This study discusses the scope of application of the Doppler backscattering(DBS)diagnostic for the tokamak with reactor technologies(TRT)project.This involved numerical modeling of the three-dimensional(3D)beam trajec...This study discusses the scope of application of the Doppler backscattering(DBS)diagnostic for the tokamak with reactor technologies(TRT)project.This involved numerical modeling of the three-dimensional(3D)beam trajectories.Calculations were performed to investigate the propagation of microwaves in the V(40–75 GHz)and W(75–110 GHz)frequency ranges with O-mode polarization for the density profile of the base TRT scenario.Our analysis showed that the DBS system antenna on the TRT would need to be tilted in both the poloidal and toroidal directions in order to meet the condition Kperp/Kpar<10%..For the DBS system located in the equatorial plane it was shown that a wide range of poloidal and toroidal angles is available for the successful implementation of the diagnostic to study the core,pedestal and scrape-off layer(SOL)regions.The DBS system located at 35 cm above the equatorial plane would be more limited in measurements only covering the SOL and pedestal regions.A shift of the cut-offs in the toroidal direction highlighted the need for 3D analysis of the DBS data.展开更多
Energy storage devices have been extensively owing to their critical role in addressing the energy and environment challenges.Aqueous trivalent metal batteries are promising due to their unique three-electron redox re...Energy storage devices have been extensively owing to their critical role in addressing the energy and environment challenges.Aqueous trivalent metal batteries are promising due to their unique three-electron redox reactions for high reversible capacity and high safety[1].Especially,aqueous aluminum-based batteries have attracted significant attention[2].However,severe water decomposition occurs due to their low redox potential(Al3+/Al,-1.66 V vs.SHE)[3].In contrast,the metallic indium(In)/or In3+has a more suitable redox potential(-0.34 V vs.SHE),which is within the water stability window,minimizingwater decomposition[4].Recently,a study on trivalent indium metal batteries was firstly reported by Wu’s group in Journal of the American Chemical Society[5].展开更多
The first results of investigation of the turbulence structure using Doppler backscattering(DBS)on the Globus-M2 tokamak are presented.A one-channel DBS system with a variable probing frequency within the 18–26 GHz r...The first results of investigation of the turbulence structure using Doppler backscattering(DBS)on the Globus-M2 tokamak are presented.A one-channel DBS system with a variable probing frequency within the 18–26 GHz range was installed to investigate the edge plasma at normalized minor radiiρ=0.9–1.1.Radial correlation Doppler reflectometry was used to study the changes in turbulence eddies after the LH transition.Correlation analysis was applied to the phase derivative of complex in-phase and quadrature(IQ)signals of the DBS diagnostic as it contains information about the poloidal plasma rotation velocity.In L-mode,the radial correlation length L_(r)is estimated to be 3 cm and after transition to H-mode reduces to approximately 2 cm.Gyrokinetic modelling in a linear local approximation using code GENE indicates that the instability with positive growth rate at the normalized minor radiusρ=0.75 in L-mode and H-mode on Globus-M2 was the ion temperature gradient(ITG)mode.展开更多
CO_(2) is the most cost-eff ective and abundant carbon resource,while the reverse water-gas reaction(rWGS)is one of the most eff ective methods of CO_(2) utilization.This work presents a comparative study of rWGS acti...CO_(2) is the most cost-eff ective and abundant carbon resource,while the reverse water-gas reaction(rWGS)is one of the most eff ective methods of CO_(2) utilization.This work presents a comparative study of rWGS activity for perovskite systems based on AFeO_(3)(where A=Ce,La,Y).These systems were synthesized by solution combustion synthesis(SCS)with diff erent ratios of fuel(glycine)and oxidizer(φ),diff erent amounts of NH 4 NO_(3),and the addition of alumina or silica as supports.Various techniques,including X-ray diff raction analysis,thermogravimetric analysis,Fourier transform infrared spectroscopy(FTIR),scanning electron microscopy,energy-dispersive X-ray spectroscopy,N 2-physisorption,H_(2) temper-ature-programmed reduction,temperature-programmed desorption of H_(2) and CO_(2),Raman spectroscopy,and in situ FTIR,were used to relate the physicochemical properties with the catalytic performance of the obtained composites.Each specifi c perovskite-containing system(either bulk or supported)has its own optimalφand NH_(4) NO_(3) amount to achieve the highest yield and dispersion of the perovskite phase.Among all synthesized systems,bulk SCS-derived La-Fe-O systems showed the highest resistance to reducing environments and the easiest hydrogen desorption,outperforming La-Fe-O produced by solgel combustion(SGC).CO_(2) conversion into CO at 600°C for bulk ferrite systems,depending on the A-cation type and preparation method,follows the order La(SGC)<Y<Ce<La(SCS).The diff erences in properties between La-Fe-O obtained by the SCS and SGC methods can be attributed to diff erent ratios of oxygen and lanthanum vacancy contributions,hydroxyl coverage,morphology,and free iron oxide presence.In situ FTIR data revealed that CO_(2) hydrogenation occurs through formates generated under reaction conditions on the bulk system based on La-Fe-O,obtained by the SCS method.γ-Al_(2)O_(3) improves the dispersion of CeFeO_(3) and LaFeO_(3) phases,the specifi c surface area,and the quantity of adsorbed H_(2) and CO_(2).This led to a signifi cant increase in CO_(2) conversion for supported CeFeO_(3) but not for the La-based system compared to bulk and SiO_(2)-supported perovskite catalysts.However,adding alumina increased the activity per mass for both Ce-and La-based perovskite systems,reducing the amount of rare-earth components in the catalyst and thereby lowering the cost without substantially compromising stability.展开更多
