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Low-temperature fabrication of high-specific strength SiC-based ceramics via photopolymerization 3D printing with controllable anisotropy
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作者 Piao Qu Guozhen Liang +5 位作者 M Irfan Hussain Muhammad Hanif Muhammad Hamza Kaibin Huang Yan Lou Zhangwei Chen 《International Journal of Extreme Manufacturing》 2025年第5期275-292,共18页
The combination of silicon carbide(SiC)ceramics and stereolithography technology shows promise for manufacturing complex-shaped SiC components,expanding application possibilities.However,high sintering temperature and... The combination of silicon carbide(SiC)ceramics and stereolithography technology shows promise for manufacturing complex-shaped SiC components,expanding application possibilities.However,high sintering temperature and structural-performance anisotropy limit the practical use of 3D-printed SiC components.Herein,a novel method is introduced to produce high-specific-strength SiC-based ceramics at a relatively low temperature of 1100℃.A mixed SiC/SiO_(2) slurry(30%SiO_(2) and 70%SiC by volume)with a solid loading of up to 40%was prepared to improve UV light penetration and printability.Additionally,incorporating a high content of methyl-phenyl-polysiloxane(PSO)solution(75%by weight)enabled low-temperature pyrolysis of SiC/SiO_(2)/PSO ceramics.The SiC/SiO_(2)/PSO ceramic lattices after pyrolysis achieved a specific strength as high as(1.03×10^(5))N·m·kg^(-1) and a density of 1.75 g·cm^(-3),outperforming similar SiC-based lattices structures of similar porosities.The bending strength of(95.49±8.79)MPa was comparable to that of ceramics sintered at 1400℃ or higher.Notably,the addition of the silicon carbide oxide(SiOC)phase reduced anisotropy,lowering the transverse and longitudinal compression strength ratios from 1.87 to 1.08,and improving mechanical properties by 79%.This improvement is attributed to SiOC shrinkage,promoting a uniform distribution of sintered components,resulting in a more robust and balanced material structure.This method offers valuable insight into the additive manufacturing(AM)of SiC-based ceramics at lower temperatures and provides new guidance for controlling anisotropy in 3D-printed ceramic parts. 展开更多
关键词 silicon carbide vat photopolymerization 3D printing POLYSILOXANE anisotropy compensation
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Tensile mechanical behavior of additively manufactured 316L austenitic stainless steels in liquid lead-bismuth eutectic and in air
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作者 WEN Tao ZHONG Zhi-huai +6 位作者 ZHU Sai-sai ZHOU Man-man WANG Pei CHAI Lin-jiang LIU Guo-qing PANG Bo GONG Xing 《Journal of Central South University》 2025年第8期2823-2840,共18页
In this work,tensile mechanical behavior of 316L steels fabricated by three different processing methods(casting,powder extrusion printing(PEP)and laser powder bed fusion(LPBF))was studied in the presence of liquid le... In this work,tensile mechanical behavior of 316L steels fabricated by three different processing methods(casting,powder extrusion printing(PEP)and laser powder bed fusion(LPBF))was studied in the presence of liquid lead-bismuth eutectic(LBE)and air at 350℃.The results show that all three steels tested in LBE are not subjected to evident degradation of tensile elongation to failure and strength compared to those tested in air,suggesting that LME does not occur regardless of the processing methods.The LPBF 316L steel exhibits the highest yield strength(420-435 MPa),followed by casting 316 L(~242 MPa)and PEP 316L(146-165 MPa).Ultimate tensile strength of three steels is comparable and ranges from 427 to 485 MPa.The PEP and casting 316L steels have similar total elongation to failure(i.e.,40.0%-43.8%),whereas this property decreases markedly to 18.6%-19.5% for the LPBF 316 L steel.The superior strength and relatively low ductility of the LPBF 316L steel can be attributed to nanosized dislocations trapped at cell structures which can produce a remarkable strengthening effect to the steel matrix.By contrast,due to massive residual micropores,the PEP 316L steel has the lowest strength. 展开更多
关键词 316L steel liquid lead-bismuth eutectic tensile properties powder extrusion printing laser powder bed fusion
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A review for design,mechanism,fabrication,and application of magnetically responsive microstructured functional surface
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作者 Jian Wang Xingyi Song +8 位作者 Chaochao Wang Yumei Zhou Ri Chen Yong Yang Bin Liu Yihao Zheng Hui Li Wei Zhou Lelun Jiang 《International Journal of Extreme Manufacturing》 2025年第1期96-128,共33页
