Development of suitable materials that acts as an interface between the implant and tissues in body system structurally, mechanically and bio functionally is important for the success of tissue engineering. This motiv...Development of suitable materials that acts as an interface between the implant and tissues in body system structurally, mechanically and bio functionally is important for the success of tissue engineering. This motivated materials scientists and biologists to find out suitable bioactive materials for the aforementioned purpose. There has been growing interest in developing bioactive synthetic ceramics that could closely mimic natural apatite characteristics. Hydroxyapatite (HAp) has been widely used as a biocompatible ceramic but mainly for contact with bone tissue, due to its resemblance to mineral bone. This study presents the synthesis and characterization of HAp materials from different sources like bovine bone and fish scales and their application in tissue engineering. The phase purity and crystallinity of different calcined HAp powder was determined by XRD and FTIR analysis. The Thermo Gravimetric and Differential Thermal Analysis were carried out to show the thermal stability of the HAp powder. The morphology of the powder was observed under Scanning Electron Microscopy (SEM). Cytotoxicity evaluation of the developed powder was carried out in RAW macrophage like cell line media for an incubation period of 72 hours. These results proved the biocompatibility of HAp powders obtained from different biosources for tissue engineering applications.展开更多
Electromagnetic devices have been widely used in the fields of information communication,medical treatment,electrical engineering,and national defense,and their properties are strongly dependent on the constituent ele...Electromagnetic devices have been widely used in the fields of information communication,medical treatment,electrical engineering,and national defense,and their properties are strongly dependent on the constituent electromagnetic materials.Conversely,electromagnetic metamaterials(EMMs),which are artificially engineered with distinctive electromagnetic properties,can overcome the limitations of natural materials owing to their structural advantages.Three-dimensional(3D)printing is the most effec-tive technique for fabricating EMM devices with different geometric parameters and associated proper-ties.However,conventional 3D-printed EMM devices may lack manufacturing flexibility and environmental adaptability to different physical stimuli,such as electric and magnetic fields.Four-dimensional(4D)printing is an ideal technique for schemes to integrate structural design with intelligent materials environmentally adaptive to external fields,for example,the printed components can change shape under electric stimulation.Given the rapid advancements in the EMM field,this paper first reviews typical EMM devices,their design theories,and underlying principles.Subsequently,it presents various EMM structural topologies and manufacturing technologies,emphasizing the feasibility of combining 3D and 4D printing.In addition,we highlight the important applications of EMMs and their future trends and the challenges associated with functional EMMs and additive manufacturing.展开更多
1.Introduction To design novel architectures with unique properties that surpass those of natural matter,scientists have developed diverse structures/materials by incorporating artificial structures of periodic/aperio...1.Introduction To design novel architectures with unique properties that surpass those of natural matter,scientists have developed diverse structures/materials by incorporating artificial structures of periodic/aperiodic nano-,micro-,and macro-scale,so called metamaterials.展开更多
Machine learning(ML)methods have been extensively applied to optimize additive manufacturing(AM)process parameters.However,existing studies predominantly focus on the relationship between processing parameters and pro...Machine learning(ML)methods have been extensively applied to optimize additive manufacturing(AM)process parameters.However,existing studies predominantly focus on the relationship between processing parameters and properties for specifc alloys,thus limiting their applicability to a broader range of materials.To address this issue,dimensionless parameters,which can be easily calculated from simple analytical expressions,were used as inputs to construct an ML model for classifying the relative density in laser-powder bed fusion.The model was trained using data from four widely used alloys collected from literature.The accuracy and generalizability of the trained model were validated using two laser-powder bed fusion(L-PBF)high-entropy alloys that were not included in the training process.The results demonstrate that the accuracy scores for both cases exceed 0.8.Moreover,the simple dimensionless inputs in the present model can be calculated conveniently without numerical simulations,thereby facilitating the recommendation of process parameters.展开更多
Hot compression experiments were conducted under conditions of deformation temperatures ranging from 950 to 1150℃,strain rates of 0.001-10 s^(-1),and deformation degrees ranging from 20%to 80%.The hot deformation beh...Hot compression experiments were conducted under conditions of deformation temperatures ranging from 950 to 1150℃,strain rates of 0.001-10 s^(-1),and deformation degrees ranging from 20%to 80%.The hot deformation behavior and microstructure evolution of millimeter-grade coarse grains(MCGs)in the as-cast Ti-6Cr-5Mo-5V-4Al(Ti-6554)alloy were studied,and a hot processing map was established.Under compression along the rolling direction(RD),continuous dynamic recrystallization(CDRX)ensues due to the progressive rotation of subgrains within the MCGs.Along the transverse direction(TD),discontinuous dynamic recrystallization(DDRX)resulting from grain boundary bulging or bridging,occurs on the boundaries of the MCGs.With decreasing strain rate,increasing temperature,and higher deformation degree,dynamic recrystallization becomes more pronounced,resulting in a reduction in the original average grain size.The optimal processing parameters fall within a temperature range of 1050-1150℃,a strain rate of 0.01 s^(-1),and a deformation degree between 40%and 60%.展开更多
Vibration isolation is vital in engineering machinery,as it not only seriously affects the service life of machine components but also reduces the operating efficiency.Recently,metamaterials have been proposed for cus...Vibration isolation is vital in engineering machinery,as it not only seriously affects the service life of machine components but also reduces the operating efficiency.Recently,metamaterials have been proposed for customized vibration-isolation needs through various functional designs.As a synthetic material,polymer materials have the advantages of good elasticity,low density,high specific strength,good corrosion resistance and easy processing,making it an ideal raw material for vibration-isolation metamaterials.At the same time,the rapid development of additive manufacturing(AM)provides a feasible method for preparing polymeric vibration-isolation metamaterials with complex structures.In this paper,we systematically analyze the vibration-isolation mechanism of metamaterials,review the applications of metamaterials in vibration isolation and the research on polymer metamaterials,and survey the AM process methods for polymer metamaterials.Finally,the prospects and directions for the development of polymer vibration-isolation metamaterials are envisioned,providing new ideas for further research on polymer metamaterials in the field of vibration isolation.展开更多
