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Enhancing Corrosion Resistance and Antibacterial Properties of ZK60 Magnesium Alloy Using Micro-Arc Oxidation Coating Containing Nano-Zinc Oxide 被引量:3
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作者 Jin-Xiu Li Jun-Xiu Chen +6 位作者 M.A.Siddiqui S.K.Kolawole Yang Yang Ying Shen Jian-Ping Yang Jian-Hua Wang Xu-Ping Su 《Acta Metallurgica Sinica(English Letters)》 2025年第1期45-58,共14页
Nano-zinc oxides(ZnO)demonstrate remarkable antibacterial properties.To further enhance the corrosion resistance and antibacterial efficiency of magnesium alloy micro-arc oxidation(MAO)coatings,this study investigates... Nano-zinc oxides(ZnO)demonstrate remarkable antibacterial properties.To further enhance the corrosion resistance and antibacterial efficiency of magnesium alloy micro-arc oxidation(MAO)coatings,this study investigates the preparation of ZnO-containing micro-arc oxidation coatings with dual functionality by incorporating nano-ZnO into MAO electrolyte.The influence of varying ZnO concentrations on the microstructure,corrosion resistance,and antibacterial properties of the coating was examined through microstructure analysis,immersion tests,electrochemical experiments,and antibacterial assays.The findings revealed that the addition of nano-ZnO significantly enhanced the corrosion resistance of the MAO-coated alloy.Specifically,when the ZnO concentration in the electrolyte was 5 g/L,the corrosion rate was more than ten times lower compared to the MAO coatings without ZnO.Moreover,the antibacterial efficacy of ZnO+MAO coating,prepared with a ZnO concentration of 5 g/L,surpassed 95%after 24 h of co-culturing with Staphylococcus aureus(S.aureus).The nano-ZnO+MAO-coated alloy exhibited exceptional degradation resistance,corrosion resistance,and antibacterial effectiveness. 展开更多
关键词 NANO-ZNO Micro-arc oxidation(MAO)coating ZK60 alloy Corrosion behavior Antibacterial characteristics
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Microstructure and electrochemical behavior of Al-8Si-3Fe-xIn coating alloy in a low chlorine environment
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作者 SHEN Ying ZHANG Jing +4 位作者 KOLAWOLE Sharafadeen Kunle LIU Ya ZHU Xiang-ying CHEN Jun-xiu SU Xu-ping 《Journal of Central South University》 2025年第4期1252-1271,共20页
In the process of protecting ferrous materials,aluminum coating usually forms a dense oxide film on the surface of the iron-based alloy.However,the capacity of the sacrificial anode is rather insufficient.In order to ... In the process of protecting ferrous materials,aluminum coating usually forms a dense oxide film on the surface of the iron-based alloy.However,the capacity of the sacrificial anode is rather insufficient.In order to solve this problem,the microstructure and electrochemical corrosion properties of Al-8Si-3Fe-xIn alloy under low chlorine conditions were studied.The results show that indium(In)dissolves to form In^(3+)and In^(+)reverse plating on the surface of the bare substrate to form a passivation film defect.When the In content is high,the segregated In forms an activation point in the form of a cathode phase.In activatesτ_(6)phase to form a micro-couple,which improves the non-uniform corrosion.The In-containing corrosion products at the phase boundary hinder the diffusion of Cl−.With an increase of In content,the self-corrosion potential(Ecorr)of the alloy shifts negatively,and the self-corrosion current density(Jcorr)decreases from 6.477μA/cm^(2)to 1.352μA/cm^(2),and then increases gradually.However,when the In content is 0.1%,the Ecorr of the alloy changes from−0.824 V to−0.932 V,and the Jcorr decreases from 6.477μA/cm^(2)to 4.699μA/cm^(2),suggesting that the use of sacrificial anode will give the best effect. 展开更多
关键词 aluminum coating MICROSTRUCTURE electrochemical corrosion properties sacrificial anode hot-dip galvanizing
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The role of psychological meaningfulness in the relationship between job complexity and work-family conflict among secondary school teachers in Nigeria
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作者 Gabriel C.Kanu Noah Adeji +3 位作者 Tobias C.Obi Elom S.Omena Raphael U.Anike Alexander U.Amaechi 《Journal of Psychology in Africa》 2025年第1期1-5,共5页
This study examined how psychological meaningfulness moderates job complexity and work-family conflict in Nigerian secondary school teachers.This study included 1694 teachers from 17 Nigerian secondary schools(female=6... This study examined how psychological meaningfulness moderates job complexity and work-family conflict in Nigerian secondary school teachers.This study included 1694 teachers from 17 Nigerian secondary schools(female=69.54%,mean age=33.19,SD=6.44 years).The participants completed the Work-family Conflict Scale,Job Complexity Scale,and Psychological Meaningfulness Scale.Study design was cross-sectional.Hayes PROCESS macro analysis results indicate a higher work-family conflict with job complexity among the secondary school teachers.While psychological meaningfulness was not associated with work-family conflict,it moderated the link between job complexity and work-family conflict in secondary school teachers such that a meaningful work endorsement is associated with lower employee’s work-life conflict.Thesefindings point to the importance of job functions to quality of family life.The studyfindings also suggest a need for supporting psychological meaningfulness for healthy work related quality of family life based on balancing work and family role demands. 展开更多
