The utilization of perovskite oxide materials as catalysts for the photodegradation of organic pollutants in water is a promising and rapidly advancing field.In this study,a series of La_(1−x)Ba_(x)CoO_(3)(x=0.2,0.3,0...The utilization of perovskite oxide materials as catalysts for the photodegradation of organic pollutants in water is a promising and rapidly advancing field.In this study,a series of La_(1−x)Ba_(x)CoO_(3)(x=0.2,0.3,0.4,0.5,0.6)catalysts with varying Ba doping ratios were synthesized using the citric acid complexation-hydrothermal synthesis combined method for the degradation of phenol under visible light irradiation.Among the synthesized catalysts,La_(0.5)Ba_(0.5)CoO_(3) exhibited the highest photocatalytic activity.In addition,the photocatalytic mechanism for La_(0.5)Ba_(0.5)CoO_(3) perovskite degradation of phenol was also discussed.The synthesized catalysts were characterized using XRD,SEM,FT-IR,XPS,MPMS and other characterization techniques.The results revealed that the diffraction peak intensity of La_(1−x)Ba_(x)CoO_(3) increased with higher Ba doping ratios,and the La_(0.4)Ba_(0.6)CoO_(3) exhibited the strongest diffraction peaks.The catalyst particle sizes ranged from 10 to 50 nm,and the specific surface area decreased with increasing Ba content.Additionally,the paramagnetic properties of La_(0.5)Ba_(0.5)CoO_(3) were similar to that of La_(0.4)Ba_(0.6)CoO_(3).The experimental results suggested that the incorporation of Ba could significantly improve the catalytic performance of La_(1−x)Ba_(x)CoO_(3) perovskites,promote electron transfer and favor to the generation of hydroxyl radicals(•OH),leading to the efficiently degradation of phenol.展开更多
The Bi-LS method based on QR decomposition provides a convenient framework for de-veloping efficient subspace tracking algorithms.To overcome the shortcoming of the backsubstitution step and improve the parallel archi...The Bi-LS method based on QR decomposition provides a convenient framework for de-veloping efficient subspace tracking algorithms.To overcome the shortcoming of the backsubstitution step and improve the parallel architecture of the Bi-LS algorithms,a Bi-LS subspace tracking algorithm based on Inverse QR(IQR) decomposition is developed.The proposed IQR iterative algorithm for subspace tracking is well suited for the parallel implementation in the systolic array.Simulation results are presented to illustrate the effectiveness of the proposed IQR subspace tracking algorithm.展开更多
This paper introduces the concept and motivates the use of finite-interval based measures for physically realizable and measurable quantities, which we call -measures. We demonstrate the utility and power of -measures...This paper introduces the concept and motivates the use of finite-interval based measures for physically realizable and measurable quantities, which we call -measures. We demonstrate the utility and power of -measures by illustrating their use in an interval-based analysis of a prototypical Bell’s inequality in the measurement of the polarization states of an entangled pair of photons. We show that the use of finite intervals in place of real-numbered values in the Bell inequality leads to reduced violations. We demonstrate that, under some conditions, an interval-based but otherwise classically calculated probability measure can be made to arbitrarily closely approximate its quantal counterpart. More generally, we claim by heuristic arguments and by formal analogy with finite-state machines that -measures can provide a more accurate model of both classical and quantal physical property values than point-like, real numbers—as originally proposed by Tuero Sunaga in 1958.展开更多
基金The Fundamental Research Program for Young Scientists of Shanxi Province(Project No.202103021223294)The Fundamental Research Program of Shanxi Province(Project No.202203021211203)+1 种基金The Start-up Fund for Doctorate Scientific Research Project of Taiyuan University of Science and Technology(Project No.20232124)The Innovation and Entrepreneurship Training Program for Undergraduate,Taiyuan University of Science and Technology(Project No.DCX2024162).
文摘The utilization of perovskite oxide materials as catalysts for the photodegradation of organic pollutants in water is a promising and rapidly advancing field.In this study,a series of La_(1−x)Ba_(x)CoO_(3)(x=0.2,0.3,0.4,0.5,0.6)catalysts with varying Ba doping ratios were synthesized using the citric acid complexation-hydrothermal synthesis combined method for the degradation of phenol under visible light irradiation.Among the synthesized catalysts,La_(0.5)Ba_(0.5)CoO_(3) exhibited the highest photocatalytic activity.In addition,the photocatalytic mechanism for La_(0.5)Ba_(0.5)CoO_(3) perovskite degradation of phenol was also discussed.The synthesized catalysts were characterized using XRD,SEM,FT-IR,XPS,MPMS and other characterization techniques.The results revealed that the diffraction peak intensity of La_(1−x)Ba_(x)CoO_(3) increased with higher Ba doping ratios,and the La_(0.4)Ba_(0.6)CoO_(3) exhibited the strongest diffraction peaks.The catalyst particle sizes ranged from 10 to 50 nm,and the specific surface area decreased with increasing Ba content.Additionally,the paramagnetic properties of La_(0.5)Ba_(0.5)CoO_(3) were similar to that of La_(0.4)Ba_(0.6)CoO_(3).The experimental results suggested that the incorporation of Ba could significantly improve the catalytic performance of La_(1−x)Ba_(x)CoO_(3) perovskites,promote electron transfer and favor to the generation of hydroxyl radicals(•OH),leading to the efficiently degradation of phenol.
基金Supported in part by the 973 Program (No.2008CB-317109)the National Natural Science Foundation of China (No.60572054)the SRF for ROCS, SEM
文摘The Bi-LS method based on QR decomposition provides a convenient framework for de-veloping efficient subspace tracking algorithms.To overcome the shortcoming of the backsubstitution step and improve the parallel architecture of the Bi-LS algorithms,a Bi-LS subspace tracking algorithm based on Inverse QR(IQR) decomposition is developed.The proposed IQR iterative algorithm for subspace tracking is well suited for the parallel implementation in the systolic array.Simulation results are presented to illustrate the effectiveness of the proposed IQR subspace tracking algorithm.
文摘This paper introduces the concept and motivates the use of finite-interval based measures for physically realizable and measurable quantities, which we call -measures. We demonstrate the utility and power of -measures by illustrating their use in an interval-based analysis of a prototypical Bell’s inequality in the measurement of the polarization states of an entangled pair of photons. We show that the use of finite intervals in place of real-numbered values in the Bell inequality leads to reduced violations. We demonstrate that, under some conditions, an interval-based but otherwise classically calculated probability measure can be made to arbitrarily closely approximate its quantal counterpart. More generally, we claim by heuristic arguments and by formal analogy with finite-state machines that -measures can provide a more accurate model of both classical and quantal physical property values than point-like, real numbers—as originally proposed by Tuero Sunaga in 1958.
