This study presents a fully coupled thermo-hydro-mechanical (THM) constitutive model for clay rocks. The model is formulated within the elastic-viscoplasticity framework, which considers nonlinearity and softening aft...This study presents a fully coupled thermo-hydro-mechanical (THM) constitutive model for clay rocks. The model is formulated within the elastic-viscoplasticity framework, which considers nonlinearity and softening after peak strength, anisotropy of stiffness and strength, as well as permeability variation due to damage. In addition, the mechanical properties are coupled with thermal phenomena and accumulated plastic strains. The adopted nonlocal and viscoplastic approaches enhance numerical efficiency and provide the possibility to simulate localization phenomena. The model is validated against experimental data from laboratory tests conducted on Callovo-Oxfordian (COx) claystone samples that are initially unsaturated and under suction. The tests include a thermal phase where the COx specimens are subjected to different temperature increases. A good agreement with experimental data is obtained. In addition, parametric analyses are carried out to investigate the influence of the hydraulic boundary conditions (B.C.) and post-failure behavior models on the THM behavior evolution. It is shown that different drainage conditions affect the thermally induced pore pressures that, in turn, influence the onset of softening. The constitutive model presented constitutes a promising approach for simulating the most important features of the THM behavior of clay rocks. It is a tool with a high potential for application to several relevant case studies, such as thermal fracturing analysis of nuclear waste disposal systems.展开更多
The increase in the frequency and intensity of drought events expected in the coming decades in Western Europe may disturb forest biogeochemical cycles and create nutrient deficiencies in trees.One possible origin of ...The increase in the frequency and intensity of drought events expected in the coming decades in Western Europe may disturb forest biogeochemical cycles and create nutrient deficiencies in trees.One possible origin of nutrient deficiency is the disturbance of the partitioning of the green leaf pool during the leaf senescence period between resorption,foliar leaching and senesced leaves.However,the effects of drought events on this partitioning and the consequences for the maintenance of tree nutrition are poorly documented.An experiment in a beech forest in Meuse(France)was conducted to assess the effect of drought events on nutrient canopy exchanges and on the partitioning of the green leaf pool during the leaf senescence period.The aim was to identify potential nutritional consequences of droughts for trees.Monitoring nutrient dynamics,including resorption,chemistry of green and senesced leaves,foliar absorption and leaching in mature beech stands from 2012 to 2019 allowed us to compare the nutrient exchanges for three nondry and three dry years(i.e.,with an intense drought event during the growing season).During dry years,we observed a decrease by almost a third of the potassium(K)partitioning to resorption(i.e.resorption efficiency),thus reducing the K reserve in trees for the next growing season.This result suggests that with the increased drought frequency and intensity expected for the coming decades,there will be a risk of potassium deficiency in trees,as already observed in a rainfall exclusion experiment on the same study site.Reduced foliar leaching and higher parititioning to the senesced leaves for K and phosphorus(P)were also observed.In addition,a slight increase in nitrogen(N)resorption efficiency occurred during dry years which is more likely to improve tree nutrition.The calcium(Ca)negative resorption decreased,with no apparent consequence in our study site.Our results show that nutrient exchanges in the canopy and the partitioning of the green leaf pool can be modified by drought events,and may have consequences on tree nutrition.展开更多
The enhanced coalbed methane recovery using CO_(2) injection(CO_(2)-ECBM)is widely proposed as a way of achieving the energy transition and reducing atmospheric CO_(2),in areas such as the Lorrain basin in France,wher...The enhanced coalbed methane recovery using CO_(2) injection(CO_(2)-ECBM)is widely proposed as a way of achieving the energy transition and reducing atmospheric CO_(2),in areas such as the Lorrain basin in France,where heavy industry is responsible for huge CO_(2) emissions and coal mines have been closed for more than a decade.This paper deals with the feasibility of extracting methane from the Lorraine basin using CO_(2)-ECBM by comparing data from sorption isotherms,thermogravimetric analyses and breakthrough curves for two coal samples.One is bituminous(Box 18),from Folschviller(France)and is compared with another sub-bituminous(THO1)from La Houve(France),which is used as a reference because it was identified as a good candidate for CO_(2)-ECBM in a previous research program.The quantities of adsorbed gases(CO_(2)/CH_(4))obtained by sorption isotherms,thermogravimetry and CO,breakthrough curves showed that Box 18 adsorbs more CO_(2) and CH_(4) than THO1 due to its higher porosity and good affinity for gases(CO_(2)/CH_(4)).Toth model fits the experimental CH_(4) and CO_(2) adsorption isotherms better,reflecting the fact that the adsorption surface of the coals studied is heterogeneous.Adsorption enthalpies obtained by calorimetry indicated physisorption for gas-coal interactions,with higher values for CO_(2) than for CH_(4).Thermogravimetric analyses and breakthrough curves carried out at up to 50%relative humidity showed that the adsorption capacity of CO_(2) decreases with increasing temperature and the presence of water,respectively.The compilation of these experimental data explained the adsorption process of the studied coals and revealed their advantages for CO_(2)-ECBM.展开更多
Rivers are progressively being exposed to increased anthropogenic pollution stresses that are undermining their designated uses and affecting sensitive coastal areas. In this study, three adjacent eastern Mediterranea...Rivers are progressively being exposed to increased anthropogenic pollution stresses that are undermining their designated uses and affecting sensitive coastal areas. In this study, three adjacent eastern Mediterranean coastal rivers, Ibrahim, Kaleb and Beirut, were evaluated. Water quality samples were collected in dry and wet seasons from different sampling sites along the river from the source to the outlet which represent a gradient of increased urbanization. The spatiotemporal variability of the physio-chemical properties, heavy metals (Zn, Pb, Cu, Cr, and Cd) and organic matter (DOC) were statistically analyzed to better understand the contribution of point and nonpoint pollution sources. The three rivers (Beirut, Kaleb and Ibrahim) show a similar behavior in calcium and carbonate alkalinity due to the carbonate mineral weathering effect, so they are of calcium bicarbonate type due to their calcareous geological nature. The speciation of anions was affected by temporal variation. Moreover, it is obvious that the Beirut River has a different behavioral characteristic where the water is a sulfate type water with a preferable metal-OM complexation mainly with lead, zinc and copper, whereas Kaleb and Ibrahim are considered to be of a nitrate phosphate type with a preferable metal inorganic complexation, especially copper, that has a consistent behavior in both types of waters. This difference is attributed to the urbanization effect highly impacting the Beirut River.展开更多