Controlling low-frequency noise presents a significant challenge for traditional sound absorption materials,such as foams and fibrous substances.Recently developed acoustic absorption metamaterials,which rely on local...Controlling low-frequency noise presents a significant challenge for traditional sound absorption materials,such as foams and fibrous substances.Recently developed acoustic absorption metamaterials,which rely on local resonance can effectively balance the volume occupation and low-frequency absorption performance.However,these materials often exhibit a very narrow and fixed absorption band.Inspired by Helmholtz resonators and bistable structures,we propose bistable reconfigurable acoustic metamaterials(BRAMs)that offer multiband low-frequency absorption.These BRAMs are fabricated using shape-memory polylactic acid(SM-PLA)via four-dimension(4D)printing technology.Consequently,the geometry and absorption performance of the BRAMs can be adjusted by applying thermal stimuli(at 55℃)to switch between two stable states.The BRAMs demonstrate excellent low-frequency absorption with multiband characteristics,achieving an absorption coefficient of 0.981 at 136 Hz and 0.998 at 230 Hz for stable state I,and coefficients of 0.984 at 156 Hz and 0.961 at 542 Hz for stable state II.It was found that the BRAMs with different inclined plate angles had linear recovery stages,and the recovery speeds range from 0.75 mm/s to 1.1 mm/s.By combining a rational structural design and 4D printing,the reported reconfigurable acoustic metamaterials will inspire further studies on the design of dynamic and broadband absorption devices.展开更多
Although a new-class of heat pumps based on mechanically flexible nanoporous materials holds great poten-tial for the utilization of sustainable refrigerants with a considerably high coefficient of performance(COP),re...Although a new-class of heat pumps based on mechanically flexible nanoporous materials holds great poten-tial for the utilization of sustainable refrigerants with a considerably high coefficient of performance(COP),reducing their system volume remains a challenge.In this study,we explored the potential of this innovative type of heat pump in terms of COP and system volume.To broaden the scope of material exploration,we devised a new thermodynamic heat pump system applicable to soft mesoporous materials,in addition to the conventional system that is suitable only for flexible microporous materials.Several key factors have been identified through the comparison of various nanoporous materials and refrigerants.Our systematic investigation reveals that the combination of mechanically softer nanoporous materials with ammonia refrigerants can achieve a high COP and a reduced system volume.展开更多
Al_(2)O_(3)-based eutectic ceramics are considered as promising candidates for ultra-high-temperature structural materials due to their exceptional thermal stability and mechanical properties.Nonetheless,several chall...Al_(2)O_(3)-based eutectic ceramics are considered as promising candidates for ultra-high-temperature structural materials due to their exceptional thermal stability and mechanical properties.Nonetheless,several challenges must be overcome before they can be widely used.This paper reviews in detail the tailoring of microstructure from the aspect of process parameters,the updated knowledge gained in microstructure(crystallographic orientation,high-resolution interfacial structures)and the latest means of optimizing eutectic microstructure(seed-induced method,introducing low-energy grain boundaries and high-entropy phase).Additionally,the paper explores future techniques for the fabrication of bulk ceramic materials and effective toughening approaches.This review highlights the achievements made especially in the last 15 years,current limitations in Al_(2)O_(3)-based eutectic ceramics,and offers comprehensive insights and strategic guidance for further mechanical breakthroughs.展开更多
Doping modification is one of the most effective ways to optimize the thermoelectric properties of Bi_(2)Te_(3)-based alloys.P-type Bi_(2−x)Sb_(x)Te_(3) thermoelectric materials have been successfully prepared by dire...Doping modification is one of the most effective ways to optimize the thermoelectric properties of Bi_(2)Te_(3)-based alloys.P-type Bi_(2−x)Sb_(x)Te_(3) thermoelectric materials have been successfully prepared by direct Sb doping method.It can be found that doping Sb into Bi_(2)Te_(3) lattice array for Bi-site replacement facilitates the generation of Sb′Te anti-site defects.This anti-site defects can increase the hole concentration and optimize electrical transport properties of Bi_(2−x)Sb_(x)Te_(3) alloys.In addition,the point defects induced by mass and stress fluctuations and the Sb impurities produced during the sintering process can enhance the multi-scale phonon scattering and reduce the lattice thermal conductivity.As a result,the Bi_(0.47)Sb_(1.63)Te_(3) sample has a maximum thermoelectric figure of merit ZT of 1.04 at 350 K.It is worth noting that the bipolar effect of Bi_(2)Te_(3)-based alloys can be weakened with the increase of Sb content.The Bi_(0.44)Sb_(1.66)Te_(3) sample has a maximum average ZT value(0.93)in the temperature range of 300–500 K,indicating that direct doping of Sb can broaden the temperature range corresponding to the optimal ZT value.This work provides an idea for developing high-performance near room temperature thermoelectric materials with a wide temperature range.展开更多
Titanium plates with a Ti−O solid solution surface-hardened layer were cold roll-bonded with 304 stainless steel plates with high work hardening rates.The evolution and mechanisms affecting the interfacial bonding str...Titanium plates with a Ti−O solid solution surface-hardened layer were cold roll-bonded with 304 stainless steel plates with high work hardening rates.The evolution and mechanisms affecting the interfacial bonding strength in titanium/stainless steel laminated composites were investigated.Results indicate that the hardened layer reduces the interfacial bonding strength from over 261 MPa to less than 204 MPa.During the cold roll-bonding process,the hardened layer fractures,leading to the formation of multi-scale cracks that are difficult for the stainless steel to fill.This not only hinders the development of an interlocking interface but also leads to the presence of numerous microcracks and hardened blocks along the nearly straight interface,consequently weakening the interfacial bonding strength.In metals with high work hardening rates,the conventional approach of enhancing interface interlocking and improving interfacial bonding strength by using a surface-hardened layer becomes less effective.展开更多
