The mechanism of strength and toughness variation in Ti microalloyed steel within the range of 0.04–0.157 wt.%was investigated.By adding 0.13 wt.%Ti,the steel achieves higher strength while maintaining a certain leve...The mechanism of strength and toughness variation in Ti microalloyed steel within the range of 0.04–0.157 wt.%was investigated.By adding 0.13 wt.%Ti,the steel achieves higher strength while maintaining a certain level of elongation and low-temperature impact toughness.With increasing Ti content,the grain size in the steel decreased from 17.7 to 8.9μm.This decrease in grain size is accompanied by an increase in the percentage of low-angle grain boundaries and dislocations,which act as barriers to hinder crack propagation.The Ti microalloyed steel exhibits a 20%increase in yield strength and a 14%increase in tensile strength.The transformation of steel plasticity occurs when the Ti content exceeds 0.102 wt.%.The low-temperature impact toughness of the steel gradually decreases with increasing Ti content.At low Ti content,the low-temperature impact toughness is reduced due to crack initiation by large-size inclusions.At high Ti content,the low-temperature impact toughness of the steel deteriorates due to several factors.These include the narrower tough–brittle transition zone,grain boundary embrittlement caused by small-sized grains,and the decrease in the solid solution strengthening effect.展开更多
Accurate crown control is paramount for ensuring the quality of hot-rolled strip products.Given the multitude of influencing parameters and the intricate coupling and genetic relationships among them,the conventional ...Accurate crown control is paramount for ensuring the quality of hot-rolled strip products.Given the multitude of influencing parameters and the intricate coupling and genetic relationships among them,the conventional crown control method is no longer sufficient to meet the precision requirements of schedule-free rolling.To address this limitation,an optimization framework for hot-rolled strip crown control was developed based on model-driven digital twin(MDDT).This framework enhances the strip crown control precision by facilitating collaborative operations among physical entities,virtual models,and functional application layers.In virtual modeling,a data-driven approach that integrates the extreme gradient boosting and the improved Harris hawk optimization algorithm was firstly proposed to fit the relationship between key process parameters and strip crown,and a global-local collaborative training strategy was proposed to enhance the model adaptability to diverse working conditions.Subsequently,the influence of crucial process factors on the virtual model was examined through model responses.Furthermore,a novel optimization mode for crown control based on MDDT was established by aligning and reconstructing both the physical and virtual models,thereby enhancing the crown control precision.Finally,data trials were conducted to validate the effectiveness of the proposed framework.The results indicated that the proposed method exhibited satisfactory performance and could be effectively utilized to improve the crown control precision.展开更多
Invar steels possess excellent thermal expansion properties,making them suitable as materials for manufacturing precision instruments.However,conventional invar steels lack sufficient strength for engineering applicat...Invar steels possess excellent thermal expansion properties,making them suitable as materials for manufacturing precision instruments.However,conventional invar steels lack sufficient strength for engineering applications,and various strengthening methods are urgently needed to enhance their strength.In this work,the possibility of enhancing the strength and maintaining low coefficient of thermal expansion(CTE)of the steel through mechanical heat treatment and the introduction of vanadium carbonitride is demonstrated.V-N microalloying and various heat treatment processes enable invar steel to enhance its strength while maintaining low thermal expansion properties.The strength of low-nitrogen addition invar steel measured 593 MPa during direct aging,representing a 44.6% increase compared to invar steel.After undergoing cold-deformation aging,the strength of low-nitrogen invar steel increased to 790 MPa,indicating a substantial improvement in strength relative to the direct aging condition.Notably,the coefficient of thermal expansion remained at 0.98×10^(-6)℃^(-1).By further increasing N content to introduce more vanadium carbonitride,the strength of high-nitrogen invar steel reached 927 MPa under cold-deformation process while maintaining a low CTE value of 1.02×10^(-6)℃^(-1).This achieved an extraordinary balance of high strength and low CTE,which is due to a well combination of various strengthening mechanisms,especially the Orowan strengthening where dislocations continuously bypass vanadium carbonitride to achieve the strengthening effect.The resulting findings are important for future preparation of excellent properties invar steel in industrial applications.展开更多
A series of Sn microalloying high-strength low-alloy(HSLA)steels were prepared through vacuum melting and hot rolling.Their stress corrosion cracking(SCC)behavior under high Cl^(−)environments was investigated using U...A series of Sn microalloying high-strength low-alloy(HSLA)steels were prepared through vacuum melting and hot rolling.Their stress corrosion cracking(SCC)behavior under high Cl^(−)environments was investigated using U-bend immersion,slow strain rate testing,electrochemical methods,and novel SCC sensor.Results revealed that HSLA steel microalloying with 0.1 wt.%Sn demonstrated superior SCC resistance,primarily attributed to the effective inhibition of the anodic dissolution mechanism.Fracture morphology revealed a transformation in fracture mode from brittle to a mixture of brittle-ductile characteristics,accompanied by the formation of a protective SnO_(2)oxide film on the steel surface.However,excessive Sn content exacerbated SCC susceptibility due to the increased hydrolysis of Sn^(2+),leading to localized pitting and crack initiation.The critical role of optimal Sn content was highlighted in balancing mechanical properties and corrosion resistance,suggesting potential applications in industries where materials face harsh chloride environments.展开更多
Catalyst-aided regeneration is a promising method for reducing the high regeneration energy consumption of amine-based CO_(2)capture technologies.However,the intrinsic relationship between the properties of the acidic...Catalyst-aided regeneration is a promising method for reducing the high regeneration energy consumption of amine-based CO_(2)capture technologies.However,the intrinsic relationship between the properties of the acidic sites and their catalytic activity is controversial.In this study,a series of W-based catalysts supported by ZrTiO_(x)were synthesised,and the effects of the intensity,distribution,and type of acid sites were systematically investigated by quantitatively regulating the acidic site properties.The results indicate stronger acidic sites play a more important role in the catalytic reaction.Moreover,the catalysts showed excellent performance only if the Br?nsted acid sites(BASs)and Lewis acid sites(LASs)coexisted.During the catalytic reaction,the BASs facilitated deprotonation,and the LASs promoted the decomposition of carbamates.The ratio of BASs to LASs(B/L)was a critical factor for catalytic activity,wherein optimal performance was achieved when the B/L ratio was close to 1.The 10%HPW/ZrTiO_(x)composite performed better than WO_(3)/ZrTiO_(x)and HSiW/ZrTiO_(x)because it had a stronger acid intensity and a suitable B/L ratio.As a result,the relative heat duty was reduced by 47%compared to 30%aqueous MEA,and the maximum CO_(2)desorption rate was increased by 83%.The Bader charge indicated that the W atoms of HPW/ZrTiO_(x)lost more electrons(0.18)than those of WO_(3)/ZrTiO_(x),which can weaken the O±H bond energy.Consequently,the calculated deprotonation energy is as low as 257 kJ mol^(-1)for HPW/ZrTiO_(x).展开更多