Landscape urbanization broadly affects ecosystems in coastal watersheds, but, until now, the influence of nonpoint source urban inputs on dissolved organic matter (DOM) amount, composition, and source is poorly unders...Landscape urbanization broadly affects ecosystems in coastal watersheds, but, until now, the influence of nonpoint source urban inputs on dissolved organic matter (DOM) amount, composition, and source is poorly understood. To understand how DOM composition varied with urbanization, fluorescence excitation-emission matrices (EEMs) were determined for urban and non-urban waters from upstream to downstream sites along three adjacent coastal watersheds that flow into the Mediterranean Sea. Two humic DOM fluorescent components (humic-like and fulvic-like peaks) and two proteinic components (tyrosine-like and tryptophane-like peaks) were identified by EEM fluorescence. The results indicated that urbanization had an important influence on DOM concentration and composition, with urban waters having a high degree of DOM variation due to different land uses surrounding each body of water. Urban waters show a higher DOM fluorescence index (FI), the highest fluorescence intensity of protein-like manifested also by BIX values, and a lower value of the humification index (HIX) than non-urban waters which were dominated by allochthonous inputs. In addition, the EEM was compared in dry and wet season where higher DOM amounts and FI appeared in summer due to autochthonous production coming from algae growth compared to allochthonous input from rainfall dominated in wet season. The concentration of DOC increased from upstream to downstream for the three rivers, especially Beirut River. The increase in DOC values was observed in both dry and wet seasons by 39 and 19 times respectively compared to upstream (0.93 - 0.91 mgC/L).展开更多
Alteration minerals and silicification are typically associated with a variety of ore mineralizations and could be detected using multispectral remote sensing sensors as indicators for mineral exploration.In this inve...Alteration minerals and silicification are typically associated with a variety of ore mineralizations and could be detected using multispectral remote sensing sensors as indicators for mineral exploration.In this investigation,the Visible Near-Infra-Red(VNIR),Short-Wave Infra-Red(SWIR),and Thermal Infra-Red(TIR)bands of the ASTER satellite sensor derived layers were fused to detect alteration minerals and silicification in east the Kerdous inlier for cupriferous mineralization exploration.Several image processing techniques were executed in the present investigation,namely,Band Ratio(BR),Selective Principal Component Analysis(SPCA)and Constrained Energy Minimization(CEM)techniques.Initially,the BR and SPCA processing results revealed several alteration zones,including argillic,phyllic,dolomitization and silicification as well as iron oxides and hydroxides.Then,these zones were mapped at sub-pixel level using the CEM technique.Pyrophyllite,kaolinite,dolomite,illite,muscovite,montmorillonite,topaz and hematite were revealed displaying a significant distribution in relation with the eastern Amlen region lithological units and previously detected mineral potential zones using HyMap imaging spectroscopy.Mainly,a close spatial association between iron oxides and hydroxide minerals,argillic,and phyllic alteration was detected,as well as a strong silicification was detected around doleritic dykes unit in Jbel Lkest area.A weighted overlay approach was used in the integration of hydrothermal alteration minerals and silicification,which allowed the elaboration of a new mineral alteration map of study area with five alteration intensities.ASTER and the various employed processing techniques allowed a practical and cost effective mapping of alteration features,which corroborates well with field survey and X-ray diffraction analysis.Therefore,ASTER data and the employed processing techniques offers a practical approach for mineral prospection in comparable settings.展开更多
Toarcian claystone such as that of the Callovo-Oxfordian is a qualified multiphase material. The claystone samples tested in this study are composed of four main mineral phases: silicates(clay minerals, quartz,feldspa...Toarcian claystone such as that of the Callovo-Oxfordian is a qualified multiphase material. The claystone samples tested in this study are composed of four main mineral phases: silicates(clay minerals, quartz,feldspars, micas)(z86%), sulphides(pyrite)(z3%), carbonates(calcite, dolomite)(z10%) and organic kerogen(z1%). Three sets of measurements of the modulus of deformability were compared as determined in(i) nanoindentation tests with a constant indentation depth of 2 mm,(ii) micro-indentation tests with a constant indentation depth of 20 mm, and(iii) meso-compression tests with a constant displacement of 200 mm. These three experimental methods have already been validated in earlier studies. The main objective of this study is to demonstrate the influence of the scaling effect on the modulus of deformability of the material. Different frequency distributions of the modulus of deformability were obtained at the different sample scales:(i) in nano-indentation tests, the distribution was spread between 15 GPa and 90 GPa and contained one peak at34 GPa and another at 51 GPa;(ii) in the micro-indentation tests, the distribution was spread between 25 GPa and 60 GPa and displayed peaks at 26 GPa and 37 GPa; and(iii) in the meso-compression tests, a narrow frequency distribution was obtained, ranging from 25 GPa to 50 GPa and with a maximum at around 35 GPa.展开更多
Felsic intrusions present ubiquitous structures.They result from the differential interactions between the magma components(crystal,melt,gas phase) while it flows or when the flow is perturbed by a new magma injection...Felsic intrusions present ubiquitous structures.They result from the differential interactions between the magma components(crystal,melt,gas phase) while it flows or when the flow is perturbed by a new magma injection.The most obvious structure consists in fabrics caused by the interactions of rotating grains in a flowing viscous melt.New magma inputs through dikes affect the buk massif flow,considered as global within each mineral facies.A review of the deformation and flow types developing in a magma chamber identifis the patterns that could be expected.It determines their controlling parameters and summarizes the tools for their quantification.Similarly,a brief review of the theology of a complex multiphase magma identifies and suggests interactions between the different components.The specific responses each component presents lead to instability development.In particular,the change in vorticity orientation,associated with the switch between monoclinic to triclinic flow is a cause of many instabilities.Those are preferentially local.Illustrations include fabric development,shear zones and flow banding.They depend of the underlying rheology of interacting magmas.Dikes,enclaves,schlieren and ladder dikes result from the interactions between the magma components and changing boundary conditions.Orbicules,pegmatites,unidirectional solidification textures and miarolitic cavities result from the interaction of the melt with a gaseous phase.The illustrations examine what is relevant to the bulk flow,local structures or boundary conditions.In each case a field observation illustrates the instability.The discussion reformulates instability observations,suggesting new trails for ther description and interpretation in terms of local departure to a bulk flow.A brief look at larger structures and at their evolution tries to relate these instabilities on a broader scale.The helical structures of the Ricany pluton,Czech Republic and by the multiple granitic intrusions of Dolbel,Niger illustrate such events.展开更多
Landsat 8 Oli,ASTER,and Sentinel 2A satellite images processing was used to map geological formations,lineaments and hydrothermal alteration minerals in the Aouli inlier,as a case study to illustrate the application o...Landsat 8 Oli,ASTER,and Sentinel 2A satellite images processing was used to map geological formations,lineaments and hydrothermal alteration minerals in the Aouli inlier,as a case study to illustrate the application of digital images processing and Geographic Information System(GIS)in geological mapping and mining prospecting.Principal Component Analysis(PCA)applied to the Landsat images allowed good lithological discrimination and contributed to the updating of available geological maps.The Automatic lineament extraction from Sentinel images revealed the main tectonic structures affecting Aouli inlier.The ratio bands(b5+b7)/b6 and the false color composite(b4/b6,b2/b1,b3/b2)allowed the hydrothermal alteration minerals mapping from Aster images.Combined with available geological data and field observations,the satellite derived data were integrated and analyzed in a GIS software to establish mining prospecting guides.The results showed that the anomaly zones are intimately linked to NNE-SSW and NW-SE oriented faults and to highly fractured areas developing argillic and Fe rich alterations.Verified via field survey,this approach was successfully applied to the Aouli inlier to rapidly target potential areas to be explored in the tactical phase.This provides a model for future prospecting efforts for similar mineral deposits in other areas.展开更多