Machine learning-assisted methods for rapid and accurate prediction of temperature field,mushy zone,and grain size were proposed for the heating−cooling combined mold(HCCM)horizontal continuous casting of C70250 alloy...Machine learning-assisted methods for rapid and accurate prediction of temperature field,mushy zone,and grain size were proposed for the heating−cooling combined mold(HCCM)horizontal continuous casting of C70250 alloy plates.First,finite element simulations of casting processes were carried out with various parameters to build a dataset.Subsequently,different machine learning algorithms were employed to achieve high precision in predicting temperature fields,mushy zone locations,mushy zone inclination angle,and billet grain size.Finally,the process parameters were quickly optimized using a strategy consisting of random generation,prediction,and screening,allowing the mushy zone to be controlled to the desired target.The optimized parameters are 1234℃for heating mold temperature,47 mm/min for casting speed,and 10 L/min for cooling water flow rate.The optimized mushy zone is located in the middle of the second heat insulation section and has an inclination angle of roughly 7°.展开更多
Selective laser melting(SLM) is an attractive rapid prototyping technology for the fabrication of metallic components with complex structure and high performance. Aluminum alloy, one of the most pervasive structural m...Selective laser melting(SLM) is an attractive rapid prototyping technology for the fabrication of metallic components with complex structure and high performance. Aluminum alloy, one of the most pervasive structural materials, is well known for high specific strength and good corrosion resistance. But the poor laser formability of aluminum alloy restricts its application. There are problems such as limited processable materials, immature process conditions and metallurgical defects on SLM processing aluminum alloys. Some efforts have been made to solve the above problems. This paper discusses the current research status both related to the scientific understanding and technology applications. The paper begins with a brief introduction of basic concepts of aluminum alloys and technology characterization of laser selective melting. In addition, solidification theory of SLM process and formation mechanism of metallurgical defects are discussed. Then, the current research status of microstructure, properties and heat treatment of SLM processing aluminum alloys is systematically reviewed respectively. Lastly, a future outlook is given at the end of this review paper.展开更多
Magnesium(Mg)alloys have been extensively used in various fields,such as aerospace,automobile,electronics,and biomedical industries,due to their high specific strength and stiff ness,excellent vibration absorption,ele...Magnesium(Mg)alloys have been extensively used in various fields,such as aerospace,automobile,electronics,and biomedical industries,due to their high specific strength and stiff ness,excellent vibration absorption,electromagnetic shielding eff ect,good machinability,and recyclability.Friction stir processing(FSP)is a severe plastic deformation technique,based on the principle of friction stir welding.In addition to introducing the basic principle and advantages of FSP,this paper reviews the studies of FSP in the modification of the cast structure,superplastic deformation behavior,preparation of finegrained Mg alloys and Mg-based surface composites,and additive manufacturing.FSP not only refines,homogenizes,and densifies the microstructure,but also eliminates the cast microstructure defects,breaks up the brittle and network-like phases,and prepares fine-grained,ultrafine-,and nano-grained Mg alloys.Indeed,FSP significantly improves the comprehensive mechanical properties of the alloys and achieves low-temperature and/or high strain rate superplasticity.Furthermore,FSP can produce particle-and fiber-reinforced Mg-based surface composites.As a promising additive manufacturing technique of light metals,FSP enables the additive manufacturing of Mg alloys.Finally,we prospect the future research direction and application with friction stir processed Mg alloys.展开更多
Magnesium matrix nanocomposite reinforced with carbon nanotubes(CNTs/AZ91D) was fabricated by mechanical stirring and high intensity ultrasonic dispersion processing.The microstructures and mechanical properties of th...Magnesium matrix nanocomposite reinforced with carbon nanotubes(CNTs/AZ91D) was fabricated by mechanical stirring and high intensity ultrasonic dispersion processing.The microstructures and mechanical properties of the nanocomposite were investigated.The results show that CNTs are well dispersed in the matrix and combined with the matrix very well.As compared with AZ91D magnesium alloy matrix,the tensile strength,yield strength and elongation of the 1.5%CNTs/AZ91D nanocomposite are improved by 22%,21%and 42%respectively in permanent mold casting.The strength and ductility of the nanocomposite are improved simultaneously.The tensile fracture analysis shows that the damage mechanism of nanocomposite is still brittle fracture.But the CNTs can prevent the local crack propagation to some extent.展开更多
Researching for interphase materials that can protect SiC fibers from oxygen and water vapor attacks has become one of the most important issues for the applications of SiC_f/SiC composites in high-temperature combust...Researching for interphase materials that can protect SiC fibers from oxygen and water vapor attacks has become one of the most important issues for the applications of SiC_f/SiC composites in high-temperature combustion environment. However, such kinds of interphase materials are not available yet. Herein,we report theoretically predicted properties of two promising interphase materials Y_5Si_3 C and Y_3Si_2C_2.Although crystallizing in different structures, they share the common features of layered structure,anisotropic chemical bonding, anisotropic electrical and mechanical properties, and low shear deformation resistance. The bulk moduli for Y_5Si_3C and Y_3Si_2C_2 are 78 and 93 GPa, respectively; while their shear moduli are 52 and 50GPa, respectively. The maximum to minimum Young's modulus ratios are1.44 for Y_5Si_3C and 3.27 for Y_3Si_2C_2. Based on the low shear deformation resistance and low Pugh's ratios(G/B = 0.666 forY_5Si_3C and 0.537 for Y_3Si_2C_2; G: shear modulus; B: bulk modulus), they are predicted as damage tolerant and soft ceramics with predicted Vickers hardness of 9.6 and 6.9 GPa, respectively.The cleavage plane and possible slip systems are(000 l) and(0001)[1120] and(1010)[0001] forY_5Si_3C,and those for Y_3Si_2C_2 are {h00} and(010)[101]. Since the oxidation products are water-vapor resistant Y2 Si2 O7, Y2 SiO5 and/or Y_2 O_3 upon oxidation, and the volume expansions are ca 140% and ca 26% for Y_5Si_3C and Y_3Si_2C_2, they are expected to seal the interfacial cracks in SiC_f/SiC composites. The unique combination of easy cleavage, low shear deformation resistance, volume expansions upon oxidation, and the resistance of the oxidation products to water vapor attack warrant them promising as interphase materials of SiC_f/SiC composites for water-vapor laden environment applications.展开更多
