Achieving high energy and power densities is currently a core challenge in the fabrication of energy storage materials.Although numerous high-capacity materials have been developed,conventional planar electrodes canno...Achieving high energy and power densities is currently a core challenge in the fabrication of energy storage materials.Although numerous high-capacity materials have been developed,conventional planar electrodes cannot achieve high active material loading and efficient ion/electron transport simultaneously.By contrast,three-dimensional(3D)structures have attracted increasing interest because of their capacity to enhance active material utilization,shorten ion and electron transport pathways,reduce interfacial impedance,and provide spatial accommodation for volume expansion.Additive manufacturing(AM)technology effectively fabricates energy-storage materials with 3D structures by accurately constructing complex 3D structures via layer-by-layer deposition.Recent studies have employed AM to construct ordered 3D electrodes that can optimize ion/electron transport,regulate electric field distribution,or improve the electrode-electrolyte interface,thereby contributing to enhanced kinetic performance and cycling stability.This review systematically summarizes the applications of several AM technologies in the fabrication of energy storage materials and analyzes their respective advantages and limitations.Subsequently,the advantages of AM technology in the fabrication of energy storage materials and several major optimization strategies are comprehensively discussed.Finally,the major challenges and potential applications of AM technology in energy storage material optimization are discussed.展开更多
This paper proposes two types of integrated sound absorbing-insulating metamaterials with low thickness and efficient sound attenuation in the low-frequency bandwidth,i.e.,labyrinth-type metamaterial and multi-order r...This paper proposes two types of integrated sound absorbing-insulating metamaterials with low thickness and efficient sound attenuation in the low-frequency bandwidth,i.e.,labyrinth-type metamaterial and multi-order resonator metamaterial.The labyrinth-type metamaterial is designed through spatial dimension transfer,transferring the required dimension in the thickness direction to the planar thin layer.Based on the Helmholtz resonance,the metamaterial achieves noise reduction through the reflection of sound waves and the thermoviscous dissipation of holes and cavities.This mechanism enables its sound insulation performance to produce the same gain effect as absorption,thereby accomplishing the broadband absorbing-insulating integrated design.With a thickness of only 33 mm,it achieves both sound absorption and insulation effects over more than one octave.The multi-order resonator metamaterial has a larger working bandwidth than the labyrinth-type metamaterial.It is designed based on the multiorder resonance absorption mechanism,and consists of 9 different orders of resonator units.The metamaterial obtains a continuous sound absorption coefficient curve in the low-frequency range of 362–1712 Hz,and possesses high transmission loss(TL)above 346 Hz.In addition,this paper deeply explores the sound absorbing-insulating mechanism through the correlation analysis between the sound absorption coefficient and TL curves.The experimental results verify the continuous and efficient absorption effects of the two metamaterials,as well as their insulation performance that breaks the mass law.In low-frequency engineering applications,the two designed metamaterials demonstrate great potential and value at sub-wavelength dimensions.展开更多
As the speeds of trains increase,higher demands are placed on brake materials.In order to overcome the thermal degradation phenomenon of brake pads during high-speed braking,we prepared copper fiber reinforced alkali-...As the speeds of trains increase,higher demands are placed on brake materials.In order to overcome the thermal degradation phenomenon of brake pads during high-speed braking,we prepared copper fiber reinforced alkali-activated slag composite(AASC)friction materials by hot-pressing method,using slag as matrix,Na_(2)SiO_(3)·9H_(2)O as alkali excitant,copper fiber as reinforcement,and graphite as friction modifier.The results show that the AASC prepared by hot-pressing method has undergone alkali-activated reaction and has geopolymer amorphous characteristics as the conventional cast molding AASC by XRD analysis.The addition of copper fibers can improve the mechanical strength and toughness of the composites substantially,and the AASC has the highest flexural strength,compressive strength and impact toughness when the volume fraction of copper fibers reaches 25 vol%.Toughening mechanisms such as drawing,bridging and crack deflection of copper fibers in composites were analyzed by SEM morphology.Addition of appropriate amount of graphite to AASC can effectively reduce the wear rate and improve the stability of the material friction coefficient.The coefficient of friction also remains stable in the high-speed friction experiments without thermal degradation.Therefore,copper fiber reinforced AASC friction materials prepared by hot-pressing method has good mechanical and friction properties.展开更多
As electronic technology continues to evolve towards miniaturization and integration,the demand for micro-refrigeration technology in microelectronic systems is increasing.Ferroelectric(FE)refrigeration technology bas...As electronic technology continues to evolve towards miniaturization and integration,the demand for micro-refrigeration technology in microelectronic systems is increasing.Ferroelectric(FE)refrigeration technology based on the electrocaloric effect(ECE)has emerged as a highly promising candidate in this field,due to its advantages of high energy efficiency,simple structure,easy miniaturization,low cost,and environmental friendliness.The EC performance of FE materials essentially depends on the phase transition features under the coupled electric and thermal fields,making the E–T phase diagram a core tool for decoding the underlying mechanism of ECE.This paper reviews the development of EC materials,focusing on the comprehensive study of E–T phase diagrams.By correlating the microscopic phase structure of FE materials with the macroscopic physical properties,it clarifies the manipulation mechanism for enhanced ECE performance,providing theoretical support for the targeted design of high-performance EC materials.In the future,the introduction of data-driven methods is expected to enable the high-throughput construction of FE phase diagrams,thereby accelerating the optimization of high-performance EC materials and promoting the practical application of FE refrigeration technology.展开更多
