The Bayinqinggeli deposit in the northern Ordos Basin, northwestern of China, is a recently discovered sandstone-type uranium deposit. The uranium(U) orebodies are generally hosted in the lower member of the Jurassic ...The Bayinqinggeli deposit in the northern Ordos Basin, northwestern of China, is a recently discovered sandstone-type uranium deposit. The uranium(U) orebodies are generally hosted in the lower member of the Jurassic Zhiluo Formation(Fm.), and are primarily tabular or irregular in shape. In the study area, 23 sandstone samples were collected from the Zhiluo Fm. and analyzed for major, trace, and rare earth elements(REEs). The geochemical characteristics of these sandstones are used to evaluate the factors controlling U mineralization. The source rocks of the Zhiluo Fm. sandstones are mainly volcanic and felsic magmatic rocks formed in continental arc and active continentalmarginal arc environments, and they provided the material required for the mineralization. The index of compositional variability ranges from 1.02 to 3.29(average1.38), indicating that the Zhiluo Fm. sandstones are immature and composed of first-cycle sediments. The corrected chemical index of alteration averages 56, suggesting that the source rocks underwent weak chemical weathering. The ore host rocks are loose, providing favorable conditions for epigenetic oxidation and U precipitation and enrichment. Ferrous iron in minerals such as chlorite, biotite, ilmenite, and pyrite might have played a role either in adsorbing or reducing the uranium.展开更多
The northwestern margin of Junggar Basin is the region with the richest oil sand resources in China.For better understanding the enrichment rules and deployment of exploration and development of regional oil sand,it i...The northwestern margin of Junggar Basin is the region with the richest oil sand resources in China.For better understanding the enrichment rules and deployment of exploration and development of regional oil sand,it is of great scientific significance to study the accumulation conditions of oil sand in different strata and mining areas of the Junggar Basin.Through a large number of field investigations,drilling verification and sampling tests,it is found that the oil sand in the region covers an area of 2000 km^(2),with shallow and thick reservoir,and predicted resource of 180 million tons.The oil sand resources are mainly distributed in four geological strata,namely the Middle Triassic Karamay Formation,Early Jurassic Badaowan Formation,Late Jurassic Qigu Formation,and Early Cretaceous Qingshuihe Formation.The reservoir is mainly composed of sandstone with high porosity and permeability,and the reservoir space is mainly intergranular pores with a medium average oil content.The oil sand deposit in the region is a typical destructive oil reservoir.The crude oil in the oil sand layer is degraded and thickened from the deep to the shallow,the content of saturated hydrocarbon decreased,and the content of aromatic hydrocarbon,non-hydrocarbon and asphaltene increased.The oil source comes from the deep Permian hydrocarbon-generating depression.Unconformities,faults and marginal fan delta-braided river depositional systems constitute effective migration and storage systems.Caprocks of the Upper Triassic Baijiantan Formation,Lower Jurassic Sangonghe Formation and Lower Cretaceous Hutubihe Formation were formed by three large scale lake transgressions.The Indosinian,Yanshan and Late Yanshan movements are the main driving forces for the migration of deep oil and gas to the shallow edge to form oil sand deposits.It is considered that the oil sand in the northwestern margin of Junggar Basin is of a slope complex migration type.展开更多
Multiple instances of the Late Cretaceous granodiorites within the Anglonggangri region of the northwestern Lhasa Block were identified,their petrogenesis were explored and mineralization potential were assessed.The z...Multiple instances of the Late Cretaceous granodiorites within the Anglonggangri region of the northwestern Lhasa Block were identified,their petrogenesis were explored and mineralization potential were assessed.The zircon U-Pb dating of the Anglonggangri granodiorites revealed ages of 82.8 and 80.8 Ma.Granodiorite samples have SiO2 contents of 64.36-68.33 wt%,with high Sr/Y(55-95)and A/CNK ratios(0.99-1.06).Zirconε_(Hf)(t)values range from−0.3 to+16.2.Two granodiorite samples have(^(87)Sr/^(86)Sr)i values of 0.7034 and 0.7043 and positiveɛNd(t)values of 3.51 and 3.83.These geochemical properties indicate that they are adakitic rocks formed by partial melting of the juvenile thickened lower crust,slightly contaminated with material from the mantle due to the small-scale delamination of the lower crust.The zircons in the granodiorites have moderate Ce/Nd(2.5-43),logfO2(−20.0 to−9.6),andΔFMQ(−1.28 to+4.00)values;low(Ce/Nd)/Y(0.001-0.049)ratios;and high Dy/Yb(0.17-1.16)ratios,which indicate that these granodiorites exhibit moderate oxygen fugacity and lower magma water content than the Miocene Gangdese porphyry copper deposits associated with high-Sr/Y granites.Their ability to create porphyry-type copper deposits could have been hampered by their low magma water content and moderate oxygen fugacity.展开更多
Outcrop and drill hole data show that the Jurassic coal measures in the northeastern Ordos Basin are composed mainly of the Yan’an Formation and the lowstand system tract of the Zhiluo Formation,and there is a region...Outcrop and drill hole data show that the Jurassic coal measures in the northeastern Ordos Basin are composed mainly of the Yan’an Formation and the lowstand system tract of the Zhiluo Formation,and there is a regional unconformity between them.The Dongsheng uranium deposit is associated with the Jurassic coal measures.Research data indicate that the Jurassic coal measures in the study area have a certain hydrocarbon-generating capacity,although the metamorphic grade is low(Ro=0.40%–0.58%).In the Dongsheng region alone,the accumulative amount of generated coalbed methane(CBM)is about 2028.29×108–2218.72×108 m3;the residual amount is about 50.92×108 m3,and the lost amount is about 1977×108 m3.Analysis of the burial history of the host rocks and the evolutionary history of the Dongsheng uranium deposit suggests that the Jurassic coal measures generated hydrocarbon mainly from Middle Jurassic to Early Crataceous,which is the main mineralization phase of the Dongsheng uranium deposit.By the Late Cretaceous,a mass of CBM dissipated due to the strong tectonic uplift,and the Dongsheng uranium deposit stepped into the preservation phase.Therefore,the low-mature hydrocarbon-containing fluid in the Jurassic coal measures not only served as a reducing agent for the formation of sandstone-type uranium deposits,but also rendered the second reduction of paleo-interlayer oxidation zone and become the primary reducing agent for ore conservation.Regional strata correlation reveals that the sandstone-type uranium reservoir at the bottom of the Zhiluo Formation is in contact with the underlying industrial coal seams in the Yan’an Formation through incision or in the form of an unconformity surface.In the Dongsheng region with poorly developed fault systems,the unconformity surface and scour surface served as the main migration pathways for low-mature hydrocarbon-containing fluid migrating to the uranium reservoir.展开更多
The Jinding superlarge lead and zinc deposit has attracted the attention of geologists of the world and its metallogenesis has long been in dispute. This paper takes the Jinding deposit and the Baiyangping Cu-Ag-Co de...The Jinding superlarge lead and zinc deposit has attracted the attention of geologists of the world and its metallogenesis has long been in dispute. This paper takes the Jinding deposit and the Baiyangping Cu-Ag-Co deposit which was recently found at about 30 km north of Jinding as one ore belt, and, based on researches on the helium, argon, and xenon isotopic compositions of primary inclusions in ore-forming solutions of the main stage, the authors have found that the 3He/4He ratio of the ore-forming fluid is 2.7×10?6 (varying from 0.19 to 1.97 Ra), the 4He/40Ar ratio (0.24–3.12) is close to the mantle characteristic ratio, and the xenon isotopic composition and evolution show characters of the mantle xenon. The above results reveal the characteristics of mantle source and crust-mantle fluid mixing (mantle helium reaching 32%) and the metallogenic contributions of the deep processes in the Jinding-Baiyangping ore belt.展开更多
The Shitoukengde Ni-Cu deposit, located in the Eastern Kunlun Orogen, comprises three mafic-ultramafic complexes, with the No. I complex hosting six Ni-Cu orebodies found recently. The deposit is hosted in the small u...The Shitoukengde Ni-Cu deposit, located in the Eastern Kunlun Orogen, comprises three mafic-ultramafic complexes, with the No. I complex hosting six Ni-Cu orebodies found recently. The deposit is hosted in the small ultramafic bodies intruding Proterozoic metamorphic rocks. Complexes at Shitoukengde contain all kinds of mafic-ultramafic rocks, and olivine websterite and pyroxene peridotite are the most important Ni-Cu-hosted rocks. Zircon U-Pb dating suggests that the Shitoukengde Ni-Cu deposit formed in late Silurian (426-422 Ma), and their zircons have ~Hf(t) values of-9.4 to 5.9 with the older TDMm ages (0.80-1.42 Ga). Mafic-ultramafic rocks from the No. I complex show the similar rare earth and trace element patterns, which are enriched in light rare earth elements and large ion iithophile elements (e.g., K, Rb, Th) and depleted in heavy rare earth elements and high field strength elements (e.g., Ta, Nb, Zr, Ti). Sulfides from the deposit have the slightly higher ~34S values of 1.9-4.3%o than the mantle (0 ~ 2%o). The major and trace element characteristics, and Sr-Nd-Pb and Hf, S isotopes indicate that their parental magmas originated from a metasomatised, asthenospheric mantle source which had previously been modified by subduction-related fluids, and experienced significant crustal contamination both in the magma chamber and during ascent triggering S oversaturation by addition of S and Si, that resulted in the deposition and enrichment of sulfides. Combined with the tectonic evolution, we suggest that the Shitoukengde Ni-Cu deposit formed in the post-collisional, extensional regime related to the subducted oceanic slab break-off after the Wanbaogou oceanic basalt plateau collaged northward to the Qaidam Block in late Silurian.展开更多