关键词 psychological meaningfulness job complexity work-family conflict secondary school TEACHERS
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Effects of rare-earth Pr^(3+)-Dy^(3+)doping on structural,magnetic,optical and dielectric properties of Zn_(2)Y hexaferrite
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作者 Ibrahim Mohammed Mohamed E.El Sayed +5 位作者 Ali Shawabkeh Mohammad N.Murshed Ibtehaj F.Alshdoukhi Zeinhom M.El-Bahy J.Mohammed A.K.Srivastava 《Journal of Rare Earths》 2025年第2期329-336,I0004,共9页
This study was conducted to investigate the properties of Pr^(3+)-Dy^(3+)doped Zn_(2)Y-type hexaferrite for potential technological applications.X-ray diffraction(XRD),Fourier transform infrared spectroscopy(FTIR)and ... This study was conducted to investigate the properties of Pr^(3+)-Dy^(3+)doped Zn_(2)Y-type hexaferrite for potential technological applications.X-ray diffraction(XRD),Fourier transform infrared spectroscopy(FTIR)and field-emission scanning electron microscopy(FESEM)were used to analyze structural properties.The crystallite size in the synthesized samples varies between 57.54 and 68.57 nm.The vibrational bands at 400 and 600 cm^(-1),common to all hexaferrites,were confirmed through FTIR.The FESEM analysis reveals an agglomeration of magnetic grains and a decrease in the average grain size from 1.24 to1.06μm.The M-H loops show that,with x values of 0.0,0.1,and 0.2,the saturation magnetization is determined to be 34.76,34.23,and 32.52 emu/g,respectively.The corresponding coercivity values are21.24,30.39,and 33.99 Oe.UV-visible spectroscopy using Tauc theory reveals an increase in the optical band gap from 2.32 to 2.50 eV,indicating a tunable energy band structure by incorporating Pr^(3+)-Dy^(3+)ions.The dielectric constant increases,whereas AC conductivity decreases with increased Pr^(3+)-Dy^(3+)concentration.The obtained results suggest the potential suitability of these materials for various technological applications. 展开更多
关键词 Zn_(2)Y-type hexaferrite Pr^(3+)-Dy^(3+) Magnetic hysteresis Optical band gap Dielectric constant Rare earths
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Preliminary study of microstructure, mechanical properties and corrosion resistance of antibacterial Ti-15Zr-xCu alloy for dental application 被引量:5
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作者 Sharafadeen Kunle Kolawole Wang Hai +6 位作者 Shuyuan Zhang Ziqing Sun Muhammad Ali Siddiqui Ihsan Ullah Wei Song Frank Witte Ke Yang 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2020年第15期31-43,共13页
Ti-15 Zr-xCu(3≤x≤7,wt.%) novel antibacterial and antibiofilm alloys with competitive mechanical properties,biological responses and corrosion resistance were designed and fabricated.Annealing heat treatment on Ti-15... Ti-15 Zr-xCu(3≤x≤7,wt.%) novel antibacterial and antibiofilm alloys with competitive mechanical properties,biological responses and corrosion resistance were designed and fabricated.Annealing heat treatment on Ti-15 Zr-7 Cu(TZC-7 A),after holding for 2 h at slightly above their beta transus temperature(BTT) ensured their tensile strength(UTS),yield strength(YS) and hardness(HRV) were improved by31.2%,20% and 12.3% respectively compared to the control without Cu,Ti-15 Zr(T-15 ZA).Although the3 wt.% Cu alloy displayed the highest elongation(26%),the TZC-7 A alloy also possessed a good ductility.Presence of evenly dispersed Ti2 Cu and Zr2 Cu Cu-rich intermetallic phases formed as interwoven and alternating lamellae within the α+β matrix as a result of Cu addition,as revealed by X-ray diffraction(XRD),scanning electron microscopy(SEM) and transmission electron microscopy(TEM).These greatly contributed to their strengthening and bactericidal properties.Over 98% antibacterial effect against E.coli and S.aureus have been imparted,coupled with excellent biofilm inhibition.Potentiodynamic polarization curves showed that the TZC-7 A alloy possessed higher corrosion resistance than commercially pure titanium,cp-Ti;contact angle test revealed enhanced hydrophilicity;while confocal laser scanning microscopy(CLSM) and cell counting kit(CCK-8) assays also displayed drastically lowered bacterial adhesion rate with comparatively no cytotoxicity.Cell attachment on all alloys was similar but the best spread was obtained on TZC-7 A after 24 h.The developed alloy has good potential as an antibacterial implant material with combination of optimized properties. 展开更多
关键词 Ti-Zr alloy Cu addition ANTIBACTERIAL Mechanical properties Intermetallic phases
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On the volatility of daily stock returns of Total Nigeria Plc: evidence from GARCH models, value-at-risk and backtesting 被引量:3
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作者 Ngozi G.Emenogu Monday Osagie Adenomon Nwaze Obini Nweze 《Financial Innovation》 2020年第1期347-371,共25页