To avoid carbonate precipitation for CO_(2) electrolysis,developing CO_(2) conversion in an acid electrolyte is viewed as an ultimately challenging technology.In Nature,Xia et al.recently explored a proton-exchange me...To avoid carbonate precipitation for CO_(2) electrolysis,developing CO_(2) conversion in an acid electrolyte is viewed as an ultimately challenging technology.In Nature,Xia et al.recently explored a proton-exchange membrane system for reducing CO_(2) to formic acid with a Pb±Pb SO_(4) composite catalyst derived from waste lead-acid batteries based on the lattice carbon activation mechanism.Up to 93%Faradaic efficiency was realized when formic acid was produced by this technology.展开更多
Porous metal–organic frameworks(MOFs) have been recently discovered to be efficient catalysts for energy applications and green technologies. Here, we report on a scalable catalytic platform using Cu–based MOFs for ...Porous metal–organic frameworks(MOFs) have been recently discovered to be efficient catalysts for energy applications and green technologies. Here, we report on a scalable catalytic platform using Cu–based MOFs for electrocatalytic alkaline hydrogen evolution reaction. First, the solvothermal synthesis of Cu–BTC MOFs(BTC = 1,3,5–benzenetricarboxylate) at 85 ℃ and a 1:60 ligand–to–solvent ratio allowed for minimizing the chemical consumption. Second, the obtained platform demonstrated enhanced electrochemical performance compared with commercially available Cu–based MOFs, with a potential of –230 versus –232 eV, logarithm of the current density of –3.6 versus –4.2 cm2, and electrochemical surface area of 75 versus 25 cm2per cm2of geometric area, respectively. Morphological and Raman analyses also revealed that the high concentration of defects in the obtained submicron Cu–BTC MOFs can contribute to their improved catalytic performance. Thus, our findings pave the way to the low–cost synthesis of energy–efficient MOF–based catalysts for hydrogen production.展开更多
A new theoretical method to study super-multiperiod superlattices has been developed.The method combines the precision of the 8-band kp-method with the flexibility of the shooting method and the Monte Carlo approach.T...A new theoretical method to study super-multiperiod superlattices has been developed.The method combines the precision of the 8-band kp-method with the flexibility of the shooting method and the Monte Carlo approach.This method was applied to examine the finest quality samples of super-multiperiod Al_(0.3)Ga_(0.7)As/GaAs superlattices grown by molecular beam epitaxy.The express photoreflectance spectroscopy method was utilized to validate the proposed theoretical method.For the first time,the accurate theoretical analysis of the energy band diagram of super-multiperiod superlattices with experimental verification has been conducted.The proposed approach highly accurately determines transition peak positions and enables the calculation of the energy band diagram,transition energies,relaxation rates,and gain estimation.It has achieved a remarkably low 5%error compared to the commonly used method,which typically results in a 25%error,and allowed to recover the superlattice parameters.The retrieved intrinsic parameters of the samples aligned with XRD data and growth parameters.The proposed method also accurately predicted the escape of the second energy level for quantum well thicknesses less than 5 nm,as was observed in photoreflectance experiments.The new designs of THz light-emitting devices operating at room temperature were suggested by the developed method.展开更多
Up to date,solid-state carbon dots(CDs)with bright red fluorescence have scarcely achieved due to aggregation-caused quenching(ACQ)effect and extremely low quantum yield in deep-red to near infrared region.Here,we rep...Up to date,solid-state carbon dots(CDs)with bright red fluorescence have scarcely achieved due to aggregation-caused quenching(ACQ)effect and extremely low quantum yield in deep-red to near infrared region.Here,we report a novel fluorine-defects induced solid-state red fluorescence(λ_(em)=676 nm,the absolute fluorescence quantum yields is 4.17%)in fluorine,nitrogen and sulfur co-doped CDs(F,N,S-CDs),which is the first report of such a long wavelength emission of solid-state CDs.As a control,CDs without fluorine-doping(N,S-CDs)show no fluorescence in solid-state,and the fluorescence quantum yield/emission wavelength of N,S-CDs in solution-state are also lower/shorter than that of F,N,S-CDs,which is mainly due to the F-induced defect traps on the surface/edge of F,N,S-CDs.Moreover,the solid-state F,N,S-CDs exhibit an interesting temperature-sensitive behavior in the range of 80-420 K,with the maximum fluorescence intensity at 120 K,unveiling its potential as the temperature-dependent fluorescent sensor and the solid-state light-emitting device adapted to multiple temperatures.展开更多
Mass-spectrometric interface for the measurement of anaesthetic agent concentration in biological fluids (blood plasma and cerebrospinal fluid) is described. Sampling of biological fluids was performed during balanced...Mass-spectrometric interface for the measurement of anaesthetic agent concentration in biological fluids (blood plasma and cerebrospinal fluid) is described. Sampling of biological fluids was performed during balanced inhalational (desflurane, fentanyl) anaesthesia and total intravenous (propofol, fentanyl) anaesthesia. The described method for drug concentration measurement in biologic fluids does not require long-term sample processing before injecting the sample into mass-spectrometer interface, in contrast to chromatographic methods. A hydrophobic membrane was used in the interface to separate anaesthetic agents from biological fluids: inhalational anaesthetic desflurane, hypnotic propofol, analgesic fentanyl. A possibility to use the interface for measurement of desflurane and propofol absolute concentration in blood plasma and cerebrospinal fluid was demonstrated for the study of blood-brain barrier (BBB) properties.展开更多
