Boron-based fuels,recognized for their high energy density and potential in energetic applications,encounter challenges such as long ignition delays and incomplete combustion,which result in reduced combustion efficie...Boron-based fuels,recognized for their high energy density and potential in energetic applications,encounter challenges such as long ignition delays and incomplete combustion,which result in reduced combustion efficiency and limited performance in aerospace propulsion.In this study,boron carbide(B4C)is investigated as an alternative fuel to pristine boron due to its favorable gas-phase combustion.Both metal oxide(nickel oxide(NiO))and metal fluoride(nickel fluoride(NiF_(2)))are selected as oxidizing modifiers to enhance the reactivity of B4C.A method combining laser ignition with optical diagnostics is employed to investigate the enhancing effects of different oxidizers on the ignition and combustion characteristics of B4C.Both NiO and NiF_(2)can significantly increase the combustion radiation intensity and reduce the time to maximum intensity of B4C.Differential scanning calorimetry,in-situ X-ray diffraction,and Fourier transform infrared spectroscopy were used for simultaneous thermal analysis of the B4C composite powders.Combined thermal analysis showed that the effects of NiO and NiF_(2)on promoting B4C combustion is mainly achieved via the formation of NimBn and the release of a large number of gas products.It is reasonable to speculate that the phase separation at the B2O3/NimBn interface forms new pathways for oxygen diffusion and reaction with the B core.The difference in the combustion mechanism of B4C with NiO and NiF_(2)lies in the gas phase products,i.e.,CO_(2)and BF3,respectively,thus leading to significant differences in their reaction processes.展开更多
Columnar grains offer considerable advantages in terms of microstructure for resisting high-temperature low-cycle fatigue. In additive manufacturing, the formation of fine columnar grains is common. However, post-heat...Columnar grains offer considerable advantages in terms of microstructure for resisting high-temperature low-cycle fatigue. In additive manufacturing, the formation of fine columnar grains is common. However, post-heat treatment often transforms these grains into equiaxed grains. This study aimed to tailor the grain morphology by controlling the precipitation of carbides. By balancing the restraining effects of carbide pinning and grain growth, we achieved carbide-assisted in situ-directional recrystallization. This process preserved the columnar grains created via laser powder bed fusion, even after high-temperature heat treatment. The approach emphasizes promoting the longitudinal growth of columnar grains while preventing their broadening. Additionally, we characterized the evolution of carbides and γ′ precipitates and examined their role in nucleation and growth during recrystallization. This study supports the viability of carbide-assisted in situ-directional recrystallization in additive manufacturing alloys, introducing an innovative strategy for microstructure customization. The implementation of carbon stabilization (CS) treatment to control the carbide distribution led to a 40 % improvement in the creep life at 900 ℃ and 150 MPa.展开更多
基金The National Natural Science Foundation of China(Grant Nos.523B2063 and 52376089)。
文摘Boron-based fuels,recognized for their high energy density and potential in energetic applications,encounter challenges such as long ignition delays and incomplete combustion,which result in reduced combustion efficiency and limited performance in aerospace propulsion.In this study,boron carbide(B4C)is investigated as an alternative fuel to pristine boron due to its favorable gas-phase combustion.Both metal oxide(nickel oxide(NiO))and metal fluoride(nickel fluoride(NiF_(2)))are selected as oxidizing modifiers to enhance the reactivity of B4C.A method combining laser ignition with optical diagnostics is employed to investigate the enhancing effects of different oxidizers on the ignition and combustion characteristics of B4C.Both NiO and NiF_(2)can significantly increase the combustion radiation intensity and reduce the time to maximum intensity of B4C.Differential scanning calorimetry,in-situ X-ray diffraction,and Fourier transform infrared spectroscopy were used for simultaneous thermal analysis of the B4C composite powders.Combined thermal analysis showed that the effects of NiO and NiF_(2)on promoting B4C combustion is mainly achieved via the formation of NimBn and the release of a large number of gas products.It is reasonable to speculate that the phase separation at the B2O3/NimBn interface forms new pathways for oxygen diffusion and reaction with the B core.The difference in the combustion mechanism of B4C with NiO and NiF_(2)lies in the gas phase products,i.e.,CO_(2)and BF3,respectively,thus leading to significant differences in their reaction processes.
基金supported by the National Key Research and Development Program of China(Grant No.2019YFA0705300)the National Natural Science Foundation of China(Grant No.51974057)the Fundamental Research Funds for the Central Universities。
文摘Columnar grains offer considerable advantages in terms of microstructure for resisting high-temperature low-cycle fatigue. In additive manufacturing, the formation of fine columnar grains is common. However, post-heat treatment often transforms these grains into equiaxed grains. This study aimed to tailor the grain morphology by controlling the precipitation of carbides. By balancing the restraining effects of carbide pinning and grain growth, we achieved carbide-assisted in situ-directional recrystallization. This process preserved the columnar grains created via laser powder bed fusion, even after high-temperature heat treatment. The approach emphasizes promoting the longitudinal growth of columnar grains while preventing their broadening. Additionally, we characterized the evolution of carbides and γ′ precipitates and examined their role in nucleation and growth during recrystallization. This study supports the viability of carbide-assisted in situ-directional recrystallization in additive manufacturing alloys, introducing an innovative strategy for microstructure customization. The implementation of carbon stabilization (CS) treatment to control the carbide distribution led to a 40 % improvement in the creep life at 900 ℃ and 150 MPa.
