High-temperature radiative cooling is essential for solar absorbers,as it mitigates efficiency degradation resulting from thermal accumulation.While porous structures have proven effective in enhancing absorber perfor...High-temperature radiative cooling is essential for solar absorbers,as it mitigates efficiency degradation resulting from thermal accumulation.While porous structures have proven effective in enhancing absorber performance,practical manufacturing processes and prolonged operational wear inevitably introduce surface roughness and structural deviations,which profoundly impact radiative properties.This study constructs a ZnS/Ag solar absorber model with surface roughness and employs the finite-difference time-domain method to investigate how characteristic length,surface roughness,porosity,pore shape factor,and taper influence its radiative properties in the 3μm-5μm band at 750 K.Results show optimal absorption at a 1μm characteristic length with a 36.72%improvement compared to the model with l=0.25μm,increased absorption with higher porosity with a 69.29%improvement at 0.6 compared to the non-porous structure,lower circularity with a 19.03%improvement for C=0.89 compared to C=1.00,while surface roughness with a 61.24%improvement at RMS=0.031 compared to RMS=0 and taper with a 38.29%improvement at β=20°compared to β=0°also exert significant effects.This work provides engineering design guidelines for high-efficiency,low-cost absorbers.展开更多
Ultrathin,lightweight,and flexible aligned single-walled carbon nanotube(SWCNT)films are fabricated by a facile,environmentally friendly,and scalable printing methodology.The aligned pattern and outstanding intrinsic ...Ultrathin,lightweight,and flexible aligned single-walled carbon nanotube(SWCNT)films are fabricated by a facile,environmentally friendly,and scalable printing methodology.The aligned pattern and outstanding intrinsic properties render“metal-like”thermal conductivity of the SWCNT films,as well as excellent mechanical strength,flexibility,and hydrophobicity.Further,the aligned cellular microstructure promotes the electromagnetic interference(EMI)shielding ability of the SWCNTs,leading to excellent shielding effectiveness(SE)of~39 to 90 dB despite a density of only~0.6 g cm^(−3) at thicknesses of merely 1.5-24μm,respectively.An ultrahigh thickness-specific SE of 25693 dB mm^(−1) and an unprecedented normalized specific SE of 428222 dB cm^(2)g^(−1) are accomplished by the freestanding SWCNT films,significantly surpassing previously reported shielding materials.In addition to an EMI SE greater than 54 dB in an ultra-broadband frequency range of around 400 GHz,the films demonstrate excellent EMI shielding stability and reliability when subjected to mechanical deformation,chemical(acid/alkali/organic solvent)corrosion,and high-/low-temperature environments.The novel printed SWCNT films offer significant potential for practical applications in the aerospace,defense,precision components,and smart wearable electronics industries.展开更多
Tumor cells show acidic conditions compared with normal cells,which further inspires scientist to build nanocarrier responsive to tumor microenvironment(TME)for enhancing tumor therapeutic efficacy.Here,we report a pH...Tumor cells show acidic conditions compared with normal cells,which further inspires scientist to build nanocarrier responsive to tumor microenvironment(TME)for enhancing tumor therapeutic efficacy.Here,we report a pH-sensitive and biocompatible polyprodrug based on dextran-doxorubicin(DOX)prodrug(DOXDT)for enhanced chemotherapy.Highdensity DOX component was covalently decorated on the nanocarrier and the drug molecules could be effectively released in the acidic tumor tissue/cells,improving chemotherapy efficacy.Specifically,a dextran-based copolymer was preliminarily prepared by one-step atom transfer radical polymerization(ATRP);then DOX was conjugated on the copolymer component via pH-responsive hydrazone bond.The structure of DOXDT can be well-controlled.The resulting DOXDT was able to further self-assemble into nanoscale micelles with a hydration diameter of about 32.4 nm,which presented excellent micellar stability.Compared to lipid-based drug delivery system,the DOXDT prodrug showed higher drug load capacity up to 23.6%.In addition,excellent stability and smaller size of the nanocarrier contributed to better tissue permeability and tumor suppressive effects in vivo.Hence,this amphipathic DOXDT prodrug is promising in the development of translational DOX formulations,which would be widely applied in cancer therapy.展开更多
Due to its high mobility and flexible deployment,unmanned aerial vehicle(UAV)is drawing unprecedented interest in both military and civil applications to enable agile and ubiquitous connectivity.Mainly operating in an...Due to its high mobility and flexible deployment,unmanned aerial vehicle(UAV)is drawing unprecedented interest in both military and civil applications to enable agile and ubiquitous connectivity.Mainly operating in an open environment,UAV communications benefit from dominant line-of-sight links;however,this on the other hand renders the communications more vulnerable to malicious attacks.Recently,physical layer security(PLS)has been introduced to UAV systems as an important complement to the conventional cryptography-based approaches.In this paper,a comprehensive survey on the current achievements of UAV-PLS is conducted.We first introduce the basic concepts including typical static/-mobile UAV deployment scenarios,the unique air-toground channel and aerial nodes distribution models,as well as various roles that a UAV may act when PLS is concerned.Then,we start by reviewing the secrecy performance analysis and enhancing techniques for statically deployed UAV systems,and extend the discussion to the more general scenario where the UAVs’mobility is further exploited.For both cases,respectively,we summarize the commonly adopted methodologies,then describe important works in the litera ture in detail.Finally,potential research directions and challenges are discussed to provide an outlook for future works in the area of UAV-PLS.展开更多
Fuel cells and electrolysis are promising candidates for future energy production from renewable energy sources. Usually, polymer electrolyte fuel cell systems run on hydrogen and air, while the most of electrolysis s...Fuel cells and electrolysis are promising candidates for future energy production from renewable energy sources. Usually, polymer electrolyte fuel cell systems run on hydrogen and air, while the most of electrolysis systems vent out oxygen as unused by-product. Replacing air with pure oxygen, fuel cell electrochemical performance, durability and system efficiency can be significantly increased with a further overall system simplification and increased reliability. This work, which represents the initial step for pure H;/O;polymer electrolyte fuel cell operation in closed-loop systems, focuses on performance validation of a single cell operating with pure H;/O;under different relative humidity（RH） levels, reactants stoichiometry conditions and temperature. As a result of this study, the most convenient and appropriate operative conditions for a polymer electrolyte fuel cell stack integrated in a closed loop system were selected.展开更多
