Supercapacitors are favored by researchers because of their high power density,especially with the acceleration of people’s life rhythm.However,their energy density,especially from the point of view of the whole ener...Supercapacitors are favored by researchers because of their high power density,especially with the acceleration of people’s life rhythm.However,their energy density,especially from the point of view of the whole energy storage device,is far lower than that of commercial batteries.In this work,a kind of customizable full paper-based supercapacitor device with excellent self-healing ability is fabricated by simple and low-cost screen printing,electropolymerization and dip coating methods.The resultant separatorfree supercapacitor device exhibits both ultrahigh gravimetric and areal specific energy(power)densities of 39 Wh kg^(-1)(69 k W kg^(-1))and 692μWh cm^(-2)(236 m W cm^(-2)),achieving excellent supercapacitor performance.Notably,the addition of vitrimers endows the whole device with outstanding self-healing properties,which is helpful for enhancing the adaptability of the device to the environment.In addition,this kind of paper-based device also displays good photothermal and electromagnetic shielding performances.These striking features make paper matrix composites attractive in the fields of supercapacitors,medical photothermal treatment and electromagnetic shielding.展开更多
In recent years,paper-based functional materials have received extensive attention in the field of energy storage due to their advantages of rich and adjustable porous network structure and good flexibility.As an impo...In recent years,paper-based functional materials have received extensive attention in the field of energy storage due to their advantages of rich and adjustable porous network structure and good flexibility.As an important energy storage device,paper-based supercapacitors have important application prospects in many fields and have also received extensive attention from researchers in recent years.At present,researchers have modified and regulated paper-based materials by different means such as structural design and material composition to enhance their electrochemical storage capacity.The development of paper-based supercapacitors provides an important direction for the development of green and sustainable energy.Therefore,it is of great significance to summarize the relevant work of paper-based supercapacitors for their rapid development and application.In this review,the recent research progress of paper-based supercapacitors based on cellulose was summarized in terms of various cellulose-based composites,preparation skills,and electrochemical performance.Finally,some opinions on the problems in the development of this field and the future development trend were proposed.It is hoped that this review can provide valuable references and ideas for the rapid development of paper-based energy storage devices.展开更多
The demand for flexible electric heating devices has increased due to technology advancement and improved living standards.These devices have various applications including personal thermal management,hyperthermia,def...The demand for flexible electric heating devices has increased due to technology advancement and improved living standards.These devices have various applications including personal thermal management,hyperthermia,defrosting,agricultural heating film,and oil-water separation.Joule heat,generated by electric currents,is commonly used in electrical appliances.To incorporate Joule heating into flexible electronics,new materials with excellent mechanical properties are necessary.Traditional polymers,used as reinforcements,limit the continuity of conductive networks in composites.Therefore,there is a need to develop flexible Joule thermal composite materials with enhanced mechanical strength and conductivity.Cellulose,a widely available renewable resource,is attracting attention for its excellent mechanical properties.It can be used as a dispersant and reinforcing agent for conductive fillers in cellulose-based composites,creating highly conductive networks.Various forms of cellulose,such as wood,nanocellulose,pulp fiber,bacterial cellulose,cellulose paper,textile clothing,and aramid fiber,have been utilized to achieve high-performance Joule thermal composites.Researchers have achieved excellent mechanical properties and developed efficient electric heating devices by designing cellulose-based composites with different structures.The scalable production methods enable large-scale application of cellulose-based devices,each with unique advantages in 1D,2D,and 3D structures.This review summarizes recent advancements in cellulose-based Joule thermal composites,providing insights into different structural devices,and discussing prospects and challenges in the field.展开更多
