The high-temperature interaction of nanostructured Lu_(2)Si_(2)O_(7) environmental barrier coatings(EBCs)with calcium-magnesium-aluminosilicate(CMAS)was investigated at 1400℃ for 1,10,25,and 50 h to evaluate the coat...The high-temperature interaction of nanostructured Lu_(2)Si_(2)O_(7) environmental barrier coatings(EBCs)with calcium-magnesium-aluminosilicate(CMAS)was investigated at 1400℃ for 1,10,25,and 50 h to evaluate the coating’s resistance to CMAS corrosion.The results indicate a phase transformation over time,transitioning from Ca_(2)Lu_(8)(SiO_(4))6O_(2) apatite and Lu_(2)Si_(2)O_(7) to solely Lu_(2)Si_(2)O_(7).The interaction of the Lu_(2)Si_(2)O_(7) coating with the CMAS melts was divided into three stages based on the corrosion reaction behavior.The delamination cracks were distributed throughout the interface between the Si bond layer and Lu_(2)Si_(2)O_(7) layer after corroded at 1400℃ for 50 h,signifying coating failure.In addition,the influence of monosilicates,disilicates,and corrosion duration on the recession layer thickness was analyzed by comparing previous reports on RE_(2)SiO_(5)/RE_(2)Si_(2)O_(7) coatings(RE=Gd,Yb,Lu,Er).Furthermore,the variation in the thermally grown oxide layer thickness in CMAS-corroded Lu_(2)Si_(2)O_(7) coatings was systematically investigated.展开更多
Over the past several decades,the integration of IONs into EP emerged as an effective method for enhancing its mechanical properties.Nevertheless,challenges remain,especially with u-IONs,where the interfacial strength...Over the past several decades,the integration of IONs into EP emerged as an effective method for enhancing its mechanical properties.Nevertheless,challenges remain,especially with u-IONs,where the interfacial strength with EP is suboptimal,resulting in aggregation within the EP matrix and a subsequent deterioration in the mechanical performance of u-ION/EP nanocomposites.In this comprehensive review,we explored advanced chemical modification techniques tailored for IONs incorporated into EP,providing a detailed examination of the mechanical characteristics of surface cm-ION/EP nanocomposites.This review investigates various chemical modification methods and their distinct impacts on the mechanical attributes of the resulting EP nanocomposites.Special emphasis is given to addressing the persistent challenges of inadequate interfacial strength and aggregation.Furthermore,this article examines prospective surface modification approaches for inorganic oxide nanoparticles,offering a visionary outlook on methods to improve the mechanical performance of EP in future.展开更多
The complex ceramic core used for hollow turbine blades requires a high porosity and a high fiexural strength. For a better balance between porosity and fiexural strength, ceramic materials with porous structures are ...The complex ceramic core used for hollow turbine blades requires a high porosity and a high fiexural strength. For a better balance between porosity and fiexural strength, ceramic materials with porous structures are preferred. In order to achieve the transition from disordered pore formation to ordered pore formation, Al_(2)O_(3) ceramic cores with triply periodic minimal surface(TPMS) micro lattice structures with different structural configurations(gyroid, diamond, and neovius) and different volume fractions of lattice structures(30, 40, and 50, vol.%) were designed and prepared by vat photopolymerization 3D printing. The effects of structural configuration and volume fraction of the lattice structure on the following structural shrinkage, microstructure, and flexural strength were investigated. The shrinkage relationship of the three lattice configurations is: neovius>diamond>gyroid. Besides, it is found that with an increase in the volume fraction of the 3D printed Al_(2)O_(3) ceramic micro lattice structures, their fiexural strength correspondingly increases ranging from 54.95 MPa to 139.1 MPa. The maximum average fiexural strength of the 3D printed Al_(2)O_(3) ceramic micro lattice structures is obtained when the structural configuration is diamond and with a volume fraction of 50vol.%, which is 139.1 MPa. Even when the volume fraction of the lattice structure is 30vol.%, that is to say the porosity is 70%, the fiexural strength is as high as 50-70 MPa, which can still be maintained at a high level. In addition, when the volume fraction of the lattice structure is a certain value, the sample with diamond configuration has a higher strength. The internal pore morphology, pore size, and porosity of the cores are precisely controlled, achieving both a high porosity and a high strength. Therefore, this study maintains high porosity and high strength simultaneously, providing a new lattice structure design idea for 3D printed ceramic cores.展开更多
This study pioneers the integrated fabrication of magnesium corrugated-core sandwich structures using wire-arc directed energy deposition(WA-DED).Two sandwich structures—V-type and X-type—were designed with optimize...This study pioneers the integrated fabrication of magnesium corrugated-core sandwich structures using wire-arc directed energy deposition(WA-DED).Two sandwich structures—V-type and X-type—were designed with optimized deposition paths to achieve comparable grain morphology while enhancing strength.The compression properties and failure modes of the two corrugated-core sandwich structures were examined through quasi-static compression tests.Results showed that the V-type structure exhibited a higher specific compressive strength(93 MPa∙cm^(3)/g)than the X-type structure(72 MPa∙cm^(3)/g).Both finite element analysis and experimental compression tests indicated that failure occurred at the midsection of the corrugated core.This work offers valuable insights for the efficient fabrication of high-strength corrugated-core sandwich structures.展开更多
The development of machine learning has provided a new perspective for the design of electromagnetic metastructures,particularly in the rapid design of key performance metrics such as effective absorption bandwidth.Tr...The development of machine learning has provided a new perspective for the design of electromagnetic metastructures,particularly in the rapid design of key performance metrics such as effective absorption bandwidth.Traditional methods,grounded in electromagnetic theory and empirical approaches,often lacked sufficient flexibility and adaptability.In this work,three types of machine learning models were developed to establish the relationship between effective absorption bandwidth and structural parameters.The results indicated that the random forest model achieved the most accurate and efficient design for this task.Then,the additive manufacturing optimal metastructure obtained using this approach outperformed existing designs in terms of both effective absorption bandwidth and reflectivity,while also exhibiting superior radar stealth performance and mechanical load-bearing capacity.Furthermore,through interpretable machine learning and data analysis,the intrinsic mechanisms underlying the relationship between effective absorption bandwidth and structural parameters were revealed.Overall,this work introduced a novel approach to metastructure design and enhanced the understanding of the relationship between structural parameters and electromagnetic properties,providing a key foundation for future design.展开更多
