The propagation of shock waves in a cellular bar is systematically studied in the framework of continuum solids by adopting two idealized material models, viz. the dynamic rigid, perfectly plastic, locking （D-R-PP-L...The propagation of shock waves in a cellular bar is systematically studied in the framework of continuum solids by adopting two idealized material models, viz. the dynamic rigid, perfectly plastic, locking （D-R-PP-L） model and the dynamic rigid, linear hardening plastic, locking （D-R-LHP-L） model, both considering the effects of strain-rate on the material properties. The shock wave speed relevant to these two models is derived. Consider the case of a bar made of one of such material with initial length L 0 and initial velocity v i impinging onto a rigid target. The variations of the stress, strain, particle velocity, specific internal energy across the shock wave and the cease distance of shock wave are all determined analytically. In particular the ＂energy conservation condition＂ and the ＂kinematic existence condition＂ as proposed by Tan et al. （2005） is re-examined, showing that the ＂energy conservation condition＂ and the consequent ＂critical velocity＂, i.e. the shock can only be generated and sustained in R-PP-L bars when the impact velocity is above this critical velocity, is incorrect. Instead, with elastic deformation, strain-hardening and strain-rate sensitivity of the cellular materials being considered, it is appropriate to redefine a first and a second critical impact velocity for the existence and propagation of shock waves in cellular solids. Starting from the basic relations for shock wave propagating in D-R-LHP-L cellular materials, a new method for inversely determining the dynamic stress-strain curve for cellular materials is proposed. By using e.g. a combination of Taylor bar and Hopkinson pressure bar impact experimental technique, the dynamic stress-strain curve of aluminum foam could bedetermined. Finally, it is demonstrated that this new formulation of shock theory in this one-dimensional stress state can be generalized to shocks in a one-dimensional strain state, i.e. for the case of plate impact on cellular materials, by simply making proper replacements of the elastic and plastic constants.展开更多
How the wave propagation analysis plays a key role in the studies of dynamic response of materials at high strain rates is analyzed. For the wave propagation technique, the followings are important: the loading and un...How the wave propagation analysis plays a key role in the studies of dynamic response of materials at high strain rates is analyzed. For the wave propagation technique, the followings are important: the loading and unloading constitutive relation presumed, the positions of the sensors embedded, the interactions between loading waves and unloading waves. For the split Hopkinson pressure bar (SHPB) technique, the assumption of one-dimensional stress wave propagation and the assumption of stress uniformity along the specimen should be satisfied. When the larger diameter bars are employed, the wave dispersion effects should be considered, including the high frequency oscillations, non-uniform stress distribution across the bar section, increase of rise time, and amplitude attenuation. The stress uniformity along the specimen is influenced by the reflection times in specimen, the wave impedance ratio of the specimen and the bar, and the waveform.展开更多
Cellular material under high-velocity impacthas a typical feature oflayer-wise collapse.A cell-based finite element model is employed to simulate the direct impact of closed-cell foam, and one-dimensional velocity fie...Cellular material under high-velocity impacthas a typical feature oflayer-wise collapse.A cell-based finite element model is employed to simulate the direct impact of closed-cell foam, and one-dimensional velocity field distributionsareobtained to characterize thecrushing bandpropagating through a cellular material. An explicit expression of continuous velocity distribution is derivedbased on the features of velocity gradient distribution. The velocity distribution function is adopted to determine the dynamic stress-strain statesof cellular materials under dynamic loading.The local stress-strain history distribution reveals that sectional cells experience a process from the precursor of elastic behavior to the shock stress state, through the dynamic initial crushing state. A power-law relation between the dynamic initial crushing stress andthe strainrate isestablished, which confirms the strain-rate effect of cellular materials. By extracting the critical points immediately before the unloading stage on the local dynamic stress-strain history curves, the dynamic stress-strain statesof cellular materials are determined. They exhibit loading rate-dependence but are independent of the initial impact velocity.Furthermore, with the increase of relative density, the dynamic hardening behaviorof cellular specimen is enhanced and the crushing process event is advanced. The particle velocity-based analytical method is appliedto analyze the dynamic responses of cellular materials.This method is better than continuum-based shock models, since itdoes not require a pre-assumed constitutive relation.Therefore,the particle velocity-based analytical method proposed in this study may provide new ideas to carry out dynamic experimental measurement, which is especially applicable toinhomogeneous materials.展开更多
ZnO nanostructure materials doped with different La contents were synthesized by sonochemical method. The products were characterized by X-ray diffraction（XRD）, scanning electron microscopy（SEM）,transmission elect...ZnO nanostructure materials doped with different La contents were synthesized by sonochemical method. The products were characterized by X-ray diffraction（XRD）, scanning electron microscopy（SEM）,transmission electron microscopy（TEM）, Raman spectroscopy, and Fourier transform infrared spectroscopy（FTIR）. In this research, XRD patterns of pure ZnO and La-doped ZnO are specified as hexagonal wurtzite ZnO structure with no detection of La2O3 phase. SEM and TEM characterization revealed the flower shape of pure ZnO built-up from petals of hexagonal prisms with hexagonal pyramid tips. Upon doping with La, the flower-shaped ZnO is broken into individual 1D prism-like nanorods. Photocatalytic activities of the as-synthesized products were determined by measuring the degradation of methylene blue（MB） under ultraviolet–visible（UV） light irradiation.Among them, the 2.0 mol% La-doped ZnO shows better photocatalytic properties than any other products.展开更多