Intelligent reflecting surface(IRS)is a newly emerged and promising paradigm to substantially improve the performance of wireless communications by constructing favorable communication channels via properly tuning mas...Intelligent reflecting surface(IRS)is a newly emerged and promising paradigm to substantially improve the performance of wireless communications by constructing favorable communication channels via properly tuning massive reflecting elements.This paper considers a distributed IRS aided decode-and-forward(DF)relaying system over Nakagami-m fading channels.Based on a tight approximation for the distribution of the received signalto-noise ratio(SNR),we first derive exact closed-form expressions of the outage probability,ergodic capacity,and energy efficiency for the considered system.Moreover,we propose the optimal IRS configuration considering the energy efficiency and pilot overhead.Finally,we compare the performance between the distributed IRS-aided DF relaying and multi-IRS-only systems,and verify the analytical results by using monte carlo simulations.展开更多
The membrane-electrodes assembly(MEA) is the core of the Polymer Electrolyte Fuel Cell(PEFC). It consists of a membrane, catalytic(CL) and gas diffusion layers(GDL). In order to manufacture MEAs with suitable performa...The membrane-electrodes assembly(MEA) is the core of the Polymer Electrolyte Fuel Cell(PEFC). It consists of a membrane, catalytic(CL) and gas diffusion layers(GDL). In order to manufacture MEAs with suitable performance, a hot-pressing procedure is generally used. The relevant parameters are the temperature, pressure and time of hot-pressing. Such variables need to be adjusted as a function of the type of ionomer used in the catalytic layer and membrane. In this study, an evaluation of the temperature of hot-pressing was carried out and its influence on MEA electrochemical performance was assessed. In particular, preparation trials of MEAs were carried out with reinforced experimental membranes based on Aquivion^■ short-side-chain PFSA(by Solvay Specialty Polymers). The membranes were coupled to gas diffusion electrodes, and MEAs were manufactured using different temperatures for the hot-pressing procedure in order to evaluate their influence on the electrochemical performance of PEFCs, in the temperature range of 80–95 °C, with low relative humidity of the reactant gases. The electrochemical performance of the prepared MEAs was tested in a H2/Air 25 cm^2 single cell in terms of polarization curves and accelerated stress test(AST).展开更多
In this paper, a low-profile wideband dielectric resonator antenna(DRA) with a very compact planar size is investigated. The antenna consists of a high permittivity dielectric sheet on the top, a low permittivity subs...In this paper, a low-profile wideband dielectric resonator antenna(DRA) with a very compact planar size is investigated. The antenna consists of a high permittivity dielectric sheet on the top, a low permittivity substrate in the middle, and a probe feeding structure at the bottom. By digging an annular slot in the designated area of the square dielectric sheet, the resonant frequency of fundamental TE111 mode can be effectively increased to be close to the high-order TE131 mode. The two modes can be finally merged together, yielding a wide impedance bandwidth of16.6%. Most importantly, the combination of the two modes is done on the premise of a fixed antenna planar size, which can be very compact and suitable for beam-scanning applications. A probe feeding structure is used to excite the DRA, making the antenna simple and practical to be integrated with other RF circuits. For verification, antenna prototypes with singlefeed linear polarization and differential-feed dual polarization were fabricated and measured. Reasonable agreement between the measured and simulated results is observed.展开更多
This paper investigates an unmanned aerial vehicle(UAV)-enabled maritime secure communication network,where the UAV aims to provide the communication service to a legitimate mobile vessel in the presence of multiple e...This paper investigates an unmanned aerial vehicle(UAV)-enabled maritime secure communication network,where the UAV aims to provide the communication service to a legitimate mobile vessel in the presence of multiple eavesdroppers.In this maritime communication networks(MCNs),it is challenging for the UAV to determine its trajectory on the ocean,since it cannot land or replenish energy on the sea surface,the trajectory should be pre-designed before the UAV takes off.Furthermore,the take-off location of the UAV and the sea lane of the vessel may be random,which leads to a highly dynamic environment.To address these issues,we propose two reinforcement learning schemes,Q-learning and deep deterministic policy gradient(DDPG)algorithms,to solve the discrete and continuous UAV trajectory design problem,respectively.Simulation results are provided to validate the effectiveness and superior performance of the proposed reinforcement learning schemes versus the existing schemes in the literature.Additionally,the proposed DDPG algorithm converges faster and achieves higher utilities for the UAV,compared to the Q-learning algorithm.展开更多
In this paper, comprehensive methods to apply several formulations of nonlinear estimators to integrated navigation problems are considered and developed. The problem of linear and nonlinear filters such as Kalman Fil...In this paper, comprehensive methods to apply several formulations of nonlinear estimators to integrated navigation problems are considered and developed. The problem of linear and nonlinear filters such as Kalman Filter (KF) and Extended Kalman Filter (EKF) is stated. Analog solution which is based on fisher information matrix propagation for linear and nonlinear filtering is also developed. Additionally, the idea of iterations is included through the update step both for Kalman filters and Information filters in order to improve accuracy. Through this development, two new formulations of High order Kalman filters and High order Information filters are presented. Finally, in order to compare these different nonlinear filters, special applications are analyzed by using the proposed techniques to estimate two well-known mathematical state space models, which are based on nonlinear time series used to apply these estimation algorithms. A criterion used for comparison is the root mean square error RMSE and several simulations under specific conditions are illustrated.展开更多
Microbial fuel cell(MFC) is an advanced bioelectrochemical technique that can utilize biomass materials in the process of simultaneously generating electricity and biodegrading or bio transforming toxic pollutants fro...Microbial fuel cell(MFC) is an advanced bioelectrochemical technique that can utilize biomass materials in the process of simultaneously generating electricity and biodegrading or bio transforming toxic pollutants from wastewater. The overall performance of the system is largely dependent on the efficiency of the anode electrode to enhance electron transportation. Furthermore, the anode electrode has a significant impact on the overall cost of MFC setup. Hence, the need to explore research focused towards developing cost-effective material as anode in MFC. This material must also have favourable properties for electron transportation. Graphene oxide(GO) derivatives and its modification with nanomaterials have been identified as a viable anode material. Herein, we discussed an economically effective strategy for the synthesis of graphene derivatives from waste biomass materials and its subsequent fabrication into anode electrode for MFC applications. This review article offers a promising approach towards replacing commercial graphene materials with biomass-derived graphene derivatives in a view to achieve a sustainable and commercialized MFC.展开更多