Deep mineral exploration is increasingly important for finding new mineral resources but there are many uncertainties.Understanding the factors controlling the localization of mineralization at depth can reduce the ri...Deep mineral exploration is increasingly important for finding new mineral resources but there are many uncertainties.Understanding the factors controlling the localization of mineralization at depth can reduce the risk in deep mineral exploration.One of the relatively poorly constrained but important factors is the hydrodynamics of mineralization.This paper reviews the principles of hydrodynamics of mineralization,especially the nature of relationships between mineralization and structures,and their applications to various types of mineralization systems in the context of hydrodynamic linkage between shallow and deep parts of the systems.Three categories of mineralization systems were examined,i.e.,magmatic-hydrothermal systems,structurally controlled hydrothermal systems with uncertain fluid sources,and hydrothermal systems associated with sedimentary basins.The implications for deep mineral exploration,including potentials for new mineral resources at depth,favorable locations for mineralization,as well as uncertainties,are discussed.展开更多
Southern India and Sri-Lanka are the places where “incipient charnockites”,i.e.the local transformation of amphibolite-facies gneisses into orthopyroxene-bearing,igneous looking charnockites,have been discovered in ...Southern India and Sri-Lanka are the places where “incipient charnockites”,i.e.the local transformation of amphibolite-facies gneisses into orthopyroxene-bearing,igneous looking charnockites,have been discovered in the early sixties.The fact that some incipient charnockites occur along a network of brittle fractures,together with CO_(2) remnants preserved in mineral inclusions,had called for the role of fluids during charnockite alteration.The present work presents new observations on fluid inclusions and microtextures of incipient charnockites from type localities in southern India.In addition to CO_(2)-rich fluid inclusions in quartz and feldspar,all of the occurrences have disrupted remnants of concentrated aqueous alkali chloride solutions.CO_(2) inclusions are more abundant in paragneiss (Kerala) than in orthogneiss (Karnataka/Tamil Nadu).The finding of disrupted brine inclusions in the Kabbal charnockite is a key link between closely associated massive charnockites and Closepet Granite,both of which also share the brine remnants.All of the occurrences studied here have feldspar or feldspar-quartz microvein networks along grain boundaries of recrystallized quartz,feldspar and orthopyroxene.These metasomatic veins again indicate the action of alkali-exchanging fluids (i.e.,saline solutions).Feldspar microveins,which have been found in most “massive” charnockites,along with the CO_(2)-rich fluid inclusions,suggest a commonality of incipient charnockite and massive charnockite,both types differing in intensity of interaction with metasomatizing pore fluids.展开更多
During granulite-facies metamorphism of metasedimentary rocks by the infiltration of carbonic fluids, the disappearance of hydrated minerals leads to the liberation of aqueous fluids. These fluids are strongly enriche...During granulite-facies metamorphism of metasedimentary rocks by the infiltration of carbonic fluids, the disappearance of hydrated minerals leads to the liberation of aqueous fluids. These fluids are strongly enriched in F and C1, and a series of Large-lon-Lithophile （LIL） elements and rare metals, resulting in their depletion in granulites. To sum up the fate of these elements, we focus on three domains representing different crustal levels and showing distinct behaviours with respect to these elements. The Lapland metasedimentary granulites illustrate the behaviour of the LILE and rare metals during lower crustal metamorphism. There is no change in Ba, moderate loss in Rb, and extreme depletion in Cs, Li, and Sn. F and CI contents are also very low compared to the protoliths or average upper continental crust. Biotite and amphibole breakdown leads to the incorporation of their partitioning into a fluid or a melt. The Tranomaro metasomatized marbles recrystallizing under granulite-facies conditions represent a demonstrative example of fluid transfer from granulite-facies supracrustals to traps represented by regional scale skarns. Such fluids may be at the origin of the incompatible element enrichment detected in leucosomes of migmatites from St Malo in Brittany （France） and Black Hills in South Dakota, The northern French Massif Central provides us with an example of a potential association between incompatible element enrichment of granitic melts and granulite-facies metamorphism. U- and F- enriched fine-grained granites are emplaced along a crustal scale shear zone active during the emplacement within the St Sylvestre peraluminous leucogranitic complex, We propose that during granulite-facies metamorphism dominated by carbonic waves in a deep segment of the continental crust, these shear zones control： （i） the percolation of F-, LILE-, rare metal-rich fluids liberated primarily by the breakdown of biotite; （ii） the enhancement of partial melting by F-rich fluids at intermediate crustal levels with the generation of F-, LILE-, rare metal-rich granitic melts; （iii） their transfer through the crust with protracted fractionation facilitated by their low viscosity due to high F-Li contents; and finally （iv） their emplacement as rare metal intrusions at shallow crust levels.展开更多
Analysis and prediction of structural instabilities in open pit mines are an important design and operational consideration for ensuring safety and productivity of the operation. Unstable wedges and blocks occurring a...Analysis and prediction of structural instabilities in open pit mines are an important design and operational consideration for ensuring safety and productivity of the operation. Unstable wedges and blocks occurring at the surface of the pit walls may be identified through three-dimensional(3D) image analysis combined with the discrete fracture network(DFN) approach. Kinematic analysis based on polyhedral modelling can be used for first pass analysis but cannot capture composite failure mechanisms involving both structurally controlled and rock mass progressive failures. A methodology is proposed in this paper to overcome such limitations by coupling DFN models with geomechanical simulations based on the discrete element method(DEM). Further, high resolution photogrammetric data are used to identify valid model scenarios. An identified wedge failure that occurred in an Australian coal mine is used to validate the methodology. In this particular case, the failure surface was induced as a result of the rock mass progressive failure that developed from the toe of the structure inside the intact rock matrix. Analysis has been undertaken to determine in what scenarios the measured and predicted failure surfaces can be used to calibrate strength parameters in the model.展开更多
The olive species(Olea europaea L.)is an ancient traditional crop grown under rainfed conditions in the Mediterranean Basin.In response to the growing national and international demand for olive oil,the olive cultivar...The olive species(Olea europaea L.)is an ancient traditional crop grown under rainfed conditions in the Mediterranean Basin.In response to the growing national and international demand for olive oil,the olive cultivars are introduced into highly arid new bioclimatic areas.Subsequently,the morpho-physiology and phytochemistry of olive trees are potentially changing among cultivar types and geographical conditions.In the present work,we have undertaken an assessment on the impacts of geographical location and cultivar types on the leaf morpho-physiology and phytochemistry of olive trees.Thus,leaves of the two most cultivated olive tree varieties,Chemlal and Sigoise,were collected from three geographical regions(Setif,Batna,and Eloued)with increasing aridity in Algeria.Leaf samples from the geographical regions were analyzed using the standard physiological experiment,colorimetric method,and a chromatography assay.Leaves of both cultivars exhibited a significant variance in terms of the leaf shape index but not for the leaf tissue density,specific leaf weight,and specific leaf area.Photosynthetic pigment contents were affected by both cultivar type and geographical location,with the lowest pigment content recorded in the Sigoise cultivar from the Setif region.Compared