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Applications of molecular dynamics simulation in studying shale oil reservoirs at the nanoscale:Advances,challenges and perspectives 被引量:1
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作者 Lu Wang Yi-Fan Zhang +6 位作者 Run Zou Yi-Fan Yuan Rui Zou Liang Huang Yi-Sheng Liu Jing-Chen Ding Zhan Meng 《Petroleum Science》 2025年第1期234-254,共21页
The global energy demand is increasing rapidly,and it is imperative to develop shale hydrocarbon re-sources vigorously.The prerequisite for enhancing the exploitation efficiency of shale reservoirs is the systematic e... The global energy demand is increasing rapidly,and it is imperative to develop shale hydrocarbon re-sources vigorously.The prerequisite for enhancing the exploitation efficiency of shale reservoirs is the systematic elucidation of the occurrence characteristics,flow behavior,and enhanced oil recovery(EOR)mechanisms of shale oil within commonly developed nanopores.Molecular dynamics(MD)technique can simulate the occurrence,flow,and extraction processes of shale oil at the nanoscale,and then quantitatively characterize various fluid properties,flow characteristics,and action mechanisms under different reservoir conditions by calculating and analyzing a series of MD parameters.However,the existing review on the application of MD simulation in shale oil reservoirs is not systematic enough and lacks a summary of technical challenges and solutions.Therefore,recent MD studies on shale oil res-ervoirs were summarized and analyzed.Firstly,the applicability of force fields and ensembles of MD in shale reservoirs with different reservoir conditions and fluid properties was discussed.Subsequently,the calculation methods and application examples of MD parameters characterizing various properties of fluids at the microscale were summarized.Then,the application of MD simulation in the study of shale oil occurrence characteristics,flow behavior,and EOR mechanisms was reviewed,along with the elucidation of corresponding micro-mechanisms.Moreover,influencing factors of pore structure,wall properties,reservoir conditions,fluid components,injection/production parameters,formation water,and inorganic salt ions were analyzed,and some new conclusions were obtained.Finally,the main challenges associated with the application of MD simulations to shale oil reservoirs were discussed,and reasonable prospects for future MD research directions were proposed.The purpose of this review is to provide theoretical basis and methodological support for applying MD simulation to study shale oil reservoirs. 展开更多
关键词 Molecular dynamics Shale oil reservoirs NANOPORES Enhanced oil recovery Fluid flow behavior Shale oil occurrence
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Data-Driven Prediction of Maximum Displacement of Flexible Riser Based on Movement of Platform 被引量:1
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作者 SONG Jin-ze WU Yu-ze +3 位作者 HE Yu-fa ZHOU Shui-gen ZHU Hong-jun DENG Kai-rui 《China Ocean Engineering》 2025年第5期793-805,共13页
Mitigating vortex-induced vibrations(VIV)in flexible risers represents a critical concern in offshore oil and gas production,considering its potential impact on operational safety and efficiency.The accurate predictio... Mitigating vortex-induced vibrations(VIV)in flexible risers represents a critical concern in offshore oil and gas production,considering its potential impact on operational safety and efficiency.The accurate prediction of displacement and position of VIV in flexible risers remains challenging under actual marine conditions.This study presents a data-driven model for riser displacement prediction that corresponds to field conditions.Experimental data analysis reveals that the XGBoost algorithm predicts the maximum displacement and position with superior accuracy compared with Support vector regression(SVR),considering both computational efficiency and precision.Platform displacement in the Y-direction demonstrates a significant positive correlation with both axial depth and maximum displacement magnitude.The fourth point displacement exhibits the highest contribution to model prediction outcomes,showing a positive influence on maximum displacement while negatively affecting the axial depth of maximum displacement.Platform displacement in the X-and Y-directions exhibits competitive effects on both the riser’s maximum displacement and its axial depth.Through the implementation of XGBoost algorithm and SHapley Additive exPlanation(SHAP)analysis,the model effectively estimates the riser’s maximum displacement and its precise location.This data-driven approach achieves predictions using minimal,readily available data points,enhancing its practical field applications and demonstrating clear relevance to academic and professional communities. 展开更多
关键词 data-driven method flexible riser vortex-induced vibration(VIV) platform displacement
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Application of modified two-point hedging policy in groundwater resources planning in the Kashan Plain Aquifer
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作者 Marzie Ghorbaniaghdam Hossein Khozeymehnezhad +1 位作者 Mohsen Pourreza bilondi Hoda Ghasemie 《Journal of Groundwater Science and Engineering》 2025年第1期62-73,共12页