The curing behavior of composites significantly influences their performance,making it crucial to understand the curing process.This study experimentally measured specific heat capacity,thermal conductivity,glass tran...The curing behavior of composites significantly influences their performance,making it crucial to understand the curing process.This study experimentally measured specific heat capacity,thermal conductivity,glass transition temperature,coefficient of thermal expansion,and cure shrinkage of materials.A simulation model of its curing deformation was established and validated against strain data obtained from fiber Bragg grating experiments.The effects of thickness,heating rate,and cooling rate on the curing temperature field and residual stress field during the molding of thick-section composite plates were analyzed.展开更多
Thermal controllers equipped with phase-change materials are widely used for maintaining the moderate temperatures of various electric devices used in spacecraft. Yet, the structures of amounts of thermal controllers ...Thermal controllers equipped with phase-change materials are widely used for maintaining the moderate temperatures of various electric devices used in spacecraft. Yet, the structures of amounts of thermal controllers add up to such a large value that restricts the employment of scientific devices due to the limit of rocket capacity. A lightweight structure of phase-change thermal controllers has been one of the main focuses of spacecraft design engineering. In this work, we design a lightweight phase-change thermal controller structure based on lattice cells. The structure is manufactured entirely with AlSi10 Mg by direct metal laser melting. The dimensions of the structure are 230 mm × 170 mm × 15 mm, and the mass is 190 g, which is 60% lighter than most traditional structures(500–600 g) with the same dimensions. The 3 D-printed structure can reduce the risk of leakage at soldering manufacture by a welding process. Whether the strength of the designed structure is sufficient is determined through mechanical analysis and experiments. Thermal test results show that the thermal capacity of the lattice-based thermal controller is increased by50% compared to that of traditional controllers with the same volume.展开更多
A graded structural material(GSM)with a material transition from TA15 to TC11 was fabricated by wire arc additive manufacturing(WAAM)method.The grain morphology,chemical composition,microstructure and mechanical prope...A graded structural material(GSM)with a material transition from TA15 to TC11 was fabricated by wire arc additive manufacturing(WAAM)method.The grain morphology,chemical composition,microstructure and mechanical properties of the as-deposited GSM were all characterized to investigate their variations along the deposition direction.The results indicate that from TA15 to TC11,the grain size decreases and a transition from columnar grains to equiaxed grains occurs.The content of alloy element alters greatly within a short distance,and the width of the mutation zone is 800μm.Both TA15 and TC11 regions exhibit basketweave microstructure withα-phase andβ-phase.However,during the transition from TA15 to TC11,theα-lath becomes fine,which leads to an increase in microhardness.The tensile test shows that the bonding strength at the interface is higher than the longitudinal strength of TA15,and the lateral elongation at the interface is higher than that of TA15 and TC11.展开更多
This paper presents a combination of experimental and numerical investigations on the dynamic response of scaling cabin structures under internal blast loading.The purpose of this study is to modify the similar relati...This paper presents a combination of experimental and numerical investigations on the dynamic response of scaling cabin structures under internal blast loading.The purpose of this study is to modify the similar relationship between the scaled-down model and the prototype of the cabin structures under internal blast loading.According to the Hopkinson’s scaling law,three sets of cabin structure models with different scaling factors combined with different explosive masses were designed for the experimental study.The dynamic deformation process of the models was recorded by a three-dimensional digital imaging correlation(DIC)method and a 3D scanning technology was used to reconstruct the deformation modes of the specimen.In addition,a finite element model was developed for the modification of the scaling law.The experimental results showed that the final deflection-to-thickness ratio was increased with the increase of the model size despite of the similar trend of their deformation processes.The reason for this inconsistency was discussed based on the traditional scaling law and a modified formula considering of the effects of size and strain-rate was provided.展开更多
Inspired by the gradient structure of the nature,two gradient lattice structures,i.e.,unidirectional gradient lattice(UGL)and bidirectional gradient lattice(BGL),are proposed based on the body-centered cubic(BCC)latti...Inspired by the gradient structure of the nature,two gradient lattice structures,i.e.,unidirectional gradient lattice(UGL)and bidirectional gradient lattice(BGL),are proposed based on the body-centered cubic(BCC)lattice to obtain specially designed mechanical behaviors,such as load-bearing and energy absorption capacities.First,a theoretical model is proposed to predict the initial stiffness of the gradient lattice structure under compressive loading,and validated against quasi-static compression tests and finite element models(FEMs).The deformation and failure mechanisms of the two structures are further studied based on experiments and simulations.The UGL structure exhibits a layer-by-layer failure mode,which avoids structure-wise shear failure in uniform structures.The BGL structure presents a symmetry deformation pattern,and the failure initiates at the weakest part.Finally,the energy absorption behaviors are also discussed.This study demonstrates the potential application of gradient lattice structures in load-transfer-path modification and energy absorption by topology design.展开更多
