Energy is an important resource that supports the development of human society,and energy security is even more relevant to the strength of a country.In order to ensure energy security,countries around the world are t...Energy is an important resource that supports the development of human society,and energy security is even more relevant to the strength of a country.In order to ensure energy security,countries around the world are taking measures to carry out energy transformation and construct new energy systems.As an important part of the new energy system,energy storage technology is highly valued by all countries.Among many large-scale energy storage technologies,salt cavern compressed air energy storage(CAES)technology stands out for its safety and economy,which is recognized and valued by scholars from various countries.For the construction of salt cavern CAES power station,it is very important to ensure the stability of salt cavern.Therefore,scholars have investigated the mechanical properties of salt rocks and the stability of salt caverns for CAES.This paper synthesizes the findings of current research on the creep and fatigue properties of salt rock,highlighting three key points:The factors influencing the creep and fatigue characteristics of salt rock include its composition,stress levels,and temperature.Notably,impurities and surrounding pressure tend to inhibit the deformation of salt rock,whereas elevated temperature and differential stress facilitate its deformation;The mechanisms governing creep and fatigue damage in salt rock are primarily associated with dislocation movement and microcracking;Most existing constitutive models for creep and fatigue are based on viscoelastic-plasticity theory,with fewer models derived from micro-mechanical perspectives.Additionally,this paper reviews studies on the stability of salt cavern CAES reservoirs utilizing numerical simulation methods and offers insights into future research directions concerning the creep and fatigue properties of salt rocks.展开更多
The plastic flow behaviors of AA6061-T4 sheets at different temperatures(21-300°C)and strain rates(0.002-4 s^(-1))were studied.Significant nonlinear effects of temperature and strain rate on flow behaviors were r...The plastic flow behaviors of AA6061-T4 sheets at different temperatures(21-300°C)and strain rates(0.002-4 s^(-1))were studied.Significant nonlinear effects of temperature and strain rate on flow behaviors were revealed,as well as underlying micromechanical factors.Phenomenology and machine learning-based constitutive models were developed.Both models were formulated in the framework of a temperature-dependent linear combination regulated by a transition function to capture the evolution of strain-hardening behavior with increasing temperature.Novel mathematical functions for describing temperature and strain rate sensitivities were formulated for the phenomenological constitutive model.The threshold temperature related to microstructure evolution was considered in the modeling.A data-enrichment strategy based on extrapolating experimental data via classical strain hardening laws was adopted to improve neural network training.An efficient inverse identification strategy,focusing solely on the transition function,was proposed to enhance the prediction accuracy of post-necking deformation by both constitutive models.展开更多
The history of architectural and urban practices reflects humanity’s enduring quest to comprehend and shape its environment,often through the lens of unifying meta-narratives.This paper critiques the tendency to seek...The history of architectural and urban practices reflects humanity’s enduring quest to comprehend and shape its environment,often through the lens of unifying meta-narratives.This paper critiques the tendency to seek cohesive frameworks,drawing from Graham Harman’s speculative realism and Bruno Latour’s“Principle of Irreduction,”which challenge hierarchical structures in understanding reality.These perspectives underscore the irreducibility and multiplicity of existence,advocating for a paradigm shift that resists determinism and embraces open-endedness.In this context,Adrian Bejan’s constructal law offers a compelling alternative for interpreting architectural and urban forms.Constructal theory conceptualizes form and design as evolutionary responses to flow systems,framing architecture as an active participant in the dynamic interplay of environmental,social,and temporal forces.This perspective encourages a reevaluation of architectural practices not as definitive solutions but as iterative processes that engage with complexity and contingency.By integrating constructal theory with contemporary philosophical critiques,this article proposes a polynarrative of architecture and urbanism that aligns with the fluidity and multiplicity of modern existence.It argues for a departure from static frameworks toward adaptive methodologies that acknowledge the interconnectedness of actors,scales,and temporalities.Ultimately,this approach reframes design as a dialogic process,fostering resilience and innovation in confronting the uncertainties of a rapidly evolving world.展开更多