Due to their rich and adjustable porous network structure,paper-based functional materials have become a research hotspot in the field of energy storage.However,reasonably designing and making full use of the rich por...Due to their rich and adjustable porous network structure,paper-based functional materials have become a research hotspot in the field of energy storage.However,reasonably designing and making full use of the rich pore structure of paper-based materials to improve the electrochemical performance of paper-based energy storage devices still faces many challenges.Herein,we propose a structure engineering technique to develop a conductive integrated gradient porous paper-based(CIGPP)supercapacitor,and the kinetics process for the influence of gradient holes on the electrochemical performance of the CIGPP is investigated through experimental tests and COMSOL simulations.All results indicate that the gradient holes endow the CIGPP with an enhanced electrochemical performance.Specifically,the CIGPP shows a significant improvement in the specific capacitance,displays rich frequency response characteristics for electrolyte ions,and exhibits a good rate performance.Also,the CIGPP supercapacitor exhibits a low self-discharge and maintains a stable electrochemical performance in different electrolyte environments because of gradient holes.More importantly,when the CIGPP is used as a substrate to fabricate a CIGPP-PANI hybrid,it still maintains good electrochemical properties.In addition,the CIGPP supercapacitor also shows excellent stability and sensitivity for monitoring human motion and deaf-mute voicing,showing potential application prospects.This study provides a reference and feasible way for the design of structure-engineered integrated paper-based energy storage devices with outstanding comprehensive electrochemical performance.展开更多
Recently,multifunctional materials have received widespread attention from researchers.Cellulose nanofibers(CNF)is one of biomass materials with abundant hydroxyl groups,which shows great potential in manufacturing mu...Recently,multifunctional materials have received widespread attention from researchers.Cellulose nanofibers(CNF)is one of biomass materials with abundant hydroxyl groups,which shows great potential in manufacturing multifunctional composite material.In this paper,a kind of polyaniline@CNF/polyvinyl alcohol-H_(2)SO_(4) multifunctional composite material(PANI@CNF/PVA-H_(2)SO_(4))was successfully designed by in-situ chemical polymerization of conductive polyaniline(PANI)onto CNF aerogel with high aspect ratio,and then coated with PVA-H_(2)SO_(4) gel.The composite material has a specific capacitance of 502.2 F/g at a scan rate of 5 mV/s as supercapacitor electrode.Furthermore,when the composite was assembled into a symmetrical supercapacitor,it can still provide an energy density of 11.49 W·h/kg at a high power density of 413.55 W/kg.Besides,the as-obtained PANI@CNF/PVA-H_(2)SO_(4) composite has an excellent electromagnetic shielding performance of 34.75 dB in X-band.In addition,due to the excellent flexibility of CNF and PVA,the PANI@CNF/PVA-H2SO4 composites can be further applied to stress sensors to detect pressure and human motion signals.展开更多
Recent research efforts in the field of electromagnetic interference shielding(EMI)materials have focused on biomass as a green and sustainable resource.More specifically,wood and cellulose nano fiber(CNF)have many ad...Recent research efforts in the field of electromagnetic interference shielding(EMI)materials have focused on biomass as a green and sustainable resource.More specifically,wood and cellulose nano fiber(CNF)have many advantages,some of which include lightweight,porosity,widespread availability,low cost,and easy processing.These favorable properties have led researchers to consider these types of biomass as an EMI shielding material with great potential.At present,while many excellent published works in EMI shielding materials have investigated wood and CNF,this research area is still new,compared with non-biomass EMI shielding materials.More specifically,there is still a lack of in-depth research and summary on the preparation process,pore structure regulation,component optimization,and other factors affecting the EMI shielding of wood and CNF based EMI shielding materials.Thus,this review paper presents a comprehensive summary of recent research on wood and CNF based EMI shielding materials in recent three years in terms of the preparation methods,material structure design,component synergy,and EMI mechanism,and a forward future perspective for existing problems,challenges,and development trend.The ultimate goal is to provide a comprehensive and informative reference for the further development and exploration of biomass EMI shielding materials.展开更多
Developing porous self-supporting electrodes with excellent conductivity,good mechanical properties,and high electrochemical activity is crucial for constructing electrode materials with lightweight,ultra-thin,flexibl...Developing porous self-supporting electrodes with excellent conductivity,good mechanical properties,and high electrochemical activity is crucial for constructing electrode materials with lightweight,ultra-thin,flexible,and high capacitance performance.In this work,we prepared a cellulose nanofibers(CNFs)/carbon nanotubes(CNTs)/vinasse activated carbon(VAC)(CCV)composite material with a multi-layer hierarchical conductive structure through simple vacuum filtration and freeze-drying.In this composite material,the self-assembly of CNF provides the main skeleton structure of a multi-layer hierarchical structure.CNT provides a fast path for the rapid transfer of electrons and is beneficial for the loss of electromagnetic waves.VAC provides sufficient double layer performance.The synergistic effect of the above three endows CCV composite materials with excellent energy storage performance and electromagnetic interference(EMI)shielding performance.In addition,we endowed the CCV composite with a certain shape and performance by introducing a vitrimer polymer with a dynamic cross-linked network structure.In summary,thanks to the synergistic effect of various components in the multi-layer hierarchical structure,CCV composite materials exhibit excellent integration performance,especially stable energy storage performance and EMI shielding performance.These significant properties make CCV composite materials have great application prospects in the fields of energy storage and intelligent EMI shielding.展开更多