Nanostructured HoFeO_(3)powders were obtained by solution combustion method at various glycinenitrate ratios(G/N=0.2,0.4,...,1.4).According to X-ray powder diffractometry data,the presence of two modifications of HoFe...Nanostructured HoFeO_(3)powders were obtained by solution combustion method at various glycinenitrate ratios(G/N=0.2,0.4,...,1.4).According to X-ray powder diffractometry data,the presence of two modifications of HoFeO_(3)in the synthesized samples was established:orthorhombic(Pbnm)and hexagonal(P63/mmc).The crystallite size of the obtained compositions varies from 62±6 to 29±3 nm,depending on the G/N ratio.From magnetic structure studies,it is found that HoFeO_(3)obtained with a stoichiometric amount of glycine in the reaction solution is in the magnetically ordered state and is represented by a sextet with quadrupole splitting(QS)=0 mm/s,isomeric shift(IS)=0.36 mm/s and effective field strength(Heff)=497 kOe.According to the results of vibrational magnetometry,it is found that the orthoferrites obtained have a ferromagnetic structure,the main parameters of which(Ms,Mr and Hc)systematically change with a change in the redox ratio of the reaction mixture and,as a consequence,their phase composition,and reach maximum values at a G/N ratio=0.6.In the samples obtained with a significant excess and lack of glycine(G/N=0.2 and 1.4),despite their amorphous nature,hysteresis loops characteristic of the ferromagnetic state of the substance is observed.It is hopeful to obtain a pure hexagonal modification of HoFeO_(3)via heat treatment on amorphous products of glycine-nitrate combustion.展开更多
The experimental results of 3-D fracture under compression are introduced in brief and the theory of stress criterion of 3-D fracture is studied. Methods to imitate initial fractures are developed. It is pointed that ...The experimental results of 3-D fracture under compression are introduced in brief and the theory of stress criterion of 3-D fracture is studied. Methods to imitate initial fractures are developed. It is pointed that there are important defects in the extreme value （EV） method ever proposed by Palaniswamy and Knauss. The major defect lies in that only two Euler angles （2EA） are considered, but another one is neglected. If the variation of all the three Euler angles （3EA） are considered, one can get better result which is consistent with the observation of faulting that extends on curved surfaces but not on planes. The method of evaluating maximal normal stress direction vector （NSDV） is proposed and further proved to be equivalent to the 3EA method. It is proved that the NSDV method can be further optimized to the method of composition of the first principal differential plane （CFPDP）. The results from CFPDP method can fit the curved surfaces of initial growth observed in the experiments of 3-D fracture. The CFPDP method can also be used to interpret the 3-D fractures of the slipping section between the asperities in the buried fault plane that is modeled as ellipse crack. The results of 3-D fracture can be applied to interpreting the related problems of faulting including the mechanism of a lot of shatter rocks with different dimensions, the cause of earthquakes occurred at the edge of plate under low shear stress, and the mechanism of anisotropy caused by the extensive dilatancy anisotropy （EDA） cracks.展开更多
A space object exploded near the city of Chelyabinsk on February 15, 2013. Meteorite fragments reached the Earth’s surface, and accordingly we may consider this space object to have been a meteorite. However, this ev...A space object exploded near the city of Chelyabinsk on February 15, 2013. Meteorite fragments reached the Earth’s surface, and accordingly we may consider this space object to have been a meteorite. However, this event showed a number of features not corresponding to the destruction of a meteorite. The space object began to disintegrate at an altitude of 70 km when pressure (dynamical loads) on its front surface was ~6.7 × 103 N·m-2. The substance from the object’s surface was not blown off by drops, as at ablation, but was dumped by jets over a distance up to 1 km. The trail of this space object visually reminded us of a jet aircraft’s contrail, made up of water. But there is no enough water at altitudes of 30 - 70 km. It may be assumed that the object itself delivered water to these altitudes. The calculation of gas rise over the trail showed that the temperature in some parts of this trail was about 900 K. Heating of large masses of gas can be explained not only by the release of kinetic energy of the space object, but also by combustion processes of its substance. Thus, it was concluded that the meteorite could have been delivered by a comet.展开更多
Mn doped ZnO bulk single crystals are grown by the modified Bridgman method. The as-grown crystals are red in eolour. The additional Raman mode observed at 524cm^-1 is attributed to the Mn ions incorporating into ZnO ...Mn doped ZnO bulk single crystals are grown by the modified Bridgman method. The as-grown crystals are red in eolour. The additional Raman mode observed at 524cm^-1 is attributed to the Mn ions incorporating into ZnO crystal. The crystal exhibited paramagnetie under lower applied field below 2280 Oe. Then diamagnetism is observed in the crystal when the magnetic field rises up and becomes dominant under applied field above 5270 Oe. The magnetic susceptibility dependence on the temperature follows a Curie law indicating a typical paramagnetie characteristic under an applied field of 2kOe. No ferromagnetic ordering is observed in the as-grown Mn-doped ZnO crystal.展开更多