The Shuiyindong deposit is one of the largest (more than 100 tonnes of Au) and highest grade (more than 7×10-6-10×10-6), strata-bound Carlintype gold deposits in southwestern Guizhou Province, China. The dep...The Shuiyindong deposit is one of the largest (more than 100 tonnes of Au) and highest grade (more than 7×10-6-10×10-6), strata-bound Carlintype gold deposits in southwestern Guizhou Province, China. The deposit is controlled by both structure and favorable lithology. It is situated near the axis of the striking Huijiabao anticline and is hosted in bioclastic limestone of the Permian Longtan Formation. Gold mineralization occurred under low temperature with Th of 220℃± and is closely associated with decarbonation, silicification, sulfidation and dolomitization. The deposit has a characteristic elemental assemblage of Au-As-Hg-Tl. Studies of geochemistry and isotope compositions indicated that the ore-bearing materials and fluids of the gold deposit mainly originated from a plutonic source, and possess a mixing feature with the strata matter during transportation from mantle to crust. Fluid inclusions in vein quartz from the gold deposit are rich in volatile flux, indicating that metallogenic fluid is an overpres-sured one. The activity and geothermal state of the Earth's crust in the long period of time are favorable for the formation of overpressured fluids in a large area, and extensive structures would drive the fluids into ore-forming sys-tem and make gold deposits formed. The complexity of structural movement in the upper crust of southwestern Guizhou Province resulted in complicated gold mineralization. Through metallogenic prognosis and exploration, the proven reserves of the deposit increased by tens of tonnes of Au and the deposit has become a super-large strata-bound Carlin-type gold deposit.展开更多
The newly discovered Yangchongli gold deposit is a unique independent gold deposit in the Tongling ore-cluster region controlled by the tectonic alteration firstly discovered in the Lower Yangtze Metallogenic Belt (L...The newly discovered Yangchongli gold deposit is a unique independent gold deposit in the Tongling ore-cluster region controlled by the tectonic alteration firstly discovered in the Lower Yangtze Metallogenic Belt (LYMB). The host magmatic rocks mainly consist of monzodiorite and K-feldspar granite. The LA-ICP-MS U-Pb zircons dating yielded weighted mean 206pb/23SU ages of 140.7 ± 1.8 Ma and 126.4 ±1.2 Ma for the monzodiorite and K-feldspar granite, respectively. Monzodiorites are enriched in Sr, Ba, Rb, and depleted in Y, Yb with high Sr/Y and La/Yb ratios, similar to the geochemical features of adakite, considered as products of differentiation of mafic magmas originating from lithospheric mantle melt/fluids caused by metasomatism during paleo-Pacific Plate subduction in the Mesozic. In contrast, the compositions of K-feldspar granites are A-type granites, indicating an extensional tectonic background. Gold ores hosted in the fracture zone occurred as quartz vein within cataclastic rock. Sulfur and lead isotopes from pyrites show crust-mantle mixing characteristics. Metal components from strata also took part in the gold mineralization, and resulted from two episodes of magmatism that were probably related to tectonic transition from a compressive to an extensional setting between 140-126 Ma, which led to the Mesozoic large-scale polymetallic mineralization events in eastern China.展开更多
The Yinkeng orefield in Yudu County,Jiangxi Province,SE China,is a zone of concentrated Au-Ag-Pb-Zn-Cu-Mn polymetallic ores.Based on summing up basic geology and ore geology of the orefieid,the polymetallic deposits i...The Yinkeng orefield in Yudu County,Jiangxi Province,SE China,is a zone of concentrated Au-Ag-Pb-Zn-Cu-Mn polymetallic ores.Based on summing up basic geology and ore geology of the orefieid,the polymetallic deposits in the orefield have been divided into seven major substyles according to their occurring positions and control factors.The ore-forming fluid inclusion styles in the orefield include those of two-phase fluid,liquid CO2-bearing three-phase and daughter mineral-bearing multi-phase.The homogenization temperatures range from 382° to 122℃,falling into five clusters of 370° to 390°,300° to 360°,230° to 300°,210° to 290° and 120° to 200°,and the clusters of 300° to 360°,230° to 300° and 120° to 200° are three major mineralization stages,with fluid salinity peaks from 4.14% to 7.31%,2.07% to 7.31% and 0.53% to 3.90%,respectively.The ore-forming fluids are mainly type of NaCl-H2O with medium to high density (0.74-1.02 g/cm3),or CO2-bearing NaCl-H2O with medium to low density (0.18-0.79 g/cm3).The fluid salinity and density both show a decline tendency with decreasing temperature.According to the measurement and calculation of Hand O-isotopic compositions in the quartz of the quartz-sulfide veins,δDV-SMOW of the ore-forming fluid is from-84‰ to-54‰,and δ18OV-SMOW of that is from 6.75‰ to 9.21‰,indicating a magmatic fluid.The δ34SV-CDT of sulfides in the ores fall into two groups,one is from-4.4‰ to 2.2‰ with average of-1.42‰,and the other from 18.8‰ to 21.6‰ with average of 19.8‰.The S-isotopic data shows one peak at-4.4‰ to 2.2‰ (meaning-1.42‰) suggesting a simple magmatic sulfur source.The ore Pbisotopic ratios are 206pb/204pb from 17.817 to 17.983,207pb/204pb from 15.470 to 15.620 and 208pb/204pb from 38.072 to 38.481,indicating characteristics of mantle-derived lead.The data show that the major ore deposits in the orefield have a magmatic-hydrothermal genesis and that the SHRIMP zircon age of the granodiorite porphyry,closely related to the mineralization,is 151.2±4.2 Ma (MSWD =1.3),which can represent the formation ages of the ores and intrusion rocks.The study aids understanding of the ore-forming processes of the major metallic ore deposits in the orefield.展开更多
According to an analysis of the geological features in the eastern sector of the Bangong Co-Nujiang River suture zone, the Tethyan evolution can be divided into three stages. (1) The Embryo-Tethyan stage (Pz1): An imm...According to an analysis of the geological features in the eastern sector of the Bangong Co-Nujiang River suture zone, the Tethyan evolution can be divided into three stages. (1) The Embryo-Tethyan stage (Pz1): An immature volcanic arc developed in Taniantaweng (Tanen Taunggyi) Range, indicating the existence of an Embryo-Tethyan ocean. (2) The Palaeo-Tethyan stage (C-T2: During the Carboniferous the northern side of the Taniantaweng Range was the main domain of the Palaeo-Tethyan ocean, in which developed flysch sediments intercalated with bimodal volcanic rocks and oceanic tholeiite, and Pemian-Early Triassic are granites were superimposed on the Taniantaweng magmatic are; on the southern side the Dêngqên-Nujiang zone started secondary extension during the Carboniferous, in which the Nujiang ophiolite developed, and the Palaeo-Tethyan ocean closed before the Middle Triassic. (3) The Neo-Tethyan stage (T3-E): During the Late Triassic the Dêngqên zone developed into a relatively matural ocean basin, in which the Dêngqên ophiolite was formed. By the end of the Triassic intraocean subduction occurred, and the ocean domain was reduced gradually, and collided and closed by the end of the Early Jurassic, forming the Yazong mélange; then the Tethyan ocean was completely closed.展开更多
The Nadingcuo high-K calc-alkaline rocks mainly composed of trachyte and trachyandesite are the largest outcrop area of volcanic rocks in southern Qiangtang terrane in the Tibetan plateau. However,their exact source a...The Nadingcuo high-K calc-alkaline rocks mainly composed of trachyte and trachyandesite are the largest outcrop area of volcanic rocks in southern Qiangtang terrane in the Tibetan plateau. However,their exact source and peterogenesis are still debated.^(40)Ar-^(39)Ar and LAM-ICPMS zircon U-Pb isotopic dating confirm that these rocks erupted in Eocene.In addition,the Nadingcuo volcanic rocks are characterized by high Sr/Y content ratios,similar with the adakite derived from partial melting of oceanic crust.They can be further classified as high Mg~#(Mg~#=48-57) and low Mg~# (Mg~#=33-42) subtypes.The Nadingcuo adakitic rocks have relatively low(^(87)Sr/^(86)Sr)_i and highε_(Nd)(t), showing a trend of similarity to the Dongcuo ophiolite present in the Bangong-Nujiang oceanic crust. Simple modeling indicates that the Nadingcuo adakitic rocks are a mix resulting from the basalt of Bangong-Nujiang Ocean with 10%-20%crustal material of Lhasa terrane.On these bases we suggest that the low Mg~# Nadingcuo adakitic rocks are the product of partial melting of remnant oceanic crust with small sediment,and the high Mg~# rocks are the result of reaction between rising melt of remnant oceanic crust with subducted sediment and mantle wedge.Therefore,the origin of Nadingcuo adakitic rocks may be related to intracontinental subduction triggered by collision of India-Asia during Cenozoic.展开更多
