厌氧消化1号模型(Anaerobic Digestion Model No.1,ADM1)量化表达了厌氧发酵过程中各类物质的转化过程,在研究和咨询领域获得了广泛的发展和应用,但ADM1并没有过多考虑物理化学过程,这些物化过程虽然并不直接经由微生物发生,但它们却可...厌氧消化1号模型(Anaerobic Digestion Model No.1,ADM1)量化表达了厌氧发酵过程中各类物质的转化过程,在研究和咨询领域获得了广泛的发展和应用,但ADM1并没有过多考虑物理化学过程,这些物化过程虽然并不直接经由微生物发生,但它们却可以影响生化过程。通过建立ADM1气液转换模型,并基于生物甲烷潜力(BMP)测试建立液相气体浓度变化映射函数,将多元隐性模型转化为k_(L)a的显性模型,基于对k_(L)a参数的实时测算,对序批式投料的CSTR反应器搅拌装置设置变频激励机制,提高气液转换效率,促进沼气的快速逸出。经撬装CSTR中试设备连续实验测试,该智能控制模型相比传统运行方式容积产气率提升15.5%,对提升规模化沼气工程的生产效率具有显著的指导和应用价值。基于边云协同的智能控制为规模化生物燃气项目的智慧管控提供了全新的技术范式。展开更多
Emissions of exhaust gases and particulate matter from a dual fuel marine engine using methanol as fuel with marine gasoil as pilot fuel have been examined for a ferry during operation.The emission factor for nitrogen...Emissions of exhaust gases and particulate matter from a dual fuel marine engine using methanol as fuel with marine gasoil as pilot fuel have been examined for a ferry during operation.The emission factor for nitrogen oxides is lower than what is typically found for marine gasoil but does not reach the tier III limit.The emissions of particulate matter are significantly lower than for fuel oils and similar to what is found for LNG engines.The main part of the particles can be found in the ultrafine range with the peak being at around 18 nm.About 93%of the particles are evaporated and absorbed when using a thermodenuder,and thus a large majority of the particles are volatile.Methanol is a potential future marine fuel that will reduce emissions of air pollutants and can be made as a biofuel to meet emission targets for greenhouse gases.展开更多
The fuel sulfur content in marine fuels has been regulated in Sulfur Emission Control Areas(SECAs) since January 2015. However, other fuel characteristics are also believed to have an impact on particle emissions, par...The fuel sulfur content in marine fuels has been regulated in Sulfur Emission Control Areas(SECAs) since January 2015. However, other fuel characteristics are also believed to have an impact on particle emissions, particularly on the number of particles emitted. This study investigates the impact of the content of aromatics in fuel. To achieve fuel blends with concentrations of aromatics similar to those found in marine fuel oils, i.e. 20%–30% by volume(%vol.), normal diesel oil(4%–5% vol. aromatics) is doped with a mixture of aromatics. Emission measurements are conducted in test-bed engine facilities and particle emissions over a wide size range are analyzed. Results show a decreased number of particles emitted(or not change) with an increase in the aromatic concentration in fuel. This is because there is a reduction in the cetane number of the fuel with an increased aromatic content, which effects the combustion process and results in decreased particle formation. However, when ignition improver is used to increase the cetane number, particle emissions remain at a lower level than for normal diesel oil; thereby emphasizing the presence of other factors in the formation of particles.展开更多
Total nitrous oxide(N_2O) emissions from a conventional active sludge process were calculated using a mathematical emission model and dissolved N_2O in the water phase by a N_2O water sensor. Calculated emissions show...Total nitrous oxide(N_2O) emissions from a conventional active sludge process were calculated using a mathematical emission model and dissolved N_2O in the water phase by a N_2O water sensor. Calculated emissions showed good agreement with measured emissions based on concentrations and air?ow in the off-gas ventilation system from the covered process. Various tests for a wide range of potentially affecting parameters indicated robust and reliable emission estimations by the model. Thus, common uncertainties in input data would still provide good emission estimations. Measurements of dissolved N_2O required low maintenance and N_2O emission monitoring based on such measurements might therefore be considered as a signi?cant practical improvement. This would be advantageous especially in non-enclosed wastewater treatment plants(WWTPs) otherwise requiring complex off-gas measurements. As the sensor is connected directly to the WWTPs monitoring and control system, emissions calculations could be incorporated.展开更多
The lifecycle greenhouse gas(GHG)emissions(Well-to-Wake)from maritime transport must be reduced by at least 50%in absolute values by 2050 to contribute to the ambitions of the Paris Agreement(2015).A transition from c...The lifecycle greenhouse gas(GHG)emissions(Well-to-Wake)from maritime transport must be reduced by at least 50%in absolute values by 2050 to contribute to the ambitions of the Paris Agreement(2015).A transition from conventional fuels to alternative fuels with zero or lower GHG emissions is viewed as the most promising avenue to reach the GHG reductions.Whereas GHG and toxic pollutants emitted from the use of fossil fuels(heavy fuel oil(HFO)and marine gas/diesel oil(MGO/MDO))are generally well understood,the emissions associated with the new fuel options are only now being measured and communicated.This review provides an outlook on fuels that could help shipping respond to the decarbonization effort including Liquefied Petroleum Gas(LPG),Liquefied Natural Gas(LNG),methanol,ammonia,and hydrogen.A quantification of the pollutants associated from the use of these fuels is provided and challenges and barriers to their uptake are discussed.展开更多