with the Setif and Batna regions,dried leaves of both cultivars from the Eloued region showed the higher levels of the total polyphenol,total flavonoid,and total tannin,as well as a better antioxidant capacity.Liquid chromatography-mass spectrometry analysis of all leaf extracts identified the following phenolic acids as major compounds:oleuropein,naringin,apigenin-7-O-glucoside,kaempferol,quercetin,quercitrin,luteolin-7-O-naringenin,and quinic acid.Lower contents were found for p-Coumaric acid,trans-Ferulic acid,hyperoside,rutin,apigenin,caffeic acid,protocatechuic acid,o-Coumaric acid,and gallic acid.Also,epicatechin and catechin+were not found in the leaf extracts of the Sigoise cultivar.The leaf organic extracts in both cultivars displayed promising anti-cancer activity that was affected by geographical location and organic solvent polarity.Briefly,although increasing aridity and soil organic and mineral deficiency affected the leaf morpho-physiological parameters,both cultivars sustained a chemical richness,a good antioxidant,and an anti-tumoral capacity in leaves.Furthermore,the findings revealed that regardless the olive tree genotype,there was a significant impact of geographical location on the leaf morpho-physiology,bioactivity,and chemical composition,which may consequently modulate the growth and oil production of olive trees.展开更多
Agriculture is harming its own future through soil degradation and pollution of the water that it generates. The different chemical analyses carried out on surface waters and the land surveys carried out in the Nakanb...Agriculture is harming its own future through soil degradation and pollution of the water that it generates. The different chemical analyses carried out on surface waters and the land surveys carried out in the Nakanbé basin have shown that agricultural practices contribute to water pollution. The monitoring of nitrate, orthophosphate and BOD5 levels in the dams of Goinré, Ziga and Bagré during the period from August to December revealed that agricultural practices lead to variation in these parameters. The average values for nitrates are 0.833 mg/L in the Goinré fresh waterbody, 1.372 mg/L in the Ziga reservoir, and 1.267 mg/L in the Bagré fresh waterbody. As for ortho phosphate, mean values are 0.357 mg/L in the Goinré reservoir, 0.157 mg/L in the Ziga reservoir and 0.123 mg/L in the Bagré reservoir. These average values are higher than the norms established by Nisbet and Vernaux (1970) for eutrophication. Nitrates and orthophosphate are the elements that contribute to the eutrophication of water surfaces in the Nakanbé basin, although this eutrophication is of low intensity. Of all pesticides encountered in our study sites, 45% are registered by the Sahelian Pesticides Committee (CSP): 35% are non-accredited and 20% are unknown in the global list authorized by the CSP in 2010.展开更多
There are several techniques that were developed for determining the linear features. Lineament extraction?from satellite data has been the most widely used applications in geology. In the present study, lineament has...There are several techniques that were developed for determining the linear features. Lineament extraction?from satellite data has been the most widely used applications in geology. In the present study, lineament has?been extracted from the digital satellite scene (Landsat 5, TM data), in the region of Zahret Median situated in the north west of Tunisia. The image was enhanced and used for automatic extraction. Several directions of features were mapped. The directions of major invoices are NE-SW and NW-SE oriented. The validation of the obtained results is carried out by comparison with the results geophysics as well as to the studies previous of mapping developed in the sector of study.展开更多
Lizardite rich peridotite has never been used to prepare ceramic specimens,especially in Morocco.For this raison,potential use of naturally abundant lizarditic material from the Rif domain,as a supply for ceramic indu...Lizardite rich peridotite has never been used to prepare ceramic specimens,especially in Morocco.For this raison,potential use of naturally abundant lizarditic material from the Rif domain,as a supply for ceramic industry,has been evaluated.The effects of lizardite addition to magnesite and dolomite mixtures on the thermomechanical properties of the calcined ceramics were also detailed.To achieve this target,natural lizardite,magnesite and dolomite samples were collected in ultrabasic Beni Bousra massif.Those raw samples were used for the synthesis of a forsterite-monticellite rich ceramics.Both raw and sintered samples were characterized by x-ray diffraction,scanning electron microscope and fourier transform infrared.The obtained results showed that both magnesite and dolomite were mainly composed of MgCO_(3) and CaCO_(3).In contrast,lizardite sample showed high amounts of SiO_(2),MgO and Fe2O_(3).An increased amount of lizardite in the initial mixtures enhanced mechanical and dimensional properties of the prepared ceramic specimens,and subsequently,the production of ceramics with the required technological properties.Thus,the preparation of Moroccan lizardite-based ceramics is technically feasible,economically justifiable and socially desirable due to the contribution to the economic growth of the raw materials sector,especially ceramic industry.展开更多
Micro-mechanical properties of a claystone were tested after undergoing alkaline perturbation on site(Tournemire,CD borehole)for 18 years.In a saturated context and outside the excavation disturbed zone(EDZ),the clays...Micro-mechanical properties of a claystone were tested after undergoing alkaline perturbation on site(Tournemire,CD borehole)for 18 years.In a saturated context and outside the excavation disturbed zone(EDZ),the claystone exhibits a 11.6-mm black rim at the cement/paste interface,which shows a different mechanical behaviour from the rest of the claystone.Three sets of measurements of elastic modulus were performed using:(i)nano-indentation tests with a constant indentation depth of 2 mm,(ii)microindentation tests with a constant indentation depth of 20 mm,and(iii)meso-compression tests with a constant displacement of 200 mm.The increase of the modulus of deformability in the black rim is between 15 GPa and 20 GPa according to the scale.Moreover,an overall decrease of the modulus of deformability from the smallest to the largest scale is observed in each zone.In view of the mineralogy and petrographic observations,higher values of modulus of deformability in the black rim are related to carbonate content and its distribution.Precipitation of cementitious carbonates as inclusions and very thin partings leads to hardening of the claystone.展开更多
The rheological behavior of the lithosphere beneath the Northwestern(NW)Andes(Colombian)remains uncertain under a complex geological setting.Here,we analyze the earthquake distribution and the stress drop on the weste...The rheological behavior of the lithosphere beneath the Northwestern(NW)Andes(Colombian)remains uncertain under a complex geological setting.Here,we analyze the earthquake distribution and the stress drop on the western and the eastern of the transition area between the Upper Magdalena Valley(UMV)and the Middle Magdalena Valley(MMV),a zone related to a plate tectonic transition from steeper to flatter subduction style slabs(Nazca and Caribbean plates).Our results consistently explain the tectonic and geodynamic context of the study area supported in two rheological profiles,which reveal the brittle/ductile transition of the lithospheric crust and mantle and allow to constrain the lithospheric rheological thickness.The subduction phenomenon of the Nazca Plate under the South American Plate is observed in the western zone.In the eastern region,we find a remarkable aseismic zone under the Eastern Cordillera below 20-km-deep,which made more difficultan accurate estimation of the crust/mantle boundary.This seismic particularity leads us to support the hypothesis of a delamination process due to the tectonic overload generated by the Eastern Cordillera,and that promotes thermal anomalies.Our results also suggest that the earthquake dataset correlated with rheological estimations may offer a consistent interpretation of the mechanical behavior of the lithosphere.展开更多
基金funded by the European Union's Horizon 2020 research and innovation programme under a grant agreement (Grant No.847593)partially supported by the Fundamental Research Funds for the Central Universities (Grant No.22120240029).
