A number of synergistic solvent extraction （SSX） systems have been developed to recover nickel, cobalt, zinc and copper from sulphuric and chloride leach solutions by the solvent extraction team of CSIRO, Australia....A number of synergistic solvent extraction （SSX） systems have been developed to recover nickel, cobalt, zinc and copper from sulphuric and chloride leach solutions by the solvent extraction team of CSIRO, Australia. These in- clude （1） Versatic 10/CLXS0 system for the separation of Ni from Ca in sulphate solutions, （2） Versatic 10/4PC system for the separation of Ni and Co from Mn/Mg/Ca in sulphate solutions, （3） Cyanex 471X/HRJ-4277 system for the separation of Zn from Cd in sulphate solutions, （4） Versatic 10/LIX63 system for the separation of Co from Mn/Mg/Ca in sulphate solutions, （5） Versatic 10/LIX63/TBP system for separation of Ni and Co from Mn/Mg/Ca in sulphate solutions, （6） Versatic 10/LIX63 system for the separation of cobalt from nickel in sulphate solutions by difference in kinetics, （7） Cyanex 272/LIX84 system for the separation of Cu/Fe/Zn from Ni/Co in sulphate solutions, （8） Versatic 10/LIX63fFBP system to recover Cu/Ni from strong chloride solutions, and [9） Versatic 10/LIX63 system to separate Cu from Fe in strong chloride solutions. The synergistic effect on metal separation and efficiency is presented and possible industrial applications are demonstrated. The chemical stability of selected SSX systems is also reported.展开更多
Proterozoic （pre-Ediacaran） glaciations occurred under strongly seasonal climates near sea level in low palaeolatitudes. Metre-scale primary sand wedges in Cryogenian periglacial deposits are identical to those acti...Proterozoic （pre-Ediacaran） glaciations occurred under strongly seasonal climates near sea level in low palaeolatitudes. Metre-scale primary sand wedges in Cryogenian periglacial deposits are identical to those actively forming, through the infilling of seasonal （winter） thermal contraction-cracks in perma- frost by windblown sand, in present-day polar regions with a mean monthly air temperature range of 40 ~C and mean annual air temperatures of -20 ~C or lower. Varve-like rhythmites with dropstones in Proterozoic glacial successions are consistent with an active seasonal freeze-thaw cycle. The seasonal （annual） oscillation of sea level recorded by tidal rhythmites in Cryogenian glacial successions indicates a significant seasonal cycle and extensive open seas. Palaeomagnetic data determined directly for Prote- rozoic glacial deposits and closely associated rocks indicate low palaeolatitudes： Cryogenian deposits in South Australia accumulated at 〈10% most other Cryogenian deposits at 〈20~ and Palaeoproterozoic deposits at 〈15~ palaeolatitude. Palaeomagnetic data imply that the Proterozoic geomagnetic field approximated a geocentric axial dipole, hence palaeolatitudes represent geographic latitudes. The Cry- ogenian glacial environment included glacier-flee, continental permafrost regions with ground frozen on a kyr time-scale, aeolian sand-sheets, extensive and long-lived open seas, and an active hydrological cycle. This palaeoenvironment confiicts with the ＇snowball Earth＇ and ＇slushball Earth＇ hypotheses, which cannot accommodate large seasonal changes of temperature near the equator. Consequently, their proponents have attempted to refute the evidence for strong seasonality by introducing Popperian ＇auxiliary assumptions＇. However, non-actualistic arguments that the Cryogenian sand wedges indicate diurnal or weakly seasonal temperature changes are based on misunderstandings of periglacial pro- cesses. Modelling of a strongly seasonal climate for a frozen-over Earth is invalidated by the evidence for persistent open seas and glacier-free continental regions during Cryogenian glaciations, and gives a mean monthly air temperature range of only 〈10 ~C for 〈10~ latitude. By contrast, a strongly seasonal climate in low palaeolatitudes, based on the actualistic interpretation of cryogenic sand wedges and other structures, is consistent with a high obliquity of the ecliptic （〉54°） during Proterozoic low-latitude glaciations, whereby the equator would be cooler than the poles, on average, and global seasonality would be greatly amplified.展开更多
An abundance of data from seismic and geodetic monitoring has provided new insight into dyke propagation and emplacement mechanisms.These studies show that faulting and fracturing is part of the magma
We show the presence of fractal ordering of copper grade in bore core data at short range in the Cadia Ridgeway porphyry deposit and measure its persistence after mining by monitoring the output of the mine every 20 s...We show the presence of fractal ordering of copper grade in bore core data at short range in the Cadia Ridgeway porphyry deposit and measure its persistence after mining by monitoring the output of the mine every 20 s for a month using a large scale, zero field magnetic resonance sensor. A simple model is used to investigate this connection and its consequences for sorting of the ore. Fractal distributions, and their associated power laws, have two features highly favourable for segregating ore： a large proportion of low-grade pods and the large scale spatial clustering of grade.展开更多