Effective management of water resources,especially groundwater,is crucial and requires a precise understanding of aquifer characteristics,imposed stresses,and the groundwater balance.Simulation-optimization models pla... Effective management of water resources,especially groundwater,is crucial and requires a precise understanding of aquifer characteristics,imposed stresses,and the groundwater balance.Simulation-optimization models plays a vital role in guiding planners toword sustainable long-term aquifer exploita-tion.This study simulated monthly water table variations in the Kashan Plain over a ten-year period from 2008 to 2019 across 125 stress periods using the GMS model.The model was calibrated for both steady-state and transient conditions for the 2008–2016 period and validated for the 2016–2019 period.Results indicated a 4.4 m decline in groundwater levels over the 10-year study period.Given the plain's location in a arid climatic zone with limited effective precipitation for aquifer recharge,the study focused on ground-water extraction management.A modified two-point hedging policy was employed as a solution to mitigate critical groundwater depletion,reducing the annual drawdown rate from 0.44 m to 0.31 m and conserving 255 million cubic meters(mcm)of water annually.Although this approach slightly decreased reliability(i.e.the number of months meeting full water demands),it effectively minimized the risk of severe droughts and irreparable damages.This policy offers managers a dynamical and intelligent tool for regulating groundwater extraction,balancing aquifer sustainability with agricultural and urban water requirements. 展开更多
关键词 Calibration GMS Groundwater simulation-optimization model Modified two-point hedging policy Sustainable operation
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Enhanced Wheat Disease Detection Using Deep Learning and Explainable AI Techniques
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作者 Hussam Qushtom Ahmad Hasasneh Sari Masri 《Computers, Materials & Continua》 2025年第7期1379-1395,共17页
This study presents an enhanced convolutional neural network(CNN)model integrated with Explainable Artificial Intelligence(XAI)techniques for accurate prediction and interpretation of wheat crop diseases.The aim is to... This study presents an enhanced convolutional neural network(CNN)model integrated with Explainable Artificial Intelligence(XAI)techniques for accurate prediction and interpretation of wheat crop diseases.The aim is to streamline the detection process while offering transparent insights into the model’s decision-making to support effective disease management.To evaluate the model,a dataset was collected from wheat fields in Kotli,Azad Kashmir,Pakistan,and tested across multiple data splits.The proposed model demonstrates improved stability,faster conver-gence,and higher classification accuracy.The results show significant improvements in prediction accuracy and stability compared to prior works,achieving up to 100%accuracy in certain configurations.In addition,XAI methods such as Local Interpretable Model-agnostic Explanations(LIME)and Shapley Additive Explanations(SHAP)were employed to explain the model’s predictions,highlighting the most influential features contributing to classification decisions.The combined use of CNN and XAI offers a dual benefit:strong predictive performance and clear interpretability of outcomes,which is especially critical in real-world agricultural applications.These findings underscore the potential of integrating deep learning models with XAI to advance automated plant disease detection.The study offers a precise,reliable,and interpretable solution for improving wheat production and promoting agricultural sustainability.Future extensions of this work may include scaling the dataset across broader regions and incorporating additional modalities such as environmental data to enhance model robustness and generalization. 展开更多
关键词 Convolutional neural network(CNN) wheat crop disease deep learning disease detection shapley additive explanations(SHAP) local interpretable model-agnostic explanations(LIME)
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An intelligent recognition method of deep shale gas reservoir laminaset based on laminaset clustering and R-L-M algorithm
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作者 Yu Zeng Fuqiang Lai +4 位作者 Haijie Zhang Yi Jiang Junwei Pu Tongtong Luo Xiaoxia Zhao 《Artificial Intelligence in Geosciences》 2025年第1期97-112,共16页
Lamina structures,as typical sedimentary features in shale formations,determine both the quality of shale reservoirs and fracturing effects.In this study,through electric imaging logging,based on core scanning photos,... Lamina structures,as typical sedimentary features in shale formations,determine both the quality of shale reservoirs and fracturing effects.In this study,through electric imaging logging,based on core scanning photos,thin sections,and other data from the Wufeng-Longmaxi Formation shale reservoirs in the western Sichuan Block,the characteristics and classification scheme of deep shale gas reservoir laminaset were clarified.In addition,with core scale electrical images,the electrical imaging logging response characteristics of different types of laminaset were identified.Based on electrical imaging logging images,a laminaset clustering algorithm was designed to segment the laminaset and then Levenberg-Marquardt(L-M)algorithm was improved by introducing a random forest to obtain the R-L-M algorithm,which was used to extract key parameters of lam-inaset such as attitude,type,density,and thickness.The average accuracy,recall rate,and F1 score of laminaset recognition results of this algorithm were 14.82%higher than those of a well-known international commercial software(T).This method was used to evaluate the Longmaxi Formation shale gas reservoir in the western Sichuan Block.The development density of clay-siliceous(organic-lean)laminaset from the Longyi 1-4 small layer to the lower Wufeng Formation firstly decreased and then increased and the minimum value was found in Longyi 1-1 small layer.In contrast,the development density of siliceous-clay laminaset(organic-rich)first increased and then gradually decreased and the maximum value was found in Longyi 1-1 small layer.The clay-siliceous laminaset(organic matters-contained)and the calcareous-clay laminaset(organic matters-contained)showed a stable developmental trend. 展开更多