Salt caverns are widely used for energy storage.During gas storage,the internal gas pressure fluctuates cyclically in response to energy demand,making it essential to assess how these pressure variations affect rock d...Salt caverns are widely used for energy storage.During gas storage,the internal gas pressure fluctuates cyclically in response to energy demand,making it essential to assess how these pressure variations affect rock deformation.In this study,experiments were conducted under different cyclic gas pressure conditions to investigate this effect.The findings indicate that(1)the deformation process of salt rock can be segmented into three stages:the deceleration stage,the steady-state stage,and the acceleration stage.(2)When the axial pressure remains constant,both axial and radial deformations exhibit a stepwise increasing trend in response to cyclic gas pressure variations.Similarly,under axial graded loading,the deformations also demonstrate a progressive rise.By analyzing the deformation differences and model coefficient fluctuations within a single gas pressure cycle,it is found that radial deformation is higher sensitive to changes in cyclic gas pressure.(3)The axial deformation shows a stepwise increase,and the radial deformation showed a cyclic change with changing gas pressure.Therefore,the cyclic gas pressure influence factor α,axial loading influence factor β,and state variable σ^(*)are introduced to develop a viscoplastic ontological model that accounts for the impacts of cyclic gas pressure,confining pressure and axial stress.Validated by the deformation data,the new model can better fit both the axial deformation and the radial deformation of the three stages and has strong applicability and accuracy by changing only fewer parameters.The state variable rate shows the same stage as the deformation rate and residual strain of salt rock,which can better reflect the internal hardening of salt rock.展开更多
Destress blasting is a widely adopted technique for mitigating rockburst hazards in deep underground excavations.However,its effectiveness is closely linked to the mechanical degradation characteristics of the rock ma...Destress blasting is a widely adopted technique for mitigating rockburst hazards in deep underground excavations.However,its effectiveness is closely linked to the mechanical degradation characteristics of the rock mass after failure,which are often overlooked in design practices.This study presents a numerical assessment of how residual rock mass properties influence the performance of destress blasting,focusing specifically on residual cohesion,residual friction angle,and critical plastic strain.Three models were developed using the 3DEC code to represent(1)a conventional excavation without boreholes,(2)excavation with relief holes but no blasting,and(3)excavation with relief holes subjected to dynamic loading.Each model was tested under three sets of residual parameters to simulate varying degrees of post-failure degradation.Simulation results show that boreholes without dynamic loading do not induce failure or stress relief,regardless of residual strength conditions.In contrast,when dynamic loading is applied,the extent and continuity of plastic zones,as well as the magnitude of stress redistribution,are significantly influenced by the residual parameters.Lower values of critical plastic strain result in greater post-yield stress reduction in the rock mass and lead to more pronounced stress relief near the excavation face.Additionally,the destressing effects are spatially non-uniform,with greater reductions observed near the center of the drift face where blast influence is strongest.These findings highlight the critical role of post-peak rock behavior in determining the effectiveness of destress blasting.Considering the residual mechanical properties of the rock mass after blast-induced damage is essential for optimizing blast design and enhancing excavation safety in deep mining operations.展开更多
The publisher regrets that the article type for this publication was incorrectly labeled as a Research Article.The correct designation should be Review Article.