High-entropy diborides(HEBs)have attracted extensive research due to their potential ultra-high hardness.In the present work,the effects of transition metals(TM)on lattice parameters,electron work function(EWF),bondin...High-entropy diborides(HEBs)have attracted extensive research due to their potential ultra-high hardness.In the present work,the effects of transition metals(TM)on lattice parameters,electron work function(EWF),bonding charge density,and hardness of HEBs are comprehensively investigated by the first-principles calculations,including(TiZrHfNbTa)B_(2),(TiZrHfNbMo)B_(2),(TiZrHfTaMo)B_(2),(TiZrNbTaMo)B_(2),and(TiHfNbTaMo)B_(2).It is revealed that the disordered TM atoms result in a severe local lattice distortion and the formation of weak spots.In view of bonding charge density,it is understood that the degree of electron contribution of TM atoms directly affects the bonding strength of the metallic layer,contributing to the optimized hardness of HEBs.Moreover,the proposed power-law-scaled relationship integrating the EWF and the grain size yields an excellent agreement between our predicted results and those reported experimental ones.It is found that the HEBs exhibit relatively high hardness which is higher than those of single transition metal diborides.In particular,the hardness of(TiZrNbTaMo)B_(2)and(TiHfNbTaMo)B_(2)can be as high as29.15 and 28.02 GPa,respectively.This work provides a rapid strategy to discover/design advanced HEBs efficiently,supported by the coupling hardening mechanisms of solid solution and grain refinement based on the atomic and electronic interactions.展开更多
Increasing attention has been focused on potassium ion batteries(KIBs) as promising energy-sto rage system(ESS) owing to the abundance and low-cost of potassium resources.Here,SnS2/SnO2 hete rostructures were successf...Increasing attention has been focused on potassium ion batteries(KIBs) as promising energy-sto rage system(ESS) owing to the abundance and low-cost of potassium resources.Here,SnS2/SnO2 hete rostructures were successfully fixed onto stainless steel mesh(SnS2/SnO2/SSM) through a facile two-step hydrothermal method and used as anodes for KIBs.Due to the advantages of SnS2/SnO2 heterostructures and good conductivity of SSM substrate,the SnS2/SnO2/SSM anodes display enhanced electrochemical performance.The SnS2/SnO2/SSM anodes deliver specific capacity of 394 mA h g^-1 at 50 mA g^-1 over 100 cycles,better than SnO2/SSM.Even at 500 mA g^-1 after 250 cycles,high capacity of 155 mA h g^-1 can still be obtained.展开更多
Fe-based powder with a composition of Fe_（42.87）Cr_（15.98）Mo_（16.33）C_（15.94）B_（8.88）（at.%）was used to fabricate coatings by high-velocity oxygen fuel spraying.The effects of the spraying parameters on the...Fe-based powder with a composition of Fe_（42.87）Cr_（15.98）Mo_（16.33）C_（15.94）B_（8.88）（at.%）was used to fabricate coatings by high-velocity oxygen fuel spraying.The effects of the spraying parameters on the microstructure and the wear properties of the Fe-based alloy coatings were systematically studied.The results showed that the obtained Fe-based coatings with a thickness of about 400μm consisted of a large-volume amorphous phase and some nanocrystals.With increasing the fuel and oxygen flow rates,the porosity of the obtained coatings decreased.The coating deposited under optimized parameters exhibited the lowest porosity of 2.8%.The excellent wear resistance of this coating was attributed to the properties of the amorphous matrix and the presence of nanocrystals homogeneously distributed within the matrix.The wear mechanism of the coatings was discussed on the basis of observations of the worn surfaces.展开更多
Benefiting from excellent mechanical properties and low density,cellular ceramic structures(CCSs)are competitive candidates as structural components.However,inherent brittleness from strong chemical bonds among atoms ...Benefiting from excellent mechanical properties and low density,cellular ceramic structures(CCSs)are competitive candidates as structural components.However,inherent brittleness from strong chemical bonds among atoms extremely impeded CCSs'application.Natural materials occupied outstanding strength and toughness simultaneously due to the dual-phase interpenetrated structure.Inspired by natural materials,it was proposed to fabricate coating covered and fulfilled polyurea/CCS interpenetrated composites(C/CCSs and B/CCSs)to circumvent the brittleness of 3D-printed Al_(2)O_(3)CCSs.It was demonstrated that polyurea coating had less effect on the compressive strength of C/CCSs but tremendously improved their energy-absorbing ability.The energy-absorbing ability of C/CCSs was improved from26.48-52.57 kJ·m^(-3)of CCSs to 1.04-1.89 MJ·m^(-3)because of the extended plateau stage.Furthermore,compressive strength and energy-absorbing ability of B/CCSs were strengthened to 1.33-1.36 and 2.84-4.61 times of C/CCSs,respectively.Besides,failure mode of C/CCSs changed from localized deformation to fracturing entirely with the increase in relative density of CCSs inside,which was the same as that of CCSs.However,with the help of polyurea coating,C/CCSs were still intact at strains up to60%,which would neve r fail catastrophically as CCSs at low strains.B/CCSs tended to fracture as a whole,which was not influenced by relative density of pristine CCSs.It was believed that this work provided a creative way to circumvent the brittleness of CCSs and improve their mechanical performances.展开更多
Auxetic metastructures have attracted tremendous attention because of their robust multifunctional properties and promising potential industrial applications.This paper studies the in-plane mechanical behaviors of a c...Auxetic metastructures have attracted tremendous attention because of their robust multifunctional properties and promising potential industrial applications.This paper studies the in-plane mechanical behaviors of a chiral S-shaped metastructure subjected to tensile loading in both X-direction and Y-direction and wave propagation properties using the finite element(FE)method.The relationships between structural parameters and elastic behaviors are also discussed.The results indicate that the orientation of chiral S-shaped metastructure under tensile loading in the X-direction exhibits higher auxeticity and stiffness.Then,the band structures and the edge modes of each band gap of the chiral S-shaped metastructure are explored,and the relations between band gap properties and structural parameters are also systematically analyzed.Moreover,we explore the wave mitigation of the chiral S-shaped metastructures by regulating the structural parameters.Finally,the transmission properties of the finite chiral S-shaped periodic metastructures are studied to confirm the results of band gap simulation.This study promotes the engineering application of vibration isolation of chiral structures based on the band gap theory.展开更多