文摘This study presents a fully coupled thermo-hydro-mechanical (THM) constitutive model for clay rocks. The model is formulated within the elastic-viscoplasticity framework, which considers nonlinearity and softening after peak strength, anisotropy of stiffness and strength, as well as permeability variation due to damage. In addition, the mechanical properties are coupled with thermal phenomena and accumulated plastic strains. The adopted nonlocal and viscoplastic approaches enhance numerical efficiency and provide the possibility to simulate localization phenomena. The model is validated against experimental data from laboratory tests conducted on Callovo-Oxfordian (COx) claystone samples that are initially unsaturated and under suction. The tests include a thermal phase where the COx specimens are subjected to different temperature increases. A good agreement with experimental data is obtained. In addition, parametric analyses are carried out to investigate the influence of the hydraulic boundary conditions (B.C.) and post-failure behavior models on the THM behavior evolution. It is shown that different drainage conditions affect the thermally induced pore pressures that, in turn, influence the onset of softening. The constitutive model presented constitutes a promising approach for simulating the most important features of the THM behavior of clay rocks. It is a tool with a high potential for application to several relevant case studies, such as thermal fracturing analysis of nuclear waste disposal systems.
基金supported by the Lorraine University of Excellence via the DEEPSURF project(ANR 70315-IDEX-04-LUE)。
文摘The increase in the frequency and intensity of drought events expected in the coming decades in Western Europe may disturb forest biogeochemical cycles and create nutrient deficiencies in trees.One possible origin of nutrient deficiency is the disturbance of the partitioning of the green leaf pool during the leaf senescence period between resorption,foliar leaching and senesced leaves.However,the effects of drought events on this partitioning and the consequences for the maintenance of tree nutrition are poorly documented.An experiment in a beech forest in Meuse(France)was conducted to assess the effect of drought events on nutrient canopy exchanges and on the partitioning of the green leaf pool during the leaf senescence period.The aim was to identify potential nutritional consequences of droughts for trees.Monitoring nutrient dynamics,including resorption,chemistry of green and senesced leaves,foliar absorption and leaching in mature beech stands from 2012 to 2019 allowed us to compare the nutrient exchanges for three nondry and three dry years(i.e.,with an intense drought event during the growing season).During dry years,we observed a decrease by almost a third of the potassium(K)partitioning to resorption(i.e.resorption efficiency),thus reducing the K reserve in trees for the next growing season.This result suggests that with the increased drought frequency and intensity expected for the coming decades,there will be a risk of potassium deficiency in trees,as already observed in a rainfall exclusion experiment on the same study site.Reduced foliar leaching and higher parititioning to the senesced leaves for K and phosphorus(P)were also observed.In addition,a slight increase in nitrogen(N)resorption efficiency occurred during dry years which is more likely to improve tree nutrition.The calcium(Ca)negative resorption decreased,with no apparent consequence in our study site.Our results show that nutrient exchanges in the canopy and the partitioning of the green leaf pool can be modified by drought events,and may have consequences on tree nutrition.
基金financed by the REGALOR project(Ressources Gazieres de Lorraine).
文摘The enhanced coalbed methane recovery using CO_(2) injection(CO_(2)-ECBM)is widely proposed as a way of achieving the energy transition and reducing atmospheric CO_(2),in areas such as the Lorrain basin in France,where heavy industry is responsible for huge CO_(2) emissions and coal mines have been closed for more than a decade.This paper deals with the feasibility of extracting methane from the Lorraine basin using CO_(2)-ECBM by comparing data from sorption isotherms,thermogravimetric analyses and breakthrough curves for two coal samples.One is bituminous(Box 18),from Folschviller(France)and is compared with another sub-bituminous(THO1)from La Houve(France),which is used as a reference because it was identified as a good candidate for CO_(2)-ECBM in a previous research program.The quantities of adsorbed gases(CO_(2)/CH_(4))obtained by sorption isotherms,thermogravimetry and CO,breakthrough curves showed that Box 18 adsorbs more CO_(2) and CH_(4) than THO1 due to its higher porosity and good affinity for gases(CO_(2)/CH_(4)).Toth model fits the experimental CH_(4) and CO_(2) adsorption isotherms better,reflecting the fact that the adsorption surface of the coals studied is heterogeneous.Adsorption enthalpies obtained by calorimetry indicated physisorption for gas-coal interactions,with higher values for CO_(2) than for CH_(4).Thermogravimetric analyses and breakthrough curves carried out at up to 50%relative humidity showed that the adsorption capacity of CO_(2) decreases with increasing temperature and the presence of water,respectively.The compilation of these experimental data explained the adsorption process of the studied coals and revealed their advantages for CO_(2)-ECBM.
文摘Rivers are progressively being exposed to increased anthropogenic pollution stresses that are undermining their designated uses and affecting sensitive coastal areas. In this study, three adjacent eastern Mediterranean coastal rivers, Ibrahim, Kaleb and Beirut, were evaluated. Water quality samples were collected in dry and wet seasons from different sampling sites along the river from the source to the outlet which represent a gradient of increased urbanization. The spatiotemporal variability of the physio-chemical properties, heavy metals (Zn, Pb, Cu, Cr, and Cd) and organic matter (DOC) were statistically analyzed to better understand the contribution of point and nonpoint pollution sources. The three rivers (Beirut, Kaleb and Ibrahim) show a similar behavior in calcium and carbonate alkalinity due to the carbonate mineral weathering effect, so they are of calcium bicarbonate type due to their calcareous geological nature. The speciation of anions was affected by temporal variation. Moreover, it is obvious that the Beirut River has a different behavioral characteristic where the water is a sulfate type water with a preferable metal-OM complexation mainly with lead, zinc and copper, whereas Kaleb and Ibrahim are considered to be of a nitrate phosphate type with a preferable metal inorganic complexation, especially copper, that has a consistent behavior in both types of waters. This difference is attributed to the urbanization effect highly impacting the Beirut River.