A combination of hard(SiCP)and soft(fly ash)particulate reinforcements could be a strategy to enhance combination of multiple properties of Magnesium and its alloys which otherwise suffer from low stiffness,low wear r...A combination of hard(SiCP)and soft(fly ash)particulate reinforcements could be a strategy to enhance combination of multiple properties of Magnesium and its alloys which otherwise suffer from low stiffness,low wear resistance,and many other critical properties.However,at present a comprehensive and robust map correlating different properties in particle-reinforced composites is much lacking.In this work,an industrial grade AZ91 magnesium alloy reinforced with hard SiC and soft fly ash particles(with 3 vol.%each),has been prepared using stir casting followed by hot extrusion at 325℃with a ratio of 21.5.Microstructure of the hybrid composite was characterized using optical and scanning electron microscopes.The composite exhibited a reduction in average grain size from 13.6 to 7.1μm,concomitantly an increase in Vickers hardness from 73 to 111 HV.The tension-compression yield asymmetry ratios of the unreinforced alloy and hybrid composite were 1.165 and 0.976,respectively indicating higher yield strength for the composite under compressive load.The composite exhibited 76%improvement in damping capacity under time sweep mode,and 28%improvement at 423 K under temperature sweep mode.The tribological characteristics of the composite under dry sliding conditions at sliding speeds and loads in the range of 0.5 to 1.5 m s^(-1)and 10 to 30 N,respectively showed higher wear resistance than the unreinforced alloy.The composite showed 23%improvement in sliding wear resistance at a load of 20 N and a speed of 1 m s^(-1).Finally,efforts have been made to understand the influence of one property on the other by developing statistical property correlation maps from the properties obtained in this study and from the literature.These maps are expected to help in the design of hybrid Metal Matrix Composites for a variety of targeted applications in different sectors.展开更多
This work aimed to study the efficiency of the reverse micelle(RM)preparation route in the syntheses of sub-5 nm Fe-doped CeO_(2)nanocrystals for boosting the visible-light-driven photocatalytic hydrogen production fr...This work aimed to study the efficiency of the reverse micelle(RM)preparation route in the syntheses of sub-5 nm Fe-doped CeO_(2)nanocrystals for boosting the visible-light-driven photocatalytic hydrogen production from methanol aqueous solutions.The effectiveness of confining precipitation reactions within micellar cages was evaluated through extensive physicochemical cha racterization.In particula r,the nominal composition(0-5 mol%Fe)was preserved as ascertained by ICP-MS analysis,and the absence of separate iron-containing crystalline phases was supported by X-ray diffraction.The effective aliovalent doping and modulation of the optical properties were investigated using UV-Vis,Raman,and photoluminescence spectroscopies.2.5 mol%iron was found to be an optimal content to achieve a significant decrease in the band gap,enhance the concentration of oxygen vacancy defects,and increase the charge carrier lifetime.The photocatalytic activity of Fe-doped CeO_(2)prepared at different Fe contents with RM preparation was studied and compared with undoped CeO_(2).The optimal iron load was identified to be2.5 mol%,achieving the highest hydrogen production(7566μmol L-1after 240 min under visible light).Moreover,for comparison,the conventional precipitation(P)method was adopted to prepare iron containing CeO_(2)at the optimal content(2.5 mol%Fe).The Fe-doped CeO_(2)catalyst prepared by RM showed a significantly higher hydrogen production than that obtained with the sample prepared by the P method.The optimal Fe-doped CeO_(2),prepared by the RM method,was stable for six reuse cycles.Moreover,the role of water in the mechanism of photocatalytic hydrogen evolution under visible light was studied through the test in the presence of D2O.The obtained results evidenced that hydrogen was produced from the reduction of H^(+)by the electrons promoted in the conduction band,while methanol was preferentially oxidized by the photogenerated positive holes.展开更多
In order to investigate the damage tolerance of a metastable Ti-5Al-3V-3Mo-2Cr-2Zr-1Nb-1Fe(Ti5321)alloy with bimodal microstructure using void growth quantification and micromechanical modeling,in situ tensile testing...In order to investigate the damage tolerance of a metastable Ti-5Al-3V-3Mo-2Cr-2Zr-1Nb-1Fe(Ti5321)alloy with bimodal microstructure using void growth quantification and micromechanical modeling,in situ tensile testing was performed during X-ray microtomography experiments.Compared with investigations of surface voids by traditional two-dimensional(2D)methods involving post-mortem characterization,three-dimensional(3D)information on void evolution inside optically opaque samples obtained through X-ray microtomography is essential.The Rice and Tracey model and Huang model were applied to predict void growth and show good agreement with experimental data using calibration of the damage parameterα.The void growth kinetics of Ti5321 with bimodal microstructure was analyzed by comparing theαvalue with that of Ti64 for different microstructure morphologies.The damage mechanism of ductile fracture of Ti5321 with bimodal microstructure is discussed.It was found that the size of the voids apparently increases with the triaxiality of stress.Post-mortem scanning electron microscopy(SEM)was also used to demonstrate this damage mechanism of ductile fracture of Ti5321.展开更多