This study investigates the volatility in daily stock returns for Total Nigeria Plc using nine variants of GARCH models:sGARCH,girGARCH,eGARCH,iGARCH,aGARCH,TGARCH,NGARCH,NAGARCH,and AVGARCH along with value at risk e... This study investigates the volatility in daily stock returns for Total Nigeria Plc using nine variants of GARCH models:sGARCH,girGARCH,eGARCH,iGARCH,aGARCH,TGARCH,NGARCH,NAGARCH,and AVGARCH along with value at risk estimation and backtesting.We use daily data for Total Nigeria Plc returns for the period January 2,2001 to May 8,2017,and conclude that eGARCH and sGARCH perform better for normal innovations while NGARCH performs better for student t innovations.This investigation of the volatility,VaR,and backtesting of the daily stock price of Total Nigeria Plc is important as most previous studies covering the Nigerian stock market have not paid much attention to the application of backtesting as a primary approach.We found from the results of the estimations that the persistence of the GARCH models are stable except for few cases for which iGARCH and eGARCH were unstable.Additionally,for student t innovation,the sGARCH and girGARCH models failed to converge;the mean reverting number of days for returns differed from model to model.From the analysis of VaR and its backtesting,this study recommends shareholders and investors continue their business with Total Nigeria Plc because possible losses may be overcome in the future by improvements in stock prices.Furthermore,risk was reflected by significant up and down movement in the stock price at a 99%confidence level,suggesting that high risk brings a high return. 展开更多
关键词 VOLATILITY Returns Stocks Total petroleum Akaike information criterion(AIC) GARCH Value-at-risk(VaR) BACKTESTING
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Antibacterial Activities of <i>Psidium guajava</i>(Guava) and <i>Velvet tamarin</i>(Icheku) Local Chewing Sticks on <i>Streptococcus mutans</i>Isolated from Human Mouth 被引量:7
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作者 I. A. Ojiuko C. O. Anyamene +2 位作者 C. U. Ezebialu A. P. Unamadu C. S. Alisigwe 《Open Journal of Medical Microbiology》 2021年第2期80-90,共11页
<span style="font-family:Verdana;">Globally dental diseases are mainly caused by</span><i><span style="font-family:Verdana;"> Streptococcus mutans</span></i><... <span style="font-family:Verdana;">Globally dental diseases are mainly caused by</span><i><span style="font-family:Verdana;"> Streptococcus mutans</span></i><span style="font-family:""><span style="font-family:Verdana;">, it is one of the leading causative agents of dental caries worldwide, because of its resistance to </span><span><span style="font-family:Verdana;">conventional antibacterial agents, alternative therapies are used to control resistance of oral pathogens. This research was done to determine the antibacterial activities of </span><i><span style="font-family:Verdana;">Psidium guajava</span></i><span style="font-family:Verdana;"> (guava) and </span><i><span style="font-family:Verdana;">Velvet tamarin</span></i><span style="font-family:Verdana;"> (Icheku) chewing sticks on </span><i><span style="font-family:Verdana;">Streptococcus mutans</span></i><span style="font-family:Verdana;"> isolated from the oral cavity. The study was conducted in Owerri Imo State Nigeria during November-December</span></span><span style="font-family:Verdana;"> period. Phytochemical analysis of the plant extracts was done using appropriate techniques. The procedure used for antimicrobial susceptibility test was disk diffusion method. Serial dilutions of</span><i><span style="font-family:Verdana;"> Psidium guajava</span></i><span style="font-family:Verdana;"> (guava) and </span><i><span style="font-family:Verdana;">Velvet tamarind</span></i><span style="font-family:Verdana;"> (Icheku) extracts were prepared, Muller-Hinton media was used to put together the extract of serial dilutions of </span><i><span style="font-family:Verdana;">Psidium guajava</span></i><span style="font-family:Verdana;"> (guava) and </span><i><span style="font-family:Verdana;">Velvet tamarin</span></i><span style="font-family:Verdana;"> (Icheku) and </span></span><span style="font-family:Verdana;">a </span><span style="font-family:Verdana;">microbiological procedure w</span><span style="font-family:Verdana;">ere</span><span style="font-family:Verdana;"> used for visually determining the minimum inhibitory concentration as well as minimum bactericidal concentration. Phytochemical evaluation of the plants</span><span style="font-family:Verdana;">’</span><span style="font-family:""><span style="font-family:Verdana;"> extracts revealed that it contains saponins, tannins, alkaloid, steriods, glycosides and phenol. The results obtained from the antibacterial susceptibility testing of the extracts against </span><i><span style="font-family:Verdana;">Streptococcus mutans</span></i><span style="font-family:Verdana;"> showed that the zones of inhibition recorded ranged from 18</span></span><span style="font-family:""> </span><span style="font-family:Verdana;">mm to 27</span><span style="font-family:""> </span><span