovince in China is presented. Ulanowicz's development capacity formula w as introduced to discuss the relationship of development and ecological footprin t's diversity. The diversity of ecological impacts is related to the e fficiency with which an economy uses the source and sink services of the environment and, in this view, should be a factor in economic output. Developme nt capacity, calculated from the ecological footprint and its diversity , is used to examine the relationship of economic output with the st ructure of the ecological footprint. China and its provinces are prese nted as a case study to investigate this relationship. The analysis s hows that footprint capacity is significant in predicting economic outp ut. Increasing the ecological footprint's diversity is presented as another way to increase development capacity.
基金National Natural Science Foundation of China, No.41261104 No.40971078+1 种基金 National Social Science Foundation Youth Project of China, No.12CTJ001 Youth Fund Projects of Science and Technology from Gansu Province, No.1107RJYA077
文摘The study employs slope, aspect, relief degree of land surface, land use, vegetation index, hydrology and climate, as evaluation indexes to set up the Human Settlements Environmental Index （HEI） model to evaluate the environmental suitability for human settlements in the Shiyang River Basin. By using GIS spatial analysis technology, such as spatial overlay analysis, buffer analysis and density analysis, the environmental suitability of the human set- tlement spatial situation and spatial pattern are established to analyze their spatial distribution The results show that the index of suitability for human settlements in the Shiyang River Basin is between 17.13 and 84.32. In general, suitability for human settlements decreases from the southwest to the northeast. Seen from an area pattern, the suitable region is mainly distributed in the Minqin oasis, Wuwei oasis and Changning basin, which are about 1080.01 km2 and account for 2.59% of the total area. Rather and comparatively suitable region is mainly distributed around the counties of Gulang, Yongchang and north of Tianzhu, which is about 1100.30 km2. The common suitable region is mainly distributed outside the counties of Yongchang, Jinchuan and most parts of Minqin County, which are about 23328.04 km2, accounting for 56.08% of the total area. The unsuitable region is mainly distributed upstream and to the north of the river, which is about 9937.60 km2, accounting for 23.89% of the total area. Meanwhile, the least suitable region is distributed around the Qilian Mountains, which are covered by snow and cold desert and lie in the intersecting area between the Tengger Desert and Badain Jaran Desert. The total area is about 6154.05 km2, accounting for 14.79% of the total area. Suitable regions for human habitation are mainly distributed around rivers in the form of ribbons and batches, while others are scattered. The distribution pattern is iden- tical to the residential spatial pattern. In addition, the relationships between HEI and other factors have been analyzed. There is a clear logarithmic correlation between the residential environment and population, that is, the correlation coefficient between the evaluation valueand population density reaches 0.851. There is also a positive correlation between the residential environment and economy, which reaches an evaluation value of 0.845 between the residential environment and GDP. Results also show that the environment is out of bearing with the existing population in Shiyang River Basin. Spatial distribution of population is pro- foundly affected by severe environmental problems, such as the expanded deserts, the hilly terrain and the changing climate. Surface water shortage and slow economic growth are bot- tlenecks for suitable human settlement in the Shiyang River Basin. Combining these prob- lems with planning for construction of new country and the exploitation of local land, some residential areas should be relocated to improve the residential environment.
文摘Oxidation of cyclohexene under 1 atmospheric pressure of molecular oxygen at 70C in the absence of solvent catalyzed by PAMAM-SA-M (Where PAMAM = polyamidoamine; SA = salicyaldehyde; M = metal ions Fe3+, Co2+, Ni2+, Mn2+, Cu2+, Zn2+, respectively) dendrimers, afforded 2-cyclohexen-1-ol 1, 2-cyclohexen-1-one 2, 7-oxabicyclo [4,1,0] heptane 3 and 7-oxabicyl [4,1,0] heptan-2-one 4 as the major products. The factors that affect this reaction are also discussed.
文摘By employing the reductive perturbation technique we derived a Kadomtsev-Petviashvili equation forunmagnetized dusty plasmas. It suggests that the nonlinear dust acoustic solitary waves with adiabatic variation of dustcharge are stable even there are some higher order transverse perturbatoins. There are only rarefactive solitary wavesfor this system which has been verified analytically in this paper.
基金Supported by the Project of International Cooperation between China and U kraine(No.0 4 3- 0 5 ) and the Project ofKJCXGC- 0 1Northwest Norm al U niversityChina
文摘A new analytical method is proposed for the determination of heroin based on a sequential perturbation caused by trace amounts of heroin in the Cu(Ⅱ)-catalyzed oscillating reaction between hydrogen peroxide and sodium thiocyanate in an alkaline medium with the aid of a continuous-flow stirred tank reactor(CSTR). The method relies on the linear relationship between the change in oscillation period of the system and the concentration of heroin, with a detecting limit of 4.0×10^(-7) mol/L. The calibration curve fits a linear equation very well when the concentration of heroin is in the range of 2.0×10^(-6)_1.2×10^(-5) mol/L(r=0.9971). This method features good precision(RSD=0.98%). The influences of temperature, injection point, flow rate and reaction variables on the oscillation period were investigated in detail and a possible mechanism of the performance of heroin in the Cu(Ⅱ)-catalyzed oscillating reaction system is also discussed. The proposed method opens a new avenue for the determination of heroin.