A virtual Taylor impact of cellular materials is analyzed with a wave propagation technique, i.e. the Lagrangian analysis method, of which the main advantage is that no pre-assumed constitutive relationship is require...A virtual Taylor impact of cellular materials is analyzed with a wave propagation technique, i.e. the Lagrangian analysis method, of which the main advantage is that no pre-assumed constitutive relationship is required. Time histories of particle velocity, local strain, and stress profiles are calculated to present the local stress-strain history curves, from which the dynamic stress-strain states are obtained. The present results reveal that the dynamic-rigid-plastic hardening （D-R-PH） material model introduced in a previous study of our group is in good agreement with the dynamic stress-strain states under high loading rates obtained by the Lagrangian analysis method. It directly reflects the effectiveness and feasibility of the D-R-PH material model for the cellular materials under high loading rates.展开更多
Dynamic transformation(DT)of austenite(γ)to ferrite(α)in the hot deformation of various carbon steels was widely investigated.However,the nature of DT remains unclear due to the lack of quantitative analysis of stre...Dynamic transformation(DT)of austenite(γ)to ferrite(α)in the hot deformation of various carbon steels was widely investigated.However,the nature of DT remains unclear due to the lack of quantitative analysis of stress partitioning between two phases and the uncertainty of local distribution of substitu-tional elements at the interface in multi-component carbon steels used in the previous studies.Therefore,in the present study,a binary Fe-Ni alloy withα+γduplex microstructure in equilibrium was prepared and isothermally compressed inα+γtwo-phase region to achieve a quantitative analysis of microstruc-ture evolution,stress partitioning,and thermodynamics during DT.γtoαDT during isothermal compres-sion andαtoγreverse transformation on isothermal annealing under unloaded condition after deforma-tion were accompanied by Ni partitioning.The lattice strains during thermomechanical processing were obtained via in-situ neutron diffraction measurement,based on which the stress partitioning behavior betweenγandαwas discussed by using the generalized Hooke’s law.A thermodynamic framework for the isothermal deformation in solids was established based on the basic laws of thermodynamics,and it was shown that the total Helmholtz free energy change in the deformable material during the isothermal process should be smaller than the work done to the deformable material.Under the present thermody-namic framework,the microstructure evolution in the isothermal compression of Fe-14Ni alloy was well explained by considering the changes in chemical free energy,plastic and elastic energies,and the work done to the material.In addition,the stabilization of the softαphase in Fe-14Ni alloy by deformation was rationalized since theγtoαtransformation decreased the total Helmholtz free energy by decreasing the elastic and dislocation energies.展开更多
Kagome magnets were predicted to be a good platform to investigate correlated topology band structure,Chern quantum phase,and geometrical frustration due to their unique lattice geometry.Here we reported single crysta...Kagome magnets were predicted to be a good platform to investigate correlated topology band structure,Chern quantum phase,and geometrical frustration due to their unique lattice geometry.Here we reported single crystal growth of 166-type kagome magnetic materials,including HfMn_(6)Sn_(6),ZrMn_(6)Sn_(6),GdMn_(6)Sn_(6)and GdV_(6)Sn_(6),by using the flux method with Sn as the flux.Among them,HfMn_(6)Sn_(6)and ZrMn_(6)Sn_(6)single crystals were grown for the first time.X-ray diffraction measurements reveal that all four samples crystallize in HfFe6Ge6-type hexagonal structure with space group P6/mmm.All samples show metallic behavior from temperature dependence of resistivity measurements,and the dominant carrier is hole,except for GdV6Sn6 which is electron dominated.All samples have magnetic order with different transition temperatures,HfMn_(6)Sn_(6),ZrMn_(6)Sn_(6)and GdV_(6)Sn_(6)are antiferromagnetic with TN of 541 K,466 K and 4 K respectively,while GdMn_(6)Sn_(6)is ferrimagnetic with the critical temperature of about 470 K.This study will enrich the research platform of magnetic kagome materials and help explore the novel quantum phenomena in these interesting materials.The dataset of specific crystal structure parameters for HfMn_(6)Sn_(6)are available in Science Data Bank,with the link.展开更多
The hysteresis of magnetoresistance observed in superconductors is of great interest due to its potential connectionwith unconventional superconductivity.In this study,we perform electrical transport measurements on k...The hysteresis of magnetoresistance observed in superconductors is of great interest due to its potential connectionwith unconventional superconductivity.In this study,we perform electrical transport measurements on kagome superconductorCsV_(3)Sb_(5)nanoflakes and uncover unusual hysteretic behavior of magnetoresistance in the superconducting state.This hysteresis can be induced by applying either a large DC or AC current at temperatures(T)well below the superconductingtransition temperature(T_(c)).As T approaches T_(c),similar weak hysteresis is also detected by applying a smallcurrent.Various scenarios are discussed,with particular focus on the effects of vortex pinning and the presence of timereversal-symmtery-breaking superconducting domains.Our findings support the latter,hinting at chiral superconductivityin kagome superconductors.展开更多
Concrete subjected to fire loads is susceptible to explosive spalling, which can lead to the exposure of reinforcingsteel bars to the fire, substantially jeopardizing the structural safety and stability. The spalling ...Concrete subjected to fire loads is susceptible to explosive spalling, which can lead to the exposure of reinforcingsteel bars to the fire, substantially jeopardizing the structural safety and stability. The spalling of fire-loaded concreteis closely related to the evolution of pore pressure and temperature. Conventional analytical methods involve theresolution of complex, strongly coupled multifield equations, necessitating significant computational efforts. Torapidly and accurately obtain the distributions of pore-pressure and temperature, the Pix2Pix model is adoptedin this work, which is celebrated for its capabilities in image generation. The open-source dataset used hereinfeatures RGB images we generated using a sophisticated coupled model, while the grayscale images encapsulate the15 principal variables influencing spalling. After conducting a series of tests with different layers configurations,activation functions and loss functions, the Pix2Pix model suitable for assessing the spalling risk of fire-loadedconcrete has been meticulously designed and trained. The applicability and reliability of the Pix2Pix model inconcrete parameter prediction are verified by comparing its outcomes with those derived fromthe strong couplingTHC model. Notably, for the practical engineering applications, our findings indicate that utilizing monochromeimages as the initial target for analysis yields more dependable results. This work not only offers valuable insightsfor civil engineers specializing in concrete structures but also establishes a robust methodological approach forresearchers seeking to create similar predictive models.展开更多