Unusual reliefs on the Earth’s surface were found in aerial photographs of Eastern Siberia in the late 20<sup>th</sup> century. These reliefs consist of several tens (up to hundreds) of stripes that have ...Unusual reliefs on the Earth’s surface were found in aerial photographs of Eastern Siberia in the late 20<sup>th</sup> century. These reliefs consist of several tens (up to hundreds) of stripes that have arisen as a result of the destruction of vegetation and the surface layer of the ground. Structures of stripes are extended, ranging in size from 6 km to ≥20 km, with a width of several kilometers. Every strip (scratch on the ground) is roughly estimated to be up to 50 m wide and ≥500 m long. The stripes start from one edge of the relief and stretch at inter-vals to the other, slightly diverging symmetrically from the central axis. It was determined that these reliefs are not associated with the movement of soil (avalanches, mudflows) or with the impact of air currents (hurricanes, storm, tornado). Geographically, these struc-tures of stripes are located within a circle with a radius of 770 km, described around the epicenter of the Tunguska catastrophe.展开更多
A number of numerical experiments with artificial random signals (the second order autoregressive processes), which have important statistical properties similar to that of the observed instrumental temperature (1850-...A number of numerical experiments with artificial random signals (the second order autoregressive processes), which have important statistical properties similar to that of the observed instrumental temperature (1850-2015), were carried out. The results show that in frame of the selected mathematical model the return period of climatic events, analogous to the current global warming (linear increase of temperature for 0.95°C during the last 135 years) is 2849-5180 years (one event per 2849-5180 years). This means that global warming (GW) of the last 135 years can unlikely be fully explained by inherent oscillations of the climatic system. It was found however, that natural fluctuations of climate may appreciably contribute to the GW. The return period of climatic episodes with 0.5°C warming during the 135 years (half of the observed GW) was less than 500 years. The result testifies that the role of external factors (emission of greenhouse gases, solar activity etc.) in the GW could be less than often presumed.展开更多
For the first time, DySrA104 of K2NiF4-type structure was synthesized. The parameters of DySrA104 ele- mentary unit cell are determined as follows： a = 0.368 （4） nm, c = 1.229 （2） nm, V = 0.166 （4） nm3. The res...For the first time, DySrA104 of K2NiF4-type structure was synthesized. The parameters of DySrA104 ele- mentary unit cell are determined as follows： a = 0.368 （4） nm, c = 1.229 （2） nm, V = 0.166 （4） nm3. The research of the complex aluminates ZnSrA104 （Ln = Nd, Gd, Dy） solid-state process demonstrated the change of the formation mecha- nism among LnSrA104 （Ln = Nd, Gd, Dy） series from DySrA104 oxide. The performed analysis provided a possibility to realize why chemists couldn＇t get DySrA104 for a long period of time.展开更多
Studying the behavior of effective ion charge Zeff, which indicates the degree of pollution of plasma and can provide valuable information about many processes taking place in plasma, mechanisms of the releasing impur...Studying the behavior of effective ion charge Zeff, which indicates the degree of pollution of plasma and can provide valuable information about many processes taking place in plasma, mechanisms of the releasing impurities, transport, etc is of great interest. This paper describes the development of the Zeff diagnostic system for the Globus-M2 tokamak. The effective ion charge is determined on the basis of measurements of the bremsstrahlung intensity and Thomson scattering data-Te and ne profiles. The results of the first Zeff measurements obtained for several discharges on the Globus-M tokamak are presented in this paper. The results have been validated by simulation using the ASTRA transport code for the same discharges, and it has demonstrated a good agreement with the experimental results.展开更多
Two different types of MHD instabilities with rapidly chirping frequency were found to arise in the Globus-M2 spherical tokamak in substantially different frequency ranges.The first type arises at frequencies of an or...Two different types of MHD instabilities with rapidly chirping frequency were found to arise in the Globus-M2 spherical tokamak in substantially different frequency ranges.The first type arises at frequencies of an order of 1 MHz in ohmic plasmas at relatively low density(n_(e))<2×10^(19) m^(-3) in a wide range of toroidal magnetic fields and plasma currents.This type of instability was identified as compressional Alfven waves,driven by electrons,accelerated during a sawtooth crush.It was found that the mode frequency is sweeping in time,according to the Berk-Breizman hole-clump nonlinear chirping model.The second type of wave arises in a specific single-swing regime of the central solenoid current with a very narrow plasma column,when the plasma tends to decay at extremely low density(n_(e))<2×10^(18) m^(-3) and,in fact,is an instability of the runaway electron beam.The exited modes cover the whole observed frequency range and are divided into several(two or three)frequency regions:approximately 0-30 MHz,60-120 MHz and sometimes 30-60 MHz.Reconnection of the branches was also observed.Single chirps are more rapid than for 1 MHz Alfven instability and follow an exponential law.This paper,to our knowledge,is the first report of frequency chirping instabilities excited by accelerated electrons at a spherical tokamak.展开更多
The advanced tokamak scenario is a promising operation scenario for ITER and fusion neutron sources.In this scenario the minimum value of the safety factor in the center of the plasma exceeds unity.In the compact sphe...The advanced tokamak scenario is a promising operation scenario for ITER and fusion neutron sources.In this scenario the minimum value of the safety factor in the center of the plasma exceeds unity.In the compact spherical tokamak Globus-M,the formation of such conditions is possible with neutral beam injection at the current ramp-up phase.Due to the slower diffusion of current inside the plasma,a zone is formed with reduced heat and particle transport across the magnetic field,which affects the temperature and density profiles of the plasma.This leads to the peaked density profile formation and improvement of the energy confinement time.To achieve a high fraction of the bootstrap current,it is necessary to increase the plasma pressure.At the same time,the maximum allowable pressure is limited to the normalized beta limit.展开更多