The Tashisayi nephrite deposit is located in South Altyn Tagh.in Qiemo County,Xinjiang Province,northwest China.It is a recent discovery in the vast,well-known Kunlun-Altyn nephrite belt distributed along the south of...The Tashisayi nephrite deposit is located in South Altyn Tagh.in Qiemo County,Xinjiang Province,northwest China.It is a recent discovery in the vast,well-known Kunlun-Altyn nephrite belt distributed along the south of the Tarim Basin,producing more than half of the nephrite from the whole belt in 2017.Field investigations revealed that it is a dolomitic marble-related(D-type)nephrite deposit,but little is known about its age of formation and relationships between the granites and marble.Here we report field investigations,petrography of the neph rite,as well as petrography,geochemistry,geochronology of the zoisite-quartz altered intrusive rock and adjacent granites.An A-type granite is identified with a SHRIMP U-Pb zircon age of 926±7 Ma,suggesting it was emplaced in an extensional tectonic environment at that time.The altered intrusive rock has a cluster of U-Pb zircon age of 433±10 Ma.with similar trace element features to the A-type granite,suggesting it was formed in an extensional regime at this later time.Nephrite formed because of the metasomatism of dolomite marble by hydrothermal fluids.It is inferred that Ca^2+was released from the dolomitic marble by metasomatism forming Ca-rich fluids,which caused alteration of both the intrusive rocks(6.00-8.22 wt.%CaO)and granite(1.76-3.68 wt.%CaO)near the nephrite ore bodies.It is also inferred that Fe^2+from the granite migrated towards the dolomite marble.The fluids gave rise to the formation of Ca-minerals.such as zoisite,in the nephrite and altered intrusive rock,and epidote in the granite.Based on the contact relationships.similarity in hydrothermal processes,and consumption of Ca^2+,the Tashisayi nephrite is considered to have formed at the same time as the alteration of the intrusive rocks,i.e.~433 Ma.The geochronological similarity(~926 Ma.433 Ma)of South Altyn and North Qaidam may suggest that tectonically they belong to one single complex in the past,which was offset by the Altyn Tagh fault(ATF).The similar formation ages of the nephrites from Altyn Tagh(433 Ma)and the previously studied areas of West Kunlun(378-441 Ma)and East Kunlun(416 Ma)indicate that these nephrites formed during the closure of Proto-Tethys and in the accompanving post-collisional.extensional environment.展开更多
The Mamupu skarn-type Cu-Au polymetallic deposit represents the first discovery of a medium deposit in the southern Yulong porphyry copper belt(YPCB),eastern Tibet.The Cu-Au mineralization mainly occurs as chalcopyrit...The Mamupu skarn-type Cu-Au polymetallic deposit represents the first discovery of a medium deposit in the southern Yulong porphyry copper belt(YPCB),eastern Tibet.The Cu-Au mineralization mainly occurs as chalcopyrite in breccia,within the plate-like carbonate interlayer,being closely related to chloritization(e.g.,chlorite,magnetite and epidote)and skarnization(e.g.,diopside,tremolite and garnet).The ore-related quartz syenite porphyry(QSP)and granodiorite porphyry(GP)were emplaced at 40.1±0.2 Ma and 39.9±0.3 Ma,respectively.The QSP of Mamupu is an alkaline-rich intrusion,relatively enriched in LREE,LILE,depleted in HFSE,with no significant negative Eu and Ce anomalies,slightly high(^(87)Sr/^(86)Sr)i,lowε_(Nd)(t),uniform(^(206)Pb/^(204)Pb)i andε_(Hf)(t)values,which indicates that the porphyry magma may be caused by both the mixing of metasomatized EM II enriched mantle and thickened juvenile lower crust.The QSP in the Mamupu deposit shares a similar genesis of petrology to other ore-related porphyries within the YPCB.High oxygen fugacity and water content of the magmas are essential for the formation of porphyry and skarn Cu deposits.The QSP has similar high magmatic oxidation states and water content to the Yulong deposit,which indicates that the Mamupu has a high prospecting potential.Differences in the geological characteristics and scale of mineralization between the Mamupu and other YPCB deposits may be due to the different emplacement depths of ore-related intrusions,as well as differences in the surrounding rocks.展开更多
The Bayingobi basin is the Mesozoic-Cenozoic basin in North China in which the Tamusu uranium deposit is located.The ore-target layer of the deposit is the Lower Cretaceous Bayingobi Formation,which developed as a fan...The Bayingobi basin is the Mesozoic-Cenozoic basin in North China in which the Tamusu uranium deposit is located.The ore-target layer of the deposit is the Lower Cretaceous Bayingobi Formation,which developed as a fan deltashallow lacustrine deposit.The distributary channel sand body of the fan delta plain and the underwater distributary channel sand body of the fan delta front formed a favorable uranium reservoir,so the study of sequence stratigraphy is extremely important to understanding the genesis of uranium deposits.On the basis of field investigation and a large number of borehole logs,the high resolution sequence stratigraphy of the Lower Cretaceous is divided and the system tracts of different periods are established.The relationship between deposition,interlayer oxidation and uranium enrichment is discussed.The Lower Cretaceous Bayingobi Formation can be divided into two fourth-order sequences(Sq1 and Sq2).The lower member of the Bayingobi Formation is referred to as Sq1,which is composed of a falling-stage system tract(FSST)on top.On the other hand,the upper member of the Bayingobi Formation is referred to as Sq2,which is composed of a lowstand system tract(LST),transgressive system tract(TST)and highstand system tract(HST).The lowstand system tract forms a favorable stratigraphic structure(mud-sand-mud formation)with the lacustrine mudstone of the overlying transgressive system tract,that is conducive for the migration of uranium-bearing oxygen water.The organic matter and pyrite in the fan delta sand body,as well as the dark mudstone in the distributary bay,provided a reducing medium for uranium mineralization.The ore body mainly occurs in the distributary channel,underwater distributary channel or the mouth bar of the fan delta.As a result of the moderate thickness,high permeability,favorable barrier and rich reducing medium,the rich ore body mainly occurs in the underwater distributary channel and mouth bar sand body of the delta front.Based on study of the sequence stratigraphy,the model of the sequence,sedimentation and mineralization of the uranium deposit is established,which enriches uranium metallogenic theory and provides a reference for exploration of the same type of uranium deposits.展开更多
The Lower Carboniferous Jiujialu Formation bauxite deposits of northern Guizhou Province,China,are a Kazakhstan subtype of karst bauxite deposits.The provenance of the Jiujialu Formation has long been debated,with unc...The Lower Carboniferous Jiujialu Formation bauxite deposits of northern Guizhou Province,China,are a Kazakhstan subtype of karst bauxite deposits.The provenance of the Jiujialu Formation has long been debated,with uncertainty about the formation of the bauxite deposits.Here we report new geochemical data that indicate the affinity between the Lower-Middle Ordovician clastic rocks and argillaceous dolostones and the overlying Carboniferous bauxite deposits,all of which are characterized by high Al_(2)0_(3),K2_(O),and∑REE contents,flat post-Archean Australian shale(PAAS)-normalized REE patterns,and uniform immobile element ratios(TiO2/Al_(2)0_(3),Nb/TiO2,and Zr/TiO2).Their similar detrital zircon age distributions further indicate the link between the bauxite deposits and the clastic rocks and argillaceous dolostones.Zircon age spectra of clastic rocks of the Lower Silurian Hanchiatien Formation in northern Guizhou match those of the bauxite deposits,with a maximum age peak at-980 Ma and other secondary age peaks,suggesting these clastic rocks may represent the provenance of the bauxite deposits.The youngest detrital zircons(-445 Ma)occur only in the bauxite deposits and are probably sourced from K-bentonite beds of the Ordovician-Silurian tran-sition.Our analyses indicate that the source materials of the bauxite deposits in the Jiujialu Formation are of mixed provenance:Lower-Middle Ordovician aluminosilicate rocks and argillaceous dolostones of the underlying strata,and Lower Silurian clastic rocks and K-bentonite from adjacent areas.A comparison of Early Carboniferous bauxitic provenances in northern and central Guizhou indicates that paleotopography was the major factor controlling the provenance of these bauxite deposits.展开更多
Previous studies have obtained some petrogenetic and metallogenic chronological data with SHRIMP (sensitive high-resolution ion microprobe) zircon U-Pb, zircon LA-ICPMS (laser-ablation-inductively coupled plasma ma...Previous studies have obtained some petrogenetic and metallogenic chronological data with SHRIMP (sensitive high-resolution ion microprobe) zircon U-Pb, zircon LA-ICPMS (laser-ablation-inductively coupled plasma mass spectroscopy) U-Pb, molybdenite Re-Os isochron and muscovite Ar-Ar methods in southern Jiangxi Province and its adjacent areas. Based on these, the purpose of this paper is to study the petrogenetic and metallogenic ages and their time gap for different genetic types of W-Sn deposits, and thus to research their numerous episodes, zonal arrangement and their geodynamic background. The result shows that the large-scale W-Sn mineralization in southern Jiangxi Province occurred in the middle to late Jurassic (170-150 Ma), the skarn W-Sn-polymetallic deposits formed much earlier (170-161 Ma), and all of the wolframite-quartz vein type, greisen type, altered granite type and fractured zone type tungsten deposits formed in the late Jurassic (160-150 Ma). In one ore field or ore district, greisen type tungsten deposits formed earlier than quartz vein type ones hosted in the endoor exo-contact zone; and quartz vein type hosted in the endocontact zone formed earlier than that of exocontact zone. There is no significant time difference between tungstentin mineralization and its intimately associated parent granite emplacement (1-6 Ma). They all formed in the same rock-forming and ore-forming system and under the same geodynamic setting. Regionally, rock-forming and ore-forming processes of the W-Sn deposits in the Nanling region (include southern Jiangxi Province, southern Hunan Province, northern Guangdong Province and eastern Guangxi Zhuang Autonomous Region) exhibit numerous episodes. The mineralization in the Nanling region mainly occurred at (240-210) Ma, (170-150) Ma and (130-90) Ma. The tungsten-tin deposits in this region are centered by the largest scale in southern Jiangxi Province and southern Hunan Province, and become small in the east, west, south and north directions. This displays a zonal arrangement and temporal and spatial distribution regularity. Integrated with the latest research results, it is concluded that the W-Sn mineralization in southern Jiangxi Province and its adjacent areas corresponds to the second large-scale mineralization in South China. The Indosinian W-Sn mineralization formed under the extensional tectonic regime between collisional compressional stages, while the Yanshanian large-scale petrogenetic and metallogenic processes occurred in the Jurassic intraplate extensional geodynamic setting of lithosphere extension.展开更多