Forest plays a vital role in the global biogeochemical cycles through a high rate of carbon sequestration and harboring biodiversity.However,local species diversity is declining while also becoming increasingly homoge...Forest plays a vital role in the global biogeochemical cycles through a high rate of carbon sequestration and harboring biodiversity.However,local species diversity is declining while also becoming increasingly homogenized across communities.Although eff ects of local biotic processes(e.g.,speciesα-diversity and stand structural heterogeneity)and environmental factors on aboveground biomass(AGB)have been widely tested,there is a huge knowledge gap for the eff ect of regional biotic processes(i.e.,taxonomic and functionalβ-diversity)in forests.Here,we hypothesized that regional and local environmental factors along with biotic processes jointly regulate AGB through species shifts in tropical forests.Using piecewise structural equation modeling(pSEM),we linked climatic water availability,soil fertility,stand structural heterogeneity(either tree DBH inequality,height inequality,or stand density),speciesα-diversity,taxonomic or functionalβ-diversity(and its two components;β-turnover andβ-richness),and AGB across 189 inventory plots in tropical forests of Sri Lanka.Soil fertility and climatic water availability shaped local and regional biotic processes.Stand structural heterogeneity promoted speciesα-diversity but declinedβ-diversity(but increasedβ-taxonomic turnover).Speciesα-diversity and stand structural heterogeneity promoted AGB whereas taxonomic and functionalβ-diversity declined(butβ-taxonomic turnover increased)AGB.The relationships of AGB with speciesα-diversity andβ-diversity varied from signifi cant to nonsignifi cant positive depending on the specifi c combinations of stand structural heterogeneity metrics used.This study shows that local biotic processes could increase AGB due to the local and regional niche complementarity eff ect whereas the regional biotic processes could restrict AGB due to the regional selection or functional redundancy eff ect under favorable environmental conditions.We argue that biotic homogenization,as well as drought conditions,may have strong divergent impacts on forest functions and that the impacts of tree diversity loss may greatly reduce carbon sequestration.展开更多
The paper provides an investigation and understanding of the significance of various wastewater flows on microplastics retainment and emission to the environment. WWTPs and sewer overflows as an important pathway of m...The paper provides an investigation and understanding of the significance of various wastewater flows on microplastics retainment and emission to the environment. WWTPs and sewer overflows as an important pathway of microplastics to the environment are assessed by considering the removal of microplastics in WWTPs with different treatment processes and several sewer overflow types and their contribution to microplastic loads to recipients. On the example of the Baltic Sea basin, presented results indicate a considerable discharge of microplastic from WWTPs despite the relatively good overall removal efficiency. Results show that the discharge of microplastics from sewer overflows can be in the same magnitude as from treated wastewater although the total flow is much lower than that of treated wastewater. Sewer overflow events frequently occur and are expected to increase due to climate change and urbanization, unless infrastructure is adapted. At the same time, sewer overflows are often neglected in conventional wastewater handling.展开更多
Investigation of amino acids in hydrothermal systems is of prime importance for the understanding of geochemistry and microbiology of hydrothermal vents and plumes, for carbon and metals global cycles, for metabolism ...Investigation of amino acids in hydrothermal systems is of prime importance for the understanding of geochemistry and microbiology of hydrothermal vents and plumes, for carbon and metals global cycles, for metabolism of some hydrothermal microorganisms and for the origin of life issue. Extensive theoretical and experimental work on amino acids behaviour in hydrothermal fluids has been done, conversely only few data exist on natural samples. Because each hydrothermal vent is unique, the more data we collect the better we will be able to address each of these questions. Usually amino acids in hydrothermal fluids have been measured by HPLC-FLD. The chromatographic separation was at least 26 min and up to 135 min and the required derivatization step may be time consuming, may use harmful chemicals and may be source of contamination. Alternatively, we describe here a method combining quickness (4.5 min), high resolution (10,000), very low LOD (sub-ppb) and without derivatization. Characterisation and separation of 10 relevant proteinogenic underivatized amino acids was achieved by ion-pairing reversed-phase Ultra-high Performance Liquid Chromatography-Electrospray Ionisation-Quadrupole Time of Flight-Mass Spectrometry (UPLC-ESI-QTOF-MS). Excellent linearity in the response was obtained for all amino acids with correlation coefficients > 0.9921. This method was successfully applied to natural hydrothermal fluid samples from ultramafic-hosted vents of the Mid-Atlantic Ridge region. Results are consistent with the only 2 other studies published on ultramafic-hosted vents and complete the few available data.展开更多
Correction to:J.For.Res.https://doi.org/10.1007/s11676-022-01560-8 During production process,the below mentioned errors appeared in the original article and inadvertently published with error.
