Thermohaline features, spatial extensions, and depths of the antarctic circumpolar deep water, the antarctic bottom water, and the upper layer water near the Prydz Bay （ including the Prydz Bay s.mmer surface water, ...Thermohaline features, spatial extensions, and depths of the antarctic circumpolar deep water, the antarctic bottom water, and the upper layer water near the Prydz Bay （ including the Prydz Bay s.mmer surface water, the antarctic winter water, and the Prydz Bay shelf water ） are analyzed and studied by use of the full depth CTD data obtained in the Southern Ocean near the Prydz Bay during the 1998/1999 austral summer. The northward extension of the shelf water, the thickness of the temperature inversion layer, the minima in the vertical temperature profile and the vertical temperature gradient are interpreted. On the basis of analysis of gravitational potential field, the geostrophic current and the geostrophic volume transport are calculated to determine the location of the strongest current in the zonal circulation near the Prydz Bay and to find the spatial variability of the volume transport in the64° -66.5°S zone. In addition, the central location, the frontal strength, the vertical depth and thickness of the continental water boundary （CWB） are estimated from the CTD data to expound the spatial variability of CWB in the study area （64° -66.5°S, 70° -75°E）.展开更多
Oceanographic surveying has been one of the key missions of the Chinese National Antarctic Research Expedition since 1984. Using the field data obtained in these surveys and the results from remote sensing and numeric...Oceanographic surveying has been one of the key missions of the Chinese National Antarctic Research Expedition since 1984. Using the field data obtained in these surveys and the results from remote sensing and numerical models, Chinese physical oceanographers have investigated the water masses, fronts and circulation patterns in the Southern Ocean. The results of nearly 30 years of research are summarized in this paper. Most oceanographic observations by Chinese researchers have been con- ducted in Prydz Bay and the adjacent seas. CTD （Conductivity Temperature and Depth） data, collected during the past 20 years, have been applied to study several features of the water masses in this region： The spatial variation of warm summer surface water, the northward extension of shelf water, the flow of ice shelf water from the cavity beneath the Amery Ice Shelf, the upweUing of the Circumpolar Deep Water, and the formation of the Antarctic Bottom Water. The circulation and its dynamic factors have been analyzed with dynamic heights calculated from CTD data as well as by numerical models. The structure and strength of the fronts in the southeast Indian Ocean and the Drake Passage were investigated with underway XBT/XCTD （Expendable Bathythermo- graph/Expendable CTD） and ADCP （Acoustic Doppler Current Profiler） data. Their interaunual variations have been determined and the factors of influence, especially the atmospheric forcing and mesoscale oceanic processes, were studied using remote sens- ing data. The dynamic mechanism of the Antarctic Circumpolar Current （ACC） was analyzed by theoretical models. The transport and pattern of the ACC have been well reproduced by coupled sea ice-ocean models. Additional details of ACC variability were identified based on satellite altimeter data. The response of the ACC to climate change was studied using reanalysis data. Prospects for future research are presented at the end of this paper.展开更多
A global ocean carbon cycle model based on the ocean general circulation model POP and the improved biogeochemical model OCMIP-2 is employed to simulate carbon cycle processes under the historically observed atmospher...A global ocean carbon cycle model based on the ocean general circulation model POP and the improved biogeochemical model OCMIP-2 is employed to simulate carbon cycle processes under the historically observed atmospheric CO 2 concentration and different future scenarios （called Rep- resentative Concentration Pathways, or RCPs）. The RCPs in this paper follow the design of Inter- governmental Panel on Climate Change （IPCC） for the Fifth Assessment Report （AR5）. The model results show that the ocean absorbs CO 2 from atmosphere and the absorbability will continue in the 21st century under the four RCPs. The net air-sea CO 2 flux increased during the historical time and reached 1.87 Pg/a （calculated by carbon） in 2005; however, it would reach peak and then decrease in the 21st century. The ocean absorbs CO 2 mainly in the mid latitude, and releases CO 2 in the equator area. However, in the Antarctic Circumpolar Current （ACC） area the ocean would change from source to sink under the rising CO 2 concentration, including RCP4.5, RCP6.0, and RCP8.5. In 2100, the anthropogenic carbon would be transported to the 40 S in the Atlantic Ocean by the North Atlantic Deep Water （NADW）, and also be transported to the north by the Antarctic Bottom Water （AABW） along the Antarctic continent in the Atlantic and Pacific oceans. The ocean pH value is also simulated by the model. The pH decreased by 0.1 after the industrial revolution, and would continue to decrease in the 21st century. For the highest concentration sce- nario of RCP8.5, the global averaged pH would decrease by 0.43 to reach 7.73 due to the absorption of CO 2 from atmosphere.展开更多
The South Yellow Sea basin is filled with Mesozoic-Cenozoic continental sediments overlying pre-Palaeozoic and Mesozoic-Palaeozoic marine sediments.Conventional multi-channel seismic data cannot describe the velocity ...The South Yellow Sea basin is filled with Mesozoic-Cenozoic continental sediments overlying pre-Palaeozoic and Mesozoic-Palaeozoic marine sediments.Conventional multi-channel seismic data cannot describe the velocity structure of the marine residual basin in detail,leading to the lack of a deeper understanding of the distribution and lithology owing to strong energy shielding on the top interface of marine sediments.In this study,we present seismic tomography data from ocean bottom seismographs that describe the NEE-trending velocity distributions of the basin.The results indicate that strong velocity variations occur at shallow crustal levels.Horizontal velocity bodies show good correlation with surface geological features,and multi-layer features exist in the vertical velocity framework(depth:0–10 km).The analyses of the velocity model,gravity data,magnetic data,multichannel seismic profiles,and drilling data showed that high-velocity anomalies(>6.5 km/s)of small(thickness:1–2 km)and large(thickness:>5 km)scales were caused by igneous complexes in the multi-layer structure,which were active during the Palaeogene.Possible locations of good Mesozoic and Palaeozoic marine strata are limited to the Central Uplift and the western part of the Northern Depression along the wide-angle ocean bottom seismograph array.Following the Indosinian movement,a strong compression existed in the Northern Depression during the extensional phase that caused the formation of folds in the middle of the survey line.This study is useful for reconstructing the regional tectonic evolution and delineating the distribution of the marine residual basin in the South Yellow Sea basin.展开更多
The Indonesian Throughflow(ITF)plays important roles in global ocean circulation and climate systems.Previous studies suggested the ITF interannual variability is driven by both the El Niño-Southern Oscillation(E...The Indonesian Throughflow(ITF)plays important roles in global ocean circulation and climate systems.Previous studies suggested the ITF interannual variability is driven by both the El Niño-Southern Oscillation(ENSO)and the Indian Ocean Dipole(IOD)events.The detailed processes of ENSO and/or IOD induced anomalies impacting on the ITF,however,are still not clear.In this study,this issue is investigated through causal relation,statistical,and dynamical analyses based on satellite observation.The results show that the driven mechanisms of ENSO on the ITF include two aspects.Firstly,the ENSO related wind field anomalies driven anomalous cyclonic ocean circulation in the western Pacific,and off equatorial upwelling Rossby waves propagating westward to arrive at the western boundary of the Pacific,both tend to induce negative sea surface height anomalies(SSHA)in the western Pacific,favoring ITF reduction since the develop of the El Niño through the following year.Secondly,the ENSO events modulate equatorial Indian Ocean zonal winds through Walker Circulation,which in turn trigger eastward propagating upwelling Kelvin waves and westward propagating downwelling Rossby waves.The Rossby waves are reflected into downwelling Kelvin waves,which then propagate eastward along the equator and the Sumatra-Java coast in the Indian Ocean.As a result,the wave dynamics tend to generate negative(positive)SSHA in the eastern Indian Ocean,and thus enhance(reduce)the ITF transport with time lag of 0-6 months(9-12 months),respectively.Under the IOD condition,the wave dynamics also tend to enhance the ITF in the positive IOD year,and reduce the ITF in the following year.展开更多