Critical impact velocity （CIV） of oxygen-free high-conductivity （OFHC） copper is experimentally measured with a novel facility in a gas gun system. The results are compared with the theoretical predictions using t...Critical impact velocity （CIV） of oxygen-free high-conductivity （OFHC） copper is experimentally measured with a novel facility in a gas gun system. The results are compared with the theoretical predictions using the typical constitutive relations, and the measured CIV value is much lower than the predictions. The difference of physical mechanisms in experiment and in theoretical calculation is discussed. It is suggested that the reduction of CIV in experiment would be related with the damage evolution in tensile copper that needs to be considered in the computation model.展开更多
The split Hopkinson pressure bar（SHPB） technique and the wave propagation inverse analysis（WPIA） technique are both extensively used to experimentally investigate the impact behavior of materials, although neither...The split Hopkinson pressure bar（SHPB） technique and the wave propagation inverse analysis（WPIA） technique are both extensively used to experimentally investigate the impact behavior of materials, although neither of them alone provides a fully satisfactory analysis. In the present paper, attention is given to new experimental techniques by incorporating a damagemodified constitutive model into the SHPB technique and combining the Hopkinson pressure bar（HPB） technique with WPIA. First, to distinguish the response due to dynamic constitutive behavior and the response due to dynamic damage evolution, the SHPB method incorporating a damage-modified constitutive model is developed, including an explicit damage-modified Zhu–Wang–Tang model and an implicit damage-modified constitutive model. Second, when the SHPB results become invalid, a method of combining new Lagrange inverse analyses with the HPB technique is developed, including cases of the HPB arranged in front of a long specimen and behind the specimen. As examples of these new methods, typical results are given for nonlinear viscoelastic polymers and concretes considering damage evolution, a super-elastic Ti–Ni alloy with phase transformation and an aluminum foam with shock waves propagating within it.展开更多
The determination of the precise thickness-shear frequency of electroded crystal plates has practical importance in quartz crystal resonator design and fabricatiom especially when the high fundamental thickness-shear ...The determination of the precise thickness-shear frequency of electroded crystal plates has practical importance in quartz crystal resonator design and fabricatiom especially when the high fundamental thickness-shear frequency has reduced the crystal plate thickness to such a degree that proper consideration of the effect of electrodes is very important. The electrodes effect as mass loading in the estimation of the resonance frequency has to be modified to consider the stiffness of electrodes, as the relative strength is increasingly noticeable. By following a known procedure in the determination of the thickness-shear frequency of an infinite AT-cut crystal plate, frequency equations of crystal plate without and with piezoelectric effect are obtained in terms of elastic constants and the electrode material density. After solving these equations for the usual design parameters of crystal resonators, the design process can be optimized to pinpoint the precise configuration to avoid time-consuming trial and reduction steps. Since these equations and solutions are presented for widely used materials and parameters, they can be easily integrated into the existing crystal resonator design and manufacturing processes.展开更多
The dynamic fracture behaviors of the extruded 2024-T4 and 7075-T6 aluminum alloys are investigated by using an instrumented drop tower machine.The specimens are made from a 25 mm diameter extruded circular rod.The dy...The dynamic fracture behaviors of the extruded 2024-T4 and 7075-T6 aluminum alloys are investigated by using an instrumented drop tower machine.The specimens are made from a 25 mm diameter extruded circular rod.The dynamic three-point bending tests of each alloy are carried out at different impact velocities.The initiation fracture toughness and average propagation fracture toughness of 2024-T4 and 7075-T6 are determined at different loading rates.The results show that both the initiation toughness and the propagation toughness increase with the loading rate.Further,the difference between the fracture toughness behaviors of 2024-T4 and 7075-T6 is found to be dependent on the variation of fracture mechanism.The comprehensive fractographic investigations of the fracture surfaces clearly demonstrate that the fracture mode of 2024-T4 is predominantly transgranular fracture with high density small-sized dimples,and the fracture mode of 7075-T6 is mainly intergranular fracture with many intermetallic particles in the bottom of voids located in the fracture surface.展开更多
The expansion property of cement mortar under the attack of sulfate ions is studied by experimental and theoretical methods. First, cement mortars are fabricated with the ratio of water to cement of 0.4, 0.6, and 0.8....The expansion property of cement mortar under the attack of sulfate ions is studied by experimental and theoretical methods. First, cement mortars are fabricated with the ratio of water to cement of 0.4, 0.6, and 0.8. Secondly, the expansion of specimen immerged in sulphate solution is measured at different times. Thirdly, a theoretical model of expansion of cement mortar under sulphate erosion is suggested by virtue of represent volume element method. In this model, the damage evolution due to the interaction between delayed ettringite and cement mortar is taken into account. Finally, the numerical calculation is results indicate that the model perfectly describes performed. The numerical and experimental the expansion of the cement mortar.展开更多