Rubberized concrete is one of the most studied applications of discarded tires and offers a promising approach to developing materials with enhanced properties.The rubberized concrete mixture results in a reduced modu...Rubberized concrete is one of the most studied applications of discarded tires and offers a promising approach to developing materials with enhanced properties.The rubberized concrete mixture results in a reduced modulus of elasticity and a reduced compressive and tensile strength compared to traditional concrete.This study employs finite element simulations to investigate the elastic properties of rubberized mortar(RuM),considering the influence of inclusion stiffness and interfacial debonding.Different homogenization schemes,including Voigt,Reuss,and mean-field approaches,are implemented using DIGIMAT and ANSYS.Furthermore,the influence of the interfacial transition zone(ITZ)between mortar and rubber is analyzed by periodic homogenization.Subsequently,the influence of the ITZ is examined through a linear fracture analysis with the stress intensity factor as a key parameter,using the ANSYS SMART crack growth tool.Finally,a non-linear study in FEniCS is carried out to predict the strength of the composite material through a compression test.Comparisons with high density polyethylene(HDPE)and gravel inclusions show that increasing inclusion stiffness enhances compressive strength far more effectively than simply improving the mortar/rubber bond.Indeed,when the inclusions are much softer than the surrounding matrix,any benefit gained on the elastic modulus or strength from stronger interfacial adhesion becomes almost negligible.This study provide numerical evidence that tailoring the rubber’s intrinsic stiffness—not merely strengthening the rubber/mortar interface—is a decisive factor for improving the mechanical performance of RuM.展开更多
Modern industrial equipment is increasingly characterized by miniaturization,integration,and high performance,necessitating the production of complex structural parts with exceptionally high internal surface quality.D...Modern industrial equipment is increasingly characterized by miniaturization,integration,and high performance,necessitating the production of complex structural parts with exceptionally high internal surface quality.Direct manufacturing often leads to high internal surface roughness,which traditional finishing and measuring methods cannot adequately address due to the decreasing size and increasing complexity of internal structures.This is especially true for components like pipes with large aspect ratios,extremely small deep holes,multi-stage bends,cross pipes,and array holes.To meet the high-performance manufacturing demands of these parts,advanced internal surface finishing and roughness measurement technologies have gained significant attention.This review focuses on the challenges and solutions related to internal surface parts with various apertures and complex structures.Internal surface finishing methods are categorized into mechanical finishing,fluid-based finishing,and energy-field-based finishing based on their characteristics.Roughness measurement technologies are divided into tool-probing and non-probing methods.The principles,required equipment,and key parameters of each finishing and measurement approach are discussed in detail.Additionally,the advantages and limitations of these methods are summarized,and future trends are forecasted.This paper serves as a comprehensive guide for researchers and engineers aiming to enhance the internal surface quality of complex structure parts.展开更多
We report the observation of Zeeman splitting in multiple spectral lines emitted by a laser-produced,magnetized plasma(1–3×10^(18)cm^(-3),1–15 eV)in the context of a laboratory astrophysics experiment under a c...We report the observation of Zeeman splitting in multiple spectral lines emitted by a laser-produced,magnetized plasma(1–3×10^(18)cm^(-3),1–15 eV)in the context of a laboratory astrophysics experiment under a controlled magneticfield up to 20T.Nitrogen lines(NII)in the visible range were used to diagnose the magneticfield and plasma conditions.This was performed by coupling our data with(563–574 nm)the Stark–Zeeman line-shape code PPPB.The excellent agreement between experiment and simulations paves the way for a non-intrusive experimental platform to get time-resolved measurements of the local magneticfield in laboratory plasmas.展开更多
基金supported by the Natural Science Fund of China(No.51834003,52274073,52022014).