The hot deformation behavior and microstructure evolution of 6082 aluminum alloy fabricated through squeeze casting(SC)under different pressures were studied.The alloy was subjected to hot compression tests and 3D hot...The hot deformation behavior and microstructure evolution of 6082 aluminum alloy fabricated through squeeze casting(SC)under different pressures were studied.The alloy was subjected to hot compression tests and 3D hot processing maps were established.The microstructure evolution was studied by optical microscope(OM),scanning electron microscope(SEM),and electron backscattered diffraction(EBSD).It is found that more dynamic recrystallization(DRX)grains are generated during the deformation of the specimen fabricated under higher SC pressure.At high temperature the effect of SC pressure on microstructure evolution weakens due to the dissolution of second phase particles.In addition,uneven second phase particles in specimens fabricated under higher SC pressure compressed with low temperature and middle strain rate would result in flow localization instability.Finally,the optimum deformation conditions for the 6082 aluminum alloy fabricated by SC were obtained at the temperatures of 430−500℃ and the strain rates of 0.01−1 s^(−1).展开更多
Vacuum die casting can reduce the'air entrapment'phenomenon during casting process.Based on the temperature measurements at metal-die interface with different processing parameters,such as slow shot speed(VL),...Vacuum die casting can reduce the'air entrapment'phenomenon during casting process.Based on the temperature measurements at metal-die interface with different processing parameters,such as slow shot speed(VL),high shot speed(VH),pouring temperature(Tp)and initial die temperature(Tm),inverse method was developed to determine the interfacial heat transfer coefficient(IHTC).The results indicate that a closer contact between the casting and die could be achieved when the vacuum system is used.It is found that the vacuum could strongly increase the values of IHTC and decrease the grain size in castings.The IHTC could have a higher peak value with increasing the Tp from680to720℃or the VL from0.1to0.4m/s.In addition,the influence of the VH and Tm on IHTC could be negligible.展开更多
High strength β titanium alloys are widely used in large load bearing components in the aerospace field. At present, large parts are generally formed by die forging. Different initial microstructures and deformation ...High strength β titanium alloys are widely used in large load bearing components in the aerospace field. At present, large parts are generally formed by die forging. Different initial microstructures and deformation process parameters will significantly affect the flow behavior. To precisely control the microstructures, researchers have conducted many studies to analyze the microstructure evolution law and deformation mechanism during hot compression. This review focuses on the microstructure evolution of high strength β titanium alloys during hot deformation, including dynamic recrystallization and dynamic recovery in the single-phase region and the dynamic evolution of the α phase in the two-phase region. Furthermore, the optimal hot processing regions, instability regions,and the relationship between the efficiency of power dissipation and the deformation mechanism in the hot processing map are summarized. Finally, the problems and development direction of using hot processing maps to optimize process parameters are also emphasized.展开更多
Thermal barrier coating(TBC) materials play important roles in gas turbine engines to protect the Nibased super-alloys from the high temperature airflow damage. High melting point, ultra-low thermal conductivity, larg...Thermal barrier coating(TBC) materials play important roles in gas turbine engines to protect the Nibased super-alloys from the high temperature airflow damage. High melting point, ultra-low thermal conductivity, large thermal expansion coefficient, excellent damage tolerance and moderate mechanical properties are the main requirements of promising TBC materials. In order to improve the efficiency of jet and/or gas turbine engines, which is the key of improved thrust-to-weight ratios and the energysaving, significant efforts have been made on searching for enhanced TBC materials. Theoretically, density functional theory has been successfully used in scanning the structure and properties of materials, and at the same time predicting the mechanical and thermal properties of promising TBC materials for high and ultrahigh temperature applications, which are validated by subsequent experiments. Experimentally,doping and/or alloying are also widely applied to further decrease their thermal conductivities. Now, the strategy through combining theoretical calculations and experiments on searching for next generation thermal insulator materials is widely adopted. In this review, the common used techniques and the recent advantages on searching for promising TBC materials in both theory and experiments are summarized.展开更多
文摘Development of suitable materials that acts as an interface between the implant and tissues in body system structurally, mechanically and bio functionally is important for the success of tissue engineering. This motivated materials scientists and biologists to find out suitable bioactive materials for the aforementioned purpose. There has been growing interest in developing bioactive synthetic ceramics that could closely mimic natural apatite characteristics. Hydroxyapatite (HAp) has been widely used as a biocompatible ceramic but mainly for contact with bone tissue, due to its resemblance to mineral bone. This study presents the synthesis and characterization of HAp materials from different sources like bovine bone and fish scales and their application in tissue engineering. The phase purity and crystallinity of different calcined HAp powder was determined by XRD and FTIR analysis. The Thermo Gravimetric and Differential Thermal Analysis were carried out to show the thermal stability of the HAp powder. The morphology of the powder was observed under Scanning Electron Microscopy (SEM). Cytotoxicity evaluation of the developed powder was carried out in RAW macrophage like cell line media for an incubation period of 72 hours. These results proved the biocompatibility of HAp powders obtained from different biosources for tissue engineering applications.