To explore the geochemical characteristics and genesis of the elements in ferromanganese nodules from the Northwest Pacific,this study analyses the mineral composition,elemental content,occurrence phase and genetic me...To explore the geochemical characteristics and genesis of the elements in ferromanganese nodules from the Northwest Pacific,this study analyses the mineral composition,elemental content,occurrence phase and genetic mechanisms of samples by X-ray diffraction(XRD),inductively coupled plasma-optical emission spectrometry(ICP-OES),inductively coupled plasma-mass spectrometry(ICP-MS)and phase analysis methods.The results show that ferromanganese nodules are mainly hydrogenetic,and Mn/Fe content ratio ranges from 0.95 to 2.05.The major minerals are vernadite(δ-MnO_(2))and amorphous ferric oxyhydroxide(FeOOH),and the secondary minerals include todorokite,birnessite,quartz and plagioclase.Ferromanganese nodules contain high contents of Co(0.24%-0.42%),Cu(0.23%-0.73%),Ni(0.33%-0.86%)and rare earth elements(REEs,1192-1990μg/g),which have positive Ce and negative Y anomalies but no Eu anomaly.A cluster analysis suggests that the elements in ferromanganese nodules can be divided into three groups:hydrogenetic components,including Fe,Ti,Zr,P,Pb,Co,Ba,Sr,V and REEs;diagenetic components,including Mn,Ni,Mg,Zn and Cu;and detrital components,including Al,Na,K and Ca.According to chemical leaching,ferromanganese nodules can be divided into four phases:Na,Ca,Mg and Sr are mainly enriched in the carbonate phase;Mn,Co,Ni and Ba are mainly enriched in the Mn-oxide phase;Fe,P,Ti,Cu,Pb,V,Zn,Zr and REEs are mainly enriched in the Fe-oxide phase;and Al and K are mainly enriched in the residual phase.A combination of the two different methods reveal selective enrichment of metal elements from seawater by ferromanganese nodules,featuring multisource mineralization.Moreover,through ion exchange and adsorption,approximately 71.2%of REEs are enriched in the Fe-oxide phase,15.4%in the Mn-oxide phase and 12.4%in the residual phase,while REE contents in the carbonate phase are relatively low.In addition,under the oxic conditions of seawater,the oxidation of soluble Ce^(3+)to insoluble CeO_(2)together with Fe-Mn minerals results in Ce enrichment in ferromanganese nodules.This study provides a reference for the metallogenesis of ferromanganese nodules from the Northwest Pacific.展开更多
The characteristics of modified Circumpolar Deep Water(mCDW)on the continental shelf in Prydz Bay,East Antarctica,are studied based on hydrographic data obtained by the Chinese National Antarctic Research Expeditions ...The characteristics of modified Circumpolar Deep Water(mCDW)on the continental shelf in Prydz Bay,East Antarctica,are studied based on hydrographic data obtained by the Chinese National Antarctic Research Expeditions across 14 summers from 1999 to 2022.In austral summer,the mCDW upwells along the upper continental slope then intrudes on the continental shelf across the shelf break in a warm tongue that gradually upwells poleward.The mCDW intrusion at the 73°E section is relatively weaker in December and stronger in February while showing significant interannual variability.During strong intrusions(January 2000 and February 2003),the mCDW extends southward to 68°S and upwells to 50 m,whereas the mCDW only reaches the shelf break during weak intrusions(December 2004,January 2006,January 2011,and February 2015).The intensity of the mCDW intrusions correlates strongly with the accumulated wind stress curl(30 days prior)north of the shelf break(73.5°-78.0°E,64.5°-66.0°S).The summertime westerly winds play a key role in regulating the interannual variability of mCDW intrusion onto the continental shelf.A southward shift of the westerly winds promotes the upwelling and southward intrusion of mCDW across the shelf break.In addition,mCDW at 73°E can reach as far as 68°S due to the southward flow of mCDW being hindered by a northward outflowing branch of the coastal current at the Amery Ice Shelf(AIS)front.In austral summer,the mCDW had never been observed at the section along the AIS front;thus,it cannot directly contribute to the basal melting of the ice shelf.展开更多
Using literature published from 2010 onwards, this study investigates the ~3 500 km extension of the shallow shelf current in the South China Sea(SCS) during the winter and summer monsoons. This current is later ackno...Using literature published from 2010 onwards, this study investigates the ~3 500 km extension of the shallow shelf current in the South China Sea(SCS) during the winter and summer monsoons. This current is later acknowledged as the South China Sea shallow shelf Current(SCSSC). This current is primarily driven by monsoonal winds, and influenced by regional river plumes [Zhujiang(Pearl) River, Hong River, Mekong River] and the prominent South China Sea Warm Current(SCSWC) and South China Sea Western Boundary Current(SCSWBC). The current exhibits significant seasonal variations in both direction and pattern. During winter, it flows along the northern South China Sea's(NSCS) shelf and splits into two branches at the east of Hainan Island. One branch enters the Beibu Gulf through the Qiongzhou Strait and forms a major cyclonic circulation within the gulf, while the other branch flows southwestward along the southern coast of Hainan Island. These branches converge around 16°N latitude at the east of the Vietnamese shelf, then flow southward along the Sunda Shelf, where they deflect southwestward in “broadband”forms before curving southeastward along the east coast of Peninsular Malaysia(ECPM) and exiting via the Karimata Strait. In summer, the current exhibits a complex pattern. At the Sunda Shelf, it flows northwestward along the ECPM,then deflects northeastward around 6°N latitude, forming the Sunda Shelf's anti-cyclonic eddy(SSE) and causing upwelling on the east coast of Peninsular Malaysia(ECPMU). Near the eastern Vietnamese shelf, the current splits around 11°-12°N latitude into three distinct currents: the southward-flowing Vietnam Current, the northward-flowing Vietnam Meandering Current(VMC), and the southward-flowing SCSWBC. The VMC flows northward and then deflects northeastward south of Hainan Island, continuing northeastward along the NSCS's shelf and exiting through the Taiwan Strait.展开更多
Mussels are common anchoring organisms that adhere to the surfaces of various substrates with their byssus.The adhesion of mussel to substrates is contingent upon the presence of mussel foot proteins,of which Mytilus ...Mussels are common anchoring organisms that adhere to the surfaces of various substrates with their byssus.The adhesion of mussel to substrates is contingent upon the presence of mussel foot proteins,of which Mytilus edulis foot protein-1(Mefp-1)has been identified as the most abundant protein.It has been found that lipids are involved in the mussel adhesion process and can facilitate Mefp-1adhesion.In this research,the adhesion behavior of Mefp-1 on various substrate surfaces under the effect of typical seawater cations with or without the presence of lipid were investigated using a quartz crystal microbalance with dissipation(QCM-D).Results indicate that the presence of cations Ca^(2+),Mg^(2+),Na^(+),and K^(+)leads to varying degrees of reduction in the adhesion performance of Mefp-1 on different substrates.The degree of this reduction,however,was much alleviated in the presence of palmitic acid,which is involved in the mussel adhesion process.Therefore,the involvement of palmitic acid is advantageous for mussel protein adhesion to the substrate surface in the marine environment.This study illustrated the significant contribution of palmitic acid to mussel adhesion,which can help to better understand biofouling mechanisms and develop biomimetic adhesive materials.展开更多
The heat transfer coefficient of the water surface is an important parameter in the design of thermal discharge in nuclear power plant engineering.In this study,in situ observations were performed in the northwestern ...The heat transfer coefficient of the water surface is an important parameter in the design of thermal discharge in nuclear power plant engineering.In this study,in situ observations were performed in the northwestern South China Sea near a coastal nuclear power plant to evaluate the applicability of heat transfer coefficient calculation algorithms commonly used in marine thermal discharge engineering in China.The results show that the Regulation for Hydraulic and Thermal Model in Cooling Water Projects(SL 160-2012)is not applicable in calculating the heat transfer coefficient in offshore areas.SL 160-2012 significantly overestimates the heat loss at the sea surface.However,Code for Design of Cooling for Industrial Recirculating Water(GB/T 50102-2014)performs well,and its estimation coefficient is roughly consistent with the estimations of the COARE 3.6 bulk algorithm,which is extensively used in physical oceanography for calculating air-sea heat fluxes,and the Gunneberg formula.In a 3-day observation,the average heat transfer coefficients estimated using these three algorithms were 50.4,48.5,and 48.8 W m^(-2)℃^(-1),respectively,with a deviation of less than 4% among them,whereas that estimated using SL 160-2012 was as high as 176.3 W m^(-2)℃^(-1).The abnormally large value of SL 160-2012 is due to its additional cooling term,which is artificially increased by 100 times because of the incorrect unit conversion used when developing the regulation.If this error is corrected,the value will decrease to 50.5 W m^(-2)℃^(-1),which is very close to the estimation of GB/T 50102-2014.展开更多