The wave dispersion due to the lateral inertia in the split Hopkinson pressure bar(SHPB) with large-(diameter) bar is numerically analyzed by means of the LS-DYNA3D code. The results show that, ① the stress distribut...The wave dispersion due to the lateral inertia in the split Hopkinson pressure bar(SHPB) with large-(diameter) bar is numerically analyzed by means of the LS-DYNA3D code. The results show that, ① the stress distribution across the bar section is non-uniform along the radius direction and such non-uniformity depends on the material Poisson ratio and propagation distance; ② with increasing the bar diameter, the high frequency oscillations are notably enhanced and the rise time of wave front becomes longer, meanwhile the amplitude of the stress wave attenuates; ③ with decreasing the rise time of wave front, the wave dispersion markedly enhanced, particularly in the large diameter bar. All of those effects should not be neglected in order to obtain accurate results by the SHPB test..展开更多
The free carrier density and mobility in n-type 4H-SiC substrates and epilayers were determined by accurately analysing the frequency shift and the full-shape of the longitudinal optic phono-plasmon coupled （LOPC） m...The free carrier density and mobility in n-type 4H-SiC substrates and epilayers were determined by accurately analysing the frequency shift and the full-shape of the longitudinal optic phono-plasmon coupled （LOPC） modes, and compared with those determined by Hall-effect measurement and that provided by the vendors. The transport properties of thick and thin 4H-SiC epilayers grown in both vertical and horizontal reactors were also studied. The free carrier density ranges between 2× 10^18 cm^-3 and 8× 10^18 cm^-3with a carrier mobility of 30-55 cm2/（V.s） for ntype 4H-SiC substrates and 1× 10^16 -3× 10^16 cm^-3 with mobility of 290-490 cm2/（V.s） for both thick and thin 4H-SiC epilayers grown in a horizontal reactor, while thick 4H-SiC epilayers grown in vertical reactor have a slightly higher carrier concentration of around 8.1×10^16 cm^-3 with mobility of 380 cm2/（V.s）. It was shown that Raman spectroscopy is a potential technique for determining the transport properties of 4H-SiC wafers with the advantage of being able to probe very small volumes and also being non-destructive. This is especially useful for future mass production of 4H-SiC epi-wafers.展开更多
When manned spacecraft comes back to the earth, it relies on the impact attenuation seat to protect astronauts from injuries during landing phase. Hence, the seat needs to transfer impact load, as small as possible, t...When manned spacecraft comes back to the earth, it relies on the impact attenuation seat to protect astronauts from injuries during landing phase. Hence, the seat needs to transfer impact load, as small as possible, to the crew. However, there is little room left for traditional seat to improve further. Herein, a new seat system biologically-inspired by felids＇ landing is proposed. Firstly, a series of experiments was carried out on cats and tigers, in which they were trained to jump down voluntarily from different heights. Based on the ground reaction forces combined with kinematics, the experiment indicated that felids＇ landing after self-initial jump was a multi-step impact attenuation process and the new seat was inspired by this. Then the construction and work process of new seat were redesigned to realize the multi-step impact attenuation. The dynamic response of traditional and new seat is analyzed under the identical conditions and the results show that the new concept seat can significantly weaken the occupant overload in two directions compared with that of traditional seat. As a consequence, the risk of injury evaluated for spinal and head is also lowered, meaning a higher level of protection which is especially beneficial to the debilitated astronaut.展开更多
It is necessary to study the validation of strength models under planar shock loading in view of the fact that strength models for metals obtained at moderate strain rates are often used in the numerical simulations o...It is necessary to study the validation of strength models under planar shock loading in view of the fact that strength models for metals obtained at moderate strain rates are often used in the numerical simulations of shock wave phenomena. The variations of longitudinal stress, transverse stress and yield strength of oxygen-free high conductance （OFHC） copper with time under planar shock loading are obtained by using the manganin stress gauges and compared with the predicted results by the constructed seven constitutive models based on Y/G=constant and on G/B=constant （Y the yield strength, G the shear modulus, B the bulk modulus）, respectively. It seems that the pressure, density, temperature and plastic strain dependence of the yield strength for OFHC copper under planar shock loading is essential to the constitutive description.展开更多
基金supported by the National Natural Science Foundation of China (11032001)the K.C.Wong Magna Fund in Ningbo University
文摘The propagation of shock waves in a cellular bar is systematically studied in the framework of continuum solids by adopting two idealized material models, viz. the dynamic rigid, perfectly plastic, locking （D-R-PP-L） model and the dynamic rigid, linear hardening plastic, locking （D-R-LHP-L） model, both considering the effects of strain-rate on the material properties. The shock wave speed relevant to these two models is derived. Consider the case of a bar made of one of such material with initial length L 0 and initial velocity v i impinging onto a rigid target. The variations of the stress, strain, particle velocity, specific internal energy across the shock wave and the cease distance of shock wave are all determined analytically. In particular the ＂energy conservation condition＂ and the ＂kinematic existence condition＂ as proposed by Tan et al. （2005） is re-examined, showing that the ＂energy conservation condition＂ and the consequent ＂critical velocity＂, i.e. the shock can only be generated and sustained in R-PP-L bars when the impact velocity is above this critical velocity, is incorrect. Instead, with elastic deformation, strain-hardening and strain-rate sensitivity of the cellular materials being considered, it is appropriate to redefine a first and a second critical impact velocity for the existence and propagation of shock waves in cellular solids. Starting from the basic relations for shock wave propagating in D-R-LHP-L cellular materials, a new method for inversely determining the dynamic stress-strain curve for cellular materials is proposed. By using e.g. a combination of Taylor bar and Hopkinson pressure bar impact experimental technique, the dynamic stress-strain curve of aluminum foam could bedetermined. Finally, it is demonstrated that this new formulation of shock theory in this one-dimensional stress state can be generalized to shocks in a one-dimensional strain state, i.e. for the case of plate impact on cellular materials, by simply making proper replacements of the elastic and plastic constants.