Radio Frequency(RF) fingerprinting is one physical-layer authentication method for wireless communication, which uses the unique hardware characteristic of the transmitter to identify its true identity.To improve the ...Radio Frequency(RF) fingerprinting is one physical-layer authentication method for wireless communication, which uses the unique hardware characteristic of the transmitter to identify its true identity.To improve the performance of RF Fingerprint(RFF)based on preamble with fixed duration, a nonlinear RF fingerprinting method based on payload symbols is proposed for the wireless OFDM communication with the bit mapping scheme of QPSK. The wireless communication system is modeled as a Hammerstein system containing the nonlinear transmitter and multipath fading channel. A parameter separation technique based on orthogonal polynomial is presented for the estimation of the parameters of the Hammerstein system. The Hammerstein system parameter separation technique is firstly used to estimate the linear parameter with the training signal, which is used to compensate the adverse effect of the linear channel for the demodulation of the successive payload symbols. The demodulated payload symbols are further used to estimate the nonlinear coefficients of the transmitter with the Hammerstein system parameter separation technique again, which is used as the novel RFF for the authentication of the QPSK-OFDM device. Numerical simulations have verified the proposed method, which can also be extended to the OFDM signals with other bit mapping schemes.展开更多
In this paper, we investigate a joint beamforming and time switching(TS) design for an energy-constrained cognitive two-way relay(TWR) network. In the network, the energy-constrained secondary user(SU) relay employs T...In this paper, we investigate a joint beamforming and time switching(TS) design for an energy-constrained cognitive two-way relay(TWR) network. In the network, the energy-constrained secondary user(SU) relay employs TS protocol to harvest energy from the signals sent by the circuit-powered primary user(PU) transmitter, and then exploits the harvested energy to perform information forwarding. Our aim is to maximize the sum rate of SUs under the constraints of the data rate of PU, the energy harvesting and the transmit power of the SU relay. To determine the beamforming matrix and TS ratio, we decouple the original non-convex problem into two subproblems which can be solved by semidefinite relaxation and successive convex optimization methods. Furthermore, we derive closed form expressions of the optimal solutions for each subproblem, which facilitates the design of a suboptimal iterative algorithm to handle the original sum rate maximization problem. Simulation results are presented to illustrate the effectiveness and superior performance of the proposed joint design against other conventional schemes in the literature.展开更多
The maritime communication network(MCN)plays an important role in the 6th generation(6G)system development.In MCNs,packet transport over long-distance lossy links will be ubiquitous.Transmission control protocol(TCP),...The maritime communication network(MCN)plays an important role in the 6th generation(6G)system development.In MCNs,packet transport over long-distance lossy links will be ubiquitous.Transmission control protocol(TCP),the dominant transport protocol in the past decades,have had performance issues in such links.In this paper,we propose a novel transport approach which uses user datagram protocol(UDP)along with a simple yet effective bandwidth estimator for congestion control,and with a proactive packet-level forward erasure correction(FEC)code called streaming code to provide low-delay loss recovery without data retransmissions at all.We show that the approach can effectively address two issues of the state-of-the-art TCP variants in the long-distance lossy links,namely 1)the low bandwidth utilization caused by the slow increase of the congestion window(CWND)due to long roundtrip time(RTT)and the frequent CWND drop due to random and congestion losses,and 2)the high endto-end in-order delivery delay when re-transmissions are incurred to recover lost packets.In addition,we show that the scheme’s goodput has good smoothness and short-term intra-protocol fairness properties,which are beneficial for multimedia streaming and interactive applications that are prominent parts of today’s wireless traffic.展开更多
This paper investigates interfacial heat transfer characteristics in amulti-layer structure under ultra-high heat flux conditions,focusing on thermal contact resistance(TCR)between adjacent layers.Athree-layer computa...This paper investigates interfacial heat transfer characteristics in amulti-layer structure under ultra-high heat flux conditions,focusing on thermal contact resistance(TCR)between adjacent layers.Athree-layer computational model with dual rough interfaces was developed to systematically analyze the synergistic effects of interfacial pressure,surface emissivity,and thermal interface materials(TIMs).Surface reconstruction using experimental measurement data generated two representative roughness models to quantify the impact of surface roughness on heat dissipation.Numerical simulations demonstrate that the absence of TIMs leads to insufficient thermal dissipation capacity under ultra-high heat flux conditions.Compared to TIMapplication,merely increasing the convective heat transfer coefficient shows limited effectiveness in enhancing heat dissipation efficiency.展开更多
In exploring hypersonic propulsion,precooler combined engines require the development of lightweight,efficient,and compact heat exchangers(HX).As additive manufacturing technology continues to progress,triply periodic...In exploring hypersonic propulsion,precooler combined engines require the development of lightweight,efficient,and compact heat exchangers(HX).As additive manufacturing technology continues to progress,triply periodic minimal surface(TPMS)structures,characterized by exceptionally high surface area to volume ratios and intricate geometric structures,have demonstrated superior heat transfer performance.This research examines the thermal-hydraulic(TH)behavior of FKS and Diamond as heat transfer structures under different Reynolds numbers through numerical simulations.The Nusselt number for FKS is 13.2%–17.6%higher than Diamond,while the friction factor for FKS is approximately 18.8%–29.3%higher.A detailed analysis of the internal flow mechanisms reveals that the flow pattern within TPMS can be summarized as cyclic convergence-separation-convergence.The fluid experiences constant disturbances from the structure in all spatial directions,generating strong turbulent mixing and large wall shear stresses,which significantly enhance heat transfer performance.展开更多