文摘Energy is an important resource that supports the development of human society,and energy security is even more relevant to the strength of a country.In order to ensure energy security,countries around the world are taking measures to carry out energy transformation and construct new energy systems.As an important part of the new energy system,energy storage technology is highly valued by all countries.Among many large-scale energy storage technologies,salt cavern compressed air energy storage(CAES)technology stands out for its safety and economy,which is recognized and valued by scholars from various countries.For the construction of salt cavern CAES power station,it is very important to ensure the stability of salt cavern.Therefore,scholars have investigated the mechanical properties of salt rocks and the stability of salt caverns for CAES.This paper synthesizes the findings of current research on the creep and fatigue properties of salt rock,highlighting three key points:The factors influencing the creep and fatigue characteristics of salt rock include its composition,stress levels,and temperature.Notably,impurities and surrounding pressure tend to inhibit the deformation of salt rock,whereas elevated temperature and differential stress facilitate its deformation;The mechanisms governing creep and fatigue damage in salt rock are primarily associated with dislocation movement and microcracking;Most existing constitutive models for creep and fatigue are based on viscoelastic-plasticity theory,with fewer models derived from micro-mechanical perspectives.Additionally,this paper reviews studies on the stability of salt cavern CAES reservoirs utilizing numerical simulation methods and offers insights into future research directions concerning the creep and fatigue properties of salt rocks.
文摘The plastic flow behaviors of AA6061-T4 sheets at different temperatures(21-300°C)and strain rates(0.002-4 s^(-1))were studied.Significant nonlinear effects of temperature and strain rate on flow behaviors were revealed,as well as underlying micromechanical factors.Phenomenology and machine learning-based constitutive models were developed.Both models were formulated in the framework of a temperature-dependent linear combination regulated by a transition function to capture the evolution of strain-hardening behavior with increasing temperature.Novel mathematical functions for describing temperature and strain rate sensitivities were formulated for the phenomenological constitutive model.The threshold temperature related to microstructure evolution was considered in the modeling.A data-enrichment strategy based on extrapolating experimental data via classical strain hardening laws was adopted to improve neural network training.An efficient inverse identification strategy,focusing solely on the transition function,was proposed to enhance the prediction accuracy of post-necking deformation by both constitutive models.
文摘The history of architectural and urban practices reflects humanity’s enduring quest to comprehend and shape its environment,often through the lens of unifying meta-narratives.This paper critiques the tendency to seek cohesive frameworks,drawing from Graham Harman’s speculative realism and Bruno Latour’s“Principle of Irreduction,”which challenge hierarchical structures in understanding reality.These perspectives underscore the irreducibility and multiplicity of existence,advocating for a paradigm shift that resists determinism and embraces open-endedness.In this context,Adrian Bejan’s constructal law offers a compelling alternative for interpreting architectural and urban forms.Constructal theory conceptualizes form and design as evolutionary responses to flow systems,framing architecture as an active participant in the dynamic interplay of environmental,social,and temporal forces.This perspective encourages a reevaluation of architectural practices not as definitive solutions but as iterative processes that engage with complexity and contingency.By integrating constructal theory with contemporary philosophical critiques,this article proposes a polynarrative of architecture and urbanism that aligns with the fluidity and multiplicity of modern existence.It argues for a departure from static frameworks toward adaptive methodologies that acknowledge the interconnectedness of actors,scales,and temporalities.Ultimately,this approach reframes design as a dialogic process,fostering resilience and innovation in confronting the uncertainties of a rapidly evolving world.