style="font-family:""><span style="font-family:Verdana;">mm. Ethanol (Soxhlet) extract of I</span><span style="font-family:Verdana;">cheku twig showed no zone of inhibition on the isolated organism. The</span><span style="font-family:Verdana;"> ethanol (soxhlet) extract of the individual </span><i><span style="font-family:Verdana;">Psidium guajava</span></i><span style="font-family:Verdana;"> (guava) and </span><i><span style="font-family:Verdana;">Velvet tamarin</span></i><span style="font-family:Verdana;"> (Icheku) has a better antibacterial effect when compared to their aqueous extracts and combined forms. </span><i><span style="font-family:Verdana;">Psidium guajava</span></i><span style="font-family:Verdana;"> (Guava) and </span><i><span style="font-family:Verdana;">Velvet tamarin</span></i><span style="font-family:Verdana;"> (Icheku) twigs are made up of composite that </span></span><span style="font-family:Verdana;">is</span><span style="font-family:""><span style="font-family:Verdana;"> active against </span><i><span style="font-family:Verdana;">S. mutans</span></i><span style="font-family:Verdana;"> and can be used in oral hygiene. There is </span></span><span style="font-family:Verdana;">a </span><span style="font-family:Verdana;">need for further investigation on the plant extracts as the rural poor make use of it because it is cheap, readily available and the rich also use it once they are in the village mostly in Eastern Nigeria. Similarly chewing sticks has been reported to be practiced by 90 of rural population in Nigeria</span><span style="font-family:Verdana;">. 展开更多
关键词 Antibacterial Activity Chewing Sticks Psidium guajava (Guava) Velvet tamarin (Icheku) Streptococcus mutans
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Review of GTAW Welding Parameters 被引量:3
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作者 Bolarinwa Johnson Kutelu Saliu Ojo Seidu +1 位作者 Godwin Idenala Eghabor Ayotunde Idris Ibitoye 《Journal of Minerals and Materials Characterization and Engineering》 2018年第5期541-554,共14页
Welding as a fabrication process is one of the vital production routes for most manufacturing industries. Several factors are involved in the choice of welding process for specific applications;notable among these are... Welding as a fabrication process is one of the vital production routes for most manufacturing industries. Several factors are involved in the choice of welding process for specific applications;notable among these are compositional range of the material to be welded, the thickness of the base materials and type of current. Most metals oxidize rapidly in their molten state, and therefore, the weld area needs to be protected from atmospheric contamination;this is achieved in gas tungsten arc welding GTAW by a shielding gas (argon, helium, nitrogen). GTAW technique is one of the major processes for joining austenitic stainless steels (ASS) and ferritic stainless steel (FSS) fabrication. However, the microstructural change that occurs during welding and at weld joint is still a major challenge today as it affects both the corrosion resistance and the mechanical properties. Therefore, this present paper reviews past research findings on GTA welding of ASS and FSS. Results of the findings have confirmed that, depending on the amount of heat input, which can be controlled by welding parameters (welding speed, voltage and current), welded joints particularly, heat affected zones (HAZs) of both grades of steels can undergo mechanical failure and can be susceptible to corrosion attack if the joints are produced with a less ideal combination of welding parameters. 展开更多
关键词 AUSTENITIC Stainless Steel (ASS) GTA WELDING HEAT Affected Zone (HAZ) WELDING Speed Voltage Current HEAT Input Shielding Gas Filler Metal
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Magnetohydrodynamic approach of non-Newtonian blood flow with magnetic particles in stenosed artery 被引量:1
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作者 I. A. MIRZAt M. ABDULHAMEED S. SHAFIE 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2017年第3期379-392,共14页
The non-Newtonian blood flow, together with magnetic particles in a stenosed artery, is studied using a magneto-hydrodynamic approach. The wall slip condition is also considered. Approximate solutions are obtained in ... The non-Newtonian blood flow, together with magnetic particles in a stenosed artery, is studied using a magneto-hydrodynamic approach. The wall slip condition is also considered. Approximate solutions are obtained in series forms under the assumption that the Womersley frequency parameter has small values. Using an integral transform method, analytical solutions for any values of the Womersley parameter are obtained.Numerical simulations are performed using MATHCAD to study the influence of stenosis and magnetic field on the flow parameters. When entering the stenosed area, blood velocity increases slightly, but increases considerably and reaches its maximum value in the stenosis throat. It is concluded that the magnitude of axial velocity varies considerably when the applied magnetic field is strong. The magnitude of maximum fluid velocity is high in the case of weak magnetic fields. This is due to the Lorentz's force that opposes motion of an electrically conducting fluid. The effect of externally transverse magnetic field is to decelerate the flow of blood. The shear stress consistently decreases in the presence of a magnetic field with increasing intensity. 展开更多
