Four polyoxometalates(POMs)were combined with an artificial reductase based on polyethyleneimine(PEI)and flavin mononucleotide(FMN)which is capable of delivering single electrons upon addition of nicotinamide adenine ...Four polyoxometalates(POMs)were combined with an artificial reductase based on polyethyleneimine(PEI)and flavin mononucleotide(FMN)which is capable of delivering single electrons upon addition of nicotinamide adenine dinucleotide(NADH).The efficiency of this system for sulfoxidation reactions in water,at room temperature,under atmospheric pressure and with dioxygen as an oxidant was demonstrated,with yields up to 82%in sulfoxide.展开更多
基金supported by the Ministère de l’Enseignement Supérieur et de la Recherche,the CNRS,the Universitéde Versailles Saint Quentin en Yvelines,the UniversitéParis-Sud,The University Paris Saclay and a public grant overseen by the French National Research Agency(ANR)as part of the“Investissements d’Avenir”program no.ANR-11-IDEX-0003-02 and CHARMMMAT ANR-11-LABEX-0039.
文摘Four polyoxometalates(POMs)were combined with an artificial reductase based on polyethyleneimine(PEI)and flavin mononucleotide(FMN)which is capable of delivering single electrons upon addition of nicotinamide adenine dinucleotide(NADH).The efficiency of this system for sulfoxidation reactions in water,at room temperature,under atmospheric pressure and with dioxygen as an oxidant was demonstrated,with yields up to 82%in sulfoxide.
