Current research primarily focuses on emerging organic pollutants,with limited attention to emerging inorganic pollutants (EIPs).However,due to advances in detection technology and the escalating environmental and hea...Current research primarily focuses on emerging organic pollutants,with limited attention to emerging inorganic pollutants (EIPs).However,due to advances in detection technology and the escalating environmental and health challenges posed by pollution,there is a growing interest in treating waters contaminated with EIPs.This paper explores biochar characteristics and modification methods,encompassing physical,chemical,and biological approaches for adsorbing EIPs.It offers a comprehensive review of research advancements in employing biochar for EIPs remediation in water,outlines the adsorption mechanisms of EIPs by biochar,and presents an environmental and economic analysis.It can be concluded that using biochar for the adsorption of EIPs in wastewater exhibits promising potential.Nonetheless,it is noteworthy that certain EIPs like Au(III),Rh(III),Ir(III),Ru(III),Os(III),Sc(III),and Y(III),have not been extensively investigated regarding their adsorption onto biochar.This comprehensive review will catalyze further inquiry into the biochar-based adsorption of EIPs,addressing current research deficiencies and advancing the practical implementation of biochar as a potent substrate for EIP removal from wastewater streams.展开更多
Tetracyclines (TCs) are the second most commonly used antibiotics worldwide, utilized in medical treatments and animal husbandry. Although effective against various infectious diseases, TC residues persist in the envi...Tetracyclines (TCs) are the second most commonly used antibiotics worldwide, utilized in medical treatments and animal husbandry. Although effective against various infectious diseases, TC residues persist in the environment and contribute to the emergence of antibiotic-resistant pathogens, posing significant risks to human health. This study employed the heterogeneous Fenton process to degrade TC using soybean residue-derived magnetic biochar (Fe-SoyB) as the catalyst. The Fe-SoyB sample was characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), and superconducting quantum interference device (SQUID) techniques. The effects of key parameters, including pH, H2O2 concentration, catalyst dosage, and initial TC concentration, on TC degradation were investigated. The results indicated that the TC removal efficiency decreased with increasing initial TC concentration, while it was improved with higher H2O2 concentrations and greater catalyst dosages. The optimal conditions for the Fenton-like process were determined: a pH of 3, a H2O2 concentration of 245 mmol/L, an initial TC concentration of 800 mg/L, and a catalyst dosage of 0.75 g/L, achieving a removal efficiency of 90.0% after 150 min. Additionally, the TC removal efficiency of the Fe-SoyB system varied significantly across different water matrices, with 87.1% for deionized water, 78.5% for tap water, and 72.5% for river water. The catalyst demonstrated notable stability, maintaining a TC removal efficiency of 79.7% after three cycles of use. Overall, Fe-SoyB shows promise as a cost-effective catalyst for the elimination of organic pollutants in aqueous solutions.展开更多
Urban sprawl is a critical challenge in the urban development trajectory of developing countries,necessitating precise measurement,trend projection,and strategic management to achieve sustainable urban growth.This stu...Urban sprawl is a critical challenge in the urban development trajectory of developing countries,necessitating precise measurement,trend projection,and strategic management to achieve sustainable urban growth.This study focuses on the Yangtze River Economic Belt(YREB)as a case region and introduces a comprehensive evaluation framework that incorporates multidimensional factors and addresses the scale effects of urban sprawl.We emphasize the value of a systematic geographical approach by quantifying urban sprawl through simulated scenarios and analyzing its driving factors.We constructed an innovative urban sprawl index(USI)to assess the degree of sprawl within the YREB.This assessment integrates two geographic models with an artificial neural network algorithm,enabling simulation of urban sprawl trends under two future scenarios for 2035.Additionally,two analytical methods were employed to identify the key driving mechanisms of urban sprawl in the region.Findings indicate a strong correlation between urban scale and the extent of urban sprawl:larger urban areas exhibit more pronounced sprawl,with agglomeration and morphological transformations identified as primary contributors to urban sprawl.The study further reveals an intricate association between urban sprawl and the compactness of urban internal structures.While both development scenarios offer distinct advantages,the Coordinated Development Scenario is projected to foster a more balanced urban expansion.The robustness of the evaluation framework was enhanced through simulation and an in-depth analysis of internal mechanisms,bolstering confidence in its applicability.We advocate for the adoption and continued refinement of this framework as a tool for promoting balanced urban growth.The strategic recommendations provided herein are vital for mitigating multi-scale urban sprawl,advancing economic development,and improving residents’quality of life across cities in the YREB.展开更多