The development of electrochemical energy storage systems capable of operating under low-temperature conditions is crucial for enabling renewable energy applications in extreme environments.Although lithium-ion batter...The development of electrochemical energy storage systems capable of operating under low-temperature conditions is crucial for enabling renewable energy applications in extreme environments.Although lithium-ion batteries(LIBs)occupied the market of rechargeable batteries,their limited lithium salt and awful low-temperature performance severely hamper their widely application.In contrast,sodium-ion batteries(SIBs)have attracted extensive attention as a promising alternative,owing to the naturally abundant sodium salt and its favorable physicochemical properties(smaller Stokes radius and lower desolvation energy),which enable better ionic conductivity and rate capability at low temperatures.However,the practical deployment of SIBs in cold environments remains hindered by sluggish electrochemical kinetics,unstable electrode-electrolyte interfaces,and structural degradation,particularly at the anode.To address these problems,considerable efforts have been made to explore anode materials for low-temperature SIBs(LT-SIBs).This paper reviews recent advances in the design and synthesis of advanced anode materials for LT-SIBs.It discusses the influence mechanism of temperature on the performance of the anode and summarizes the latest modification strategies to improve the low-temperature electrochemical performance of intercalation-/conversion-/alloying-type and Na anodes.Finally,the review outlines the prospects and directions for future research on low-temperature anodes.It is hoped that this review will offer meaningful guidance for the development of anode materials for SIBs operation in all climates.展开更多
Recent years have witnessed the significant breakthrough in the field of new materials discovery brought about by the artificial intelligence(AI).AI has successfully been applied for predicting the formability,reveali...Recent years have witnessed the significant breakthrough in the field of new materials discovery brought about by the artificial intelligence(AI).AI has successfully been applied for predicting the formability,revealing the properties,and guiding the experimental synthesis of materials.Rapid progress has been made in the integration of increasing database and improved computing power.Though some reviews present the development from their unique aspects,reviews from the view of how AI empowered both discovery of new materials and cognition of existing materials that covers the completed contents with two synergistical aspects are few.Here,the newest development is systematically reviewed in the field of AI empowered materials,reflecting advanced design of the intelligent systems for discovery,synthesis,prediction and validation of materials.First,background and mechanisms are briefed,after which the design for the AI systems with data,machine learning and automated laboratory included is illustrated.Next,strategies are summarized to obtain the AI systems for materials with improved performance which comprehensively cover the aspects from the in-depth cognizance of existing material and the rapid discovery of new materials,and then,the design thought for future AI systems in material science is pointed out.Finally,some perspectives are put forward.展开更多
NaCu_(0.2)Fe_(0.3)Mn_(0.5)O_(2) (NCFM) cathode material was synthesized using a simple solid-state reaction, and the effect of calcination temperature on its interlayer spacing and oxygen vacancies concentration was i...NaCu_(0.2)Fe_(0.3)Mn_(0.5)O_(2) (NCFM) cathode material was synthesized using a simple solid-state reaction, and the effect of calcination temperature on its interlayer spacing and oxygen vacancies concentration was investigated. Through electrochemical testing and material characterizations, higher calcination temperatures increase the electrostatic repulsion between oxygen atoms in adjacent layers, resulting in an expansion of Na layer spacing. This structural change enhances the diffusion kinetics of Na^(+), thereby significantly improving the rate performance of NCFM. Furthermore, elevated calcination temperatures facilitate the reduction of oxygen vacancies, leading to improved crystallinity. This enhancement in crystallinity mitigates structural strain during phase transitions, contributing to improved cyclic stability. Consequently, the optimized NCFM shows an initial discharge specific capacity of 143.3 mA·h/g at 0.1C, with a capacity retention rate of 79.28% after 100 cycles at 1C.展开更多
We mixed Bacillus subtilis and brewing yeast to prepare composite microbial self-healing materials,and studied the self-healing effect of composite microorganisms in mortar cracks of different widths and cracking ages...We mixed Bacillus subtilis and brewing yeast to prepare composite microbial self-healing materials,and studied the self-healing effect of composite microorganisms in mortar cracks of different widths and cracking ages.The experimental results show that the performance and self-healing effect of composite micro-organisms are significantly better than those of single microorganisms.For cracks with widths of 0.2-0.4 mm,the repair effect of the composite microorganisms at 28 days is 42.7%and 71.2%higher than that of pure Bacillus and pure yeast,respectively.The repairing rate of the area with the widths of the cracks of 0.2-0.4,0.4-0.6,and 0.6-0.8 mm are 100%,77.3%,and 53.4%,respectively.The area repair rates corresponding to cracking ages of 56,90,and 180 days are 73.3%,55.4%,and 30.8%,respectively.展开更多
Oily cold rolling mill （CRM） sludge is one of metallurgical industry solid wastes. The recycle of these wastes can not only protect the environment but also permit their reutilization. In this research, a new proces...Oily cold rolling mill （CRM） sludge is one of metallurgical industry solid wastes. The recycle of these wastes can not only protect the environment but also permit their reutilization. In this research, a new process of ＂hydrometallurgical treatment ＋ hydrothermal synthesis＂ was investigated for the combined recovery of iron and organic materials from oily CRM sludge. Hydrometallurgical treatment, mainly including acid leaching, centrifugal separation, neutralization reaction, oxidizing, and preparation of hydrothermal reaction precursor, was first utilized for processing the sludge. Then, micaceous iron oxide （MIO） pigment powders were prepared through hydrothermal reaction of the obtained precursor in alkaline media. The separated organic materials can be used for fuel or chemical feedstock. The quality of the prepared MIO pigments is in accordance with the standards of MIO pigments for paints （ISO 10601-2007）. This clean, effective, and economical technology offers a new way to recycle oily CRM sludge.展开更多
With the increase of energy consumption,the shortage of fossil resource,and the aggravation of environmental pollution,the development of cost-effective and environmental friendly bio-based energy storage devices has ...With the increase of energy consumption,the shortage of fossil resource,and the aggravation of environmental pollution,the development of cost-effective and environmental friendly bio-based energy storage devices has become an urgent need.As the second most abundant natural polymer found in nature,lignin is mainly produced as the by-product of paper pulping and bio-refining industries.It possesses several inherent advantages,such as low-cost,high carbon content,abundant functional groups,and bio-renewable,making it an attractive candidate for the rechargeable battery material.Consequently,there has been a surge of research interest in utilizing lignin or lignin-based carbon materials as the components of lithium-ion(LIBs)or sodium-ion batteries(SIBs),including the electrode,binder,separator,and electrolyte.This review provides a comprehensive overview on the research progress of lignin-derived materials used in LIBs/SIBs,especially the application of lignin-based carbons as the anodes of LIBs/SIBs.The preparation methods and properties of lignin-derived materials with different dimensions are systemically discussed,which emphasizes on the relationship between the chemical/physical structures of lignin-derived materials and the performances of LIBs/SIBs.The current challenges and future prospects of lignin-derived materials in energy storage devices are also proposed.展开更多