A flexible 3D N-doped reduced graphene oxide(N-RGO)/carbon nanotube(CNT)eMnO_(2) hybrid film was constructed with outstanding supercapacitor,excellent oxygen reduction reaction(ORR)and good sensing performances.The re...A flexible 3D N-doped reduced graphene oxide(N-RGO)/carbon nanotube(CNT)eMnO_(2) hybrid film was constructed with outstanding supercapacitor,excellent oxygen reduction reaction(ORR)and good sensing performances.The resultant hybrid film possessed large specific capacitances of 418 F g^(-1) and 209 mF cm^(-2) in aqueous and solid electrolytes,and outstanding capacitance retentions of 95% and 94% were obtained for both electrolytes after experiencing 5000 cycles.A simple supercapacitor based on the resultant flexible hybrid film was further fabricated with a much smaller time constant τ0(0.38 s)than that of typical activated-carbon supercapacitors,suggesting a quick response frequency.Moreover,the assembled supercapacitor device showed high energy densities of 45.72 and 92.13 Wh kg^(-1) and simultaneously sustained large power densities of 12,526 and 15873 W kg^(-1) under a scan rate of 50 mV s^(-1) in aqueous and solid electrolytes,respectively.Furthermore,the resultant flexible film showed excellent performance in the ORR and can also be used to assemble a strain sensor with an excellent sensing performance for bending strain.展开更多
Recently,with the continuous development of human society and the continuous innovation of technologies,the intelligence era has arrived.Various intelligent electronic devices continue to be developed,in which flexibl...Recently,with the continuous development of human society and the continuous innovation of technologies,the intelligence era has arrived.Various intelligent electronic devices continue to be developed,in which flexible wearable electronic devices are highly favored by people.To meet the requirements of the normal operation of intelligent devices,the key point lies in the development of new smart energy storage devices.Accordingly,smart supercapacitors have been widely focused on and studied by researchers recently with the introduction of intelligent functions,such as electrochromism,self‐healing,and shape memory,into supercapacitors to broaden their application fields and promote their smart development.This can meet not only people's energy needs but also people's diverse personality needs and make our life more convenient,fast,and more intelligent than ever.Therefore,it is very important to summarize related work on smart supercapacitors.Although researchers have performed much research on smart supercapacitors,there is still little literature summary on the related work of different smart supercapacitors.Accordingly,this paper mainly introduces the research progress on electrochromic,self‐healing,shape memory,and self‐charging smart supercapacitors in recent years and discusses the development prospects and challenges of smart supercapacitors.展开更多
基金financially supported by the National Natural Science Foundation of China(No.22078184)the China Postdoctoral Science Foundation(No.2019M653853XB)+6 种基金the Natural Science Foundation of Shaanxi Province(No.2020JQ-729)the Key Projects of Collaborative Innovation Center of Shaanxi Provincial Department of Educationthe Opening Project of Guangxi Key Laboratory of Clean Pulp&Papermaking and Pollution Control(No.2019KF21)the Natural Science Advance Research Foundation of Shaanxi University of Science and Technology(No.2018QNBJ-03)the National Demonstration Center for Experimental Light Chemistry Engineering Education(No.2018QGSJ02-13)the Jiangxi Qingyue Technology Co.,Ltd(No.210200122)the Biomass Chemistry and Materials Academician Workstation Project in SUST(No.134090002)。
文摘Supercapacitors are favored by researchers because of their high power density,especially with the acceleration of people’s life rhythm.However,their energy density,especially from the point of view of the whole energy storage device,is far lower than that of commercial batteries.In this work,a kind of customizable full paper-based supercapacitor device with excellent self-healing ability is fabricated by simple and low-cost screen printing,electropolymerization and dip coating methods.The resultant separatorfree supercapacitor device exhibits both ultrahigh gravimetric and areal specific energy(power)densities of 39 Wh kg^(-1)(69 k W kg^(-1))and 692μWh cm^(-2)(236 m W cm^(-2)),achieving excellent supercapacitor performance.Notably,the addition of vitrimers endows the whole device with outstanding self-healing properties,which is helpful for enhancing the adaptability of the device to the environment.In addition,this kind of paper-based device also displays good photothermal and electromagnetic shielding performances.These striking features make paper matrix composites attractive in the fields of supercapacitors,medical photothermal treatment and electromagnetic shielding.