In this study,a novel Pt-loaded Cu Pc/g-C_(3)N_(4)(Pt Cu CN)composite was synthesized for the selective photocatalytic reduction of CO_(2)to CH_(4)under visible light.The Pt Cu CN catalyst achieved a CH_(4)yield of 3...In this study,a novel Pt-loaded Cu Pc/g-C_(3)N_(4)(Pt Cu CN)composite was synthesized for the selective photocatalytic reduction of CO_(2)to CH_(4)under visible light.The Pt Cu CN catalyst achieved a CH_(4)yield of 39.8μmol g^(-1)h^(-1),significantly outperforming bulk g-C_(3)N_(4)and Cu Pc alone by factors of 2.5 and 3.1,respectively,with a high selectivity of 90%.In comparison with other commonly studied photocatalysts,such as g-C_(3)N_(4)-based catalysts,the Pt Cu CN composite exhibited superior CH_(4)yield and product selectivity,demonstrating its potential as a more efficient photocatalyst for CO_(2)reduction.X-ray photoelectron spectroscopy(XPS),density functional theory(DFT)calculations,and in-situ infrared(IR)analysis revealed that the Pt^(0)species effectively lower the activation energy for CH_(4)formation,while Cu Pc extends the light absorption range and enhances charge separation.The combined effects of these components in a Z-scheme heterojunction provide new insights into designing highly selective CO_(2)-to-CH_(4)photocatalysts.This work demonstrates the potential of Pt Cu CN as a highly efficient and stable catalyst for CO_(2)reduction to CH_(4)under visible light.展开更多
Based on four phases of TM images acquired in 1990, 1995, 2000 and 2005, this paper took Kitakyushu in Japan as a case study to analyze spatial change of land use landscape and corresponding effects on environmental i...Based on four phases of TM images acquired in 1990, 1995, 2000 and 2005, this paper took Kitakyushu in Japan as a case study to analyze spatial change of land use landscape and corresponding effects on environmental issues guided by landscape ecology theory in virtue of combining technology of Remote Sensing with GIS. Firstly, land use types were divided into 6 classes （farmland, mountain, forestland, water body, urban land and unused land） according to national classification standard of land use, comprehensible ability of TM image and purpose of this study. Secondly, following the theory of landscape ecology analysis, 11 typical landscape indices were abstracted to evaluate the environmental effects and spatial feature changes of land use. Research results indicated that land use has grown more and more diversified and unbalanced, human activities have disturbed the landscape more seriously. Finally, transfer matrix of Markov was applied to forecast change process of land use in the future different periods, and then potential land use changes were also simulated from 2010 to 2050. Results showed that conversion tendency for all types of land use in Kitakyushu into urban construction land were enhanced. The study was anticipated to help local authorities better understand and address a complex land use system, and develop improved land use management strategies that could better balance urban expansion and ecological conservation.展开更多
To investigate the secondary formation and pollution sources of atmospheric particles in urban Beijing,PM2.5 and its chemical components were collected and determined by URG-9000 D ambient ion monitor(AIM) from March ...To investigate the secondary formation and pollution sources of atmospheric particles in urban Beijing,PM2.5 and its chemical components were collected and determined by URG-9000 D ambient ion monitor(AIM) from March 2016 to January 2017.Among water-soluble ions(WSIs), NO3-,SO42- and NH4+(SNA) had the largest proportion(77.8%) with the total concentration of 23.8 μg/m3.Moreover,as fine particle pollution worsened,the NO3-,SO4<sup>2- and NH4+ concentrations increased basically,which revealed that secondary aerosols were the main cause of particle pollution in Beijing.Furthermore,the particle neutralization ratio(1.1),the ammonia to sulfate molar ratio(3.4) and the nitrate to sulfate molar ratio(2.2) showed that secondary aerosols are under ammonium-rich conditions with the main chemical forms of NH4 NO3 and(NH4)2 SO4,and vehicle emission could be the main anthropogenic source of secondary aerosols in Beijing.Source analysis further indicated that secondary aerosols,solid fuel combustion,dust and marine aerosol were the principal pollution sources of PM2.5,accounting for about 46.1%,22.4% and 13.0%,respectively,and Inner Mongolia and Hebei Provinces could be considered as the main potential sources of PM2.5 in urban Beijing.In addition,secondary formation process was closely related with gaseous precursor emission amounts(SO2,NO2,NH3 and HONG),atmospheric ozone concentration(O3),meteorological conditions(temperature and relative humidity) and particle components.Sensitive analysis of the thermodynamic equilibrium model(ISORROPIA Ⅱ)revealed that controlling total nitrate(TN) is the effective measure to mitigate fine particle pollution in Beijing.展开更多