Although lithium-ion batteries(LIBs)currently dominate a wide spectrum of energy storage applications,they face challenges such as fast cycle life decay and poor stability that hinder their further application.To addr...Although lithium-ion batteries(LIBs)currently dominate a wide spectrum of energy storage applications,they face challenges such as fast cycle life decay and poor stability that hinder their further application.To address these limitations,element doping has emerged as a prevalent strategy to enhance the discharge capacity and extend the durability of Li-Ni-Co-Mn(LNCM)ternary compounds.This study utilized a machine learning-driven feature screening method to effectively pinpoint four key features crucially impacting the initial discharge capacity(IC)of Li-Ni-Co-Mn(LNCM)ternary cathode materials.These features were also proved highly predictive for the 50^(th)cycle discharge capacity(EC).Additionally,the application of SHAP value analysis yielded an in-depth understanding of the interplay between these features and discharge performance.This insight offers valuable direction for future advancements in the development of LNCM cathode materials,effectively promoting this field toward greater efficiency and sustainability.展开更多
This paper focuses on ACF artificial cartilage biomimetic energy-absorbing materials,exploring the entire process from fundamental research to industrial transformation.By analyzing the key nodes and technological bre...This paper focuses on ACF artificial cartilage biomimetic energy-absorbing materials,exploring the entire process from fundamental research to industrial transformation.By analyzing the key nodes and technological breakthroughs in the research and development journey,as well as the market strategies and collaboration models in the transformation practices,this study reveals the profound insights ACF provides to the technological innovation ecosystem in terms of concepts,mechanisms,and resource integration,and constructs a universally applicable and forward-looking paradigm for technological innovation.Aiming to provide comprehensive and in-depth case studies for materials science and the entire technological innovation system,facilitating the innovative development and progress in related areas.展开更多
Reducing the resistance of vehicles,ships,aircraft and other means of transport during movement can significantly improve the speed,save energy and reduce emissions.After billions of years of continuous evolution,orga...Reducing the resistance of vehicles,ships,aircraft and other means of transport during movement can significantly improve the speed,save energy and reduce emissions.After billions of years of continuous evolution,organisms in nature have gradually developed the ability to move at high speed to achieve better survival.These evolved organisms provide a perfect template for the human development of drag reduction materials.Revealing the unique physiological structural characteristics of organisms and their relationship with resistance during movement can provide a feasible approach tosolving the problem of reducing friction resistance.Whether flying in the sky,running on the ground,swimming in the water,or even living in the soil,many creatures in various environments have the ability to reduce resistance.Driven by these inspirations,researchers have done a lot of work to explore and imitate these biological epidermis structures to achieve drag reduction.In this paper,the biomimetic drag reduction materials is introduced in detail in the order of drag reduction mechanism,structural characteristics of biological epidermis(including marine animals,flying animals,soil animals and plants),biomimetic preparation methods,performance testing methods and application fields.Finally,the potential of various biomimetic drag reduction materials in engineering application and the problems to be overcome are summarized and prospected.This paper can help readers comprehensively understand the research progress of biomimetic drag reduction materials,and provide reference for further designing the next generation of drag reduction materials.展开更多
Two sets of alloys,Mg-Zn-Ca-xNi(0≤x≤5),have been developed with tunable corrosion and mechanical properties,optimized for fracturing materials.High-zinc artificial aged(T6)Mg-12Zn-0.5Ca-x Ni(0≤x≤5)series,featuring...Two sets of alloys,Mg-Zn-Ca-xNi(0≤x≤5),have been developed with tunable corrosion and mechanical properties,optimized for fracturing materials.High-zinc artificial aged(T6)Mg-12Zn-0.5Ca-x Ni(0≤x≤5)series,featuring a straightforward preparation method and the potential for manufacturing large-scale components,exhibit notable corrosion rates up to 29 mg cm^(-2)h^(-1)at 25℃ and 643 mg cm^(-2)h^(-1)at 93℃.The high corrosion rate is primary due to the Ni–containing second phases,which intensify the galvanic corrosion that overwhelms their corrosion barrier effect.Low-zinc rolled Mg-1.5Zn-0.2Ca-x Ni(0≤x≤5)series,characterizing excellent deformability with an elongation to failure of~26%,present accelerated corrosion rates up to 34 mg cm^(-2)h^(-1)at 25℃ and 942 mg cm^(-2)h^(-1)at 93℃.The elimination of corrosion barrier effect via deformation contributes to the further increase of corrosion rate compared to the T6 series.Additionally,Mg-Zn-Ca-xNi(0≤x≤5)alloys exhibit tunable ultimate tensile strengths ranging from~190 to~237 MPa,depending on their specific composition.The adjustable corrosion rate and mechanical properties render the Mg-Zn-Ca-x Ni(0≤x≤5)alloys suitable for fracturing materials.展开更多
Protein fibers derived from silk fibroin(SF)were chemically extracted and purified from cocoons.It was used as a reinforced fiber for hydrogel formation with collagen(Col)and hyaluronic acid(HA).Calcium chloride(8 wt....Protein fibers derived from silk fibroin(SF)were chemically extracted and purified from cocoons.It was used as a reinforced fiber for hydrogel formation with collagen(Col)and hyaluronic acid(HA).Calcium chloride(8 wt.%)was employed as a crosslinking reagent to synthesize the SF/Col/HA-based hydrogel composite.FTIR spec-troscopy confirmed the presence of N-H stretching due to the plane bending of amide II in theβ-sheet structure.XRD analysis confirmed the crystallinity of the SF/Col/HA-based hydrogel composite.Scanning electron mi-croscopy revealed three-dimensional porous structures with interconnected pores.These porous structures can serve as reservoirs for storing adsorbent media.The hydrogel composite was thermally stable at 250℃.The lowboiling bound solvent evaporation temperature,glass transition temperature,and degradation temperature were 102℃-105℃,298℃-300℃,and 524℃-545℃,respectively.The ranges of porosity and gel fraction were 60%-80%and 90%-95%,respectively.The hydrogel composite was rapidly swollen within 1 h,reaching a plateau afterward.The compressive strength was 4-6 MPa.As absorbent media,hydrogels can easily adhere to lead ions via electrostatic interactions.They can be used as reservoirs for the adsorption of heavy metals.展开更多
In this work,we synthesize two luminescent Pt(Ⅱ)complexes using differentπ-conjugated bidentate ligands.Both complexes are assembled into three-dimensional(3D)networks through non-classical intermolecular interactio...In this work,we synthesize two luminescent Pt(Ⅱ)complexes using differentπ-conjugated bidentate ligands.Both complexes are assembled into three-dimensional(3D)networks through non-classical intermolecular interactions in the crystal state.Unexpectedly,substituting pyridine with the more extensivelyπ-conjugated quinoline significantly increases the dihedral angles between the phenyl and quinolyl groups of the bidentate ligands.This alteration disrupts theπ-πinteractions between molecules,resulting in distinct optical properties upon exposure to external stimuli.By integrating these complexes into polymers,we fabricate electrospun films containing luminescent nanofibers that exhibit reversible optical changes.These findings have paved the way for the development of high-performance optical encryption and anti-counterfeiting materials,achieved through the employment of simple chromophores.展开更多
