Flotation is the most common method to obtain concentrate through the selective adsorption of collectors on target minerals to make them hydrophobic and floatable.In the hydrometallurgy of concentrate,collectors adsor...Flotation is the most common method to obtain concentrate through the selective adsorption of collectors on target minerals to make them hydrophobic and floatable.In the hydrometallurgy of concentrate,collectors adsorbed on concentrate can damage ion-exchange resin and increase the chemical oxygen demand(COD)value of wastewater.In this work,we proposed a new scheme,i.e.,desorbing the collectors from concentrate in ore dressing plant and reusing them in flotation flowsheet.Lead nitrate and benzohydroxamic acid(Pb-BHA)complex is a common collector in scheelite flotation.In this study,different physical(stirring or ultrasonic waves)and chemical(strong acid or alkali environment)methods for facilitating the desorption of Pb-BHA collector from scheelite concentrate were explored.Single-mineral desorption tests showed that under the condition of pulp pH 13 and ultrasonic treatment for 15 min,the highest desorption rates of Pb and BHA from the scheelite concentrate were 90.48%and 63.75%,respectively.Run-of-mine ore flotation tests revealed that the reuse of desorbed Pb and BHA reduced the collector dosage by 30%for BHA and 25%for Pb.The strong alkali environment broke the chemical bonds between Pb and BHA.The cavitation effect of ultrasonic waves effectively reduced the interaction intensity between Pb-BHA collector and scheelite surfaces.This method combining ultrasonic waves and strong alkali environment can effectively desorb the collectors from concentrate and provide“clean”scheelite concentrate for metallurgic plants;the reuse of desorbed collector in flotation flowsheet can reduce reagent cost for ore dressing plants.展开更多
Based on analysis of a large data set and supplementary sampling and analysis for hazardous trace elements in coal samples from the Huainan Coalfield,a generalized contrast-weighted scale index method was used to esta...Based on analysis of a large data set and supplementary sampling and analysis for hazardous trace elements in coal samples from the Huainan Coalfield,a generalized contrast-weighted scale index method was used to establish a model to evaluate the grade of coal cleanliness and its regional distribution in the main coal seam(No.13-1)The results showed that:(1)The contents of Cr,Mn and Ni in the coal seam are relatively high and the average values are greater than 20μg/g.The contents of Se and Hg are at a high level while most other trace elements are at normal levels.(2)The cleanliness grade of the coal seam is mainly grade III-IV,which corresponds to a relatively good-medium coal cleanliness grade.However,some parts of the seam are at grade V(relatively poor coal cleanliness).(3)Coal of relatively good cleanliness grade(grade III)is distributed mainly in the regions corresponding to the Zhuji-Dingji-Gubei coal mines and in the eastern periphery of the Panji coal mine.Coal of medium cleanliness(grade IV)is distributed mainly in the regions of the Panji-Xiejiaji and Kouzidong coalmines.Relatively poor grade coal(grade V)is distributed in the southwest regions of the coalfield and the contents of Cr,As and Hg in coal collected from the relatively poor coal cleanliness regions often exceed the regulatory standards for the maximum concentration limits.展开更多
A variety of dust control methods are often applied in coal mines,among which the application of wet scrubbers has proven to be an efficient technology for the removal of dust in airstreams,rather than diluting or con...A variety of dust control methods are often applied in coal mines,among which the application of wet scrubbers has proven to be an efficient technology for the removal of dust in airstreams,rather than diluting or confining the dust.In this paper,a wet scrubber design was developed.Based on a self-designed experimental test platform,the total dust concentration,respirable dust concentration,air volume,and average pressure drops of wet scrubbers with 12,16,20,and 24 blades were measured under different water intake conditions.The results show that the different water intake levels have only minimal effects on the air volume of the wet scrubbers.However,increased water intake had improved the dust removal efficiency of the wet scrubbers with the same number of blades.The wet scrubber with 16 blades was found to have the best dust removal efficiency at a water intake level of 1.35 m^(3)/h.Its total dust and respirable dust removal efficiency reached 96.81%and 95.59%,respectively.The air volume was 200.4 m^(3)/min,and the average pressure drop was determined to be 169.4 Pa.In addition,when the wet scrubber with 16 blades was applied in a coal preparation plant in China's Shanxi Province,it was observed that the total dust concentration had fallen below 8.1 mg/m^(3),and the respirable dust concentration had fallen below 5.9 mg/m^(3).Therefore,the results obtained in this research investigation provide important references for the use of wet scrubbers to improve coal production environmental conditions.展开更多