基金supported by the National Natural Science Foundation of China (No.52274073)National Key R&D Program of China (No.2024YFB4007100)+2 种基金Chongqing Natural Science Foundation Innovation and Development Joint Fund (Municipal Education Commission)(No.CSTB2024NSCQ-LZX0056)Open Research Fund of State Key Laboratory of Geomechanics and Geotechnical Engineering Safety (No.SKLGGES-024006)financial support from the Rut and Sten Brand Foundation
文摘Salt caverns are widely used for energy storage.During gas storage,the internal gas pressure fluctuates cyclically in response to energy demand,making it essential to assess how these pressure variations affect rock deformation.In this study,experiments were conducted under different cyclic gas pressure conditions to investigate this effect.The findings indicate that(1)the deformation process of salt rock can be segmented into three stages:the deceleration stage,the steady-state stage,and the acceleration stage.(2)When the axial pressure remains constant,both axial and radial deformations exhibit a stepwise increasing trend in response to cyclic gas pressure variations.Similarly,under axial graded loading,the deformations also demonstrate a progressive rise.By analyzing the deformation differences and model coefficient fluctuations within a single gas pressure cycle,it is found that radial deformation is higher sensitive to changes in cyclic gas pressure.(3)The axial deformation shows a stepwise increase,and the radial deformation showed a cyclic change with changing gas pressure.Therefore,the cyclic gas pressure influence factor α,axial loading influence factor β,and state variable σ^(*)are introduced to develop a viscoplastic ontological model that accounts for the impacts of cyclic gas pressure,confining pressure and axial stress.Validated by the deformation data,the new model can better fit both the axial deformation and the radial deformation of the three stages and has strong applicability and accuracy by changing only fewer parameters.The state variable rate shows the same stage as the deformation rate and residual strain of salt rock,which can better reflect the internal hardening of salt rock.
基金supported by the opening project of State Key Laboratory of Coal Mine Disaster Dynamics and Control(No.2011DA105287-FW202409)special fund of State Key Laboratory of Intelligent Deep Metal Mining and Equipment(No.IDMEKFJJB01)financial support from the Rut and Sten Brand foundation.
文摘Destress blasting is a widely adopted technique for mitigating rockburst hazards in deep underground excavations.However,its effectiveness is closely linked to the mechanical degradation characteristics of the rock mass after failure,which are often overlooked in design practices.This study presents a numerical assessment of how residual rock mass properties influence the performance of destress blasting,focusing specifically on residual cohesion,residual friction angle,and critical plastic strain.Three models were developed using the 3DEC code to represent(1)a conventional excavation without boreholes,(2)excavation with relief holes but no blasting,and(3)excavation with relief holes subjected to dynamic loading.Each model was tested under three sets of residual parameters to simulate varying degrees of post-failure degradation.Simulation results show that boreholes without dynamic loading do not induce failure or stress relief,regardless of residual strength conditions.In contrast,when dynamic loading is applied,the extent and continuity of plastic zones,as well as the magnitude of stress redistribution,are significantly influenced by the residual parameters.Lower values of critical plastic strain result in greater post-yield stress reduction in the rock mass and lead to more pronounced stress relief near the excavation face.Additionally,the destressing effects are spatially non-uniform,with greater reductions observed near the center of the drift face where blast influence is strongest.These findings highlight the critical role of post-peak rock behavior in determining the effectiveness of destress blasting.Considering the residual mechanical properties of the rock mass after blast-induced damage is essential for optimizing blast design and enhancing excavation safety in deep mining operations.
文摘The publisher regrets that the article type for this publication was incorrectly labeled as a Research Article.The correct designation should be Review Article.
