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Critical quality indicators of high-performance polyetherimide(ULTEM)over the MEX 3D printing key generic control parameters:Prospects for personalized equipment in the defense industry
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作者 Nectarios Vidakis Markos Petousis +6 位作者 Constantine David Nektarios K.Nasikas Dimitrios Sagris Nikolaos Mountakis Mariza Spiridaki Amalia Moutsopoulou Emmanuel Stratakis 《Defence Technology(防务技术)》 2025年第1期150-167,共18页
Additive Manufacturing(AM)can provide customized parts that conventional techniques fail to deliver.One important parameter in AM is the quality of the parts,as a result of the material extrusion 3D printing(3D-P)proc... Additive Manufacturing(AM)can provide customized parts that conventional techniques fail to deliver.One important parameter in AM is the quality of the parts,as a result of the material extrusion 3D printing(3D-P)procedure.This can be very important in defense-related applications,where optimum performance needs to be guaranteed.The quality of the Polyetherimide 3D-P specimens was examined by considering six control parameters,namely,infill percentage,layer height,deposition angle,travel speed,nozzle,and bed temperature.The quality indicators were the root mean square(Rq)and average(Ra)roughness,porosity,and the actual to nominal dimensional deviation.The examination was performed with optical profilometry,optical microscopy,and micro-computed tomography scanning.The Taguchi design of experiments was applied,with twenty-five runs,five levels for each control parameter,on five replicas.Two additional confirmation runs were conducted,to ensure reliability.Prediction equations were constructed to express the quality indicators in terms of the control parameters.Three modeling approaches were applied to the experimental data,to compare their efficiency,i.e.,Linear Regression Model(LRM),Reduced Quadratic Regression Model,and Quadratic Regression Model(QRM).QRM was the most accurate one,still the differences were not high even considering the simpler LRM model. 展开更多
关键词 Polyetherimide(PEI) Material extrusion(MEX) Three-dimensional printing(3D-P) Critical quality indicators(CQIs) Quadratic regression model(QRM) Taguchi
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双波长纳秒激光清洗技术在大理石文物上的应用 被引量:1
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作者 李晨毓 胡文哲 +6 位作者 张雪雁 刘瀚文 刘晓龙 曲亮 祝萌 段鸿莺 Paraskevi Pouli 《中国光学(中英文)》 EI CAS CSCD 北大核心 2024年第5期1050-1059,共10页
传统的清洗方法不能对文物表面较小污染颗粒进行清洗,并且容易造成文物表面不可逆的损伤。为提高清洗污染物的能力,激光清洗技术逐渐应用于不同类型文物的清洗。本文研制了纳秒激光清洗系统并对故宫博物院的大理石模拟样品和大理石碎片... 传统的清洗方法不能对文物表面较小污染颗粒进行清洗,并且容易造成文物表面不可逆的损伤。为提高清洗污染物的能力,激光清洗技术逐渐应用于不同类型文物的清洗。本文研制了纳秒激光清洗系统并对故宫博物院的大理石模拟样品和大理石碎片进行清洗,清洗的对象是黑色结壳污染物。为了避免变黄效应,采用波长为1064 nm近红外光与355 nm紫外相结合的方法对大理石模拟样本进行激光清洗。当两者的能量密度比值为3∶2时,显微观测系统的照片显示有较好的清洗效果。将此比值应用于大理石碎片样本,利用显微拉曼光谱仪对清洗效果进行分析。实验结果证实了激光清洗的优势,也为激光清洗大理石表面污染物提供参数和评价方法参考。本文研究也为激光清洗技术在其他石质文物表面的清洗提供借鉴。 展开更多
关键词 激光清洗技术 大理石 双波长
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Morphology and Structure of Nb Thin Films Grown by Pulsed Laser Deposition at Different Substrate Temperatures 被引量:3
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作者 F.Gontad A.Lorusso +2 位作者 A.Manousaki A.Klini A.Perrone 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2016年第11期1192-1196,共5页
This paper reports the fabrication of Nb thin films through pulsed laser deposition at different substrate temperatures, ranging from 300 to 660 K. While the variation of the substrate temperature does not affect sign... This paper reports the fabrication of Nb thin films through pulsed laser deposition at different substrate temperatures, ranging from 300 to 660 K. While the variation of the substrate temperature does not affect significantly the excellent Nb thin film adhesion to the Si(100) substrate surface, the increase of the substrate temperature up to 570 K promotes an improvement of the grown film in terms of morphology and roughness. Such improvement is achieved through the formation of wider columnar structures with a reduced superficial roughness, around 5 nm, as shown by scanning electron microscopy(SEM) and atomic force microscopy. The use of temperatures over 570 K increases the substrate roughness due to the formation of irregular structures inside the film, as observed by SEM cross section analysis, and does not produce a relevant improvement on the crystalline structure of the material. 展开更多
