Chalcogenide perovskites(CPs)based on zirconium(Zr)and hafnium(Hf)are becoming increasingly attractive as a new class of materials for next-generation solar cells.CPs with the ABX_(3) structure stand out due to their ...Chalcogenide perovskites(CPs)based on zirconium(Zr)and hafnium(Hf)are becoming increasingly attractive as a new class of materials for next-generation solar cells.CPs with the ABX_(3) structure stand out due to their attractive optical and electrical properties,such as efficient light absorption,direct bandgaps in the range of 1.1–2.1 eV,and remarkable defect tolerance,making them a compelling alternative to hybrid and double perovskites for solar energy conversion.Although theoretical studies have progressed rapidly,experimental verification still faces challenges such as the high synthesis temperatures required(>900℃),particularly in producing high-quality,phase-pure thin films and scalable solution-based processes.In this review,we aim to provide a comprehensive overview of the progress and remaining obstacles in advancing CP-based materials and devices.First,we describe the structure and composition as well as the different CPs in which the B site is occupied by Zr and Hf.Second,we summarize the methods used and the challenges that researchers face in producing an effective device.We highlight the main features that make CPs a preferred option for photovoltaic and other applications.Third,we look at the progress made in simulating solar cells that can achieve a power conversion efficiency(PCE)of over 30%using SCAPS-1D software.In the end,challenges and future research directions toward the development of CP materials and devices are provided.Overall,this review will serve as a valuable resource for researchers in selecting suitable strategies to achieve high-performance optoelectronic devices.展开更多
The use of cold thermal storage systems in low-temperature industrial applications is considered one of the most promising ways of improving energy efficiency and reducing the use of power during peak periods.In this ...The use of cold thermal storage systems in low-temperature industrial applications is considered one of the most promising ways of improving energy efficiency and reducing the use of power during peak periods.In this study,the thermal performance of a shell-and-tube cold storage system under realistic operating conditions is investigated numerically.The proposed model is developed based on energy balances and then validated using existing experimental data from the literature.Glycol/water is used as the heat transfer fluid(HTF)and the phase transition phenomena in the phase change material(PCM)is simulated using the enthalpy-porosity approach.The influence of several design and operating parameters,including the HTF mass flow rate,HTF temperature,PCM type,and volume,on the cold storage performance during the crystallization process is presented and analyzed.The numerical results show that increasing the HTF mass flow rate accelerates the PCM crystallization process.However,the delivery periods of constant thermal power and constant HTF outlet temperature are reduced.The HTF inlet temperature has a significant effect on the cold storage performance,and the complete charging period is reduced by approximately 37%when the HTF inlet temperature is reduced from−4°C to−7°C.Increasing the number of tubes in the cold storage unit is concluded to significantly improve the thermal performance of the system,and using water/ice as a cold storage medium is more suitable than using the commercial PCMs RT2-HC and RT4-HC.Finally,the proposed numerical model for cold storage systems can be successfully used to design and simulate their realistic operation under different conditions.展开更多
基金the“Initiative on Energy Research”,founded by the University Mohammed VI Polytechnic,for the financial support through the project“Toward efficient,stable,environmentally friendly,and scalable Perovskite Solar Cells”the financial support from DAAD and BMZ through the WE-AFRICA project+1 种基金the U.S.Department of Energy,Office of Science,Basic Energy Sciences,Early Career Program,under Award No.DOE DESC0025350the National Academies of Sciences,Engineering,and Medicine for their support through the U.S.-Africa Frontiers Fellowship。
文摘Chalcogenide perovskites(CPs)based on zirconium(Zr)and hafnium(Hf)are becoming increasingly attractive as a new class of materials for next-generation solar cells.CPs with the ABX_(3) structure stand out due to their attractive optical and electrical properties,such as efficient light absorption,direct bandgaps in the range of 1.1–2.1 eV,and remarkable defect tolerance,making them a compelling alternative to hybrid and double perovskites for solar energy conversion.Although theoretical studies have progressed rapidly,experimental verification still faces challenges such as the high synthesis temperatures required(>900℃),particularly in producing high-quality,phase-pure thin films and scalable solution-based processes.In this review,we aim to provide a comprehensive overview of the progress and remaining obstacles in advancing CP-based materials and devices.First,we describe the structure and composition as well as the different CPs in which the B site is occupied by Zr and Hf.Second,we summarize the methods used and the challenges that researchers face in producing an effective device.We highlight the main features that make CPs a preferred option for photovoltaic and other applications.Third,we look at the progress made in simulating solar cells that can achieve a power conversion efficiency(PCE)of over 30%using SCAPS-1D software.In the end,challenges and future research directions toward the development of CP materials and devices are provided.Overall,this review will serve as a valuable resource for researchers in selecting suitable strategies to achieve high-performance optoelectronic devices.
文摘The use of cold thermal storage systems in low-temperature industrial applications is considered one of the most promising ways of improving energy efficiency and reducing the use of power during peak periods.In this study,the thermal performance of a shell-and-tube cold storage system under realistic operating conditions is investigated numerically.The proposed model is developed based on energy balances and then validated using existing experimental data from the literature.Glycol/water is used as the heat transfer fluid(HTF)and the phase transition phenomena in the phase change material(PCM)is simulated using the enthalpy-porosity approach.The influence of several design and operating parameters,including the HTF mass flow rate,HTF temperature,PCM type,and volume,on the cold storage performance during the crystallization process is presented and analyzed.The numerical results show that increasing the HTF mass flow rate accelerates the PCM crystallization process.However,the delivery periods of constant thermal power and constant HTF outlet temperature are reduced.The HTF inlet temperature has a significant effect on the cold storage performance,and the complete charging period is reduced by approximately 37%when the HTF inlet temperature is reduced from−4°C to−7°C.Increasing the number of tubes in the cold storage unit is concluded to significantly improve the thermal performance of the system,and using water/ice as a cold storage medium is more suitable than using the commercial PCMs RT2-HC and RT4-HC.Finally,the proposed numerical model for cold storage systems can be successfully used to design and simulate their realistic operation under different conditions.