文摘Landscape urbanization broadly affects ecosystems in coastal watersheds, but, until now, the influence of nonpoint source urban inputs on dissolved organic matter (DOM) amount, composition, and source is poorly understood. To understand how DOM composition varied with urbanization, fluorescence excitation-emission matrices (EEMs) were determined for urban and non-urban waters from upstream to downstream sites along three adjacent coastal watersheds that flow into the Mediterranean Sea. Two humic DOM fluorescent components (humic-like and fulvic-like peaks) and two proteinic components (tyrosine-like and tryptophane-like peaks) were identified by EEM fluorescence. The results indicated that urbanization had an important influence on DOM concentration and composition, with urban waters having a high degree of DOM variation due to different land uses surrounding each body of water. Urban waters show a higher DOM fluorescence index (FI), the highest fluorescence intensity of protein-like manifested also by BIX values, and a lower value of the humification index (HIX) than non-urban waters which were dominated by allochthonous inputs. In addition, the EEM was compared in dry and wet season where higher DOM amounts and FI appeared in summer due to autochthonous production coming from algae growth compared to allochthonous input from rainfall dominated in wet season. The concentration of DOC increased from upstream to downstream for the three rivers, especially Beirut River. The increase in DOC values was observed in both dry and wet seasons by 39 and 19 times respectively compared to upstream (0.93 - 0.91 mgC/L).
文摘Alteration minerals and silicification are typically associated with a variety of ore mineralizations and could be detected using multispectral remote sensing sensors as indicators for mineral exploration.In this investigation,the Visible Near-Infra-Red(VNIR),Short-Wave Infra-Red(SWIR),and Thermal Infra-Red(TIR)bands of the ASTER satellite sensor derived layers were fused to detect alteration minerals and silicification in east the Kerdous inlier for cupriferous mineralization exploration.Several image processing techniques were executed in the present investigation,namely,Band Ratio(BR),Selective Principal Component Analysis(SPCA)and Constrained Energy Minimization(CEM)techniques.Initially,the BR and SPCA processing results revealed several alteration zones,including argillic,phyllic,dolomitization and silicification as well as iron oxides and hydroxides.Then,these zones were mapped at sub-pixel level using the CEM technique.Pyrophyllite,kaolinite,dolomite,illite,muscovite,montmorillonite,topaz and hematite were revealed displaying a significant distribution in relation with the eastern Amlen region lithological units and previously detected mineral potential zones using HyMap imaging spectroscopy.Mainly,a close spatial association between iron oxides and hydroxide minerals,argillic,and phyllic alteration was detected,as well as a strong silicification was detected around doleritic dykes unit in Jbel Lkest area.A weighted overlay approach was used in the integration of hydrothermal alteration minerals and silicification,which allowed the elaboration of a new mineral alteration map of study area with five alteration intensities.ASTER and the various employed processing techniques allowed a practical and cost effective mapping of alteration features,which corroborates well with field survey and X-ray diffraction analysis.Therefore,ASTER data and the employed processing techniques offers a practical approach for mineral prospection in comparable settings.
文摘Toarcian claystone such as that of the Callovo-Oxfordian is a qualified multiphase material. The claystone samples tested in this study are composed of four main mineral phases: silicates(clay minerals, quartz,feldspars, micas)(z86%), sulphides(pyrite)(z3%), carbonates(calcite, dolomite)(z10%) and organic kerogen(z1%). Three sets of measurements of the modulus of deformability were compared as determined in(i) nanoindentation tests with a constant indentation depth of 2 mm,(ii) micro-indentation tests with a constant indentation depth of 20 mm, and(iii) meso-compression tests with a constant displacement of 200 mm. These three experimental methods have already been validated in earlier studies. The main objective of this study is to demonstrate the influence of the scaling effect on the modulus of deformability of the material. Different frequency distributions of the modulus of deformability were obtained at the different sample scales:(i) in nano-indentation tests, the distribution was spread between 15 GPa and 90 GPa and contained one peak at34 GPa and another at 51 GPa;(ii) in the micro-indentation tests, the distribution was spread between 25 GPa and 60 GPa and displayed peaks at 26 GPa and 37 GPa; and(iii) in the meso-compression tests, a narrow frequency distribution was obtained, ranging from 25 GPa to 50 GPa and with a maximum at around 35 GPa.
文摘Felsic intrusions present ubiquitous structures.They result from the differential interactions between the magma components(crystal,melt,gas phase) while it flows or when the flow is perturbed by a new magma injection.The most obvious structure consists in fabrics caused by the interactions of rotating grains in a flowing viscous melt.New magma inputs through dikes affect the buk massif flow,considered as global within each mineral facies.A review of the deformation and flow types developing in a magma chamber identifis the patterns that could be expected.It determines their controlling parameters and summarizes the tools for their quantification.Similarly,a brief review of the theology of a complex multiphase magma identifies and suggests interactions between the different components.The specific responses each component presents lead to instability development.In particular,the change in vorticity orientation,associated with the switch between monoclinic to triclinic flow is a cause of many instabilities.Those are preferentially local.Illustrations include fabric development,shear zones and flow banding.They depend of the underlying rheology of interacting magmas.Dikes,enclaves,schlieren and ladder dikes result from the interactions between the magma components and changing boundary conditions.Orbicules,pegmatites,unidirectional solidification textures and miarolitic cavities result from the interaction of the melt with a gaseous phase.The illustrations examine what is relevant to the bulk flow,local structures or boundary conditions.In each case a field observation illustrates the instability.The discussion reformulates instability observations,suggesting new trails for ther description and interpretation in terms of local departure to a bulk flow.A brief look at larger structures and at their evolution tries to relate these instabilities on a broader scale.The helical structures of the Ricany pluton,Czech Republic and by the multiple granitic intrusions of Dolbel,Niger illustrate such events.
文摘Landsat 8 Oli,ASTER,and Sentinel 2A satellite images processing was used to map geological formations,lineaments and hydrothermal alteration minerals in the Aouli inlier,as a case study to illustrate the application of digital images processing and Geographic Information System(GIS)in geological mapping and mining prospecting.Principal Component Analysis(PCA)applied to the Landsat images allowed good lithological discrimination and contributed to the updating of available geological maps.The Automatic lineament extraction from Sentinel images revealed the main tectonic structures affecting Aouli inlier.The ratio bands(b5+b7)/b6 and the false color composite(b4/b6,b2/b1,b3/b2)allowed the hydrothermal alteration minerals mapping from Aster images.Combined with available geological data and field observations,the satellite derived data were integrated and analyzed in a GIS software to establish mining prospecting guides.The results showed that the anomaly zones are intimately linked to NNE-SSW and NW-SE oriented faults and to highly fractured areas developing argillic and Fe rich alterations.Verified via field survey,this approach was successfully applied to the Aouli inlier to rapidly target potential areas to be explored in the tactical phase.This provides a model for future prospecting efforts for similar mineral deposits in other areas.