基金supported by the fund of the National Natural Science Foundation of China(22078184,22171170)the China Postdoctoral Science Foundation(2019M653853XB)+1 种基金the Natural Science Advance Research Foundation of Shaanxi University of Science and Technology(2018QNBJ-03)Major Scientific and Technological Innovation Projects in Shandong Province(2019TSLH0316)
文摘In recent years,paper-based functional materials have received extensive attention in the field of energy storage due to their advantages of rich and adjustable porous network structure and good flexibility.As an important energy storage device,paper-based supercapacitors have important application prospects in many fields and have also received extensive attention from researchers in recent years.At present,researchers have modified and regulated paper-based materials by different means such as structural design and material composition to enhance their electrochemical storage capacity.The development of paper-based supercapacitors provides an important direction for the development of green and sustainable energy.Therefore,it is of great significance to summarize the relevant work of paper-based supercapacitors for their rapid development and application.In this review,the recent research progress of paper-based supercapacitors based on cellulose was summarized in terms of various cellulose-based composites,preparation skills,and electrochemical performance.Finally,some opinions on the problems in the development of this field and the future development trend were proposed.It is hoped that this review can provide valuable references and ideas for the rapid development of paper-based energy storage devices.
基金supported by the fund of the National Natural Science Foundation of China(Nos.22378249,22078184,and 22171170)the China Postdoctoral Science Foundation(No.2019M653853XB)the Natural Science Advance Research Foundation of Shaanxi University of Science and Technology(No.2018QNBJ-03).
文摘The demand for flexible electric heating devices has increased due to technology advancement and improved living standards.These devices have various applications including personal thermal management,hyperthermia,defrosting,agricultural heating film,and oil-water separation.Joule heat,generated by electric currents,is commonly used in electrical appliances.To incorporate Joule heating into flexible electronics,new materials with excellent mechanical properties are necessary.Traditional polymers,used as reinforcements,limit the continuity of conductive networks in composites.Therefore,there is a need to develop flexible Joule thermal composite materials with enhanced mechanical strength and conductivity.Cellulose,a widely available renewable resource,is attracting attention for its excellent mechanical properties.It can be used as a dispersant and reinforcing agent for conductive fillers in cellulose-based composites,creating highly conductive networks.Various forms of cellulose,such as wood,nanocellulose,pulp fiber,bacterial cellulose,cellulose paper,textile clothing,and aramid fiber,have been utilized to achieve high-performance Joule thermal composites.Researchers have achieved excellent mechanical properties and developed efficient electric heating devices by designing cellulose-based composites with different structures.The scalable production methods enable large-scale application of cellulose-based devices,each with unique advantages in 1D,2D,and 3D structures.This review summarizes recent advancements in cellulose-based Joule thermal composites,providing insights into different structural devices,and discussing prospects and challenges in the field.
基金This work was supported by the fund of the National Natural Science Foundation of China(Nos.22078184 and 52006130)China Postdoctoral Science Foundation(No.2019M653853XB)+3 种基金Opening Project of Guangxi Key Laboratory of Clean Pulp&Papermaking and Pollution Control(No.2019KF21)Natural science advance research foundation of Shaanxi University of Science and Technology(No.2018QNBJ-03)the Youth Innovation Team of Shaanxi Universities(No.21JP017)the Joint Research Funds of Department of Science and Technology of Shaanxi Province and Northwestern Polytechnical University(No.2020GXLH-Z-025).