关键词 SHALE Electrical image laminaset CLUSTERING R-L-M
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Numerical Simulation of Gas-Water Two-Phase Flow in a Proppant-Filled Layer
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作者 Jian Yang Xinghao Gou +4 位作者 Jiayi Sun Fei Liu Xiaojin Zhou Xu Liu Tao Zhang 《Fluid Dynamics & Materials Processing》 2025年第8期1935-1954,共20页
Shale gas production involves complex gas-water two-phase flow,with flow patterns in proppant-filled fractures playing a critical role in determining production efficiency.In this study,3D geometric models of 40/70 me... Shale gas production involves complex gas-water two-phase flow,with flow patterns in proppant-filled fractures playing a critical role in determining production efficiency.In this study,3D geometric models of 40/70 mesh ceramic particles and quartz sand proppant clusters were elaborated using computed tomography(CT)scanning.These models were used to develop a numerical simulation framework based on the lattice Boltzmann method(LBM),enabling the investigation of gas-water flow behavior within proppant-filled fractures under varying driving forces and surface tensions.Simulation results at a closure pressure of 15 MPa have revealed that ceramic particles exhibit a simpler and more porous internal structure than quartz sand of the same size.Under identical flow conditions,ceramic proppants demonstrate higher fluid replacement efficiency.Replacement efficiency increases with higher porosity,greater driving force,and lower surface tension.Furthermore,fluid displacement is strongly influenced by pore geometry:flow is faster in straighter and wider channels,with preferential movement through larger pores forming dominant flow paths.The replacement velocity exhibits a characteristic time evolution,initially rapid,then gradually decreasing,correlating positively with the development of these dominant channels. 展开更多
关键词 Proppant fractures gas-water two-phase flow numerical simulation lattice Boltzmann method flow behavior
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Eco-friendly collectors in apatite froth flotation:A review
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作者 Gabriela Budemberg Rickard Jolsterå Saeed Chehreh Chelgani 《International Journal of Mining Science and Technology》 2025年第4期539-551,共13页
The global reliance on phosphate rock for agriculture and other industries,coupled with chemical regulations in developed countries,has driven the search for green alternatives in apatite flotation.This review investi... The global reliance on phosphate rock for agriculture and other industries,coupled with chemical regulations in developed countries,has driven the search for green alternatives in apatite flotation.This review investigates eco-friendly collectors’effectiveness in promoting sustainable mineral processing,guiding future alternatives to traditional reagents.The manuscript discussed the surface properties of apatite and its interaction with eco-friendly collectors,assessing existing fundamental studies.This study sought to:(1)define,organize,and classify“eco-friendly”collectors;(2)evaluate their effect in IEP and contact angle;(3)provide a better understanding of the adsorption behavior of the different fatty acid chains into apatite surface;(4)assess their ability to reversely and directly float apatite;(5)address gaps to achieve selectivity and process optimization.Outcomes demonstrated that fatty acids are largely applied,but other renewable sources of these reagents have been promisingly evaluated.In addition,other natural reagents have been tested,and new green synthetics have demonstrated synergistic effects when combined with fatty acids,yielding significant improvements in grade and recovery.However,collector effectiveness varies with ore characteristics,like particle size and surface properties,which remain underexplored.Future research should design tailored collectors that align with mineralogical differences to enhance selectivity. 展开更多
关键词 APATITE FLOTATION Eco-friendly collectors ADSORPTION Synergic interactions
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Impact of International Student Mobility in Distinctive Disciplines on Internationalization Capabilities
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作者 Guangli Xu Liangxue Cai Gao Li 《Journal of Contemporary Educational Research》 2025年第9期1-9,共9页
To deeply analyze the impact of international student mobility on their internationalization capabilities in the field of Petroleum and Natural Gas Engineering,this study systematically reviewed the exchange dynamics ... To deeply analyze the impact of international student mobility on their internationalization capabilities in the field of Petroleum and Natural Gas Engineering,this study systematically reviewed the exchange dynamics of international students at Southwest Petroleum University from 2014 to 2024,as well as detailed data on students’overseas visits from 2016 to 2024,carefully outlining the trends and characteristics of student international mobility over the past decade.Based on this,using an evaluation system for internationalization capabilities constructed by the authors,which closely follows the characteristics of Petroleum and Natural Gas Engineering and covers key dimensions such as language skills,international perspective,cross-cultural communication,and global cooperation,graduate students from the research team of international students were selected as a sample group.Through a carefully designed survey questionnaire,their current internationalization capabilities were systematically evaluated.The results showed that compared to the benchmark level in 2019,students’internationalization capabilities have shown a significant improvement trend,especially in cross-cultural communication.This finding not only reveals the positive role of international student mobility in promoting academic exchanges and integration but also further emphasizes the unique value of multicultural integration in scientific research teams to enhance the internationalization capabilities of domestic students. 展开更多
