A liquid thermoelectric conversion device(LTE)converts environmental heat into electric power via the electrochemical Seebeck coefficientα.The maximum power(W_(max))is expressed as W_(max)=(α^(2)Δ^(T)/(4R′),where...A liquid thermoelectric conversion device(LTE)converts environmental heat into electric power via the electrochemical Seebeck coefficientα.The maximum power(W_(max))is expressed as W_(max)=(α^(2)Δ^(T)/(4R′),whereΔT and R′are the temperature difference between electrodes and device resistance in operation,respectively.Here,we systematically investigated the resistance components of LTEs composed of aqueous,methanol(MeOH)and acetone solutions containing 0.8 M Fe(ClO_(4))_(2)/Fe(ClO_(4))_(3).We found that the charge transfer resistance Rct of the MeOH LTE is the smallest among the three LTEs.We demonstrated that the W_(max)of the MeOH LTE is slightly larger than or comparable with that of the corresponding aqueous LTE.We further discussed the effects of the convection of an electrolyte on R′.展开更多
Tin-based perovskite solar cells(TPSCs)as the most promising candidate for lead-free PSCs have incurred extensive researches all over the world.However,the crystallization process of tin-based perovskite is too fast d...Tin-based perovskite solar cells(TPSCs)as the most promising candidate for lead-free PSCs have incurred extensive researches all over the world.However,the crystallization process of tin-based perovskite is too fast during the solution-deposited process,resulting in abundant pinholes and poor homogeneity that cause serious charge recombination in perovskite layer.Here,we employed theπ-conjugated Lewis base molecules with high electron density to systematically control the crystallization rate of FASnI3 perovskite by forming stable intermediate phase with the Sn-I frameworks,leading to a compact and uniform perovskite film with large increase in the carrier lifetime.Meanwhile,the introduction of theπ-conjugated systems also retards the permeation of moisture into perovskite crystal,which significantly suppresses the film degradation in air.These benefits contributed to a stabilizing power conversion efficiency(PCE)of 10.1%for the TPSCs and maintained over 90%of its initial PCE after 1000-h light soaking in air.Also,a steady-state efficiency of 9.2%was certified at the accredited test center.展开更多
Background Water availability is the key limiting factor for plant productivity in drylands covering ca.40%of Earth’s land surface.For such ecosystems to retain productivity and biodiversity under climatic change,it ...Background Water availability is the key limiting factor for plant productivity in drylands covering ca.40%of Earth’s land surface.For such ecosystems to retain productivity and biodiversity under climatic change,it would be valu-able to identify/promote keystone plant species that(i)have developed strategies to more efficiently utilize moisture resources not easily accessible and(ii)improve moisture conditions for neighboring plants.The very deep-rooted Ziziphus lotus,considered an ecosystem engineer,is one such example.However,it is not known which biotic traits:(a)canopy interception of moisture/rainfall,(b)hydraulic redistribution of deep ground moisture by roots,or non-biotic factors:(c)soil’s volume,and(d)organic matter content,Z.lotus activates/modulates to play such a role.We,thus,selected dryland ecosystems where the plant dominates and measured for potential effects on the less deep-rooted Thymbra capitata.For assessing impacts on ecosystem productivity,we measured the spatial aggregation of ca.3600 T.capitata plants.As a proxy for soil moisture availability and its spatial variability,we conducted a 7-year-long study using thymes’nighttime rehydration.Sampling extended up to 15 m away from Z.lotus.Results The density of T.capitata plants growing up to 5 m around Z.lotus vs.thymes growing 10-15 m away was found significantly increased(2.5-4.5 times),while their stem/leaf moisture was ca.10%higher at predawn compared to nightfall during the dry season.This suggests that ecosystem productivity is driven by a greater soil moisture avail-ability around Z.lotus permitting more thyme daytime transpiration,in contrast to thymes growing further away.The phenomenon appeared only under dry topsoil(during the dry season;becoming stronger during dry years).Morning dew/rainfall interception from the canopy or soil depth/organic matter did not show significant effects,leaving only the hydraulic lift properties of Z.lotus as the most likely driver for soil moisture availability.Conclusions The deep-rooting properties and hydraulic lift potential of Z.lotus may be the key in permitting it to boost ecosystem productivity.Such hydraulic plant traits require more attention as they may prove valuable in com-bating desertification and restoring ecosystems in arid/semiarid regions threatened by climate change.展开更多
基金supported by the Yazaki Memorial Foundation for Science and Technology,the Iwatani Naoji Foundation,and the joint research with Taisei Rotec Corporation.