Zhuzhou was one of the most polluted cities in China with the serious acid rain.Due to the implementation of air pollution control measures from 2016 to 2018,the acid rain pollution in this city has reduced.In order t...Zhuzhou was one of the most polluted cities in China with the serious acid rain.Due to the implementation of air pollution control measures from 2016 to 2018,the acid rain pollution in this city has reduced.In order to understand the recent situation,a comprehensive study on the acid rain was carried out from January 2011 to December 2020.The pH values during the study period varied from 3.3 to 7.5,with a volume-weighted mean value of 4.7.The predominant acidic components of the precipitation were SO_(4)^(2-)and NO_(3)^(-),accounting for 89.3% of the total anions.The ratio of non-sea-salt SO_(4)^(2-)to NO_(3)^(-)showed a decreasing trend,revealing that the pollution type of acid rain changed from sulfuric acid type to sulfuric acid and nitric acid compound type.The correlation analysis(p<0.05)showed that SO_(4)^(2-)was positively correlated with NH_(4)^(+),Ca^(2+),and Mg^(2+);hence,it predominated in precipitation as(NH_(4))_(2)SO_(4),NH_(4)HSO_(4),CaSO_(4),and MgSO_(4).Significant positive correlation of Ca^(2+)with Mg^(2+)shows that they may originated mainly from crust.Significant positive correlation between SO_(4)^(2-)and F^(-)and Cl^(-)indicate that their source may be related to the non-ferrous metal smelting industry in Zhuzhou.Further correlation analysis shows that emissions from the non-ferrous metal smelting industry in the area have a large significant on SO_(4)^(2-)and F^(-)in precipitation,while Cl^(-)may still be emitted from other anthropogenic sources.展开更多
The effect of wind environment is becoming increasingly important in analyzing and selecting sites for better naturalventilation of residential buildings, external comfort, and pollution dispersion. The mainpurpose of...The effect of wind environment is becoming increasingly important in analyzing and selecting sites for better naturalventilation of residential buildings, external comfort, and pollution dispersion. The mainpurpose of this study was to develop a setof methods for wind environment assessment in coastal concave terrains. This set of methods can be used to provide quantifiableindicators of preferable wind conditions and help site analysis. Firstly, a total of 20 types of coastal bays with concave terrains inEast Asia were characterized to find ideal locations. The selected areas were divided into five categories according to the mainterrain features. Then a sample database for the concave terrains was compiled for modelling comparisons. Secondly, a number ofkey wind variables were identified. Computational fluid dynamics （CFD） models of the typical coastal concave terrains identifiedas a result of the study were created, and the local wind environments were simulated with input from geographic informationsystem （GIS） and statistic package for social science （SPSS） analysis. A measure of wind suitability was proposed that takes windvelocity and wind direction into account using GIS. Finally, SPSS was used to find the relationship between wind suitability andkey terrain factors. The results showed that wind suitability was significantly associated with terrain factors, especially altitude.The results suggest that residential building sites should be selected such that their bay openings face the direction of the prevailingwind and that the opposite direction should be avoided.展开更多
There is an abrupt boundary between two well-developed wetland forests, a stand consisting of a broad-leaved, nitrogen-fixer Alnusjaponica and a stand of the needle-leaved Picea glehnii Masters, in eastern Hokkaido, J...There is an abrupt boundary between two well-developed wetland forests, a stand consisting of a broad-leaved, nitrogen-fixer Alnusjaponica and a stand of the needle-leaved Picea glehnii Masters, in eastern Hokkaido, Japan. To clarify maintenance mechanisms, we studied the forest profile, water level, groundwater and precipitation chemistry, seedling establishment patterns in relation to microhabitats, and seed migration. The profile of groundwater level insufficiently explained the abrupt boundary formation, while the groundwater chemistry differed significantly between the two forests ; i.e., EC, Na^＋, K^＋, Mg^2＋, Ca^2＋ and Cl^- were higher in P. glehnii forest and pH was lower. Precipitation in P. glehnii forest contained richer Na＋, Ca^2＋ and Cl^-, indicating that the differences in surface-water chemistry were mostly derived from precipitation. Solar radiation was less than 2.2 MJ.m^-2.d^-1 on P. glehnii forest in late June, while that was patchily distributed in A.japonica forest with a range from 1.0 to 3.7 MJ＇m^-2＇d^-1. Moss cover on the soil surface, most of which were made of Sphagnum spp., was 60% in P. glehnii forest, but was 10% in A. japonica forest. Surface water chemistry represented by pH was considered to determine the development of Sphagnum moss. About 70% of P. glehnii seedlings 〈 1.3 m in height established on moss cover. Seed-sowing experiments suggested that seed germination and seedling survival for both species were significantly higher in P. glehnii forest. Therefore, the regeneration of P. glehnii in A. japonica forest was negligible, owing to the paucity of favorable microhabitats and low seedling establishment. A. japonica regenerated only by resprouting, and the seedlings were few in both forests. In addition, A. japonica seed migration into the P. glehnii forests was greatly restricted, and low solar radiation in the P. glehnii forest contributed to low seedling survival. Based on those results, we concluded that Picea glehnii and Alnusjaponica could develop distinct and selfish environments being unsuitable for the other species and inhibit natural afforestation of another species each other by excluding invasion.展开更多