The Pengshan Sn-polymetallic ore field is located in the southeastern part of the Yangtze block,spanning the southeast edge of the MLYDZ and the northern edge of the mid-segment of the Jiangnan Uplift,and on one side ...The Pengshan Sn-polymetallic ore field is located in the southeastern part of the Yangtze block,spanning the southeast edge of the MLYDZ and the northern edge of the mid-segment of the Jiangnan Uplift,and on one side of the MLYDZ.The studies of LA-ICP-MS zircon U-Pb chronology and petrogeochemistry for Early Cretaceous acid granites from the Pengshan ore field were carried out in this paper.We report zircon U-Pb geochronology and whole-rock geochemistry for acid granites in the Pengshan ore field.The zircon U-Pb ages of the muscovite-granite,biotite adamellite and granite-porphyry are 127.6±1.7 Ma,126.9±1.6 Ma and 126.6±2.0 Ma,respectively.The granites in Pengshan are characterized by a high silicon content and are rich in alkali.They belong to high-potassium,calc-alkaline,peraluminous granite.The rocks have a relatively high Rb/Ba ratio,and the data points for muscovite-granite and biotite adamellite all fall within the clay-rich sources region,near the pelite-derived end-member,showing that the Pengshan muscovite-granite and biotite adamellite mainly originated from the partial melting of metapelites with high maturity.The transformation of the compressional and extensional tectonics in this region approximately 128 Ma obviously lags behind that in the mid-segment of the Jiangnan Uplift(135 Ma),but occurred earlier than the MLYDZ(126 Ma).The Pengshan ore field extends from the mid-segment of the Jiangnan Uplift to the MLYDZ.Although the tectonic stress field is constrained by the combination of the two secondary tectonic units,the time of tectonic system transformation is closer to the MLYDZ because the spatial orientation of the area is enclosed in the MLYDZ.Relevant geophysical and drilling data confirm the rationality of Pengshan-Ao'xia as a multi-center vertical zoning ore field,and show the scientificity of the prospecting idea of abutting joint between the north-west of Pengshan area and the south-east of Ao'xia area.展开更多
The Weiquan Ag-polymetallic deposit is located on the southern margin of the Central Asian Orogenic Belt and in the western segment of the Aqishan-Yamansu arc belt in East Tianshan,northwestern China. Its orebodies, c...The Weiquan Ag-polymetallic deposit is located on the southern margin of the Central Asian Orogenic Belt and in the western segment of the Aqishan-Yamansu arc belt in East Tianshan,northwestern China. Its orebodies, controlled by faults, occur in the lower Carboniferous volcanosedimentary rocks of the Yamansu Formation as irregular veins and lenses. Four stages of mineralization have been recognized on the basis of mineral assemblages, ore fabrics, and crosscutting relationships among the ore veins. Stage I is the skarn stage(garnet + pyroxene), Stage Ⅱ is the retrograde alteration stage(epidote + chlorite + magnetite ± hematite 士 actinolite ± quartz),Stage Ⅲ is the sulfide stage(Ag and Bi minerals + pyrite + chalcopyrite + galena + sphalerite + quartz ± calcite ± tetrahedrite),and Stage IV is the carbonate stage(quartz + calcite ± pyrite). Skarnization,silicification, carbonatization,epidotization,chloritization, sericitization, and actinolitization are the principal types of hydrothermal alteration. LAICP-MS U-Pb dating yielded ages of 326.5±4.5 and 298.5±1.5 Ma for zircons from the tuff and diorite porphyry, respectively. Given that the tuff is wall rock and that the orebodies are cut by a late diorite porphyry dike, the ages of the tuff and the diorite porphyry provide lower and upper time limits on the age of ore formation. The δ13C values of the calcite samples range from-2.5‰ to 2.3‰, the δ18OH2 Oand δDVSMOWvalues of the sulfide stage(Stage Ⅲ) vary from 1.1‰ to 5.2‰ and-111.7‰ to-66.1‰, respectively,and the δ13C, δ18OH2 Oand δDV-SMOWvalues of calcite in one Stage IV sample are 1.5‰,-0.3‰, and-115.6‰, respectively. Carbon, hydrogen, and oxygen isotopic compositions indicate that the ore-forming fluids evolved gradually from magmatic to meteoric sources. The δ34SV-CDTvalues of the sulfides have a large range from-6.9‰ to 1.4‰, with an average of-2.2‰, indicating a magmatic source, possibly with sedimentary contributions. The206Pb/204Pb,207Pb/204Pb, and208Pb/204Pb ratios of the sulfides are 17.9848-18.2785,15.5188-15.6536, and 37.8125-38.4650, respectively, and one whole-rock sample at Weiquan yields206Pb/204Pb,207Pb/204Pb, and208Pb/204Pb ratios of 18.2060, 15.5674, and 38.0511,respectively. Lead isotopic systems suggest that the ore-forming materials of the Weiquan deposit were derived from a mixed source involving mantle and crustal components. Based on geological features, zircon U-Pb dating, and C-H-OS-Pb isotopic data, it can be concluded that the Weiquan polymetallic deposit is a skarn type that formed in a tectonic setting spanning a period from subduction to post-collision. The ore materials were sourced from magmatic ore-forming fluids that mixed with components derived from host rocks during their ascent, and a gradual mixing with meteoric water took place in the later stages.展开更多
Three special types of xenoliths have recently been found in an aegirine-augite syenite porphyry in Liuhe, Yunnan, China. Petrographical, petrochemical, electron microprobe, and scanning electron microscopy studies in...Three special types of xenoliths have recently been found in an aegirine-augite syenite porphyry in Liuhe, Yunnan, China. Petrographical, petrochemical, electron microprobe, and scanning electron microscopy studies indicate that pure calcite xenocrysts and quartz-bearing topaz pegmatite xenoliths result from the degassing of mantle fluids during their migration, and that black microcrystalline iron-rich silicate-melt xenoliths are the product of the extraction of mantle fluids accompanying degassing and are composed dominantly of quartz, chlorite, and iron-rich columnar and sheet silicate minerals with characteristic minerals, such as native iron, apatite, and zircon. According to the bulk-rock chemical and mineral compositions and crystallization states, the microcrystalline melt xenoliths are not the product of conventional magmatism, and especially the existence of native iron further proves that the xenoliths were mantle fluid materials under reduction or anoxic conditions. The study of the special xenoliths furnishes an important deep-process geochemical background of polymetallic mineralization in different rocks and strata in the study area.展开更多
The ductile shear zone-type gold deposit is a kind that both the ore-forming mechanism and ore-controlling factors are closely related to the ductile shear zone and its evolution. Ductile shear zone develops in Beisha...The ductile shear zone-type gold deposit is a kind that both the ore-forming mechanism and ore-controlling factors are closely related to the ductile shear zone and its evolution. Ductile shear zone develops in Beishan area, Gansu of Northwest China, and develops especially well in the south belt. The controls of the ductile shear zone on gold deposits are as follows. (1) The regional distribution of gold deposits (and gold spots) is controlled by the ductile shear zone. (2) The ductile-brittle shear zone is formed in the evolution process of ductile shear zone and both are only ore-bearing structures and control the shape, attitude, scale, and distribution of mineralization zones and ore-bodies. (3) Compresso-shear ductile deformation results in that the main kind of gold mineralization is altered mylonite type and the main alteralization is metasomatic. (4) Ore-bearing fracture systems are mainly P-type ones, some D-type and R-type ones, but only individual R'-type and T-type ones. (5) Dynamic differen- tiation and dynamic metamorphic hydrothermal solution resulting from ductile deformation is one of the sources of ore-forming fluid of gold mineralization, and this is identical with that ore-forming materials are mainly from metamorphic rocks, and ore-forming fluid is mainly composed of metamorphic water, and with the fluid inclusion and geo-chemical characteristics of the deposit. (6) There is a negative correlation between the gold abundance and susceptibility anlsotropy (P) of the altered mylonlte samples from the deposit, which shows that the gold mineralization is slightly later than the structural deformation. All above further expound the ore-forming model of the ductile shear zone type of gold deposits.展开更多
基金jointly supported by the CNNC Research and Innovation Project(grant no.Geo-SD04and Geo-LTD-1601)funded by the project“Geology of mineral resources in China”from China Geological Survey(grant nos.DD20160346,DD20190379)。
文摘The Bayinqinggeli deposit in the northern Ordos Basin, northwestern of China, is a recently discovered sandstone-type uranium deposit. The uranium(U) orebodies are generally hosted in the lower member of the Jurassic Zhiluo Formation(Fm.), and are primarily tabular or irregular in shape. In the study area, 23 sandstone samples were collected from the Zhiluo Fm. and analyzed for major, trace, and rare earth elements(REEs). The geochemical characteristics of these sandstones are used to evaluate the factors controlling U mineralization. The source rocks of the Zhiluo Fm. sandstones are mainly volcanic and felsic magmatic rocks formed in continental arc and active continentalmarginal arc environments, and they provided the material required for the mineralization. The index of compositional variability ranges from 1.02 to 3.29(average1.38), indicating that the Zhiluo Fm. sandstones are immature and composed of first-cycle sediments. The corrected chemical index of alteration averages 56, suggesting that the source rocks underwent weak chemical weathering. The ore host rocks are loose, providing favorable conditions for epigenetic oxidation and U precipitation and enrichment. Ferrous iron in minerals such as chlorite, biotite, ilmenite, and pyrite might have played a role either in adsorbing or reducing the uranium.