With extensive attention being paid to the potential environmental hazards of discarded face masks,catalytic pyrolysis technologies have been proposed to realize the valorization of wastes.However,recent catalyst sele...With extensive attention being paid to the potential environmental hazards of discarded face masks,catalytic pyrolysis technologies have been proposed to realize the valorization of wastes.However,recent catalyst selection and system design have focused solely on conversion efficiency,ignoring economic cost and potential life-cycle environmental damage.Here,we propose an economic-environmental hybrid pre-assessment method to help identify catalysts and reactors with less environmental impact and high economic returns among various routes to convert discarded face masks into carbon nanotubes(CNTs)and hydrogen.In catalyst selection,it was found that a widely known Fe-Ni catalyst exhibits higher catalytic activity than a cheaper Fe catalyst,potentially increasing the economic viability of the catalytic pyrolysis system by 38%-55%.The use of this catalyst also results in a carbon reduction of 4.12-10.20kilogram CO_(2) equivalent for 1 kilogram of discarded face masks,compared with the cheaper Fe catalyst.When the price of CNTs exceeds 1.49×10^(4) USD·t^(-1),microwave-assisted pyrolysis is the optimal choice due to its superior environmental performance(in terms of its life-cycle greenhouse gas reduction potential,eutrophication potential,and human toxicity)and economic benefits.In contrast,conventional heating pyrolysis may be a more economical option due to its good stability over 43 reaction regeneration cycles,as compared with a microwave-assisted pyrolysis catalyst with a higher conversion efficiency.This study connects foundational science with ecological economics to guide emerging technologies in their research stage toward technical efficiency,economic benefits,and environmental sustainability.展开更多
In recent years,explosion shock wave has been considered as a signature injury of the current military conflicts.Although strong shock wave is lethal to the human body,weak shock wave can cause many more lasting conse...In recent years,explosion shock wave has been considered as a signature injury of the current military conflicts.Although strong shock wave is lethal to the human body,weak shock wave can cause many more lasting consequences.To investigate the protection ability and characteristics of flexible materials and structures under weak shock wave loading,the blast wave produced by TNT explosive is loaded on the polyurethane foam with the density of 200.0 kg/m3(F-200)and 400.0 kg/m3(F-400),polyurea with the density of 1100.0 kg/m^(3)(P-1100)and structures composed of the two materials,which are intended for individual protection.Experimental results indicate that the shock wave is attenuated to weak pressure disturbance after interacting with the flexible materials which are not damaged.The shock wave protective capability of single-layer materials is dependent on their thickness,density and microscopic characteristics.The overpressure,maximum pressure rise rate and impulse of transmitted wave decrease exponentially with increase in sample thickness.For the same thickness,F-400 provides better protective capability than F-200 while P-1100 shows the best protective capability among the three materials.In this study,as the materials are not destroyed,F-200 with a thickness more than10.0 mm,F-400 with a thickness more than 4.0 mm,and P-1100 with a thickness more than 1.0 mm can attenuate the overpressure amplitude more than 90.0%.Further,multi-layer flexible composites are designed.Different layer layouts of designed structures and layer thickness of the single-layer materials can affect the protective performance.Within the research range,the structure in which polyurea is placed on the impact side shows the optimal shock wave protective performance,and the thicknesses of polyurea and polyurethane foam are 1.0 mm and 4.0 mm respectively.The overpressure attenuation rate reached maximum value of 93.3%and impulse attenuation capacity of this structure are better than those of single-layer polyurea and polyurethane foam with higher areal density.展开更多
As an important part of future 5G wireless networks,a vehicular network demands safety,reliability and connectivity.In this context,networking survivability is usually considered an important metric to evaluate networ...As an important part of future 5G wireless networks,a vehicular network demands safety,reliability and connectivity.In this context,networking survivability is usually considered an important metric to evaluate network performance.In this paper,we propose a survivability model for vehicle communication networking based on dual cluster heads,wherein a backup cluster head(CH)will be activated if the primary CH fails,thereby effectively enhancing the network lifetime.Additionally,we introduce a software rejuvenation strategy for the prime CH to further improve the survivability of the entire network.Using the Probabilistic Symbolic Model Checker(PRISM),we verify and discuss the proposed survivability model via numerical simulations.The results show that network survivability can be effectively improved by introducing an additional CH and further enhanced by adopting the software rejuvenation technique.展开更多
In the post-Moore era, as the energy consumption of micro-nano electronic devices rapidly increases, near-field radiative heat transfer(NFRHT) with super-Planckian phenomena has gradually shown great potential for app...In the post-Moore era, as the energy consumption of micro-nano electronic devices rapidly increases, near-field radiative heat transfer(NFRHT) with super-Planckian phenomena has gradually shown great potential for applications in efficient and ultrafast thermal modulation and energy conversion. Recently, hyperbolic materials, an important class of anisotropic materials with hyperbolic isofrequency contours, have been intensively investigated. As an exotic optical platform, hyperbolic materials bring tremendous new opportunities for NFRHT from theoretical advances to experimental designs. To date, there have been considerable achievements in NFRHT for hyperbolic materials, which range from the establishment of different unprecedented heat transport phenomena to various potential applications. This review concisely introduces the basic physics of NFRHT for hyperbolic materials, lays out the theoretical methods to address NFRHT for hyperbolic materials, and highlights unique behaviors as realized in different hyperbolic materials and the resulting applications. Finally, key challenges and opportunities of the NFRHT for hyperbolic materials in terms of fundamental physics, experimental validations, and potential applications are outlined and discussed.展开更多
基金funded by the National Natural Science Foundation of China,grant number 52406102,received by Haiyan YuShandong Provincial Natural Science Foundation,grant number ZR2023QE258,received by Haiyan Yu.