In order to determine the contribution of aquatic macrophyte communities on nutrition to sustain the high primary productivity of an estuary aquatic community, we analyzed the process of phosphorus release from sedime...In order to determine the contribution of aquatic macrophyte communities on nutrition to sustain the high primary productivity of an estuary aquatic community, we analyzed the process of phosphorus release from sediments in aquatic macrophyte community in the estuary of the Chikugogawa River, South-Western Japan. Vertical profile of PD3-4 concentration and redox potential (Eh) of pore water in sediments were investigated within and outside the Phragmites australis community. Sediment horizon lower than 23 cm layer from the surface showed anaerobic (Eh australis community, whereas sediment was constantly oxic (Eh > 0 mV) up to 50 cm depth outside the P. australis community without organic matter accumulation. Non-vegetated sediment with organic matter accumulation showed anoxic profile as vegetated site. PD3-4 concentration in anaerobic parts of sediment showed higher than oxic parts, and higher PD3-4 concentration in sediment pore water corresponded to sulfur deposition in sediment. Sulfate ion supplied from the sea water is reduced under the anoxic condition and S2- reacts with water-insoluble phosphorus salts e.g. Fe3(PO4)2 or AlPO4 and Fe2S3 or Al2S3 precipitates. Thus PD3-4 was mobilized and released under anoxic sediments. P. australis supply organic litter to sediment and the sediment within the P. australis community showed anoxic after aerobic decomposition of organic substances in sediment. Incubation of sediments under N2 atmosphere accumulated PD3-4 in the medium corresponding to low Eh (3-4 was released under anaerobic condition. Estuary P. australis community has function for supplying PD3-4 to river water.展开更多
The gully region of Loess Plateau is one of the earliest human settlement areas and the most ecologically sensitive areas in China. It has been facing challenges for future development. Gully village is the smallest s...The gully region of Loess Plateau is one of the earliest human settlement areas and the most ecologically sensitive areas in China. It has been facing challenges for future development. Gully village is the smallest social units on Loess Plateau that owns large amount of agricultural population. However, due to inappropriate development planning and lack of developing directions, they are gradually disappearing. Based on the practical investigations of the Gully Regions of Loess Plateau, this paper aims to explore a new way for the future development of gully villages. Firstly, it classifies the gully villages by the distribution of location. Secondly, selecting ecological construction evaluation factors of gully village and completing the quantitative evaluation are applied on the suitability and sensitivity of ecological sustainable development classification. Thirdly, according to the comprehensive evaluation, the developing condition of each gully village is divided into “Good”, “General” and “Poor”. Finally, this paper figures out the future developing direction for gully villages in different developing conditions.展开更多
In the present study reduction of nitrogen oxides using reburning technology, during combustion of sewage sludge (fuel I) and the mixture of sewage sludge, wasted bleaching earth and CaO (fuel II), was carried out. Th...In the present study reduction of nitrogen oxides using reburning technology, during combustion of sewage sludge (fuel I) and the mixture of sewage sludge, wasted bleaching earth and CaO (fuel II), was carried out. The experimental works were conducted in a laboratory-scale fluidized bed reactor (power up to 10 kW) with application of two types of beds: chemically inert bed (sand) and chemically active bed (CaO). The second combustion (reburning) zone in the reactor was formed by dosing into an area above the bed, additional gaseous fuel (propane). Obtained reduction in emissions of nitrogen oxides in both types of beds was at a level 70% - 79%. Additionally bed of CaO has the desulfurizing effect and also reduces the CO concentration in the exhaust fumes. A significant drawback of active bed is the adverse effect on increase of the primary NO which enters the second combustion zone. The result of this fact is higher NOx emission during combustion of the same fuel in bed of CaO in comparison to the combustion of this fuel in the sand bed, when the same maximum degree of reduction of NOx will be obtained for both types of beds.展开更多