关键词 BINGHAM plastic fluid magnetic particle blood flow magnetohydrodynam-ics ARTERY STENOSIS
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Gold grade variation and stream sediment geochemistry of the Vaimba-Lidi drainage system, northern Cameroon (West Africa) 被引量:3
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作者 Victor F. Embui Benjamin O. Omang +2 位作者 Vivian B. Che Melvin T. Nforba Emmanuel C. Suh 《Natural Science》 2013年第2期282-290,共9页
Stream sediment geochemistry remains a versatile tool in exploration especially in regions where knowledge of the primary mineralization is lacking and the exploration activities are still at reconnaissance stage. In ... Stream sediment geochemistry remains a versatile tool in exploration especially in regions where knowledge of the primary mineralization is lacking and the exploration activities are still at reconnaissance stage. In this study, we investigate the concentrations of gold and associated elements in stream sediment samples from the Vaimba-Lidi drainage system in northern Cameroon;a relatively remote area where alluvial gold is worked locally, and exploration activities are at early stage. The main river and its principal first and second order tributaries were sampled, panned for gold grain recovery and the 100 μm size fraction analyzed for Au by fire assay with Ni finish. A suite of other elements were analyzed for by inductively coupled plasma mass spectrometry (ICP-MS). Gold grades estimated by the panning and weighing technique rarely exceed1 g/t while the Au concentrations from chemical analysis range from 3.0 to 354.0 ppm. The spatial distribution of gold and all the other elements are presented as point symbol maps and the data analyzed using multivariate statistics. From the principal component analysis (PCA), the As-Mo-W-Ag as well as the Au-Zn factors point to the presence of primary hydrothermal gold-sulphide mineralization in the area and this can be further investigated. These results highlight the importance of multielement analysis and multivariate statistical interpretation of sediment geochemical data in inferring the nature of the underlying primary mineralization in any region. 展开更多
关键词 Gold Grade Principal Component Analysis (PCA) GEOCHEMISTRY STREAM SEDIMENTS Cameroon
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Optimized Mechanical Properties,Corrosion Resistance and Bactericidal Ability of Ti-15Zr-xCu Biomedical Alloys During Aging Treatment 被引量:1
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作者 Sharafadeen Kunle Kolawole Ling Ren +5 位作者 Muhammad Ali Siddiqui Ihsan Ullah Hai Wang Shuyuan Zhang Ji Zhang Ke Yang 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2022年第2期304-316,共13页
The effects of different aging conditions on the microstructure,strength,corrosion resistance,cytotoxicity and antibacterial ability of Ti-15Zr-xCu(3≤x≤7,wt%)(TZC)alloys were systematically investigated.Microstructu... The effects of different aging conditions on the microstructure,strength,corrosion resistance,cytotoxicity and antibacterial ability of Ti-15Zr-xCu(3≤x≤7,wt%)(TZC)alloys were systematically investigated.Microstructural evolution and behavior were analyzed by X-ray diffraction(XRD)patterns and scanning electron microscopy with energy-dispersive spectroscopy(SEM-EDS),while potentiodynamic polarization technique was employed to characterize the corrosion response of the alloys after solution-treatment and aging(STA).High-temperature aging at 660℃ for 4 h(660-4)gave the best combination of properties by enabling significant precipitation of the Cu-rich Ti_(2)Cu and Zr_(2)Cu compounds,and mild formation of the Zr_(7)Cu_(10) secondary phase.The high kinetics at this condition was beneficial to the complete precipitation and more homogeneous distribution of the intermetallic particles.These led to the inhibition of dislocation movements and allowed for significantly improved mechanical strengths with added ductility,availability of more Cu ions for the desired oligodynamic activity without evoking cytotoxicity,better corrosion resistance and very high antibacterial ability(over 99.5%),thus improving the overall properties of the TZC alloys for biomedical applications. 展开更多
关键词 Ti-15Zr-xCu alloys Solution treatment and aging Cu-rich precipitates Improved strength Corrosion resistance Antibacterial ability
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Heat and Mass Transfer in MHD Micropolar Fluid Flow over a Stretching Sheet with Velocity and Thermal Slip Conditions 被引量:2
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作者 E. O. Fatunmbi A. Adeniyan 《Open Journal of Fluid Dynamics》 2018年第2期195-215,共21页
