Perovskite solar cells have aroused a worldwide research upsurge in recent years due to their soaring photovoltaic performance,ease of solution processing,and low cost.The power conversion efficiency record is constan...Perovskite solar cells have aroused a worldwide research upsurge in recent years due to their soaring photovoltaic performance,ease of solution processing,and low cost.The power conversion efficiency record is constantly being broken and has recently reached 26.1%in the lab,which is comparable to the established photovoltaic technologies such as crystalline silicon,copper indium gallium selenide and cadmium telluride(CdTe)solar cells.Currently,perovskite solar cells are standing at the entrance of industrialization,where huge opportunities and risks coexist.However,towards commercialization,challenges of up-scaling,stability and lead toxicity still remain,the proper handling of which could potentially lead to the widespread adoption of perovskite solar cells as a low-cost and efficient source of renewable energy.This review gives a holistic analysis of the path towards commercialization for perovskite solar cells.A comprehensive overview of the current state-of-the-art level for perovskite solar cells and modules will be introduced first,with respect to the module efficiency,stability and current status of industrialization.We will then discuss the challenges that get in the way of commercialization and the corresponding strategies to address them,involving the upscaling,the stability and the lead toxicity issue.Insights into the future direction of commercialization of perovskite photovoltaics was also provided,including the flexible perovskite cells and modules and perovskite indoor photovoltaics.Finally,the future perspectives towards commercialization are put forward.展开更多
In this study, a quaternary blending strategy was applied in the fabrication of organic photovoltaic devices and large-area modules. As a result, the ultimate quaternary organic solar cells(OSCs) deliver 16.71% effici...In this study, a quaternary blending strategy was applied in the fabrication of organic photovoltaic devices and large-area modules. As a result, the ultimate quaternary organic solar cells(OSCs) deliver 16.71% efficiency for small-area devices and 13.25% for large-area(19.34 cm2) modules(certified as 12.36%), which is one of the highest efficiencies for organic solar modules to date. Our results have proved the synergistic effects of multiple components in OSCs, providing an effective strategy for achieving high-performance organic photovoltaic devices and modules.展开更多
The interfacial properties between charge transporting material and perovskite(PVSK)play critical roles in governing the photovoltaic performances of perovskite solar cells(PVSCs).Herein,we develop a multifunctional f...The interfacial properties between charge transporting material and perovskite(PVSK)play critical roles in governing the photovoltaic performances of perovskite solar cells(PVSCs).Herein,we develop a multifunctional fulleropyrrolidine(FMG)as an electron transporting material(ETM),which facilitates the construction of efficient and stable inverted PVSCs and modules.It revealed that the facile and scalable FMG possesses not only excellent electron extraction capabilities,but also multi-groups to simultaneously passivate PVSKs via Lewis acid-base and hydrogen bonding interactions.The coating of FMG onto PVSK interestingly yields a dense and interactive layer with the graded ETM-PVSK heterojunction architecture.As a result,FMGbased PVSCs demonstrate a champion efficiency of 23.8%,outperforming 21.0%of PCBM-based devices.FMG could also be utilized to improve photovoltaic performance of large-scale modules.In addition,FMG has successfully elongated the lifetime of the corresponding PVSCs,maintaining 85%of the initial performance after the continuous 60-day one sun equivalent illumination in ambient.展开更多
基金the National Key Research and Development Program of China(2022YFB3803300 and 2023YFE0116800)Beijing Natural Science Foundation(IS23037).
文摘Perovskite solar cells have aroused a worldwide research upsurge in recent years due to their soaring photovoltaic performance,ease of solution processing,and low cost.The power conversion efficiency record is constantly being broken and has recently reached 26.1%in the lab,which is comparable to the established photovoltaic technologies such as crystalline silicon,copper indium gallium selenide and cadmium telluride(CdTe)solar cells.Currently,perovskite solar cells are standing at the entrance of industrialization,where huge opportunities and risks coexist.However,towards commercialization,challenges of up-scaling,stability and lead toxicity still remain,the proper handling of which could potentially lead to the widespread adoption of perovskite solar cells as a low-cost and efficient source of renewable energy.This review gives a holistic analysis of the path towards commercialization for perovskite solar cells.A comprehensive overview of the current state-of-the-art level for perovskite solar cells and modules will be introduced first,with respect to the module efficiency,stability and current status of industrialization.We will then discuss the challenges that get in the way of commercialization and the corresponding strategies to address them,involving the upscaling,the stability and the lead toxicity issue.Insights into the future direction of commercialization of perovskite photovoltaics was also provided,including the flexible perovskite cells and modules and perovskite indoor photovoltaics.Finally,the future perspectives towards commercialization are put forward.
基金National Key Research and Development Program of China (2017YFA0207700)National Key Research and Development Program of Zhejiang Province(2018C04SA170313)+1 种基金Outstanding Youth Fund of Natural Science Foundation of Zhejiang (LR18F050001)National Natural Science Foundation of China (61705194, 61804134)。
文摘In this study, a quaternary blending strategy was applied in the fabrication of organic photovoltaic devices and large-area modules. As a result, the ultimate quaternary organic solar cells(OSCs) deliver 16.71% efficiency for small-area devices and 13.25% for large-area(19.34 cm2) modules(certified as 12.36%), which is one of the highest efficiencies for organic solar modules to date. Our results have proved the synergistic effects of multiple components in OSCs, providing an effective strategy for achieving high-performance organic photovoltaic devices and modules.
基金supported by the National Natural Science Foundation of China(22125901,51961145301)the National Key Research and Development Program of China(2019YFA0705900)the Fundamental Research Funds for the Central Universities。
文摘The interfacial properties between charge transporting material and perovskite(PVSK)play critical roles in governing the photovoltaic performances of perovskite solar cells(PVSCs).Herein,we develop a multifunctional fulleropyrrolidine(FMG)as an electron transporting material(ETM),which facilitates the construction of efficient and stable inverted PVSCs and modules.It revealed that the facile and scalable FMG possesses not only excellent electron extraction capabilities,but also multi-groups to simultaneously passivate PVSKs via Lewis acid-base and hydrogen bonding interactions.The coating of FMG onto PVSK interestingly yields a dense and interactive layer with the graded ETM-PVSK heterojunction architecture.As a result,FMGbased PVSCs demonstrate a champion efficiency of 23.8%,outperforming 21.0%of PCBM-based devices.FMG could also be utilized to improve photovoltaic performance of large-scale modules.In addition,FMG has successfully elongated the lifetime of the corresponding PVSCs,maintaining 85%of the initial performance after the continuous 60-day one sun equivalent illumination in ambient.