Supramolecular materials,characterized by dynamic reversibility and responsiveness to environmental stimuli,have found widespread applications in numerous fields.Unlike traditional materials,supramolecular materials t...Supramolecular materials,characterized by dynamic reversibility and responsiveness to environmental stimuli,have found widespread applications in numerous fields.Unlike traditional materials,supramolecular materials that rely on non-covalent interactions can allow spontaneous reorganization and self-healing at room temperature.However,these materials typically exhibit low strength due to the weak bonding energies of non-covalent interactions.This study presents the development of a high-strength self-healing supramolecular material that combines multiple interactions including ionic bonding,hydrogen bonding,and coordination bonding.The material,formed by the aggregation of the negatively charged picolinate-grafted copolymer(PCM)with positively charged hyperbranched molecules(HP),is further enhanced by Eu^(3+)ion complexation.The resulting film exhibits a high modulus of 427 MPa,tensile strength of 10.5 MPa,and toughness of 14.7 MJ m^(−3).Meanwhile,the non-covalent interaction of this supramolecular material endows it with a self-healing efficiency of 92%within 24 h at room temperature,as well as multiple remolding properties.The incorporation of lanthanide ions also imparts tunable fluorescence.This study not only provides insights into the development of high-strength self-healing materials but also offers new possibilities for the functionalization of supramolecular materials.展开更多
Ni-rich cathode materials have become the mainstream choice in the mileage electric vehicle sector due to their high specific capacity and safety factor.However,the volume changes occurring during charging and dischar...Ni-rich cathode materials have become the mainstream choice in the mileage electric vehicle sector due to their high specific capacity and safety factor.However,the volume changes occurring during charging and discharging lead to microcracking and surface remodeling,posing challenges to achieving such as high specific capacity and long cycle stability.This paper reviews existing modification strategies for Ni-rich layered oxide cathode materials.Unlike previous reviews and related papers,we comprehensively discuss a variety of modification strategies and deeply discuss the synergistic modification effect of surface coating and bulk doping,which is how to improve the cycling stability of the Ni-rich cathode.In addition,based on recent research advances,the prospects and challenges of modifying Ni-rich layered cathodes for cycle stability upgrading of the lithium-ion battery,as well as the potential application prospects in the field of power automobiles,are comprehensively analyzed.展开更多
Investigating thermal transport mechanisms at the interface between phase change materials(PCMs)and high thermally conductive fillers has become increasingly significant in developing phase change energy storage techn...Investigating thermal transport mechanisms at the interface between phase change materials(PCMs)and high thermally conductive fillers has become increasingly significant in developing phase change energy storage technologies.This study explores the interfacial thermal transport between a representative PCM,erythritol,and various fillers,including crystalline(Si C,Si_(3)N_(4))and amorphous(Si O_(2))nanoparticles,using molecular dynamics(MD)simulations.Additionally,time-domain thermoreflectance(TDTR)experiments were performed to quantify the interfacial thermal conductance between erythritol and the three types of fillers,yielding values of 50.1,40.0,and25.6 MW m^(–2)K^(-1).These results align well with the trends observed in the simulations.Furthermore,the underlying mechanisms of interfacial heat transfer were analyzed by examining the phonon density of states,overlap energy,and interaction energy.This research provides innovative insights into nanoscale interfacial thermal transport in composite PCMs.This could lead to significant advancements in thermal management technologies,particularly in developing more efficient thermal energy storage systems.展开更多
Although manganese-based oxide is regarded as a promising cathode material for zincion hybrid supercapacitors(ZHSCs),its practical application is hindered by slow zinc ion diffusion and the instability of MnO_(2).To o...Although manganese-based oxide is regarded as a promising cathode material for zincion hybrid supercapacitors(ZHSCs),its practical application is hindered by slow zinc ion diffusion and the instability of MnO_(2).To overcome this obstacle,a δ-MnO_(2)/MXene heterostructure was created using a simple one-step process under gentle condition.The ZHSC was assembled using this heterostructure as the cathode,activated carbon(AC)as the anode and 2 mol·L−1 ZnSO_(4) as the electrolyte.The resultingδ-MnO_(2)/MXene//ZnSO4//AC ZHSC shows a maximum specific capacitance of 97.4 F·g^(−1) and an energy density of 32.27 Wh·kg^(−1) at the best cathode-to-anode mass ratio.Ex situ characterizations reveal the reversible energy storage mechanism combing Zn^(2+)insertion/extraction in the cathode,ion adsorption and desorption on the anode surface,and partial reversible formation and dissolution of Zn_(4)SO_(4)(OH)_(6)·5H_(2)O(ZHS)components on both electrodes.Adding of Mn^(2+)to the electrolyte reduced Mn dissolution,improving the ZHSC’s specific capacitance and energy density to 140.4 F·g^(−1) and 49.36 Wh·kg^(−1),respectively,while also enhancing its rate performance and cyclability.The improved electrochemical reaction kinetics was verified through various tests.The results suggest that the δ-MnO_(2)/MXene heterostructure has great potential as a high-performance cathode material for ZHSCs.展开更多
基金support of the National Natural Science Foundation of China(No.52574411)Beijing Natural Science Foundation(No.2242043).
文摘Achieving high energy and power densities is currently a core challenge in the fabrication of energy storage materials.Although numerous high-capacity materials have been developed,conventional planar electrodes cannot achieve high active material loading and efficient ion/electron transport simultaneously.By contrast,three-dimensional(3D)structures have attracted increasing interest because of their capacity to enhance active material utilization,shorten ion and electron transport pathways,reduce interfacial impedance,and provide spatial accommodation for volume expansion.Additive manufacturing(AM)technology effectively fabricates energy-storage materials with 3D structures by accurately constructing complex 3D structures via layer-by-layer deposition.Recent studies have employed AM to construct ordered 3D electrodes that can optimize ion/electron transport,regulate electric field distribution,or improve the electrode-electrolyte interface,thereby contributing to enhanced kinetic performance and cycling stability.This review systematically summarizes the applications of several AM technologies in the fabrication of energy storage materials and analyzes their respective advantages and limitations.Subsequently,the advantages of AM technology in the fabrication of energy storage materials and several major optimization strategies are comprehensively discussed.Finally,the major challenges and potential applications of AM technology in energy storage material optimization are discussed.