Suitable temperature and light intensity play important roles in the formation of harmful algae blooms(HABs),which can pose serious threats to aquatic ecosystems and human health.In this study,we measured the growth,p...Suitable temperature and light intensity play important roles in the formation of harmful algae blooms(HABs),which can pose serious threats to aquatic ecosystems and human health.In this study,we measured the growth,physiological function,and paralytic shellfish toxins(PSTs)production of Alexandrium pacificum(CCMA-272),a strain isolated from East China Sea,at different temperatures(15,20,and 25℃)and light intensities(30,60,and 90μmol photons/(m^(2)·s)).Results indicate that temperature and light intensity significantly affected the growth,physiology,and toxigenic potentials of A.pacificum.The optimal conditions for the growth of A.pacificum were observed at 20℃ under60μmol photons/(m^(2)·s).Regarding the production of PSTs,this strain of A.pacificum produced 12 PSTs,including carbamate toxins:saxitoxin(STX),neosaxitoxin(NEO),and gonyautoxin 1–4(GTX1,GTX2,GTX3,GTX4);dicarbamoyl toxins:dicarbamoylsaxitoxin(dcSTX),dicarbamoylgonyautoxin 2,3(dcGTX2,dcGTX3);and N-sulfocarbamoyl toxins:N-sulfocarbamoylgonyautoxin 1,2(C1,C2),and gonyautoxin 5(GTX5).Among all the PSTs,C2 was the most abundant.Low temperature(15℃)and high light intensity(90μmol photons/(m^(2)·s))were beneficial for the production of PSTs in A.pacificum.When cultured at 20 and 25℃,A.pacificum generated comparable total quantities of PSTs,yet the toxicity levels were lower at 25℃.Intra-cellular PSTs contents were greater than extra-cellular PSTs contents,except those under the condition of 25℃ with 30μmol photons/(m^(2)·s).However,as the increase of temperature,A.pacificum released more amounts of analogues with higher toxicity levels(e.g.,STX and dcGTX_(2))into the environment than intracellularly.These findings emphasize the significant sensitivity of A.pacificum to temperature and light intensity,highlighting the importance of evaluating both intra-cellular and extra-cellular PSTs for assessing its toxicity and aiding in the prediction and management of HABs.展开更多
Significant wave period is an important parameter in coastal and offshore engineering design.Traditional spectral wave models do not directly calculate this parameter,which means that it needs to be estimated from the...Significant wave period is an important parameter in coastal and offshore engineering design.Traditional spectral wave models do not directly calculate this parameter,which means that it needs to be estimated from the spectral periods using empirical formulas.The wave energy period is one of the wave periods directly output by many wave models and is often used in studies of wave energy.This study investigated the relationship between significant wave period and wave energy period using wave data measured at three stations in the coastal waters of China.The observations recorded at these stations in the South China Sea,the East China Sea,and the Bohai Sea covered a wide range of surface wave conditions.Analysis indicated that the ratio of significant wave period to wave energy period is closely related to the Goda peakedness parameter of the wave spectra.Therefore,we proposed an empirical formula in which significant wave period is a function of wave energy period and the Goda peakedness parameter.Evaluation results showed that the performance of this formula is substantially better than that of fitting formulas that use constant coefficients.展开更多
The code of the list of sea and island problems is the unique identification code of the regulatory files,which is accompanied by the whole life cycle of the regulatory"discovery,verification and disposal".S...The code of the list of sea and island problems is the unique identification code of the regulatory files,which is accompanied by the whole life cycle of the regulatory"discovery,verification and disposal".Standardized coding of problems found by supervision and tracking and recording the whole life cycle of supervision can quickly guide supervisors to find problems,identify problems,initiate responses and carry out follow-up disposal,which is a reflection of whole-process management of supervision.Combining with sea and island regulatory systems and mechanisms,combed the supervision business flow,divides the supervision link,based on the existing coding system,from the Angle of supervision refinement,puts forward a whole lifetime oriented regulatory system of sea and island issues list for coding,coding through to find and stop and disposal of the three links all process application scenarios,The implementation of the whole business"one code"association,the whole process of"one code"management,practice verification shows the effectiveness of the method,compared with the original coding rules for the supervision of all links and results reflect more intuitive,comprehensive,can be better applied to the practice of supervision.展开更多
Harmful macroalgal blooms caused by Ulva prolifera and Sargassum horneri are increasing in the Yellow Sea and East China Sea.However,our understanding of macroalgal blooms before 2008 is fragmented and unclear.Using t...Harmful macroalgal blooms caused by Ulva prolifera and Sargassum horneri are increasing in the Yellow Sea and East China Sea.However,our understanding of macroalgal blooms before 2008 is fragmented and unclear.Using time-series Landsat imagery from 1984 to 2008,we examined macroalgal bloom events and their evolutionary patterns.The results suggest that no macroalgal blooms were observed before 1999.Ulva blooms could be traced back to 1999 and occurred on a small scale in 2000,2004 and 2005,before escalating into large green tides in 2007 and 2008.Notably,these Ulva blooms were confined to the southern Yellow Sea from May to August.In comparison,Sargassum blooms were first detected in the East China Sea in March 2000 and occurred almost every year thereafter,although the size of the blooms showed significant interannual variation.The distribution areas generally moved northwards from March until the bloom dissipated in May or June,suggesting the influence of the monsoon and currents.Our investigation provided some insight into the bloom history of these two harmful macroalgal blooms in the Yellow Sea and East China Sea.展开更多
To explore the relationship of microplastic pollution in different media in marine environment,microplastics in the surface seawater and sediments of Laizhou Bay,Bohai Sea,North China,were studied.Seawater samples wer...To explore the relationship of microplastic pollution in different media in marine environment,microplastics in the surface seawater and sediments of Laizhou Bay,Bohai Sea,North China,were studied.Seawater samples were collected using a pre-concentrator equipped with a 20-μm mesh size sieve,and sediment samples were collected by a box sampler.The shape,color,size,and type of microplastics were obtained by a stereomicroscope and a Fourier transform infrared spectrometer(ATR-μ-FT-IR).Results show that the abundance of microplastics in the surface seawater of Laizhou Bay was 858.3±573.2 items/m~3,and that of microplastics in sediments was 151.0±77.4 items/kg dry weight(d.w.)The microplastics in seawater and sediments were mainly fibrous.Meanwhile,the microplastics in seawater were mainly transparent,and those in sediments were transparent and blue.The highest proportion of microplastics in seawater was rayon(77.48%),followed by polyethylene terephthalate(PET,13.17%).The highest proportion of microplastics in sediments was rayon(73.66%),followed by PET(8.90%).The size of microplastics in 1000-2000μm accounted for the largest proportion of 28.54%in seawater,while that in 500-1000μm took 27.93%in sediment.Microplastics in seawater and sediment showed medium-level pollution.In seawater,microplastic abundance was higher in offshore and nearshore areas of Weifang.In sediment,microplastic abundance was higher in offshore and nearshore areas of Dongying.The results of the principal component analysis(PCA)indicated that microplastics in sediment exhibited greater stability compared to those in seawater.The microplastics in seawater and sediment show a positive correlation in terms of shape and plastic type,while exhibiting a negative correlation in terms of color.Overall,microplastics in sediments were smaller in size,and those in seawater and sediments had consistent size distribution characteristics in space.展开更多