文摘A number of synergistic solvent extraction （SSX） systems have been developed to recover nickel, cobalt, zinc and copper from sulphuric and chloride leach solutions by the solvent extraction team of CSIRO, Australia. These in- clude （1） Versatic 10/CLXS0 system for the separation of Ni from Ca in sulphate solutions, （2） Versatic 10/4PC system for the separation of Ni and Co from Mn/Mg/Ca in sulphate solutions, （3） Cyanex 471X/HRJ-4277 system for the separation of Zn from Cd in sulphate solutions, （4） Versatic 10/LIX63 system for the separation of Co from Mn/Mg/Ca in sulphate solutions, （5） Versatic 10/LIX63/TBP system for separation of Ni and Co from Mn/Mg/Ca in sulphate solutions, （6） Versatic 10/LIX63 system for the separation of cobalt from nickel in sulphate solutions by difference in kinetics, （7） Cyanex 272/LIX84 system for the separation of Cu/Fe/Zn from Ni/Co in sulphate solutions, （8） Versatic 10/LIX63fFBP system to recover Cu/Ni from strong chloride solutions, and [9） Versatic 10/LIX63 system to separate Cu from Fe in strong chloride solutions. The synergistic effect on metal separation and efficiency is presented and possible industrial applications are demonstrated. The chemical stability of selected SSX systems is also reported.
文摘Proterozoic （pre-Ediacaran） glaciations occurred under strongly seasonal climates near sea level in low palaeolatitudes. Metre-scale primary sand wedges in Cryogenian periglacial deposits are identical to those actively forming, through the infilling of seasonal （winter） thermal contraction-cracks in perma- frost by windblown sand, in present-day polar regions with a mean monthly air temperature range of 40 ~C and mean annual air temperatures of -20 ~C or lower. Varve-like rhythmites with dropstones in Proterozoic glacial successions are consistent with an active seasonal freeze-thaw cycle. The seasonal （annual） oscillation of sea level recorded by tidal rhythmites in Cryogenian glacial successions indicates a significant seasonal cycle and extensive open seas. Palaeomagnetic data determined directly for Prote- rozoic glacial deposits and closely associated rocks indicate low palaeolatitudes： Cryogenian deposits in South Australia accumulated at 〈10% most other Cryogenian deposits at 〈20~ and Palaeoproterozoic deposits at 〈15~ palaeolatitude. Palaeomagnetic data imply that the Proterozoic geomagnetic field approximated a geocentric axial dipole, hence palaeolatitudes represent geographic latitudes. The Cry- ogenian glacial environment included glacier-flee, continental permafrost regions with ground frozen on a kyr time-scale, aeolian sand-sheets, extensive and long-lived open seas, and an active hydrological cycle. This palaeoenvironment confiicts with the ＇snowball Earth＇ and ＇slushball Earth＇ hypotheses, which cannot accommodate large seasonal changes of temperature near the equator. Consequently, their proponents have attempted to refute the evidence for strong seasonality by introducing Popperian ＇auxiliary assumptions＇. However, non-actualistic arguments that the Cryogenian sand wedges indicate diurnal or weakly seasonal temperature changes are based on misunderstandings of periglacial pro- cesses. Modelling of a strongly seasonal climate for a frozen-over Earth is invalidated by the evidence for persistent open seas and glacier-free continental regions during Cryogenian glaciations, and gives a mean monthly air temperature range of only 〈10 ~C for 〈10~ latitude. By contrast, a strongly seasonal climate in low palaeolatitudes, based on the actualistic interpretation of cryogenic sand wedges and other structures, is consistent with a high obliquity of the ecliptic （〉54°） during Proterozoic low-latitude glaciations, whereby the equator would be cooler than the poles, on average, and global seasonality would be greatly amplified.
文摘An abundance of data from seismic and geodetic monitoring has provided new insight into dyke propagation and emplacement mechanisms.These studies show that faulting and fracturing is part of the magma
基金Newcrest Mining Limited for funding the project and allowing publication of the data
文摘We show the presence of fractal ordering of copper grade in bore core data at short range in the Cadia Ridgeway porphyry deposit and measure its persistence after mining by monitoring the output of the mine every 20 s for a month using a large scale, zero field magnetic resonance sensor. A simple model is used to investigate this connection and its consequences for sorting of the ore. Fractal distributions, and their associated power laws, have two features highly favourable for segregating ore： a large proportion of low-grade pods and the large scale spatial clustering of grade.