In this paper,a liquid-solid origami composite design is proposed for the improvement of impact resistance.Employing this design strategy,Kresling origami composite structures with different fillings were designed and...In this paper,a liquid-solid origami composite design is proposed for the improvement of impact resistance.Employing this design strategy,Kresling origami composite structures with different fillings were designed and fabricated,namely air,water,and shear thickening fluid(STF).Quasi-static compression and drop-weight impact experiments were carried out to compare and reveal the static and dynamic mechanical behavior of these structures.The results from drop-weight impact experiments demonstrated that the solid-liquid Kresling origami composite structures exhibited superior yield strength and reduced peak force when compared to their empty counterparts.Notably,the Kresling origami structures filled with STF exhibited significantly heightened yield strength and reduced peak force.For example,at an impact velocity of 3 m/s,the yield strength of single-layer STF-filled Kresling origami structures increased by 772.7%and the peak force decreased by 68.6%.This liquid-solid origami composite design holds the potential to advance the application of origami structures in critical areas such as aerospace,intelligent protection and other important fields.The demonstrated improvements in impact resistance underscore the practical viability of this approach in enhancing structural performance for a range of applications.展开更多
Carbon Carbon(C/C)composites in thermal-protection system are exposed to severe thermochemical ablation and mechanical erosion,and their thermal-protection performance is of vital importance to the structural safety a...Carbon Carbon(C/C)composites in thermal-protection system are exposed to severe thermochemical ablation and mechanical erosion,and their thermal-protection performance is of vital importance to the structural safety and flight status of hypersonic vehicles.We numerically analyzes the mesoscopic ablation-erosion of C/C Composites with Inclined Fibers(CCIF).First,a thermochemical ablation model describing the reaction-diffusion coupled problem of C/C composites on mesoscale is employed to analyze ablative process,and the corresponding surface ablation morphology is obtained.Then,the ablation morphology of CCIF is taken as the geometrical model for mechanical erosion analysis,and their damage and failure behavior under high-speed airflow shear is analyzed by using progressive damage method.Moreover,the effects of fiber inclined angle and airflow direction on the mechanical erosion of CCIF are investigated,and the ablationerosion behavior is analyzed and discussed.The results show that the failure modes of mechanical erosion in inner and edge regions are obviously different,showing granular and block erosion phenomena respectively.The mechanical erosion of CCIF in the direction of reverse flow is easier than that in the direction of forward flow.These results can provide a theoretical basis for the design and optimization of thermal protection system materials.展开更多
Electrochemical metallurgy at low temperature(<473 K)shows promise for the extraction and refinement of metals and alloys in a green and sustainable manner.However,the kinetics of the electrodeposition process is g...Electrochemical metallurgy at low temperature(<473 K)shows promise for the extraction and refinement of metals and alloys in a green and sustainable manner.However,the kinetics of the electrodeposition process is generally slow at low temperature,resulting in large overpotential and low current efficiency.Thus,the application of external physical fields has emerged as an effective strategy for improving the mass and charge transfer processes during electrochemical reactions.This review highlights the challenges associated with low-temperature electrochemical processes and briefly discusses recent achievements in optimizing electrodeposition processes through the use of external physical fields.The regulating effects on the optimization of the electrodeposition process and the strategies for select-ing various external physical fields,including magnetic,supergravity,and ultrasonic fields are summarized from the perspectives of equipment and mechanisms.Finally,advanced methods for in-situ characterization of external physical field-assisted electrodeposition processes are reviewed to gain a deeper understanding of metallic electrodeposition.An in-depth exploration of the mechanism by which external physical fields affect the electrode process is essential for enhancing the efficiency of metal extraction at low temperatures.展开更多
Vat photopolymerization additive manufacturing produces lightweight load-bearing ceramic lattice structures that have flexibility,time-efficiency,and high precision,compared to conventional technology.However,understa...Vat photopolymerization additive manufacturing produces lightweight load-bearing ceramic lattice structures that have flexibility,time-efficiency,and high precision,compared to conventional technology.However,understanding the compression behavior and failure mechanism of such structures under loading remains a challenge.In this study,considering the correlation between the strut angle and bearing capacity,body-centered tetragonal(BCT)lattice structures with varying angles are designed based on a body-centered cubic(BCC)structure.BCT Al_(2)O_(3) ceramic lattice structures with varying angles are fabricated by vat photopolymerization.The mechanical properties,deformation process,and failure mechanism of the Al_(2)O_(3) ceramic lattice structures are characterized through a combination of ex-and in-situ X-ray computed tomography(X-CT)compression testing and analyzed using a finite element method(FEM)at macro-and micro-levels.The results demonstrate that as the angle increases,the stress concentration gradually expands from the node to the strut,resulting in an increased loadbearing capacity.Additionally,the failure mode of the Al_(2)O_(3) ceramic lattice structures is identified as diagonal slip shear failure.These findings provide a greater understanding of ceramic lattice structure failures and design optimization approaches.展开更多
The development of low-energy consumption and environmentally friendly electrodeposition of metal/alloy films or coatings is presently one of the primary topics for the research community.For this purpose,deep eutecti...The development of low-energy consumption and environmentally friendly electrodeposition of metal/alloy films or coatings is presently one of the primary topics for the research community.For this purpose,deep eutectic solvents(DESs)are valued as electrolytes for their advantages of low operating temperature and wide electrochemical windows.At present,there is large amount of literature on this emerging field,but there are no specialized reviews of these studies.Here,after a brief introduction of DESs’concept and history,we comprehensively reviewed the lastest progress on the metal/alloy electrodeposition in DESs.Additionally,we discussed the key influence factors of the electrodeposition process and analyzed the corresponding mechanisms.Based on these,we emphasized the importance of the establishment of predictive models for dealing with the challenges in large-scale applications.展开更多
基金supported by the National Science and Technology Major Project of China(No.2017-VI-0020-0093).