Polymetallic nodules,hereinafter referred to as PN,enriched with Co,Ni,Mn,and Cu,are likely to be commercially mined in the near future.These metals in PN are potential strategic alternatives for the world’s energy t...Polymetallic nodules,hereinafter referred to as PN,enriched with Co,Ni,Mn,and Cu,are likely to be commercially mined in the near future.These metals in PN are potential strategic alternatives for the world’s energy transition.Therefore,intensive studies are necessary on the spatial distribution patterns of PN in the deep sea.In this study,the distribution probabilities of PN in the Pacific,Indian and Atlantic oceans were estimated based on binary logistic regression of PN occurrence with ore-controlling factors including water depth(WD),marine sediment thickness(SedTh),Calcium carbonate(CaCO_(3))concentrations in surface sediments,primary productivity(PP),near bottom current velocities(BC).Furthermore,the distribution probability of PN was constrained by seafloor ages and PN sites,and subsequently,the prospects for nodules in the Pacific,Indian and Atlantic oceans were obtained.The results indicate that the low-latitude Pacific region(30°N-30°S),particularly the Clarion-Clipperton Zone and the Penrhyn Basin,is the most promising area for PN exploration.展开更多
The intertidal zone of mangroves has a significant impact on the ecological environment by serving as a crucial habitat for a wide range of organisms.When assessing heavy metal contamination in sediments within this z...The intertidal zone of mangroves has a significant impact on the ecological environment by serving as a crucial habitat for a wide range of organisms.When assessing heavy metal contamination in sediments within this zone,it is essential to establish a regional geochemical baseline that accounts for natural variations.In this study,regional geochemical baselines of heavy metals were established based on core sediment samples collected from Dongzhai Harbor in November 2015.Linear regression analysis was employed to examine the correlations between heavy metals and potential normalized elements.Subsequently,the sediment quality and intensity of pollutant input in the sediments of a mangrove intertidal zone were evaluated with enrichment factor(EF)and excessive influx of heavy metals.The EF values for Cr,Cd,Pb,Zn,and Ni in the study area were all below 1.5,indicating minimal levels of contamination;however,minor Cu contamination was observed in the high tidal flat area due to potential terrestrial inputs.These findings suggest that the overall environmental quality about heavy metals was good within the intertidal zone of mangroves.Moreover,as for the excess fluxes of heavy metals in intertidal sediments,there was consistency between influence and intervention of human activities on sedimentary environment during the selected period when examining variation trends.展开更多
The research on ocean dynamics information plays a crucial role in understanding ocean phenomena, assessing marine environmental impacts, and guiding engineering designs. The Doppler information observed by radars ref...The research on ocean dynamics information plays a crucial role in understanding ocean phenomena, assessing marine environmental impacts, and guiding engineering designs. The Doppler information observed by radars reflects sea surface dynamics, to which ocean waves make important contributions. Low-incidence-angle real aperture radar(RAR)demonstrates great potential for independently observing vectorial Doppler information on the ocean surface. To systematically characterize and accurately estimate the wave-induced Doppler frequency shift(WVF) from lowincidence-angle RAR, this study conducts comprehensive influencing factor analysis and establishes sea-stateparameterized WVF models. First, a simulated WVF dataset is generated under a rotating low-incidence-angle RAR.The feature parameters of WVF are then determined by analysing contributing factors including wind waves, swells,and sea state parameters. Furthermore, two WVF models(WVF_Ku P9 with 9 inputs and WVF_Ku P4 with 4 inputs) are constructed by the Transformer encoder for different application scenarios. Both models achieve high accuracy for WVF estimation with root mean square errors(RMSE) of 1.874 Hz and 2.716 Hz, respectively. The reliability and superiority of the proposed models are validated through comparisons with the Ka DOP, which is a typical geophysical model function(GMF). The findings in this paper advance the understanding of WVF characteristics and generation mechanisms. The proposed estimation models can provide reliable estimates, offering critical references for lowincidence-angle RAR applications such as ocean surface current retrieval.展开更多
Decabromodiphenyl ethane(DBDPE)is widely used as an additive flame retardant and has led to global pollution.Its has a large molecular mass and is prone to debromination and degradation under photothermal conditions,r...Decabromodiphenyl ethane(DBDPE)is widely used as an additive flame retardant and has led to global pollution.Its has a large molecular mass and is prone to debromination and degradation under photothermal conditions,resulting in smaller homologous compounds.Due to the lack of standard substances for debromination products,the in-depth study of DBDPE environmental geochemical behavior through debromination conversion has been hindered.Therefore,based on DBDPE photodegradation experiment,this study first analyzed and identified the brominated products of DBDPE using high-performance liquid chromatography-atmospheric pressure photoionization-time of flight mass spectrometry(HPLC-APPI-TOF/MS).Four debromination products-nonabromodiphenyl ethane(nonaBDPE),octabromodiphenyl ethane(octa-BDPE),heptabromodiphenyl ethane(hepta-BDPE)and hexabromodiphenyl ethane(hexa-BDPE)are identified based on the characteristic ion peak of[M-Br+O]^(-) in negative ion mode.Subsequently,using methanol as the mobile phase,four debromination products of DBDPE were separated and purified with a semi-preparative high-performance liquid chromatography(SP-HPLC)system equipped with an Agilent Zorbax Eclipse PAH column(4.6 mm×250 mm,5μm).The first-time acquisition of hexa-BDPE(60.00μg),octa-BDPE(19.40μg),hepta-BDPE(31.20μg)and octa-BDPE(isomer,45.20μg)with purity exceeding 90%has been achieved.Among them,the purity of one hepta-BDPE monomer is as high as 98.91%.This study indicates that based on photodegradation experiments,the combination of HPLC-APPI-TOF/MS and SP-HPLC techniques can rapidly identify and prepare DBDPE debrominated products.This approach meets the requirements for preliminary research on the pollution characteristics of DBDPE debrominated compounds and offers a feasible solution for the preparation of standard reference materials for emerging pollutants.展开更多
The Malacca Strait(MS)is a vital conduit for the exchange of water and sediment between the Indian Ocean and the Pacific Ocean,serving as a critical‘gateway'for sediment transport.Here,we present the geochemical ...The Malacca Strait(MS)is a vital conduit for the exchange of water and sediment between the Indian Ocean and the Pacific Ocean,serving as a critical‘gateway'for sediment transport.Here,we present the geochemical characteristics of surface sediments in the MS to elucidate the relationship between terrestrial material inputs and modern oceanic dynamic transport processes in the strait.The results reveal that the MS can be divided into three distinct geochemical provinces.ProvinceⅠ,located in the central region of the strait,is characterized by residual deposits.The preservation of these residual deposits can be attributed to the restricted sediment supply and the relatively weaker modern sedimentary hydrodynamic conditions.ProvinceⅡ,situated to the north of ProvinceⅠ,exhibits provenance differences between its southern and northern regions.The northern region is primarily supplied by sediments originating from the eastern shelf of the Andaman Sea,whereas sediments derived from Sumatra and the Sunda Shelf are predominantly deposited in the southern part of ProvinceⅡ.ProvinceⅢextends along the western coast of the Malaysian Peninsula,with sediments primarily sourced from the Malaysian Peninsula and the Sunda Shelf,while contributions from Sumatra and the eastern shelf of the Andaman Sea are negligible.River sediments from the Malaysian Peninsula and Sumatra are transported northwestward along their respective coasts by prevailing currents,which also facilitate the transportation of Sunda Shelf sediments within the strait,while sediments from the eastern shelf of the Andaman Sea are delivered to the MS via southward coastal currents during the southwest monsoon period.The southward currents and well-developed eddies potentially impede the northward transport of sediments from the Sunda Shelf and restrict the distribution of Andaman Sea sediments within the strait.This study substantially enhances the understanding of source-to-sink processes in the Indo-Pacific region.展开更多
基金This study was jointly supported by the National National Science Foundation of China under contract Nos 40376009,40231013 and 49836010the Ministry of Science and Technology of China under contact Nos 2003DIB4J135,2005DIB3J114 and 2006BAC06B02.