关键词 International mobility Internationalization capabilities Petroleum and natural gas engineering discipline
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Advancements in hydrogen storage technologies:Integrating with renewable energy and innovative solutions for a sustainable future
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作者 Yasin Khalili Sara Yasemi +1 位作者 Mohammadreza Bagheri Ali Sanati 《Energy Geoscience》 2025年第2期24-48,共25页
Hydrogen storage plays a crucial role in achieving net-zero emissions by enabling large-scale energy storage,balancing renewable energy fluctuations,and ensuring a stable supply for various applications.This study pro... Hydrogen storage plays a crucial role in achieving net-zero emissions by enabling large-scale energy storage,balancing renewable energy fluctuations,and ensuring a stable supply for various applications.This study provides a comprehensive analysis of hydrogen storage technologies,with a particular focus on underground storage in geological formations such as salt caverns,depleted gas reservoirs,and aquifers.These formations offer high-capacity storage solutions,with salt caverns capable of holding up to 6 TWh of hydrogen and depleted gas reservoirs exceeding 1 TWh per site.Case studies from leading projects demonstrate the feasibility of underground hydrogen storage(UHS)in reducing energy intermittency and enhancing supply security.Challenges such as hydrogen leakage,groundwater contamination,induced seismicity,and economic constraints remain critical concerns.Our findings highlight the technical,economic,and regulatory considerations for integrating UHS into the oil and gas industry,emphasizing its role in sustainable energy transition and decarbonization strategies. 展开更多
关键词 Hydrogen storage Oil and gas industry Enhanced oil recovery(EOR) Greenhouse gas emission reduction Sustainable energy solution
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Fine interfacial control mechanism of ammonium perchlorate and aluminum powder:Thermal reaction characteristics and kinetic studies
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作者 Jun LIU Tianyu YANG +2 位作者 Yi XIAO Qilong YAN Yunlan SUN 《Chinese Journal of Aeronautics》 2025年第10期507-525,共19页
To gain insight into the fine interfacial control mechanism exhibited by oxidant-coated Al powder to improve combustion performance,we prepared Al/AP and Al@AP composite fuels using ball milling and spray-drying techn... To gain insight into the fine interfacial control mechanism exhibited by oxidant-coated Al powder to improve combustion performance,we prepared Al/AP and Al@AP composite fuels using ball milling and spray-drying technology.The thermal reaction characteristics,AP decomposition behavior,and decomposition reaction pathways of Al/AP and Al@AP composite fuels were investigated using thermal analysis and Ab Initio Molecular Dynamics(AIMD)calculations.Under the influence of fine interfacial control,the low-temperature decomposition heat release peak of AP was delayed by 25.5℃,while the high-temperature decomposition peak was advanced by 36.2℃,leading to an increase in the decomposition heat release of AP from 410.7 J/g to 1068.7 J/g.Compared to the unclad structure,the apparent activation energy of AP in low-temperature decomposition increased,and slightly decreased during high-temperature decomposition in the Al@AP composite fuel.The physical model of AP decomposition shifted to the model with higher degrees of freedom and a faster diffusion rate,characterized by rapid bidirectional diffusion at the interface.Furthermore,due to fine interfacial control,the oxidation reaction pathway of Al has been altered,changing from the final products of AP decomposition(O_(2),Cl2,etc.)to the direct oxidation of AP decomposition intermediates(HClO,ClO_(2),etc.).This accelerated and strengthened the oxidation reaction process of Al.As a result of these performance improvements,the final combustion temperature of Al@AP in the Microcanonical Ensemble(NVE)system stabilized at 2370 K,which is significantly higher than 1400 K observed for Al/AP,indicating enhanced ignition and combustion performance. 展开更多
关键词 Ab Initio Molecular Dynamics(AIMD) ALUMINUM Ammonium persulfate(AP) Composite materials Fine interfacial control Thermal decomposition kinetics
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Climate change trends and adaptation strategies in Southern Regions of Iraq
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作者 Laheab A Al-Maliki Rana Abd Al Hadi Mukheef +1 位作者 Khaled El-Tawil Nadhir Al-Ansari 《Journal of Groundwater Science and Engineering》 2025年第4期449-468,共20页
