We consider the 4s^(2)4p^(4)(^(3)P_(1))nd,4s^(2)4p^(4)(^(1)D_(2))nd and 4s^(2)4p^(4)(^(1)S_(0))nd Rydberg series of Rb^(2+)originating from the 4s^(2)4p^(5)(^(2)P^(0)_(1/2))ground state and 4s^(2)4p^(5)(^(2)P^(0)_(3/2...We consider the 4s^(2)4p^(4)(^(3)P_(1))nd,4s^(2)4p^(4)(^(1)D_(2))nd and 4s^(2)4p^(4)(^(1)S_(0))nd Rydberg series of Rb^(2+)originating from the 4s^(2)4p^(5)(^(2)P^(0)_(1/2))ground state and 4s^(2)4p^(5)(^(2)P^(0)_(3/2))metastable state of Rb^(2+)converging respectively to the 4s^(2)4p^(4)(^(3)P_(1)),4s^(2)4p^(4)(^(1)D_(2))and 4s^(2)4p^(4)(^(1)S_(0))series limit in Rb^(3+).The semi-empirical procedure of Modified Atomic Orbital Theory(MAOT)is applied to perform calculations in the present work from n=6 up to n=45.We note that the MAOT procedure gives accurate results compared to available Advanced Light Source(ALS)experimental data and other theoretical results.We tabulate new data from n=22-45 for 4s^(2)4p^(4)(^(1)S_(0))nd Rydberg series originating from the 4s^(2)4p^(5)(^(2)P^(0)_(1/2))ground state and 4s^(2)4p^(5)(^(2)P^(0)_(3/2))metastable state of Rb^(2+).The other Rydberg series 4s^(2)4p^(4)(^(3)P_(1))nd and 4s^(2)4p^(4)(^(1)D_(2))nd are extended up to n=45.展开更多
文摘We consider the 4s^(2)4p^(4)(^(3)P_(1))nd,4s^(2)4p^(4)(^(1)D_(2))nd and 4s^(2)4p^(4)(^(1)S_(0))nd Rydberg series of Rb^(2+)originating from the 4s^(2)4p^(5)(^(2)P^(0)_(1/2))ground state and 4s^(2)4p^(5)(^(2)P^(0)_(3/2))metastable state of Rb^(2+)converging respectively to the 4s^(2)4p^(4)(^(3)P_(1)),4s^(2)4p^(4)(^(1)D_(2))and 4s^(2)4p^(4)(^(1)S_(0))series limit in Rb^(3+).The semi-empirical procedure of Modified Atomic Orbital Theory(MAOT)is applied to perform calculations in the present work from n=6 up to n=45.We note that the MAOT procedure gives accurate results compared to available Advanced Light Source(ALS)experimental data and other theoretical results.We tabulate new data from n=22-45 for 4s^(2)4p^(4)(^(1)S_(0))nd Rydberg series originating from the 4s^(2)4p^(5)(^(2)P^(0)_(1/2))ground state and 4s^(2)4p^(5)(^(2)P^(0)_(3/2))metastable state of Rb^(2+).The other Rydberg series 4s^(2)4p^(4)(^(3)P_(1))nd and 4s^(2)4p^(4)(^(1)D_(2))nd are extended up to n=45.