文摘Thermohaline features, spatial extensions, and depths of the antarctic circumpolar deep water, the antarctic bottom water, and the upper layer water near the Prydz Bay （ including the Prydz Bay s.mmer surface water, the antarctic winter water, and the Prydz Bay shelf water ） are analyzed and studied by use of the full depth CTD data obtained in the Southern Ocean near the Prydz Bay during the 1998/1999 austral summer. The northward extension of the shelf water, the thickness of the temperature inversion layer, the minima in the vertical temperature profile and the vertical temperature gradient are interpreted. On the basis of analysis of gravitational potential field, the geostrophic current and the geostrophic volume transport are calculated to determine the location of the strongest current in the zonal circulation near the Prydz Bay and to find the spatial variability of the volume transport in the64° -66.5°S zone. In addition, the central location, the frontal strength, the vertical depth and thickness of the continental water boundary （CWB） are estimated from the CTD data to expound the spatial variability of CWB in the study area （64° -66.5°S, 70° -75°E）.
基金supported by the Chinese Polar Environment Comprehensive Investigation and Assessment Programmes (Grant nos.CHINARE2013-04-01,CHINARE2013-04-04)the National High-tech Research & Development Program of China (Grant no.2010CB950301)
文摘Oceanographic surveying has been one of the key missions of the Chinese National Antarctic Research Expedition since 1984. Using the field data obtained in these surveys and the results from remote sensing and numerical models, Chinese physical oceanographers have investigated the water masses, fronts and circulation patterns in the Southern Ocean. The results of nearly 30 years of research are summarized in this paper. Most oceanographic observations by Chinese researchers have been con- ducted in Prydz Bay and the adjacent seas. CTD （Conductivity Temperature and Depth） data, collected during the past 20 years, have been applied to study several features of the water masses in this region： The spatial variation of warm summer surface water, the northward extension of shelf water, the flow of ice shelf water from the cavity beneath the Amery Ice Shelf, the upweUing of the Circumpolar Deep Water, and the formation of the Antarctic Bottom Water. The circulation and its dynamic factors have been analyzed with dynamic heights calculated from CTD data as well as by numerical models. The structure and strength of the fronts in the southeast Indian Ocean and the Drake Passage were investigated with underway XBT/XCTD （Expendable Bathythermo- graph/Expendable CTD） and ADCP （Acoustic Doppler Current Profiler） data. Their interaunual variations have been determined and the factors of influence, especially the atmospheric forcing and mesoscale oceanic processes, were studied using remote sens- ing data. The dynamic mechanism of the Antarctic Circumpolar Current （ACC） was analyzed by theoretical models. The transport and pattern of the ACC have been well reproduced by coupled sea ice-ocean models. Additional details of ACC variability were identified based on satellite altimeter data. The response of the ACC to climate change was studied using reanalysis data. Prospects for future research are presented at the end of this paper.
基金The 973 Project under contract Nos 2010CB950300 and 2010CB950500the Key Project of the National Natural Science Foundation of China under contract No. 40730842+1 种基金the Public Science and Technology Research Funds projects of ocean under contract No. 201105019the International Cooperation Project of Ministry of Science and Technology of China under contract No. S2011GR0348
文摘A global ocean carbon cycle model based on the ocean general circulation model POP and the improved biogeochemical model OCMIP-2 is employed to simulate carbon cycle processes under the historically observed atmospheric CO 2 concentration and different future scenarios （called Rep- resentative Concentration Pathways, or RCPs）. The RCPs in this paper follow the design of Inter- governmental Panel on Climate Change （IPCC） for the Fifth Assessment Report （AR5）. The model results show that the ocean absorbs CO 2 from atmosphere and the absorbability will continue in the 21st century under the four RCPs. The net air-sea CO 2 flux increased during the historical time and reached 1.87 Pg/a （calculated by carbon） in 2005; however, it would reach peak and then decrease in the 21st century. The ocean absorbs CO 2 mainly in the mid latitude, and releases CO 2 in the equator area. However, in the Antarctic Circumpolar Current （ACC） area the ocean would change from source to sink under the rising CO 2 concentration, including RCP4.5, RCP6.0, and RCP8.5. In 2100, the anthropogenic carbon would be transported to the 40 S in the Atlantic Ocean by the North Atlantic Deep Water （NADW）, and also be transported to the north by the Antarctic Bottom Water （AABW） along the Antarctic continent in the Atlantic and Pacific oceans. The ocean pH value is also simulated by the model. The pH decreased by 0.1 after the industrial revolution, and would continue to decrease in the 21st century. For the highest concentration sce- nario of RCP8.5, the global averaged pH would decrease by 0.43 to reach 7.73 due to the absorption of CO 2 from atmosphere.
基金The National Natural Science Foundation of China under contract No.41806048the Open Fund of the Hubei Key Laboratory of Marine Geological Resources under contract No.MGR202009+2 种基金the Fund from the Key Laboratory of Deep-Earth Dynamics of Ministry of Natural Resource,Institute of Geology,Chinese Academy of Geological Sciences under contract No.J1901-16the Aoshan Science and Technology Innovation Project of Pilot National Laboratory for Marine Science and Technology(Qingdao)under contract No.2015ASKJ03-Seabed Resourcesthe Fund from the Korea Institute of Ocean Science and Technology(KIOST)under contract No.PE99741.
文摘The South Yellow Sea basin is filled with Mesozoic-Cenozoic continental sediments overlying pre-Palaeozoic and Mesozoic-Palaeozoic marine sediments.Conventional multi-channel seismic data cannot describe the velocity structure of the marine residual basin in detail,leading to the lack of a deeper understanding of the distribution and lithology owing to strong energy shielding on the top interface of marine sediments.In this study,we present seismic tomography data from ocean bottom seismographs that describe the NEE-trending velocity distributions of the basin.The results indicate that strong velocity variations occur at shallow crustal levels.Horizontal velocity bodies show good correlation with surface geological features,and multi-layer features exist in the vertical velocity framework(depth:0–10 km).The analyses of the velocity model,gravity data,magnetic data,multichannel seismic profiles,and drilling data showed that high-velocity anomalies(>6.5 km/s)of small(thickness:1–2 km)and large(thickness:>5 km)scales were caused by igneous complexes in the multi-layer structure,which were active during the Palaeogene.Possible locations of good Mesozoic and Palaeozoic marine strata are limited to the Central Uplift and the western part of the Northern Depression along the wide-angle ocean bottom seismograph array.Following the Indosinian movement,a strong compression existed in the Northern Depression during the extensional phase that caused the formation of folds in the middle of the survey line.This study is useful for reconstructing the regional tectonic evolution and delineating the distribution of the marine residual basin in the South Yellow Sea basin.
基金The Fund of Laoshan Laboratory under contract No.LSKJ202202700the Basic Scientific Fund for National Public Research Institutes of China under contract No.2024Q02+1 种基金the National Natural Science Foundation of China under contract Nos 42076023 and 42430402the Global Change and Air-Sea InteractionⅡProject under contract No.GASI-01-ATP-STwin.
文摘The Indonesian Throughflow(ITF)plays important roles in global ocean circulation and climate systems.Previous studies suggested the ITF interannual variability is driven by both the El Niño-Southern Oscillation(ENSO)and the Indian Ocean Dipole(IOD)events.The detailed processes of ENSO and/or IOD induced anomalies impacting on the ITF,however,are still not clear.In this study,this issue is investigated through causal relation,statistical,and dynamical analyses based on satellite observation.The results show that the driven mechanisms of ENSO on the ITF include two aspects.Firstly,the ENSO related wind field anomalies driven anomalous cyclonic ocean circulation in the western Pacific,and off equatorial upwelling Rossby waves propagating westward to arrive at the western boundary of the Pacific,both tend to induce negative sea surface height anomalies(SSHA)in the western Pacific,favoring ITF reduction since the develop of the El Niño through the following year.Secondly,the ENSO events modulate equatorial Indian Ocean zonal winds through Walker Circulation,which in turn trigger eastward propagating upwelling Kelvin waves and westward propagating downwelling Rossby waves.The Rossby waves are reflected into downwelling Kelvin waves,which then propagate eastward along the equator and the Sumatra-Java coast in the Indian Ocean.As a result,the wave dynamics tend to generate negative(positive)SSHA in the eastern Indian Ocean,and thus enhance(reduce)the ITF transport with time lag of 0-6 months(9-12 months),respectively.Under the IOD condition,the wave dynamics also tend to enhance the ITF in the positive IOD year,and reduce the ITF in the following year.