This study investigates the impacts of climate change on temperature and precipitation patterns across four governorates in southern Iraq—Basrah,Thi Qar,Al Muthanna,and Messan—using an inte-grated modeling framework... This study investigates the impacts of climate change on temperature and precipitation patterns across four governorates in southern Iraq—Basrah,Thi Qar,Al Muthanna,and Messan—using an inte-grated modeling framework that combines the Long Ashton Research Station Weather Generator(LARS-WG)with three CMIP5-based Global Climate Models(Hadley Centre Global Environmental Model version 2-Earth System(HadGEM2-ES)),European Community Earth-System Model(EC-Earth),and Model for Interdisciplinary Research on Climate version 5(MIROC5).Projections were generated for three future time periods(2021–2040,2041–2060,and 2061–2080)under two Representative Concentration Pathways(RCP4.5 and RCP8.5).By integrating high-resolution climate simulations with localized drought risk analy-sis,this study provides a detailed outlook on climate change trends in the region.The novelty of this research lies in its high-resolution,station-level analysis and its integration of localized statistical downscal-ing techniques to enhance the spatial applicability of coarse GCM outputs.Model calibration and validation 2 were performed using historical climate data(1990–2020),resulting in high accuracy across all stations(R=0.91–0.99;RMSE=0.19–2.78),thus reinforcing the robustness of the projections.Results indicate a significant rise in average annual maximum and minimum temperatures,with increases ranging from 0.88°C to 3.68°C by the end of the century,particularly under the RCP8.5 scenario.Precipitation patterns exhibit pronounced interannual variability,with the highest predicted increases reaching up to 19.26 mm per season,depending on the model and location.These shifts suggest heightened vulnerability to drought and water scarcity,particularly in already arid regions such as Muthanna and Thi Qar.The findings under-score the urgent need for adaptive strategies in water resource management and agricultural planning,providing decision-makers with region-specific climate insights critical for sustainable development under changing climate conditions. 展开更多
关键词 Climate model projections Climate vulnerability Extreme events Hydrological risk Statisti-cal downscaling
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Al-Mg@PVDF and Al-Si@PVDF composites with enhanced combustion and energy release characteristics
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作者 Zhanjun Yang Hao Liu +4 位作者 Mi Li Xiaoqian Wang Oisik Das Zhong xuan Han Lin Jiang 《Defence Technology(防务技术)》 2025年第6期1-25,共25页
To investigate the differences in combustion and energy release characteristics of metastable intermolecular composite materials composed of aluminum alloys and polyvinylidene fluoride(PVDF)with different compositions... To investigate the differences in combustion and energy release characteristics of metastable intermolecular composite materials composed of aluminum alloys and polyvinylidene fluoride(PVDF)with different compositions,two types of alloys were selected:Al-Mg and Al-Si.Pure aluminum powder of the same size was also chosen for comparison.The PVDF-coated metal particle composites and the mixtures of PVDF with metal particles were prepared using electrospray(ES)and physical blending methods(PM),respectively.A systematic study was conducted on the morphology,compositional structure,combustion performance,energy release characteristics,and thermal reactivity of the fabricated composites and their combustion products through scanning electron microscopy(SEM),energy-dispersive X-ray spectroscopy(EDS),X-ray diffraction(XRD),combustion performance experiments,closed vessel pressure tests,and simultaneous thermogravimetric-differential scanning calorimetry(TG-DSC).The experimental results indicated that the PVDF-coated metal particles prepared by the electrospray method exhibited a distinct core-shell structure,with the metal particles in close contact with the PVDF matrix.Compared to the PM blended materials,the ES composites demonstrated superior combustion performance and energy release characteristics during combustion.Analysis of different metal fuel systems under identical preparation conditions revealed that Al-Mg and Al-Si fuels modulate the combustion and energy release properties of aluminum alloy-PVDF MICs through two distinct pathways. 展开更多
关键词 ES(electrostatic spraying) PM(physical mixing) AL-MG AL-SI COMBUSTION Combustion and energy release CHARACTERISTICS
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The Water Flooding Seepage Mechanism in the Inter-Fractures of Horizontal Wells in Tight Oil Reservoirs
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作者 Xinli Zhao Qianhua Xiao +3 位作者 Xuewei Liu Yu Shi Xiangji Dou Guoqiang Xing 《Fluid Dynamics & Materials Processing》 2025年第2期427-444,共18页
Tight oil reservoirs face significant challenges,including rapid production decline,low recovery rates,and a lack of effective energy replenishment methods.In this study,a novel development model is proposed,based on ... Tight oil reservoirs face significant challenges,including rapid production decline,low recovery rates,and a lack of effective energy replenishment methods.In this study,a novel development model is proposed,based on inter-fracture injection following volumetric fracturing and relying on a high-temperature and high-pressure large-scale physical simulation system.Additionally,the CMG(Computer Modelling Group Ltd.,Calgary City,Canada)software is also used to elucidate the impact of various single factors on the production of horizontal wells while filtering out the interference of others.The effects of fracture spacing,fracture half-length,and the injection-production ratio are studied.Results indicate that under rejection pressures of 6.89,3.45,and 1.88 MPa,the times to establish stable flow are 50,193,and 395 min,respectively.Higher injection pressures lead to an increased oil recovery efficiency,with the highest observed efficiency at 16.93%.This indicates that,compared with conventional medium and high permeability reservoirs,tight oil reservoirs exhibit similar pore throats and larger capillary forces when oil and water flow in both phases.Higher pressures reduce capillary forces,displacing more oil droplets,thus enhancing oil recovery efficiency.Moreover,under inter-fracture displacement conditions,the pressure gradient at both the injection and production ends remain consistent,with minimal pressure loss near the wellbore.This feature ensures that the crude oil in the middle of the reservoir also possesses displacement energy,thereby enhancing overall crude oil displacement efficiency. 展开更多
