Lithium-ion batteries(LIBs)play a critical role in reducing carbon emissions in the automotive industry.However,they face challenges related to safety and performance failures.Smart technologies offer a promising solu...Lithium-ion batteries(LIBs)play a critical role in reducing carbon emissions in the automotive industry.However,they face challenges related to safety and performance failures.Smart technologies offer a promising solution to address these issues.Bioinspired microcapsules are a common approach to enhancing the performance and safety of smart LIBs.However,despite their potential,this area has not been thoroughly explored.This review provides an overview of the preparation methods for microcapsules,including physical,chemical,and physicochemical techniques.These microcapsules are categorized based on their mechanisms into electrode self-healing burst microcapsules,interphase-forming sustained-release microcapsules,live-lithium sustained-release microcapsules,and flame-retardant burst microcapsules.A comprehensive analysis of their bioinspired design concepts,mechanisms,and performance is presented,along with the design criteria for microcapsules suitable for LIBs.Finally,the review explores the potential applications of microcapsule technologies in LIBs and their future trends,such as enhancing existing technologies for novel applications like solid-state batteries and developing new types of microcapsules.This review aims to provide a foundation for the implementation of microcapsule technologies in LIBs and to highlight the latest advancements in smart batteries.展开更多
When the proton exchange membrane fuel cell(PEMFC)system is running,there will be a condition that does not require power output for a short time.In order to achieve zero power output under low power consumption,it is...When the proton exchange membrane fuel cell(PEMFC)system is running,there will be a condition that does not require power output for a short time.In order to achieve zero power output under low power consumption,it is necessary to consider the diversity of control targets and the complexity of dynamic models,which brings the challenge of high-precision tracking control of the stack output power and cathode intake flow.For system idle speed control,a modelbased nonlinear control framework is constructed in this paper.Firstly,the nonlinear dynamic model of output power and cathode intake flow is derived.Secondly,a control scheme combining nonlinear extended Kalman filter observer and state feedback controller is designed.Finally,the control scheme is verified on the PEMFC experimental platform and compared with the proportion-integration-differentiation(PID)controller.The experimental results show that the control strategy proposed in this paper can realize the idle speed control of the fuel cell system and achieve the purpose of zero power output.Compared with PID controller,it has faster response speed and better system dynamics.展开更多
Magnetorheological elastomers(MREs)hold significant promise in various fields such as automotive engineering,and civil engineering,where they serve as intelligent materials.Depending on the application of an external ...Magnetorheological elastomers(MREs)hold significant promise in various fields such as automotive engineering,and civil engineering,where they serve as intelligent materials.Depending on the application of an external magnetic field,these materials exhibit varying magnetorheological and viscoelastic properties,including shear stress,yield stress,dynamic moduli,and damping.In this work,a new type of MRE,termed self-healing MREs(SH-MREs),has been developed by adding a novel self-healing agent into existing MREs.The dynamic modulus and loss factor of SH-MREs with different compositions have been characterized under various conditions of frequency,temperature,and strain.The results show that as the strain value increases,the loss factor also increases.Moreover,the loss factor initially increases and then decreases with increasing magnetic field strength.Although higher concentrations of ferromagnetic particles increase the loss factor,they enhance the operational range due to their better responsiveness to magnetic fields.SH-MREs demonstrate improved damping capabilities,attributed to the formation of coordination bonds between ferromagnetic particles and the self-healing agent.The stable structure increases the viscosity of MREs.The results of the regression model suggest a direct proportionality between sensitivity to the magnetic field and the ferromagnetic particle concentration.展开更多
Lithium(Li)is considered one of the most promising anode materials for next-generation batteries.However,Li dendrites and uncontrollable volume changes emerge during cycling,which severely restrict their commercial ap...Lithium(Li)is considered one of the most promising anode materials for next-generation batteries.However,Li dendrites and uncontrollable volume changes emerge during cycling,which severely restrict their commercial application.To achieve efficient and stable Li storage,we proposed an insitu lithiophilic strategy based on three-dimensional graphite(3D-G)current collectors.Specifically,we prepared the 3D-G rapidly with a high specific surface area(∼190.3 m2 g−1)using a freeze-drying technology.During an electrochemical prelithiation process,Li ions first intercalated into graphite to form a lithiophilic Li intercalated compound,and transformed into Li0,filling the pores,which weakened the local electron/ion mismatching during direct Li+→Li0 reaction and provided a smooth initial nucleation.Even at a high rate,the nucleation reaction under synchronous intercalation also promoted a superior nucleation process.Therefore,the LiFePO4||3D-G@Li battery maintained a capacity retention rate of 86%and a discharge specific capacity of 118.7mAh g−1 after 1000 cycles at 1 C.Furthermore,a finite element analysis showed that 3D-G exerted a uniform Li+distribution and a low local current density,conducive to the uniform deposition of Li.展开更多
基金supported by the Jilin Provincial Science and Technology Development Plan Project(No.20220508003RC)the National Natural Science Foundation of China(52202440,52003012)。
文摘Lithium-ion batteries(LIBs)play a critical role in reducing carbon emissions in the automotive industry.However,they face challenges related to safety and performance failures.Smart technologies offer a promising solution to address these issues.Bioinspired microcapsules are a common approach to enhancing the performance and safety of smart LIBs.However,despite their potential,this area has not been thoroughly explored.This review provides an overview of the preparation methods for microcapsules,including physical,chemical,and physicochemical techniques.These microcapsules are categorized based on their mechanisms into electrode self-healing burst microcapsules,interphase-forming sustained-release microcapsules,live-lithium sustained-release microcapsules,and flame-retardant burst microcapsules.A comprehensive analysis of their bioinspired design concepts,mechanisms,and performance is presented,along with the design criteria for microcapsules suitable for LIBs.Finally,the review explores the potential applications of microcapsule technologies in LIBs and their future trends,such as enhancing existing technologies for novel applications like solid-state batteries and developing new types of microcapsules.This review aims to provide a foundation for the implementation of microcapsule technologies in LIBs and to highlight the latest advancements in smart batteries.