In order to clarify the effect of condensate inundation on steam condensation in a large tube bundle, condensation heat transfer and the condensate flow pattern in the tube bundle have been experimentally investigated...In order to clarify the effect of condensate inundation on steam condensation in a large tube bundle, condensation heat transfer and the condensate flow pattern in the tube bundle have been experimentally investigated. Test tube bundle consists of 36 cooling tubes, 12 condensate supply tubes and 24 un-cooled dummy tubes. Cooling test tubes are made of copper and have an outer diameter of 19.1 mm and condensing length of 150 mm, Steam flows horizontally through the test tube bundle at gap velocities 15-27 m/s at pressures of 8.8 kPa. In this study, experimental data about condensate flow pattern and condensation heat transfer in a tube bundle were collected for the optimization of tube arrangement in large power plant condensers.展开更多
There is an abrupt boundary between two well-developed wetland forests, a stand consisting of a broad-leaved, nitrogen-fixer Alnus japonica and a stand of the needle-leaved Picea glehnii Masters, in eastern Hokkaido, ...There is an abrupt boundary between two well-developed wetland forests, a stand consisting of a broad-leaved, nitrogen-fixer Alnus japonica and a stand of the needle-leaved Picea glehnii Masters, in eastern Hokkaido, Japan.To clarify maintenance mechanisms, we studied the forest profile, water level, groundwater and precipitation chemistry, seedling establishment patterns in relation to microhabitats, and seed migration.The profile of groundwater level insufficiently explained the abrupt boundary formation, while the groundwater che-mistry differed significantly between the two forests;i.e., EC, Na+, K+, Mg2+, Ca2+ and Cl-were higher in P.glehnii forest and pH was lower.Precipitation in P.glehnii forest contained richer Na+, Ca2+ and Cl-, indicating that the differences in surface-water chemistry were mostly derived from precipitation.Solar radiation was less than 2.2 MJ·m-2·d-1 on P.glehnii forest in late June, while that was patchily distributed in A.japonica forest with a range from 1.0 to 3.7 MJ·m-2·d-1.Moss cover on the soil surface, most of which were made of Sphagnum spp., was 60% in P.glehnii forest, but was 10% in A.japonica forest.Surface water chemistry represented by pH was considered to determine the development of Sphagnum moss.About 70% of P.glehnii seedlings < 1.3 m in height established on moss cover.Seed-sowing experiments suggested that seed germination and seedling survival for both species were significantly higher in P.glehnii forest.Therefore, the regeneration of P.glehnii in A.japonica forest was negligible, owing to the paucity of favorable microhabitats and low seedling establishment.A.japonica regenerated only by resprouting, and the seedlings were few in both forests.In addition, A.japonica seed migration into the P.glehnii forests was greatly restricted, and low solar radiation in the P.glehnii forest contributed to low seedling survival.Based on those results, we concluded that Picea glehnii and Alnus japonica could develop distinct and selfish environments being unsuitable for the other species and inhibit natural afforestation of another species each other by excluding invasion.展开更多
We investigated the chemical properties of stemflow of Picea glehnii,Abies sachalinensis and Alnus japonica as well as peat pore water chemistry,including the distance and depth profiles of pore water chemistry,in an ...We investigated the chemical properties of stemflow of Picea glehnii,Abies sachalinensis and Alnus japonica as well as peat pore water chemistry,including the distance and depth profiles of pore water chemistry,in an ombrogenous mire.The effect of stemflow on the peat pore water chemistry was clear at the stem base in the peat forest in the mire,and the peat pore water around the stem base of a tree had its own chemical properties specific to each species.P.glehnii showed the highest concentration of salts both in stemflow and peat-pore water,whereas A.japonica showed the lowest concentrations;however,the gradient of the chemical environment from the stem base to outside of the canopy is formed.The peat pore water chemistry under the canopy was mainly controlled by the chemical processes diluted by the abundant peat pore water;the stemflow movement in the high water content of the peat was more slowly because of the flat topography（〈 1o）.This would be due to the fact that the chemicals in stemflow would be diluted by the abundant peat pore water.The spatial heterogeneity of chemical environment between microsites within forested peatland would be also contributed indirectly through the control of microorganism activity,and nutrient regeneration mediated the surface water and the stemflow of the dominant canopy trees.展开更多