This study presents the problem of a steady, two-dimensional, heat and mass transfer of an incompressible, electrically conducting micropolar fluid flow past a stretching surface with velocity and thermal slip conditi... This study presents the problem of a steady, two-dimensional, heat and mass transfer of an incompressible, electrically conducting micropolar fluid flow past a stretching surface with velocity and thermal slip conditions. Also, the influences of temperature dependent viscosity, thermal radiation and non-uniform heat generation/absorption and chemical reaction of a general order are examined on the fluid flow. The governing system of partial differential equations of the fluid flow are transformed into non-linear ordinary differential equations by an appropriate similarity variables and the resulting equations are solved by shooting method coupled with fourth order Runge-Kutta integration scheme. The effects of the controlling parameters on the velocity, temperature, microrotation and concentration profiles as well as on the skin friction, Nusselt number, Sherwood and wall couple stress are investigated through tables and graphs. Comparison of the present results with the existing results in the literature in some limiting cases shows an excellent agreement. 展开更多
关键词 MICROPOLAR Fluid MAGNETOHYDRODYNAMICS SLIP Conditions STRETCHING Sheet
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球形表面富锰Mn_(x)Co_(3-x)O_(4-η)尖晶石型催化剂选择性催化还原NO_(x)研究 被引量:1
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作者 高凤雨 刘恒恒 +7 位作者 姚小龙 Zaharaddeen Sani 唐晓龙 罗宁 易红宏 赵顺征 于庆君 周远松 《物理化学学报》 SCIE CAS CSCD 北大核心 2023年第9期136-148,共13页
采用共沉淀法制备了高比表面积的Mn_(x)Co_(3-x)O_(4)球形催化剂,研究了NH3选择性催化还原NOx性能。Mn-Co金属氧化物具有尖晶石结构,随着Co含量的增加,晶体结构由四方相转变为立方相。高浓度的表面活性氧物种和变价元素的强有效电子转移... 采用共沉淀法制备了高比表面积的Mn_(x)Co_(3-x)O_(4)球形催化剂,研究了NH3选择性催化还原NOx性能。Mn-Co金属氧化物具有尖晶石结构,随着Co含量的增加,晶体结构由四方相转变为立方相。高浓度的表面活性氧物种和变价元素的强有效电子转移(Co^(3+)+Mn^(3+)↔Co^(2+)+Mn^(4+))有利于提高Mn_(x)Co_(3-x)O_(4)(x=1.0、1.5、2.0)尖晶型石催化剂的氧化还原能力,催化剂表面的Mn富集作用形成了氧缺陷结构和丰富的表面活性位点,进一步促进SCR脱硝反应,呈现出优异的催化性能。COtet(CoMn)octO_(4)晶体结构中,Mn离子(Mn^(3+)和Mn^(4+),以三价锰为主)和部分Co离子被配置到八面体中心,这些物种作为活性位点存在着较强的电子转移交互作用,该构型对促进低温脱硝活性和保护活性位点耐受SO_(2)毒害具有重要的意义。Mn-Co尖晶石表面的NH_(3)-SCR脱硝反应过程主要遵循Eley-Rideal反应机理,即吸附态NH_(3)与气态NO(或NO_(2))的反应路径。随着反应温度的增加,反应生成的NH_(4)NO_(3)中间体很可能转化为NH_(4)NO_(2)物种,进而分解为N_(2),提高了催化剂的氮气选择性。 展开更多
关键词 Mn-Co复合氧化物 尖晶石结构 富锰表面 选择性催化还原 协同作用 反应机理
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The Physico-Chemical Composition and Energy Recovery Potentials of Municipal Solid Waste Generated in Numan Town, North-Eastern Nigeria 被引量:1
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作者 Alkasim Abubakar Maigida H. Barnabas Baba M. Tanko 《Energy and Power Engineering》 2018年第11期475-485,共11页
Numan is an urban center in Adamawa State North-Eastern Nigeria. Its waste characteristics are similar to other places in sub-Saharan Africa. In this paper, the physico-chemical characterization of municipal solid was... Numan is an urban center in Adamawa State North-Eastern Nigeria. Its waste characteristics are similar to other places in sub-Saharan Africa. In this paper, the physico-chemical characterization of municipal solid waste generated in Numan Town was carried out to estimate the electrical power to be generated from it. The solid waste types were observed to comprise of polythene (27%), organic waste (24.1%), plastic (10.2%), textile (13.2%), paper (9.8%), glass (9.3%) and metals (6.4%). The moisture content as discarded and daily average solid waste generation rate are 16.49% and 0.583 kg/sec respectively. The chemical formula with and without water was determined as C923.28H1632.60O258.28N12.89S and C923.28H2099.70O494.16N12.89S respectively. The suitability of the municipal solid waste as a possible source of electrical power was also considered. The energy content of the solid waste on ash free dry-basis was determined as 20861.48 kJ/kg. The estimated power generation per day using incinerating plant at an assumed efficiency of 25% was 3031.5 kW. 展开更多
关键词 MUNICIPAL Solid Waste Moisture Content Energy Recovery Power Generation
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On the Time Series Forecasting of Road Traffic Accidents in Ondo State of Nigeria 被引量:1
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作者 B. A. Afere S. A. Oyewole I. Haruna 《Journal of Statistical Science and Application》 2015年第5期153-162,共10页
This paper focuses on time series forecasting of monthly occurrence of fatal road accidents in Ondo State of Nigeria. Its aim, however, is to use time series analysis to analyze the data obtained from Federal Road Saf... This paper focuses on time series forecasting of monthly occurrence of fatal road accidents in Ondo State of Nigeria. Its aim, however, is to use time series analysis to analyze the data obtained from Federal Road Safety Corps (FRSC), Ondo State Command; which was considered in two cases: the total cases reported (TCR) and the number of deaths resulted from accidents (NOD). Various smoothing models for time series were used to analyze the two cases. Based on the models, predictions were made and the results show a steady increase as a result of long-term effects on road accidents for the two cases. It was found also that simple exponential smoothing model is the appropriate model for both TCR and NOD. 展开更多
关键词 Forecasting Time Series Ondo State Road traffic accidents Exponential smoothing.