In this study,a cleaner method for separation and recovery of V/W/Na in waste selective catalytic reduction(SCR)catalyst alkaline leaching solution was proposed.The method involved membrane electrolysis followed by io...In this study,a cleaner method for separation and recovery of V/W/Na in waste selective catalytic reduction(SCR)catalyst alkaline leaching solution was proposed.The method involved membrane electrolysis followed by ion morphology pretreatme nt and solvent extraction.An acidic V(Ⅴ)/W(Ⅵ)solution was obtained using the me mbrane electrolysis method without adding any other chemical reagents.In addition,Na was recovered in the form of NaOH by product,avoiding the generation of Na containing wastewater.The electrolysis parameters were investigated,the lowest power consumption of 3063 kW·h·t^(-1)NaOH was obtained at a current density of 125 A·m^(-2)and an initial NaOH concentration of 2 mol·L^(-1).After electrolysis,oxalic acid was added to the acidic V/W containing solution,converting V(Ⅴ)negative ion to V(Ⅳ)positive ion.Since W(Ⅵ)ion state remained in negative form,the generation of heteropolyacid ions(W_(x)V_(y)O_(z)^(n-))was prevented.It was found that under the condition of oxalic acid addition/theoretical consumption 1.2 and reaction temperature 75℃,100%V(Ⅴ)was co nverted to V(Ⅳ4).Using 10%N263+10%noctanol+80%sulfonated kerosene as extractant,the highest W(Ⅵ)/V(Ⅳ)separation coefficient of 7559.76was obtained at pH=1.8,O:A ratio=1:1 and extraction time 15 min.With 2 mol·L^(-1)NaOH as stripping reagent,the W stripping efficiency reached 98.50%at O:A ratio=2:1 after 4-stages of stripping.The enrichment of V remained in the solution was realized using P204 as extractant and 20%(mass)H_(2)SO_(4)as stripping reagent.The parameters of extraction/stripping process were investigated,using 10%P204+10%TBP+80%sulfonated kerosene as extractant,the V extraction efficiency reached 97.50%at O:A ratio=1:2after 4 stages of extraction.Using 20%H_(2)SO_(4)as the stripping reagent,the V stripping efficiency was 98.30%at an O:A ratio of 4:1 after five stage s of stripping.After the entire process,a high-purity VOSO_(4)and Na_(2)WO_(4)product solutions were obtained with V/W recovery efficiency 95.84%/98.50%,separately.This study examined a more effective and cleaner method for separating V/W/Na in Na_(2)WO_(4)/NaVO_(3)solution,which may serve as a reference for the separation and recovery of V/W/Na in waste SCR catalysts.展开更多
Different stress states have a significant influence on the magnitude of the microscopic plastic strain and result in the development of the microstructure evolution.As a result,a comprehensive understanding of the di...Different stress states have a significant influence on the magnitude of the microscopic plastic strain and result in the development of the microstructure evolution.As a result,a comprehensive understanding of the different scale variation on microstructure evolution during bending deformation is essential.The advanced high strength dual-phase(DP1180)steel was investigated using multiscale microstructure-based 3D representative volume element(RVE)modelling technology with emphasis on understanding the relationship between the microstructure,localised stress-strain evolution as well as the deformation characteristics in the bending process.It is demonstrated that the localised development in bending can be more accurately described by microscopic deformation when taking into account microstructural properties.Microstructure-based 3D RVEs from each chosen bending condition generally have comparable localisation properties,whilst the magnitudes and intensities differ.In addition,the most severe localised bands are predicted to occur close to the ferrite and martensite phase boundaries where the martensite grains are close together or have a somewhat sharp edge.The numerically predicted results for the microstructure evolution,shear bands development and stress and strain distribution after 3-point bending exhibit a good agreement with the relevant experimental observations.展开更多
About 70%of the flue gas in the iron-steel industry has achieved multi-pollutant ultra-low emissions in China until 2023,and then the blast furnace gas purification has become the control step and bottleneck.Our resea...About 70%of the flue gas in the iron-steel industry has achieved multi-pollutant ultra-low emissions in China until 2023,and then the blast furnace gas purification has become the control step and bottleneck.Our research group has designed and constructed the world’s first blast furnace gas desulfurization pilot plant with the scale of 2000 Nm^(3)/h in October 2021.The pilot plant is a two-step combined desulfurization device including catalytic hydrolysis of carbonyl sulfur(COS)and absorption-oxidation of H_(2)S,continuously running for 120 days.In the hydrolysis system,one reason for catalyst deactivation has been verified from the sulfur deposition.HCN in blast furnace gas can be hydrolyzed on the hydrolysis catalyst to produce the nitrogen deposition,which is one of the reasons for catalyst deactivation and has never been found in previous studies.The deposition forms of S and N elements are determined,S element forms elemental sulfur and sulfate,while N element forms-NH_(2)and NH_(4)^(+).In the absorption-oxidation system,the O_(2)loading and the residence time have been optimized to control the oxidation of HS^(−)to produce elemental sulfur instead of by-product S_(2)O_(3)^(2−).The balance and distribution of S and N elements have been calculated for thewholemulti-phase system,approximately 84.4%of the sulfur is converted to solid sulfur product,about 1.3%of the sulfur and 19.2%of N element are deposited on the hydrolysis catalyst.The pilot plant provides technical support formulti-pollutant control of blast furnace.展开更多
In the traditional blast furnace(BF)ironmaking process in China,a notable deviation exists between the theoretical and actual yield of hot metal,leading to unexpected iron loss and restricting the improvement of produ...In the traditional blast furnace(BF)ironmaking process in China,a notable deviation exists between the theoretical and actual yield of hot metal,leading to unexpected iron loss and restricting the improvement of production capacity,which cannot adapt to the increasingly intensified smelting rhythm.Focusing on a BF in a Chinese steel enterprise,a deep neural network algorithm was designed to model the impact of multiple parameters on actual yield of hot metal in a single BF smelting cycle,successfully accomplishing the theoretical computation and real-time prediction of yield of hot metal for subsequent,unknown BF smelting cycle.Test results show that the proposed algorithm demonstrates an impressive prediction accuracy of 86.7% within an error range of±10 t and can swiftly complete the training and convergence process in 32.5 s.By integrating prediction results with Nomogram,a regulatory mechanism was engineered to minimize the deviation between theoretical and actual yield of hot metal.This mechanism ensures the yield enhancement of hot metal through dynamic adjustments of BF operational parameters.Industrial-scale application experiments confirmed that the intelligent operation and optimization system,developed in the laboratory,can maintain the yield deviation of hot metal within a stable range of 30 t,achieving a maximum reduction in iron loss rate of 17.65%compared to that before system operation.The findings provide robust support for the yield increase and efficiency improvement of the experimental BF.展开更多
The sticking behavior of pellets affects the continuity of production in hydrogen-based shaft furnace.The coupling influences of V_(2)O_(5) and reduction temperature on reduction sticking behavior and mechanism evolut...The sticking behavior of pellets affects the continuity of production in hydrogen-based shaft furnace.The coupling influences of V_(2)O_(5) and reduction temperature on reduction sticking behavior and mechanism evolution of pellets under hydrogen atmosphere are investigated.The increase in V_(2)O_(5) addition aggravated the reduction sticking behavior,which is attributed to the combined functions of the development of unique interwoven structure in the metallic iron interconnections at the reduction sticking interface and the deterioration of reduction swelling behavior of pellets.In addition,the strength of metallic iron interconnections enhanced and reduction sticking behavior aggravated with the increase in reduction temperature.Importantly,compared to other reduction temperatures,the reduction sticking behavior of pellets was most significantly aggravated with the increase in V_(2)O_(5) addition at 1000℃.And the values of sticking index increased from 10.22%to 15.36% as the V_(2)O_(5) addition increased from 0 to 1.00 wt.%at 1000℃.展开更多