This paper presents an assessment of air quality of the Kathmandu valley, capital city of Nepal. This is the largest urbanized area in the country of about 300 km2. In the last two decades an intensive development of ...This paper presents an assessment of air quality of the Kathmandu valley, capital city of Nepal. This is the largest urbanized area in the country of about 300 km2. In the last two decades an intensive development of demographic, traffic and industry growth in the region was observed which was reflected on the air quality degradation. In order to evaluate the urban air quality in Kathmandu, a field monitoring network for particle deposition, nitrogen dioxide （NO2） and sulphur dioxide （SO2） by passive sampling with high space resolution was implemented in co-operation with IVL-Sweden. The net work composed of 60 monitoring sites distributed in a grid of 1 × 1 km2 covering all over the main city and some rural valley. Monitoring were carried out for two seasons, rainy and dry as two campaign monitoring. The diffusive samplers were prepared and analyzed in IVL, Sweden. Good agreements in particle deposition between the two campaigns were observed. The particle deposition to the surrogate surface varied between 3 and 608 μg@cm2·monthl for the monitoring periods. The NOz concentrations on the other hand were quite similar in the two campaigns, and the SO2 concentrations were much lower in the first campaign compared to the second. The ranges of NO2 and SO2 concentrations were found to be from 5.6 to 52.6 μg/m3 and 0.6 to 23.4 μg·m-3 respectively. Arc Info/Arc map GIS 9.2 software was used for production of maps of spatial distribution of all the three parameters in the valley. Seasonal variation and traffic influence were also studied. Local meteorological effects in the distribution of pollutants were clearly observed and the NO2 concentrations were strictly related with traffic intensity.展开更多
文摘厌氧消化1号模型(Anaerobic Digestion Model No.1,ADM1)量化表达了厌氧发酵过程中各类物质的转化过程,在研究和咨询领域获得了广泛的发展和应用,但ADM1并没有过多考虑物理化学过程,这些物化过程虽然并不直接经由微生物发生,但它们却可以影响生化过程。通过建立ADM1气液转换模型,并基于生物甲烷潜力(BMP)测试建立液相气体浓度变化映射函数,将多元隐性模型转化为k_(L)a的显性模型,基于对k_(L)a参数的实时测算,对序批式投料的CSTR反应器搅拌装置设置变频激励机制,提高气液转换效率,促进沼气的快速逸出。经撬装CSTR中试设备连续实验测试,该智能控制模型相比传统运行方式容积产气率提升15.5%,对提升规模化沼气工程的生产效率具有显著的指导和应用价值。基于边云协同的智能控制为规模化生物燃气项目的智慧管控提供了全新的技术范式。
文摘Emissions of exhaust gases and particulate matter from a dual fuel marine engine using methanol as fuel with marine gasoil as pilot fuel have been examined for a ferry during operation.The emission factor for nitrogen oxides is lower than what is typically found for marine gasoil but does not reach the tier III limit.The emissions of particulate matter are significantly lower than for fuel oils and similar to what is found for LNG engines.The main part of the particles can be found in the ultrafine range with the peak being at around 18 nm.About 93%of the particles are evaporated and absorbed when using a thermodenuder,and thus a large majority of the particles are volatile.Methanol is a potential future marine fuel that will reduce emissions of air pollutants and can be made as a biofuel to meet emission targets for greenhouse gases.