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Modelling the Effects of Vertical Transmission in Mosquito and the Use of Imperfect Vaccine on Chikungunya Virus Transmission Dynamics 被引量:1
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作者 Martins O. Onuorah Emmanuel I. Obi Bala G. Babangida 《Applied Mathematics》 2019年第4期245-267,共23页
In this paper, a deterministic mathematical model for Chikungunya virus (Chikv) transmission and control is developed and analyzed to underscore the effect of vaccinating a proportion of the susceptible human, and ver... In this paper, a deterministic mathematical model for Chikungunya virus (Chikv) transmission and control is developed and analyzed to underscore the effect of vaccinating a proportion of the susceptible human, and vertical transmission in mosquito population. The disease free, and endemic equilibrium states were obtained and the conditions for the local and global stability or otherwise were given. Sensitivity analysis of the effective reproductive number,?Rc?(the number of secondary infections resulting from the introduction of a single infected individual into a population where a proportion is fairly protected) shows that the recruitment rate of susceptible mosquito (ΛM) and the proportion of infectious new births from infected mosquito (β)?are the most sensitive parameters. Bifurcation analysis of the model using center manifold theory reveals that the model undergoes backward bifurcation (coexistence of disease free and endemic equilibrium when Rc?< 1 ). Numerical simulation of the model shows that vaccination of susceptible human population with imperfect vaccine will have a positive impact and that vertical transmission in mosquito population has a negligible effect. To the best of our knowledge, our model is the first to incorporate vaccinated human compartment and vertical transmission in (Chikv) model. 展开更多
关键词 CHIKUNGUNYA Virus Stability EQUILIBRIUM VACCINATION ENDEMIC
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The Prevalence of Parasitic Human Intestinal Helminthes and the Efficacy of Anthelmintic Drug in Children in Uzo-Uwani Local Government Area, Enugu State, Nigeria 被引量:1
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作者 Cletus Anes Ukwubile Otalu Otalu Jr. +1 位作者 Uduak Akpabio Matthew Onyema Agu 《Open Journal of Medical Microbiology》 2013年第4期213-218,共6页
Introduction: A study on the current status of parasitic intestinal helminthes and the efficacy of anthelmintic drug was carried out among primary school pupils at Community Primary School Ogurugu, Uzo-Uwani Local Gov... Introduction: A study on the current status of parasitic intestinal helminthes and the efficacy of anthelmintic drug was carried out among primary school pupils at Community Primary School Ogurugu, Uzo-Uwani Local Government Area, Enugu State. Objectives: The research was conducted in order to determine the prevalence of human intestinal helminthes among primary school pupils, and also to determine the prevalence in relation to age and sex, and to check the efficacy of anthelmintic drug (Levamisole) on the worms, in Ogurugu Uzo-Uwani Local Government Area, Enugu State, Nigeria. Methods: A total of 242 faecal samples were collected randomly from the school children and analyzed using standard parasitological procedures. Results: Data obtained showed an overall prevalence of 143 (59.1%) out of 242 samples and that the efficacy of anthelmintic drug Ergamisole? (Levamisole R12564;Unicure Pvt.ltd India) 50 mg in reducing the worm burden was 99 (82.5%) in 120 samples treated. Age related prevalence and efficacy of anthelmintic varied across the sample groups. There was no significant difference in sex related infections in the sample group (P > 0.5). The efficacy of the drug reduces with the increase in age. Also the efficacy of Levamisole drug in reducing the worm burden were hookworm 59 (89.5%), Ascaris 24 (85.7%), Trichuris 26 (78.6%) while Taenia and Strongyloides showed drug resistance. This indicates that a single dose of the medication is not enough for total elimination of these endo parasites. Conclusion: The study revealed that poor hygienic practices as well as unsanitary conditions were responsible for high prevalence recorded in the area, and advocated health education through primary health care and mass deworming of primary school children as control measures. 展开更多
关键词 PREVALENCE ANTHELMINTIC LEVAMISOLE CHILDREN ASCARIS lumbricoides TRICHURIS trichiura
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Seroprevalence, Type-Specific of Herpes Simplex Virus and Associated Risk Factors among Women of Child Bearing Age in Kogi State, Nigeria 被引量:2
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作者 Uteno Itanyi Drisu Francis Enifo Oronsaye +7 位作者 Babatunde Ishola Gabriel Adejumo Gregory Ashimedua Uchuno Alaba Michael Emmanuel Uchechukwu Dimkpa Kingsley Ifeanyichukwu Omosor Margaret Oyarazi Adebowale Oladimeji Nasiru Abdulrahman Esmond Nwanbunwanne Ukatu 《Health》 2018年第7期1006-1017,共12页