In the suburbs of Kitakyushu,Japan,the inorganic aerosol mass concentration(IAM)was about 32.7μg/m^(3),with the aerosol pH of 3.3.To study the thermodynamics of aerosol when its individual components'concentratio...In the suburbs of Kitakyushu,Japan,the inorganic aerosol mass concentration(IAM)was about 32.7μg/m^(3),with the aerosol pH of 3.3.To study the thermodynamics of aerosol when its individual components'concentration is reduced,sensitive tests were performed using the ISORROPIAⅡmodel,in which the seven control species—TNaCl,TNH_(4)^(+),TSO_(4)^(2-),TNO_(3)^(-),TMg^(2+),TK^(+),and TCa^(2+)—were taken into account.IAM and inorganic aerosol pH after reducing TNaCl,TNO_(3)^(-),TMg^(2+),TK^(+),and TCa^(2+)responded linearly(0%≤concentration reduction ratio(CRR)≤100%,with the exception of 100%in TNaCl);the nonlinear variations of these two parameters could be observed by controlling TNH_(4)^(+)and TSO_(4)^(2-).Unexpected aerosol behavior occurred at 100%reduction of TNaCl,which was caused by the sudden increase of NO_(3)^(-),NH_(4)^(+),and aerosol liquid water content(ALWC);the increase of IAM was also observed after controlling TSO_(4)^(2-)(60%≤CRR≤100%)and TCa^(2+)(0%≤CRR≤100%),which was mainly related to the variation of ALWC driven by the response of CaSO_(4).Multiple regression analysis showed that ALWC was statistically and strongly related to the variations of NO_(3)^(-),Cl-,SO_(4)^(2-),HSO_(4)^(-),HNO_(3),and NH_(3)(P<0.05),with regression coefficients of 1.68,5.23,1.83,2.81,0.34,and 0.57,respectively.The highest coefficient(5.23)was found for Cl^(-),revealing that sea salts significantly influenced particle responses.Overall,this study comprehensively investigated aerosol characteristics and inner responses for the reduction of components,which is of great significance for a better understanding of atmospheric chemistry in Kitakyushu,Japan.展开更多
The aim of this study was to assess the runoff amount from a catchment characterized by diverse land uses by using the Soil Conservation Service Curve Number(SCS-CN) method based on Curve Number(CN) defined for domina...The aim of this study was to assess the runoff amount from a catchment characterized by diverse land uses by using the Soil Conservation Service Curve Number(SCS-CN) method based on Curve Number(CN) defined for dominant homogeneous elementary sub-regions.The calculations employed the SCS-CN method,involving the division of the catchment in two homogeneous parts and determining the runoff amount.The obtained results were compared with the results provided by three other CN determination methods,i.e.the Hawkins function,the kinetics equation,and a complementary error function peak.The catchment is located in a mountain dominated by forest land cover.Empirical CN-Precipitation(CN_(emp)-P) data pairs were analyzed using the mentioned methods,and the highest quality score was achieved from model 1.The results suggest that dividing a catchment into two homogeneous areas and determining their separate CN parameters,used later on to calculate the runoff by means of the presented approach,could be an alternative to the standard methods.The described method is relatively easy,and as it does not require an adoption of numerous parameters,and it can be employed for designing hydraulic facilities.展开更多
Over the past few decades,the metal elements(MEs)in atmospheric particles have aroused great attention.Some well-established techniques have been used to measure particlebound MEs.However,each method has its own advan...Over the past few decades,the metal elements(MEs)in atmospheric particles have aroused great attention.Some well-established techniques have been used to measure particlebound MEs.However,each method has its own advantages and disadvantages in terms of complexity,accuracy,and specific elements of interest.In this study,the performances of inductively coupled plasma-optical emission spectrometry(ICP-OES)and total reflection X-ray fluorescence spectroscopy(TXRF)were evaluated for quality control to analyze data accuracy and precision.The statistic methods(Deming regression and significance testing)were applied for intercomparison between ICP-OES and TXRF measurements for same lowloading PM_(2.5)samples in Weizhou Island.The results from the replicate analysis of standard filters(SRM 2783)and field filters samples indicated that 10 MEs(K,Ca,V,Cr,Mn,Fe,Ni,Cu,Zn,and Pb)showed good accuracies and precision for both techniques.The higher accuracy tended to the higher precision in the MEs analysis process.In addition,the interlab comparisons illustrated that V and Mn all had good agreements between ICP-OES and TXRF.The measurements of K,Cu and Zn were more reliable by TXRF analysis for low-loading PM_(2.5).ICP-OES was more accurate for the determinations for Ca,Cr,Ni and Pb,owing to the overlapping spectral lines and low sensitivity during TXRF analysis.The measurements of Fe,influenced by low-loading PM_(2.5),were not able to determine which instrument could obtain more reliable results.These conclusions could provide reference information to choose suitable instrument for the determination of MEs in low-loading PM_(2.5)samples.展开更多
Shifts in hydrological regimes alter river flow rates and flood pulses, decrease environmental heterogeneity and the floristic-structural complexity of associated plant communities. We tested the hypothesis that droug...Shifts in hydrological regimes alter river flow rates and flood pulses, decrease environmental heterogeneity and the floristic-structural complexity of associated plant communities. We tested the hypothesis that drought events affect plant community composition and structure at a small-scale within a riparian fragment towards a reduction in floristic-structural complexity. The tree community was sampled in three habitats (wet, transitional and dry) and monitored in seven inventories carried out between 1991 and 2018. Hydrological variations were evaluated through annual rainfalls, river flow rates and water level data. The species richness and the detrended correspondence analysis axes were used to characterise the temporal modifications in floristic composition. Community structure was described in terms of biomass: accumulated, growth of survivors, mortality and recruitment. Generalised linear mixed models were fitted to evaluate the effects of time and environment in community. It was concluded that the climate has become drier in recent years due to declining precipitation that has affected flow rates and water levels. The floristic-structural complexity of the study fragment was maintained during the monitoring period. However, prolonged and extreme drought events displayed the potential to impact floristic-structural patterns.展开更多