文摘High-temperature radiative cooling is essential for solar absorbers,as it mitigates efficiency degradation resulting from thermal accumulation.While porous structures have proven effective in enhancing absorber performance,practical manufacturing processes and prolonged operational wear inevitably introduce surface roughness and structural deviations,which profoundly impact radiative properties.This study constructs a ZnS/Ag solar absorber model with surface roughness and employs the finite-difference time-domain method to investigate how characteristic length,surface roughness,porosity,pore shape factor,and taper influence its radiative properties in the 3μm-5μm band at 750 K.Results show optimal absorption at a 1μm characteristic length with a 36.72%improvement compared to the model with l=0.25μm,increased absorption with higher porosity with a 69.29%improvement at 0.6 compared to the non-porous structure,lower circularity with a 19.03%improvement for C=0.89 compared to C=1.00,while surface roughness with a 61.24%improvement at RMS=0.031 compared to RMS=0 and taper with a 38.29%improvement at β=20°compared to β=0°also exert significant effects.This work provides engineering design guidelines for high-efficiency,low-cost absorbers.
基金support of National Key R&D Program of China (2021YFB3502500)Provincial Key Research and Development Program of Shandong (2019JZZY010312, 2021ZLGX01)+4 种基金Natural Science Foundation of Shandong Province (2022HYYQ-014)New 20 Funded Programs for Universities of Jinan (2021GXRC036)Qilu Young Scholar Program of Shandong University (31370082163127)the assistance of Shandong University Testing and Manufacturing Center for Advanced Materialssupport from the National Science Foundation Engineering Research Center for Power Optimization of Electro Thermal Systems (POETS) under Grant No. EEC 1449548.
文摘Ultrathin,lightweight,and flexible aligned single-walled carbon nanotube(SWCNT)films are fabricated by a facile,environmentally friendly,and scalable printing methodology.The aligned pattern and outstanding intrinsic properties render“metal-like”thermal conductivity of the SWCNT films,as well as excellent mechanical strength,flexibility,and hydrophobicity.Further,the aligned cellular microstructure promotes the electromagnetic interference(EMI)shielding ability of the SWCNTs,leading to excellent shielding effectiveness(SE)of~39 to 90 dB despite a density of only~0.6 g cm^(−3) at thicknesses of merely 1.5-24μm,respectively.An ultrahigh thickness-specific SE of 25693 dB mm^(−1) and an unprecedented normalized specific SE of 428222 dB cm^(2)g^(−1) are accomplished by the freestanding SWCNT films,significantly surpassing previously reported shielding materials.In addition to an EMI SE greater than 54 dB in an ultra-broadband frequency range of around 400 GHz,the films demonstrate excellent EMI shielding stability and reliability when subjected to mechanical deformation,chemical(acid/alkali/organic solvent)corrosion,and high-/low-temperature environments.The novel printed SWCNT films offer significant potential for practical applications in the aerospace,defense,precision components,and smart wearable electronics industries.
基金supported by Science and Technology Project from the Science Technology and Innovation Committee of Shenzhen Municipality(JCYJ20170817170110940 and JCJY20170307163529489)the Sichuan Science and Technology Program(2018JY0392 and 2018GZYZF0008)+1 种基金Sanming Project of Medicine in Shenzhen(SZSM201512033)Shenzhen Public Service Platform of Molecular Medicine in Pediatric Hematology and Oncology。
文摘Tumor cells show acidic conditions compared with normal cells,which further inspires scientist to build nanocarrier responsive to tumor microenvironment(TME)for enhancing tumor therapeutic efficacy.Here,we report a pH-sensitive and biocompatible polyprodrug based on dextran-doxorubicin(DOX)prodrug(DOXDT)for enhanced chemotherapy.Highdensity DOX component was covalently decorated on the nanocarrier and the drug molecules could be effectively released in the acidic tumor tissue/cells,improving chemotherapy efficacy.Specifically,a dextran-based copolymer was preliminarily prepared by one-step atom transfer radical polymerization(ATRP);then DOX was conjugated on the copolymer component via pH-responsive hydrazone bond.The structure of DOXDT can be well-controlled.The resulting DOXDT was able to further self-assemble into nanoscale micelles with a hydration diameter of about 32.4 nm,which presented excellent micellar stability.Compared to lipid-based drug delivery system,the DOXDT prodrug showed higher drug load capacity up to 23.6%.In addition,excellent stability and smaller size of the nanocarrier contributed to better tissue permeability and tumor suppressive effects in vivo.Hence,this amphipathic DOXDT prodrug is promising in the development of translational DOX formulations,which would be widely applied in cancer therapy.
基金supported in part by the National Key Research and Development Program of China under Grant 2020YFA0711301in part by the National Natural Science Foundation of China under Grant 61922049,61941104,61921004,62171240,61771264,62001254,61801248,61971467+2 种基金the Key Research and Development Program of Shandong Province under Grant 2020CXGC010108the Key Research and Development Program of Jiangsu Province of China under Grant BE2021013-1the Science and Technology Program of Nantong under Grants JC2021121,JC2021017。
文摘Due to its high mobility and flexible deployment,unmanned aerial vehicle(UAV)is drawing unprecedented interest in both military and civil applications to enable agile and ubiquitous connectivity.Mainly operating in an open environment,UAV communications benefit from dominant line-of-sight links;however,this on the other hand renders the communications more vulnerable to malicious attacks.Recently,physical layer security(PLS)has been introduced to UAV systems as an important complement to the conventional cryptography-based approaches.In this paper,a comprehensive survey on the current achievements of UAV-PLS is conducted.We first introduce the basic concepts including typical static/-mobile UAV deployment scenarios,the unique air-toground channel and aerial nodes distribution models,as well as various roles that a UAV may act when PLS is concerned.Then,we start by reviewing the secrecy performance analysis and enhancing techniques for statically deployed UAV systems,and extend the discussion to the more general scenario where the UAVs’mobility is further exploited.For both cases,respectively,we summarize the commonly adopted methodologies,then describe important works in the litera ture in detail.Finally,potential research directions and challenges are discussed to provide an outlook for future works in the area of UAV-PLS.
