Efficient removal of formaldehyde from indoor environments is of significance for human health.In this work,a typical binary transition metal oxide that could provide various oxidation states,β-NiMoO4,was employed as...Efficient removal of formaldehyde from indoor environments is of significance for human health.In this work,a typical binary transition metal oxide that could provide various oxidation states,β-NiMoO4,was employed as a support to immobilize the active Pt component(Pt/NiMoO4)for catalytic formaldehyde elimination at low ambient temperature(15℃).The results showed that the hydrothermal preparation temperature and time had a noticeable impact on the morphology and catalytic activity of the samples.The catalyst prepared with hydrothermal temperature of 150℃for 4 hr(Pt-150-4)exhibited superior catalytic activity and stability mainly due to its distinctly porous structure,relative abundance of adsorbed surface hydroxyls/water,and high oxidation ability,which resulted from the interaction of Pt with Ni and Mo of the bimetallic NiMoO4 support.Our results might shed light on the rational design of multifunctional catalysts for removal of indoor air pollutants at low ambient temperature.展开更多
The complete decomposition of formaldehyde(HCHO) at ambient temperature is the most potential strategy for HCHO elimination from indoor environment.Herein,extra low content of Pt nanoparticles(0.025 wt%)supported on w...The complete decomposition of formaldehyde(HCHO) at ambient temperature is the most potential strategy for HCHO elimination from indoor environment.Herein,extra low content of Pt nanoparticles(0.025 wt%)supported on water-solubility carbon nitride/ceria(Pt/gC_(3)N_(4)@CeO_(2)) was prepared for gaseous HCHO removal at ambient temperature in a simulated indoor environment.Fluorescent light(8 W) illumination could visibly boost the complete decomposition of HCHO into CO_(2) over Pt/gC_(3)N_(4)@CeO_(2).The cooperative effect in the distinct heterostructure and plenty of surface reactive oxygen species contribute primarily to the enhanced catalytic performance of Pt/g-C_(3)N_(4)@CeO_(2).Moreover,the possible mechanism of HCHO oxidation over Pt/g-C_(3)N_(4)@CeO_(2) assisted by the fluorescent light irradiation was proposed based on the physicochemical and optical characterization as well as the result of in situ diffuse reflectance infrared Fourier transform spectra.This work might shed some light on the potential application of the versatile catalysts for ambient-temperature catalytic decomposition of HCHO by making full use of the indoor energies.展开更多
基金supported by the National Natural Science Foundation of China(Nos.21577046 and 21871111)Wuhan Morning Light plan of Youth Science and Technology(No.2017050304010327)
文摘Efficient removal of formaldehyde from indoor environments is of significance for human health.In this work,a typical binary transition metal oxide that could provide various oxidation states,β-NiMoO4,was employed as a support to immobilize the active Pt component(Pt/NiMoO4)for catalytic formaldehyde elimination at low ambient temperature(15℃).The results showed that the hydrothermal preparation temperature and time had a noticeable impact on the morphology and catalytic activity of the samples.The catalyst prepared with hydrothermal temperature of 150℃for 4 hr(Pt-150-4)exhibited superior catalytic activity and stability mainly due to its distinctly porous structure,relative abundance of adsorbed surface hydroxyls/water,and high oxidation ability,which resulted from the interaction of Pt with Ni and Mo of the bimetallic NiMoO4 support.Our results might shed light on the rational design of multifunctional catalysts for removal of indoor air pollutants at low ambient temperature.
基金financially supported by the National Natural Science Foundation of China(No.21871111)the Excellent Youth Foundation of Hubei Province of China(No.2019CFA078)。
文摘The complete decomposition of formaldehyde(HCHO) at ambient temperature is the most potential strategy for HCHO elimination from indoor environment.Herein,extra low content of Pt nanoparticles(0.025 wt%)supported on water-solubility carbon nitride/ceria(Pt/gC_(3)N_(4)@CeO_(2)) was prepared for gaseous HCHO removal at ambient temperature in a simulated indoor environment.Fluorescent light(8 W) illumination could visibly boost the complete decomposition of HCHO into CO_(2) over Pt/gC_(3)N_(4)@CeO_(2).The cooperative effect in the distinct heterostructure and plenty of surface reactive oxygen species contribute primarily to the enhanced catalytic performance of Pt/g-C_(3)N_(4)@CeO_(2).Moreover,the possible mechanism of HCHO oxidation over Pt/g-C_(3)N_(4)@CeO_(2) assisted by the fluorescent light irradiation was proposed based on the physicochemical and optical characterization as well as the result of in situ diffuse reflectance infrared Fourier transform spectra.This work might shed some light on the potential application of the versatile catalysts for ambient-temperature catalytic decomposition of HCHO by making full use of the indoor energies.