基金Project supported by the National Natural Science Foundation of China(No.52250287)the Outstanding Youth Science Fund Project of Shaanxi Province of China(No.2024JC-JCQN-49)。
文摘This paper proposes two types of integrated sound absorbing-insulating metamaterials with low thickness and efficient sound attenuation in the low-frequency bandwidth,i.e.,labyrinth-type metamaterial and multi-order resonator metamaterial.The labyrinth-type metamaterial is designed through spatial dimension transfer,transferring the required dimension in the thickness direction to the planar thin layer.Based on the Helmholtz resonance,the metamaterial achieves noise reduction through the reflection of sound waves and the thermoviscous dissipation of holes and cavities.This mechanism enables its sound insulation performance to produce the same gain effect as absorption,thereby accomplishing the broadband absorbing-insulating integrated design.With a thickness of only 33 mm,it achieves both sound absorption and insulation effects over more than one octave.The multi-order resonator metamaterial has a larger working bandwidth than the labyrinth-type metamaterial.It is designed based on the multiorder resonance absorption mechanism,and consists of 9 different orders of resonator units.The metamaterial obtains a continuous sound absorption coefficient curve in the low-frequency range of 362–1712 Hz,and possesses high transmission loss(TL)above 346 Hz.In addition,this paper deeply explores the sound absorbing-insulating mechanism through the correlation analysis between the sound absorption coefficient and TL curves.The experimental results verify the continuous and efficient absorption effects of the two metamaterials,as well as their insulation performance that breaks the mass law.In low-frequency engineering applications,the two designed metamaterials demonstrate great potential and value at sub-wavelength dimensions.
基金Funded by the National Natural Science Foundation of China(No.51236003)the Natural Science Foundation of Gansu Province(No.1506RJZA076)。
文摘As the speeds of trains increase,higher demands are placed on brake materials.In order to overcome the thermal degradation phenomenon of brake pads during high-speed braking,we prepared copper fiber reinforced alkali-activated slag composite(AASC)friction materials by hot-pressing method,using slag as matrix,Na_(2)SiO_(3)·9H_(2)O as alkali excitant,copper fiber as reinforcement,and graphite as friction modifier.The results show that the AASC prepared by hot-pressing method has undergone alkali-activated reaction and has geopolymer amorphous characteristics as the conventional cast molding AASC by XRD analysis.The addition of copper fibers can improve the mechanical strength and toughness of the composites substantially,and the AASC has the highest flexural strength,compressive strength and impact toughness when the volume fraction of copper fibers reaches 25 vol%.Toughening mechanisms such as drawing,bridging and crack deflection of copper fibers in composites were analyzed by SEM morphology.Addition of appropriate amount of graphite to AASC can effectively reduce the wear rate and improve the stability of the material friction coefficient.The coefficient of friction also remains stable in the high-speed friction experiments without thermal degradation.Therefore,copper fiber reinforced AASC friction materials prepared by hot-pressing method has good mechanical and friction properties.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.U25A20232,52325208,52173217,52202128)the Interdisciplinary Research Project for Young Teachers of USTB(Grant No.FRF-IDRY24-002)。
文摘As electronic technology continues to evolve towards miniaturization and integration,the demand for micro-refrigeration technology in microelectronic systems is increasing.Ferroelectric(FE)refrigeration technology based on the electrocaloric effect(ECE)has emerged as a highly promising candidate in this field,due to its advantages of high energy efficiency,simple structure,easy miniaturization,low cost,and environmental friendliness.The EC performance of FE materials essentially depends on the phase transition features under the coupled electric and thermal fields,making the E–T phase diagram a core tool for decoding the underlying mechanism of ECE.This paper reviews the development of EC materials,focusing on the comprehensive study of E–T phase diagrams.By correlating the microscopic phase structure of FE materials with the macroscopic physical properties,it clarifies the manipulation mechanism for enhanced ECE performance,providing theoretical support for the targeted design of high-performance EC materials.In the future,the introduction of data-driven methods is expected to enable the high-throughput construction of FE phase diagrams,thereby accelerating the optimization of high-performance EC materials and promoting the practical application of FE refrigeration technology.
基金supported by the National Natural Science Foundation of China(No.52301266)the Guangdong Basic and Applied Basic Research Foundation(No.2025A1515012152)+1 种基金the Science and Technology Planning Project of Guangzhou(No.2024A04J3332)the Chenzhou National Sustainable Development Agenda Innovation Demonstration Zone Provincial Special Project(No.2023sfq11)。
文摘The development of electrochemical energy storage systems capable of operating under low-temperature conditions is crucial for enabling renewable energy applications in extreme environments.Although lithium-ion batteries(LIBs)occupied the market of rechargeable batteries,their limited lithium salt and awful low-temperature performance severely hamper their widely application.In contrast,sodium-ion batteries(SIBs)have attracted extensive attention as a promising alternative,owing to the naturally abundant sodium salt and its favorable physicochemical properties(smaller Stokes radius and lower desolvation energy),which enable better ionic conductivity and rate capability at low temperatures.However,the practical deployment of SIBs in cold environments remains hindered by sluggish electrochemical kinetics,unstable electrode-electrolyte interfaces,and structural degradation,particularly at the anode.To address these problems,considerable efforts have been made to explore anode materials for low-temperature SIBs(LT-SIBs).This paper reviews recent advances in the design and synthesis of advanced anode materials for LT-SIBs.It discusses the influence mechanism of temperature on the performance of the anode and summarizes the latest modification strategies to improve the low-temperature electrochemical performance of intercalation-/conversion-/alloying-type and Na anodes.Finally,the review outlines the prospects and directions for future research on low-temperature anodes.It is hoped that this review will offer meaningful guidance for the development of anode materials for SIBs operation in all climates.