文摘Fuel cells and electrolysis are promising candidates for future energy production from renewable energy sources. Usually, polymer electrolyte fuel cell systems run on hydrogen and air, while the most of electrolysis systems vent out oxygen as unused by-product. Replacing air with pure oxygen, fuel cell electrochemical performance, durability and system efficiency can be significantly increased with a further overall system simplification and increased reliability. This work, which represents the initial step for pure H;/O;polymer electrolyte fuel cell operation in closed-loop systems, focuses on performance validation of a single cell operating with pure H;/O;under different relative humidity（RH） levels, reactants stoichiometry conditions and temperature. As a result of this study, the most convenient and appropriate operative conditions for a polymer electrolyte fuel cell stack integrated in a closed loop system were selected.
基金supported in part by National Natural Science Foundation of China under Grant 62371262 and 61971467in part by the Key Research and Development Program of Jiangsu Province of China under Grant BE2021013-1+1 种基金in part by the Qinlan Project of Jiangsu Provincein part by the Scientific Research Program of Nantong under Grant JC22022026
文摘Intelligent reflecting surface(IRS)is a newly emerged and promising paradigm to substantially improve the performance of wireless communications by constructing favorable communication channels via properly tuning massive reflecting elements.This paper considers a distributed IRS aided decode-and-forward(DF)relaying system over Nakagami-m fading channels.Based on a tight approximation for the distribution of the received signalto-noise ratio(SNR),we first derive exact closed-form expressions of the outage probability,ergodic capacity,and energy efficiency for the considered system.Moreover,we propose the optimal IRS configuration considering the energy efficiency and pilot overhead.Finally,we compare the performance between the distributed IRS-aided DF relaying and multi-IRS-only systems,and verify the analytical results by using monte carlo simulations.
基金funding from the European Union’s Seventh Framework Programme(FP7/2007-2013)
文摘The membrane-electrodes assembly(MEA) is the core of the Polymer Electrolyte Fuel Cell(PEFC). It consists of a membrane, catalytic(CL) and gas diffusion layers(GDL). In order to manufacture MEAs with suitable performance, a hot-pressing procedure is generally used. The relevant parameters are the temperature, pressure and time of hot-pressing. Such variables need to be adjusted as a function of the type of ionomer used in the catalytic layer and membrane. In this study, an evaluation of the temperature of hot-pressing was carried out and its influence on MEA electrochemical performance was assessed. In particular, preparation trials of MEAs were carried out with reinforced experimental membranes based on Aquivion^■ short-side-chain PFSA(by Solvay Specialty Polymers). The membranes were coupled to gas diffusion electrodes, and MEAs were manufactured using different temperatures for the hot-pressing procedure in order to evaluate their influence on the electrochemical performance of PEFCs, in the temperature range of 80–95 °C, with low relative humidity of the reactant gases. The electrochemical performance of the prepared MEAs was tested in a H2/Air 25 cm^2 single cell in terms of polarization curves and accelerated stress test(AST).
基金supported by the National Natural Science Foundation of China under Grant 62071256National Natural Science Foundation of Jiangsu under Grant BK20201438+1 种基金supported by State Key Laboratory of Millimeter Waves (Nanjing) and Nantong Research Institute for Advanced Communication Technologies (Nantong)sponsored by Qing Lan Project of Jiangsu Province。
文摘In this paper, a low-profile wideband dielectric resonator antenna(DRA) with a very compact planar size is investigated. The antenna consists of a high permittivity dielectric sheet on the top, a low permittivity substrate in the middle, and a probe feeding structure at the bottom. By digging an annular slot in the designated area of the square dielectric sheet, the resonant frequency of fundamental TE111 mode can be effectively increased to be close to the high-order TE131 mode. The two modes can be finally merged together, yielding a wide impedance bandwidth of16.6%. Most importantly, the combination of the two modes is done on the premise of a fixed antenna planar size, which can be very compact and suitable for beam-scanning applications. A probe feeding structure is used to excite the DRA, making the antenna simple and practical to be integrated with other RF circuits. For verification, antenna prototypes with singlefeed linear polarization and differential-feed dual polarization were fabricated and measured. Reasonable agreement between the measured and simulated results is observed.
基金supported by the Six Categories Talent Peak of Jiangsu Province(No.KTHY-039)the Future Network Scientific Research Fund Project(No.FNSRFP-2021-YB-42)+1 种基金the Science and Technology Program of Nantong(No.JC2021016)the Key Research and Development Program of Jiangsu Province of China(No.BE2021013-1)。
文摘This paper investigates an unmanned aerial vehicle(UAV)-enabled maritime secure communication network,where the UAV aims to provide the communication service to a legitimate mobile vessel in the presence of multiple eavesdroppers.In this maritime communication networks(MCNs),it is challenging for the UAV to determine its trajectory on the ocean,since it cannot land or replenish energy on the sea surface,the trajectory should be pre-designed before the UAV takes off.Furthermore,the take-off location of the UAV and the sea lane of the vessel may be random,which leads to a highly dynamic environment.To address these issues,we propose two reinforcement learning schemes,Q-learning and deep deterministic policy gradient(DDPG)algorithms,to solve the discrete and continuous UAV trajectory design problem,respectively.Simulation results are provided to validate the effectiveness and superior performance of the proposed reinforcement learning schemes versus the existing schemes in the literature.Additionally,the proposed DDPG algorithm converges faster and achieves higher utilities for the UAV,compared to the Q-learning algorithm.
文摘In this paper, comprehensive methods to apply several formulations of nonlinear estimators to integrated navigation problems are considered and developed. The problem of linear and nonlinear filters such as Kalman Filter (KF) and Extended Kalman Filter (EKF) is stated. Analog solution which is based on fisher information matrix propagation for linear and nonlinear filtering is also developed. Additionally, the idea of iterations is included through the update step both for Kalman filters and Information filters in order to improve accuracy. Through this development, two new formulations of High order Kalman filters and High order Information filters are presented. Finally, in order to compare these different nonlinear filters, special applications are analyzed by using the proposed techniques to estimate two well-known mathematical state space models, which are based on nonlinear time series used to apply these estimation algorithms. A criterion used for comparison is the root mean square error RMSE and several simulations under specific conditions are illustrated.