文摘A liquid thermoelectric conversion device(LTE)converts environmental heat into electric power via the electrochemical Seebeck coefficientα.The maximum power(W_(max))is expressed as W_(max)=(α^(2)Δ^(T)/(4R′),whereΔT and R′are the temperature difference between electrodes and device resistance in operation,respectively.Here,we systematically investigated the resistance components of LTEs composed of aqueous,methanol(MeOH)and acetone solutions containing 0.8 M Fe(ClO_(4))_(2)/Fe(ClO_(4))_(3).We found that the charge transfer resistance Rct of the MeOH LTE is the smallest among the three LTEs.We demonstrated that the W_(max)of the MeOH LTE is slightly larger than or comparable with that of the corresponding aqueous LTE.We further discussed the effects of the convection of an electrolyte on R′.
基金supported by the National Natural Science Foundation of China(11574199,11674219,11834011)the Program for Professor of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning+1 种基金National Institute for Materials Science was supported by the New Energy and Industrial Technology Development Organization(NEDO,Japan)the KAKEHI Grant of Japan(18H02078)
文摘Tin-based perovskite solar cells(TPSCs)as the most promising candidate for lead-free PSCs have incurred extensive researches all over the world.However,the crystallization process of tin-based perovskite is too fast during the solution-deposited process,resulting in abundant pinholes and poor homogeneity that cause serious charge recombination in perovskite layer.Here,we employed theπ-conjugated Lewis base molecules with high electron density to systematically control the crystallization rate of FASnI3 perovskite by forming stable intermediate phase with the Sn-I frameworks,leading to a compact and uniform perovskite film with large increase in the carrier lifetime.Meanwhile,the introduction of theπ-conjugated systems also retards the permeation of moisture into perovskite crystal,which significantly suppresses the film degradation in air.These benefits contributed to a stabilizing power conversion efficiency(PCE)of 10.1%for the TPSCs and maintained over 90%of its initial PCE after 1000-h light soaking in air.Also,a steady-state efficiency of 9.2%was certified at the accredited test center.
文摘Background Water availability is the key limiting factor for plant productivity in drylands covering ca.40%of Earth’s land surface.For such ecosystems to retain productivity and biodiversity under climatic change,it would be valu-able to identify/promote keystone plant species that(i)have developed strategies to more efficiently utilize moisture resources not easily accessible and(ii)improve moisture conditions for neighboring plants.The very deep-rooted Ziziphus lotus,considered an ecosystem engineer,is one such example.However,it is not known which biotic traits:(a)canopy interception of moisture/rainfall,(b)hydraulic redistribution of deep ground moisture by roots,or non-biotic factors:(c)soil’s volume,and(d)organic matter content,Z.lotus activates/modulates to play such a role.We,thus,selected dryland ecosystems where the plant dominates and measured for potential effects on the less deep-rooted Thymbra capitata.For assessing impacts on ecosystem productivity,we measured the spatial aggregation of ca.3600 T.capitata plants.As a proxy for soil moisture availability and its spatial variability,we conducted a 7-year-long study using thymes’nighttime rehydration.Sampling extended up to 15 m away from Z.lotus.Results The density of T.capitata plants growing up to 5 m around Z.lotus vs.thymes growing 10-15 m away was found significantly increased(2.5-4.5 times),while their stem/leaf moisture was ca.10%higher at predawn compared to nightfall during the dry season.This suggests that ecosystem productivity is driven by a greater soil moisture avail-ability around Z.lotus permitting more thyme daytime transpiration,in contrast to thymes growing further away.The phenomenon appeared only under dry topsoil(during the dry season;becoming stronger during dry years).Morning dew/rainfall interception from the canopy or soil depth/organic matter did not show significant effects,leaving only the hydraulic lift properties of Z.lotus as the most likely driver for soil moisture availability.Conclusions The deep-rooting properties and hydraulic lift potential of Z.lotus may be the key in permitting it to boost ecosystem productivity.Such hydraulic plant traits require more attention as they may prove valuable in com-bating desertification and restoring ecosystems in arid/semiarid regions threatened by climate change.