文摘The high-temperature interaction of nanostructured Lu_(2)Si_(2)O_(7) environmental barrier coatings(EBCs)with calcium-magnesium-aluminosilicate(CMAS)was investigated at 1400℃ for 1,10,25,and 50 h to evaluate the coating’s resistance to CMAS corrosion.The results indicate a phase transformation over time,transitioning from Ca_(2)Lu_(8)(SiO_(4))6O_(2) apatite and Lu_(2)Si_(2)O_(7) to solely Lu_(2)Si_(2)O_(7).The interaction of the Lu_(2)Si_(2)O_(7) coating with the CMAS melts was divided into three stages based on the corrosion reaction behavior.The delamination cracks were distributed throughout the interface between the Si bond layer and Lu_(2)Si_(2)O_(7) layer after corroded at 1400℃ for 50 h,signifying coating failure.In addition,the influence of monosilicates,disilicates,and corrosion duration on the recession layer thickness was analyzed by comparing previous reports on RE_(2)SiO_(5)/RE_(2)Si_(2)O_(7) coatings(RE=Gd,Yb,Lu,Er).Furthermore,the variation in the thermally grown oxide layer thickness in CMAS-corroded Lu_(2)Si_(2)O_(7) coatings was systematically investigated.
基金supported by the National Key Research and Development of China(No.2018YFA0702804).
文摘Over the past several decades,the integration of IONs into EP emerged as an effective method for enhancing its mechanical properties.Nevertheless,challenges remain,especially with u-IONs,where the interfacial strength with EP is suboptimal,resulting in aggregation within the EP matrix and a subsequent deterioration in the mechanical performance of u-ION/EP nanocomposites.In this comprehensive review,we explored advanced chemical modification techniques tailored for IONs incorporated into EP,providing a detailed examination of the mechanical characteristics of surface cm-ION/EP nanocomposites.This review investigates various chemical modification methods and their distinct impacts on the mechanical attributes of the resulting EP nanocomposites.Special emphasis is given to addressing the persistent challenges of inadequate interfacial strength and aggregation.Furthermore,this article examines prospective surface modification approaches for inorganic oxide nanoparticles,offering a visionary outlook on methods to improve the mechanical performance of EP in future.
基金supported by the National Natural Science Foundation of China (Grant No. 52275310)。
文摘The complex ceramic core used for hollow turbine blades requires a high porosity and a high fiexural strength. For a better balance between porosity and fiexural strength, ceramic materials with porous structures are preferred. In order to achieve the transition from disordered pore formation to ordered pore formation, Al_(2)O_(3) ceramic cores with triply periodic minimal surface(TPMS) micro lattice structures with different structural configurations(gyroid, diamond, and neovius) and different volume fractions of lattice structures(30, 40, and 50, vol.%) were designed and prepared by vat photopolymerization 3D printing. The effects of structural configuration and volume fraction of the lattice structure on the following structural shrinkage, microstructure, and flexural strength were investigated. The shrinkage relationship of the three lattice configurations is: neovius>diamond>gyroid. Besides, it is found that with an increase in the volume fraction of the 3D printed Al_(2)O_(3) ceramic micro lattice structures, their fiexural strength correspondingly increases ranging from 54.95 MPa to 139.1 MPa. The maximum average fiexural strength of the 3D printed Al_(2)O_(3) ceramic micro lattice structures is obtained when the structural configuration is diamond and with a volume fraction of 50vol.%, which is 139.1 MPa. Even when the volume fraction of the lattice structure is 30vol.%, that is to say the porosity is 70%, the fiexural strength is as high as 50-70 MPa, which can still be maintained at a high level. In addition, when the volume fraction of the lattice structure is a certain value, the sample with diamond configuration has a higher strength. The internal pore morphology, pore size, and porosity of the cores are precisely controlled, achieving both a high porosity and a high strength. Therefore, this study maintains high porosity and high strength simultaneously, providing a new lattice structure design idea for 3D printed ceramic cores.
基金supported by JCKY Project(Grant No.JCKY2023602B012).
文摘This study pioneers the integrated fabrication of magnesium corrugated-core sandwich structures using wire-arc directed energy deposition(WA-DED).Two sandwich structures—V-type and X-type—were designed with optimized deposition paths to achieve comparable grain morphology while enhancing strength.The compression properties and failure modes of the two corrugated-core sandwich structures were examined through quasi-static compression tests.Results showed that the V-type structure exhibited a higher specific compressive strength(93 MPa∙cm^(3)/g)than the X-type structure(72 MPa∙cm^(3)/g).Both finite element analysis and experimental compression tests indicated that failure occurred at the midsection of the corrugated core.This work offers valuable insights for the efficient fabrication of high-strength corrugated-core sandwich structures.
基金financially supported by the Key Research and Development Program of the Ministry of Science and Technology under No.2022YFB3806104.
文摘The development of machine learning has provided a new perspective for the design of electromagnetic metastructures,particularly in the rapid design of key performance metrics such as effective absorption bandwidth.Traditional methods,grounded in electromagnetic theory and empirical approaches,often lacked sufficient flexibility and adaptability.In this work,three types of machine learning models were developed to establish the relationship between effective absorption bandwidth and structural parameters.The results indicated that the random forest model achieved the most accurate and efficient design for this task.Then,the additive manufacturing optimal metastructure obtained using this approach outperformed existing designs in terms of both effective absorption bandwidth and reflectivity,while also exhibiting superior radar stealth performance and mechanical load-bearing capacity.Furthermore,through interpretable machine learning and data analysis,the intrinsic mechanisms underlying the relationship between effective absorption bandwidth and structural parameters were revealed.Overall,this work introduced a novel approach to metastructure design and enhanced the understanding of the relationship between structural parameters and electromagnetic properties,providing a key foundation for future design.