Magnetically responsive microstructured functional surface(MRMFS),capable of dynamically and reversibly switching the surface topography under magnetic actuation,provides a wireless,noninvasive,and instantaneous way t... Magnetically responsive microstructured functional surface(MRMFS),capable of dynamically and reversibly switching the surface topography under magnetic actuation,provides a wireless,noninvasive,and instantaneous way to accurately control the microscale engineered surface.In the last decade,many studies have been conducted to design and optimize MRMFSs for diverse applications,and significant progress has been accomplished.This review comprehensively presents recent advancements and the potential prospects in MRMFSs.We first classify MRMFSs into one-dimensional linear array MRMFSs,two-dimensional planar array MRMFSs,and dynamic self-assembly MRMFSs based on their morphology.Subsequently,an overview of three deformation mechanisms,including magnetically actuated bending deformation,magnetically driven rotational deformation,and magnetically induced self-assembly deformation,are provided.Four main fabrication strategies employed to create MRMFSs are summarized,including replica molding,magnetization-induced self-assembly,laser cutting,and ferrofluid-infused method.Furthermore,the applications of MRMFS in droplet manipulation,solid transport,information encryption,light manipulation,triboelectric nanogenerators,and soft robotics are presented.Finally,the challenges that limit the practical applications of MRMFSs are discussed,and the future development of MRMFSs is proposed. 展开更多
关键词 functional surfaces MICROSTRUCTURES magnetic actuation MANIPULATION
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Gd_(3)Ga_(5)O_(12):A wide bandgap semiconductor electrolyte for ceramic fuel cells,effective at temperatures below 500℃
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作者 Junjiao Li Muhammad Yousaf +10 位作者 Jahangeer Ahmed Bushra Bibi Asma Noor Norah Alhokbany Muhammad Sajid Atif Nazar M.A.K.Yousaf Shah Xiaofeng Guo Xiangqin Ding Naveed Mushtaq Yuzheng Lu 《Journal of Rare Earths》 2025年第10期2248-2256,I0007,共10页
Searching for compatible electrolytes with Ni_(0.8)C_(00.15)Al_(0.05)LiO_(2-δ)(NCAL)electrodes that exhibit high ionic conductivity at low operational temperatures(<550℃)is crucial for advancing ceramics fuel cel... Searching for compatible electrolytes with Ni_(0.8)C_(00.15)Al_(0.05)LiO_(2-δ)(NCAL)electrodes that exhibit high ionic conductivity at low operational temperatures(<550℃)is crucial for advancing ceramics fuel cells(CFCs)research.In this work,the experimental and theoretical analyses demonstrate that the highly stable single-phase Gd_(3)Ga_(5)O_(12)(GGO)garnet structure,composed of Gd-O octahedrons and Ga-O tetrahedrons,provides more active sites for ion transport,resulting in enhanced peak power density(PPD)and stable open circuit voltage(OCV)at low operational temperatures.The unique internal garnet structure effectively reduces the interfacial impedance of the prepared fuel cell device,provides more active sites at triple-phase boundarie region,and increases the electrochemical stability.As a result,the constructed fuel cell device can deliver a superior peak power density of 770 mW/cm^(2)at 490℃.In addition,X-ray photoelectron spectroscopy,electrochemical impedance spectroscopy,and theoretical calculations further demonstrate electrolyte effectiveness of GGO,enabling stable an OCV even at a low temperature of 370℃under a H_(2)/air environment.This work contributes to a deeper understanding of the underlying mechanisms of a single-layer fuel cell device,which is essential for advancing this promising energy technology,even at a very low temperature of 370℃. 展开更多
关键词 Garnet structure Wide bandgap Solid oxide fuel cells Low temperature Oxygen ions transport Rare earths
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Meyer Wavelet Transform and Jaccard Deep Q Net for Small Object Classification Using Multi-Modal Images
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作者 Mian Muhammad Kamal Syed Zain Ul Abideen +7 位作者 MAAl-Khasawneh Alaa MMomani Hala Mostafa Mohammed Salem Atoum Saeed Ullah Jamil Abedalrahim Jamil Alsayaydeh Mohd Faizal Bin Yusof Suhaila Binti Mohd Najib 《Computer Modeling in Engineering & Sciences》 2025年第9期3053-3083,共31页
Accurate detection of small objects is critically important in high-stakes applications such as military reconnaissance and emergency rescue.However,low resolution,occlusion,and background interference make small obje... Accurate detection of small objects is critically important in high-stakes applications such as military reconnaissance and emergency rescue.However,low resolution,occlusion,and background interference make small object detection a complex and demanding task.One effective approach to overcome these issues is the integration of multimodal image data to enhance detection capabilities.This paper proposes a novel small object detection method that utilizes three types of multimodal image combinations,such as Hyperspectral-Multispectral(HSMS),Hyperspectral-Synthetic