Energy consumption is increasing every year in building sector, utilization and development of alternative energy sources and technologies to support the requirements of every house. The hydrogen fuel cell is one of t...Energy consumption is increasing every year in building sector, utilization and development of alternative energy sources and technologies to support the requirements of every house. The hydrogen fuel cell is one of the latest technologies for distributed energy systems. This research is aim to grasp the energy saving performance of the hydrogen co-generation system in the detached house. First, it investigated on the demand-side energy consumption including electricity, cooling, heating and hot water. Second, it introduced a distributed energy resources (DER) system and set six cases to analyze the energy utilization. Different options for changing the heating, cooling, electricity and hot water systems were compared for this type of detached house, assuming basiccase as a reference. Changes in the fuel used, energy operation machines and also demand side and supply side were analyzed. Except past case, every case will be operated under the electricitytracking mode and heat-tracking mode. The comparisons and evaluations of the energy consumption between cases can suggest the environmental performance of the hydrogen co-generation system.展开更多
基金support from the earmarked fund for XJARS(No.XJARS-06)the Bingtuan Science and Technology Program(Nos.2021DB019,2022CB001-01)+1 种基金the National Natural Science Foundation of China(No.42275014)the Guangdong Foundation for Program of Science and Technology Research,China(No.2023B1212060044)。
文摘Current research primarily focuses on emerging organic pollutants,with limited attention to emerging inorganic pollutants (EIPs).However,due to advances in detection technology and the escalating environmental and health challenges posed by pollution,there is a growing interest in treating waters contaminated with EIPs.This paper explores biochar characteristics and modification methods,encompassing physical,chemical,and biological approaches for adsorbing EIPs.It offers a comprehensive review of research advancements in employing biochar for EIPs remediation in water,outlines the adsorption mechanisms of EIPs by biochar,and presents an environmental and economic analysis.It can be concluded that using biochar for the adsorption of EIPs in wastewater exhibits promising potential.Nonetheless,it is noteworthy that certain EIPs like Au(III),Rh(III),Ir(III),Ru(III),Os(III),Sc(III),and Y(III),have not been extensively investigated regarding their adsorption onto biochar.This comprehensive review will catalyze further inquiry into the biochar-based adsorption of EIPs,addressing current research deficiencies and advancing the practical implementation of biochar as a potent substrate for EIP removal from wastewater streams.
文摘Tetracyclines (TCs) are the second most commonly used antibiotics worldwide, utilized in medical treatments and animal husbandry. Although effective against various infectious diseases, TC residues persist in the environment and contribute to the emergence of antibiotic-resistant pathogens, posing significant risks to human health. This study employed the heterogeneous Fenton process to degrade TC using soybean residue-derived magnetic biochar (Fe-SoyB) as the catalyst. The Fe-SoyB sample was characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), and superconducting quantum interference device (SQUID) techniques. The effects of key parameters, including pH, H2O2 concentration, catalyst dosage, and initial TC concentration, on TC degradation were investigated. The results indicated that the TC removal efficiency decreased with increasing initial TC concentration, while it was improved with higher H2O2 concentrations and greater catalyst dosages. The optimal conditions for the Fenton-like process were determined: a pH of 3, a H2O2 concentration of 245 mmol/L, an initial TC concentration of 800 mg/L, and a catalyst dosage of 0.75 g/L, achieving a removal efficiency of 90.0% after 150 min. Additionally, the TC removal efficiency of the Fe-SoyB system varied significantly across different water matrices, with 87.1% for deionized water, 78.5% for tap water, and 72.5% for river water. The catalyst demonstrated notable stability, maintaining a TC removal efficiency of 79.7% after three cycles of use. Overall, Fe-SoyB shows promise as a cost-effective catalyst for the elimination of organic pollutants in aqueous solutions.