Blast furnace data processing is prone to problems such as outliers.To overcome these problems and identify an improved method for processing blast furnace data,we conducted an in-depth study of blast furnace data.Bas...Blast furnace data processing is prone to problems such as outliers.To overcome these problems and identify an improved method for processing blast furnace data,we conducted an in-depth study of blast furnace data.Based on data samples from selected iron and steel companies,data types were classified according to different characteristics;then,appropriate methods were selected to process them in order to solve the deficiencies and outliers of the original blast furnace data.Linear interpolation was used to fill in the divided continuation data,the Knearest neighbor(KNN)algorithm was used to fill in correlation data with the internal law,and periodic statistical data were filled by the average.The error rate in the filling was low,and the fitting degree was over 85%.For the screening of outliers,corresponding indicator parameters were added according to the continuity,relevance,and periodicity of different data.Also,a variety of algorithms were used for processing.Through the analysis of screening results,a large amount of efficient information in the data was retained,and ineffective outliers were eliminated.Standardized processing of blast furnace big data as the basis of applied research on blast furnace big data can serve as an important means to improve data quality and retain data value.展开更多
The effects of SiO_(2) content on the preparation process and metallurgical properties of acid oxidized pellets, including compressive strength, reduction, and softening–melting behaviors, were systematically investi...The effects of SiO_(2) content on the preparation process and metallurgical properties of acid oxidized pellets, including compressive strength, reduction, and softening–melting behaviors, were systematically investigated.Mineralogical structures, elemental distribution, and pore size distribution were varied to analyze the mechanism of the effects.The results show that with an increase in SiO_(2) content from 3.51 wt%to 7.18 wt%, compressive strength decreases from 3150 N/pellet to 2100 N/pellet and reducibility decreases from 76.5% to 71.4%.The microstructure showed that pellets with high SiO_(2) content contained more magnetite in the mineralogical structures.Additionally, some liquid phases appeared, which hindered the continuous crystallization of hematite.Also, the softening–melting properties of the pellets clearly deteriorated as the SiO_(2) content increased.With increasing SiO_(2) content, the temperature range of the softening–melting zone decreased, and the maximum differential pressure and the comprehensive permeability index increased significantly.When acid oxidized pellets are used as the raw materials for blast furnace smelting, it should be combined with high basicity sinters to improve the softening–melting behaviors of the comprehensive charge.展开更多
As the largest steel-producing country,China’s steel industry has experienced rapid development in terms of production level and quality.Owing to the high consumption of coal in the iron and steel industry,air pollut...As the largest steel-producing country,China’s steel industry has experienced rapid development in terms of production level and quality.Owing to the high consumption of coal in the iron and steel industry,air pollutants and carbon dioxide(CO_(2))show similar emission properties in flue gas.In view of the collaborative reduction of pollution and carbon emissions,the emission standards for pollutants and carbon were first analyzed,suggesting that carbon emission standards for the iron and steel industry should be accelerated.A collaborative technology system for the reduction of pollution and carbon emissions from the iron and steel industry in China is demonstrated,consisting of(1)optimization of present ultra-low emission technology,(2)low-carbon innovation for present production processes,(3)steel production process reengineering,and(4)carbon capture,utilization,and storage(CCUS).Finally,the technical prospect for collaborative reduction of pollution and carbon emissions from the iron and steel industry in China is suggested to support high-quality green development in this industry.展开更多
The permeability index is one of the important production indicators to monitor the operation of blast furnace.It is crucial to grasp the trends of changes in the new permeability index in time.For the complex vibrati...The permeability index is one of the important production indicators to monitor the operation of blast furnace.It is crucial to grasp the trends of changes in the new permeability index in time.For the complex vibration spectrum of the permeability index,a prediction model of the permeability index based on the VMD-PSO-BP(variational mode decomposition-particle swarm optimization-back propagation)method was proposed.Firstly,the key factors that affect the permeability index of blast furnace were studied from multiple perspectives.Then,the permeability index was divided into multiple sub-modes based on the difference of frequency bands by the VMD algorithm,and a PSO-BP prediction model was established for each sub-mode.Finally,the prediction results of each sub-mode were summed to obtain the final one.The results show that the composite prediction accuracy by using the VMD algorithm is 3%higher than that of the traditional prediction method,which has better applicability.展开更多
Hydrogen-based shaft furnace process is gaining more and more attention due to its low carbon emission, and the reduction behavior of iron bearing burdens significantly affects its operation. In this work, the effects...Hydrogen-based shaft furnace process is gaining more and more attention due to its low carbon emission, and the reduction behavior of iron bearing burdens significantly affects its operation. In this work, the effects of reduction degree, temperature, and atmosphere on the swelling behavior of pellet has been studied thoroughly under typical hydrogen metallurgy conditions. The results show that the pellets swelled rapidly in the early reduction stage, then reached a maximum reduction swelling index (RSI) at approximately 40%reduction degree. The crystalline transformation of the iron oxides during the reduction process was the main reason of pellets swelling. The RSI increased significantly with increasing temperature in the range of 850-1050℃, the maximum RSI increased from 6.66%to 25.0%in the gas composition of 100%H_(2). With the temperature increased, the pellets suffered more thermal stress resulting in an increase of the volume. The maximum RSI decreased from 19.78%to 17.35%with the volume proportion of H_(2) in the atmosphere increased from 55%to 100%at the temperature of 950℃.The metallic iron tended to precipitate in a lamellar structure rather than whiskers. Consequently, the inside of the pellets became regular, so the RSI decreased. Overall, controlling a reasonable temperature and increasing the H_(2) proportion is an effective way to decrease the RSI of pellets.展开更多
18 Mn18 Cr0.5 N steel with an initial grain size of 28–177 μm was processed by 2.5%–20% cold rolling and annealing at 1000°C for 24 h,and the grain boundary character distribution was examined via electron bac...18 Mn18 Cr0.5 N steel with an initial grain size of 28–177 μm was processed by 2.5%–20% cold rolling and annealing at 1000°C for 24 h,and the grain boundary character distribution was examined via electron backscatter diffraction.Low strain(2.5%) favored the formation of low-Σ boundaries.At this strain,the fraction of low-Σ boundaries was insensitive to the initial grain size.However,specimens with fine initial grains showed decreasing grain size after grain boundary engineering processing.The fraction of low-Σ boundaries and the(Σ9 + Σ27)/Σ3 value decreased with increasing strain; furthermore,the specimens with fine initial grain size were sensitive to the strain.Finally,the effects of the initial grain size and strain on the grain boundary engineering were discussed in detail.展开更多