文摘How the wave propagation analysis plays a key role in the studies of dynamic response of materials at high strain rates is analyzed. For the wave propagation technique, the followings are important: the loading and unloading constitutive relation presumed, the positions of the sensors embedded, the interactions between loading waves and unloading waves. For the split Hopkinson pressure bar (SHPB) technique, the assumption of one-dimensional stress wave propagation and the assumption of stress uniformity along the specimen should be satisfied. When the larger diameter bars are employed, the wave dispersion effects should be considered, including the high frequency oscillations, non-uniform stress distribution across the bar section, increase of rise time, and amplitude attenuation. The stress uniformity along the specimen is influenced by the reflection times in specimen, the wave impedance ratio of the specimen and the bar, and the waveform.
基金This work was supported by the National Natural Science Foundation of China (Grants 11802002, 11772330, and 11372308)the Fundamental Research Funds for the Central Universities (Grant WK2480000003)the Youth Foundation of Anhui University of Technology (Grant RD 17100204).
文摘Cellular material under high-velocity impacthas a typical feature oflayer-wise collapse.A cell-based finite element model is employed to simulate the direct impact of closed-cell foam, and one-dimensional velocity field distributionsareobtained to characterize thecrushing bandpropagating through a cellular material. An explicit expression of continuous velocity distribution is derivedbased on the features of velocity gradient distribution. The velocity distribution function is adopted to determine the dynamic stress-strain statesof cellular materials under dynamic loading.The local stress-strain history distribution reveals that sectional cells experience a process from the precursor of elastic behavior to the shock stress state, through the dynamic initial crushing state. A power-law relation between the dynamic initial crushing stress andthe strainrate isestablished, which confirms the strain-rate effect of cellular materials. By extracting the critical points immediately before the unloading stage on the local dynamic stress-strain history curves, the dynamic stress-strain statesof cellular materials are determined. They exhibit loading rate-dependence but are independent of the initial impact velocity.Furthermore, with the increase of relative density, the dynamic hardening behaviorof cellular specimen is enhanced and the crushing process event is advanced. The particle velocity-based analytical method is appliedto analyze the dynamic responses of cellular materials.This method is better than continuum-based shock models, since itdoes not require a pre-assumed constitutive relation.Therefore,the particle velocity-based analytical method proposed in this study may provide new ideas to carry out dynamic experimental measurement, which is especially applicable toinhomogeneous materials.
基金financially supported by the National Research University Project for Chiang Mai University (CMU) from the Thailand’s Office of the Higher Education Commission, Thailand
文摘ZnO nanostructure materials doped with different La contents were synthesized by sonochemical method. The products were characterized by X-ray diffraction（XRD）, scanning electron microscopy（SEM）,transmission electron microscopy（TEM）, Raman spectroscopy, and Fourier transform infrared spectroscopy（FTIR）. In this research, XRD patterns of pure ZnO and La-doped ZnO are specified as hexagonal wurtzite ZnO structure with no detection of La2O3 phase. SEM and TEM characterization revealed the flower shape of pure ZnO built-up from petals of hexagonal prisms with hexagonal pyramid tips. Upon doping with La, the flower-shaped ZnO is broken into individual 1D prism-like nanorods. Photocatalytic activities of the as-synthesized products were determined by measuring the degradation of methylene blue（MB） under ultraviolet–visible（UV） light irradiation.Among them, the 2.0 mol% La-doped ZnO shows better photocatalytic properties than any other products.
基金supported by the National Natural Science Foundation of China(11372308 and 11372307)the Fundamental Research Funds for the Central Universities(WK2480000001)
文摘A virtual Taylor impact of cellular materials is analyzed with a wave propagation technique, i.e. the Lagrangian analysis method, of which the main advantage is that no pre-assumed constitutive relationship is required. Time histories of particle velocity, local strain, and stress profiles are calculated to present the local stress-strain history curves, from which the dynamic stress-strain states are obtained. The present results reveal that the dynamic-rigid-plastic hardening （D-R-PH） material model introduced in a previous study of our group is in good agreement with the dynamic stress-strain states under high loading rates obtained by the Lagrangian analysis method. It directly reflects the effectiveness and feasibility of the D-R-PH material model for the cellular materials under high loading rates.