文摘A combination of hard(SiCP)and soft(fly ash)particulate reinforcements could be a strategy to enhance combination of multiple properties of Magnesium and its alloys which otherwise suffer from low stiffness,low wear resistance,and many other critical properties.However,at present a comprehensive and robust map correlating different properties in particle-reinforced composites is much lacking.In this work,an industrial grade AZ91 magnesium alloy reinforced with hard SiC and soft fly ash particles(with 3 vol.%each),has been prepared using stir casting followed by hot extrusion at 325℃with a ratio of 21.5.Microstructure of the hybrid composite was characterized using optical and scanning electron microscopes.The composite exhibited a reduction in average grain size from 13.6 to 7.1μm,concomitantly an increase in Vickers hardness from 73 to 111 HV.The tension-compression yield asymmetry ratios of the unreinforced alloy and hybrid composite were 1.165 and 0.976,respectively indicating higher yield strength for the composite under compressive load.The composite exhibited 76%improvement in damping capacity under time sweep mode,and 28%improvement at 423 K under temperature sweep mode.The tribological characteristics of the composite under dry sliding conditions at sliding speeds and loads in the range of 0.5 to 1.5 m s^(-1)and 10 to 30 N,respectively showed higher wear resistance than the unreinforced alloy.The composite showed 23%improvement in sliding wear resistance at a load of 20 N and a speed of 1 m s^(-1).Finally,efforts have been made to understand the influence of one property on the other by developing statistical property correlation maps from the properties obtained in this study and from the literature.These maps are expected to help in the design of hybrid Metal Matrix Composites for a variety of targeted applications in different sectors.
基金funding from the"Ministero dell'Universitàe della Ricerca(MUR)"(Italy)under the"Dipartimento di Eccellenza 2018-2022"program.
文摘This work aimed to study the efficiency of the reverse micelle(RM)preparation route in the syntheses of sub-5 nm Fe-doped CeO_(2)nanocrystals for boosting the visible-light-driven photocatalytic hydrogen production from methanol aqueous solutions.The effectiveness of confining precipitation reactions within micellar cages was evaluated through extensive physicochemical cha racterization.In particula r,the nominal composition(0-5 mol%Fe)was preserved as ascertained by ICP-MS analysis,and the absence of separate iron-containing crystalline phases was supported by X-ray diffraction.The effective aliovalent doping and modulation of the optical properties were investigated using UV-Vis,Raman,and photoluminescence spectroscopies.2.5 mol%iron was found to be an optimal content to achieve a significant decrease in the band gap,enhance the concentration of oxygen vacancy defects,and increase the charge carrier lifetime.The photocatalytic activity of Fe-doped CeO_(2)prepared at different Fe contents with RM preparation was studied and compared with undoped CeO_(2).The optimal iron load was identified to be2.5 mol%,achieving the highest hydrogen production(7566μmol L-1after 240 min under visible light).Moreover,for comparison,the conventional precipitation(P)method was adopted to prepare iron containing CeO_(2)at the optimal content(2.5 mol%Fe).The Fe-doped CeO_(2)catalyst prepared by RM showed a significantly higher hydrogen production than that obtained with the sample prepared by the P method.The optimal Fe-doped CeO_(2),prepared by the RM method,was stable for six reuse cycles.Moreover,the role of water in the mechanism of photocatalytic hydrogen evolution under visible light was studied through the test in the presence of D2O.The obtained results evidenced that hydrogen was produced from the reduction of H^(+)by the electrons promoted in the conduction band,while methanol was preferentially oxidized by the photogenerated positive holes.
基金supported by the China Postdoctoral Science Foundation(No.2022M720399).
文摘In order to investigate the damage tolerance of a metastable Ti-5Al-3V-3Mo-2Cr-2Zr-1Nb-1Fe(Ti5321)alloy with bimodal microstructure using void growth quantification and micromechanical modeling,in situ tensile testing was performed during X-ray microtomography experiments.Compared with investigations of surface voids by traditional two-dimensional(2D)methods involving post-mortem characterization,three-dimensional(3D)information on void evolution inside optically opaque samples obtained through X-ray microtomography is essential.The Rice and Tracey model and Huang model were applied to predict void growth and show good agreement with experimental data using calibration of the damage parameterα.The void growth kinetics of Ti5321 with bimodal microstructure was analyzed by comparing theαvalue with that of Ti64 for different microstructure morphologies.The damage mechanism of ductile fracture of Ti5321 with bimodal microstructure is discussed.It was found that the size of the voids apparently increases with the triaxiality of stress.Post-mortem scanning electron microscopy(SEM)was also used to demonstrate this damage mechanism of ductile fracture of Ti5321.
基金financial support from the Chilean National Agency for Research and Development(ANID),National Doctorate No.21212028financial support from ANID,FONDECYT Regular Research Project No.1221793.