Ti185 alloy is widely used in key industrial fields such as aerospace due to its excellent mechanical properties.The traditional method of preparing Ti185 alloy will inevitably appear“βfleck”,resulting in the decre...Ti185 alloy is widely used in key industrial fields such as aerospace due to its excellent mechanical properties.The traditional method of preparing Ti185 alloy will inevitably appear“βfleck”,resulting in the decrease of mechanical properties,and the high price of V element limits the wide application of Ti185.In this paper,a low-cost master alloy V-Fe powder is used,a dense block is prepared by spark plasma sintering(SPS)technology,and a high-performance Ti185 alloy is prepared by controlling the sintering parameters.XRD and SEM were used to investigate the phase and microstructure of the samples prepared under different parameters.The compressive strength and friction properties of the directly prepared samples were studied.The samples with a sintering temperature of 1350 ℃ and a holding time of 30 min exhibited the most excellent comprehensive performance,with the highest compressive strength and lowest friction coefficient of 1931.59 MPa and 0.47,respectively.展开更多
The QP980-DP980 dissimilar steel joints were fabricated by fiber laser welding.The weld zone(WZ)was fully martensitic structure,and heat-affected zone(HAZ)contained newly-formed martensite and partially tempered marte...The QP980-DP980 dissimilar steel joints were fabricated by fiber laser welding.The weld zone(WZ)was fully martensitic structure,and heat-affected zone(HAZ)contained newly-formed martensite and partially tempered martensite(TM)in both steels.The supercritical HAZ of the QP980 side had higher microhardness(~549.5 Hv)than that of the WZ due to the finer martensite.A softened zone was present in HAZ of QP980 and DP980,the dropped microhardness of softened zone of the QP980 and DP980 wasΔ21.8 Hv andΔ40.9 Hv,respectively.Dislocation walls and slip bands were likely formed at the grain boundaries with the increase of strain,leading to the formation of low angle grain boundaries(LAGBs).Dislocation accumulation more easily occurred in the LAGBs than that of the HAGBs,which led to significant dislocation interaction and formation of cracks.The electron back-scattered diffraction(EBSD)results showed the fraction of LAGBs in sub-critical HAZ of DP980 side was the highest under different deformation conditions during tensile testing,resulting in the failure of joints located at the sub-critical HAZ of DP980 side.The QP980-DP980 dissimilar steel joints presented higher elongation(~11.21%)and ultimate tensile strength(~1011.53 MPa)than that of DP980-DP980 similar steel joints,because during the tensile process of the QP980-DP980 dissimilar steel joint(~8.2%and 991.38 MPa),the strain concentration firstly occurred on the excellent QP980 BM.Moreover,Erichsen cupping tests showed that the dissimilar welded joints had the lowest Erichsen value(~5.92 mm)and the peak punch force(~28.4 kN)due to the presence of large amount of brittle martensite in WZ and inhomogeneous deformation.展开更多
The iron and steel industry is not only an important foundation of the national economy,but also the largest source of industrial air pollution.Due to the current status of emissions in the iron and steel industry,ult...The iron and steel industry is not only an important foundation of the national economy,but also the largest source of industrial air pollution.Due to the current status of emissions in the iron and steel industry,ultra-low pollutant emission control technology has been researched and developed.Liquid-phase proportion control technology has been developed for magnesian fluxed pellets,and a blast furnace smelting demonstration project has been established to use a high proportion of fluxed pellets(80%)for the first time in China to realize source emission reduction of SO_(2)and NO_(x).Based on the characteristics of high NO_(x)concentrations and the coexistence of multiple pollutants in coke oven flue gas,low-NO_(x)combustion coupled with multi-pollutant cooperative control technology with activated carbon was developed to achieve efficient removal of multiple pollutants and resource utilization of sulfur.Based on the characteristics of co-existing multiple pollutants in pellet flue gas,selective non-catalytic reduction(SNCR)coupled with ozone oxidation and spray drying adsorption(SDA)was developed,which significantly reduces the operating cost of the system.In the light of the high humidity and high alkalinity in flue gas,filter materials with high humidity resistance and corrosion resistance were manufactured,and an integrated pre-charged bag dust collector device was developed,which realized ultralow emission of fine particles and reduced filtration resistance and energy consumption in the system.Through source emission reduction,process control and end-treatment technologies,five demonstration projects were built,providing a full set of technical solutions for ultra-low emissions of dust,SO_(2),NO_(x),SO_(3),mercury and other pollutants,and offering technical support for the green development of the iron and steel industry.展开更多
Based on traditional twin-roll casting process,Invar/Cu clad strips were successfully fabricated by using solid Invar alloy strip and molten Cu under conditions of high temperature,high pressure and plastic deformatio...Based on traditional twin-roll casting process,Invar/Cu clad strips were successfully fabricated by using solid Invar alloy strip and molten Cu under conditions of high temperature,high pressure and plastic deformation.A series of tests including tensile test,bending test,T-type peeling test and scanning electron microscope(SEM)and energy dispersive spectrometer(EDS)measurements were carried out to analyze the mechanical properties of Invar/Cu clad strips and the micro-morphology of tensile fracture surfaces and bonding interfaces.The results indicate that no delamination phenomenon occurs during the compatible deformation of Invar/Cu in bending test and only one stress platform exists in the tensile stress-strain curve when the bonding strength is large.On the contrary,different mechanical properties of Invar and Cu lead to delamination phenomenon during the uniaxial tensile test,which determines that two stress platforms occur on the stress-strain curve of Invar/Cu clad strips when two elements experience necking.The average peeling strength can be increased from13.85to42.31N/mm after heat treatment at800℃for1h,and the observation of the Cu side at peeling interface shows that more Fe is adhered on the Cu side after the heat treatment.All above illustrate that heat treatment can improve the strength of the bonding interface of Invar/Cu clad strips.展开更多
基金supported by the National Natural Science Foundation of China(Nos.52174311 and 51974020).
文摘The mechanism of strength and toughness variation in Ti microalloyed steel within the range of 0.04–0.157 wt.%was investigated.By adding 0.13 wt.%Ti,the steel achieves higher strength while maintaining a certain level of elongation and low-temperature impact toughness.With increasing Ti content,the grain size in the steel decreased from 17.7 to 8.9μm.This decrease in grain size is accompanied by an increase in the percentage of low-angle grain boundaries and dislocations,which act as barriers to hinder crack propagation.The Ti microalloyed steel exhibits a 20%increase in yield strength and a 14%increase in tensile strength.The transformation of steel plasticity occurs when the Ti content exceeds 0.102 wt.%.The low-temperature impact toughness of the steel gradually decreases with increasing Ti content.At low Ti content,the low-temperature impact toughness is reduced due to crack initiation by large-size inclusions.At high Ti content,the low-temperature impact toughness of the steel deteriorates due to several factors.These include the narrower tough–brittle transition zone,grain boundary embrittlement caused by small-sized grains,and the decrease in the solid solution strengthening effect.