基金supported by the Hong Kong Polytechnic University(Project No.4-ZZW1,4-YWER,97D9,4-W443)。
文摘Recent years have witnessed the significant breakthrough in the field of new materials discovery brought about by the artificial intelligence(AI).AI has successfully been applied for predicting the formability,revealing the properties,and guiding the experimental synthesis of materials.Rapid progress has been made in the integration of increasing database and improved computing power.Though some reviews present the development from their unique aspects,reviews from the view of how AI empowered both discovery of new materials and cognition of existing materials that covers the completed contents with two synergistical aspects are few.Here,the newest development is systematically reviewed in the field of AI empowered materials,reflecting advanced design of the intelligent systems for discovery,synthesis,prediction and validation of materials.First,background and mechanisms are briefed,after which the design for the AI systems with data,machine learning and automated laboratory included is illustrated.Next,strategies are summarized to obtain the AI systems for materials with improved performance which comprehensively cover the aspects from the in-depth cognizance of existing material and the rapid discovery of new materials,and then,the design thought for future AI systems in material science is pointed out.Finally,some perspectives are put forward.
基金supported by the National Natural Science Foundation of China(No.12175089)the Key Research and Development Program of Yunnan Province,China(No.202103AF140006)+2 种基金Basic Research Programs of Yunnan Provincial Science and Technology Department,China(Nos.202001AW070004,202301AS070051,202401AV070008)Yunnan Industrial Innovative Talents Program for“Xingdian Talent Support Plan”,China(No.KKXY202252001)Yunnan Major Scientific and Technological Projects,China(No.202202AG050003)。
文摘NaCu_(0.2)Fe_(0.3)Mn_(0.5)O_(2) (NCFM) cathode material was synthesized using a simple solid-state reaction, and the effect of calcination temperature on its interlayer spacing and oxygen vacancies concentration was investigated. Through electrochemical testing and material characterizations, higher calcination temperatures increase the electrostatic repulsion between oxygen atoms in adjacent layers, resulting in an expansion of Na layer spacing. This structural change enhances the diffusion kinetics of Na^(+), thereby significantly improving the rate performance of NCFM. Furthermore, elevated calcination temperatures facilitate the reduction of oxygen vacancies, leading to improved crystallinity. This enhancement in crystallinity mitigates structural strain during phase transitions, contributing to improved cyclic stability. Consequently, the optimized NCFM shows an initial discharge specific capacity of 143.3 mA·h/g at 0.1C, with a capacity retention rate of 79.28% after 100 cycles at 1C.
基金Funded by the National Key R&D Program of China(No.2023YFC3806100)the National Nature Science Foundation of China(No.52278269,52278268)+2 种基金the Tianjin Outstanding Young Scholars Science Fund Project(No.22JCJQJC00020)the Key Project of Tianjin Natural Science Foundation(No.23JCZDJC00430)the Joint Research Center of China and Foreign Countries Special Fund of Tianjin Innovation Platform(No.24PTLYHZ00240)。
文摘We mixed Bacillus subtilis and brewing yeast to prepare composite microbial self-healing materials,and studied the self-healing effect of composite microorganisms in mortar cracks of different widths and cracking ages.The experimental results show that the performance and self-healing effect of composite micro-organisms are significantly better than those of single microorganisms.For cracks with widths of 0.2-0.4 mm,the repair effect of the composite microorganisms at 28 days is 42.7%and 71.2%higher than that of pure Bacillus and pure yeast,respectively.The repairing rate of the area with the widths of the cracks of 0.2-0.4,0.4-0.6,and 0.6-0.8 mm are 100%,77.3%,and 53.4%,respectively.The area repair rates corresponding to cracking ages of 56,90,and 180 days are 73.3%,55.4%,and 30.8%,respectively.
基金financially supported by the National Key Technology R&D Program of China (Nos.2012BAC02B01,2012BAC12B05,2011BAE13B07,and 2011BAC10B02)the National High-Tech Research and Development Program of China (No.2012AA063202)+2 种基金the National Natural Science Foundation of China (Nos.51174247 and 51004011)the Science and Technology Program of Guangdong Province,China (No.2010A030200003)the Ph.D. Programs Foundation of the Ministry of Education of China (No.2010000612003)
文摘Oily cold rolling mill （CRM） sludge is one of metallurgical industry solid wastes. The recycle of these wastes can not only protect the environment but also permit their reutilization. In this research, a new process of ＂hydrometallurgical treatment ＋ hydrothermal synthesis＂ was investigated for the combined recovery of iron and organic materials from oily CRM sludge. Hydrometallurgical treatment, mainly including acid leaching, centrifugal separation, neutralization reaction, oxidizing, and preparation of hydrothermal reaction precursor, was first utilized for processing the sludge. Then, micaceous iron oxide （MIO） pigment powders were prepared through hydrothermal reaction of the obtained precursor in alkaline media. The separated organic materials can be used for fuel or chemical feedstock. The quality of the prepared MIO pigments is in accordance with the standards of MIO pigments for paints （ISO 10601-2007）. This clean, effective, and economical technology offers a new way to recycle oily CRM sludge.
基金supported by the Key R&D Program of Shandong Province,China(2023CXGC010611)the State Key Project of International Cooperation Research(2023YFE0201100)the Program for Introducing Talents of Discipline to Universities(“111”plan),and the High-Level Discipline Program of Shandong Province of China.
文摘With the increase of energy consumption,the shortage of fossil resource,and the aggravation of environmental pollution,the development of cost-effective and environmental friendly bio-based energy storage devices has become an urgent need.As the second most abundant natural polymer found in nature,lignin is mainly produced as the by-product of paper pulping and bio-refining industries.It possesses several inherent advantages,such as low-cost,high carbon content,abundant functional groups,and bio-renewable,making it an attractive candidate for the rechargeable battery material.Consequently,there has been a surge of research interest in utilizing lignin or lignin-based carbon materials as the components of lithium-ion(LIBs)or sodium-ion batteries(SIBs),including the electrode,binder,separator,and electrolyte.This review provides a comprehensive overview on the research progress of lignin-derived materials used in LIBs/SIBs,especially the application of lignin-based carbons as the anodes of LIBs/SIBs.The preparation methods and properties of lignin-derived materials with different dimensions are systemically discussed,which emphasizes on the relationship between the chemical/physical structures of lignin-derived materials and the performances of LIBs/SIBs.The current challenges and future prospects of lignin-derived materials in energy storage devices are also proposed.