关键词 Pulsed laser deposition NIOBIUM Superconducting radiofrequency cavities Deposition temperature
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Ultrashort pulsed laser induced complex surface structures generated by tailoring the melt hydrodynamics 被引量:2
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作者 Fotis Fraggelakis George D.Tsibidis Emmanuel Stratakis 《Opto-Electronic Advances》 SCIE EI 2022年第3期53-68,I0001,共17页
We present a novel approach for tailoring the laser induced surface topography upon femtosecond(fs)pulsed laser irradiation.The method employs spatially controlled double fs laser pulses to actively regulate the hydro... We present a novel approach for tailoring the laser induced surface topography upon femtosecond(fs)pulsed laser irradiation.The method employs spatially controlled double fs laser pulses to actively regulate the hydrodynamic microfluidic motion of the melted layer that gives rise to the structures formation.The pulse train used,in particular,consists of a previously unexplored spatiotemporal intensity combination including one pulse with Gaussian and another with periodically modulated intensity distribution created by Direct Laser Interference Patterning(DLIP).The interpulse delay is appropriately chosen to reveal the contribution of the microfluidic melt flow,while it is found that the sequence of the Gaussian and DLIP pulses remarkably influences the surface profile attained.Results also demonstrate that both the spatial intensity of the double pulse and the effective number of pulses per irradiation spot can further be modulated to control the formation of complex surface morphologies.The underlying physical processes behind the complex patterns’generation were interpreted in terms of a multiscale model combining electron excitation with melt hydrodynamics.We believe that this work can constitute a significant step forward towards producing laser induced surface structures on demand by tailoring the melt microfluidic phenomena. 展开更多
关键词 laser-matter interaction direct laser interference patterning surface functionalization laser micro/nano fabrication
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Charge carrier dynamics in different crystal phases of CH_(3)NH_(3)PbI_(3)perovskite 被引量:2
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作者 Efthymis Serpetzoglou Ioannis Konidakis +6 位作者 George Kourmoulakis Ioanna Demeridou Konstantinos Chatzimanolis Christos Zervos George Kioseoglou Emmanuel Kymakis Emmanuel Stratakis 《Opto-Electronic Science》 2022年第4期1-10,22-27,共16页
Despite that organic-inorganic lead halide perovskites have attracted enormous scientific attention for energy conversion applications over the recent years,the influence of temperature and the type of the employed ho... Despite that organic-inorganic lead halide perovskites have attracted enormous scientific attention for energy conversion applications over the recent years,the influence of temperature and the type of the employed hole transport layer(HTL)on the charge carrier dynamics and recombination processes in perovskite photovoltaic devices is still largely unexplored.In particular,significant knowledge is missing on how these crucial parameters for radiative and non-radiative recombinations,as well as for efficient charge extraction vary among different perovskite crystalline phases that are induced by temperature variation.Herein,we perform micro photoluminescence(pPL)and ultrafast time resolved transient absorption spectroscopy(TAS)in Glass/Perovskite and two dierent Glass/ITO/HTL/Perovskite configurations at temperatures below room temperature,in order to probe the charge carrier dynamics of different perovskite crystalline phases,while considering also the effect of the employed HTL polymer.Namely,CH_(3)NH_(3)Pbb films were deposited on Glass,PEDOT:PSS and PTAA polymers,and the developed Glass/CH_(3)NH_(3)PbI_(3)and Glass/ITO/HTL/CH_(3)NH_(3)PbI_(3)architectures were studied from 85 K up to 215 K in order to explore the charge extraction dynamics of the CH_(3)NH_(3)PbI_(3)orthorhombic and tetragonal crystalline phases.It is observed an unusual blueshift of the bandgap with temperature and the dual emission at temperature below of 100 K and also,that the charge carrier dynamics,as expressed by hole injection times and free carrier recombination rates,are strongly depended on the actual pervoskite crystal phase,as well as,from the selected hole transport material. 展开更多