Aperture Radar(HS-SAR),and HS-SAR-Digital Surface Model(HS-SAR-DSM).The detection process is done by the proposed Jaccard Deep Q-Net(JDQN),which integrates the Jaccard similarity measure with a Deep Q-Network(DQN)using regression modeling.To produce the final output,a Deep Maxout Network(DMN)is employed to fuse the detection results obtained from each modality.The effectiveness of the proposed JDQN is validated using performance metrics,such as accuracy,Mean Squared Error(MSE),precision,and Root Mean Squared Error(RMSE).Experimental results demonstrate that the proposed JDQN method outperforms existing approaches,achieving the highest accuracy of 0.907,a precision of 0.904,the lowest normalized MSE of 0.279,and a normalized RMSE of 0.528. 展开更多
关键词 Small object detection MULTIMODALITY deep learning jaccard deep Q-net deep maxout network
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Additive manufacturing of metals:Microstructure evolution and multistage control 被引量:63
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作者 Zhiyuan Liu Dandan Zhao +5 位作者 Pei Wang Ming Yan Can Yang Zhangwei Chen Jian Lu Zhaoping Lu 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2022年第5期224-236,共13页
As a revolutionary industrial technology,additive manufacturing creates objects by adding materials layer by layer and hence can fabricate customized components with an unprecedented degree of freedom.For metallic mat... As a revolutionary industrial technology,additive manufacturing creates objects by adding materials layer by layer and hence can fabricate customized components with an unprecedented degree of freedom.For metallic materials,unique hierarchical microstructures are constructed during additive manufacturing,which endow them with numerous excellent properties.To take full advantage of additive manufacturing,an in-depth understanding of the microstructure evolution mechanism is required.To this end,this review explores the fundamental procedures of additive manufacturing,that is,the formation and binding of melt pools.A comprehensive processing map is proposed that integrates melt pool energy-and geometry-related process parameters together.Based on it,additively manufactured microstructures are developed during and after the solidification of constituent melt pool.The solidification structures are composed of primary columnar grains and fine secondary phases that form along the grain boundaries.The post-solidification structures include submicron scale dislocation cells stemming from internal residual stress and nanoscale precipitates induced by intrinsic heat treatment during cyclic heating of adjacent melt pool.Based on solidification and dislocation theories,the formation mechanisms of the multistage microstructures are thoroughly analyzed,and accordingly,multistage control methods are proposed.In addition,the underlying atomic scale structural features are briefly discussed.Furthermore,microstructure design for additive manufacturing through adjustment of process parameters and alloy composition is addressed to fulfill the great potential of the technique.This review not only builds a solid microstructural framework for metallic materials produced by additive manufacturing but also provides a promising guideline to adjust their mechanical properties. 展开更多
关键词 Additive manufacturing Metallic materials Melt pool Processing map Microstructure evolution
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Current and further trajectories in designing functional materials for solid oxide electrochemical cells:A review of other reviews 被引量:5
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作者 Stanislav Baratov Elena Filonova +6 位作者 Anastasiya Ivanova Muhammad Bilal Hanif Muneeb Irshad Muhammad Zubair Khan Martin Motola Sajid Rauf Dmitry Medvedev 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第7期302-331,共30页
Complex oxides are an important class of materials with enormous potential for electrochemical appli-cations.Depending on their composition and structure,such complex oxides can exhibit either a single conductivity(ox... Complex oxides are an important class of materials with enormous potential for electrochemical appli-cations.Depending on their composition and structure,such complex oxides can exhibit either a single conductivity(oxygen-ionic or protonic,or n-type,or p-type electronic)or a combination thereof gener-ating distinct dual-conducting or even triple-conducting materials.These properties enable their use as diverse functional materials for solid oxide fuel cells,solid oxide electrolysis cells,permeable membranes,and gas sensors.The literature review shows that the field of solid oxide materials and related electro-chemical cells has a significant level of research engagement,with over 8,000 publications published since 2020.The manual analysis of such a large volume of material is challenging.However,by examining the review articles,it is possible to identify key patterns,recent achievements,prospects,and remaining obstacles.To perform such an analysis,the present article provides,for the first time,a comprehensive summary of previous review publications that have been published since 2020,with a special focus on solid oxide materials and electrochemical systems.Thus,this study provides an important reference for researchers specializing in the fields of solid state ionics,high-temperature electrochemistry,and energyconversiontechnologies. 展开更多