文摘Rubberized concrete is one of the most studied applications of discarded tires and offers a promising approach to developing materials with enhanced properties.The rubberized concrete mixture results in a reduced modulus of elasticity and a reduced compressive and tensile strength compared to traditional concrete.This study employs finite element simulations to investigate the elastic properties of rubberized mortar(RuM),considering the influence of inclusion stiffness and interfacial debonding.Different homogenization schemes,including Voigt,Reuss,and mean-field approaches,are implemented using DIGIMAT and ANSYS.Furthermore,the influence of the interfacial transition zone(ITZ)between mortar and rubber is analyzed by periodic homogenization.Subsequently,the influence of the ITZ is examined through a linear fracture analysis with the stress intensity factor as a key parameter,using the ANSYS SMART crack growth tool.Finally,a non-linear study in FEniCS is carried out to predict the strength of the composite material through a compression test.Comparisons with high density polyethylene(HDPE)and gravel inclusions show that increasing inclusion stiffness enhances compressive strength far more effectively than simply improving the mortar/rubber bond.Indeed,when the inclusions are much softer than the surrounding matrix,any benefit gained on the elastic modulus or strength from stronger interfacial adhesion becomes almost negligible.This study provide numerical evidence that tailoring the rubber’s intrinsic stiffness—not merely strengthening the rubber/mortar interface—is a decisive factor for improving the mechanical performance of RuM.
基金the financial supports from National Key R&D Program of China(No.2022YFB3403301)the Funds for International Cooperation and Exchange of the National Natural Science Foundation of China(No.52311530080)。
文摘Modern industrial equipment is increasingly characterized by miniaturization,integration,and high performance,necessitating the production of complex structural parts with exceptionally high internal surface quality.Direct manufacturing often leads to high internal surface roughness,which traditional finishing and measuring methods cannot adequately address due to the decreasing size and increasing complexity of internal structures.This is especially true for components like pipes with large aspect ratios,extremely small deep holes,multi-stage bends,cross pipes,and array holes.To meet the high-performance manufacturing demands of these parts,advanced internal surface finishing and roughness measurement technologies have gained significant attention.This review focuses on the challenges and solutions related to internal surface parts with various apertures and complex structures.Internal surface finishing methods are categorized into mechanical finishing,fluid-based finishing,and energy-field-based finishing based on their characteristics.Roughness measurement technologies are divided into tool-probing and non-probing methods.The principles,required equipment,and key parameters of each finishing and measurement approach are discussed in detail.Additionally,the advantages and limitations of these methods are summarized,and future trends are forecasted.This paper serves as a comprehensive guide for researchers and engineers aiming to enhance the internal surface quality of complex structure parts.
基金supported by grants managed by l’Agence Nationale de la Recherche under the Investissements d’Avenir programs Grant Nos. ANR-18-EURE-0014, ANR-10-LABX-0039-PALM, and ANR-22-CE30-0044supported by grants from Japan Society for the Promotion of Science (JSPS) KAKENHI (Grant No. 23K20038)+2 种基金JSPS Core-to-Core program (Grant No. JPJSCCA20230003)carried out within the framework of the EUROfusion Consortium, funded by the European Union via the Euratom Research and Training Programme (Grant Agreement No. 101052200-EUROfusion)operated within the framework of the Enabling Research Project No. AWP24-ENR-IFE.02.CEA-01 “Magnetized ICF”
文摘We report the observation of Zeeman splitting in multiple spectral lines emitted by a laser-produced,magnetized plasma(1–3×10^(18)cm^(-3),1–15 eV)in the context of a laboratory astrophysics experiment under a controlled magneticfield up to 20T.Nitrogen lines(NII)in the visible range were used to diagnose the magneticfield and plasma conditions.This was performed by coupling our data with(563–574 nm)the Stark–Zeeman line-shape code PPPB.The excellent agreement between experiment and simulations paves the way for a non-intrusive experimental platform to get time-resolved measurements of the local magneticfield in laboratory plasmas.