基金financial support of the Ministry of Science and Higher Education of the Russian Federation in the framework of the state contract in the field of science(No.FSEG-2024-0005)。
文摘This study discusses the scope of application of the Doppler backscattering(DBS)diagnostic for the tokamak with reactor technologies(TRT)project.This involved numerical modeling of the three-dimensional(3D)beam trajectories.Calculations were performed to investigate the propagation of microwaves in the V(40–75 GHz)and W(75–110 GHz)frequency ranges with O-mode polarization for the density profile of the base TRT scenario.Our analysis showed that the DBS system antenna on the TRT would need to be tilted in both the poloidal and toroidal directions in order to meet the condition Kperp/Kpar<10%..For the DBS system located in the equatorial plane it was shown that a wide range of poloidal and toroidal angles is available for the successful implementation of the diagnostic to study the core,pedestal and scrape-off layer(SOL)regions.The DBS system located at 35 cm above the equatorial plane would be more limited in measurements only covering the SOL and pedestal regions.A shift of the cut-offs in the toroidal direction highlighted the need for 3D analysis of the DBS data.
文摘Energy storage devices have been extensively owing to their critical role in addressing the energy and environment challenges.Aqueous trivalent metal batteries are promising due to their unique three-electron redox reactions for high reversible capacity and high safety[1].Especially,aqueous aluminum-based batteries have attracted significant attention[2].However,severe water decomposition occurs due to their low redox potential(Al3+/Al,-1.66 V vs.SHE)[3].In contrast,the metallic indium(In)/or In3+has a more suitable redox potential(-0.34 V vs.SHE),which is within the water stability window,minimizingwater decomposition[4].Recently,a study on trivalent indium metal batteries was firstly reported by Wu’s group in Journal of the American Chemical Society[5].
基金the financial support of the Ministry of Science and Higher Education of the Russian Federation in the framework of the State Contract in the Field of Science(No.FSEG-2024-0005)。
文摘The first results of investigation of the turbulence structure using Doppler backscattering(DBS)on the Globus-M2 tokamak are presented.A one-channel DBS system with a variable probing frequency within the 18–26 GHz range was installed to investigate the edge plasma at normalized minor radiiρ=0.9–1.1.Radial correlation Doppler reflectometry was used to study the changes in turbulence eddies after the LH transition.Correlation analysis was applied to the phase derivative of complex in-phase and quadrature(IQ)signals of the DBS diagnostic as it contains information about the poloidal plasma rotation velocity.In L-mode,the radial correlation length L_(r)is estimated to be 3 cm and after transition to H-mode reduces to approximately 2 cm.Gyrokinetic modelling in a linear local approximation using code GENE indicates that the instability with positive growth rate at the normalized minor radiusρ=0.75 in L-mode and H-mode on Globus-M2 was the ion temperature gradient(ITG)mode.
基金The research was carried out within the State Assignment of the Ministry of Science and Higher Education of the Russian Federation(project No.FFUG-2024-0036)。
文摘CO_(2) is the most cost-eff ective and abundant carbon resource,while the reverse water-gas reaction(rWGS)is one of the most eff ective methods of CO_(2) utilization.This work presents a comparative study of rWGS activity for perovskite systems based on AFeO_(3)(where A=Ce,La,Y).These systems were synthesized by solution combustion synthesis(SCS)with diff erent ratios of fuel(glycine)and oxidizer(φ),diff erent amounts of NH 4 NO_(3),and the addition of alumina or silica as supports.Various techniques,including X-ray diff raction analysis,thermogravimetric analysis,Fourier transform infrared spectroscopy(FTIR),scanning electron microscopy,energy-dispersive X-ray spectroscopy,N 2-physisorption,H_(2) temper-ature-programmed reduction,temperature-programmed desorption of H_(2) and CO_(2),Raman spectroscopy,and in situ FTIR,were used to relate the physicochemical properties with the catalytic performance of the obtained composites.Each specifi c perovskite-containing system(either bulk or supported)has its own optimalφand NH_(4) NO_(3) amount to achieve the highest yield and dispersion of the perovskite phase.Among all synthesized systems,bulk SCS-derived La-Fe-O systems showed the highest resistance to reducing environments and the easiest hydrogen desorption,outperforming La-Fe-O produced by solgel combustion(SGC).CO_(2) conversion into CO at 600°C for bulk ferrite systems,depending on the A-cation type and preparation method,follows the order La(SGC)<Y<Ce<La(SCS).The diff erences in properties between La-Fe-O obtained by the SCS and SGC methods can be attributed to diff erent ratios of oxygen and lanthanum vacancy contributions,hydroxyl coverage,morphology,and free iron oxide presence.In situ FTIR data revealed that CO_(2) hydrogenation occurs through formates generated under reaction conditions on the bulk system based on La-Fe-O,obtained by the SCS method.γ-Al_(2)O_(3) improves the dispersion of CeFeO_(3) and LaFeO_(3) phases,the specifi c surface area,and the quantity of adsorbed H_(2) and CO_(2).This led to a signifi cant increase in CO_(2) conversion for supported CeFeO_(3) but not for the La-based system compared to bulk and SiO_(2)-supported perovskite catalysts.However,adding alumina increased the activity per mass for both Ce-and La-based perovskite systems,reducing the amount of rare-earth components in the catalyst and thereby lowering the cost without substantially compromising stability.