In the present study,a numerical simulation method was adopted in order to examine the characteristics of dust dispersion during continuous dust release periods(CRP)and stop dust release periods(SRP).The purpose was t...In the present study,a numerical simulation method was adopted in order to examine the characteristics of dust dispersion during continuous dust release periods(CRP)and stop dust release periods(SRP).The purpose was to analyze the dust distributions and migration actions around road-header drivers in excavation roadways,and then determine effective dust control measures for underground coal mines.This study’s simulation results showed that the dust concentrations continuously increased,and then gradually reached a stability level during the CRP.During that time,the locations of the drivers were always at the intersection of the original migration dust and the backflow dust,and the drivers were invaded by these two strands dust.However,during the SRP,the dust concentrations gradually decreased under the actions of the roadway ventilation.Besides,obvious backflow phenomena were observed around the road-header during the SRP.The locations of the drivers were still within the backflow paths of the high dust concentrations.At the present time,dust separation and extraction systems have been implemented in coal mines,including vacuuming and air knife devices,which are designed to control the dust around the road-header drivers.The field applications of these systems were conducted in the 26 mechanized excavation faces of the Zhangcun Coal Mine.The results revealed that the use of these dust removal systems could effectively reduce the dust concentrations around the road-header drivers.In the present study,the dust removal rates during the CRP and SRP were determined to reach up to 88.7% and 94.6%,respectively.Therefore,the results of this research study provided effective theoretical guidance of the characteristics of dust distributions in coal mines,and introduced effective control methods for the hazardous dust concentrations around road-header drivers during the excavation process.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.52304314 and U23A20602)the Leading Talents of S&T Innovation of Hunan Province,China(No.2021RC4002)+2 种基金the Open Foundation of State Key Laboratory of Mineral Processing(No.BGRIMM-KJSKL-2024-16)the Open Foundation of Key Laboratory of Green Separation and Enrichment of Strategic Metal Mineral Resources(No.2023-02)the Fundamental Research Funds for the Central Universities of Central South University(No.2024ZZTS0008).
文摘Flotation is the most common method to obtain concentrate through the selective adsorption of collectors on target minerals to make them hydrophobic and floatable.In the hydrometallurgy of concentrate,collectors adsorbed on concentrate can damage ion-exchange resin and increase the chemical oxygen demand(COD)value of wastewater.In this work,we proposed a new scheme,i.e.,desorbing the collectors from concentrate in ore dressing plant and reusing them in flotation flowsheet.Lead nitrate and benzohydroxamic acid(Pb-BHA)complex is a common collector in scheelite flotation.In this study,different physical(stirring or ultrasonic waves)and chemical(strong acid or alkali environment)methods for facilitating the desorption of Pb-BHA collector from scheelite concentrate were explored.Single-mineral desorption tests showed that under the condition of pulp pH 13 and ultrasonic treatment for 15 min,the highest desorption rates of Pb and BHA from the scheelite concentrate were 90.48%and 63.75%,respectively.Run-of-mine ore flotation tests revealed that the reuse of desorbed Pb and BHA reduced the collector dosage by 30%for BHA and 25%for Pb.The strong alkali environment broke the chemical bonds between Pb and BHA.The cavitation effect of ultrasonic waves effectively reduced the interaction intensity between Pb-BHA collector and scheelite surfaces.This method combining ultrasonic waves and strong alkali environment can effectively desorb the collectors from concentrate and provide“clean”scheelite concentrate for metallurgic plants;the reuse of desorbed collector in flotation flowsheet can reduce reagent cost for ore dressing plants.
基金the Key Research and Development Projects in Anhui Province(201904a07020071)the Science and Technology Project of the Department of Land and Resources of Anhui Province(2016-K-16)the Key Research and Development Projects in Anhui Province(1804a0802198).