基金Supported by the Major Science and Technology Projects in Jilin Province and Changchun City(20220301010GX).
文摘When the proton exchange membrane fuel cell(PEMFC)system is running,there will be a condition that does not require power output for a short time.In order to achieve zero power output under low power consumption,it is necessary to consider the diversity of control targets and the complexity of dynamic models,which brings the challenge of high-precision tracking control of the stack output power and cathode intake flow.For system idle speed control,a modelbased nonlinear control framework is constructed in this paper.Firstly,the nonlinear dynamic model of output power and cathode intake flow is derived.Secondly,a control scheme combining nonlinear extended Kalman filter observer and state feedback controller is designed.Finally,the control scheme is verified on the PEMFC experimental platform and compared with the proportion-integration-differentiation(PID)controller.The experimental results show that the control strategy proposed in this paper can realize the idle speed control of the fuel cell system and achieve the purpose of zero power output.Compared with PID controller,it has faster response speed and better system dynamics.
基金the National Natural Science Foundation of China(No.52003142).
文摘Magnetorheological elastomers(MREs)hold significant promise in various fields such as automotive engineering,and civil engineering,where they serve as intelligent materials.Depending on the application of an external magnetic field,these materials exhibit varying magnetorheological and viscoelastic properties,including shear stress,yield stress,dynamic moduli,and damping.In this work,a new type of MRE,termed self-healing MREs(SH-MREs),has been developed by adding a novel self-healing agent into existing MREs.The dynamic modulus and loss factor of SH-MREs with different compositions have been characterized under various conditions of frequency,temperature,and strain.The results show that as the strain value increases,the loss factor also increases.Moreover,the loss factor initially increases and then decreases with increasing magnetic field strength.Although higher concentrations of ferromagnetic particles increase the loss factor,they enhance the operational range due to their better responsiveness to magnetic fields.SH-MREs demonstrate improved damping capabilities,attributed to the formation of coordination bonds between ferromagnetic particles and the self-healing agent.The stable structure increases the viscosity of MREs.The results of the regression model suggest a direct proportionality between sensitivity to the magnetic field and the ferromagnetic particle concentration.
基金supported by the National Natural Science Foundation of China(grant no.22479060)the State Key Laboratory of Catalysis(grant no.2024SKL-A-004)the Major Science and Technology Projects for Independent Innovation of China First Automotive Works(FAW)Group Co.,Ltd.(grant nos.20220301018GX and 20220301019GX).
文摘Lithium(Li)is considered one of the most promising anode materials for next-generation batteries.However,Li dendrites and uncontrollable volume changes emerge during cycling,which severely restrict their commercial application.To achieve efficient and stable Li storage,we proposed an insitu lithiophilic strategy based on three-dimensional graphite(3D-G)current collectors.Specifically,we prepared the 3D-G rapidly with a high specific surface area(∼190.3 m2 g−1)using a freeze-drying technology.During an electrochemical prelithiation process,Li ions first intercalated into graphite to form a lithiophilic Li intercalated compound,and transformed into Li0,filling the pores,which weakened the local electron/ion mismatching during direct Li+→Li0 reaction and provided a smooth initial nucleation.Even at a high rate,the nucleation reaction under synchronous intercalation also promoted a superior nucleation process.Therefore,the LiFePO4||3D-G@Li battery maintained a capacity retention rate of 86%and a discharge specific capacity of 118.7mAh g−1 after 1000 cycles at 1 C.Furthermore,a finite element analysis showed that 3D-G exerted a uniform Li+distribution and a low local current density,conducive to the uniform deposition of Li.