基金supported by the National Natural Science Foundation of China(Grant Nos.12172045,U2241240,and 12221002)the National Program on Key Basic Research Project,China(Grant No.2019-JCJQ-ZD-308-00).
文摘The curing behavior of composites significantly influences their performance,making it crucial to understand the curing process.This study experimentally measured specific heat capacity,thermal conductivity,glass transition temperature,coefficient of thermal expansion,and cure shrinkage of materials.A simulation model of its curing deformation was established and validated against strain data obtained from fiber Bragg grating experiments.The effects of thickness,heating rate,and cooling rate on the curing temperature field and residual stress field during the molding of thick-section composite plates were analyzed.
基金supports from Beijing Institute of Spacecraft System Engineering and the Young Elite Scientists Sponsorship Program by China Association for Science and Technology(Nos.2017QNRC001,2016QNRC001)
文摘Thermal controllers equipped with phase-change materials are widely used for maintaining the moderate temperatures of various electric devices used in spacecraft. Yet, the structures of amounts of thermal controllers add up to such a large value that restricts the employment of scientific devices due to the limit of rocket capacity. A lightweight structure of phase-change thermal controllers has been one of the main focuses of spacecraft design engineering. In this work, we design a lightweight phase-change thermal controller structure based on lattice cells. The structure is manufactured entirely with AlSi10 Mg by direct metal laser melting. The dimensions of the structure are 230 mm × 170 mm × 15 mm, and the mass is 190 g, which is 60% lighter than most traditional structures(500–600 g) with the same dimensions. The 3 D-printed structure can reduce the risk of leakage at soldering manufacture by a welding process. Whether the strength of the designed structure is sufficient is determined through mechanical analysis and experiments. Thermal test results show that the thermal capacity of the lattice-based thermal controller is increased by50% compared to that of traditional controllers with the same volume.
基金financial supports from the National Natural Science Foundation of China(Nos.51875041,51875042)。
文摘A graded structural material(GSM)with a material transition from TA15 to TC11 was fabricated by wire arc additive manufacturing(WAAM)method.The grain morphology,chemical composition,microstructure and mechanical properties of the as-deposited GSM were all characterized to investigate their variations along the deposition direction.The results indicate that from TA15 to TC11,the grain size decreases and a transition from columnar grains to equiaxed grains occurs.The content of alloy element alters greatly within a short distance,and the width of the mutation zone is 800μm.Both TA15 and TC11 regions exhibit basketweave microstructure withα-phase andβ-phase.However,during the transition from TA15 to TC11,theα-lath becomes fine,which leads to an increase in microhardness.The tensile test shows that the bonding strength at the interface is higher than the longitudinal strength of TA15,and the lateral elongation at the interface is higher than that of TA15 and TC11.
基金the support from the National Natural Science Foundation of China under Grant No. 11902031,No. 11802030 , No. 11802031Beijing Municipal Science and Technology Project Management Approach under No. Z181100004118002
文摘This paper presents a combination of experimental and numerical investigations on the dynamic response of scaling cabin structures under internal blast loading.The purpose of this study is to modify the similar relationship between the scaled-down model and the prototype of the cabin structures under internal blast loading.According to the Hopkinson’s scaling law,three sets of cabin structure models with different scaling factors combined with different explosive masses were designed for the experimental study.The dynamic deformation process of the models was recorded by a three-dimensional digital imaging correlation(DIC)method and a 3D scanning technology was used to reconstruct the deformation modes of the specimen.In addition,a finite element model was developed for the modification of the scaling law.The experimental results showed that the final deflection-to-thickness ratio was increased with the increase of the model size despite of the similar trend of their deformation processes.The reason for this inconsistency was discussed based on the traditional scaling law and a modified formula considering of the effects of size and strain-rate was provided.
基金the National Natural Science Foundation of China(Grant Nos.11972049 and 12002050)National Key Laboratory Foundation of Science and Technology on Materials under Shock and Im-pact(Grant No.6142902200401)Opening Fund of State Key Laboratory of Nonlinear Mechanics.
文摘Inspired by the gradient structure of the nature,two gradient lattice structures,i.e.,unidirectional gradient lattice(UGL)and bidirectional gradient lattice(BGL),are proposed based on the body-centered cubic(BCC)lattice to obtain specially designed mechanical behaviors,such as load-bearing and energy absorption capacities.First,a theoretical model is proposed to predict the initial stiffness of the gradient lattice structure under compressive loading,and validated against quasi-static compression tests and finite element models(FEMs).The deformation and failure mechanisms of the two structures are further studied based on experiments and simulations.The UGL structure exhibits a layer-by-layer failure mode,which avoids structure-wise shear failure in uniform structures.The BGL structure presents a symmetry deformation pattern,and the failure initiates at the weakest part.Finally,the energy absorption behaviors are also discussed.This study demonstrates the potential application of gradient lattice structures in load-transfer-path modification and energy absorption by topology design.
基金financially supported by the Science Challenge Project(No.TZ 2018002)。
文摘High-entropy diborides(HEBs)have attracted extensive research due to their potential ultra-high hardness.In the present work,the effects of transition metals(TM)on lattice parameters,electron work function(EWF),bonding charge density,and hardness of HEBs are comprehensively investigated by the first-principles calculations,including(TiZrHfNbTa)B_(2),(TiZrHfNbMo)B_(2),(TiZrHfTaMo)B_(2),(TiZrNbTaMo)B_(2),and(TiHfNbTaMo)B_(2).It is revealed that the disordered TM atoms result in a severe local lattice distortion and the formation of weak spots.In view of bonding charge density,it is understood that the degree of electron contribution of TM atoms directly affects the bonding strength of the metallic layer,contributing to the optimized hardness of HEBs.Moreover,the proposed power-law-scaled relationship integrating the EWF and the grain size yields an excellent agreement between our predicted results and those reported experimental ones.It is found that the HEBs exhibit relatively high hardness which is higher than those of single transition metal diborides.In particular,the hardness of(TiZrNbTaMo)B_(2)and(TiHfNbTaMo)B_(2)can be as high as29.15 and 28.02 GPa,respectively.This work provides a rapid strategy to discover/design advanced HEBs efficiently,supported by the coupling hardening mechanisms of solid solution and grain refinement based on the atomic and electronic interactions.