文摘Due to their rich and adjustable porous network structure,paper-based functional materials have become a research hotspot in the field of energy storage.However,reasonably designing and making full use of the rich pore structure of paper-based materials to improve the electrochemical performance of paper-based energy storage devices still faces many challenges.Herein,we propose a structure engineering technique to develop a conductive integrated gradient porous paper-based(CIGPP)supercapacitor,and the kinetics process for the influence of gradient holes on the electrochemical performance of the CIGPP is investigated through experimental tests and COMSOL simulations.All results indicate that the gradient holes endow the CIGPP with an enhanced electrochemical performance.Specifically,the CIGPP shows a significant improvement in the specific capacitance,displays rich frequency response characteristics for electrolyte ions,and exhibits a good rate performance.Also,the CIGPP supercapacitor exhibits a low self-discharge and maintains a stable electrochemical performance in different electrolyte environments because of gradient holes.More importantly,when the CIGPP is used as a substrate to fabricate a CIGPP-PANI hybrid,it still maintains good electrochemical properties.In addition,the CIGPP supercapacitor also shows excellent stability and sensitivity for monitoring human motion and deaf-mute voicing,showing potential application prospects.This study provides a reference and feasible way for the design of structure-engineered integrated paper-based energy storage devices with outstanding comprehensive electrochemical performance.
基金supported by the fund of National Natural Science Foundation of China(22078184,22378249 and 22178208)Key R&D Plan of Shaanxi Province(2024GX-YBXM-335)+1 种基金China Postdoctoral Science Foundation(2019M653853XB)Natural science advance research foundation of Shaanxi University of Science and Technology(2018QNBJ-03).
文摘Recently,multifunctional materials have received widespread attention from researchers.Cellulose nanofibers(CNF)is one of biomass materials with abundant hydroxyl groups,which shows great potential in manufacturing multifunctional composite material.In this paper,a kind of polyaniline@CNF/polyvinyl alcohol-H_(2)SO_(4) multifunctional composite material(PANI@CNF/PVA-H_(2)SO_(4))was successfully designed by in-situ chemical polymerization of conductive polyaniline(PANI)onto CNF aerogel with high aspect ratio,and then coated with PVA-H_(2)SO_(4) gel.The composite material has a specific capacitance of 502.2 F/g at a scan rate of 5 mV/s as supercapacitor electrode.Furthermore,when the composite was assembled into a symmetrical supercapacitor,it can still provide an energy density of 11.49 W·h/kg at a high power density of 413.55 W/kg.Besides,the as-obtained PANI@CNF/PVA-H_(2)SO_(4) composite has an excellent electromagnetic shielding performance of 34.75 dB in X-band.In addition,due to the excellent flexibility of CNF and PVA,the PANI@CNF/PVA-H2SO4 composites can be further applied to stress sensors to detect pressure and human motion signals.
基金the National Natural Science Foundation of China(No.22078184)China Postdoctoral Science Foundation(No.2019M653853XB)Natural science advance research foundation of Shaanxi University of Science and Technology(No.2018QNBJ-03).
文摘Recent research efforts in the field of electromagnetic interference shielding(EMI)materials have focused on biomass as a green and sustainable resource.More specifically,wood and cellulose nano fiber(CNF)have many advantages,some of which include lightweight,porosity,widespread availability,low cost,and easy processing.These favorable properties have led researchers to consider these types of biomass as an EMI shielding material with great potential.At present,while many excellent published works in EMI shielding materials have investigated wood and CNF,this research area is still new,compared with non-biomass EMI shielding materials.More specifically,there is still a lack of in-depth research and summary on the preparation process,pore structure regulation,component optimization,and other factors affecting the EMI shielding of wood and CNF based EMI shielding materials.Thus,this review paper presents a comprehensive summary of recent research on wood and CNF based EMI shielding materials in recent three years in terms of the preparation methods,material structure design,component synergy,and EMI mechanism,and a forward future perspective for existing problems,challenges,and development trend.The ultimate goal is to provide a comprehensive and informative reference for the further development and exploration of biomass EMI shielding materials.
基金supported by the National Natural Science Foundation of China(Nos.22078184 and 22378249)the China Postdoctoral Science Foundation(No.2019M653853XB)the Natural Science Advance Research Foundation of Shaanxi University of Science and Technology(No.2018QNBJ-03).