基金The Fund of Laoshan Laboratory under contract No.LSKJ202203602the National key R&D Program of China under contract No.2022YFC2803600the Taishan Scholarship from Shandong Province.
文摘To explore the geochemical characteristics and genesis of the elements in ferromanganese nodules from the Northwest Pacific,this study analyses the mineral composition,elemental content,occurrence phase and genetic mechanisms of samples by X-ray diffraction(XRD),inductively coupled plasma-optical emission spectrometry(ICP-OES),inductively coupled plasma-mass spectrometry(ICP-MS)and phase analysis methods.The results show that ferromanganese nodules are mainly hydrogenetic,and Mn/Fe content ratio ranges from 0.95 to 2.05.The major minerals are vernadite(δ-MnO_(2))and amorphous ferric oxyhydroxide(FeOOH),and the secondary minerals include todorokite,birnessite,quartz and plagioclase.Ferromanganese nodules contain high contents of Co(0.24%-0.42%),Cu(0.23%-0.73%),Ni(0.33%-0.86%)and rare earth elements(REEs,1192-1990μg/g),which have positive Ce and negative Y anomalies but no Eu anomaly.A cluster analysis suggests that the elements in ferromanganese nodules can be divided into three groups:hydrogenetic components,including Fe,Ti,Zr,P,Pb,Co,Ba,Sr,V and REEs;diagenetic components,including Mn,Ni,Mg,Zn and Cu;and detrital components,including Al,Na,K and Ca.According to chemical leaching,ferromanganese nodules can be divided into four phases:Na,Ca,Mg and Sr are mainly enriched in the carbonate phase;Mn,Co,Ni and Ba are mainly enriched in the Mn-oxide phase;Fe,P,Ti,Cu,Pb,V,Zn,Zr and REEs are mainly enriched in the Fe-oxide phase;and Al and K are mainly enriched in the residual phase.A combination of the two different methods reveal selective enrichment of metal elements from seawater by ferromanganese nodules,featuring multisource mineralization.Moreover,through ion exchange and adsorption,approximately 71.2%of REEs are enriched in the Fe-oxide phase,15.4%in the Mn-oxide phase and 12.4%in the residual phase,while REE contents in the carbonate phase are relatively low.In addition,under the oxic conditions of seawater,the oxidation of soluble Ce^(3+)to insoluble CeO_(2)together with Fe-Mn minerals results in Ce enrichment in ferromanganese nodules.This study provides a reference for the metallogenesis of ferromanganese nodules from the Northwest Pacific.
基金supported by the National Natural Science Foundation of China(No.41976217)the National Key R&D Program of China(No.2018YFA0605701).
文摘The characteristics of modified Circumpolar Deep Water(mCDW)on the continental shelf in Prydz Bay,East Antarctica,are studied based on hydrographic data obtained by the Chinese National Antarctic Research Expeditions across 14 summers from 1999 to 2022.In austral summer,the mCDW upwells along the upper continental slope then intrudes on the continental shelf across the shelf break in a warm tongue that gradually upwells poleward.The mCDW intrusion at the 73°E section is relatively weaker in December and stronger in February while showing significant interannual variability.During strong intrusions(January 2000 and February 2003),the mCDW extends southward to 68°S and upwells to 50 m,whereas the mCDW only reaches the shelf break during weak intrusions(December 2004,January 2006,January 2011,and February 2015).The intensity of the mCDW intrusions correlates strongly with the accumulated wind stress curl(30 days prior)north of the shelf break(73.5°-78.0°E,64.5°-66.0°S).The summertime westerly winds play a key role in regulating the interannual variability of mCDW intrusion onto the continental shelf.A southward shift of the westerly winds promotes the upwelling and southward intrusion of mCDW across the shelf break.In addition,mCDW at 73°E can reach as far as 68°S due to the southward flow of mCDW being hindered by a northward outflowing branch of the coastal current at the Amery Ice Shelf(AIS)front.In austral summer,the mCDW had never been observed at the section along the AIS front;thus,it cannot directly contribute to the basal melting of the ice shelf.
基金Long-Term Research Grant Scheme (LRGS:56041)Interaction of Ocean Dynamics With The Climate System of Past,Present,and Future Using Ocean Observation Integrated Data and Numerical Modeling。
文摘Using literature published from 2010 onwards, this study investigates the ~3 500 km extension of the shallow shelf current in the South China Sea(SCS) during the winter and summer monsoons. This current is later acknowledged as the South China Sea shallow shelf Current(SCSSC). This current is primarily driven by monsoonal winds, and influenced by regional river plumes [Zhujiang(Pearl) River, Hong River, Mekong River] and the prominent South China Sea Warm Current(SCSWC) and South China Sea Western Boundary Current(SCSWBC). The current exhibits significant seasonal variations in both direction and pattern. During winter, it flows along the northern South China Sea's(NSCS) shelf and splits into two branches at the east of Hainan Island. One branch enters the Beibu Gulf through the Qiongzhou Strait and forms a major cyclonic circulation within the gulf, while the other branch flows southwestward along the southern coast of Hainan Island. These branches converge around 16°N latitude at the east of the Vietnamese shelf, then flow southward along the Sunda Shelf, where they deflect southwestward in “broadband”forms before curving southeastward along the east coast of Peninsular Malaysia(ECPM) and exiting via the Karimata Strait. In summer, the current exhibits a complex pattern. At the Sunda Shelf, it flows northwestward along the ECPM,then deflects northeastward around 6°N latitude, forming the Sunda Shelf's anti-cyclonic eddy(SSE) and causing upwelling on the east coast of Peninsular Malaysia(ECPMU). Near the eastern Vietnamese shelf, the current splits around 11°-12°N latitude into three distinct currents: the southward-flowing Vietnam Current, the northward-flowing Vietnam Meandering Current(VMC), and the southward-flowing SCSWBC. The VMC flows northward and then deflects northeastward south of Hainan Island, continuing northeastward along the NSCS's shelf and exiting through the Taiwan Strait.
基金Supported by the National Natural Science Foundation of China(No.41776177)the Qingdao Marine Science and Technology Pilot National Laboratory Fund(Nos.2016ASKJ14,QNLM2016ORP0403)。
文摘Mussels are common anchoring organisms that adhere to the surfaces of various substrates with their byssus.The adhesion of mussel to substrates is contingent upon the presence of mussel foot proteins,of which Mytilus edulis foot protein-1(Mefp-1)has been identified as the most abundant protein.It has been found that lipids are involved in the mussel adhesion process and can facilitate Mefp-1adhesion.In this research,the adhesion behavior of Mefp-1 on various substrate surfaces under the effect of typical seawater cations with or without the presence of lipid were investigated using a quartz crystal microbalance with dissipation(QCM-D).Results indicate that the presence of cations Ca^(2+),Mg^(2+),Na^(+),and K^(+)leads to varying degrees of reduction in the adhesion performance of Mefp-1 on different substrates.The degree of this reduction,however,was much alleviated in the presence of palmitic acid,which is involved in the mussel adhesion process.Therefore,the involvement of palmitic acid is advantageous for mussel protein adhesion to the substrate surface in the marine environment.This study illustrated the significant contribution of palmitic acid to mussel adhesion,which can help to better understand biofouling mechanisms and develop biomimetic adhesive materials.
基金supported by the Laoshan Laboratory(No.LSKJ202201600)the National Natural Science Foundation of China(No.41821004)。
文摘The heat transfer coefficient of the water surface is an important parameter in the design of thermal discharge in nuclear power plant engineering.In this study,in situ observations were performed in the northwestern South China Sea near a coastal nuclear power plant to evaluate the applicability of heat transfer coefficient calculation algorithms commonly used in marine thermal discharge engineering in China.The results show that the Regulation for Hydraulic and Thermal Model in Cooling Water Projects(SL 160-2012)is not applicable in calculating the heat transfer coefficient in offshore areas.SL 160-2012 significantly overestimates the heat loss at the sea surface.However,Code for Design of Cooling for Industrial Recirculating Water(GB/T 50102-2014)performs well,and its estimation coefficient is roughly consistent with the estimations of the COARE 3.6 bulk algorithm,which is extensively used in physical oceanography for calculating air-sea heat fluxes,and the Gunneberg formula.In a 3-day observation,the average heat transfer coefficients estimated using these three algorithms were 50.4,48.5,and 48.8 W m^(-2)℃^(-1),respectively,with a deviation of less than 4% among them,whereas that estimated using SL 160-2012 was as high as 176.3 W m^(-2)℃^(-1).The abnormally large value of SL 160-2012 is due to its additional cooling term,which is artificially increased by 100 times because of the incorrect unit conversion used when developing the regulation.If this error is corrected,the value will decrease to 50.5 W m^(-2)℃^(-1),which is very close to the estimation of GB/T 50102-2014.
