Understanding mechanical relaxation, such as primary（α） and secondary（β） relaxation, is key to unravel the intertwined relation between the atomic dynamics and non-equilibrium thermodynamics in metallic glasses....Understanding mechanical relaxation, such as primary（α） and secondary（β） relaxation, is key to unravel the intertwined relation between the atomic dynamics and non-equilibrium thermodynamics in metallic glasses. At a fundamental level, relaxation, plastic deformation, glass transition, and crystallization of metallic glasses are intimately linked to each other, which can be related to atomic packing, inter-atomic diffusion, and cooperative atom movement. Conceptually, βrelaxation is usually associated with structural heterogeneities intrinsic to metallic glasses. However, the details of such structural heterogeneities, being masked by the meta-stable disordered long-range structure, are yet to be understood. In this paper, we briefly review the recent experimental and simulation results that were attempted to elucidate structural heterogeneities in metallic glasses within the framework of β relaxation. In particular, we will discuss the correlation amongβ relaxation, structural heterogeneity, and mechanical properties of metallic glasses.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.51401192 and 51611130120)the Natural Science Foundation of Shaanxi Province,China(Grant No.2016JM5009)+5 种基金the Fundamental Research Funds for the Central Universities of China(Grant Nos.3102015ZY027 and 3102015BJ(Ⅱ)JGZ019)the Aeronautical Science Foundation of China(Grant No.2015ZF53072)supported by the Hong Kong Scholar Program of China(Grant No.XJ2015056)the support of MINECO(Grant No.FIS2014-54734-P)Generalitat de Catalunya(Grant No.2014SGR00581)supported by the Research Grant Council,the Hong Kong City of China,through the General Research Fund(Grant No.City U11214914)
文摘Understanding mechanical relaxation, such as primary（α） and secondary（β） relaxation, is key to unravel the intertwined relation between the atomic dynamics and non-equilibrium thermodynamics in metallic glasses. At a fundamental level, relaxation, plastic deformation, glass transition, and crystallization of metallic glasses are intimately linked to each other, which can be related to atomic packing, inter-atomic diffusion, and cooperative atom movement. Conceptually, βrelaxation is usually associated with structural heterogeneities intrinsic to metallic glasses. However, the details of such structural heterogeneities, being masked by the meta-stable disordered long-range structure, are yet to be understood. In this paper, we briefly review the recent experimental and simulation results that were attempted to elucidate structural heterogeneities in metallic glasses within the framework of β relaxation. In particular, we will discuss the correlation amongβ relaxation, structural heterogeneity, and mechanical properties of metallic glasses.