基金granted by the Xinjiang Geological Exploration Fund。
文摘The northwestern margin of Junggar Basin is the region with the richest oil sand resources in China.For better understanding the enrichment rules and deployment of exploration and development of regional oil sand,it is of great scientific significance to study the accumulation conditions of oil sand in different strata and mining areas of the Junggar Basin.Through a large number of field investigations,drilling verification and sampling tests,it is found that the oil sand in the region covers an area of 2000 km^(2),with shallow and thick reservoir,and predicted resource of 180 million tons.The oil sand resources are mainly distributed in four geological strata,namely the Middle Triassic Karamay Formation,Early Jurassic Badaowan Formation,Late Jurassic Qigu Formation,and Early Cretaceous Qingshuihe Formation.The reservoir is mainly composed of sandstone with high porosity and permeability,and the reservoir space is mainly intergranular pores with a medium average oil content.The oil sand deposit in the region is a typical destructive oil reservoir.The crude oil in the oil sand layer is degraded and thickened from the deep to the shallow,the content of saturated hydrocarbon decreased,and the content of aromatic hydrocarbon,non-hydrocarbon and asphaltene increased.The oil source comes from the deep Permian hydrocarbon-generating depression.Unconformities,faults and marginal fan delta-braided river depositional systems constitute effective migration and storage systems.Caprocks of the Upper Triassic Baijiantan Formation,Lower Jurassic Sangonghe Formation and Lower Cretaceous Hutubihe Formation were formed by three large scale lake transgressions.The Indosinian,Yanshan and Late Yanshan movements are the main driving forces for the migration of deep oil and gas to the shallow edge to form oil sand deposits.It is considered that the oil sand in the northwestern margin of Junggar Basin is of a slope complex migration type.
基金jointly supported by the National Key Research&Development Program of China(2021YFC2900100)the Basic Research Fund of the Chinese Academy of Geological Sciences(KK2306)+1 种基金the Geological Survey Project(DD20230360,DD20243483)the Sichuan Provincial Natural Science Foundation(2023NSFSC0798).
文摘Multiple instances of the Late Cretaceous granodiorites within the Anglonggangri region of the northwestern Lhasa Block were identified,their petrogenesis were explored and mineralization potential were assessed.The zircon U-Pb dating of the Anglonggangri granodiorites revealed ages of 82.8 and 80.8 Ma.Granodiorite samples have SiO2 contents of 64.36-68.33 wt%,with high Sr/Y(55-95)and A/CNK ratios(0.99-1.06).Zirconε_(Hf)(t)values range from−0.3 to+16.2.Two granodiorite samples have(^(87)Sr/^(86)Sr)i values of 0.7034 and 0.7043 and positiveɛNd(t)values of 3.51 and 3.83.These geochemical properties indicate that they are adakitic rocks formed by partial melting of the juvenile thickened lower crust,slightly contaminated with material from the mantle due to the small-scale delamination of the lower crust.The zircons in the granodiorites have moderate Ce/Nd(2.5-43),logfO2(−20.0 to−9.6),andΔFMQ(−1.28 to+4.00)values;low(Ce/Nd)/Y(0.001-0.049)ratios;and high Dy/Yb(0.17-1.16)ratios,which indicate that these granodiorites exhibit moderate oxygen fugacity and lower magma water content than the Miocene Gangdese porphyry copper deposits associated with high-Sr/Y granites.Their ability to create porphyry-type copper deposits could have been hampered by their low magma water content and moderate oxygen fugacity.
基金sponsored by the National Natural Science Foundation Program of China(Nos.40772072 and 40802023)the Uranium Deposit Geological Program of Bureau of Geology,CNNC,the National Important Basic Research Program of China(No.2003CB214603 and No.2015CB453003)the Dongsheng coal and uranium exploration program of Central Geological exploration Fund(No.2008150013)
文摘Outcrop and drill hole data show that the Jurassic coal measures in the northeastern Ordos Basin are composed mainly of the Yan’an Formation and the lowstand system tract of the Zhiluo Formation,and there is a regional unconformity between them.The Dongsheng uranium deposit is associated with the Jurassic coal measures.Research data indicate that the Jurassic coal measures in the study area have a certain hydrocarbon-generating capacity,although the metamorphic grade is low(Ro=0.40%–0.58%).In the Dongsheng region alone,the accumulative amount of generated coalbed methane(CBM)is about 2028.29×108–2218.72×108 m3;the residual amount is about 50.92×108 m3,and the lost amount is about 1977×108 m3.Analysis of the burial history of the host rocks and the evolutionary history of the Dongsheng uranium deposit suggests that the Jurassic coal measures generated hydrocarbon mainly from Middle Jurassic to Early Crataceous,which is the main mineralization phase of the Dongsheng uranium deposit.By the Late Cretaceous,a mass of CBM dissipated due to the strong tectonic uplift,and the Dongsheng uranium deposit stepped into the preservation phase.Therefore,the low-mature hydrocarbon-containing fluid in the Jurassic coal measures not only served as a reducing agent for the formation of sandstone-type uranium deposits,but also rendered the second reduction of paleo-interlayer oxidation zone and become the primary reducing agent for ore conservation.Regional strata correlation reveals that the sandstone-type uranium reservoir at the bottom of the Zhiluo Formation is in contact with the underlying industrial coal seams in the Yan’an Formation through incision or in the form of an unconformity surface.In the Dongsheng region with poorly developed fault systems,the unconformity surface and scour surface served as the main migration pathways for low-mature hydrocarbon-containing fluid migrating to the uranium reservoir.
基金supported by the Chinese postdoctoral research fund,Major State Basic Research Program of China(G1999143201)special project of geological sciences(9801)of the State Planning Commission
文摘The Jinding superlarge lead and zinc deposit has attracted the attention of geologists of the world and its metallogenesis has long been in dispute. This paper takes the Jinding deposit and the Baiyangping Cu-Ag-Co deposit which was recently found at about 30 km north of Jinding as one ore belt, and, based on researches on the helium, argon, and xenon isotopic compositions of primary inclusions in ore-forming solutions of the main stage, the authors have found that the 3He/4He ratio of the ore-forming fluid is 2.7×10?6 (varying from 0.19 to 1.97 Ra), the 4He/40Ar ratio (0.24–3.12) is close to the mantle characteristic ratio, and the xenon isotopic composition and evolution show characters of the mantle xenon. The above results reveal the characteristics of mantle source and crust-mantle fluid mixing (mantle helium reaching 32%) and the metallogenic contributions of the deep processes in the Jinding-Baiyangping ore belt.
基金financially supported by the National Natural Science Foundation of China(No.41272093)China geological survey project(No.12120114080901)
文摘The Shitoukengde Ni-Cu deposit, located in the Eastern Kunlun Orogen, comprises three mafic-ultramafic complexes, with the No. I complex hosting six Ni-Cu orebodies found recently. The deposit is hosted in the small ultramafic bodies intruding Proterozoic metamorphic rocks. Complexes at Shitoukengde contain all kinds of mafic-ultramafic rocks, and olivine websterite and pyroxene peridotite are the most important Ni-Cu-hosted rocks. Zircon U-Pb dating suggests that the Shitoukengde Ni-Cu deposit formed in late Silurian (426-422 Ma), and their zircons have ~Hf(t) values of-9.4 to 5.9 with the older TDMm ages (0.80-1.42 Ga). Mafic-ultramafic rocks from the No. I complex show the similar rare earth and trace element patterns, which are enriched in light rare earth elements and large ion iithophile elements (e.g., K, Rb, Th) and depleted in heavy rare earth elements and high field strength elements (e.g., Ta, Nb, Zr, Ti). Sulfides from the deposit have the slightly higher ~34S values of 1.9-4.3%o than the mantle (0 ~ 2%o). The major and trace element characteristics, and Sr-Nd-Pb and Hf, S isotopes indicate that their parental magmas originated from a metasomatised, asthenospheric mantle source which had previously been modified by subduction-related fluids, and experienced significant crustal contamination both in the magma chamber and during ascent triggering S oversaturation by addition of S and Si, that resulted in the deposition and enrichment of sulfides. Combined with the tectonic evolution, we suggest that the Shitoukengde Ni-Cu deposit formed in the post-collisional, extensional regime related to the subducted oceanic slab break-off after the Wanbaogou oceanic basalt plateau collaged northward to the Qaidam Block in late Silurian.