关键词 transient absorption spectroscopy p-photoluminescence variable temperature perovskite crystalline phases hole transport layer charge carrier dynamics
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Impact of substrate on opto-thermal response of thin metallic targets under irradiation with femtosecond laser pulses
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作者 TSIBIDIS G D STRATAKIS E 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第10期3410-3421,共12页
Femtosecond pulsed lasers have been widely used over the past decades due to their capability to fabricate precise patterns at the micro-and nano-lengths scales. A key issue for efficient material processing is the de... Femtosecond pulsed lasers have been widely used over the past decades due to their capability to fabricate precise patterns at the micro-and nano-lengths scales. A key issue for efficient material processing is the determination of the laser parameters used in the experimental set ups. Despite a systematic investigation that has been performed to highlight the impact of every parameter independently, little attention has been drawn on the role of the substrate material on which the irradiated solid is placed. In this work, the influence of the substrate is emphasised for films of various thicknesses, which demonstrates that both the optical and thermophysical properties of the substrate affect the thermal fingerprint on the irradiated film while the impact is manifested to be higher at smaller film sizes. Two representative materials, silicon and fused silica, have been selected as typical substrates for thin films(gold and nickel) of different optical and thermophysical behaviour and the thermal response and damage thresholds are evaluated for the irradiated solids. The pronounced influence of the substrate is aimed to pave the way for new and more optimised designs of laserbased fabrication set ups and processing schemes. 展开更多
关键词 femtosecond laser pulse ultrafast dynamics optical excitation two-temperature model
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Influence of crystal polarity and metal electronegativity on the sensing properties of III-nitrides
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作者 Nikoletta Sofikiti George Tsiakatouras +2 位作者 Eleuterios Iliopoulos Alexandros Georgakilas Nikos Chaniotakis 《材料科学与工程(中英文版)》 2009年第6期28-39,共12页
关键词 极性晶体 传感特性 III 氮化物 Lewis酸性 金属 电位响应 GaN
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Interface engineering of Z-scheme heterojunction for photocatalytic water splitting
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作者 Daming Zhao Yuxiao Yang +1 位作者 Vasileios Binas Shaohua Shen 《Fundamental Research》 2025年第5期2204-2208,共5页
Photocatalytic water splitting technology can directly convert solar energy into H_(2) via a zero-carbon route,offering a sustainable solution for solar utilization and H_(2) supply.Among various developed photocataly... Photocatalytic water splitting technology can directly convert solar energy into H_(2) via a zero-carbon route,offering a sustainable solution for solar utilization and H_(2) supply.Among various developed photocatalysts,Z-scheme heterojunction mimicking natural photosynthesis by combining two dissimilar semiconductors for redox reactions in series has unequivocally demonstrated its superiority in enhanced charge transfer,robust redox driving force,and wide optical absorption range.A comprehensive understanding on the fundamental principles of interface engineering between semiconductor components is the key to construct an efficient Z-scheme heterojunction.By focusing on different types of semiconductors,this article thoroughly expounds the coupling principles of components in binary mediator-free and ternary solid-mediator Z-scheme heterojunctions for photocatalytic water splitting,from the viewpoint of band structure alignment and interfacial electric field design.In addition to the well summarized research progresses in recent years,perspectives on the challenges and opportunities for developing advanced Z-scheme heterojunctions are provided. 展开更多