基金by JST FOREST Program(Grant No.JPMJFR203W,Japan)MEXT through Grant-in-Aid for Scientific Research(B)(No.19H02473,2019-2021)+2 种基金Grant-in-Aid for Scientific Research on Innovative Areas(Research in a proposed research area)(No.18H05456,2018-2022)the partial support through the research grant funded by the Amada Foundation(2022-2023)the financial support from the Amada Foundation(AF-2022017-B2).L.L.gratefully acknowledges the financial support provided by China Scholarship Council(No.201806295030)and thanks Dr.Elango Chandiran。
文摘Dynamic transformation(DT)of austenite(γ)to ferrite(α)in the hot deformation of various carbon steels was widely investigated.However,the nature of DT remains unclear due to the lack of quantitative analysis of stress partitioning between two phases and the uncertainty of local distribution of substitu-tional elements at the interface in multi-component carbon steels used in the previous studies.Therefore,in the present study,a binary Fe-Ni alloy withα+γduplex microstructure in equilibrium was prepared and isothermally compressed inα+γtwo-phase region to achieve a quantitative analysis of microstruc-ture evolution,stress partitioning,and thermodynamics during DT.γtoαDT during isothermal compres-sion andαtoγreverse transformation on isothermal annealing under unloaded condition after deforma-tion were accompanied by Ni partitioning.The lattice strains during thermomechanical processing were obtained via in-situ neutron diffraction measurement,based on which the stress partitioning behavior betweenγandαwas discussed by using the generalized Hooke’s law.A thermodynamic framework for the isothermal deformation in solids was established based on the basic laws of thermodynamics,and it was shown that the total Helmholtz free energy change in the deformable material during the isothermal process should be smaller than the work done to the deformable material.Under the present thermody-namic framework,the microstructure evolution in the isothermal compression of Fe-14Ni alloy was well explained by considering the changes in chemical free energy,plastic and elastic energies,and the work done to the material.In addition,the stabilization of the softαphase in Fe-14Ni alloy by deformation was rationalized since theγtoαtransformation decreased the total Helmholtz free energy by decreasing the elastic and dislocation energies.
基金the Beijing Natural Science Founda-tion(Grant No.Z210006)the National Key Research and De-velopment Program of China(Grant Nos.2022YFA1403400 and 2020YFA0308800)the Beijing National Labora-tory for Condensed Matter Physics(Grant No.2023BNL-CMPKF007).
文摘Kagome magnets were predicted to be a good platform to investigate correlated topology band structure,Chern quantum phase,and geometrical frustration due to their unique lattice geometry.Here we reported single crystal growth of 166-type kagome magnetic materials,including HfMn_(6)Sn_(6),ZrMn_(6)Sn_(6),GdMn_(6)Sn_(6)and GdV_(6)Sn_(6),by using the flux method with Sn as the flux.Among them,HfMn_(6)Sn_(6)and ZrMn_(6)Sn_(6)single crystals were grown for the first time.X-ray diffraction measurements reveal that all four samples crystallize in HfFe6Ge6-type hexagonal structure with space group P6/mmm.All samples show metallic behavior from temperature dependence of resistivity measurements,and the dominant carrier is hole,except for GdV6Sn6 which is electron dominated.All samples have magnetic order with different transition temperatures,HfMn_(6)Sn_(6),ZrMn_(6)Sn_(6)and GdV_(6)Sn_(6)are antiferromagnetic with TN of 541 K,466 K and 4 K respectively,while GdMn_(6)Sn_(6)is ferrimagnetic with the critical temperature of about 470 K.This study will enrich the research platform of magnetic kagome materials and help explore the novel quantum phenomena in these interesting materials.The dataset of specific crystal structure parameters for HfMn_(6)Sn_(6)are available in Science Data Bank,with the link.
基金supported by the“Pioneer”and“Leading Goose”R&D Program of Zhejiang(Grant No.2024SDXHDX0007)the National Natural Science Foundation of China(Grant No.12474131)+4 种基金the China Postdoctoral Science Foundation(Grant Nos.2022M722845 and 2023T160586)the Zhejiang Provincial Natural Science Foundation of China for Distinguished Young Scholars(Grant No.LR23A040001)the Research Center for Industries of the Future(RCIF)at Westlake University(Grant No.WU2023C009)the National Key R&D Program of China(Grant Nos.2020YFA0308800 and 2022YFA1403400)the Beijing Natural Science Foundation(Grant No.Z210006).The authors thank the support provided by Dr.Chao Zhang from Instrumentation and Service Center for Physical Sciences at Westlake University.
文摘The hysteresis of magnetoresistance observed in superconductors is of great interest due to its potential connectionwith unconventional superconductivity.In this study,we perform electrical transport measurements on kagome superconductorCsV_(3)Sb_(5)nanoflakes and uncover unusual hysteretic behavior of magnetoresistance in the superconducting state.This hysteresis can be induced by applying either a large DC or AC current at temperatures(T)well below the superconductingtransition temperature(T_(c)).As T approaches T_(c),similar weak hysteresis is also detected by applying a smallcurrent.Various scenarios are discussed,with particular focus on the effects of vortex pinning and the presence of timereversal-symmtery-breaking superconducting domains.Our findings support the latter,hinting at chiral superconductivityin kagome superconductors.