基金supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (2021R1A2B5B01002656)。
文摘Microbial fuel cell(MFC) is an advanced bioelectrochemical technique that can utilize biomass materials in the process of simultaneously generating electricity and biodegrading or bio transforming toxic pollutants from wastewater. The overall performance of the system is largely dependent on the efficiency of the anode electrode to enhance electron transportation. Furthermore, the anode electrode has a significant impact on the overall cost of MFC setup. Hence, the need to explore research focused towards developing cost-effective material as anode in MFC. This material must also have favourable properties for electron transportation. Graphene oxide(GO) derivatives and its modification with nanomaterials have been identified as a viable anode material. Herein, we discussed an economically effective strategy for the synthesis of graphene derivatives from waste biomass materials and its subsequent fabrication into anode electrode for MFC applications. This review article offers a promising approach towards replacing commercial graphene materials with biomass-derived graphene derivatives in a view to achieve a sustainable and commercialized MFC.
文摘Radio Frequency(RF) fingerprinting is one physical-layer authentication method for wireless communication, which uses the unique hardware characteristic of the transmitter to identify its true identity.To improve the performance of RF Fingerprint(RFF)based on preamble with fixed duration, a nonlinear RF fingerprinting method based on payload symbols is proposed for the wireless OFDM communication with the bit mapping scheme of QPSK. The wireless communication system is modeled as a Hammerstein system containing the nonlinear transmitter and multipath fading channel. A parameter separation technique based on orthogonal polynomial is presented for the estimation of the parameters of the Hammerstein system. The Hammerstein system parameter separation technique is firstly used to estimate the linear parameter with the training signal, which is used to compensate the adverse effect of the linear channel for the demodulation of the successive payload symbols. The demodulated payload symbols are further used to estimate the nonlinear coefficients of the transmitter with the Hammerstein system parameter separation technique again, which is used as the novel RFF for the authentication of the QPSK-OFDM device. Numerical simulations have verified the proposed method, which can also be extended to the OFDM signals with other bit mapping schemes.
基金National Natural Science Foundation of China (61871241, 61771263)Postgraduate Research and Practice Innovation Program of Jiangsu Province (KYCX18-2422)+3 种基金Six Categories Talent Peak of Jiangsu Province (KTHY-039)Science and Technology Program of Nantong (JC2018127, JC2018129, GY22017013)Stereoscopic Coverage Communication Network Verification Platform for China Sea (PCL2018KP002)Open Research Fund of Nantong University-Nantong Joint Research Center for Intelligent Information Technology (KFKT2017A05, KFKT2017B02)
文摘In this paper, we investigate a joint beamforming and time switching(TS) design for an energy-constrained cognitive two-way relay(TWR) network. In the network, the energy-constrained secondary user(SU) relay employs TS protocol to harvest energy from the signals sent by the circuit-powered primary user(PU) transmitter, and then exploits the harvested energy to perform information forwarding. Our aim is to maximize the sum rate of SUs under the constraints of the data rate of PU, the energy harvesting and the transmit power of the SU relay. To determine the beamforming matrix and TS ratio, we decouple the original non-convex problem into two subproblems which can be solved by semidefinite relaxation and successive convex optimization methods. Furthermore, we derive closed form expressions of the optimal solutions for each subproblem, which facilitates the design of a suboptimal iterative algorithm to handle the original sum rate maximization problem. Simulation results are presented to illustrate the effectiveness and superior performance of the proposed joint design against other conventional schemes in the literature.
基金supported by Natural Science Foundation of China(NSFC)under Grant no.61801248,62171240by the Key Research and Development Program of Jiangsu Province of China under Grant BE2021013-1+2 种基金by Science and Technology Program of Nantong under JC2021121by State Key Laboratory of Advanced Optical Communication Systems and Networks under Grant 2021GZKF006by the Postgraduate Research&Practice Innovation Program of Jiangsu Province KYCX223346。
文摘The maritime communication network(MCN)plays an important role in the 6th generation(6G)system development.In MCNs,packet transport over long-distance lossy links will be ubiquitous.Transmission control protocol(TCP),the dominant transport protocol in the past decades,have had performance issues in such links.In this paper,we propose a novel transport approach which uses user datagram protocol(UDP)along with a simple yet effective bandwidth estimator for congestion control,and with a proactive packet-level forward erasure correction(FEC)code called streaming code to provide low-delay loss recovery without data retransmissions at all.We show that the approach can effectively address two issues of the state-of-the-art TCP variants in the long-distance lossy links,namely 1)the low bandwidth utilization caused by the slow increase of the congestion window(CWND)due to long roundtrip time(RTT)and the frequent CWND drop due to random and congestion losses,and 2)the high endto-end in-order delivery delay when re-transmissions are incurred to recover lost packets.In addition,we show that the scheme’s goodput has good smoothness and short-term intra-protocol fairness properties,which are beneficial for multimedia streaming and interactive applications that are prominent parts of today’s wireless traffic.
基金by the Natural Science Foundation of Shandong Province,China(No.ZR2023QE159).
文摘This paper investigates interfacial heat transfer characteristics in amulti-layer structure under ultra-high heat flux conditions,focusing on thermal contact resistance(TCR)between adjacent layers.Athree-layer computational model with dual rough interfaces was developed to systematically analyze the synergistic effects of interfacial pressure,surface emissivity,and thermal interface materials(TIMs).Surface reconstruction using experimental measurement data generated two representative roughness models to quantify the impact of surface roughness on heat dissipation.Numerical simulations demonstrate that the absence of TIMs leads to insufficient thermal dissipation capacity under ultra-high heat flux conditions.Compared to TIMapplication,merely increasing the convective heat transfer coefficient shows limited effectiveness in enhancing heat dissipation efficiency.
基金supported by the Natural Science Basic Research Program of Shaanxi(Program No.2024JC-YBMS-449)Project ZR2022QE233 supported by Shandong Provincial Natural Science Foundation.