关键词 Interface engineering Z-scheme heterojunction Water splitting PHOTOCATALYSIS Solar energy conversion
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Photocatalytic oxidation of gaseous benzene,toluene and xylene under UV and visible irradiation over Mn-doped TiO_(2)nanoparticles 被引量:8
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作者 Vassilios Binas Vassilis Stefanopoulos +1 位作者 George Kiriakidis Panos Papagiannakopoulos 《Journal of Materiomics》 SCIE EI 2019年第1期56-65,共10页
The photocatalytic oxidation of gaseous benzene,toluene and xylene(BTX)over un-doped,0.1 and 1 wt%Mn-TiO_(2)nanoparticles under ultraviolet and visible irradiation was studied in atmosphere of synthetic air or inert g... The photocatalytic oxidation of gaseous benzene,toluene and xylene(BTX)over un-doped,0.1 and 1 wt%Mn-TiO_(2)nanoparticles under ultraviolet and visible irradiation was studied in atmosphere of synthetic air or inert gas.The photocatalytic decomposition efficiency and the oxidation products were determined using a Static Photochemical Reactor coupled with FTIR spectroscopy.BTX underwent efficient decomposition over Mn-TiO_(2)photocatalysts under UV irradiation,more with oxygen presence and less without oxygen.More important toluene and xylene went substantial decomposition over 0.1 mol%Mn-TiO_(2)under visible irradiation with oxygen presence.The main final oxidation products in the UV photocatalysis of BTX were CO_(2),CO and H2O,with CO_(2) and CO yields 4 and 2 respectively.The conversion percentage of benzene,toluene,and xylene to CO_(2) were 63.6%,56.4%,51.8%,and to CO 29%,26.5%,23.2%,respectively.In the visible photocatalysis of toluene and xylene the yields of CO were insignificant.Formation of carbon containing deposits on TiO_(2)surfaces was observed after extensive UV photocatalysis of toluene and xylene,and such by-products surface coverage may reduce the photocatalytic activity of TiO_(2)samples.Some aspects of the photocatalytic mechanism were examined. 展开更多
关键词 Mn-doped TiO_(2) VISIBLE Light photocatalysis Photodegradation of benzene TOLUENE XYLENE Indoors air pollution
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金属原子诱导的微环境调控在聚合氮化碳光催化析氢中的研究 被引量:1
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作者 赵大明 杨雨骁 +1 位作者 Vasileios Binas 沈少华 《Science China Materials》 SCIE EI CAS CSCD 2024年第6期1765-1779,共15页
开发高效稳定的半导体光催化剂对光催化技术迈向实际应用至关重要.聚合物氮化碳(CN)因其优异的物理化学性质而被视为最具发展前景的制氢光催化剂之一.在过去几十年中,从热力学或动力学角度开发的一系列改性策略已经显著提升了CN的光催... 开发高效稳定的半导体光催化剂对光催化技术迈向实际应用至关重要.聚合物氮化碳(CN)因其优异的物理化学性质而被视为最具发展前景的制氢光催化剂之一.在过去几十年中,从热力学或动力学角度开发的一系列改性策略已经显著提升了CN的光催化制氢性能.近期,金属原子修饰策略为CN改性提供了一条新途径,这种策略可以精确调控CN的微环境.本文全面回顾了金属原子修饰的CN光催化剂在光催化分解水制氢领域的最新研究进展,包括金属单原子修饰的CN、金属双原子修饰的CN、金属单原子与团簇共修饰的CN,重点阐述了金属原子对提升光催化性能的关键作用.此外,本文还全面总结了发展先进的金属原子修饰的CN光催化剂所面临的挑战与机遇. 展开更多
关键词 metal atom polymeric carbon nitride hydrogen evolution PHOTOCATALYSIS solar energy conversion
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Powerful terahertz waves from long-wavelength infrared laser filaments 被引量:8
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作者 Vladimir Yu.Fedorov Stelios Tzortzakis 《Light: Science & Applications》 SCIE EI CAS CSCD 2020年第1期204-219,共16页
Strong terahertz(THz)electric and magnetic transients open up new horizons in science and applications.We review the most promising way of achieving sub-cycle THz pulses with extreme field strengths.During the nonline... Strong terahertz(THz)electric and magnetic transients open up new horizons in science and applications.We review the most promising way of achieving sub-cycle THz pulses with extreme field strengths.During the nonlinear propagation of two-color mid-infrared and far-infrared ultrashort laser pulses,long,and thick plasma strings are produced,where strong photocurrents result in intense THz transients.The corresponding THz electric and magnetic field strengths can potentially reach the gigavolt per centimeter and kilotesla levels,respectively.The intensities of these THz fields enable extreme nonlinear optics and relativistic physics.We offer a comprehensive review,starting from the microscopic physical processes of light-matter interactions with mid-infrared and far-infrared ultrashort laser pulses,the theoretical and numerical advances in the nonlinear propagation of these laser fields,and the most important experimental demonstrations to date. 展开更多