基金Supported by the National Natural Science Foundation of China(Nos.32101290,52009082)the Natural Science Foundation of Jiangsu Province(No.BK20210364)the Fundamental Research Funds for the Central Universities(No.B220202044)。
文摘Suitable temperature and light intensity play important roles in the formation of harmful algae blooms(HABs),which can pose serious threats to aquatic ecosystems and human health.In this study,we measured the growth,physiological function,and paralytic shellfish toxins(PSTs)production of Alexandrium pacificum(CCMA-272),a strain isolated from East China Sea,at different temperatures(15,20,and 25℃)and light intensities(30,60,and 90μmol photons/(m^(2)·s)).Results indicate that temperature and light intensity significantly affected the growth,physiology,and toxigenic potentials of A.pacificum.The optimal conditions for the growth of A.pacificum were observed at 20℃ under60μmol photons/(m^(2)·s).Regarding the production of PSTs,this strain of A.pacificum produced 12 PSTs,including carbamate toxins:saxitoxin(STX),neosaxitoxin(NEO),and gonyautoxin 1–4(GTX1,GTX2,GTX3,GTX4);dicarbamoyl toxins:dicarbamoylsaxitoxin(dcSTX),dicarbamoylgonyautoxin 2,3(dcGTX2,dcGTX3);and N-sulfocarbamoyl toxins:N-sulfocarbamoylgonyautoxin 1,2(C1,C2),and gonyautoxin 5(GTX5).Among all the PSTs,C2 was the most abundant.Low temperature(15℃)and high light intensity(90μmol photons/(m^(2)·s))were beneficial for the production of PSTs in A.pacificum.When cultured at 20 and 25℃,A.pacificum generated comparable total quantities of PSTs,yet the toxicity levels were lower at 25℃.Intra-cellular PSTs contents were greater than extra-cellular PSTs contents,except those under the condition of 25℃ with 30μmol photons/(m^(2)·s).However,as the increase of temperature,A.pacificum released more amounts of analogues with higher toxicity levels(e.g.,STX and dcGTX_(2))into the environment than intracellularly.These findings emphasize the significant sensitivity of A.pacificum to temperature and light intensity,highlighting the importance of evaluating both intra-cellular and extra-cellular PSTs for assessing its toxicity and aiding in the prediction and management of HABs.
基金The National Natural Science Foundation of China under contract No.41821004the Basic Scientific Fund for National Public Research Institutes of China under contract No.2020Q08the Fund of Laoshan Laboratory under contract No.LSKJ202201600.
文摘Significant wave period is an important parameter in coastal and offshore engineering design.Traditional spectral wave models do not directly calculate this parameter,which means that it needs to be estimated from the spectral periods using empirical formulas.The wave energy period is one of the wave periods directly output by many wave models and is often used in studies of wave energy.This study investigated the relationship between significant wave period and wave energy period using wave data measured at three stations in the coastal waters of China.The observations recorded at these stations in the South China Sea,the East China Sea,and the Bohai Sea covered a wide range of surface wave conditions.Analysis indicated that the ratio of significant wave period to wave energy period is closely related to the Goda peakedness parameter of the wave spectra.Therefore,we proposed an empirical formula in which significant wave period is a function of wave energy period and the Goda peakedness parameter.Evaluation results showed that the performance of this formula is substantially better than that of fitting formulas that use constant coefficients.
文摘The code of the list of sea and island problems is the unique identification code of the regulatory files,which is accompanied by the whole life cycle of the regulatory"discovery,verification and disposal".Standardized coding of problems found by supervision and tracking and recording the whole life cycle of supervision can quickly guide supervisors to find problems,identify problems,initiate responses and carry out follow-up disposal,which is a reflection of whole-process management of supervision.Combining with sea and island regulatory systems and mechanisms,combed the supervision business flow,divides the supervision link,based on the existing coding system,from the Angle of supervision refinement,puts forward a whole lifetime oriented regulatory system of sea and island issues list for coding,coding through to find and stop and disposal of the three links all process application scenarios,The implementation of the whole business"one code"association,the whole process of"one code"management,practice verification shows the effectiveness of the method,compared with the original coding rules for the supervision of all links and results reflect more intuitive,comprehensive,can be better applied to the practice of supervision.
基金funded by the National Key R&D Program of China(No.2022YFC3106005)the Shandong Provincial Natural Science Foundation(No.ZR2021MD 122)+2 种基金the MNR Key Laboratory of Eco-Environmental Science and Technology,China(No.MEEST-2023-04)the Taishan Scholars Program(No.tstp20230642)the Shandong Provincial Key Laboratory of Marine Ecological Environment and Disaster Prevention and Mitigation(Nos.201708,202209,202314)。
文摘Harmful macroalgal blooms caused by Ulva prolifera and Sargassum horneri are increasing in the Yellow Sea and East China Sea.However,our understanding of macroalgal blooms before 2008 is fragmented and unclear.Using time-series Landsat imagery from 1984 to 2008,we examined macroalgal bloom events and their evolutionary patterns.The results suggest that no macroalgal blooms were observed before 1999.Ulva blooms could be traced back to 1999 and occurred on a small scale in 2000,2004 and 2005,before escalating into large green tides in 2007 and 2008.Notably,these Ulva blooms were confined to the southern Yellow Sea from May to August.In comparison,Sargassum blooms were first detected in the East China Sea in March 2000 and occurred almost every year thereafter,although the size of the blooms showed significant interannual variation.The distribution areas generally moved northwards from March until the bloom dissipated in May or June,suggesting the influence of the monsoon and currents.Our investigation provided some insight into the bloom history of these two harmful macroalgal blooms in the Yellow Sea and East China Sea.
基金the Laoshan Laboratory(No.LSKJ202203901)the Natural Science Foundation of Shandong Province,China(No.ZR2021MD079)+1 种基金the APEC Cooperation Fund(No.WJ1323001)the Asian Cooperation Fund(Nos.WJ1223001,WJ0923015)。
文摘To explore the relationship of microplastic pollution in different media in marine environment,microplastics in the surface seawater and sediments of Laizhou Bay,Bohai Sea,North China,were studied.Seawater samples were collected using a pre-concentrator equipped with a 20-μm mesh size sieve,and sediment samples were collected by a box sampler.The shape,color,size,and type of microplastics were obtained by a stereomicroscope and a Fourier transform infrared spectrometer(ATR-μ-FT-IR).Results show that the abundance of microplastics in the surface seawater of Laizhou Bay was 858.3±573.2 items/m~3,and that of microplastics in sediments was 151.0±77.4 items/kg dry weight(d.w.)The microplastics in seawater and sediments were mainly fibrous.Meanwhile,the microplastics in seawater were mainly transparent,and those in sediments were transparent and blue.The highest proportion of microplastics in seawater was rayon(77.48%),followed by polyethylene terephthalate(PET,13.17%).The highest proportion of microplastics in sediments was rayon(73.66%),followed by PET(8.90%).The size of microplastics in 1000-2000μm accounted for the largest proportion of 28.54%in seawater,while that in 500-1000μm took 27.93%in sediment.Microplastics in seawater and sediment showed medium-level pollution.In seawater,microplastic abundance was higher in offshore and nearshore areas of Weifang.In sediment,microplastic abundance was higher in offshore and nearshore areas of Dongying.The results of the principal component analysis(PCA)indicated that microplastics in sediment exhibited greater stability compared to those in seawater.The microplastics in seawater and sediment show a positive correlation in terms of shape and plastic type,while exhibiting a negative correlation in terms of color.Overall,microplastics in sediments were smaller in size,and those in seawater and sediments had consistent size distribution characteristics in space.