基金supported jointly by the State Science and Technology Supporting Program (2006BAB01A13)the self-research project funded by the State Key Laboratory of Ore Deposit Geochemistry (Ore Deposit Special Research Project 2008.3-2)Guizhou Provincial Bureau of Geology and Mineral Resource Exploration and Development [Qian Di Kuang Ke (2009) No. 11]
文摘The Shuiyindong deposit is one of the largest (more than 100 tonnes of Au) and highest grade (more than 7×10-6-10×10-6), strata-bound Carlintype gold deposits in southwestern Guizhou Province, China. The deposit is controlled by both structure and favorable lithology. It is situated near the axis of the striking Huijiabao anticline and is hosted in bioclastic limestone of the Permian Longtan Formation. Gold mineralization occurred under low temperature with Th of 220℃± and is closely associated with decarbonation, silicification, sulfidation and dolomitization. The deposit has a characteristic elemental assemblage of Au-As-Hg-Tl. Studies of geochemistry and isotope compositions indicated that the ore-bearing materials and fluids of the gold deposit mainly originated from a plutonic source, and possess a mixing feature with the strata matter during transportation from mantle to crust. Fluid inclusions in vein quartz from the gold deposit are rich in volatile flux, indicating that metallogenic fluid is an overpres-sured one. The activity and geothermal state of the Earth's crust in the long period of time are favorable for the formation of overpressured fluids in a large area, and extensive structures would drive the fluids into ore-forming sys-tem and make gold deposits formed. The complexity of structural movement in the upper crust of southwestern Guizhou Province resulted in complicated gold mineralization. Through metallogenic prognosis and exploration, the proven reserves of the deposit increased by tens of tonnes of Au and the deposit has become a super-large strata-bound Carlin-type gold deposit.
基金supported by the DREAM project of MOST China (No.2016YFC0600404)the Natural Science Foundation of China (Grant Nos.41372087, 41673040)the Project of Geological Science and Technology of Anhui Province (2015-K-01)
文摘The newly discovered Yangchongli gold deposit is a unique independent gold deposit in the Tongling ore-cluster region controlled by the tectonic alteration firstly discovered in the Lower Yangtze Metallogenic Belt (LYMB). The host magmatic rocks mainly consist of monzodiorite and K-feldspar granite. The LA-ICP-MS U-Pb zircons dating yielded weighted mean 206pb/23SU ages of 140.7 ± 1.8 Ma and 126.4 ±1.2 Ma for the monzodiorite and K-feldspar granite, respectively. Monzodiorites are enriched in Sr, Ba, Rb, and depleted in Y, Yb with high Sr/Y and La/Yb ratios, similar to the geochemical features of adakite, considered as products of differentiation of mafic magmas originating from lithospheric mantle melt/fluids caused by metasomatism during paleo-Pacific Plate subduction in the Mesozic. In contrast, the compositions of K-feldspar granites are A-type granites, indicating an extensional tectonic background. Gold ores hosted in the fracture zone occurred as quartz vein within cataclastic rock. Sulfur and lead isotopes from pyrites show crust-mantle mixing characteristics. Metal components from strata also took part in the gold mineralization, and resulted from two episodes of magmatism that were probably related to tectonic transition from a compressive to an extensional setting between 140-126 Ma, which led to the Mesozoic large-scale polymetallic mineralization events in eastern China.
基金financially supported jointly by the National Key Basic Research Program (Grant 2012CB416704) from the Ministry of Science and Technology, Chinathe Program of High-level Geological Talents (201309) and Youth Geological Talents (201112) from the China Geological Surveyby Geological Survey Program Grant 1212010561603-2 from the China Geological Survey
文摘The Yinkeng orefield in Yudu County,Jiangxi Province,SE China,is a zone of concentrated Au-Ag-Pb-Zn-Cu-Mn polymetallic ores.Based on summing up basic geology and ore geology of the orefieid,the polymetallic deposits in the orefield have been divided into seven major substyles according to their occurring positions and control factors.The ore-forming fluid inclusion styles in the orefield include those of two-phase fluid,liquid CO2-bearing three-phase and daughter mineral-bearing multi-phase.The homogenization temperatures range from 382° to 122℃,falling into five clusters of 370° to 390°,300° to 360°,230° to 300°,210° to 290° and 120° to 200°,and the clusters of 300° to 360°,230° to 300° and 120° to 200° are three major mineralization stages,with fluid salinity peaks from 4.14% to 7.31%,2.07% to 7.31% and 0.53% to 3.90%,respectively.The ore-forming fluids are mainly type of NaCl-H2O with medium to high density (0.74-1.02 g/cm3),or CO2-bearing NaCl-H2O with medium to low density (0.18-0.79 g/cm3).The fluid salinity and density both show a decline tendency with decreasing temperature.According to the measurement and calculation of Hand O-isotopic compositions in the quartz of the quartz-sulfide veins,δDV-SMOW of the ore-forming fluid is from-84‰ to-54‰,and δ18OV-SMOW of that is from 6.75‰ to 9.21‰,indicating a magmatic fluid.The δ34SV-CDT of sulfides in the ores fall into two groups,one is from-4.4‰ to 2.2‰ with average of-1.42‰,and the other from 18.8‰ to 21.6‰ with average of 19.8‰.The S-isotopic data shows one peak at-4.4‰ to 2.2‰ (meaning-1.42‰) suggesting a simple magmatic sulfur source.The ore Pbisotopic ratios are 206pb/204pb from 17.817 to 17.983,207pb/204pb from 15.470 to 15.620 and 208pb/204pb from 38.072 to 38.481,indicating characteristics of mantle-derived lead.The data show that the major ore deposits in the orefield have a magmatic-hydrothermal genesis and that the SHRIMP zircon age of the granodiorite porphyry,closely related to the mineralization,is 151.2±4.2 Ma (MSWD =1.3),which can represent the formation ages of the ores and intrusion rocks.The study aids understanding of the ore-forming processes of the major metallic ore deposits in the orefield.
文摘According to an analysis of the geological features in the eastern sector of the Bangong Co-Nujiang River suture zone, the Tethyan evolution can be divided into three stages. (1) The Embryo-Tethyan stage (Pz1): An immature volcanic arc developed in Taniantaweng (Tanen Taunggyi) Range, indicating the existence of an Embryo-Tethyan ocean. (2) The Palaeo-Tethyan stage (C-T2: During the Carboniferous the northern side of the Taniantaweng Range was the main domain of the Palaeo-Tethyan ocean, in which developed flysch sediments intercalated with bimodal volcanic rocks and oceanic tholeiite, and Pemian-Early Triassic are granites were superimposed on the Taniantaweng magmatic are; on the southern side the Dêngqên-Nujiang zone started secondary extension during the Carboniferous, in which the Nujiang ophiolite developed, and the Palaeo-Tethyan ocean closed before the Middle Triassic. (3) The Neo-Tethyan stage (T3-E): During the Late Triassic the Dêngqên zone developed into a relatively matural ocean basin, in which the Dêngqên ophiolite was formed. By the end of the Triassic intraocean subduction occurred, and the ocean domain was reduced gradually, and collided and closed by the end of the Early Jurassic, forming the Yazong mélange; then the Tethyan ocean was completely closed.
基金supported by the following projects:National Basic Research Program of China (2009CB421004,2009CB421003)Natural Science Foundation of China(41073033,40872055,and 40930316)+1 种基金Chinese Academy of Sciences(KZCX2-YW-Q04)China Geological Survey(1212010818098)
文摘The Nadingcuo high-K calc-alkaline rocks mainly composed of trachyte and trachyandesite are the largest outcrop area of volcanic rocks in southern Qiangtang terrane in the Tibetan plateau. However,their exact source and peterogenesis are still debated.^(40)Ar-^(39)Ar and LAM-ICPMS zircon U-Pb isotopic dating confirm that these rocks erupted in Eocene.In addition,the Nadingcuo volcanic rocks are characterized by high Sr/Y content ratios,similar with the adakite derived from partial melting of oceanic crust.They can be further classified as high Mg~#(Mg~#=48-57) and low Mg~# (Mg~#=33-42) subtypes.The Nadingcuo adakitic rocks have relatively low(^(87)Sr/^(86)Sr)_i and highε_(Nd)(t), showing a trend of similarity to the Dongcuo ophiolite present in the Bangong-Nujiang oceanic crust. Simple modeling indicates that the Nadingcuo adakitic rocks are a mix resulting from the basalt of Bangong-Nujiang Ocean with 10%-20%crustal material of Lhasa terrane.On these bases we suggest that the low Mg~# Nadingcuo adakitic rocks are the product of partial melting of remnant oceanic crust with small sediment,and the high Mg~# rocks are the result of reaction between rising melt of remnant oceanic crust with subducted sediment and mantle wedge.Therefore,the origin of Nadingcuo adakitic rocks may be related to intracontinental subduction triggered by collision of India-Asia during Cenozoic.