文摘In exploring hypersonic propulsion,precooler combined engines require the development of lightweight,efficient,and compact heat exchangers(HX).As additive manufacturing technology continues to progress,triply periodic minimal surface(TPMS)structures,characterized by exceptionally high surface area to volume ratios and intricate geometric structures,have demonstrated superior heat transfer performance.This research examines the thermal-hydraulic(TH)behavior of FKS and Diamond as heat transfer structures under different Reynolds numbers through numerical simulations.The Nusselt number for FKS is 13.2%–17.6%higher than Diamond,while the friction factor for FKS is approximately 18.8%–29.3%higher.A detailed analysis of the internal flow mechanisms reveals that the flow pattern within TPMS can be summarized as cyclic convergence-separation-convergence.The fluid experiences constant disturbances from the structure in all spatial directions,generating strong turbulent mixing and large wall shear stresses,which significantly enhance heat transfer performance.
基金supported by the National Natural Science Foundation of China(52076099,52306257,and 72293601)。
文摘With extensive attention being paid to the potential environmental hazards of discarded face masks,catalytic pyrolysis technologies have been proposed to realize the valorization of wastes.However,recent catalyst selection and system design have focused solely on conversion efficiency,ignoring economic cost and potential life-cycle environmental damage.Here,we propose an economic-environmental hybrid pre-assessment method to help identify catalysts and reactors with less environmental impact and high economic returns among various routes to convert discarded face masks into carbon nanotubes(CNTs)and hydrogen.In catalyst selection,it was found that a widely known Fe-Ni catalyst exhibits higher catalytic activity than a cheaper Fe catalyst,potentially increasing the economic viability of the catalytic pyrolysis system by 38%-55%.The use of this catalyst also results in a carbon reduction of 4.12-10.20kilogram CO_(2) equivalent for 1 kilogram of discarded face masks,compared with the cheaper Fe catalyst.When the price of CNTs exceeds 1.49×10^(4) USD·t^(-1),microwave-assisted pyrolysis is the optimal choice due to its superior environmental performance(in terms of its life-cycle greenhouse gas reduction potential,eutrophication potential,and human toxicity)and economic benefits.In contrast,conventional heating pyrolysis may be a more economical option due to its good stability over 43 reaction regeneration cycles,as compared with a microwave-assisted pyrolysis catalyst with a higher conversion efficiency.This study connects foundational science with ecological economics to guide emerging technologies in their research stage toward technical efficiency,economic benefits,and environmental sustainability.
基金supported by the National Natural Science Foundation of China(Grant Nos.12221002,12102233)。
文摘In recent years,explosion shock wave has been considered as a signature injury of the current military conflicts.Although strong shock wave is lethal to the human body,weak shock wave can cause many more lasting consequences.To investigate the protection ability and characteristics of flexible materials and structures under weak shock wave loading,the blast wave produced by TNT explosive is loaded on the polyurethane foam with the density of 200.0 kg/m3(F-200)and 400.0 kg/m3(F-400),polyurea with the density of 1100.0 kg/m^(3)(P-1100)and structures composed of the two materials,which are intended for individual protection.Experimental results indicate that the shock wave is attenuated to weak pressure disturbance after interacting with the flexible materials which are not damaged.The shock wave protective capability of single-layer materials is dependent on their thickness,density and microscopic characteristics.The overpressure,maximum pressure rise rate and impulse of transmitted wave decrease exponentially with increase in sample thickness.For the same thickness,F-400 provides better protective capability than F-200 while P-1100 shows the best protective capability among the three materials.In this study,as the materials are not destroyed,F-200 with a thickness more than10.0 mm,F-400 with a thickness more than 4.0 mm,and P-1100 with a thickness more than 1.0 mm can attenuate the overpressure amplitude more than 90.0%.Further,multi-layer flexible composites are designed.Different layer layouts of designed structures and layer thickness of the single-layer materials can affect the protective performance.Within the research range,the structure in which polyurea is placed on the impact side shows the optimal shock wave protective performance,and the thicknesses of polyurea and polyurethane foam are 1.0 mm and 4.0 mm respectively.The overpressure attenuation rate reached maximum value of 93.3%and impulse attenuation capacity of this structure are better than those of single-layer polyurea and polyurethane foam with higher areal density.
基金supported by the National Natural Science Foundation of China (No. 61971245 and 61801249 )Nantong University-Nantong Joint Research Center for Intelligent Information Technology (No. KFKT2016A01)
文摘As an important part of future 5G wireless networks,a vehicular network demands safety,reliability and connectivity.In this context,networking survivability is usually considered an important metric to evaluate network performance.In this paper,we propose a survivability model for vehicle communication networking based on dual cluster heads,wherein a backup cluster head(CH)will be activated if the primary CH fails,thereby effectively enhancing the network lifetime.Additionally,we introduce a software rejuvenation strategy for the prime CH to further improve the survivability of the entire network.Using the Probabilistic Symbolic Model Checker(PRISM),we verify and discuss the proposed survivability model via numerical simulations.The results show that network survivability can be effectively improved by introducing an additional CH and further enhanced by adopting the software rejuvenation technique.
基金supported by the Natural Science Foundation of Shandong Province (ZR2020LLZ004)the National Natural Science Foundation of China (Grant No.52106099),the National Natural Science Foundation of China (Grant No.52076056)the Fundamental Research Funds for the Central Universities (Grant No.AUGA5710094020)。
文摘In the post-Moore era, as the energy consumption of micro-nano electronic devices rapidly increases, near-field radiative heat transfer(NFRHT) with super-Planckian phenomena has gradually shown great potential for applications in efficient and ultrafast thermal modulation and energy conversion. Recently, hyperbolic materials, an important class of anisotropic materials with hyperbolic isofrequency contours, have been intensively investigated. As an exotic optical platform, hyperbolic materials bring tremendous new opportunities for NFRHT from theoretical advances to experimental designs. To date, there have been considerable achievements in NFRHT for hyperbolic materials, which range from the establishment of different unprecedented heat transport phenomena to various potential applications. This review concisely introduces the basic physics of NFRHT for hyperbolic materials, lays out the theoretical methods to address NFRHT for hyperbolic materials, and highlights unique behaviors as realized in different hyperbolic materials and the resulting applications. Finally, key challenges and opportunities of the NFRHT for hyperbolic materials in terms of fundamental physics, experimental validations, and potential applications are outlined and discussed.