关键词 Tight oil reservoir volumetric fracturing inter-fracture injection and production oil drive efficiency WATERFLOODING
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Organic geochemistry and basin modeling of the Eocene Mangahewa source rock system in the Pohokura oilfield,Taranaki Basin(New Zealand)and their indication of oil and gas potential
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作者 Talha S.M.Qadri Mohammed Hail Hakimi +3 位作者 Mahdi Ali Lathbl Aref Lashin Mohammed Almobarky Afikah Rahim 《China Geology》 2025年第4期725-739,共15页
The importance of organic geochemistry and basin modeling is widely recognized and used to understand the source rock potential and hydrocarbon generation history of the Mangahewa Formation,and thereby given the found... The importance of organic geochemistry and basin modeling is widely recognized and used to understand the source rock potential and hydrocarbon generation history of the Mangahewa Formation,and thereby given the foundational role in the petroleum exploration.This study utilized the total organic carbon(TOC)content and hydrogen index(HI)to investigate the dominant kerogen type and hydrogen richness for the significance of petroleum generative potential.The Mangahewa coals and carbonaceous shales exhibit an excellent source rocks,with high total organic content(TOC)of more than 22%.The coals and carbonaceous shales were also characterised by Type Ⅱ‒Ⅲ kerogen with Type Ⅲ kerogen,promising oiland gas-prones.The Mangahewa Formation reached the main oil generation,with vitrinite reflectances between 0.53%and 1.01%.Vitrinite reflectance was also used in developing themal models and reveal the transformation(TR)of 10‒50%kerogen to oil during the Late Miocene.The models also showed that the Mangahewa source rock has a significant oil generation and little expulsion competency,with a TR of up to 54%.These findings support the substantial oil-generating potential in the Taranaki Basin's southern graben and can be used as a guide when developing strategies for an oil exploration program. 展开更多
关键词 Mangahewa Formation Thermal cracking Coal and carbonaceous shale Source rock system Oil generation modeling Pohokura oilfield New Zealand
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Controlling effects of the Mid-Permian multistage slope-break zones on paleogeomorphology and large-scale shoals in the Sichuan Basin,SW China
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作者 XU Qiang YANG Wenjie +10 位作者 WEN Long LI Shuangjian LUO Bing XIAO Di QIAO Zhanfeng LIU Shijun LI Minglong GUO Jie TAN Xianfeng SHI Shuyuan TAN Xiucheng 《Petroleum Exploration and Development》 2025年第4期952-967,共16页
This study reconstructed the paleo-uplift and depression pattern within the sequence stratigraphic framework of the Mid-Permian Maokou Formation,Sichuan Basin,investigated its tectono-sedimentary mechanisms and its co... This study reconstructed the paleo-uplift and depression pattern within the sequence stratigraphic framework of the Mid-Permian Maokou Formation,Sichuan Basin,investigated its tectono-sedimentary mechanisms and its control on paleogeomorphology and large-sale shoals based on analysis of outcrops,loggings and seismic data.The results show that the Maokou Formation comprises two third-order sequences,six fourth-order sequences(SSQ1-SSQ6),and four distinct slope-break zones developing progressively from north to south.Slope-break zones I-III in the northern basin,controlled by synsedimentary extensional faults,exhibited a NE-trending linear distribution with gradual southeastward migration.In contrast,slope-break zone IV in the southern basin displayed an arcuate distribution along the Emeishan Large Igneous Province(ELIP).The evolutions of these multistage slope-break zones governed the Mid-Permian paleogeomorphy in the Sichuan Basin transformations from a giant,north-dipping gentle slope(higher in the southwest than in the northeast)in the early-stage(SSQ1-SSQ2)to a platform(south)-basin(north)pattern in the middle-stage(SSQ3-SSQ5).Ultimately,a further depression zone developed in the southwestern basin during the late-stage(SSQ6),forming a paleo-uplift bounded by two depressions.The developments of the Mid-Permian paleogeomorphic configuration reflected the combined control by the rapid subduction of the Mianlüe Ocean and the episodic eruptions of the Emeishan mantle plume(or hot spots),which jointly facilitated the formation of extensive high-energy shoal facies belts along slope-break zones and around paleo-volcanic uplifts. 展开更多
关键词 multistage slope-break zone paleogeomorphology Mid-Permian Maokou Formation sequence stratigraphic framework high-energy shoal facies belt Mianlüe Ocean Sichuan Basin
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Deciphering dissolved inorganic carbon dynamics in Xiangshan Bay: isotopic constraints on sources, hydrodynamic controls, and anthropogenic influences