基金supported by an NSERC-DG grant(Grant No.RGPIN-2018-06458,to Chi)National Natural Science Foundation of China grant(Grant No.41930428,to Xu)。
文摘Deep mineral exploration is increasingly important for finding new mineral resources but there are many uncertainties.Understanding the factors controlling the localization of mineralization at depth can reduce the risk in deep mineral exploration.One of the relatively poorly constrained but important factors is the hydrodynamics of mineralization.This paper reviews the principles of hydrodynamics of mineralization,especially the nature of relationships between mineralization and structures,and their applications to various types of mineralization systems in the context of hydrodynamic linkage between shallow and deep parts of the systems.Three categories of mineralization systems were examined,i.e.,magmatic-hydrothermal systems,structurally controlled hydrothermal systems with uncertain fluid sources,and hydrothermal systems associated with sedimentary basins.The implications for deep mineral exploration,including potentials for new mineral resources at depth,favorable locations for mineralization,as well as uncertainties,are discussed.
文摘Southern India and Sri-Lanka are the places where “incipient charnockites”,i.e.the local transformation of amphibolite-facies gneisses into orthopyroxene-bearing,igneous looking charnockites,have been discovered in the early sixties.The fact that some incipient charnockites occur along a network of brittle fractures,together with CO_(2) remnants preserved in mineral inclusions,had called for the role of fluids during charnockite alteration.The present work presents new observations on fluid inclusions and microtextures of incipient charnockites from type localities in southern India.In addition to CO_(2)-rich fluid inclusions in quartz and feldspar,all of the occurrences have disrupted remnants of concentrated aqueous alkali chloride solutions.CO_(2) inclusions are more abundant in paragneiss (Kerala) than in orthogneiss (Karnataka/Tamil Nadu).The finding of disrupted brine inclusions in the Kabbal charnockite is a key link between closely associated massive charnockites and Closepet Granite,both of which also share the brine remnants.All of the occurrences studied here have feldspar or feldspar-quartz microvein networks along grain boundaries of recrystallized quartz,feldspar and orthopyroxene.These metasomatic veins again indicate the action of alkali-exchanging fluids (i.e.,saline solutions).Feldspar microveins,which have been found in most “massive” charnockites,along with the CO_(2)-rich fluid inclusions,suggest a commonality of incipient charnockite and massive charnockite,both types differing in intensity of interaction with metasomatizing pore fluids.
基金supported by the French National Research Agency through the national program "Investissements d'avenir" the reference ANR-10-LABX-21-RESSOURCES21
文摘During granulite-facies metamorphism of metasedimentary rocks by the infiltration of carbonic fluids, the disappearance of hydrated minerals leads to the liberation of aqueous fluids. These fluids are strongly enriched in F and C1, and a series of Large-lon-Lithophile （LIL） elements and rare metals, resulting in their depletion in granulites. To sum up the fate of these elements, we focus on three domains representing different crustal levels and showing distinct behaviours with respect to these elements. The Lapland metasedimentary granulites illustrate the behaviour of the LILE and rare metals during lower crustal metamorphism. There is no change in Ba, moderate loss in Rb, and extreme depletion in Cs, Li, and Sn. F and CI contents are also very low compared to the protoliths or average upper continental crust. Biotite and amphibole breakdown leads to the incorporation of their partitioning into a fluid or a melt. The Tranomaro metasomatized marbles recrystallizing under granulite-facies conditions represent a demonstrative example of fluid transfer from granulite-facies supracrustals to traps represented by regional scale skarns. Such fluids may be at the origin of the incompatible element enrichment detected in leucosomes of migmatites from St Malo in Brittany （France） and Black Hills in South Dakota, The northern French Massif Central provides us with an example of a potential association between incompatible element enrichment of granitic melts and granulite-facies metamorphism. U- and F- enriched fine-grained granites are emplaced along a crustal scale shear zone active during the emplacement within the St Sylvestre peraluminous leucogranitic complex, We propose that during granulite-facies metamorphism dominated by carbonic waves in a deep segment of the continental crust, these shear zones control： （i） the percolation of F-, LILE-, rare metal-rich fluids liberated primarily by the breakdown of biotite; （ii） the enhancement of partial melting by F-rich fluids at intermediate crustal levels with the generation of F-, LILE-, rare metal-rich granitic melts; （iii） their transfer through the crust with protracted fractionation facilitated by their low viscosity due to high F-Li contents; and finally （iv） their emplacement as rare metal intrusions at shallow crust levels.
基金supported by the IMSRN French Company through a CIFRE grant No. 2012/0710CSIRO Energy Flagship+1 种基金QCAT in AustraliaThe laboratory 3SR is part of the Lab Ex Tec 21 (Investissements d’Avenir e grant agreement No. ANR-11-LABX-0030)
文摘Analysis and prediction of structural instabilities in open pit mines are an important design and operational consideration for ensuring safety and productivity of the operation. Unstable wedges and blocks occurring at the surface of the pit walls may be identified through three-dimensional(3D) image analysis combined with the discrete fracture network(DFN) approach. Kinematic analysis based on polyhedral modelling can be used for first pass analysis but cannot capture composite failure mechanisms involving both structurally controlled and rock mass progressive failures. A methodology is proposed in this paper to overcome such limitations by coupling DFN models with geomechanical simulations based on the discrete element method(DEM). Further, high resolution photogrammetric data are used to identify valid model scenarios. An identified wedge failure that occurred in an Australian coal mine is used to validate the methodology. In this particular case, the failure surface was induced as a result of the rock mass progressive failure that developed from the toe of the structure inside the intact rock matrix. Analysis has been undertaken to determine in what scenarios the measured and predicted failure surfaces can be used to calibrate strength parameters in the model.