基金supported by the Natural Science Foundation of China (No. 22268003)。
文摘To avoid carbonate precipitation for CO_(2) electrolysis,developing CO_(2) conversion in an acid electrolyte is viewed as an ultimately challenging technology.In Nature,Xia et al.recently explored a proton-exchange membrane system for reducing CO_(2) to formic acid with a Pb±Pb SO_(4) composite catalyst derived from waste lead-acid batteries based on the lattice carbon activation mechanism.Up to 93%Faradaic efficiency was realized when formic acid was produced by this technology.
基金This work was supported by Russian Science Foundation(22-73-10069“Design and application of fl exible Metal organic frameworks for photonics devices,”the chemical part and structural analysis of developed MOFs)The of stability MOFs was conducted under the fi nancial support of the Ministry of Science and Higher Education of the Russian Federation as part of the World-Class Research Center program:Advanced Digital Technologies(contract No.075-15-2022-311 dated 20.04.2022)The authors thank the Engineering Centre of Saint Petersburg State Institute of Technology for PXRD analysis.
文摘Porous metal–organic frameworks(MOFs) have been recently discovered to be efficient catalysts for energy applications and green technologies. Here, we report on a scalable catalytic platform using Cu–based MOFs for electrocatalytic alkaline hydrogen evolution reaction. First, the solvothermal synthesis of Cu–BTC MOFs(BTC = 1,3,5–benzenetricarboxylate) at 85 ℃ and a 1:60 ligand–to–solvent ratio allowed for minimizing the chemical consumption. Second, the obtained platform demonstrated enhanced electrochemical performance compared with commercially available Cu–based MOFs, with a potential of –230 versus –232 eV, logarithm of the current density of –3.6 versus –4.2 cm2, and electrochemical surface area of 75 versus 25 cm2per cm2of geometric area, respectively. Morphological and Raman analyses also revealed that the high concentration of defects in the obtained submicron Cu–BTC MOFs can contribute to their improved catalytic performance. Thus, our findings pave the way to the low–cost synthesis of energy–efficient MOF–based catalysts for hydrogen production.
基金The work was supported by the Ministry of Education and Science of the Russian Federation in the framework of experimental research(Nos.075-01438-22-06 and FSEE-2022-0018)the Russian Science Foundation in theoretical research(No.RSF 23-29-00216).
文摘A new theoretical method to study super-multiperiod superlattices has been developed.The method combines the precision of the 8-band kp-method with the flexibility of the shooting method and the Monte Carlo approach.This method was applied to examine the finest quality samples of super-multiperiod Al_(0.3)Ga_(0.7)As/GaAs superlattices grown by molecular beam epitaxy.The express photoreflectance spectroscopy method was utilized to validate the proposed theoretical method.For the first time,the accurate theoretical analysis of the energy band diagram of super-multiperiod superlattices with experimental verification has been conducted.The proposed approach highly accurately determines transition peak positions and enables the calculation of the energy band diagram,transition energies,relaxation rates,and gain estimation.It has achieved a remarkably low 5%error compared to the commonly used method,which typically results in a 25%error,and allowed to recover the superlattice parameters.The retrieved intrinsic parameters of the samples aligned with XRD data and growth parameters.The proposed method also accurately predicted the escape of the second energy level for quantum well thicknesses less than 5 nm,as was observed in photoreflectance experiments.The new designs of THz light-emitting devices operating at room temperature were suggested by the developed method.
基金financially supported by the National Natural Science Foundation of China(No.51772001)Anhui Province Key Research and Development Plan Project International Science and Technology Cooperation Special Project(No.202004bll020015)support of the Key Laboratory of Structure and Functional Regulation of Hybrid Materials(Anhui University),Ministry of Education.
文摘Up to date,solid-state carbon dots(CDs)with bright red fluorescence have scarcely achieved due to aggregation-caused quenching(ACQ)effect and extremely low quantum yield in deep-red to near infrared region.Here,we report a novel fluorine-defects induced solid-state red fluorescence(λ_(em)=676 nm,the absolute fluorescence quantum yields is 4.17%)in fluorine,nitrogen and sulfur co-doped CDs(F,N,S-CDs),which is the first report of such a long wavelength emission of solid-state CDs.As a control,CDs without fluorine-doping(N,S-CDs)show no fluorescence in solid-state,and the fluorescence quantum yield/emission wavelength of N,S-CDs in solution-state are also lower/shorter than that of F,N,S-CDs,which is mainly due to the F-induced defect traps on the surface/edge of F,N,S-CDs.Moreover,the solid-state F,N,S-CDs exhibit an interesting temperature-sensitive behavior in the range of 80-420 K,with the maximum fluorescence intensity at 120 K,unveiling its potential as the temperature-dependent fluorescent sensor and the solid-state light-emitting device adapted to multiple temperatures.