基金financially supported by the National Key Research and Development Program of China(Grant No.2023YFB3710204)Guangxi Science and Technology Major Program(Grant No.AA23023028-1)+1 种基金Natural Science Foundation of Heilongjiang Province of China for Distinguished Young Scientists(Grant No.JQ2022E007)Xinjiang Production and Construction Corps Science and Technology Plan(Grant No.2023AA003).
文摘Accurate crown control is paramount for ensuring the quality of hot-rolled strip products.Given the multitude of influencing parameters and the intricate coupling and genetic relationships among them,the conventional crown control method is no longer sufficient to meet the precision requirements of schedule-free rolling.To address this limitation,an optimization framework for hot-rolled strip crown control was developed based on model-driven digital twin(MDDT).This framework enhances the strip crown control precision by facilitating collaborative operations among physical entities,virtual models,and functional application layers.In virtual modeling,a data-driven approach that integrates the extreme gradient boosting and the improved Harris hawk optimization algorithm was firstly proposed to fit the relationship between key process parameters and strip crown,and a global-local collaborative training strategy was proposed to enhance the model adaptability to diverse working conditions.Subsequently,the influence of crucial process factors on the virtual model was examined through model responses.Furthermore,a novel optimization mode for crown control based on MDDT was established by aligning and reconstructing both the physical and virtual models,thereby enhancing the crown control precision.Finally,data trials were conducted to validate the effectiveness of the proposed framework.The results indicated that the proposed method exhibited satisfactory performance and could be effectively utilized to improve the crown control precision.
基金supported by the Shanxi Provincial Basic Research Program(No.202403021221046)the National Natural Science Foundation of China(Nos.52004180 and 52204350)+5 种基金the China Postdoctoral Science Foundation(No.2020M683706XB)the Research Project Supported by Shanxi Scholarship Council of China(No.2023-080)the Fund Projects for the Central Government to Guide the Development of Local Science and Technology(No.236Z1023G)the Hebei Province High-level Talent Funding Project(No.B20231016)the National College Student Innovation and Entrepreneurship Training Program(No.202410112116)the Graduate Student Scientific Research Innovation Program(No.2024KY278).
文摘Invar steels possess excellent thermal expansion properties,making them suitable as materials for manufacturing precision instruments.However,conventional invar steels lack sufficient strength for engineering applications,and various strengthening methods are urgently needed to enhance their strength.In this work,the possibility of enhancing the strength and maintaining low coefficient of thermal expansion(CTE)of the steel through mechanical heat treatment and the introduction of vanadium carbonitride is demonstrated.V-N microalloying and various heat treatment processes enable invar steel to enhance its strength while maintaining low thermal expansion properties.The strength of low-nitrogen addition invar steel measured 593 MPa during direct aging,representing a 44.6% increase compared to invar steel.After undergoing cold-deformation aging,the strength of low-nitrogen invar steel increased to 790 MPa,indicating a substantial improvement in strength relative to the direct aging condition.Notably,the coefficient of thermal expansion remained at 0.98×10^(-6)℃^(-1).By further increasing N content to introduce more vanadium carbonitride,the strength of high-nitrogen invar steel reached 927 MPa under cold-deformation process while maintaining a low CTE value of 1.02×10^(-6)℃^(-1).This achieved an extraordinary balance of high strength and low CTE,which is due to a well combination of various strengthening mechanisms,especially the Orowan strengthening where dislocations continuously bypass vanadium carbonitride to achieve the strengthening effect.The resulting findings are important for future preparation of excellent properties invar steel in industrial applications.
基金support of the National Natural Science Foundation of China(No.52171063).
文摘A series of Sn microalloying high-strength low-alloy(HSLA)steels were prepared through vacuum melting and hot rolling.Their stress corrosion cracking(SCC)behavior under high Cl^(−)environments was investigated using U-bend immersion,slow strain rate testing,electrochemical methods,and novel SCC sensor.Results revealed that HSLA steel microalloying with 0.1 wt.%Sn demonstrated superior SCC resistance,primarily attributed to the effective inhibition of the anodic dissolution mechanism.Fracture morphology revealed a transformation in fracture mode from brittle to a mixture of brittle-ductile characteristics,accompanied by the formation of a protective SnO_(2)oxide film on the steel surface.However,excessive Sn content exacerbated SCC susceptibility due to the increased hydrolysis of Sn^(2+),leading to localized pitting and crack initiation.The critical role of optimal Sn content was highlighted in balancing mechanical properties and corrosion resistance,suggesting potential applications in industries where materials face harsh chloride environments.
基金supported by the National Natural Science Foundation of China(No.52100133,No.52222005)the Key R&D Program of Yunnan Province(No.202303AC100008)。
文摘Catalyst-aided regeneration is a promising method for reducing the high regeneration energy consumption of amine-based CO_(2)capture technologies.However,the intrinsic relationship between the properties of the acidic sites and their catalytic activity is controversial.In this study,a series of W-based catalysts supported by ZrTiO_(x)were synthesised,and the effects of the intensity,distribution,and type of acid sites were systematically investigated by quantitatively regulating the acidic site properties.The results indicate stronger acidic sites play a more important role in the catalytic reaction.Moreover,the catalysts showed excellent performance only if the Br?nsted acid sites(BASs)and Lewis acid sites(LASs)coexisted.During the catalytic reaction,the BASs facilitated deprotonation,and the LASs promoted the decomposition of carbamates.The ratio of BASs to LASs(B/L)was a critical factor for catalytic activity,wherein optimal performance was achieved when the B/L ratio was close to 1.The 10%HPW/ZrTiO_(x)composite performed better than WO_(3)/ZrTiO_(x)and HSiW/ZrTiO_(x)because it had a stronger acid intensity and a suitable B/L ratio.As a result,the relative heat duty was reduced by 47%compared to 30%aqueous MEA,and the maximum CO_(2)desorption rate was increased by 83%.The Bader charge indicated that the W atoms of HPW/ZrTiO_(x)lost more electrons(0.18)than those of WO_(3)/ZrTiO_(x),which can weaken the O±H bond energy.Consequently,the calculated deprotonation energy is as low as 257 kJ mol^(-1)for HPW/ZrTiO_(x).