关键词 SOFCS SOECs PCFCS ELECTROCHEMISTRY Energy conversion Hydrogen energy Carbon neutrality
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Review on the Fabrication of Surface Functional Structures for Enhancing Bioactivity of Titanium and Titanium Alloy Implants 被引量:1
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作者 Heng Tang Jiaxiang Xu +4 位作者 Bin Guo Yansong Xie Yalong Sun Yanjun Lu Yong Tang 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2024年第4期23-49,共27页
Titanium and its alloys have been widely applied in many biomedical fields because of its excellent mechanical properties,corrosion resistance and good biocompatibility.However,problems such as rejection,shedding and ... Titanium and its alloys have been widely applied in many biomedical fields because of its excellent mechanical properties,corrosion resistance and good biocompatibility.However,problems such as rejection,shedding and infection will occur after titanium alloy implantation due to the low biological activity of titanium alloy surface.The structures with specific functions,which can enhance osseointegration and antibacterial properties,are fabricated on the surface of titanium implants to improve the biological activity between the titanium implants and human tissues.This paper presents a comprehensive review of recent developments and applications of surface functional structure in titanium and titanium alloy implants.The applications of surface functional structure on different titanium and titanium alloy implants are introduced,and their manufacturing technologies are summarized and compared.Furthermore,the fabrication of various surface functional structures used for titanium and titanium alloy implants is reviewed and analyzed in detail.Finally,the challenges affecting the development of surface functional structures applied in titanium and titanium alloy implants are outlined,and recommendations for future research are presented. 展开更多
关键词 Surface functional structure Titanium implant Manufacturing technology Bioactivity
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Progress on the glassy-crystal laminates:From design,microstructure to deformation and future solutions 被引量:1
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作者 Yu Chen Ronggao Cui +1 位作者 Jun Shen Gang Wang 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2024年第5期113-144,共32页
The development of new design strategies to create innovative structural materials,refine existing ones,and achieves compatible combinations of strength and plasticity remains a worldwide goal.Promising alloys,such as... The development of new design strategies to create innovative structural materials,refine existing ones,and achieves compatible combinations of strength and plasticity remains a worldwide goal.Promising alloys,such as shape memory alloys(SMAs),bulk metallic glasses(BMGs),high entropy alloys(HEAs),and heterogeneous pure metals such as Cu,have excellent mechanical responses,but they still fall short of meeting all the requirements of structural materials due to specific flaws,such as lack of tensile de-formation for BMGs and low yielding strength for HEAs.To address these shortcomings,proposals such as integrating glassy matrices and crystallized alloys,such as HEAs/SMAs,have been suggested.However,these solutions have unresolved issues,such as the challenging control of B2 phase formation in BMG composites.Recently,glass-crystal(A/C)laminated alloys with alternating layers have been reported to exhibit improved mechanical properties and activated work-hardening behaviors,but they still face press-ing issues such as bonding interfaces and unknown deformation mechanisms.This review focuses on design routes such as the selection of alloy components and processing techniques,exploration of micro-structural evolution and deformation modes with an increase in strain,and future solutions to address pressing and unsolved issues.These prominent advantages include diversified deformation mechanisms,such as deformation twinning,martensitic phase transformation,and precipitation hardening,as well as tuned interactive reactions of shear bands(SBs)near the A/C interfaces.Thus,this review provides a promising pathway to design and develop structural materials in the materials field community. 展开更多
关键词 Glassy-crystal laminates Bulk metallic glasses High entropy alloys Shape memory alloys MICROSTRUCTURE Deformation mechanisms Future solutions