基金The Marine Science and Technology Fund of Shandong Province for Laoshan Laboratory under contract No.LSKJ202203600-2the China Ocean Mineral Resources Research and Development Association(COMRA)project under contract No.DY135-N2-1-04.
文摘Polymetallic nodules,hereinafter referred to as PN,enriched with Co,Ni,Mn,and Cu,are likely to be commercially mined in the near future.These metals in PN are potential strategic alternatives for the world’s energy transition.Therefore,intensive studies are necessary on the spatial distribution patterns of PN in the deep sea.In this study,the distribution probabilities of PN in the Pacific,Indian and Atlantic oceans were estimated based on binary logistic regression of PN occurrence with ore-controlling factors including water depth(WD),marine sediment thickness(SedTh),Calcium carbonate(CaCO_(3))concentrations in surface sediments,primary productivity(PP),near bottom current velocities(BC).Furthermore,the distribution probability of PN was constrained by seafloor ages and PN sites,and subsequently,the prospects for nodules in the Pacific,Indian and Atlantic oceans were obtained.The results indicate that the low-latitude Pacific region(30°N-30°S),particularly the Clarion-Clipperton Zone and the Penrhyn Basin,is the most promising area for PN exploration.
基金Supported by the Project of Investigation on the Background and Quality of Representative Intertidal Sediments in China and Compilation of Atlas,Ministry of Science and Technology of the People’s Republic of China(No.2014FY210600)the National Natural Science Foundation of China(No.41807247)。
文摘The intertidal zone of mangroves has a significant impact on the ecological environment by serving as a crucial habitat for a wide range of organisms.When assessing heavy metal contamination in sediments within this zone,it is essential to establish a regional geochemical baseline that accounts for natural variations.In this study,regional geochemical baselines of heavy metals were established based on core sediment samples collected from Dongzhai Harbor in November 2015.Linear regression analysis was employed to examine the correlations between heavy metals and potential normalized elements.Subsequently,the sediment quality and intensity of pollutant input in the sediments of a mangrove intertidal zone were evaluated with enrichment factor(EF)and excessive influx of heavy metals.The EF values for Cr,Cd,Pb,Zn,and Ni in the study area were all below 1.5,indicating minimal levels of contamination;however,minor Cu contamination was observed in the high tidal flat area due to potential terrestrial inputs.These findings suggest that the overall environmental quality about heavy metals was good within the intertidal zone of mangroves.Moreover,as for the excess fluxes of heavy metals in intertidal sediments,there was consistency between influence and intervention of human activities on sedimentary environment during the selected period when examining variation trends.
基金The National Natural Science Foundation of China under contract No. 42274159the Project supported by Key Laboratory of Space Ocean Remote Sensing and Application,MNR under contract No.2023CFO016。
文摘The research on ocean dynamics information plays a crucial role in understanding ocean phenomena, assessing marine environmental impacts, and guiding engineering designs. The Doppler information observed by radars reflects sea surface dynamics, to which ocean waves make important contributions. Low-incidence-angle real aperture radar(RAR)demonstrates great potential for independently observing vectorial Doppler information on the ocean surface. To systematically characterize and accurately estimate the wave-induced Doppler frequency shift(WVF) from lowincidence-angle RAR, this study conducts comprehensive influencing factor analysis and establishes sea-stateparameterized WVF models. First, a simulated WVF dataset is generated under a rotating low-incidence-angle RAR.The feature parameters of WVF are then determined by analysing contributing factors including wind waves, swells,and sea state parameters. Furthermore, two WVF models(WVF_Ku P9 with 9 inputs and WVF_Ku P4 with 4 inputs) are constructed by the Transformer encoder for different application scenarios. Both models achieve high accuracy for WVF estimation with root mean square errors(RMSE) of 1.874 Hz and 2.716 Hz, respectively. The reliability and superiority of the proposed models are validated through comparisons with the Ka DOP, which is a typical geophysical model function(GMF). The findings in this paper advance the understanding of WVF characteristics and generation mechanisms. The proposed estimation models can provide reliable estimates, offering critical references for lowincidence-angle RAR applications such as ocean surface current retrieval.
基金supported by the National Natural Science Foundation of China(Nos.42107284 and 22078177)the Postdoctoral Fellowship Program of CPSF(No.GZB20240410)。
文摘Decabromodiphenyl ethane(DBDPE)is widely used as an additive flame retardant and has led to global pollution.Its has a large molecular mass and is prone to debromination and degradation under photothermal conditions,resulting in smaller homologous compounds.Due to the lack of standard substances for debromination products,the in-depth study of DBDPE environmental geochemical behavior through debromination conversion has been hindered.Therefore,based on DBDPE photodegradation experiment,this study first analyzed and identified the brominated products of DBDPE using high-performance liquid chromatography-atmospheric pressure photoionization-time of flight mass spectrometry(HPLC-APPI-TOF/MS).Four debromination products-nonabromodiphenyl ethane(nonaBDPE),octabromodiphenyl ethane(octa-BDPE),heptabromodiphenyl ethane(hepta-BDPE)and hexabromodiphenyl ethane(hexa-BDPE)are identified based on the characteristic ion peak of[M-Br+O]^(-) in negative ion mode.Subsequently,using methanol as the mobile phase,four debromination products of DBDPE were separated and purified with a semi-preparative high-performance liquid chromatography(SP-HPLC)system equipped with an Agilent Zorbax Eclipse PAH column(4.6 mm×250 mm,5μm).The first-time acquisition of hexa-BDPE(60.00μg),octa-BDPE(19.40μg),hepta-BDPE(31.20μg)and octa-BDPE(isomer,45.20μg)with purity exceeding 90%has been achieved.Among them,the purity of one hepta-BDPE monomer is as high as 98.91%.This study indicates that based on photodegradation experiments,the combination of HPLC-APPI-TOF/MS and SP-HPLC techniques can rapidly identify and prepare DBDPE debrominated products.This approach meets the requirements for preliminary research on the pollution characteristics of DBDPE debrominated compounds and offers a feasible solution for the preparation of standard reference materials for emerging pollutants.
基金the National Natural Science Foundation of China(Nos.42206076,42476078)the National Program on Global Change and Air-Sea Interaction(No.GASI-02-SCSCJB01)the China-Malaysia Cooperation Project‘Effect on variability of seasonal monsoon on sedimentary process in Peninsular Malaysia waters’。
文摘The Malacca Strait(MS)is a vital conduit for the exchange of water and sediment between the Indian Ocean and the Pacific Ocean,serving as a critical‘gateway'for sediment transport.Here,we present the geochemical characteristics of surface sediments in the MS to elucidate the relationship between terrestrial material inputs and modern oceanic dynamic transport processes in the strait.The results reveal that the MS can be divided into three distinct geochemical provinces.ProvinceⅠ,located in the central region of the strait,is characterized by residual deposits.The preservation of these residual deposits can be attributed to the restricted sediment supply and the relatively weaker modern sedimentary hydrodynamic conditions.ProvinceⅡ,situated to the north of ProvinceⅠ,exhibits provenance differences between its southern and northern regions.The northern region is primarily supplied by sediments originating from the eastern shelf of the Andaman Sea,whereas sediments derived from Sumatra and the Sunda Shelf are predominantly deposited in the southern part of ProvinceⅡ.ProvinceⅢextends along the western coast of the Malaysian Peninsula,with sediments primarily sourced from the Malaysian Peninsula and the Sunda Shelf,while contributions from Sumatra and the eastern shelf of the Andaman Sea are negligible.River sediments from the Malaysian Peninsula and Sumatra are transported northwestward along their respective coasts by prevailing currents,which also facilitate the transportation of Sunda Shelf sediments within the strait,while sediments from the eastern shelf of the Andaman Sea are delivered to the MS via southward coastal currents during the southwest monsoon period.The southward currents and well-developed eddies potentially impede the northward transport of sediments from the Sunda Shelf and restrict the distribution of Andaman Sea sediments within the strait.This study substantially enhances the understanding of source-to-sink processes in the Indo-Pacific region.