基金the National Natural Science Foundation of China(NSFC)(52178324).
文摘Concrete subjected to fire loads is susceptible to explosive spalling, which can lead to the exposure of reinforcingsteel bars to the fire, substantially jeopardizing the structural safety and stability. The spalling of fire-loaded concreteis closely related to the evolution of pore pressure and temperature. Conventional analytical methods involve theresolution of complex, strongly coupled multifield equations, necessitating significant computational efforts. Torapidly and accurately obtain the distributions of pore-pressure and temperature, the Pix2Pix model is adoptedin this work, which is celebrated for its capabilities in image generation. The open-source dataset used hereinfeatures RGB images we generated using a sophisticated coupled model, while the grayscale images encapsulate the15 principal variables influencing spalling. After conducting a series of tests with different layers configurations,activation functions and loss functions, the Pix2Pix model suitable for assessing the spalling risk of fire-loadedconcrete has been meticulously designed and trained. The applicability and reliability of the Pix2Pix model inconcrete parameter prediction are verified by comparing its outcomes with those derived fromthe strong couplingTHC model. Notably, for the practical engineering applications, our findings indicate that utilizing monochromeimages as the initial target for analysis yields more dependable results. This work not only offers valuable insightsfor civil engineers specializing in concrete structures but also establishes a robust methodological approach forresearchers seeking to create similar predictive models.
基金Supported by the National Natural Science Foundation of China under Grant No 10672082, the Scientific Research Fund of Zhejiang Provincial Education Department under Grant No 20061673, and K. C. Wong Magna Fund in Ningbo University.
文摘Critical impact velocity （CIV） of oxygen-free high-conductivity （OFHC） copper is experimentally measured with a novel facility in a gas gun system. The results are compared with the theoretical predictions using the typical constitutive relations, and the measured CIV value is much lower than the predictions. The difference of physical mechanisms in experiment and in theoretical calculation is discussed. It is suggested that the reduction of CIV in experiment would be related with the damage evolution in tensile copper that needs to be considered in the computation model.
基金supported by the National Natural Science Foundation of China(No.11032001)the K.C.Wong Magna Fund in Ningbo University
文摘The split Hopkinson pressure bar（SHPB） technique and the wave propagation inverse analysis（WPIA） technique are both extensively used to experimentally investigate the impact behavior of materials, although neither of them alone provides a fully satisfactory analysis. In the present paper, attention is given to new experimental techniques by incorporating a damagemodified constitutive model into the SHPB technique and combining the Hopkinson pressure bar（HPB） technique with WPIA. First, to distinguish the response due to dynamic constitutive behavior and the response due to dynamic damage evolution, the SHPB method incorporating a damage-modified constitutive model is developed, including an explicit damage-modified Zhu–Wang–Tang model and an implicit damage-modified constitutive model. Second, when the SHPB results become invalid, a method of combining new Lagrange inverse analyses with the HPB technique is developed, including cases of the HPB arranged in front of a long specimen and behind the specimen. As examples of these new methods, typical results are given for nonlinear viscoelastic polymers and concretes considering damage evolution, a super-elastic Ti–Ni alloy with phase transformation and an aluminum foam with shock waves propagating within it.
基金Project supported by the Qianjiang River Fellow Fund of ZhejiangProvince, and Bureau of Personnel and Human Resource, Ningbo,China
文摘The determination of the precise thickness-shear frequency of electroded crystal plates has practical importance in quartz crystal resonator design and fabricatiom especially when the high fundamental thickness-shear frequency has reduced the crystal plate thickness to such a degree that proper consideration of the effect of electrodes is very important. The electrodes effect as mass loading in the estimation of the resonance frequency has to be modified to consider the stiffness of electrodes, as the relative strength is increasingly noticeable. By following a known procedure in the determination of the thickness-shear frequency of an infinite AT-cut crystal plate, frequency equations of crystal plate without and with piezoelectric effect are obtained in terms of elastic constants and the electrode material density. After solving these equations for the usual design parameters of crystal resonators, the design process can be optimized to pinpoint the precise configuration to avoid time-consuming trial and reduction steps. Since these equations and solutions are presented for widely used materials and parameters, they can be easily integrated into the existing crystal resonator design and manufacturing processes.
基金supported by the NatiS100onal Science Foundation of China under Grant No.11072119the Defense Industrial Technology Development Program under Grant No.B1520110003+2 种基金the K.C.Wong Magna Foundation of Ningbo University,Chinaa grant from the Department of Education of Zhejiang Province through the Impact and Safety of Costal Engineering Initiativea COE Program at Ningbo University
文摘The dynamic fracture behaviors of the extruded 2024-T4 and 7075-T6 aluminum alloys are investigated by using an instrumented drop tower machine.The specimens are made from a 25 mm diameter extruded circular rod.The dynamic three-point bending tests of each alloy are carried out at different impact velocities.The initiation fracture toughness and average propagation fracture toughness of 2024-T4 and 7075-T6 are determined at different loading rates.The results show that both the initiation toughness and the propagation toughness increase with the loading rate.Further,the difference between the fracture toughness behaviors of 2024-T4 and 7075-T6 is found to be dependent on the variation of fracture mechanism.The comprehensive fractographic investigations of the fracture surfaces clearly demonstrate that the fracture mode of 2024-T4 is predominantly transgranular fracture with high density small-sized dimples,and the fracture mode of 7075-T6 is mainly intergranular fracture with many intermetallic particles in the bottom of voids located in the fracture surface.