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Effect of Room Temperature Ultrasonic Vibration Compression on the Microstructure Evolution and Mechanical Properties of AZ91 Alloy 被引量:1
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作者 Ziyue Xu Huan Liu +7 位作者 Luyao Li Chao Sun Xi Tan Baishan Chen Qiangsheng Dong Yuna Wu Jinghua Jiang Jiang Ma 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2024年第7期1135-1146,共12页
To investigate the potential of direct ultrasonic vibration on improving the performance of magnesium alloys,this study first employed the ultrasonic vibration compression(UVC)on the solid solution treated AZ91 alloy,... To investigate the potential of direct ultrasonic vibration on improving the performance of magnesium alloys,this study first employed the ultrasonic vibration compression(UVC)on the solid solution treated AZ91 alloy,and explored its microstructure evolution and mechanical properties under UVC.Within only two seconds,the UVC alloys showed large deformation strains of 34.8–54.4%,and sudden increase of sample temperature to 243℃.Microstructure characterizations proved that UVC promoted the formation of abundant shear bands,fine grains,and the bimodal distribution of Mg17Al12 precipitates consisting of submicron particles located within the shear bands and nano-sized ones within the matrix.Owing to the unique microstructure,the micro-hardness(and nano-hardness)value of UVC alloy was increased by 37.7%(35%)when compared with the solution-treated alloy.Moreover,the nano-modulus of the developed AZ91 alloy was also significantly increased to 62 GPa by statistical nanoindentation tests,which could be ascribed to increased Mg_(17)Al_(12) precipitates and decreased c/a value to some extent.In general,this work provides a new insight into the design and preparation of high-performance magnesium alloys by UVC at room temperature. 展开更多
关键词 AZ91 alloys Ultrasonic vibration compression PRECIPITATION Shear bands Mechanical properties
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Practice of flow control and smart valves
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作者 Jin-yuan QIAN Wei WU +1 位作者 Min CHENG Jun-hui ZHANG 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2022年第4期243-246,共4页
Introduction The usual metaphors of“heart”and“throat”indi-cate the importance of pumps and valves in industrial systems including petroleum,chemical,metallurgy,aviation,and aerospace.With the continuous penetra-ti... Introduction The usual metaphors of“heart”and“throat”indi-cate the importance of pumps and valves in industrial systems including petroleum,chemical,metallurgy,aviation,and aerospace.With the continuous penetra-tion of the industrial internet,the miniaturization,digi-tization,multi-functionalization,and systemization of valves have become very important(Si et al.,2020;Chang et al.,2021;Pang et al.,2021;Bonilla et al.,2022;Yuan et al.,2022;Zhao et al.,2022). 展开更多
关键词 SMART INTERNET FLOW
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Micro-nano-fabrication of green functional materials by multiphase microfluidics for environmental and energy applications
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作者 Cheng Qi Tao Zhou +6 位作者 Xingjiang Wu Kailang Liu Lei Li Zhou Liu Zhuo Chen Jianhong Xu Tiantian Kong 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第8期1199-1219,共21页
Multiphase microfluidic has emerged as a powerful platform to produce novel materials with tailor-designed functionalities,as microfluidic fabrication provides precise controls over the size,component,and structure of... Multiphase microfluidic has emerged as a powerful platform to produce novel materials with tailor-designed functionalities,as microfluidic fabrication provides precise controls over the size,component,and structure of resultant materials.Recently,functional materials with well-defined micro-/nanostructures fabricated by microfluidics find important applications as environmental and energy materials.This review first illustrated in detail how different structures or shapes of droplet and jet templates are formed by typical configurations of microfluidic channel networks and multiphase flow systems.Subsequently,recent progresses on several representative energy and environmental applications,such as water purification,water collecting and energy storage,were overviewed.Finally,it is envisioned that integrating microfluidics and other novel materials will play increasing important role in contributing environmental remediation and energy storage in near future. 展开更多
关键词 MICROFLUIDICS Multi-phase flow Droplet and microfiber Environmental remediation Energy Storage
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Plasticity and rejuvenation of aged metallic glasses by ultrasonic vibrations