基金sponsored by the National Natural Science Foundation of China(52275331 and 52205358)the National Key Research and Development Program of China(2023YFB4604800)+1 种基金the Key Research and Development Program of Hubei Province(2022BAA011)the Hong Kong Scholars Program(XJ2022014).
文摘Electromagnetic devices have been widely used in the fields of information communication,medical treatment,electrical engineering,and national defense,and their properties are strongly dependent on the constituent electromagnetic materials.Conversely,electromagnetic metamaterials(EMMs),which are artificially engineered with distinctive electromagnetic properties,can overcome the limitations of natural materials owing to their structural advantages.Three-dimensional(3D)printing is the most effec-tive technique for fabricating EMM devices with different geometric parameters and associated proper-ties.However,conventional 3D-printed EMM devices may lack manufacturing flexibility and environmental adaptability to different physical stimuli,such as electric and magnetic fields.Four-dimensional(4D)printing is an ideal technique for schemes to integrate structural design with intelligent materials environmentally adaptive to external fields,for example,the printed components can change shape under electric stimulation.Given the rapid advancements in the EMM field,this paper first reviews typical EMM devices,their design theories,and underlying principles.Subsequently,it presents various EMM structural topologies and manufacturing technologies,emphasizing the feasibility of combining 3D and 4D printing.In addition,we highlight the important applications of EMMs and their future trends and the challenges associated with functional EMMs and additive manufacturing.
基金financially supported by the National Key Research and Development Program of China(2023YFB4604800)the National Natural Science Foundation of China(52275331)financial support from the Hong Kong Scholars Program(XJ2022014)。
文摘1.Introduction To design novel architectures with unique properties that surpass those of natural matter,scientists have developed diverse structures/materials by incorporating artificial structures of periodic/aperiodic nano-,micro-,and macro-scale,so called metamaterials.
基金supported by the National Key R&D Program of China(Grant No.2023YFB4606502)the National Natural Science Foundation of China(Grant No.52471017)the Research Fund of the State Key Laboratory of Solidification Processing(NPU),China(Grant No.2020-TS-06).
文摘Machine learning(ML)methods have been extensively applied to optimize additive manufacturing(AM)process parameters.However,existing studies predominantly focus on the relationship between processing parameters and properties for specifc alloys,thus limiting their applicability to a broader range of materials.To address this issue,dimensionless parameters,which can be easily calculated from simple analytical expressions,were used as inputs to construct an ML model for classifying the relative density in laser-powder bed fusion.The model was trained using data from four widely used alloys collected from literature.The accuracy and generalizability of the trained model were validated using two laser-powder bed fusion(L-PBF)high-entropy alloys that were not included in the training process.The results demonstrate that the accuracy scores for both cases exceed 0.8.Moreover,the simple dimensionless inputs in the present model can be calculated conveniently without numerical simulations,thereby facilitating the recommendation of process parameters.
基金supported by the National Key Research and Development Program of China(Nos.2022YFB3706901,2022YFB3706903)the National Natural Science Foundation of China(No.52274382)。
文摘Hot compression experiments were conducted under conditions of deformation temperatures ranging from 950 to 1150℃,strain rates of 0.001-10 s^(-1),and deformation degrees ranging from 20%to 80%.The hot deformation behavior and microstructure evolution of millimeter-grade coarse grains(MCGs)in the as-cast Ti-6Cr-5Mo-5V-4Al(Ti-6554)alloy were studied,and a hot processing map was established.Under compression along the rolling direction(RD),continuous dynamic recrystallization(CDRX)ensues due to the progressive rotation of subgrains within the MCGs.Along the transverse direction(TD),discontinuous dynamic recrystallization(DDRX)resulting from grain boundary bulging or bridging,occurs on the boundaries of the MCGs.With decreasing strain rate,increasing temperature,and higher deformation degree,dynamic recrystallization becomes more pronounced,resulting in a reduction in the original average grain size.The optimal processing parameters fall within a temperature range of 1050-1150℃,a strain rate of 0.01 s^(-1),and a deformation degree between 40%and 60%.
基金supported by National Natural Science Foundation of China(Nos.52475398,52235008,and U2341270).
文摘Vibration isolation is vital in engineering machinery,as it not only seriously affects the service life of machine components but also reduces the operating efficiency.Recently,metamaterials have been proposed for customized vibration-isolation needs through various functional designs.As a synthetic material,polymer materials have the advantages of good elasticity,low density,high specific strength,good corrosion resistance and easy processing,making it an ideal raw material for vibration-isolation metamaterials.At the same time,the rapid development of additive manufacturing(AM)provides a feasible method for preparing polymeric vibration-isolation metamaterials with complex structures.In this paper,we systematically analyze the vibration-isolation mechanism of metamaterials,review the applications of metamaterials in vibration isolation and the research on polymer metamaterials,and survey the AM process methods for polymer metamaterials.Finally,the prospects and directions for the development of polymer vibration-isolation metamaterials are envisioned,providing new ideas for further research on polymer metamaterials in the field of vibration isolation.