文摘Based on analysis of a large data set and supplementary sampling and analysis for hazardous trace elements in coal samples from the Huainan Coalfield,a generalized contrast-weighted scale index method was used to establish a model to evaluate the grade of coal cleanliness and its regional distribution in the main coal seam(No.13-1)The results showed that:(1)The contents of Cr,Mn and Ni in the coal seam are relatively high and the average values are greater than 20μg/g.The contents of Se and Hg are at a high level while most other trace elements are at normal levels.(2)The cleanliness grade of the coal seam is mainly grade III-IV,which corresponds to a relatively good-medium coal cleanliness grade.However,some parts of the seam are at grade V(relatively poor coal cleanliness).(3)Coal of relatively good cleanliness grade(grade III)is distributed mainly in the regions corresponding to the Zhuji-Dingji-Gubei coal mines and in the eastern periphery of the Panji coal mine.Coal of medium cleanliness(grade IV)is distributed mainly in the regions of the Panji-Xiejiaji and Kouzidong coalmines.Relatively poor grade coal(grade V)is distributed in the southwest regions of the coalfield and the contents of Cr,As and Hg in coal collected from the relatively poor coal cleanliness regions often exceed the regulatory standards for the maximum concentration limits.
基金supported by the Shanxi Province Colleges and Universities Science and Technology Achievement Transformation and Cultivation Project(2020CG008).
文摘A variety of dust control methods are often applied in coal mines,among which the application of wet scrubbers has proven to be an efficient technology for the removal of dust in airstreams,rather than diluting or confining the dust.In this paper,a wet scrubber design was developed.Based on a self-designed experimental test platform,the total dust concentration,respirable dust concentration,air volume,and average pressure drops of wet scrubbers with 12,16,20,and 24 blades were measured under different water intake conditions.The results show that the different water intake levels have only minimal effects on the air volume of the wet scrubbers.However,increased water intake had improved the dust removal efficiency of the wet scrubbers with the same number of blades.The wet scrubber with 16 blades was found to have the best dust removal efficiency at a water intake level of 1.35 m^(3)/h.Its total dust and respirable dust removal efficiency reached 96.81%and 95.59%,respectively.The air volume was 200.4 m^(3)/min,and the average pressure drop was determined to be 169.4 Pa.In addition,when the wet scrubber with 16 blades was applied in a coal preparation plant in China's Shanxi Province,it was observed that the total dust concentration had fallen below 8.1 mg/m^(3),and the respirable dust concentration had fallen below 5.9 mg/m^(3).Therefore,the results obtained in this research investigation provide important references for the use of wet scrubbers to improve coal production environmental conditions.
基金supported by the Shanxi Province Colleges and Universities Science and Technology Achievement Transformation and Cultivation Project(2020CG008).
文摘In the present study,a numerical simulation method was adopted in order to examine the characteristics of dust dispersion during continuous dust release periods(CRP)and stop dust release periods(SRP).The purpose was to analyze the dust distributions and migration actions around road-header drivers in excavation roadways,and then determine effective dust control measures for underground coal mines.This study’s simulation results showed that the dust concentrations continuously increased,and then gradually reached a stability level during the CRP.During that time,the locations of the drivers were always at the intersection of the original migration dust and the backflow dust,and the drivers were invaded by these two strands dust.However,during the SRP,the dust concentrations gradually decreased under the actions of the roadway ventilation.Besides,obvious backflow phenomena were observed around the road-header during the SRP.The locations of the drivers were still within the backflow paths of the high dust concentrations.At the present time,dust separation and extraction systems have been implemented in coal mines,including vacuuming and air knife devices,which are designed to control the dust around the road-header drivers.The field applications of these systems were conducted in the 26 mechanized excavation faces of the Zhangcun Coal Mine.The results revealed that the use of these dust removal systems could effectively reduce the dust concentrations around the road-header drivers.In the present study,the dust removal rates during the CRP and SRP were determined to reach up to 88.7% and 94.6%,respectively.Therefore,the results of this research study provided effective theoretical guidance of the characteristics of dust distributions in coal mines,and introduced effective control methods for the hazardous dust concentrations around road-header drivers during the excavation process.