关键词 LASER EXTREME OPTICS
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Post-glass melting synthesis and photochromic properties of composite AgCl-AgPO_(3)glasses 被引量:1
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作者 Marios Adamidis Ioannis Konidakis Emmanuel Stratakis 《Journal of Materiomics》 SCIE CSCD 2023年第3期455-463,共9页
We herein present a simple,fast,low-temperature,post-glass melting fabrication protocol in which a photochromic silver cation based modified zone is incorporated within silver metaphosphate glass(AgPO_(3)).The selecti... We herein present a simple,fast,low-temperature,post-glass melting fabrication protocol in which a photochromic silver cation based modified zone is incorporated within silver metaphosphate glass(AgPO_(3)).The selection of AgPO_(3)glass is mainly based on its relative“soft”nature(T_(g)=192℃)that enables the integration of silver cations from the surface deposited AgCl layer,while being transparent in most of the visible range,and therefore suitable for smart photochromic window applications.The suggested synthesis procedure permits the controlled formation of a silver cation modified layer within the host glass matrix,while the characteristics of the layer itself can be adjusted correspondingly.Our findings reveal a direct relationship between the developed composite AgCleAgPO_(3)glass photochromic response and the morphological features of the integrated layer,i.e.,thickness and position.More importantly,the photochromic response time with various UV irradiation doses is also studied,where remarkable response times of several seconds are obtained.Processes and efforts to further enhance the photochromic performance by utilizing the presence of silver nanoparticles within the glass matrix are also presented and discussed. 展开更多
关键词 Silver chloride Silver metaphosphate glass Soft phosphate glass Post-glass melting incorporation Photochromic properties
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Highly sensitive ozone and hydrogen sensors based on perovskite microcrystals directly grown on electrodes
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作者 Aikaterini Argyrou Konstantinos Brintakis +5 位作者 Athanasia Kostopoulou Emmanouil Gagaoudakis Ioanna Demeridou Vassilios Binas George Kiriakidis Emmanuel Stratakis 《Journal of Materiomics》 SCIE 2022年第2期446-453,共8页
Highly-sensitive and stable ozone and hydrogen sensing elements were fabricated based on well-crystalline rounded cube-shaped CsPbBr 3 microcrystals,synthesized by a facile solution process per-formed under ambient co... Highly-sensitive and stable ozone and hydrogen sensing elements were fabricated based on well-crystalline rounded cube-shaped CsPbBr 3 microcrystals,synthesized by a facile solution process per-formed under ambient conditions.It is shown that such elements demonstrate enhanced room tem-perature gas sensing ability compared to the previously reported metal halide and oxide-based ones.Electrical measurements performed on these sensing components revealed high sensitivity to ultra-low ozone and hydrogen concentrations,namely 4 ppb and 1 ppm respectively,as well as a remarkable repeatability,even after a few months of storage in ambient conditions.Both ozone and hydrogen sensors were self-activated,as they did not require the use of UV or heating external stimuli to operate,and exhibited fast detection and short restoration times.All such attractive properties along with the simple fabrication process could provide an easy,efficient and low-cost technology for the realization of future gas sensing devices. 展开更多
关键词 All-inorganic perovskite crystals Solution process Ozone sensing Hydrogen sensing High sensitivity Room-temperature sensor Perovskite sensors