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA20070304)the National Science Foundation of China(Grant No.41373055)the Fundamental Research Funds for the Central Universities(Grant No.2652016126)
文摘The Tashisayi nephrite deposit is located in South Altyn Tagh.in Qiemo County,Xinjiang Province,northwest China.It is a recent discovery in the vast,well-known Kunlun-Altyn nephrite belt distributed along the south of the Tarim Basin,producing more than half of the nephrite from the whole belt in 2017.Field investigations revealed that it is a dolomitic marble-related(D-type)nephrite deposit,but little is known about its age of formation and relationships between the granites and marble.Here we report field investigations,petrography of the neph rite,as well as petrography,geochemistry,geochronology of the zoisite-quartz altered intrusive rock and adjacent granites.An A-type granite is identified with a SHRIMP U-Pb zircon age of 926±7 Ma,suggesting it was emplaced in an extensional tectonic environment at that time.The altered intrusive rock has a cluster of U-Pb zircon age of 433±10 Ma.with similar trace element features to the A-type granite,suggesting it was formed in an extensional regime at this later time.Nephrite formed because of the metasomatism of dolomite marble by hydrothermal fluids.It is inferred that Ca^2+was released from the dolomitic marble by metasomatism forming Ca-rich fluids,which caused alteration of both the intrusive rocks(6.00-8.22 wt.%CaO)and granite(1.76-3.68 wt.%CaO)near the nephrite ore bodies.It is also inferred that Fe^2+from the granite migrated towards the dolomite marble.The fluids gave rise to the formation of Ca-minerals.such as zoisite,in the nephrite and altered intrusive rock,and epidote in the granite.Based on the contact relationships.similarity in hydrothermal processes,and consumption of Ca^2+,the Tashisayi nephrite is considered to have formed at the same time as the alteration of the intrusive rocks,i.e.~433 Ma.The geochronological similarity(~926 Ma.433 Ma)of South Altyn and North Qaidam may suggest that tectonically they belong to one single complex in the past,which was offset by the Altyn Tagh fault(ATF).The similar formation ages of the nephrites from Altyn Tagh(433 Ma)and the previously studied areas of West Kunlun(378-441 Ma)and East Kunlun(416 Ma)indicate that these nephrites formed during the closure of Proto-Tethys and in the accompanving post-collisional.extensional environment.
基金supported by the Research Project of Shengyuan Mining Group Co.Ltd,Tibet(Grant No.XZSYKYJT-JSFW-2019-001)the Basic Research Fund of Institute of mineral Resource,Chinese Academy of Geological Sciences(Grant Nos.KJ2102,KK2116,KK2017)+2 种基金the National Natural Science Foundation of China(Grant No.41902097)the Science and Technology Plan Project of the Tibetan Autonomous Region(Grant No.XZ201901-GB-24)Geological Survey project(Grant No.DD20190167)。
文摘The Mamupu skarn-type Cu-Au polymetallic deposit represents the first discovery of a medium deposit in the southern Yulong porphyry copper belt(YPCB),eastern Tibet.The Cu-Au mineralization mainly occurs as chalcopyrite in breccia,within the plate-like carbonate interlayer,being closely related to chloritization(e.g.,chlorite,magnetite and epidote)and skarnization(e.g.,diopside,tremolite and garnet).The ore-related quartz syenite porphyry(QSP)and granodiorite porphyry(GP)were emplaced at 40.1±0.2 Ma and 39.9±0.3 Ma,respectively.The QSP of Mamupu is an alkaline-rich intrusion,relatively enriched in LREE,LILE,depleted in HFSE,with no significant negative Eu and Ce anomalies,slightly high(^(87)Sr/^(86)Sr)i,lowε_(Nd)(t),uniform(^(206)Pb/^(204)Pb)i andε_(Hf)(t)values,which indicates that the porphyry magma may be caused by both the mixing of metasomatized EM II enriched mantle and thickened juvenile lower crust.The QSP in the Mamupu deposit shares a similar genesis of petrology to other ore-related porphyries within the YPCB.High oxygen fugacity and water content of the magmas are essential for the formation of porphyry and skarn Cu deposits.The QSP has similar high magmatic oxidation states and water content to the Yulong deposit,which indicates that the Mamupu has a high prospecting potential.Differences in the geological characteristics and scale of mineralization between the Mamupu and other YPCB deposits may be due to the different emplacement depths of ore-related intrusions,as well as differences in the surrounding rocks.
基金funded by the project of Investigation and Exploration of Uranium Deposits in Bayingobi Basin(Grant No.201903,202203)China Nuclear Geology,CNNC。
文摘The Bayingobi basin is the Mesozoic-Cenozoic basin in North China in which the Tamusu uranium deposit is located.The ore-target layer of the deposit is the Lower Cretaceous Bayingobi Formation,which developed as a fan deltashallow lacustrine deposit.The distributary channel sand body of the fan delta plain and the underwater distributary channel sand body of the fan delta front formed a favorable uranium reservoir,so the study of sequence stratigraphy is extremely important to understanding the genesis of uranium deposits.On the basis of field investigation and a large number of borehole logs,the high resolution sequence stratigraphy of the Lower Cretaceous is divided and the system tracts of different periods are established.The relationship between deposition,interlayer oxidation and uranium enrichment is discussed.The Lower Cretaceous Bayingobi Formation can be divided into two fourth-order sequences(Sq1 and Sq2).The lower member of the Bayingobi Formation is referred to as Sq1,which is composed of a falling-stage system tract(FSST)on top.On the other hand,the upper member of the Bayingobi Formation is referred to as Sq2,which is composed of a lowstand system tract(LST),transgressive system tract(TST)and highstand system tract(HST).The lowstand system tract forms a favorable stratigraphic structure(mud-sand-mud formation)with the lacustrine mudstone of the overlying transgressive system tract,that is conducive for the migration of uranium-bearing oxygen water.The organic matter and pyrite in the fan delta sand body,as well as the dark mudstone in the distributary bay,provided a reducing medium for uranium mineralization.The ore body mainly occurs in the distributary channel,underwater distributary channel or the mouth bar of the fan delta.As a result of the moderate thickness,high permeability,favorable barrier and rich reducing medium,the rich ore body mainly occurs in the underwater distributary channel and mouth bar sand body of the delta front.Based on study of the sequence stratigraphy,the model of the sequence,sedimentation and mineralization of the uranium deposit is established,which enriches uranium metallogenic theory and provides a reference for exploration of the same type of uranium deposits.
基金This study was supported by the Natural Science Foundation of China(Nos.U1812402,41802116)Fundamental Research Funds for the Central Universities,China University of Geosciences(Wuhan)(Nos.CUG170684,CUGQY1908).
文摘The Lower Carboniferous Jiujialu Formation bauxite deposits of northern Guizhou Province,China,are a Kazakhstan subtype of karst bauxite deposits.The provenance of the Jiujialu Formation has long been debated,with uncertainty about the formation of the bauxite deposits.Here we report new geochemical data that indicate the affinity between the Lower-Middle Ordovician clastic rocks and argillaceous dolostones and the overlying Carboniferous bauxite deposits,all of which are characterized by high Al_(2)0_(3),K2_(O),and∑REE contents,flat post-Archean Australian shale(PAAS)-normalized REE patterns,and uniform immobile element ratios(TiO2/Al_(2)0_(3),Nb/TiO2,and Zr/TiO2).Their similar detrital zircon age distributions further indicate the link between the bauxite deposits and the clastic rocks and argillaceous dolostones.Zircon age spectra of clastic rocks of the Lower Silurian Hanchiatien Formation in northern Guizhou match those of the bauxite deposits,with a maximum age peak at-980 Ma and other secondary age peaks,suggesting these clastic rocks may represent the provenance of the bauxite deposits.The youngest detrital zircons(-445 Ma)occur only in the bauxite deposits and are probably sourced from K-bentonite beds of the Ordovician-Silurian tran-sition.Our analyses indicate that the source materials of the bauxite deposits in the Jiujialu Formation are of mixed provenance:Lower-Middle Ordovician aluminosilicate rocks and argillaceous dolostones of the underlying strata,and Lower Silurian clastic rocks and K-bentonite from adjacent areas.A comparison of Early Carboniferous bauxitic provenances in northern and central Guizhou indicates that paleotopography was the major factor controlling the provenance of these bauxite deposits.
基金financially supported by the National Key Basic Research Program (Grant2012CB416704) from the Ministry of Science and Technology, Chinagrant No. 40772063 from the National Natural Science Foundation of China+1 种基金the Program of Excellent Young Scientists from the Ministry of Land and Resources (200809)Geological Survey Program Grant 1212010561603-2 from the China Geological Survey
文摘Previous studies have obtained some petrogenetic and metallogenic chronological data with SHRIMP (sensitive high-resolution ion microprobe) zircon U-Pb, zircon LA-ICPMS (laser-ablation-inductively coupled plasma mass spectroscopy) U-Pb, molybdenite Re-Os isochron and muscovite Ar-Ar methods in southern Jiangxi Province and its adjacent areas. Based on these, the purpose of this paper is to study the petrogenetic and metallogenic ages and their time gap for different genetic types of W-Sn deposits, and thus to research their numerous episodes, zonal arrangement and their geodynamic background. The result shows that the large-scale W-Sn mineralization in southern Jiangxi Province occurred in the middle to late Jurassic (170-150 Ma), the skarn W-Sn-polymetallic deposits formed much earlier (170-161 Ma), and all of the wolframite-quartz vein type, greisen type, altered granite type and fractured zone type tungsten deposits formed in the late Jurassic (160-150 Ma). In one ore field or ore district, greisen type tungsten deposits formed earlier than quartz vein type ones hosted in the endoor exo-contact zone; and quartz vein type hosted in the endocontact zone formed earlier than that of exocontact zone. There is no significant time difference between tungstentin mineralization and its intimately associated parent granite emplacement (1-6 Ma). They all formed in the same rock-forming and ore-forming system and under the same geodynamic setting. Regionally, rock-forming and ore-forming processes of the W-Sn deposits in the Nanling region (include southern Jiangxi Province, southern Hunan Province, northern Guangdong Province and eastern Guangxi Zhuang Autonomous Region) exhibit numerous episodes. The mineralization in the Nanling region mainly occurred at (240-210) Ma, (170-150) Ma and (130-90) Ma. The tungsten-tin deposits in this region are centered by the largest scale in southern Jiangxi Province and southern Hunan Province, and become small in the east, west, south and north directions. This displays a zonal arrangement and temporal and spatial distribution regularity. Integrated with the latest research results, it is concluded that the W-Sn mineralization in southern Jiangxi Province and its adjacent areas corresponds to the second large-scale mineralization in South China. The Indosinian W-Sn mineralization formed under the extensional tectonic regime between collisional compressional stages, while the Yanshanian large-scale petrogenetic and metallogenic processes occurred in the Jurassic intraplate extensional geodynamic setting of lithosphere extension.