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作者 Xue Li Xiaoyong Duan +4 位作者 Gang Tong Ping Yin Fei Gao Ke Cao Bin Chen 《Acta Oceanologica Sinica》 2025年第9期53-67,共15页
This study investigates the spatial distribution and regulatory mechanisms of dissolved inorganic carbon(DIC) in Xiangshan Bay, East China Sea, addressing critical gaps in carbon cycling research within semi-enclosed ... This study investigates the spatial distribution and regulatory mechanisms of dissolved inorganic carbon(DIC) in Xiangshan Bay, East China Sea, addressing critical gaps in carbon cycling research within semi-enclosed bays. Through isotopic analysis(δ~(13)C_(DIC), δD and δ18O) and hydrochemical measurements [salinity and dissolved oxygen(DO)] of surface and bottom seawater samples from 52 stations, we demonstrate that δ~(13)C_(DIC) values(surface:-3.6‰ to-2.1‰;bottom:-3.6‰ to-1.8‰) exhibit distinct vertical and spatial patterns, with higher values in surface waters and outer bay regions compared to bottom and inner bay areas. Conservative mixing between seawater(average contribution:56%) and freshwater dominates DIC dynamics, while tidal hydrodynamics amplify the imprint of riverine inputs during low tides. Nutrient gradients driven by saline-freshwater mixing enhance primary productivity in outer bay regions,resulting in 13C-enriched DIC and elevated dissolved organic carbon(DOC) concentrations. Conversely, bottom waters show 13C-depleted signatures(-2.75‰ mean δ~(13)C_(DIC)), reflecting organic matter degradation under oxygen-depleted conditions. Aquaculture activities exacerbate localized eutrophication, with monsoon-enhanced runoff amplifying anthropogenic impacts. This work underscores the sensitivity of coastal carbon cycling to both natural hydrodynamics and anthropogenic perturbations in semi-enclosed bays. 展开更多
关键词 carbon cycle dissolved inorganic carbon coastal region anthropogenic activities
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Fracture evolution in steel fiber reinforced concrete(SFRC)of tunnel under static and dynamic loading based on DEM‑FDM coupling model
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作者 Yu Chen Dongfeng Yu +4 位作者 Yixian Wang Yanlin Zhao Hang Lin Jingjing Meng Haoliang Wu 《International Journal of Coal Science & Technology》 2025年第1期186-213,共28页
The frequent or occasional impact loads pose serious threats to the service safety of conventional concrete structures in tunnel.In this paper,a novel three-dimensional mesoscopic model of steel fiber reinforced concr... The frequent or occasional impact loads pose serious threats to the service safety of conventional concrete structures in tunnel.In this paper,a novel three-dimensional mesoscopic model of steel fiber reinforced concrete(SFRC)is constructed by discrete element method.The model encompasses the concrete matrix,aggregate,interfacial transition zone and steel fibers,taking into account the random shape of the coarse aggregate and the stochastic distribution of steel fibers.It captures microscopic-level interactions among the coarse aggregate,steel fibers,and matrix.Subsequently,a comprehensive procedure is formulated to calibrate the microscopic parameters required by the model,and the reliability of the model is verified by comparing with the experimental results.Furthermore,a coupled finite difference method-discrete element method approach is used to construct the model of the split Hopkinson pressure bar.Compression tests are simulated on SFRC specimens with varying steel fiber contents under static and dynamic loading conditions.Finally,based on the advantages of DEM analysis at the mesoscopic level,this study analyzed mechanisms of enhancement and crack arrest in SFRC.It shed a light on the perspectives of interface failure process,microcrack propagation,contact force field evolution and energy analysis,offering valuable insights for related mining engineering applications. 展开更多
关键词 Steel fiber reinforced concrete Dynamic loading Contact force field ENERGY
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C-BIVM:A Cognitive-Based Integrity Verification Model for IoT-Driven Smart Cities
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作者 Radhika Kumari Kiranbir Kaur +4 位作者 Ahmad Almogren Ayman Altameem Salil Bharany Yazeed Yasin Ghadi Ateeq Ur Rehman 《Computers, Materials & Continua》 2025年第9期5509-5525,共17页
The exponential growth of the Internet of Things(IoT)has revolutionized various domains such as healthcare,smart cities,and agriculture,generating vast volumes of data that require secure processing and storage in clo... The exponential growth of the Internet of Things(IoT)has revolutionized various domains such as healthcare,smart cities,and agriculture,generating vast volumes of data that require secure processing and storage in cloud environments.However,reliance on cloud infrastructure raises critical security challenges,particularly regarding data integrity.While existing cryptographic methods provide robust integrity verification,they impose significant computational and energy overheads on resource-constrained IoT devices,limiting their applicability in large-scale,real-time scenarios.To address these challenges,we propose the Cognitive-Based Integrity Verification Model(C-BIVM),which leverages Belief-Desire-Intention(BDI)cognitive intelligence and algebraic signatures to enable lightweight,efficient,and scalable data integrity verification.The model incorporates batch auditing,reducing resource consumption in large-scale IoT environments by approximately 35%,while achieving an accuracy of over 99.2%in detecting data corruption.C-BIVM dynamically adapts integrity checks based on real-time conditions,optimizing resource utilization by minimizing redundant operations by more than 30%.Furthermore,blind verification techniques safeguard sensitive IoT data,ensuring privacy compliance by preventing unauthorized access during integrity checks.Extensive experimental evaluations demonstrate that C-BIVM reduces computation time for integrity checks by up to 40%compared to traditional bilinear pairing-based methods,making it particularly suitable for IoT-driven applications in smart cities,healthcare,and beyond.These results underscore the effectiveness of C-BIVM in delivering a secure,scalable,and resource-efficient solution tailored to the evolving needs of IoT ecosystems. 展开更多