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Observatory science with eXTP 被引量:1
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作者 Jean J.M.in 't Zand Enrico Bozzo +181 位作者 JinLu Qu Xiang-Dong Li Lorenzo Amati Yang Chen Immacolata Donnarumma Victor Doroshenko Stephen A.Drake Margarita Hernanz Peter A.Jenke Thomas J.Maccarone Simin Mahmoodifar Domitilla de Martino Alessandra De Rosa Elena M.Rossi Antonia Rowlinson Gloria Sala Giulia Stratta Thomas M.Tauris Joern Wilms XueFeng Wu Ping Zhou Iván Agudo Diego Altamirano Jean-Luc Atteia Nils A.andersson M.Cristina Baglio David R.Ballantyne Altan Baykal Ehud Behar Tomaso Belloni Sudip Bhattacharyya Stefano Bianchi Anna Bilous Pere Blay Joao Braga Sφren Brandt Edward F.Brown Niccolo Bucciantini Luciano Burderi Edward M.Cackett Riccardo Campana Sergio Campana Piergiorgio Casella Yuri Cavecchi Frank Chambers Liang Chen Yu-Peng Chen Jér?me Chenevez Maria Chernyakova ChiChuan Jin Riccardo Ciolfi Elisa Costantini Andrew Cumming Antonino D'Aì Zi-Gao Dai Filippo D'Ammando Massimiliano De Pasquale Nathalie Degenaar Melania Del Santo Valerio D'Elia Tiziana Di Salvo Gerry Doyle Maurizio Falanga XiLong Fan Robert D.Ferdman Marco Feroci Federico Fraschetti Duncan K.Galloway Angelo F.Gambino Poshak Gandhi MingYu Ge Bruce Gendre Ramandeep Gill Diego G?tz Christian Gouiffès Paola Grandi Jonathan Granot Manuel Güdel Alexander Heger Craig O.Heinke Jeroen Homan Rosario Iaria Kazushi Iwasawa Luca Izzo Long Ji Peter G.Jonker Jordi José Jelle S.Kaastra Emrah Kalemci Oleg Kargaltsev Nobuyuki Kawai Laurens Keek Stefanie Komossa Ingo Kreykenbohm Lucien Kuiper Devaky Kunneriath Gang Li En-Wei Liang Manuel Linares Francesco Longo FangJun Lu Alexander A.Lutovinov Denys Malyshev Julien Malzac Antonios Manousakis Ian McHardy Missagh Mehdipour YunPeng Men Mariano Méndez Roberto P.Mignani Romana Mikusincova M.Coleman Miller Giovanni Miniutti Christian Motch Joonas Nättilä Emanuele Nardini Torsten Neubert Paul T.O'Brien Mauro Orlandini Julian P.Osborne Luigi Pacciani Stéphane Paltani Maurizio Paolillo Iossif E.Papadakis Biswajit Paul Alberto Pellizzoni Uria Peretz Miguel A.Pérez Torres Emanuele Perinati Chanda Prescod-Weinstein Pablo Reig Alessandro Riggio Jerome Rodriguez Pablo Rodríguez-Gil Patrizia Romano Agata Rózańska Takanori Sakamoto Tuomo Salmi Ruben Salvaterra andrea Sanna andrea Santangelo Tuomas Savolainen Stéphane Schanne Hendrik Schatz LiJing Shao andy Shearer Steven N.Shore Ben W.Stappers Tod E.Strohmayer Valery F.Suleimanov Jirí Svoboda F.-K.Thielemann Francesco Tombesi Diego F.Torres Eleonora Torresi Sara Turriziani andrea Vacchi Stefano Vercellone Jacco Vink Jian-Min Wang JunFeng Wang Anna L.Watts ShanShan Weng Nevin N.Weinberg Peter J.Wheatley Rudy Wijnands Tyrone E.Woods Stan E.Woosley ShaoLin Xiong YuPeng Xu Zhen Yan George Younes WenFei Yu Feng Yuan Luca Zampieri Silvia Zane andrzej A.Zdziarski Shuang-Nan Zhang Shu Zhang Shuo Zhang Xiao Zhang Michael Zingale 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS CSCD 2019年第2期97-138,共42页
In this White Paper we present the potential of the enhanced X-ray Timing and Polarimetry(eXTP) mission for studies related to Observatory Science targets. These include flaring stars, supernova remnants, accreting wh... In this White Paper we present the potential of the enhanced X-ray Timing and Polarimetry(eXTP) mission for studies related to Observatory Science targets. These include flaring stars, supernova remnants, accreting white dwarfs, low and high mass X-ray binaries, radio quiet and radio loud active galactic nuclei, tidal disruption events, and gamma-ray bursts. eXTP will be excellently suited to study one common aspect of these objects: their often transient nature. Developed by an international Consortium led by the Institute of High Energy Physics of the Chinese Academy of Science, the eXTP mission is expected to be launched in the mid 2020s. 展开更多
关键词 space research in struments nuclear astrophysics flare stars accretion and accretion disks mass loss and stellar winds cataclysmic binaries X-ray binaries supernova remnants active galactic nuclei X-ray bursts gamma-ray bursts gravitational waves
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