By simplifying the r-bridge unit,a nonfused ring electron acceptor(NFREA)BM-2F was designed and synthesized with several high-yield steps.The specific molecular structure features of BM-2F are planar molecular backbon...By simplifying the r-bridge unit,a nonfused ring electron acceptor(NFREA)BM-2F was designed and synthesized with several high-yield steps.The specific molecular structure features of BM-2F are planar molecular backbone and out-of-plane side chain,which is favorable for charge transport and can suppress the over-aggregation.BM-2F based neat and blend films display obvious face-on molecular orientation.Specially,D18:BM-2F based blend film can form good bicontinuous interpenetrating network.More excitingly,a power conversion efficiency of 16.15%was achieved with D18:BM-2F based photovoltaic devices,which is the highest one based on NFREAs.Our researches manifest that NFREA is a promising direction for low-cost and high-performance organic solar cells.展开更多
基金This research was made possible thanks to the financial support from the National Natural Science Foundation of China(51933001,52173174,22109080,21734009).
文摘By simplifying the r-bridge unit,a nonfused ring electron acceptor(NFREA)BM-2F was designed and synthesized with several high-yield steps.The specific molecular structure features of BM-2F are planar molecular backbone and out-of-plane side chain,which is favorable for charge transport and can suppress the over-aggregation.BM-2F based neat and blend films display obvious face-on molecular orientation.Specially,D18:BM-2F based blend film can form good bicontinuous interpenetrating network.More excitingly,a power conversion efficiency of 16.15%was achieved with D18:BM-2F based photovoltaic devices,which is the highest one based on NFREAs.Our researches manifest that NFREA is a promising direction for low-cost and high-performance organic solar cells.