基金supported by the National Natural Science Foundation of China(Nos.52122408,52071023)the Program for Science&Technology Innovation Talents in the University of Henan Province(No.22HASTIT1006)+2 种基金the Program for Central Plains Talents(No.ZYYCYU202012172)the Ministry of Education,Singapore(No.RG70/20)the Opening Project of National Joint Engineering Research Center for Abrasion Control and Molding of Metal Materials,Henan University of Science and Technology(No.HKDNM201906).
文摘Although lithium-ion batteries(LIBs)currently dominate a wide spectrum of energy storage applications,they face challenges such as fast cycle life decay and poor stability that hinder their further application.To address these limitations,element doping has emerged as a prevalent strategy to enhance the discharge capacity and extend the durability of Li-Ni-Co-Mn(LNCM)ternary compounds.This study utilized a machine learning-driven feature screening method to effectively pinpoint four key features crucially impacting the initial discharge capacity(IC)of Li-Ni-Co-Mn(LNCM)ternary cathode materials.These features were also proved highly predictive for the 50^(th)cycle discharge capacity(EC).Additionally,the application of SHAP value analysis yielded an in-depth understanding of the interplay between these features and discharge performance.This insight offers valuable direction for future advancements in the development of LNCM cathode materials,effectively promoting this field toward greater efficiency and sustainability.
文摘This paper focuses on ACF artificial cartilage biomimetic energy-absorbing materials,exploring the entire process from fundamental research to industrial transformation.By analyzing the key nodes and technological breakthroughs in the research and development journey,as well as the market strategies and collaboration models in the transformation practices,this study reveals the profound insights ACF provides to the technological innovation ecosystem in terms of concepts,mechanisms,and resource integration,and constructs a universally applicable and forward-looking paradigm for technological innovation.Aiming to provide comprehensive and in-depth case studies for materials science and the entire technological innovation system,facilitating the innovative development and progress in related areas.
基金the National Natural Science Foundation of China(No.52305236)supported by National Natural Science Foundation of China.
文摘Reducing the resistance of vehicles,ships,aircraft and other means of transport during movement can significantly improve the speed,save energy and reduce emissions.After billions of years of continuous evolution,organisms in nature have gradually developed the ability to move at high speed to achieve better survival.These evolved organisms provide a perfect template for the human development of drag reduction materials.Revealing the unique physiological structural characteristics of organisms and their relationship with resistance during movement can provide a feasible approach tosolving the problem of reducing friction resistance.Whether flying in the sky,running on the ground,swimming in the water,or even living in the soil,many creatures in various environments have the ability to reduce resistance.Driven by these inspirations,researchers have done a lot of work to explore and imitate these biological epidermis structures to achieve drag reduction.In this paper,the biomimetic drag reduction materials is introduced in detail in the order of drag reduction mechanism,structural characteristics of biological epidermis(including marine animals,flying animals,soil animals and plants),biomimetic preparation methods,performance testing methods and application fields.Finally,the potential of various biomimetic drag reduction materials in engineering application and the problems to be overcome are summarized and prospected.This paper can help readers comprehensively understand the research progress of biomimetic drag reduction materials,and provide reference for further designing the next generation of drag reduction materials.
基金supported by the National Key Research and Development Program(No.2022YFE0122000)National Natural Science Foundation of China under Grant Nos.52234009,52274383,52222409,and 52201113。
文摘Two sets of alloys,Mg-Zn-Ca-xNi(0≤x≤5),have been developed with tunable corrosion and mechanical properties,optimized for fracturing materials.High-zinc artificial aged(T6)Mg-12Zn-0.5Ca-x Ni(0≤x≤5)series,featuring a straightforward preparation method and the potential for manufacturing large-scale components,exhibit notable corrosion rates up to 29 mg cm^(-2)h^(-1)at 25℃ and 643 mg cm^(-2)h^(-1)at 93℃.The high corrosion rate is primary due to the Ni–containing second phases,which intensify the galvanic corrosion that overwhelms their corrosion barrier effect.Low-zinc rolled Mg-1.5Zn-0.2Ca-x Ni(0≤x≤5)series,characterizing excellent deformability with an elongation to failure of~26%,present accelerated corrosion rates up to 34 mg cm^(-2)h^(-1)at 25℃ and 942 mg cm^(-2)h^(-1)at 93℃.The elimination of corrosion barrier effect via deformation contributes to the further increase of corrosion rate compared to the T6 series.Additionally,Mg-Zn-Ca-xNi(0≤x≤5)alloys exhibit tunable ultimate tensile strengths ranging from~190 to~237 MPa,depending on their specific composition.The adjustable corrosion rate and mechanical properties render the Mg-Zn-Ca-x Ni(0≤x≤5)alloys suitable for fracturing materials.
基金supported by a Matching Fund between Tham-masat University Research Fund and the National Taipei University of Technology(Taipei Tech),contract no MF 1/2567National Taipei University of Technology-Thammasat University Joint Research Program(NTUT-TU Joint Research Program NTUT-TU-113-03).
文摘Protein fibers derived from silk fibroin(SF)were chemically extracted and purified from cocoons.It was used as a reinforced fiber for hydrogel formation with collagen(Col)and hyaluronic acid(HA).Calcium chloride(8 wt.%)was employed as a crosslinking reagent to synthesize the SF/Col/HA-based hydrogel composite.FTIR spec-troscopy confirmed the presence of N-H stretching due to the plane bending of amide II in theβ-sheet structure.XRD analysis confirmed the crystallinity of the SF/Col/HA-based hydrogel composite.Scanning electron mi-croscopy revealed three-dimensional porous structures with interconnected pores.These porous structures can serve as reservoirs for storing adsorbent media.The hydrogel composite was thermally stable at 250℃.The lowboiling bound solvent evaporation temperature,glass transition temperature,and degradation temperature were 102℃-105℃,298℃-300℃,and 524℃-545℃,respectively.The ranges of porosity and gel fraction were 60%-80%and 90%-95%,respectively.The hydrogel composite was rapidly swollen within 1 h,reaching a plateau afterward.The compressive strength was 4-6 MPa.As absorbent media,hydrogels can easily adhere to lead ions via electrostatic interactions.They can be used as reservoirs for the adsorption of heavy metals.