基金financially supported by National Key Research and Development Program of China(Grant No.2023YFB4604800)National Natural Science Foundation of China(Grant No.52275331)financial support from the Hong Kong Scholars Program(Grant No.XJ2022014).
文摘Controlling low-frequency noise presents a significant challenge for traditional sound absorption materials,such as foams and fibrous substances.Recently developed acoustic absorption metamaterials,which rely on local resonance can effectively balance the volume occupation and low-frequency absorption performance.However,these materials often exhibit a very narrow and fixed absorption band.Inspired by Helmholtz resonators and bistable structures,we propose bistable reconfigurable acoustic metamaterials(BRAMs)that offer multiband low-frequency absorption.These BRAMs are fabricated using shape-memory polylactic acid(SM-PLA)via four-dimension(4D)printing technology.Consequently,the geometry and absorption performance of the BRAMs can be adjusted by applying thermal stimuli(at 55℃)to switch between two stable states.The BRAMs demonstrate excellent low-frequency absorption with multiband characteristics,achieving an absorption coefficient of 0.981 at 136 Hz and 0.998 at 230 Hz for stable state I,and coefficients of 0.984 at 156 Hz and 0.961 at 542 Hz for stable state II.It was found that the BRAMs with different inclined plate angles had linear recovery stages,and the recovery speeds range from 0.75 mm/s to 1.1 mm/s.By combining a rational structural design and 4D printing,the reported reconfigurable acoustic metamaterials will inspire further studies on the design of dynamic and broadband absorption devices.
文摘Although a new-class of heat pumps based on mechanically flexible nanoporous materials holds great poten-tial for the utilization of sustainable refrigerants with a considerably high coefficient of performance(COP),reducing their system volume remains a challenge.In this study,we explored the potential of this innovative type of heat pump in terms of COP and system volume.To broaden the scope of material exploration,we devised a new thermodynamic heat pump system applicable to soft mesoporous materials,in addition to the conventional system that is suitable only for flexible microporous materials.Several key factors have been identified through the comparison of various nanoporous materials and refrigerants.Our systematic investigation reveals that the combination of mechanically softer nanoporous materials with ammonia refrigerants can achieve a high COP and a reduced system volume.
基金financially supported by the National Natural Science Foundation of China(No.52171046)National Natural Science Foundation of China-key programme(No.52234010)the Fundamental Research Funds for the Central Universities and Shaanxi Provincial Key Science and Technology Innovation Team(No.2023-CX-TD-14).
文摘Al_(2)O_(3)-based eutectic ceramics are considered as promising candidates for ultra-high-temperature structural materials due to their exceptional thermal stability and mechanical properties.Nonetheless,several challenges must be overcome before they can be widely used.This paper reviews in detail the tailoring of microstructure from the aspect of process parameters,the updated knowledge gained in microstructure(crystallographic orientation,high-resolution interfacial structures)and the latest means of optimizing eutectic microstructure(seed-induced method,introducing low-energy grain boundaries and high-entropy phase).Additionally,the paper explores future techniques for the fabrication of bulk ceramic materials and effective toughening approaches.This review highlights the achievements made especially in the last 15 years,current limitations in Al_(2)O_(3)-based eutectic ceramics,and offers comprehensive insights and strategic guidance for further mechanical breakthroughs.
基金supported by the Anhui Province Natural Science Foundation for Excellent Youth Scholars(2208085Y17)the University Synergy Innovation Program of Anhui Province(GXXT-2022-008+1 种基金GXXT-2021-022)the Anhui Key Lab of Metal Material and Processing Open Project.
文摘Doping modification is one of the most effective ways to optimize the thermoelectric properties of Bi_(2)Te_(3)-based alloys.P-type Bi_(2−x)Sb_(x)Te_(3) thermoelectric materials have been successfully prepared by direct Sb doping method.It can be found that doping Sb into Bi_(2)Te_(3) lattice array for Bi-site replacement facilitates the generation of Sb′Te anti-site defects.This anti-site defects can increase the hole concentration and optimize electrical transport properties of Bi_(2−x)Sb_(x)Te_(3) alloys.In addition,the point defects induced by mass and stress fluctuations and the Sb impurities produced during the sintering process can enhance the multi-scale phonon scattering and reduce the lattice thermal conductivity.As a result,the Bi_(0.47)Sb_(1.63)Te_(3) sample has a maximum thermoelectric figure of merit ZT of 1.04 at 350 K.It is worth noting that the bipolar effect of Bi_(2)Te_(3)-based alloys can be weakened with the increase of Sb content.The Bi_(0.44)Sb_(1.66)Te_(3) sample has a maximum average ZT value(0.93)in the temperature range of 300–500 K,indicating that direct doping of Sb can broaden the temperature range corresponding to the optimal ZT value.This work provides an idea for developing high-performance near room temperature thermoelectric materials with a wide temperature range.
基金supported by the National Key R&D Program of China (No. 2018YFA0707300)the National Natural Science Foundation of China (No. 52374376)the Introduction Plan for High end Foreign Experts, China (No. G2023105001L)。
文摘Titanium plates with a Ti−O solid solution surface-hardened layer were cold roll-bonded with 304 stainless steel plates with high work hardening rates.The evolution and mechanisms affecting the interfacial bonding strength in titanium/stainless steel laminated composites were investigated.Results indicate that the hardened layer reduces the interfacial bonding strength from over 261 MPa to less than 204 MPa.During the cold roll-bonding process,the hardened layer fractures,leading to the formation of multi-scale cracks that are difficult for the stainless steel to fill.This not only hinders the development of an interlocking interface but also leads to the presence of numerous microcracks and hardened blocks along the nearly straight interface,consequently weakening the interfacial bonding strength.In metals with high work hardening rates,the conventional approach of enhancing interface interlocking and improving interfacial bonding strength by using a surface-hardened layer becomes less effective.