基金Angpanneföreningen’s Foundation for Research and Development(11-164)the Foundation for Swedish Environmental Research Institute(SIVL)Swedish Maritime Organization and Lighthouse for their financial support
文摘The fuel sulfur content in marine fuels has been regulated in Sulfur Emission Control Areas(SECAs) since January 2015. However, other fuel characteristics are also believed to have an impact on particle emissions, particularly on the number of particles emitted. This study investigates the impact of the content of aromatics in fuel. To achieve fuel blends with concentrations of aromatics similar to those found in marine fuel oils, i.e. 20%–30% by volume(%vol.), normal diesel oil(4%–5% vol. aromatics) is doped with a mixture of aromatics. Emission measurements are conducted in test-bed engine facilities and particle emissions over a wide size range are analyzed. Results show a decreased number of particles emitted(or not change) with an increase in the aromatic concentration in fuel. This is because there is a reduction in the cetane number of the fuel with an increased aromatic content, which effects the combustion process and results in decreased particle formation. However, when ignition improver is used to increase the cetane number, particle emissions remain at a lower level than for normal diesel oil; thereby emphasizing the presence of other factors in the formation of particles.
文摘Total nitrous oxide(N_2O) emissions from a conventional active sludge process were calculated using a mathematical emission model and dissolved N_2O in the water phase by a N_2O water sensor. Calculated emissions showed good agreement with measured emissions based on concentrations and air?ow in the off-gas ventilation system from the covered process. Various tests for a wide range of potentially affecting parameters indicated robust and reliable emission estimations by the model. Thus, common uncertainties in input data would still provide good emission estimations. Measurements of dissolved N_2O required low maintenance and N_2O emission monitoring based on such measurements might therefore be considered as a signi?cant practical improvement. This would be advantageous especially in non-enclosed wastewater treatment plants(WWTPs) otherwise requiring complex off-gas measurements. As the sensor is connected directly to the WWTPs monitoring and control system, emissions calculations could be incorporated.
文摘The lifecycle greenhouse gas(GHG)emissions(Well-to-Wake)from maritime transport must be reduced by at least 50%in absolute values by 2050 to contribute to the ambitions of the Paris Agreement(2015).A transition from conventional fuels to alternative fuels with zero or lower GHG emissions is viewed as the most promising avenue to reach the GHG reductions.Whereas GHG and toxic pollutants emitted from the use of fossil fuels(heavy fuel oil(HFO)and marine gas/diesel oil(MGO/MDO))are generally well understood,the emissions associated with the new fuel options are only now being measured and communicated.This review provides an outlook on fuels that could help shipping respond to the decarbonization effort including Liquefied Petroleum Gas(LPG),Liquefied Natural Gas(LNG),methanol,ammonia,and hydrogen.A quantification of the pollutants associated from the use of these fuels is provided and challenges and barriers to their uptake are discussed.
基金funded by the Swedish Energy Agency(Project No 35586-1)for supporting the fieldworkSpecial Project(No.521100221033)of Hebei University for the interpretation of results
文摘Forest plays a vital role in the global biogeochemical cycles through a high rate of carbon sequestration and harboring biodiversity.However,local species diversity is declining while also becoming increasingly homogenized across communities.Although eff ects of local biotic processes(e.g.,speciesα-diversity and stand structural heterogeneity)and environmental factors on aboveground biomass(AGB)have been widely tested,there is a huge knowledge gap for the eff ect of regional biotic processes(i.e.,taxonomic and functionalβ-diversity)in forests.Here,we hypothesized that regional and local environmental factors along with biotic processes jointly regulate AGB through species shifts in tropical forests.Using piecewise structural equation modeling(pSEM),we linked climatic water availability,soil fertility,stand structural heterogeneity(either tree DBH inequality,height inequality,or stand density),speciesα-diversity,taxonomic or functionalβ-diversity(and its two components;β-turnover andβ-richness),and AGB across 189 inventory plots in tropical forests of Sri Lanka.Soil fertility and climatic water availability shaped local and regional biotic processes.Stand structural heterogeneity promoted speciesα-diversity but declinedβ-diversity(but increasedβ-taxonomic turnover).Speciesα-diversity and stand structural heterogeneity promoted AGB whereas taxonomic and functionalβ-diversity declined(butβ-taxonomic turnover increased)AGB.The relationships of AGB with speciesα-diversity andβ-diversity varied from signifi cant to nonsignifi cant positive depending on the specifi c combinations of stand structural heterogeneity metrics used.This study shows that local biotic processes could increase AGB due to the local and regional niche complementarity eff ect whereas the regional biotic processes could restrict AGB due to the regional selection or functional redundancy eff ect under favorable environmental conditions.We argue that biotic homogenization,as well as drought conditions,may have strong divergent impacts on forest functions and that the impacts of tree diversity loss may greatly reduce carbon sequestration.