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作者 Zhe Chen Shuai Ren +8 位作者 Rui Zhao Jian Zhu Xin Li Heting Zhang Hongji Lin Jiahua Zhu Sajad Sohrabi Wenqing Ruan Jiang Ma 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2024年第14期231-239,共9页
Metallic glasses(MGs)possess exceptional properties,but their properties consistently deteriorate over time,thereby resulting in increased complexity in processing.It thus poses a formidable challenge to the forming o... Metallic glasses(MGs)possess exceptional properties,but their properties consistently deteriorate over time,thereby resulting in increased complexity in processing.It thus poses a formidable challenge to the forming of long-term aged MGs.Here,we report ultrasonic vibration(UV)loading can lead to large plas-ticity and strong rejuvenation in significantly aged MGs within 1 s.A large UV-induced plasticity(UVIP)of 80%height reduction can be achieved in LaNiAl MG samples aged at 85%of its glass transition tem-perature(0.85 T_(g))for a duration of up to 1 month.The energy threshold required for UVIP monotonously increases with aging time.After the UV loading process,the aged samples show strong rejuvenation,with the relaxation enthalpy even surpassing that of as-cast samples.These findings suggest that UV loading is an effective technique for forming and rejuvenating aged MGs simultaneously,providing an alterna-tive avenue to explore the interplay between the property and microstructures as well as expanding the application prospects of MGs. 展开更多
关键词 Metallic glass Ultrasonic vibration induced plasticity AGING REJUVENATION
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A plastic iron-based nanocrystalline alloy with high saturation magnetic flux density and low coercivity via flexible-annealing
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作者 Xuesong Li Rongce Sun +9 位作者 Dongyang Li Chengyue Song Jing Zhou Zhiyong Xue Chuntao Chang Baoan Sun Bo Zhang Haibo Ke Weihua Wang Haiyang Bai 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2024年第23期229-235,共7页
The traditional high-temperature annealing process is difficult to control the morphology and size of the crystallization phases in amorphous alloy systems with high ferromagnetic element content,lead-ing to mechanica... The traditional high-temperature annealing process is difficult to control the morphology and size of the crystallization phases in amorphous alloy systems with high ferromagnetic element content,lead-ing to mechanical brittleness and soft magnetic properties deterioration.Here,we developed a flexible-annealing technique and successfully achieved a fine nanocrystalline structure in a high-ferromagnetic-content system of(Fe_(0.8)Co_(0.2))_(85)Si_(2)B_(12)Cu_(0.8)Mo_(0.2).It is exciting that the(Fe_(0.8)Co_(0.2))_(85)Si_(2)B_(12)Cu_(0.8)Mo_(0.2) nanocrystalline alloy exhibits high Bs up to 1.88 T,low coercivity of 6.3 A m-1,as well as good plas-ticity.The excellent comprehensive properties are attributed to the controllable construction of di-luted amorphous-nanocrystalline structure,the rapid release of internal stress,and the suppression of relaxation-induced uniformity achieved by the flexible annealing process.The results provide a fast and new paradigm for the development of next-generation high-Bs soft magnetic materials. 展开更多
关键词 Nanocrystalline alloy Flexible annealing High saturation magnetic flux density Low coercivity PLASTIC
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Alternative Strategy for Development of Dielectric Calcium Copper Titanate‑Based Electrolytes for Low‑Temperature Solid Oxide Fuel Cells 被引量:1
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作者 Sajid Rauf Muhammad Bilal Hanif +8 位作者 Zuhra Tayyab Matej Veis MAKYousaf Shah Naveed Mushtaq Dmitry Medvedev Yibin Tian Chen Xia Martin Motola Bin Zhu 《Nano-Micro Letters》 SCIE EI CAS 2025年第1期310-332,共23页
The development of low-temperature solid oxide fuel cells(LT-SOFCs)is of significant importance for realizing the widespread application of SOFCs.This has stimulated a substantial materials research effort in developi... The development of low-temperature solid oxide fuel cells(LT-SOFCs)is of significant importance for realizing the widespread application of SOFCs.This has stimulated a substantial materials research effort in developing high oxide-ion conductivity in the electrolyte layer of SOFCs.In this context,for the first time,a dielectric material,CaCu_(3)Ti_(4)O_(12)(CCTO)is designed for LT-SOFCs electrolyte application in this study.Both individual CCTO and its heterostructure materials with a p-type Ni_(0.8)Co_(0.15)Al_(0.05)LiO_(2−δ)(NCAL)semiconductor are evaluated as alternative electrolytes in LT-SOFC at 450–550℃.The single cell with the individual CCTO electrolyte exhibits a power output of approximately 263 mW cm^(-2) and an open-circuit voltage(OCV)of 0.95 V at 550℃,while the cell with the CCTO–NCAL heterostructure electrolyte capably delivers an improved power output of approximately 605 mW cm^(-2) along with a higher OCV over 1.0 V,which indicates the introduction of high hole-conducting NCAL into the CCTO could enhance the cell performance rather than inducing any potential short-circuiting risk.It is found that these promising outcomes are due to the interplay of the dielectric material,its structure,and overall properties that led to improve electrochemical mechanism in CCTO–NCAL.Furthermore,density functional theory calculations provide the detailed information about the electronic and structural properties of the CCTO and NCAL and their heterostructure CCTO–NCAL.Our study thus provides a new approach for developing new advanced electrolytes for LT-SOFCs. 展开更多