基金financially supported by the National Key Research and Development Program of China (No. 2023YFB3812601)the National Natural Science Foundation of China (No. 51925401)the Young Elite Scientists Sponsorship Program by CAST, China (No. 2022QNRC001)。
文摘Machine learning-assisted methods for rapid and accurate prediction of temperature field,mushy zone,and grain size were proposed for the heating−cooling combined mold(HCCM)horizontal continuous casting of C70250 alloy plates.First,finite element simulations of casting processes were carried out with various parameters to build a dataset.Subsequently,different machine learning algorithms were employed to achieve high precision in predicting temperature fields,mushy zone locations,mushy zone inclination angle,and billet grain size.Finally,the process parameters were quickly optimized using a strategy consisting of random generation,prediction,and screening,allowing the mushy zone to be controlled to the desired target.The optimized parameters are 1234℃for heating mold temperature,47 mm/min for casting speed,and 10 L/min for cooling water flow rate.The optimized mushy zone is located in the middle of the second heat insulation section and has an inclination angle of roughly 7°.
基金sponsored by National Key Research and Development Program "Additive Manufacturing and Laser Manufacturing" (No. 2016YFB1100101)Natural and Science Foundation of China (Grant Nos. 51775208, 51505166)+4 种基金Hubei Science Fund for Distinguished Young Scholars (No. 0216110085)Wuhan Morning Light Plan of Youth Science and Technology (No. 0216110066)Graduates’ Innovation Fund, Huazhong University of Science and Technology (No. 5003110027)Fundamental Research Funds for the Central University (No. 2017JYCXJJ004)the Academic frontier youth team at Huazhong University of Science and Technology (HUST)
文摘Selective laser melting(SLM) is an attractive rapid prototyping technology for the fabrication of metallic components with complex structure and high performance. Aluminum alloy, one of the most pervasive structural materials, is well known for high specific strength and good corrosion resistance. But the poor laser formability of aluminum alloy restricts its application. There are problems such as limited processable materials, immature process conditions and metallurgical defects on SLM processing aluminum alloys. Some efforts have been made to solve the above problems. This paper discusses the current research status both related to the scientific understanding and technology applications. The paper begins with a brief introduction of basic concepts of aluminum alloys and technology characterization of laser selective melting. In addition, solidification theory of SLM process and formation mechanism of metallurgical defects are discussed. Then, the current research status of microstructure, properties and heat treatment of SLM processing aluminum alloys is systematically reviewed respectively. Lastly, a future outlook is given at the end of this review paper.
基金sponsorship from the National Natural Science Foundation of China(Nos.51574192,51404180,51974220,and U1760201)the Key Industrial Research Program of Shaanxi Province,China(No.2017ZDXMGY-037)+1 种基金the National Key Research and Development Program of China(No.Z20180407)the Youth Innovation Team of Shaanxi Universities(No.2019-2022).
文摘Magnesium(Mg)alloys have been extensively used in various fields,such as aerospace,automobile,electronics,and biomedical industries,due to their high specific strength and stiff ness,excellent vibration absorption,electromagnetic shielding eff ect,good machinability,and recyclability.Friction stir processing(FSP)is a severe plastic deformation technique,based on the principle of friction stir welding.In addition to introducing the basic principle and advantages of FSP,this paper reviews the studies of FSP in the modification of the cast structure,superplastic deformation behavior,preparation of finegrained Mg alloys and Mg-based surface composites,and additive manufacturing.FSP not only refines,homogenizes,and densifies the microstructure,but also eliminates the cast microstructure defects,breaks up the brittle and network-like phases,and prepares fine-grained,ultrafine-,and nano-grained Mg alloys.Indeed,FSP significantly improves the comprehensive mechanical properties of the alloys and achieves low-temperature and/or high strain rate superplasticity.Furthermore,FSP can produce particle-and fiber-reinforced Mg-based surface composites.As a promising additive manufacturing technique of light metals,FSP enables the additive manufacturing of Mg alloys.Finally,we prospect the future research direction and application with friction stir processed Mg alloys.
文摘Magnesium matrix nanocomposite reinforced with carbon nanotubes(CNTs/AZ91D) was fabricated by mechanical stirring and high intensity ultrasonic dispersion processing.The microstructures and mechanical properties of the nanocomposite were investigated.The results show that CNTs are well dispersed in the matrix and combined with the matrix very well.As compared with AZ91D magnesium alloy matrix,the tensile strength,yield strength and elongation of the 1.5%CNTs/AZ91D nanocomposite are improved by 22%,21%and 42%respectively in permanent mold casting.The strength and ductility of the nanocomposite are improved simultaneously.The tensile fracture analysis shows that the damage mechanism of nanocomposite is still brittle fracture.But the CNTs can prevent the local crack propagation to some extent.