文摘The olive species(Olea europaea L.)is an ancient traditional crop grown under rainfed conditions in the Mediterranean Basin.In response to the growing national and international demand for olive oil,the olive cultivars are introduced into highly arid new bioclimatic areas.Subsequently,the morpho-physiology and phytochemistry of olive trees are potentially changing among cultivar types and geographical conditions.In the present work,we have undertaken an assessment on the impacts of geographical location and cultivar types on the leaf morpho-physiology and phytochemistry of olive trees.Thus,leaves of the two most cultivated olive tree varieties,Chemlal and Sigoise,were collected from three geographical regions(Setif,Batna,and Eloued)with increasing aridity in Algeria.Leaf samples from the geographical regions were analyzed using the standard physiological experiment,colorimetric method,and a chromatography assay.Leaves of both cultivars exhibited a significant variance in terms of the leaf shape index but not for the leaf tissue density,specific leaf weight,and specific leaf area.Photosynthetic pigment contents were affected by both cultivar type and geographical location,with the lowest pigment content recorded in the Sigoise cultivar from the Setif region.Compared with the Setif and Batna regions,dried leaves of both cultivars from the Eloued region showed the higher levels of the total polyphenol,total flavonoid,and total tannin,as well as a better antioxidant capacity.Liquid chromatography-mass spectrometry analysis of all leaf extracts identified the following phenolic acids as major compounds:oleuropein,naringin,apigenin-7-O-glucoside,kaempferol,quercetin,quercitrin,luteolin-7-O-naringenin,and quinic acid.Lower contents were found for p-Coumaric acid,trans-Ferulic acid,hyperoside,rutin,apigenin,caffeic acid,protocatechuic acid,o-Coumaric acid,and gallic acid.Also,epicatechin and catechin+were not found in the leaf extracts of the Sigoise cultivar.The leaf organic extracts in both cultivars displayed promising anti-cancer activity that was affected by geographical location and organic solvent polarity.Briefly,although increasing aridity and soil organic and mineral deficiency affected the leaf morpho-physiological parameters,both cultivars sustained a chemical richness,a good antioxidant,and an anti-tumoral capacity in leaves.Furthermore,the findings revealed that regardless the olive tree genotype,there was a significant impact of geographical location on the leaf morpho-physiology,bioactivity,and chemical composition,which may consequently modulate the growth and oil production of olive trees.
文摘Agriculture is harming its own future through soil degradation and pollution of the water that it generates. The different chemical analyses carried out on surface waters and the land surveys carried out in the Nakanbé basin have shown that agricultural practices contribute to water pollution. The monitoring of nitrate, orthophosphate and BOD5 levels in the dams of Goinré, Ziga and Bagré during the period from August to December revealed that agricultural practices lead to variation in these parameters. The average values for nitrates are 0.833 mg/L in the Goinré fresh waterbody, 1.372 mg/L in the Ziga reservoir, and 1.267 mg/L in the Bagré fresh waterbody. As for ortho phosphate, mean values are 0.357 mg/L in the Goinré reservoir, 0.157 mg/L in the Ziga reservoir and 0.123 mg/L in the Bagré reservoir. These average values are higher than the norms established by Nisbet and Vernaux (1970) for eutrophication. Nitrates and orthophosphate are the elements that contribute to the eutrophication of water surfaces in the Nakanbé basin, although this eutrophication is of low intensity. Of all pesticides encountered in our study sites, 45% are registered by the Sahelian Pesticides Committee (CSP): 35% are non-accredited and 20% are unknown in the global list authorized by the CSP in 2010.
文摘There are several techniques that were developed for determining the linear features. Lineament extraction?from satellite data has been the most widely used applications in geology. In the present study, lineament has?been extracted from the digital satellite scene (Landsat 5, TM data), in the region of Zahret Median situated in the north west of Tunisia. The image was enhanced and used for automatic extraction. Several directions of features were mapped. The directions of major invoices are NE-SW and NW-SE oriented. The validation of the obtained results is carried out by comparison with the results geophysics as well as to the studies previous of mapping developed in the sector of study.
文摘Lizardite rich peridotite has never been used to prepare ceramic specimens,especially in Morocco.For this raison,potential use of naturally abundant lizarditic material from the Rif domain,as a supply for ceramic industry,has been evaluated.The effects of lizardite addition to magnesite and dolomite mixtures on the thermomechanical properties of the calcined ceramics were also detailed.To achieve this target,natural lizardite,magnesite and dolomite samples were collected in ultrabasic Beni Bousra massif.Those raw samples were used for the synthesis of a forsterite-monticellite rich ceramics.Both raw and sintered samples were characterized by x-ray diffraction,scanning electron microscope and fourier transform infrared.The obtained results showed that both magnesite and dolomite were mainly composed of MgCO_(3) and CaCO_(3).In contrast,lizardite sample showed high amounts of SiO_(2),MgO and Fe2O_(3).An increased amount of lizardite in the initial mixtures enhanced mechanical and dimensional properties of the prepared ceramic specimens,and subsequently,the production of ceramics with the required technological properties.Thus,the preparation of Moroccan lizardite-based ceramics is technically feasible,economically justifiable and socially desirable due to the contribution to the economic growth of the raw materials sector,especially ceramic industry.
文摘Micro-mechanical properties of a claystone were tested after undergoing alkaline perturbation on site(Tournemire,CD borehole)for 18 years.In a saturated context and outside the excavation disturbed zone(EDZ),the claystone exhibits a 11.6-mm black rim at the cement/paste interface,which shows a different mechanical behaviour from the rest of the claystone.Three sets of measurements of elastic modulus were performed using:(i)nano-indentation tests with a constant indentation depth of 2 mm,(ii)microindentation tests with a constant indentation depth of 20 mm,and(iii)meso-compression tests with a constant displacement of 200 mm.The increase of the modulus of deformability in the black rim is between 15 GPa and 20 GPa according to the scale.Moreover,an overall decrease of the modulus of deformability from the smallest to the largest scale is observed in each zone.In view of the mineralogy and petrographic observations,higher values of modulus of deformability in the black rim are related to carbonate content and its distribution.Precipitation of cementitious carbonates as inclusions and very thin partings leads to hardening of the claystone.
基金the Geophysical Research Group and the Geophysical Instrumentation Laboratory(LIG),belonging to the Geosciences Department of the Universidad Nacional de Colombia at Bogota,which support our work with the following grant IDs:Hermes-43777-UNAL
文摘The rheological behavior of the lithosphere beneath the Northwestern(NW)Andes(Colombian)remains uncertain under a complex geological setting.Here,we analyze the earthquake distribution and the stress drop on the western and the eastern of the transition area between the Upper Magdalena Valley(UMV)and the Middle Magdalena Valley(MMV),a zone related to a plate tectonic transition from steeper to flatter subduction style slabs(Nazca and Caribbean plates).Our results consistently explain the tectonic and geodynamic context of the study area supported in two rheological profiles,which reveal the brittle/ductile transition of the lithospheric crust and mantle and allow to constrain the lithospheric rheological thickness.The subduction phenomenon of the Nazca Plate under the South American Plate is observed in the western zone.In the eastern region,we find a remarkable aseismic zone under the Eastern Cordillera below 20-km-deep,which made more difficultan accurate estimation of the crust/mantle boundary.This seismic particularity leads us to support the hypothesis of a delamination process due to the tectonic overload generated by the Eastern Cordillera,and that promotes thermal anomalies.Our results also suggest that the earthquake dataset correlated with rheological estimations may offer a consistent interpretation of the mechanical behavior of the lithosphere.