关键词 LT-SOFCs Dielectric CaCu_(3)Ti_(4)O_(12) Semiconductor Ni_(0.8)Co_(0.15)Al_(0.05)LiO_(2−δ) Ionic conductivity Heterostructure electrolyte
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Enhanced magnetic properties in a Fe-based amorphous alloy via ultrasonic vibration rapid processing 被引量:1
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作者 Hong-Zhen Li Sajad Sohrabi +4 位作者 Xin Li Lu-Yao Li Jiang Ma Huan-Lin Peng Chao Yang 《Rare Metals》 2025年第4期2853-2860,共8页
In general,the rapid growth of α-Fe clusters is a challenge in high Fe-content Fe-based amorphous alloys,negatively affecting their physical properties.Herein,we introduce an efficient and rapid post-treatment techni... In general,the rapid growth of α-Fe clusters is a challenge in high Fe-content Fe-based amorphous alloys,negatively affecting their physical properties.Herein,we introduce an efficient and rapid post-treatment technique known as ultrasonic vibration rapid processing(UVRP),which enables the formation of high-density strong magnetic α-Fe clusters,thereby enhancing the soft magnetic properties of Fe_(78)Si(13)B_(9) amorphous alloy ribbon. 展开更多
关键词 enhancing soft magnetic properties soft magnetic properties physical propertieshereinwe Fe based amorphous alloy amorphous alloy ribbon ultrasonic vibration rapid processing uvrp which Fe clusters ultrasonic vibration rapid processing
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Hot Isostatic Pressing for Enhancing Mechanical Properties of Mo Alloys Prepared by Laser Powder Bed Fusion
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作者 Liang Xunwen Fu Zhongxue +3 位作者 Zhang Shiming Che Yusi Cheng Pengming Wang Pei 《稀有金属材料与工程》 北大核心 2025年第3期587-592,共6页
To enhance the mechanical properties of Mo alloys prepared through laser powder bed fusion(LPBF),a hot isostatic pressing(HIP)treatment was used.Results show that following HIP treatment,the porosity decreases from 0.... To enhance the mechanical properties of Mo alloys prepared through laser powder bed fusion(LPBF),a hot isostatic pressing(HIP)treatment was used.Results show that following HIP treatment,the porosity decreases from 0.27%to 0.22%,enabling the elements Mo and Ti to diffuse fully and to distribute more uniformly,and to forming a substantial number of low-angle grain boundaries.The tensile strength soars from 286±32 MPa to 598±22 MPa,while the elongation increases from 0.08%±0.02%to 0.18%±0.02%,without notable alterations in grain morphology during the tensile deformation.HIP treatment eliminates the molten pool boundaries,which are the primary source for premature failure in LPBFed Mo alloys.Consequently,HIP treatment emerges as a novel and effective approach for strengthening the mechanical properties of LPBFed Mo alloys,offering a fresh perspective on producing high-performance Mo-based alloys. 展开更多
关键词 Mo alloys hot isostatic pressing laser powder bed fusion mechanical properties
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Tailored gradient nanocrystallization in bulk metallic glass via ultrasonic vibrations
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作者 Yu Zhang Sajad Sohrabi +2 位作者 Xin Li Shuai Ren Jiang Ma 《Journal of Materials Science & Technology》 2025年第7期109-120,共12页
To advance materials with superior performance,the construction of gradient structures has emerged as a promising strategy.In this study,a gradient nanocrystalline-amorphous structure was induced in Zr46Cu46Al8 bulk m... To advance materials with superior performance,the construction of gradient structures has emerged as a promising strategy.In this study,a gradient nanocrystalline-amorphous structure was induced in Zr46Cu46Al8 bulk metallic glass(BMG)through ultrasonic vibration(UV)treatment.Applying a 20 kHz ultrasonic cyclic loading in the elastic regime,controllable gradient structures with varying crystallized volume fractions can be achieved in less than 2 s by adjusting the input UV energy.In contrast to tradi-tional methods of inducing structural gradients in BMGs,this novel approach offers distinct advantages:it is exceptionally rapid,requires minimal stress,and allows for easy tuning of the extent of structural gradients through precise adjustment of processing parameters.Nanoindentation