文摘TiO_2 nanoparticles with different phases are prepared by hydrolysis oftitanium tetrabutoxide in the presence of HC1. The composition and microstructure of the resultingsamples are studied by XRD and TEM. These results show that the range of particle size of TiO_2 isfrom 20 to 30 nm. The mechanism of TiO_2 photocatalysis reaction has been discussed extensively.Photocatalytic activities of nanometer TiO_2 are also evaluated by degradation of the crystal violetsolution. Experimental results indicate that the synergistic action of H_2O_2 and ultrasonic wavegreatly enhances photo-catalytic reaction of TiO_2.
基金supported by the Northwest Normal University-Bring Forth new Idea Project of Science and Technology P. R. China
文摘A new steroid named as Zhonghualiaoine I (1) was isolated from Polygonum nodosum Pers (Chinese name 揨honghualiao? Berberidaceae). Its structure was deduced on the basis of its spectral data.
文摘Dy0.8Sr0.2FeO3 nano powder, a synthetic oxide, is made by sol-gel method from metal nitrate and diethylenetriaminepentaacetic acid (DTPA), and the processing parameters are optimized. The process of the preparation, thermal decomposition and the property of the powder are studied by TG-DTA, IR, TEM, and XRD. The diameter of the average grain is about 70 nm. This new technique can be used in the preparation and the studying of na'no materials in the complex oxide system.
文摘This mini-review covers the literatures of the determination of gallium, indium, and thallium by instrumental analysis with computer-assisted searching over the period of 1994 to 2003. Some papers appearing in the early of 2004 are also included. Because the rapid progress in the instrument has been made, these new papers are prioritized in selection in the similar papers. The contents are considered to be separation and preconcentration, spectrophotometry, spectrofluorimetry, electroanalyses, atomic absorption spectrometry, inductively coupled plasma-atomic emission spectrometry, inductively coupled plasma-mass spectrometry and so forth.
基金Supported by the National Natural Science Foundation of China(60276015)the Key Project of Ministry of Education of China(2041391 and the Foundation of Northwest Normal University(NWNU-KJCXGC-214).
文摘Luminescence study from the silicon oxide filmsembedded nm carbon particles (CSO) and nm silicon particles (SSO) is of great importance in integrated optoelectronics. The pioneering work on electroluminescence (EL) from the SSO was reported bu Dimaria et al.
基金We thank the National Natural Science Foundation of China(NO.20272047)the Northwest Normal University Science and Technology Development Foundation of China for financial support.
文摘An rapid and efficient synthesis of 2, 4, 6-triarylpyridines is reported using substituted benzaldehydes, substituted acetophenones and ammonia as starting materials under microwave irradiation in the presence of PEG-400.
文摘diketone type chelating ligands have high coordinative activity and selectivity, and are widely applied in analytical chemistry. In order to obtain profounder understanding to the properties of bis(4 acylpyrazolone 5), A new 4 acylpyrazol 5 one derivative (H 2BPMPP) was syntheszed, which contains a heterocyclic ring between two 1 phenyl 3 methyl 4 acylpyrazol 5 one rings. The new compound was characterized by element analyses, UV, IR and 1H NMR spectra. The equilibrium of the keto enol tautomerism was studied. The results show that a lower dielectric constant of solvent favors the enol form which has a higher λ max . Due to special merits of paraffin wax, the solid liquid extraction behavior of Ce(Ⅲ) with molten paraffin wax as a diluent was also investigated at higher temperature. The value of the pH 1/2 was 3.19 and the value of log K ex was 3.467. The chemical composition of the complex was obtained by the slope analysis method.
基金financially supported by the National Natural Science Foundation of China(No.20174031).
文摘Five ruthenium complexes such as Phen-Ru-Phen, Phen-Ru-Bipy, Phen-Ru-Quin, Quin-Ru-Quin and Bipy-Ru-Quin (where Phen=1, 10-phenanthroline, Quin=8-hydroxyquinoline, Bipy=2, 2′-bipyridine) were synthesized and used as catalysts for the oxidation of benzylic and primary aliphatic alcohols with iodosylbenzene as oxidant. The oxidations were carried out at room temperature, affording the corresponding aldehydes and ketones with high selectivity.
文摘A novel, simple, rapid, sensitive and highly selective flow injection procedure for the spectrophotometric determination of chlorine dioxide in the presence of other chlorine species, viz,free chlorine, chlorite, chlorate and hypochlorite, is developed. The method is based on the discoloration reaction between chlorine dioxide and chlorophenol red and can overcome the shortcomings existed in direct spectrophotometric determination for chlorine dioxide owing to the serious interference of free and combined chlorine. The procedure gave a linear calibration graph over the range 0—0.71 mg/L of chlorine dioxide. With a detection limit of 0.024 mg/L and a sample throughput of 60 samples/h.
文摘An efficient poly(ethylene glycol) (PEG)-supported liquid-phase parallel approach to di(aryloxyacetyl)thiosemicarbazides is described. PEG-bound phenol reacted with chloroacetic acid to afford PEG-bound phenyloxyacetic acid, which was readily converted into corresponding phenyloxyacetyl chloride. Subsequent nucleophilic substitution with ammonium thiocyanate followed by addition of aryloxyacetic acid hydrazides gave PEG-bound di(aryloxyacetyl)thiosemi-carbazides, which were easily cleaved to give the resulting library of 1-aryloxyacetyl-4-(4'-methoxylcarbonylphenyloxyacetyl)thiosemicarbazides in good to high yield and high purity.