文摘Developing porous self-supporting electrodes with excellent conductivity,good mechanical properties,and high electrochemical activity is crucial for constructing electrode materials with lightweight,ultra-thin,flexible,and high capacitance performance.In this work,we prepared a cellulose nanofibers(CNFs)/carbon nanotubes(CNTs)/vinasse activated carbon(VAC)(CCV)composite material with a multi-layer hierarchical conductive structure through simple vacuum filtration and freeze-drying.In this composite material,the self-assembly of CNF provides the main skeleton structure of a multi-layer hierarchical structure.CNT provides a fast path for the rapid transfer of electrons and is beneficial for the loss of electromagnetic waves.VAC provides sufficient double layer performance.The synergistic effect of the above three endows CCV composite materials with excellent energy storage performance and electromagnetic interference(EMI)shielding performance.In addition,we endowed the CCV composite with a certain shape and performance by introducing a vitrimer polymer with a dynamic cross-linked network structure.In summary,thanks to the synergistic effect of various components in the multi-layer hierarchical structure,CCV composite materials exhibit excellent integration performance,especially stable energy storage performance and EMI shielding performance.These significant properties make CCV composite materials have great application prospects in the fields of energy storage and intelligent EMI shielding.
基金supported by the fund of the China Postdoctoral Science Foundation(2019M653853XB)State Key Laboratory of Solidification Processing in NWPU(SKLSP201815)+4 种基金Opening Project of Guangxi Key Laboratory of Clean Pulp&Papermaking and Pollution Control(2019KF21)Natural science advance research foundation of Shaanxi University of Science and Technology(2018QNBJ-03)National Demonstration Center for Experimental Light Chemistry Engineering Education(Shaanxi University of Science&Technology)High-level Foreign Experts Project(GDT20186100425)and Biomass Chemistry and Materials Academician Workstation Project in SUST(134090002).
文摘A flexible 3D N-doped reduced graphene oxide(N-RGO)/carbon nanotube(CNT)eMnO_(2) hybrid film was constructed with outstanding supercapacitor,excellent oxygen reduction reaction(ORR)and good sensing performances.The resultant hybrid film possessed large specific capacitances of 418 F g^(-1) and 209 mF cm^(-2) in aqueous and solid electrolytes,and outstanding capacitance retentions of 95% and 94% were obtained for both electrolytes after experiencing 5000 cycles.A simple supercapacitor based on the resultant flexible hybrid film was further fabricated with a much smaller time constant τ0(0.38 s)than that of typical activated-carbon supercapacitors,suggesting a quick response frequency.Moreover,the assembled supercapacitor device showed high energy densities of 45.72 and 92.13 Wh kg^(-1) and simultaneously sustained large power densities of 12,526 and 15873 W kg^(-1) under a scan rate of 50 mV s^(-1) in aqueous and solid electrolytes,respectively.Furthermore,the resultant flexible film showed excellent performance in the ORR and can also be used to assemble a strain sensor with an excellent sensing performance for bending strain.
基金supported by the National Natural Science Foundation of China(No.22078184)China Postdoctoral Science Foundation(No.2019M653853XB)+1 种基金Natural Science Advance Research Foundation of Shaanxi University of Science and Technology(No.2018QNBJ‐03)Major Scientific and Technological Innovation Projects in Shandong Province(No.2019TSLH0316).
文摘Recently,with the continuous development of human society and the continuous innovation of technologies,the intelligence era has arrived.Various intelligent electronic devices continue to be developed,in which flexible wearable electronic devices are highly favored by people.To meet the requirements of the normal operation of intelligent devices,the key point lies in the development of new smart energy storage devices.Accordingly,smart supercapacitors have been widely focused on and studied by researchers recently with the introduction of intelligent functions,such as electrochromism,self‐healing,and shape memory,into supercapacitors to broaden their application fields and promote their smart development.This can meet not only people's energy needs but also people's diverse personality needs and make our life more convenient,fast,and more intelligent than ever.Therefore,it is very important to summarize related work on smart supercapacitors.Although researchers have performed much research on smart supercapacitors,there is still little literature summary on the related work of different smart supercapacitors.Accordingly,this paper mainly introduces the research progress on electrochromic,self‐healing,shape memory,and self‐charging smart supercapacitors in recent years and discusses the development prospects and challenges of smart supercapacitors.