基金the support the National Natural Science Foundation of China(5210440)S&T Program of Hebei(23311501D)Program of HBIS Group under HG2023222。
文摘In this study,a cleaner method for separation and recovery of V/W/Na in waste selective catalytic reduction(SCR)catalyst alkaline leaching solution was proposed.The method involved membrane electrolysis followed by ion morphology pretreatme nt and solvent extraction.An acidic V(Ⅴ)/W(Ⅵ)solution was obtained using the me mbrane electrolysis method without adding any other chemical reagents.In addition,Na was recovered in the form of NaOH by product,avoiding the generation of Na containing wastewater.The electrolysis parameters were investigated,the lowest power consumption of 3063 kW·h·t^(-1)NaOH was obtained at a current density of 125 A·m^(-2)and an initial NaOH concentration of 2 mol·L^(-1).After electrolysis,oxalic acid was added to the acidic V/W containing solution,converting V(Ⅴ)negative ion to V(Ⅳ)positive ion.Since W(Ⅵ)ion state remained in negative form,the generation of heteropolyacid ions(W_(x)V_(y)O_(z)^(n-))was prevented.It was found that under the condition of oxalic acid addition/theoretical consumption 1.2 and reaction temperature 75℃,100%V(Ⅴ)was co nverted to V(Ⅳ4).Using 10%N263+10%noctanol+80%sulfonated kerosene as extractant,the highest W(Ⅵ)/V(Ⅳ)separation coefficient of 7559.76was obtained at pH=1.8,O:A ratio=1:1 and extraction time 15 min.With 2 mol·L^(-1)NaOH as stripping reagent,the W stripping efficiency reached 98.50%at O:A ratio=2:1 after 4-stages of stripping.The enrichment of V remained in the solution was realized using P204 as extractant and 20%(mass)H_(2)SO_(4)as stripping reagent.The parameters of extraction/stripping process were investigated,using 10%P204+10%TBP+80%sulfonated kerosene as extractant,the V extraction efficiency reached 97.50%at O:A ratio=1:2after 4 stages of extraction.Using 20%H_(2)SO_(4)as the stripping reagent,the V stripping efficiency was 98.30%at an O:A ratio of 4:1 after five stage s of stripping.After the entire process,a high-purity VOSO_(4)and Na_(2)WO_(4)product solutions were obtained with V/W recovery efficiency 95.84%/98.50%,separately.This study examined a more effective and cleaner method for separating V/W/Na in Na_(2)WO_(4)/NaVO_(3)solution,which may serve as a reference for the separation and recovery of V/W/Na in waste SCR catalysts.
基金supported by HBIS Group under the Grant No.IRIS 200506003.
文摘Different stress states have a significant influence on the magnitude of the microscopic plastic strain and result in the development of the microstructure evolution.As a result,a comprehensive understanding of the different scale variation on microstructure evolution during bending deformation is essential.The advanced high strength dual-phase(DP1180)steel was investigated using multiscale microstructure-based 3D representative volume element(RVE)modelling technology with emphasis on understanding the relationship between the microstructure,localised stress-strain evolution as well as the deformation characteristics in the bending process.It is demonstrated that the localised development in bending can be more accurately described by microscopic deformation when taking into account microstructural properties.Microstructure-based 3D RVEs from each chosen bending condition generally have comparable localisation properties,whilst the magnitudes and intensities differ.In addition,the most severe localised bands are predicted to occur close to the ferrite and martensite phase boundaries where the martensite grains are close together or have a somewhat sharp edge.The numerically predicted results for the microstructure evolution,shear bands development and stress and strain distribution after 3-point bending exhibit a good agreement with the relevant experimental observations.
基金supported by the Key Research and Development Program of Hebei Province(No.21373702D)the Key Science and Technology Program of HBIS Group Co.,Ltd.(No.HG2021117)+1 种基金the National Natural Science Foundation of China(No.52370124)the National Key R&D Program of China(No.2023YFC3707003).
文摘About 70%of the flue gas in the iron-steel industry has achieved multi-pollutant ultra-low emissions in China until 2023,and then the blast furnace gas purification has become the control step and bottleneck.Our research group has designed and constructed the world’s first blast furnace gas desulfurization pilot plant with the scale of 2000 Nm^(3)/h in October 2021.The pilot plant is a two-step combined desulfurization device including catalytic hydrolysis of carbonyl sulfur(COS)and absorption-oxidation of H_(2)S,continuously running for 120 days.In the hydrolysis system,one reason for catalyst deactivation has been verified from the sulfur deposition.HCN in blast furnace gas can be hydrolyzed on the hydrolysis catalyst to produce the nitrogen deposition,which is one of the reasons for catalyst deactivation and has never been found in previous studies.The deposition forms of S and N elements are determined,S element forms elemental sulfur and sulfate,while N element forms-NH_(2)and NH_(4)^(+).In the absorption-oxidation system,the O_(2)loading and the residence time have been optimized to control the oxidation of HS^(−)to produce elemental sulfur instead of by-product S_(2)O_(3)^(2−).The balance and distribution of S and N elements have been calculated for thewholemulti-phase system,approximately 84.4%of the sulfur is converted to solid sulfur product,about 1.3%of the sulfur and 19.2%of N element are deposited on the hydrolysis catalyst.The pilot plant provides technical support formulti-pollutant control of blast furnace.
基金the financial supports from the National Natural Science Foundation of China(52004096)Natural Science Foundation of Hebei Province(E2024209101)+2 种基金Hebei Province Science and Technology R&D Platform Construction Project(23560301D)Tangshan Science and Technology Bureau Project(23130202E)Graduate Student Innovation Fund of North China University of Science and Technology(CXZZBS2025150).
文摘In the traditional blast furnace(BF)ironmaking process in China,a notable deviation exists between the theoretical and actual yield of hot metal,leading to unexpected iron loss and restricting the improvement of production capacity,which cannot adapt to the increasingly intensified smelting rhythm.Focusing on a BF in a Chinese steel enterprise,a deep neural network algorithm was designed to model the impact of multiple parameters on actual yield of hot metal in a single BF smelting cycle,successfully accomplishing the theoretical computation and real-time prediction of yield of hot metal for subsequent,unknown BF smelting cycle.Test results show that the proposed algorithm demonstrates an impressive prediction accuracy of 86.7% within an error range of±10 t and can swiftly complete the training and convergence process in 32.5 s.By integrating prediction results with Nomogram,a regulatory mechanism was engineered to minimize the deviation between theoretical and actual yield of hot metal.This mechanism ensures the yield enhancement of hot metal through dynamic adjustments of BF operational parameters.Industrial-scale application experiments confirmed that the intelligent operation and optimization system,developed in the laboratory,can maintain the yield deviation of hot metal within a stable range of 30 t,achieving a maximum reduction in iron loss rate of 17.65%compared to that before system operation.The findings provide robust support for the yield increase and efficiency improvement of the experimental BF.
基金supported by the authors are especially grateful to the National Natural Science Foundation of China(Grant No.51904063)the Key Program of National Natural Science Foundation of China(No.U23A20608)+6 种基金Fundamental Research Funds for the Central Universities(N2025023,N2225046)Postdoctoral Followship Program of CPSF(GZC20230392)Science&Technology Plan Project of Liaoning Province(2022JH24/10200027)Science&Technology Plan Project of Hebei Province(23314601L)Science and Technology Program of Liaoning of China(2023JH2/101700304)China Postdoctoral Science Foundation(2023M740551)Liaoning Province Science and Technology Plan Joint Program(Key Research and Development Program Project)(2023JH2/101800058).