基金supported by China Geological Survey Development Research Center Program(Grant No.DD2016005234)Geological exploration fund Program of Jiangxi Province(Grant No.20160010)Jiangxi Bureau of Geology&Mineral Exploration Program(Grant No.201698)。
文摘The Pengshan Sn-polymetallic ore field is located in the southeastern part of the Yangtze block,spanning the southeast edge of the MLYDZ and the northern edge of the mid-segment of the Jiangnan Uplift,and on one side of the MLYDZ.The studies of LA-ICP-MS zircon U-Pb chronology and petrogeochemistry for Early Cretaceous acid granites from the Pengshan ore field were carried out in this paper.We report zircon U-Pb geochronology and whole-rock geochemistry for acid granites in the Pengshan ore field.The zircon U-Pb ages of the muscovite-granite,biotite adamellite and granite-porphyry are 127.6±1.7 Ma,126.9±1.6 Ma and 126.6±2.0 Ma,respectively.The granites in Pengshan are characterized by a high silicon content and are rich in alkali.They belong to high-potassium,calc-alkaline,peraluminous granite.The rocks have a relatively high Rb/Ba ratio,and the data points for muscovite-granite and biotite adamellite all fall within the clay-rich sources region,near the pelite-derived end-member,showing that the Pengshan muscovite-granite and biotite adamellite mainly originated from the partial melting of metapelites with high maturity.The transformation of the compressional and extensional tectonics in this region approximately 128 Ma obviously lags behind that in the mid-segment of the Jiangnan Uplift(135 Ma),but occurred earlier than the MLYDZ(126 Ma).The Pengshan ore field extends from the mid-segment of the Jiangnan Uplift to the MLYDZ.Although the tectonic stress field is constrained by the combination of the two secondary tectonic units,the time of tectonic system transformation is closer to the MLYDZ because the spatial orientation of the area is enclosed in the MLYDZ.Relevant geophysical and drilling data confirm the rationality of Pengshan-Ao'xia as a multi-center vertical zoning ore field,and show the scientificity of the prospecting idea of abutting joint between the north-west of Pengshan area and the south-east of Ao'xia area.
基金funded by the China Geological Survey (No. 1212011220731)
文摘The Weiquan Ag-polymetallic deposit is located on the southern margin of the Central Asian Orogenic Belt and in the western segment of the Aqishan-Yamansu arc belt in East Tianshan,northwestern China. Its orebodies, controlled by faults, occur in the lower Carboniferous volcanosedimentary rocks of the Yamansu Formation as irregular veins and lenses. Four stages of mineralization have been recognized on the basis of mineral assemblages, ore fabrics, and crosscutting relationships among the ore veins. Stage I is the skarn stage(garnet + pyroxene), Stage Ⅱ is the retrograde alteration stage(epidote + chlorite + magnetite ± hematite 士 actinolite ± quartz),Stage Ⅲ is the sulfide stage(Ag and Bi minerals + pyrite + chalcopyrite + galena + sphalerite + quartz ± calcite ± tetrahedrite),and Stage IV is the carbonate stage(quartz + calcite ± pyrite). Skarnization,silicification, carbonatization,epidotization,chloritization, sericitization, and actinolitization are the principal types of hydrothermal alteration. LAICP-MS U-Pb dating yielded ages of 326.5±4.5 and 298.5±1.5 Ma for zircons from the tuff and diorite porphyry, respectively. Given that the tuff is wall rock and that the orebodies are cut by a late diorite porphyry dike, the ages of the tuff and the diorite porphyry provide lower and upper time limits on the age of ore formation. The δ13C values of the calcite samples range from-2.5‰ to 2.3‰, the δ18OH2 Oand δDVSMOWvalues of the sulfide stage(Stage Ⅲ) vary from 1.1‰ to 5.2‰ and-111.7‰ to-66.1‰, respectively,and the δ13C, δ18OH2 Oand δDV-SMOWvalues of calcite in one Stage IV sample are 1.5‰,-0.3‰, and-115.6‰, respectively. Carbon, hydrogen, and oxygen isotopic compositions indicate that the ore-forming fluids evolved gradually from magmatic to meteoric sources. The δ34SV-CDTvalues of the sulfides have a large range from-6.9‰ to 1.4‰, with an average of-2.2‰, indicating a magmatic source, possibly with sedimentary contributions. The206Pb/204Pb,207Pb/204Pb, and208Pb/204Pb ratios of the sulfides are 17.9848-18.2785,15.5188-15.6536, and 37.8125-38.4650, respectively, and one whole-rock sample at Weiquan yields206Pb/204Pb,207Pb/204Pb, and208Pb/204Pb ratios of 18.2060, 15.5674, and 38.0511,respectively. Lead isotopic systems suggest that the ore-forming materials of the Weiquan deposit were derived from a mixed source involving mantle and crustal components. Based on geological features, zircon U-Pb dating, and C-H-OS-Pb isotopic data, it can be concluded that the Weiquan polymetallic deposit is a skarn type that formed in a tectonic setting spanning a period from subduction to post-collision. The ore materials were sourced from magmatic ore-forming fluids that mixed with components derived from host rocks during their ascent, and a gradual mixing with meteoric water took place in the later stages.
基金supported by National Natural Science Foundation of China grant 40473027 and 40773031Foundation of Open Subjects of the State Key Laboratory of Geological Processes and Mineral Resources of the China University of Geosciences grant GPMR0509 and GPMR200705the Project of the State Key(Preparation Support)Disciplines of Mineralogy,Petrology and Mineral Deposit Geology of Sichuan Province.
文摘Three special types of xenoliths have recently been found in an aegirine-augite syenite porphyry in Liuhe, Yunnan, China. Petrographical, petrochemical, electron microprobe, and scanning electron microscopy studies indicate that pure calcite xenocrysts and quartz-bearing topaz pegmatite xenoliths result from the degassing of mantle fluids during their migration, and that black microcrystalline iron-rich silicate-melt xenoliths are the product of the extraction of mantle fluids accompanying degassing and are composed dominantly of quartz, chlorite, and iron-rich columnar and sheet silicate minerals with characteristic minerals, such as native iron, apatite, and zircon. According to the bulk-rock chemical and mineral compositions and crystallization states, the microcrystalline melt xenoliths are not the product of conventional magmatism, and especially the existence of native iron further proves that the xenoliths were mantle fluid materials under reduction or anoxic conditions. The study of the special xenoliths furnishes an important deep-process geochemical background of polymetallic mineralization in different rocks and strata in the study area.
基金This paper is supported by the National 305 Program (Nos. 2001BA609A-07-02, 2006BAB07B02-04)Research Foundation of former Ministry of Geology and Mineral Re-sources of China (No.96-21)
文摘The ductile shear zone-type gold deposit is a kind that both the ore-forming mechanism and ore-controlling factors are closely related to the ductile shear zone and its evolution. Ductile shear zone develops in Beishan area, Gansu of Northwest China, and develops especially well in the south belt. The controls of the ductile shear zone on gold deposits are as follows. (1) The regional distribution of gold deposits (and gold spots) is controlled by the ductile shear zone. (2) The ductile-brittle shear zone is formed in the evolution process of ductile shear zone and both are only ore-bearing structures and control the shape, attitude, scale, and distribution of mineralization zones and ore-bodies. (3) Compresso-shear ductile deformation results in that the main kind of gold mineralization is altered mylonite type and the main alteralization is metasomatic. (4) Ore-bearing fracture systems are mainly P-type ones, some D-type and R-type ones, but only individual R'-type and T-type ones. (5) Dynamic differen- tiation and dynamic metamorphic hydrothermal solution resulting from ductile deformation is one of the sources of ore-forming fluid of gold mineralization, and this is identical with that ore-forming materials are mainly from metamorphic rocks, and ore-forming fluid is mainly composed of metamorphic water, and with the fluid inclusion and geo-chemical characteristics of the deposit. (6) There is a negative correlation between the gold abundance and susceptibility anlsotropy (P) of the altered mylonlte samples from the deposit, which shows that the gold mineralization is slightly later than the structural deformation. All above further expound the ore-forming model of the ductile shear zone type of gold deposits.