文摘Mass-spectrometric interface for the measurement of anaesthetic agent concentration in biological fluids (blood plasma and cerebrospinal fluid) is described. Sampling of biological fluids was performed during balanced inhalational (desflurane, fentanyl) anaesthesia and total intravenous (propofol, fentanyl) anaesthesia. The described method for drug concentration measurement in biologic fluids does not require long-term sample processing before injecting the sample into mass-spectrometer interface, in contrast to chromatographic methods. A hydrophobic membrane was used in the interface to separate anaesthetic agents from biological fluids: inhalational anaesthetic desflurane, hypnotic propofol, analgesic fentanyl. A possibility to use the interface for measurement of desflurane and propofol absolute concentration in blood plasma and cerebrospinal fluid was demonstrated for the study of blood-brain barrier (BBB) properties.
文摘Nanostructured HoFeO_(3)powders were obtained by solution combustion method at various glycinenitrate ratios(G/N=0.2,0.4,...,1.4).According to X-ray powder diffractometry data,the presence of two modifications of HoFeO_(3)in the synthesized samples was established:orthorhombic(Pbnm)and hexagonal(P63/mmc).The crystallite size of the obtained compositions varies from 62±6 to 29±3 nm,depending on the G/N ratio.From magnetic structure studies,it is found that HoFeO_(3)obtained with a stoichiometric amount of glycine in the reaction solution is in the magnetically ordered state and is represented by a sextet with quadrupole splitting(QS)=0 mm/s,isomeric shift(IS)=0.36 mm/s and effective field strength(Heff)=497 kOe.According to the results of vibrational magnetometry,it is found that the orthoferrites obtained have a ferromagnetic structure,the main parameters of which(Ms,Mr and Hc)systematically change with a change in the redox ratio of the reaction mixture and,as a consequence,their phase composition,and reach maximum values at a G/N ratio=0.6.In the samples obtained with a significant excess and lack of glycine(G/N=0.2 and 1.4),despite their amorphous nature,hysteresis loops characteristic of the ferromagnetic state of the substance is observed.It is hopeful to obtain a pure hexagonal modification of HoFeO_(3)via heat treatment on amorphous products of glycine-nitrate combustion.
基金supported by National Natural Science Foundation of China(No. 41090292)
文摘The experimental results of 3-D fracture under compression are introduced in brief and the theory of stress criterion of 3-D fracture is studied. Methods to imitate initial fractures are developed. It is pointed that there are important defects in the extreme value （EV） method ever proposed by Palaniswamy and Knauss. The major defect lies in that only two Euler angles （2EA） are considered, but another one is neglected. If the variation of all the three Euler angles （3EA） are considered, one can get better result which is consistent with the observation of faulting that extends on curved surfaces but not on planes. The method of evaluating maximal normal stress direction vector （NSDV） is proposed and further proved to be equivalent to the 3EA method. It is proved that the NSDV method can be further optimized to the method of composition of the first principal differential plane （CFPDP）. The results from CFPDP method can fit the curved surfaces of initial growth observed in the experiments of 3-D fracture. The CFPDP method can also be used to interpret the 3-D fractures of the slipping section between the asperities in the buried fault plane that is modeled as ellipse crack. The results of 3-D fracture can be applied to interpreting the related problems of faulting including the mechanism of a lot of shatter rocks with different dimensions, the cause of earthquakes occurred at the edge of plate under low shear stress, and the mechanism of anisotropy caused by the extensive dilatancy anisotropy （EDA） cracks.
文摘A space object exploded near the city of Chelyabinsk on February 15, 2013. Meteorite fragments reached the Earth’s surface, and accordingly we may consider this space object to have been a meteorite. However, this event showed a number of features not corresponding to the destruction of a meteorite. The space object began to disintegrate at an altitude of 70 km when pressure (dynamical loads) on its front surface was ~6.7 × 103 N·m-2. The substance from the object’s surface was not blown off by drops, as at ablation, but was dumped by jets over a distance up to 1 km. The trail of this space object visually reminded us of a jet aircraft’s contrail, made up of water. But there is no enough water at altitudes of 30 - 70 km. It may be assumed that the object itself delivered water to these altitudes. The calculation of gas rise over the trail showed that the temperature in some parts of this trail was about 900 K. Heating of large masses of gas can be explained not only by the release of kinetic energy of the space object, but also by combustion processes of its substance. Thus, it was concluded that the meteorite could have been delivered by a comet.
基金Supported by the National Natural Science Foundation of China under Grant No 50372076.
文摘Mn doped ZnO bulk single crystals are grown by the modified Bridgman method. The as-grown crystals are red in eolour. The additional Raman mode observed at 524cm^-1 is attributed to the Mn ions incorporating into ZnO crystal. The crystal exhibited paramagnetie under lower applied field below 2280 Oe. Then diamagnetism is observed in the crystal when the magnetic field rises up and becomes dominant under applied field above 5270 Oe. The magnetic susceptibility dependence on the temperature follows a Curie law indicating a typical paramagnetie characteristic under an applied field of 2kOe. No ferromagnetic ordering is observed in the as-grown Mn-doped ZnO crystal.