基金This work was financially supported by the National Natural Science Foundation of China(Nos.51704188,51464020,5170219961705125 and 51802181)the research starting foundation from Shaanxi University of Science and Technology(No.2018GBJ-04)。
文摘Increasing attention has been focused on potassium ion batteries(KIBs) as promising energy-sto rage system(ESS) owing to the abundance and low-cost of potassium resources.Here,SnS2/SnO2 hete rostructures were successfully fixed onto stainless steel mesh(SnS2/SnO2/SSM) through a facile two-step hydrothermal method and used as anodes for KIBs.Due to the advantages of SnS2/SnO2 heterostructures and good conductivity of SSM substrate,the SnS2/SnO2/SSM anodes display enhanced electrochemical performance.The SnS2/SnO2/SSM anodes deliver specific capacity of 394 mA h g^-1 at 50 mA g^-1 over 100 cycles,better than SnO2/SSM.Even at 500 mA g^-1 after 250 cycles,high capacity of 155 mA h g^-1 can still be obtained.
基金Item Sponsored by National Natural Science Foundation of China(51205001)Key Project of Natural Science of Education Department of Anhui Province of China(KJ2014A023)Scientific Research Starting Foundation of Anhui Polytechnic University of China(2012YQQ006)
文摘Fe-based powder with a composition of Fe_（42.87）Cr_（15.98）Mo_（16.33）C_（15.94）B_（8.88）（at.%）was used to fabricate coatings by high-velocity oxygen fuel spraying.The effects of the spraying parameters on the microstructure and the wear properties of the Fe-based alloy coatings were systematically studied.The results showed that the obtained Fe-based coatings with a thickness of about 400μm consisted of a large-volume amorphous phase and some nanocrystals.With increasing the fuel and oxygen flow rates,the porosity of the obtained coatings decreased.The coating deposited under optimized parameters exhibited the lowest porosity of 2.8%.The excellent wear resistance of this coating was attributed to the properties of the amorphous matrix and the presence of nanocrystals homogeneously distributed within the matrix.The wear mechanism of the coatings was discussed on the basis of observations of the worn surfaces.
基金financially supported by the National Natural Science Foundation of China(No.52275310)the Open Project of State Key Laboratory of Explosion Science and Technology(No.QNKT22-15)the BIT Research and Innovation Promoting Project(No.2022YCX020)。
文摘Benefiting from excellent mechanical properties and low density,cellular ceramic structures(CCSs)are competitive candidates as structural components.However,inherent brittleness from strong chemical bonds among atoms extremely impeded CCSs'application.Natural materials occupied outstanding strength and toughness simultaneously due to the dual-phase interpenetrated structure.Inspired by natural materials,it was proposed to fabricate coating covered and fulfilled polyurea/CCS interpenetrated composites(C/CCSs and B/CCSs)to circumvent the brittleness of 3D-printed Al_(2)O_(3)CCSs.It was demonstrated that polyurea coating had less effect on the compressive strength of C/CCSs but tremendously improved their energy-absorbing ability.The energy-absorbing ability of C/CCSs was improved from26.48-52.57 kJ·m^(-3)of CCSs to 1.04-1.89 MJ·m^(-3)because of the extended plateau stage.Furthermore,compressive strength and energy-absorbing ability of B/CCSs were strengthened to 1.33-1.36 and 2.84-4.61 times of C/CCSs,respectively.Besides,failure mode of C/CCSs changed from localized deformation to fracturing entirely with the increase in relative density of CCSs inside,which was the same as that of CCSs.However,with the help of polyurea coating,C/CCSs were still intact at strains up to60%,which would neve r fail catastrophically as CCSs at low strains.B/CCSs tended to fracture as a whole,which was not influenced by relative density of pristine CCSs.It was believed that this work provided a creative way to circumvent the brittleness of CCSs and improve their mechanical performances.
基金supported by the National Natural Science Foundation of China under the Grant Number of 12072241 and the Fundamental Research Funds for the Central Universities under the Grant Number of 2042022kf0009.
文摘Auxetic metastructures have attracted tremendous attention because of their robust multifunctional properties and promising potential industrial applications.This paper studies the in-plane mechanical behaviors of a chiral S-shaped metastructure subjected to tensile loading in both X-direction and Y-direction and wave propagation properties using the finite element(FE)method.The relationships between structural parameters and elastic behaviors are also discussed.The results indicate that the orientation of chiral S-shaped metastructure under tensile loading in the X-direction exhibits higher auxeticity and stiffness.Then,the band structures and the edge modes of each band gap of the chiral S-shaped metastructure are explored,and the relations between band gap properties and structural parameters are also systematically analyzed.Moreover,we explore the wave mitigation of the chiral S-shaped metastructures by regulating the structural parameters.Finally,the transmission properties of the finite chiral S-shaped periodic metastructures are studied to confirm the results of band gap simulation.This study promotes the engineering application of vibration isolation of chiral structures based on the band gap theory.
基金supported by the National Natural Science Foundation of China(Grant Nos.12302151 and 52105575)the BIT Research and Innovation Promoting Project(Grant No.2023YCXY049)+2 种基金the Fundamental Research Funds for the Central Universities(Grant No.QTZX23063)the Aeronautical Science Foundation of China(Grant No.2022Z073081001)the Open Research Funds of State Key Laboratory of Intelligent Manufacturing Equipment and Technology(Grant No.IMETKF2024008).