关键词 Internet of Things(IoT) smart cities data integrity verification BDI cognitive intelligence algebraic signatures batch auditing resource-constrained devices blind verification
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Cryogenic liquid nitrogen treatment for enhancing gas production in Sui main limestone carbonates, Central Indus Basin, Pakistan
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作者 Muhammad Ali Abdul Majeed Shar +5 位作者 Nurudeen Yekeen Muhammad Furqan Qureshi Muhammad Usman Mohammed Al Kobaisi Muhammad Shahzad Kamal Hussein Hoteit 《Earth Energy Science》 2025年第3期270-281,共12页
The Early Eocene Sui Main Limestone(SML)reservoirs in the Qadirpur area are significant hydrocarbon-producing formations but suffer from low permeability and poor reservoir characteristics that lead to well abandonmen... The Early Eocene Sui Main Limestone(SML)reservoirs in the Qadirpur area are significant hydrocarbon-producing formations but suffer from low permeability and poor reservoir characteristics that lead to well abandonment.Although commonly used,conventional stimulation techniques such as hydraulic fracturing and acidizing pose environmental risks,high costs,and sensitivity to fluctuations in crude oil prices.Meanwhile,cryogenic liquid nitrogen(LN2)treatment has emerged as an innovative,eco-friendly alternative due to its thermal shock effects,which enhance rock permeability and porosity.Herein,SML core samples are treated with LN2 for 30,60,and 90 min to obtain samples designated as SML_30,SML_60,and SML_90,respectively.These are examined using X-ray diffraction(XRD),atomic force microscopy(AFM),scanning electron microscopy(SEM),energy dispersive spectroscopy(EDS),nanoindentation,and petrophysical measurements to evaluate the changes in their petrophysical,morphological,and micromechanical properties.The post-treatment analysis reveals that LN2 cooling effectively induces micro-cracks,with fracture widths of up to 40μm,along with a substantial increase in surface roughness from 350 to 942 nm.Additionally,micromechanical analysis indicates notable changes in the indentation modulus due to stress-induced alterations in the rock matrix.At optimal LN2 exposure(90 min),the porosity and permeability of the SML sample is more than doubled.These findings provide valuable insights into LN2-induced reservoir enhancements,thereby contributing to a better understanding of fluid flow behavior and hydrocarbon recovery in tight gas reservoirs.Thus,LN2 treatment presents a promising,cost-effective,and environmentally sustainable alternative to conventional stimulation methods. 展开更多
关键词 Sui main limestone Carbonate rocks Cryogenic liquid nitrogen Petrography Pore morphology Petrophysics Central Indus basin
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Experimental investigation into CO_(2) huff-n-puff in low-permeability heavy oil reservoirs: Role of fractures
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作者 Di Zhu Bin-Fei Li +4 位作者 Lei Zheng Maen M.Husein Zheng-Xiao Xu Bo-Liang Li Zhao-Min Li 《Petroleum Science》 2025年第3期1200-1213,共14页
Low-permeability heavy oil reservoirs are characterized by poor flowability, generally mandating hydraulic fracturing to commence production. CO_(2) huff-n-puff in fractured reservoirs is an effective enhanced oil rec... Low-permeability heavy oil reservoirs are characterized by poor flowability, generally mandating hydraulic fracturing to commence production. CO_(2) huff-n-puff in fractured reservoirs is an effective enhanced oil recovery method. This paper uses nuclear magnetic resonance imaging to elucidate the role of propped and unpropped fractures on CO_(2) huff-n-puff in cores under different confining pressures. In presence of fractures, significant improvement in the rate of early stage oil recovery is observed, up to 0.255 mL/min. Fractures enlarge the contact area between CO_(2) and the heavy oil, hence improve CO_(2) dissolution and oil flowability. Fractures improve oil recovery from micropores, small pores, and mesopores, as well as reduce CO_(2) consumption ratio. The oil recovery factor in propped fractures is significantly higher than that in unpropped fractures, and with higher oil recovery from small pores and mesopores. The oil recovery in fractured cores noticeably decreases with increasing confining pressure. The extent of fracture closure increases and the matrix pore throats compress under pressure leading to lower apparent permeability. The decrease in oil recovery factor is more pronounced in unpropped fractured cores. A relationship between the apparent permeability of the fracture aperture is derived based on the modified cubic law of percolation to quantitatively characterize the fracture. Additionally, both the reduction in heavy oil viscosity and the increase in experimental temperature and pressure can improve the CO_(2) huff-n-puff oil recovery factor in fractured cores. 展开更多
关键词 Low-permeability reservoir Heavy oil CO_(2)HnP Unpropped fracture Fracture aperture
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