文摘Unusual reliefs on the Earth’s surface were found in aerial photographs of Eastern Siberia in the late 20<sup>th</sup> century. These reliefs consist of several tens (up to hundreds) of stripes that have arisen as a result of the destruction of vegetation and the surface layer of the ground. Structures of stripes are extended, ranging in size from 6 km to ≥20 km, with a width of several kilometers. Every strip (scratch on the ground) is roughly estimated to be up to 50 m wide and ≥500 m long. The stripes start from one edge of the relief and stretch at inter-vals to the other, slightly diverging symmetrically from the central axis. It was determined that these reliefs are not associated with the movement of soil (avalanches, mudflows) or with the impact of air currents (hurricanes, storm, tornado). Geographically, these struc-tures of stripes are located within a circle with a radius of 770 km, described around the epicenter of the Tunguska catastrophe.
文摘A number of numerical experiments with artificial random signals (the second order autoregressive processes), which have important statistical properties similar to that of the observed instrumental temperature (1850-2015), were carried out. The results show that in frame of the selected mathematical model the return period of climatic events, analogous to the current global warming (linear increase of temperature for 0.95°C during the last 135 years) is 2849-5180 years (one event per 2849-5180 years). This means that global warming (GW) of the last 135 years can unlikely be fully explained by inherent oscillations of the climatic system. It was found however, that natural fluctuations of climate may appreciably contribute to the GW. The return period of climatic episodes with 0.5°C warming during the 135 years (half of the observed GW) was less than 500 years. The result testifies that the role of external factors (emission of greenhouse gases, solar activity etc.) in the GW could be less than often presumed.
文摘For the first time, DySrA104 of K2NiF4-type structure was synthesized. The parameters of DySrA104 ele- mentary unit cell are determined as follows： a = 0.368 （4） nm, c = 1.229 （2） nm, V = 0.166 （4） nm3. The research of the complex aluminates ZnSrA104 （Ln = Nd, Gd, Dy） solid-state process demonstrated the change of the formation mecha- nism among LnSrA104 （Ln = Nd, Gd, Dy） series from DySrA104 oxide. The performed analysis provided a possibility to realize why chemists couldn＇t get DySrA104 for a long period of time.
基金funded by RSF according to the research project(No.17-72-20076).The experimental investigations were performed on the Unique Scientific Facility ‘Spherical tokamak Globus-M’,which is incorporated in the Federal Joint Research Center ‘Material science and characterization in advanced technology’.The maintenance of routine diagnostics was supported by the Ioffe Institute
文摘Studying the behavior of effective ion charge Zeff, which indicates the degree of pollution of plasma and can provide valuable information about many processes taking place in plasma, mechanisms of the releasing impurities, transport, etc is of great interest. This paper describes the development of the Zeff diagnostic system for the Globus-M2 tokamak. The effective ion charge is determined on the basis of measurements of the bremsstrahlung intensity and Thomson scattering data-Te and ne profiles. The results of the first Zeff measurements obtained for several discharges on the Globus-M tokamak are presented in this paper. The results have been validated by simulation using the ASTRA transport code for the same discharges, and it has demonstrated a good agreement with the experimental results.
文摘Two different types of MHD instabilities with rapidly chirping frequency were found to arise in the Globus-M2 spherical tokamak in substantially different frequency ranges.The first type arises at frequencies of an order of 1 MHz in ohmic plasmas at relatively low density(n_(e))<2×10^(19) m^(-3) in a wide range of toroidal magnetic fields and plasma currents.This type of instability was identified as compressional Alfven waves,driven by electrons,accelerated during a sawtooth crush.It was found that the mode frequency is sweeping in time,according to the Berk-Breizman hole-clump nonlinear chirping model.The second type of wave arises in a specific single-swing regime of the central solenoid current with a very narrow plasma column,when the plasma tends to decay at extremely low density(n_(e))<2×10^(18) m^(-3) and,in fact,is an instability of the runaway electron beam.The exited modes cover the whole observed frequency range and are divided into several(two or three)frequency regions:approximately 0-30 MHz,60-120 MHz and sometimes 30-60 MHz.Reconnection of the branches was also observed.Single chirps are more rapid than for 1 MHz Alfven instability and follow an exponential law.This paper,to our knowledge,is the first report of frequency chirping instabilities excited by accelerated electrons at a spherical tokamak.
基金financially supported by an RSF research project (no. 17-7220076)
文摘The advanced tokamak scenario is a promising operation scenario for ITER and fusion neutron sources.In this scenario the minimum value of the safety factor in the center of the plasma exceeds unity.In the compact spherical tokamak Globus-M,the formation of such conditions is possible with neutral beam injection at the current ramp-up phase.Due to the slower diffusion of current inside the plasma,a zone is formed with reduced heat and particle transport across the magnetic field,which affects the temperature and density profiles of the plasma.This leads to the peaked density profile formation and improvement of the energy confinement time.To achieve a high fraction of the bootstrap current,it is necessary to increase the plasma pressure.At the same time,the maximum allowable pressure is limited to the normalized beta limit.