tests reveal higher hard-ness near the struck surface,attributed to a greater degree of nanocrystal formation,which gradually di-minishes with depth.As a result of the gradient dispersion of nanocrystals,an increased plasticity was found after UV treatment,characterized by the formation of multiple shear bands.Microstructural in-vestigations suggest that UV-induced nanocrystallization originates from local atomic rearrangements in phase-separated Cu-rich regions with high diffusional mobility.Our study underscores the tunability of structural gradients and corresponding performance improvements in BMGs through ultrasonic energy modulation,offering valuable insights for designing advanced metallic materials with tailored mechanical properties. 展开更多
关键词 Bulk metallic glass NANOCRYSTALLIZATION Ultrasonic vibration PLASTICITY Structural heterogeneities
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Study on Dry Electrical Discharge Assisted Grinding of SiCp/Al Composite
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作者 Yanjun Lu Yuming Huang +2 位作者 Xiaobu Liu Rong Cheng Shunda Zhan 《Chinese Journal of Mechanical Engineering》 2025年第1期106-118,共13页
SiC-reinforced aluminum matrix(SiCp/Al)composite is widely utilized in the aerospace,automotive,and electronics industries due to the combination of ceramic hardness and metal toughness.However,the significant dispari... SiC-reinforced aluminum matrix(SiCp/Al)composite is widely utilized in the aerospace,automotive,and electronics industries due to the combination of ceramic hardness and metal toughness.However,the significant disparity in properties between SiC particles and the aluminum matrix results in severe tool wear and diminished surface quality during conventional machining.This study proposes an environmentally friendly and clean dry electrical discharge assisted grinding process as an efficient and low-damage machining method for SiCp/Al.An experimental platform was set up to study the impact of grinding and discharge process parameters on surface quality.The study compared the chip formation mechanism and surface quality between dry electrical discharge assisted grinding and conventional grinding,revealing relationships between surface roughness,grinding force,grinding temperature,and related parameters.The results indicate that the proposed grinding method leads to smaller chip sizes,lower grinding forces and temperatures,and an average reduction of 19.2%in surface roughness compared to conventional grinding.The axial,tangential,and normal grinding forces were reduced by roughly 10.5%,37.8%,and 23.0%,respectively.The optimized process parameters were determined to be N=2500 r/min,vf=30 mm/min,a=10μm,E=15 V,f=5000 Hz,dc=80%,resulting in a surface roughness of 0.161μm. 展开更多
关键词 Dry electrical discharge assisted grinding SiCp/Al composite Surface quality Grinding force Grinding temperature
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Strong absorption in ultra-wide band by surface nano engineering of metallic glass
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作者 Jianan Fu Xin Li +8 位作者 Zhen Li Fei Sun Wenxin Wen Jinlai Zhao Wenqing Ruan Shuai Ren Zhenxuan Zhang Xiong Liang Jiang Ma 《Fundamental Research》 2025年第1期307-314,共8页
Broadband light absorption is important for applications such as infrared detectors,solar energy collectors,and photothermal conversion.We propose a facile and common strategy to fabricate light absorbers with strong ... Broadband light absorption is important for applications such as infrared detectors,solar energy collectors,and photothermal conversion.We propose a facile and common strategy to fabricate light absorbers with strong ultra-wideband absorption.Due to their excellent thermoplastic forming ability,metallic glasses could be patterned into finely arranged nanowire arrays,which show extremely low reflectivity(∼0.6%)in the visible and near-infrared regimes,and a low reflectivity(∼15%)in the mid-infrared regime as caused by multiscale nano spacing,multiple reflections,and plasmonic behavior.The strong absorption at surfaces with nanowires provides excellent photothermal conversion properties.The photothermal properties show that a surface with nanowires can be rapidly heated up to∼160°C at a rate of 28.75°C/s,which is 30 times higher than smooth surfaces.Meanwhile,a surface with nanowires shows a high photothermal conversion efficiency(η_(PT)=56.36%).The fabricated metallic glass absorbers exhibit adaptability as they can be easily formed into various complex shapes and meet the requirements under harsh conditions.The outcomes of our research open the door to manufacturing high-performance absorbers for applications in photothermal electric power generation,desalination,and photodetectors. 展开更多
关键词 Metallic glass Nanoforming Ultra-wideband absorption Photothermal properties Thermoplastic forming
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