A model is proposed to describe soot formation and oxidation during bio-oil gasification.It is based on the description of bio-oil heating,devolatilization,reforming of gases and conversion of both char and soot solid...A model is proposed to describe soot formation and oxidation during bio-oil gasification.It is based on the description of bio-oil heating,devolatilization,reforming of gases and conversion of both char and soot solids.Detailed chemistry (159 species and 773 reactions) is used in the gas phase.Soot production is described by a single reaction based on C2H2species concentration and three heterogeneous soot oxidation reactions.To support the validation of the model,three sets of experiments were carried out in a lab-scale Entrained Flow Reactor (EFR) equipped with soot quantification device.The temperature was varied from 1000 to 1400 C and three gaseous atmospheres were considered:default of steam,large excess of steam(H2O/C=8),and the presence of oxygen in the O/C range of 0.075–0.5.The model is shown to accurately describe the evolution of the concentration of the main gas species and to satisfactorily describe the soot concentration under the three atmospheres using a single set of identified kinetic parameters.Thanks to this model the contribution of different mechanisms involved in soot formation and oxidation in various situations can be assessed.展开更多
The present study refers to a cavitating Venturi type section geometry characterized by a convergent angle of 18°?and a divergent angle of about 8°?where the sheet cavity presents typical self-oscillation be...The present study refers to a cavitating Venturi type section geometry characterized by a convergent angle of 18°?and a divergent angle of about 8°?where the sheet cavity presents typical self-oscillation behavior with quasi-periodic vapor clouds shedding. This work is an extension of previous works concerning void ratio measurements and velocity fields using double optical probe and constitutes a complete analysis of the two-phase structure of unsteady cavitating flow. This paper provides a new method based on conditional and phase averaging technique with wall pressure signal to treat experimental data in order to evaluate more precisely time-averaged and rms values of the void ratio and instantaneous velocity fields. Conditional analysis shows a different behavior of the two-phase flow dynamics leading to highlight high void ratio events linked to the break-off cycle. Unsteady phase averaging of the optical probe signal gives the evolution of the void ratio at each studied location in the venturi and shows that the fluctuations close to the wall (where the re-entrant jet is predominant) are in phase with the upper part of the cavity instead of the thickness of the cavity which is unchanged.展开更多
A volume averaged columnar solidification model,which couples the flow,temperature and solute concentration fields,is applied to simulate experimental continuous casting cases with and without vertical electromagnetic...A volume averaged columnar solidification model,which couples the flow,temperature and solute concentration fields,is applied to simulate experimental continuous casting cases with and without vertical electromagnetic stirring(V-EMS).The calculated distribution of magnetic induction intensity and final macrosegregation maps are consistent with the experimental results.Calculation results reveal that the V-EMS promotes longitudinal melt flow,accelerates heat dissipation and solidification and finally reduces the central segregation of carbon.However,when V-EMS is applied,the solute distribution becomes asymmetric because the melt flow shows opposite directions between the near and far sides from stirrer.An obvious positive segregation band is observed at about 1/4 width of the billet near the stirrer in both calculated and experimental results.The position and degree of such positive segregation could be affected by installation height of stirrer,as demonstrated by additional simulation cases.展开更多
基金the financial support from EnerBio Program of Fondation Tuck France,and express their gratitude to Mr
文摘A model is proposed to describe soot formation and oxidation during bio-oil gasification.It is based on the description of bio-oil heating,devolatilization,reforming of gases and conversion of both char and soot solids.Detailed chemistry (159 species and 773 reactions) is used in the gas phase.Soot production is described by a single reaction based on C2H2species concentration and three heterogeneous soot oxidation reactions.To support the validation of the model,three sets of experiments were carried out in a lab-scale Entrained Flow Reactor (EFR) equipped with soot quantification device.The temperature was varied from 1000 to 1400 C and three gaseous atmospheres were considered:default of steam,large excess of steam(H2O/C=8),and the presence of oxygen in the O/C range of 0.075–0.5.The model is shown to accurately describe the evolution of the concentration of the main gas species and to satisfactorily describe the soot concentration under the three atmospheres using a single set of identified kinetic parameters.Thanks to this model the contribution of different mechanisms involved in soot formation and oxidation in various situations can be assessed.
文摘The present study refers to a cavitating Venturi type section geometry characterized by a convergent angle of 18°?and a divergent angle of about 8°?where the sheet cavity presents typical self-oscillation behavior with quasi-periodic vapor clouds shedding. This work is an extension of previous works concerning void ratio measurements and velocity fields using double optical probe and constitutes a complete analysis of the two-phase structure of unsteady cavitating flow. This paper provides a new method based on conditional and phase averaging technique with wall pressure signal to treat experimental data in order to evaluate more precisely time-averaged and rms values of the void ratio and instantaneous velocity fields. Conditional analysis shows a different behavior of the two-phase flow dynamics leading to highlight high void ratio events linked to the break-off cycle. Unsteady phase averaging of the optical probe signal gives the evolution of the void ratio at each studied location in the venturi and shows that the fluctuations close to the wall (where the re-entrant jet is predominant) are in phase with the upper part of the cavity instead of the thickness of the cavity which is unchanged.
基金financial support from the National Natural Science Foundation of China(Grant No.U1760206)the National Key R&D Program of China(Grant No.2017YFE0107900)+1 种基金the 111 Project 2.0 of China(Grant No.BP0719037)the financial support provided by the ESA-MAP MICAST project contract 14347/01/NL/SH.
文摘A volume averaged columnar solidification model,which couples the flow,temperature and solute concentration fields,is applied to simulate experimental continuous casting cases with and without vertical electromagnetic stirring(V-EMS).The calculated distribution of magnetic induction intensity and final macrosegregation maps are consistent with the experimental results.Calculation results reveal that the V-EMS promotes longitudinal melt flow,accelerates heat dissipation and solidification and finally reduces the central segregation of carbon.However,when V-EMS is applied,the solute distribution becomes asymmetric because the melt flow shows opposite directions between the near and far sides from stirrer.An obvious positive segregation band is observed at about 1/4 width of the billet near the stirrer in both calculated and experimental results.The position and degree of such positive segregation could be affected by installation height of stirrer,as demonstrated by additional simulation cases.