文摘The sticking behavior of pellets affects the continuity of production in hydrogen-based shaft furnace.The coupling influences of V_(2)O_(5) and reduction temperature on reduction sticking behavior and mechanism evolution of pellets under hydrogen atmosphere are investigated.The increase in V_(2)O_(5) addition aggravated the reduction sticking behavior,which is attributed to the combined functions of the development of unique interwoven structure in the metallic iron interconnections at the reduction sticking interface and the deterioration of reduction swelling behavior of pellets.In addition,the strength of metallic iron interconnections enhanced and reduction sticking behavior aggravated with the increase in reduction temperature.Importantly,compared to other reduction temperatures,the reduction sticking behavior of pellets was most significantly aggravated with the increase in V_(2)O_(5) addition at 1000℃.And the values of sticking index increased from 10.22%to 15.36% as the V_(2)O_(5) addition increased from 0 to 1.00 wt.%at 1000℃.
基金This work is financially supported by the National Nature Science Foundation of China(No.52004096)the Hebei Province High-End Iron and Steel Metallurgical Joint Research Fund Project,China(No.E2019209314)+1 种基金the Scientific Research Program Project of Hebei Education Department,China(No.QN2019200)the Tangshan Science and Technology Planning Project,China(No.19150241E).
文摘Blast furnace data processing is prone to problems such as outliers.To overcome these problems and identify an improved method for processing blast furnace data,we conducted an in-depth study of blast furnace data.Based on data samples from selected iron and steel companies,data types were classified according to different characteristics;then,appropriate methods were selected to process them in order to solve the deficiencies and outliers of the original blast furnace data.Linear interpolation was used to fill in the divided continuation data,the Knearest neighbor(KNN)algorithm was used to fill in correlation data with the internal law,and periodic statistical data were filled by the average.The error rate in the filling was low,and the fitting degree was over 85%.For the screening of outliers,corresponding indicator parameters were added according to the continuity,relevance,and periodicity of different data.Also,a variety of algorithms were used for processing.Through the analysis of screening results,a large amount of efficient information in the data was retained,and ineffective outliers were eliminated.Standardized processing of blast furnace big data as the basis of applied research on blast furnace big data can serve as an important means to improve data quality and retain data value.
基金financially supported by the Key Program of the National Natural Science Foundation of China (No.U1360205)the Natural Science Foundation of Hebei Province of China (No.E2019209424)。
文摘The effects of SiO_(2) content on the preparation process and metallurgical properties of acid oxidized pellets, including compressive strength, reduction, and softening–melting behaviors, were systematically investigated.Mineralogical structures, elemental distribution, and pore size distribution were varied to analyze the mechanism of the effects.The results show that with an increase in SiO_(2) content from 3.51 wt%to 7.18 wt%, compressive strength decreases from 3150 N/pellet to 2100 N/pellet and reducibility decreases from 76.5% to 71.4%.The microstructure showed that pellets with high SiO_(2) content contained more magnetite in the mineralogical structures.Additionally, some liquid phases appeared, which hindered the continuous crystallization of hematite.Also, the softening–melting properties of the pellets clearly deteriorated as the SiO_(2) content increased.With increasing SiO_(2) content, the temperature range of the softening–melting zone decreased, and the maximum differential pressure and the comprehensive permeability index increased significantly.When acid oxidized pellets are used as the raw materials for blast furnace smelting, it should be combined with high basicity sinters to improve the softening–melting behaviors of the comprehensive charge.
基金supported by the National Natural Science Foundation of China(52230002 and 52170118)the Key Research and Development Program of Hebei Province(22373701D)the"Clean Combustion and Low-carbon Utilization of Coal,"Strategic Priority Research Program of the Chinese Academy of Sciences(XDA 29000000)。
文摘As the largest steel-producing country,China’s steel industry has experienced rapid development in terms of production level and quality.Owing to the high consumption of coal in the iron and steel industry,air pollutants and carbon dioxide(CO_(2))show similar emission properties in flue gas.In view of the collaborative reduction of pollution and carbon emissions,the emission standards for pollutants and carbon were first analyzed,suggesting that carbon emission standards for the iron and steel industry should be accelerated.A collaborative technology system for the reduction of pollution and carbon emissions from the iron and steel industry in China is demonstrated,consisting of(1)optimization of present ultra-low emission technology,(2)low-carbon innovation for present production processes,(3)steel production process reengineering,and(4)carbon capture,utilization,and storage(CCUS).Finally,the technical prospect for collaborative reduction of pollution and carbon emissions from the iron and steel industry in China is suggested to support high-quality green development in this industry.
基金supports from the National Natural Science Foundation of China Youth Fund Project(52004096).
文摘The permeability index is one of the important production indicators to monitor the operation of blast furnace.It is crucial to grasp the trends of changes in the new permeability index in time.For the complex vibration spectrum of the permeability index,a prediction model of the permeability index based on the VMD-PSO-BP(variational mode decomposition-particle swarm optimization-back propagation)method was proposed.Firstly,the key factors that affect the permeability index of blast furnace were studied from multiple perspectives.Then,the permeability index was divided into multiple sub-modes based on the difference of frequency bands by the VMD algorithm,and a PSO-BP prediction model was established for each sub-mode.Finally,the prediction results of each sub-mode were summed to obtain the final one.The results show that the composite prediction accuracy by using the VMD algorithm is 3%higher than that of the traditional prediction method,which has better applicability.
基金financially supported by the National Natural Science Foundation of China (No.51904063)the China Postdoctoral Science Foundation (No.2018M640259)+2 种基金the Fundamental Research Funds for the Central Universities(No.N2025023)the Key research and development project of Hebei Province (No.21314001D)the Plan of Xingliao Talents,China (No.XLYC1902118)。
文摘Hydrogen-based shaft furnace process is gaining more and more attention due to its low carbon emission, and the reduction behavior of iron bearing burdens significantly affects its operation. In this work, the effects of reduction degree, temperature, and atmosphere on the swelling behavior of pellet has been studied thoroughly under typical hydrogen metallurgy conditions. The results show that the pellets swelled rapidly in the early reduction stage, then reached a maximum reduction swelling index (RSI) at approximately 40%reduction degree. The crystalline transformation of the iron oxides during the reduction process was the main reason of pellets swelling. The RSI increased significantly with increasing temperature in the range of 850-1050℃, the maximum RSI increased from 6.66%to 25.0%in the gas composition of 100%H_(2). With the temperature increased, the pellets suffered more thermal stress resulting in an increase of the volume. The maximum RSI decreased from 19.78%to 17.35%with the volume proportion of H_(2) in the atmosphere increased from 55%to 100%at the temperature of 950℃.The metallic iron tended to precipitate in a lamellar structure rather than whiskers. Consequently, the inside of the pellets became regular, so the RSI decreased. Overall, controlling a reasonable temperature and increasing the H_(2) proportion is an effective way to decrease the RSI of pellets.