基金supported financially by the National Natural Science Foundation of China (Nos. U1435206 and 51672064)the Beijing Municipal Science & Technology Commission (No. D161100002416001)
文摘Researching for interphase materials that can protect SiC fibers from oxygen and water vapor attacks has become one of the most important issues for the applications of SiC_f/SiC composites in high-temperature combustion environment. However, such kinds of interphase materials are not available yet. Herein,we report theoretically predicted properties of two promising interphase materials Y_5Si_3 C and Y_3Si_2C_2.Although crystallizing in different structures, they share the common features of layered structure,anisotropic chemical bonding, anisotropic electrical and mechanical properties, and low shear deformation resistance. The bulk moduli for Y_5Si_3C and Y_3Si_2C_2 are 78 and 93 GPa, respectively; while their shear moduli are 52 and 50GPa, respectively. The maximum to minimum Young's modulus ratios are1.44 for Y_5Si_3C and 3.27 for Y_3Si_2C_2. Based on the low shear deformation resistance and low Pugh's ratios(G/B = 0.666 forY_5Si_3C and 0.537 for Y_3Si_2C_2; G: shear modulus; B: bulk modulus), they are predicted as damage tolerant and soft ceramics with predicted Vickers hardness of 9.6 and 6.9 GPa, respectively.The cleavage plane and possible slip systems are(000 l) and(0001)[1120] and(1010)[0001] forY_5Si_3C,and those for Y_3Si_2C_2 are {h00} and(010)[101]. Since the oxidation products are water-vapor resistant Y2 Si2 O7, Y2 SiO5 and/or Y_2 O_3 upon oxidation, and the volume expansions are ca 140% and ca 26% for Y_5Si_3C and Y_3Si_2C_2, they are expected to seal the interfacial cracks in SiC_f/SiC composites. The unique combination of easy cleavage, low shear deformation resistance, volume expansions upon oxidation, and the resistance of the oxidation products to water vapor attack warrant them promising as interphase materials of SiC_f/SiC composites for water-vapor laden environment applications.
基金financially supported by the National Natural Science Foundation of China (Nos.52090043,51725504)the Key Research and Development Program of Hubei Province,China (No.2020BAB040)the Fundamental Research Funds for the Central Universities,China (No.2021GCRC003)。
文摘The hot deformation behavior and microstructure evolution of 6082 aluminum alloy fabricated through squeeze casting(SC)under different pressures were studied.The alloy was subjected to hot compression tests and 3D hot processing maps were established.The microstructure evolution was studied by optical microscope(OM),scanning electron microscope(SEM),and electron backscattered diffraction(EBSD).It is found that more dynamic recrystallization(DRX)grains are generated during the deformation of the specimen fabricated under higher SC pressure.At high temperature the effect of SC pressure on microstructure evolution weakens due to the dissolution of second phase particles.In addition,uneven second phase particles in specimens fabricated under higher SC pressure compressed with low temperature and middle strain rate would result in flow localization instability.Finally,the optimum deformation conditions for the 6082 aluminum alloy fabricated by SC were obtained at the temperatures of 430−500℃ and the strain rates of 0.01−1 s^(−1).
基金Project (2016YFB0301001) supported by the National Key Research and Development Program of ChinaProject (2015M580093) supported by the General Financial Grant from the China Postdoctoral Science Foundation of China
文摘Vacuum die casting can reduce the'air entrapment'phenomenon during casting process.Based on the temperature measurements at metal-die interface with different processing parameters,such as slow shot speed(VL),high shot speed(VH),pouring temperature(Tp)and initial die temperature(Tm),inverse method was developed to determine the interfacial heat transfer coefficient(IHTC).The results indicate that a closer contact between the casting and die could be achieved when the vacuum system is used.It is found that the vacuum could strongly increase the values of IHTC and decrease the grain size in castings.The IHTC could have a higher peak value with increasing the Tp from680to720℃or the VL from0.1to0.4m/s.In addition,the influence of the VH and Tm on IHTC could be negligible.
基金supported by the Project of National Key Laboratory for Precision Hot Processing of Metals, Harbin Institute of Technology, China (No. 6142909190207)Shaanxi Key Laboratory of High-performance Precision Forming Technology and Equipment (SKL-HPFTE), China (No. PETE-2019-KF-01)。
文摘High strength β titanium alloys are widely used in large load bearing components in the aerospace field. At present, large parts are generally formed by die forging. Different initial microstructures and deformation process parameters will significantly affect the flow behavior. To precisely control the microstructures, researchers have conducted many studies to analyze the microstructure evolution law and deformation mechanism during hot compression. This review focuses on the microstructure evolution of high strength β titanium alloys during hot deformation, including dynamic recrystallization and dynamic recovery in the single-phase region and the dynamic evolution of the α phase in the two-phase region. Furthermore, the optimal hot processing regions, instability regions,and the relationship between the efficiency of power dissipation and the deformation mechanism in the hot processing map are summarized. Finally, the problems and development direction of using hot processing maps to optimize process parameters are also emphasized.
基金supported by the National Natural Science Foundation of China (No. 51602188)the Program for Professor of Special Appointment (Eastern Scholar)by Shanghai Municipal Education Commission (No. TP2015040)
文摘Thermal barrier coating(TBC) materials play important roles in gas turbine engines to protect the Nibased super-alloys from the high temperature airflow damage. High melting point, ultra-low thermal conductivity, large thermal expansion coefficient, excellent damage tolerance and moderate mechanical properties are the main requirements of promising TBC materials. In order to improve the efficiency of jet and/or gas turbine engines, which is the key of improved thrust-to-weight ratios and the energysaving, significant efforts have been made on searching for enhanced TBC materials. Theoretically, density functional theory has been successfully used in scanning the structure and properties of materials, and at the same time predicting the mechanical and thermal properties of promising TBC materials for high and ultrahigh temperature applications, which are validated by subsequent experiments. Experimentally,doping and/or alloying are also widely applied to further decrease their thermal conductivities. Now, the strategy through combining theoretical calculations and experiments on searching for next generation thermal insulator materials is widely adopted. In this review, the common used techniques and the recent advantages on searching for promising TBC materials in both theory and experiments are summarized.