文摘The paper provides an investigation and understanding of the significance of various wastewater flows on microplastics retainment and emission to the environment. WWTPs and sewer overflows as an important pathway of microplastics to the environment are assessed by considering the removal of microplastics in WWTPs with different treatment processes and several sewer overflow types and their contribution to microplastic loads to recipients. On the example of the Baltic Sea basin, presented results indicate a considerable discharge of microplastic from WWTPs despite the relatively good overall removal efficiency. Results show that the discharge of microplastics from sewer overflows can be in the same magnitude as from treated wastewater although the total flow is much lower than that of treated wastewater. Sewer overflow events frequently occur and are expected to increase due to climate change and urbanization, unless infrastructure is adapted. At the same time, sewer overflows are often neglected in conventional wastewater handling.
文摘Investigation of amino acids in hydrothermal systems is of prime importance for the understanding of geochemistry and microbiology of hydrothermal vents and plumes, for carbon and metals global cycles, for metabolism of some hydrothermal microorganisms and for the origin of life issue. Extensive theoretical and experimental work on amino acids behaviour in hydrothermal fluids has been done, conversely only few data exist on natural samples. Because each hydrothermal vent is unique, the more data we collect the better we will be able to address each of these questions. Usually amino acids in hydrothermal fluids have been measured by HPLC-FLD. The chromatographic separation was at least 26 min and up to 135 min and the required derivatization step may be time consuming, may use harmful chemicals and may be source of contamination. Alternatively, we describe here a method combining quickness (4.5 min), high resolution (10,000), very low LOD (sub-ppb) and without derivatization. Characterisation and separation of 10 relevant proteinogenic underivatized amino acids was achieved by ion-pairing reversed-phase Ultra-high Performance Liquid Chromatography-Electrospray Ionisation-Quadrupole Time of Flight-Mass Spectrometry (UPLC-ESI-QTOF-MS). Excellent linearity in the response was obtained for all amino acids with correlation coefficients > 0.9921. This method was successfully applied to natural hydrothermal fluid samples from ultramafic-hosted vents of the Mid-Atlantic Ridge region. Results are consistent with the only 2 other studies published on ultramafic-hosted vents and complete the few available data.
文摘Correction to:J.For.Res.https://doi.org/10.1007/s11676-022-01560-8 During production process,the below mentioned errors appeared in the original article and inadvertently published with error.
文摘This paper presents an assessment of air quality of the Kathmandu valley, capital city of Nepal. This is the largest urbanized area in the country of about 300 km2. In the last two decades an intensive development of demographic, traffic and industry growth in the region was observed which was reflected on the air quality degradation. In order to evaluate the urban air quality in Kathmandu, a field monitoring network for particle deposition, nitrogen dioxide （NO2） and sulphur dioxide （SO2） by passive sampling with high space resolution was implemented in co-operation with IVL-Sweden. The net work composed of 60 monitoring sites distributed in a grid of 1 × 1 km2 covering all over the main city and some rural valley. Monitoring were carried out for two seasons, rainy and dry as two campaign monitoring. The diffusive samplers were prepared and analyzed in IVL, Sweden. Good agreements in particle deposition between the two campaigns were observed. The particle deposition to the surrogate surface varied between 3 and 608 μg@cm2·monthl for the monitoring periods. The NOz concentrations on the other hand were quite similar in the two campaigns, and the SO2 concentrations were much lower in the first campaign compared to the second. The ranges of NO2 and SO2 concentrations were found to be from 5.6 to 52.6 μg/m3 and 0.6 to 23.4 μg·m-3 respectively. Arc Info/Arc map GIS 9.2 software was used for production of maps of spatial distribution of all the three parameters in the valley. Seasonal variation and traffic influence were also studied. Local meteorological effects in the distribution of pollutants were clearly observed and the NO2 concentrations were strictly related with traffic intensity.