Background: Viruses of the Herpes viridae family infect 90% of the Earth’s population. Humans are the hosts of at least nine unique herpes viruses. Aim: This study is aimed at evaluating the seroprevalence of type sp... Background: Viruses of the Herpes viridae family infect 90% of the Earth’s population. Humans are the hosts of at least nine unique herpes viruses. Aim: This study is aimed at evaluating the seroprevalence of type specific herpes simplex virus infection and the associated risk factors in a cross-section of asymptomatic healthy women of childbearing age in Kogi state, Nigeria. Methodology: A total of 330 females of child bearing age (15 - 49 years) participated in this study. They were recruited from various local government areas of three Senatorial districts of Kogi state. Blood samples were collected from participants and analyzed for HSV-1 and HSV-2 antibodies (IgG) quantitatively with ELISA kit. Results: The overall prevalence of HSV was 76.7%. Data further show that majority (96.4%) of the population studied had HSV-1, while 77% had HSV-2 infections. Results also showed that the young adults indicated prevalence of 95.7% for HSV-1 and 74.7% for HSV-2, while in the middle aged, the prevalence were 98.6% for HSV-1, and 84.9% for HSV-2. 99.2% of the married women were positive for HSV-1, while 86.9% were positive for HSV-2. 94.5% of the unmarried women were positive for HSV-1, while 70.5% were positive for HSV-2. The risk of HVS-1 or VS-2 infections was not associated with age, age of first sexual exposure and number sex partners before marriage. Married women were at greater risk for HSV-1 (p = 0.03) and HSV-2 (p ≤ 0.001) infections compared to the unmarried women. Conclusion: The prevalence of the HSV-1 and HSV-2 infections was high among asymptomatic healthy women of childbearing age in Kogi state, Nigeria. Efforts should be made to increase the awareness of HSV infection among the child bearing populace. 展开更多
关键词 HSV-1/HSV-2 Antibody Infection WOMEN Kogi STATE NIGERIA
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Accessibility Analysis of Healthcare Delivery System within Enugu Urban Area Using Geographic Information System 被引量:1
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作者 Ifeanyi R. Ejiagha Johnbusco C. Ojiako Chijioke G. Eze 《Journal of Geographic Information System》 2012年第4期312-321,共10页
The problem of accessibility of health institution, with respect to the available facility to serve the entire population leaving in an area, can be solved using GIS. This paper presents an analysis on accessibility o... The problem of accessibility of health institution, with respect to the available facility to serve the entire population leaving in an area, can be solved using GIS. This paper presents an analysis on accessibility of healthcare facilities in Enugu urban area in a GIS environment. This was achieved through acquisition of a base map of Enugu State showing geographic extent of Enugu Urban, determining the geometric positions of health institutions in Enugu urban using handheld GPS, Creation of a spatial database of existing healthcare facilities and demonstrating through various analyses the potentials of GIS in measurement of accessibility to healthcare facilities in Enugu urban Area. The analysis includes network analysis, used to determine the closeness of a facility and shortest route to these healthcare facilities. ARCGIS 9.3 was the main software used. This was supported by Geocal for coordinate conversion and Microsoft office packages. The result of the study showed the spatial distribution of health institutions, closest facilities in case of emergency and route to those health institutions within Enugu urban Area. It was noticed that most of the healthcare facilities were located within Enugu North local government area (LGA). Other settlements and LGAs had fewer healthcare facilities. Areas deprived of healthcare facility were also identified. Routes and closest facilities to those deprived areas were identified in the settlements/area. The analysis showed the efficacy of GIS in determining accessibility of healthcare institutions in Enugu urban area. The study is thus, recommended as a spatial decision support system for decisions regarding spatial accessibility of healthcare facilities in an urban area. 展开更多
关键词 GIS ACCESSIBILITY DATABASE Healthcare Facilities DISTRICT HEALTH System
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Solution of Combined Heat and Power Economic Dispatch Problem Using Direct Optimization Algorithm 被引量:1
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作者 Dedacus N. Ohaegbuchi Olaniyi S. Maliki +1 位作者 Chinedu P. A. Okwaraoka Hillary Erondu Okwudiri 《Energy and Power Engineering》 CAS 2022年第12期737-746,共10页
This paper presents the solution to the combined heat and power economic dispatch problem using a direct solution algorithm for constrained optimization problems. With the potential of Combined Heat and Power (CHP) pr... This paper presents the solution to the combined heat and power economic dispatch problem using a direct solution algorithm for constrained optimization problems. With the potential of Combined Heat and Power (CHP) production to increase the efficiency of power and heat generation simultaneously having been researched and established, the increasing penetration of CHP systems, and determination of economic dispatch of power and heat assumes higher relevance. The Combined Heat and Power Economic Dispatch (CHPED) problem is a demanding optimization problem as both constraints and objective functions can be non-linear and non-convex. This paper presents an explicit formula developed for computing the system-wide incremental costs corresponding with optimal dispatch. The circumvention of the use of iterative search schemes for this crucial step is the innovation inherent in the proposed dispatch procedure. The feasible operating region of the CHP unit three is taken into account in the proposed CHPED problem model, whereas the optimal dispatch of power/heat outputs of CHP unit is determined using the direct Lagrange multiplier solution algorithm. The proposed algorithm is applied to a test system with four units and results are provided. 展开更多
关键词 Economic Dispatch Lagrange Multiplier Algorithm Combined Heat and Power Constraints and Objective Functions Optimal Dispatch
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