基金supported by the National Natural Science Foundation of China(No.10572064)the National Basic Research Program of China(973 Program,2009CD623203)+1 种基金K.C.Wong Magna Fund in Ningbo Universitythe Natural Science Foundation of Zhejiang Province(No.Y107780).
文摘The expansion property of cement mortar under the attack of sulfate ions is studied by experimental and theoretical methods. First, cement mortars are fabricated with the ratio of water to cement of 0.4, 0.6, and 0.8. Secondly, the expansion of specimen immerged in sulphate solution is measured at different times. Thirdly, a theoretical model of expansion of cement mortar under sulphate erosion is suggested by virtue of represent volume element method. In this model, the damage evolution due to the interaction between delayed ettringite and cement mortar is taken into account. Finally, the numerical calculation is results indicate that the model perfectly describes performed. The numerical and experimental the expansion of the cement mortar.
文摘The wave dispersion due to the lateral inertia in the split Hopkinson pressure bar(SHPB) with large-(diameter) bar is numerically analyzed by means of the LS-DYNA3D code. The results show that, ① the stress distribution across the bar section is non-uniform along the radius direction and such non-uniformity depends on the material Poisson ratio and propagation distance; ② with increasing the bar diameter, the high frequency oscillations are notably enhanced and the rise time of wave front becomes longer, meanwhile the amplitude of the stress wave attenuates; ③ with decreasing the rise time of wave front, the wave dispersion markedly enhanced, particularly in the large diameter bar. All of those effects should not be neglected in order to obtain accurate results by the SHPB test..
基金supported by the National Natural Science Foundation of China (Grant No. 60876003)the Knowledge Innovation Project of Chinese Academy of Sciences (Grant Nos. Y072011000 and ISCAS2008T04)the Science and Technology Projects of the State Grid Corporation of China (ZL71-09-001)
文摘The free carrier density and mobility in n-type 4H-SiC substrates and epilayers were determined by accurately analysing the frequency shift and the full-shape of the longitudinal optic phono-plasmon coupled （LOPC） modes, and compared with those determined by Hall-effect measurement and that provided by the vendors. The transport properties of thick and thin 4H-SiC epilayers grown in both vertical and horizontal reactors were also studied. The free carrier density ranges between 2× 10^18 cm^-3 and 8× 10^18 cm^-3with a carrier mobility of 30-55 cm2/（V.s） for ntype 4H-SiC substrates and 1× 10^16 -3× 10^16 cm^-3 with mobility of 290-490 cm2/（V.s） for both thick and thin 4H-SiC epilayers grown in a horizontal reactor, while thick 4H-SiC epilayers grown in vertical reactor have a slightly higher carrier concentration of around 8.1×10^16 cm^-3 with mobility of 380 cm2/（V.s）. It was shown that Raman spectroscopy is a potential technique for determining the transport properties of 4H-SiC wafers with the advantage of being able to probe very small volumes and also being non-destructive. This is especially useful for future mass production of 4H-SiC epi-wafers.
基金financially supported by the National Natural Science Foundation of China (No. 11032001)
文摘When manned spacecraft comes back to the earth, it relies on the impact attenuation seat to protect astronauts from injuries during landing phase. Hence, the seat needs to transfer impact load, as small as possible, to the crew. However, there is little room left for traditional seat to improve further. Herein, a new seat system biologically-inspired by felids＇ landing is proposed. Firstly, a series of experiments was carried out on cats and tigers, in which they were trained to jump down voluntarily from different heights. Based on the ground reaction forces combined with kinematics, the experiment indicated that felids＇ landing after self-initial jump was a multi-step impact attenuation process and the new seat was inspired by this. Then the construction and work process of new seat were redesigned to realize the multi-step impact attenuation. The dynamic response of traditional and new seat is analyzed under the identical conditions and the results show that the new concept seat can significantly weaken the occupant overload in two directions compared with that of traditional seat. As a consequence, the risk of injury evaluated for spinal and head is also lowered, meaning a higher level of protection which is especially beneficial to the debilitated astronaut.
基金Supported by the National Natural Science Foundation of China under Grant No 10472048, and the Laboratory for Shock Wave and Detonation Physics Research, Institute of Fluid Physics, CAEP, under Grant No 9140C6702020603.
文摘It is necessary to study the validation of strength models under planar shock loading in view of the fact that strength models for metals obtained at moderate strain rates are often used in the numerical simulations of shock wave phenomena. The variations of longitudinal stress, transverse stress and yield strength of oxygen-free high conductance （OFHC） copper with time under planar shock loading are obtained by using the manganin stress gauges and compared with the predicted results by the constructed seven constitutive models based on Y/G=constant and on G/B=constant （Y the yield strength, G the shear modulus, B the bulk modulus）, respectively. It seems that the pressure, density, temperature and plastic strain dependence of the yield strength for OFHC copper under planar shock loading is essential to the constitutive description.