基金financially supported by the National Natural Science Foundation of China (No.51505416)the Natural Science Foundation-Steel and Iron Foundation of Hebei Province,China (No.E2017203041)+1 种基金the Natural Science Foundation of Hebei Province,China (No.E2016203436)the Post-Doctoral Research Project of Hebei Province,China (No.B2016003029)
文摘18 Mn18 Cr0.5 N steel with an initial grain size of 28–177 μm was processed by 2.5%–20% cold rolling and annealing at 1000°C for 24 h,and the grain boundary character distribution was examined via electron backscatter diffraction.Low strain(2.5%) favored the formation of low-Σ boundaries.At this strain,the fraction of low-Σ boundaries was insensitive to the initial grain size.However,specimens with fine initial grains showed decreasing grain size after grain boundary engineering processing.The fraction of low-Σ boundaries and the(Σ9 + Σ27)/Σ3 value decreased with increasing strain; furthermore,the specimens with fine initial grain size were sensitive to the strain.Finally,the effects of the initial grain size and strain on the grain boundary engineering were discussed in detail.
基金Projects(51671152,51874225)supported by the National Natural Science Foundation of ChinaProject(2020ZDLGY13-10)supported by Shaanxi Provincial Science and Technology,China。
文摘Ti185 alloy is widely used in key industrial fields such as aerospace due to its excellent mechanical properties.The traditional method of preparing Ti185 alloy will inevitably appear“βfleck”,resulting in the decrease of mechanical properties,and the high price of V element limits the wide application of Ti185.In this paper,a low-cost master alloy V-Fe powder is used,a dense block is prepared by spark plasma sintering(SPS)technology,and a high-performance Ti185 alloy is prepared by controlling the sintering parameters.XRD and SEM were used to investigate the phase and microstructure of the samples prepared under different parameters.The compressive strength and friction properties of the directly prepared samples were studied.The samples with a sintering temperature of 1350 ℃ and a holding time of 30 min exhibited the most excellent comprehensive performance,with the highest compressive strength and lowest friction coefficient of 1931.59 MPa and 0.47,respectively.
基金Supported by National Natural Science Foundation of China(Grant Nos.51871010,51875129)Beijing Municipal Natural Science Foundation of China(Grant No.32020163212008).
文摘The QP980-DP980 dissimilar steel joints were fabricated by fiber laser welding.The weld zone(WZ)was fully martensitic structure,and heat-affected zone(HAZ)contained newly-formed martensite and partially tempered martensite(TM)in both steels.The supercritical HAZ of the QP980 side had higher microhardness(~549.5 Hv)than that of the WZ due to the finer martensite.A softened zone was present in HAZ of QP980 and DP980,the dropped microhardness of softened zone of the QP980 and DP980 wasΔ21.8 Hv andΔ40.9 Hv,respectively.Dislocation walls and slip bands were likely formed at the grain boundaries with the increase of strain,leading to the formation of low angle grain boundaries(LAGBs).Dislocation accumulation more easily occurred in the LAGBs than that of the HAGBs,which led to significant dislocation interaction and formation of cracks.The electron back-scattered diffraction(EBSD)results showed the fraction of LAGBs in sub-critical HAZ of DP980 side was the highest under different deformation conditions during tensile testing,resulting in the failure of joints located at the sub-critical HAZ of DP980 side.The QP980-DP980 dissimilar steel joints presented higher elongation(~11.21%)and ultimate tensile strength(~1011.53 MPa)than that of DP980-DP980 similar steel joints,because during the tensile process of the QP980-DP980 dissimilar steel joint(~8.2%and 991.38 MPa),the strain concentration firstly occurred on the excellent QP980 BM.Moreover,Erichsen cupping tests showed that the dissimilar welded joints had the lowest Erichsen value(~5.92 mm)and the peak punch force(~28.4 kN)due to the presence of large amount of brittle martensite in WZ and inhomogeneous deformation.
基金supported by the National Key R&D Program of China(Nos.2017YFC0210600 and 2019YFC0214803)。
文摘The iron and steel industry is not only an important foundation of the national economy,but also the largest source of industrial air pollution.Due to the current status of emissions in the iron and steel industry,ultra-low pollutant emission control technology has been researched and developed.Liquid-phase proportion control technology has been developed for magnesian fluxed pellets,and a blast furnace smelting demonstration project has been established to use a high proportion of fluxed pellets(80%)for the first time in China to realize source emission reduction of SO_(2)and NO_(x).Based on the characteristics of high NO_(x)concentrations and the coexistence of multiple pollutants in coke oven flue gas,low-NO_(x)combustion coupled with multi-pollutant cooperative control technology with activated carbon was developed to achieve efficient removal of multiple pollutants and resource utilization of sulfur.Based on the characteristics of co-existing multiple pollutants in pellet flue gas,selective non-catalytic reduction(SNCR)coupled with ozone oxidation and spray drying adsorption(SDA)was developed,which significantly reduces the operating cost of the system.In the light of the high humidity and high alkalinity in flue gas,filter materials with high humidity resistance and corrosion resistance were manufactured,and an integrated pre-charged bag dust collector device was developed,which realized ultralow emission of fine particles and reduced filtration resistance and energy consumption in the system.Through source emission reduction,process control and end-treatment technologies,five demonstration projects were built,providing a full set of technical solutions for ultra-low emissions of dust,SO_(2),NO_(x),SO_(3),mercury and other pollutants,and offering technical support for the green development of the iron and steel industry.
基金Project (51474189) supported by the National Natural Science Foundation of ChinaProject (E2018203446) supported by the Excellent Youth Foundation of Hebei Scientific Committee,ChinaProject (QN2015214) supported by the Educational Commission of Hebei Province,China
文摘Based on traditional twin-roll casting process,Invar/Cu clad strips were successfully fabricated by using solid Invar alloy strip and molten Cu under conditions of high temperature,high pressure and plastic deformation.A series of tests including tensile test,bending test,T-type peeling test and scanning electron microscope(SEM)and energy dispersive spectrometer(EDS)measurements were carried out to analyze the mechanical properties of Invar/Cu clad strips and the micro-morphology of tensile fracture surfaces and bonding interfaces.The results indicate that no delamination phenomenon occurs during the compatible deformation of Invar/Cu in bending test and only one stress platform exists in the tensile stress-strain curve when the bonding strength is large.On the contrary,different mechanical properties of Invar and Cu lead to delamination phenomenon during the uniaxial tensile test,which determines that two stress platforms occur on the stress-strain curve of Invar/Cu clad strips when two elements experience necking.The average peeling strength can be increased from13.85to42.31N/mm after heat treatment at800℃for1h,and the observation of the Cu side at peeling interface shows that more Fe is adhered on the Cu side after the heat treatment.All above illustrate that heat treatment can improve the strength of the bonding interface of Invar/Cu clad strips.