基金supported by the National Natural Science Foundation of China(Nos.22201057 and 22472044)Zhejiang Provincial Natural Science Foundation of China(Nos.LR22B010001 and LQ23B010001)。
文摘In this work,we synthesize two luminescent Pt(Ⅱ)complexes using differentπ-conjugated bidentate ligands.Both complexes are assembled into three-dimensional(3D)networks through non-classical intermolecular interactions in the crystal state.Unexpectedly,substituting pyridine with the more extensivelyπ-conjugated quinoline significantly increases the dihedral angles between the phenyl and quinolyl groups of the bidentate ligands.This alteration disrupts theπ-πinteractions between molecules,resulting in distinct optical properties upon exposure to external stimuli.By integrating these complexes into polymers,we fabricate electrospun films containing luminescent nanofibers that exhibit reversible optical changes.These findings have paved the way for the development of high-performance optical encryption and anti-counterfeiting materials,achieved through the employment of simple chromophores.
基金supported by Zhejiang Provincial Natural Science Foundation of China under(LD22A020002)National Natural Science Foundation of China(52473116,22322508)+1 种基金International Cooperation Project of Ningbo City(2023H019)the Sino-German mobility program(M-0424).
文摘Supramolecular materials,characterized by dynamic reversibility and responsiveness to environmental stimuli,have found widespread applications in numerous fields.Unlike traditional materials,supramolecular materials that rely on non-covalent interactions can allow spontaneous reorganization and self-healing at room temperature.However,these materials typically exhibit low strength due to the weak bonding energies of non-covalent interactions.This study presents the development of a high-strength self-healing supramolecular material that combines multiple interactions including ionic bonding,hydrogen bonding,and coordination bonding.The material,formed by the aggregation of the negatively charged picolinate-grafted copolymer(PCM)with positively charged hyperbranched molecules(HP),is further enhanced by Eu^(3+)ion complexation.The resulting film exhibits a high modulus of 427 MPa,tensile strength of 10.5 MPa,and toughness of 14.7 MJ m^(−3).Meanwhile,the non-covalent interaction of this supramolecular material endows it with a self-healing efficiency of 92%within 24 h at room temperature,as well as multiple remolding properties.The incorporation of lanthanide ions also imparts tunable fluorescence.This study not only provides insights into the development of high-strength self-healing materials but also offers new possibilities for the functionalization of supramolecular materials.
基金supported by the Science and Technology Research Project of Changchun City(24GXYSZZ01)the Natural Science Foundation of Jilin Province(NO.20220101036JC)。
文摘Ni-rich cathode materials have become the mainstream choice in the mileage electric vehicle sector due to their high specific capacity and safety factor.However,the volume changes occurring during charging and discharging lead to microcracking and surface remodeling,posing challenges to achieving such as high specific capacity and long cycle stability.This paper reviews existing modification strategies for Ni-rich layered oxide cathode materials.Unlike previous reviews and related papers,we comprehensively discuss a variety of modification strategies and deeply discuss the synergistic modification effect of surface coating and bulk doping,which is how to improve the cycling stability of the Ni-rich cathode.In addition,based on recent research advances,the prospects and challenges of modifying Ni-rich layered cathodes for cycle stability upgrading of the lithium-ion battery,as well as the potential application prospects in the field of power automobiles,are comprehensively analyzed.
基金supported by the National Natural Science Foundation of China(Nos.52222602,and52236006)the Fundamental Research Funds for the Central Universities(Nos.FRF-EYIT-23-05,and FRF-TP-22-001C1)+1 种基金Noncommunicable Chronic Diseases-National Science and Technology Major Project(No.2023ZD0500902)the member of the Youth Innovation Promotion Association Foundation of CAS,China(No.2023310)。
文摘Investigating thermal transport mechanisms at the interface between phase change materials(PCMs)and high thermally conductive fillers has become increasingly significant in developing phase change energy storage technologies.This study explores the interfacial thermal transport between a representative PCM,erythritol,and various fillers,including crystalline(Si C,Si_(3)N_(4))and amorphous(Si O_(2))nanoparticles,using molecular dynamics(MD)simulations.Additionally,time-domain thermoreflectance(TDTR)experiments were performed to quantify the interfacial thermal conductance between erythritol and the three types of fillers,yielding values of 50.1,40.0,and25.6 MW m^(–2)K^(-1).These results align well with the trends observed in the simulations.Furthermore,the underlying mechanisms of interfacial heat transfer were analyzed by examining the phonon density of states,overlap energy,and interaction energy.This research provides innovative insights into nanoscale interfacial thermal transport in composite PCMs.This could lead to significant advancements in thermal management technologies,particularly in developing more efficient thermal energy storage systems.
基金supported by Natural Science Foundation of Ningxia Province,China(No.2023AAC05047)Special Project for the Central-Guided Local Science and Technology Development(No.2024FRD05062)+1 种基金Graduate Student Innovation Project of North Minzu University(No.YCX24102)Ningxia Science and Technology Innovation Team for Key Materials and Devices in High-Performance Secondary Batteries(No.2024CXTD003).
文摘Although manganese-based oxide is regarded as a promising cathode material for zincion hybrid supercapacitors(ZHSCs),its practical application is hindered by slow zinc ion diffusion and the instability of MnO_(2).To overcome this obstacle,a δ-MnO_(2)/MXene heterostructure was created using a simple one-step process under gentle condition.The ZHSC was assembled using this heterostructure as the cathode,activated carbon(AC)as the anode and 2 mol·L−1 ZnSO_(4) as the electrolyte.The resultingδ-MnO_(2)/MXene//ZnSO4//AC ZHSC shows a maximum specific capacitance of 97.4 F·g^(−1) and an energy density of 32.27 Wh·kg^(−1) at the best cathode-to-anode mass ratio.Ex situ characterizations reveal the reversible energy storage mechanism combing Zn^(2+)insertion/extraction in the cathode,ion adsorption and desorption on the anode surface,and partial reversible formation and dissolution of Zn_(4)SO_(4)(OH)_(6)·5H_(2)O(ZHS)components on both electrodes.Adding of Mn^(2+)to the electrolyte reduced Mn dissolution,improving the ZHSC’s specific capacitance and energy density to 140.4 F·g^(−1) and 49.36 Wh·kg^(−1),respectively,while also enhancing its rate performance and cyclability.The improved electrochemical reaction kinetics was verified through various tests.The results suggest that the δ-MnO_(2)/MXene heterostructure has great potential as a high-performance cathode material for ZHSCs.