文摘In this paper,a liquid-solid origami composite design is proposed for the improvement of impact resistance.Employing this design strategy,Kresling origami composite structures with different fillings were designed and fabricated,namely air,water,and shear thickening fluid(STF).Quasi-static compression and drop-weight impact experiments were carried out to compare and reveal the static and dynamic mechanical behavior of these structures.The results from drop-weight impact experiments demonstrated that the solid-liquid Kresling origami composite structures exhibited superior yield strength and reduced peak force when compared to their empty counterparts.Notably,the Kresling origami structures filled with STF exhibited significantly heightened yield strength and reduced peak force.For example,at an impact velocity of 3 m/s,the yield strength of single-layer STF-filled Kresling origami structures increased by 772.7%and the peak force decreased by 68.6%.This liquid-solid origami composite design holds the potential to advance the application of origami structures in critical areas such as aerospace,intelligent protection and other important fields.The demonstrated improvements in impact resistance underscore the practical viability of this approach in enhancing structural performance for a range of applications.
基金supported by the National Natural Science Foundation of China(Nos.U2241240,12172045 and 12221002)the Opening Fund of State Key Laboratory of Explosion Science and Technology of Beijing Institute of Technology,China(No.ZDKT23-02)。
文摘Carbon Carbon(C/C)composites in thermal-protection system are exposed to severe thermochemical ablation and mechanical erosion,and their thermal-protection performance is of vital importance to the structural safety and flight status of hypersonic vehicles.We numerically analyzes the mesoscopic ablation-erosion of C/C Composites with Inclined Fibers(CCIF).First,a thermochemical ablation model describing the reaction-diffusion coupled problem of C/C composites on mesoscale is employed to analyze ablative process,and the corresponding surface ablation morphology is obtained.Then,the ablation morphology of CCIF is taken as the geometrical model for mechanical erosion analysis,and their damage and failure behavior under high-speed airflow shear is analyzed by using progressive damage method.Moreover,the effects of fiber inclined angle and airflow direction on the mechanical erosion of CCIF are investigated,and the ablationerosion behavior is analyzed and discussed.The results show that the failure modes of mechanical erosion in inner and edge regions are obviously different,showing granular and block erosion phenomena respectively.The mechanical erosion of CCIF in the direction of reverse flow is easier than that in the direction of forward flow.These results can provide a theoretical basis for the design and optimization of thermal protection system materials.
基金supported by Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai)(No.SML2023SP243)the National Key Research and Development Program of China(No.2022YFC2906100)the National Natural Science Foundation of China(No.92475202)are acknowledged.
文摘Electrochemical metallurgy at low temperature(<473 K)shows promise for the extraction and refinement of metals and alloys in a green and sustainable manner.However,the kinetics of the electrodeposition process is generally slow at low temperature,resulting in large overpotential and low current efficiency.Thus,the application of external physical fields has emerged as an effective strategy for improving the mass and charge transfer processes during electrochemical reactions.This review highlights the challenges associated with low-temperature electrochemical processes and briefly discusses recent achievements in optimizing electrodeposition processes through the use of external physical fields.The regulating effects on the optimization of the electrodeposition process and the strategies for select-ing various external physical fields,including magnetic,supergravity,and ultrasonic fields are summarized from the perspectives of equipment and mechanisms.Finally,advanced methods for in-situ characterization of external physical field-assisted electrodeposition processes are reviewed to gain a deeper understanding of metallic electrodeposition.An in-depth exploration of the mechanism by which external physical fields affect the electrode process is essential for enhancing the efficiency of metal extraction at low temperatures.
基金supported by National Natural Science Foundation of China(Grant Nos.52275310,52402084)the China Postdoctoral Science Foundation(Grant No.2024M751646).
文摘Vat photopolymerization additive manufacturing produces lightweight load-bearing ceramic lattice structures that have flexibility,time-efficiency,and high precision,compared to conventional technology.However,understanding the compression behavior and failure mechanism of such structures under loading remains a challenge.In this study,considering the correlation between the strut angle and bearing capacity,body-centered tetragonal(BCT)lattice structures with varying angles are designed based on a body-centered cubic(BCC)structure.BCT Al_(2)O_(3) ceramic lattice structures with varying angles are fabricated by vat photopolymerization.The mechanical properties,deformation process,and failure mechanism of the Al_(2)O_(3) ceramic lattice structures are characterized through a combination of ex-and in-situ X-ray computed tomography(X-CT)compression testing and analyzed using a finite element method(FEM)at macro-and micro-levels.The results demonstrate that as the angle increases,the stress concentration gradually expands from the node to the strut,resulting in an increased loadbearing capacity.Additionally,the failure mode of the Al_(2)O_(3) ceramic lattice structures is identified as diagonal slip shear failure.These findings provide a greater understanding of ceramic lattice structure failures and design optimization approaches.
基金financially supported from the National Natural Science Foundation of China(Nos.52274291,52204305)Beijing Institute of Technology Research Fund Program for Young Scholars,China(No.1740011182102).
文摘The development of low-energy consumption and environmentally friendly electrodeposition of metal/alloy films or coatings is presently one of the primary topics for the research community.For this purpose,deep eutectic solvents(DESs)are valued as electrolytes for their advantages of low operating temperature and wide electrochemical windows.At present,there is large amount of literature on this emerging field,but there are no specialized reviews of these studies.Here,after a brief introduction of DESs’concept and history,we comprehensively reviewed the lastest progress on the metal/alloy electrodeposition in DESs.Additionally,we discussed the key influence factors of the electrodeposition process and analyzed the corresponding mechanisms.Based on these,we emphasized the importance of the establishment of predictive models for dealing with the challenges in large-scale applications.