基金supported by the National Natural Science Foundation of China(Grant No.U24A20580)National Natural Science Foundation of China(Grant No.42171298)+1 种基金Natural Science Foundation of Chongqing,China(Grant No.CSTB2023NSCQLZX0009)Philosophy and Social Science Major Project of Chongqing Municipal Education Commission(Grant No.24SKZDZX04).
文摘Urban sprawl is a critical challenge in the urban development trajectory of developing countries,necessitating precise measurement,trend projection,and strategic management to achieve sustainable urban growth.This study focuses on the Yangtze River Economic Belt(YREB)as a case region and introduces a comprehensive evaluation framework that incorporates multidimensional factors and addresses the scale effects of urban sprawl.We emphasize the value of a systematic geographical approach by quantifying urban sprawl through simulated scenarios and analyzing its driving factors.We constructed an innovative urban sprawl index(USI)to assess the degree of sprawl within the YREB.This assessment integrates two geographic models with an artificial neural network algorithm,enabling simulation of urban sprawl trends under two future scenarios for 2035.Additionally,two analytical methods were employed to identify the key driving mechanisms of urban sprawl in the region.Findings indicate a strong correlation between urban scale and the extent of urban sprawl:larger urban areas exhibit more pronounced sprawl,with agglomeration and morphological transformations identified as primary contributors to urban sprawl.The study further reveals an intricate association between urban sprawl and the compactness of urban internal structures.While both development scenarios offer distinct advantages,the Coordinated Development Scenario is projected to foster a more balanced urban expansion.The robustness of the evaluation framework was enhanced through simulation and an in-depth analysis of internal mechanisms,bolstering confidence in its applicability.We advocate for the adoption and continued refinement of this framework as a tool for promoting balanced urban growth.The strategic recommendations provided herein are vital for mitigating multi-scale urban sprawl,advancing economic development,and improving residents’quality of life across cities in the YREB.
基金financial support from the National Natural Science Foundation of China(Grant NO.22466023,52470119,52260013)the Applied Basic Research Foundation of Yunnan Province(Grant NO.202401AT070408)+1 种基金Yunnan Provincial Key Laboratory of Energy Saving in Phosphorus Chemical Engineering and New Phosphorus Materials(Grant NO.202205AG070067)Yunnan Technological Innovation Center of Phosphorus Resources(Grant NO.202305AK340002)。
文摘In this study,a novel Pt-loaded Cu Pc/g-C_(3)N_(4)(Pt Cu CN)composite was synthesized for the selective photocatalytic reduction of CO_(2)to CH_(4)under visible light.The Pt Cu CN catalyst achieved a CH_(4)yield of 39.8μmol g^(-1)h^(-1),significantly outperforming bulk g-C_(3)N_(4)and Cu Pc alone by factors of 2.5 and 3.1,respectively,with a high selectivity of 90%.In comparison with other commonly studied photocatalysts,such as g-C_(3)N_(4)-based catalysts,the Pt Cu CN composite exhibited superior CH_(4)yield and product selectivity,demonstrating its potential as a more efficient photocatalyst for CO_(2)reduction.X-ray photoelectron spectroscopy(XPS),density functional theory(DFT)calculations,and in-situ infrared(IR)analysis revealed that the Pt^(0)species effectively lower the activation energy for CH_(4)formation,while Cu Pc extends the light absorption range and enhances charge separation.The combined effects of these components in a Z-scheme heterojunction provide new insights into designing highly selective CO_(2)-to-CH_(4)photocatalysts.This work demonstrates the potential of Pt Cu CN as a highly efficient and stable catalyst for CO_(2)reduction to CH_(4)under visible light.
基金Sasakawa Scientific Foundation of Japan, No.20-238 National Basic Research Program of China （973 Program）, No.2006CB403200+1 种基金 National Natural Science Foundation of China, No.40261002 No.40561006
文摘Based on four phases of TM images acquired in 1990, 1995, 2000 and 2005, this paper took Kitakyushu in Japan as a case study to analyze spatial change of land use landscape and corresponding effects on environmental issues guided by landscape ecology theory in virtue of combining technology of Remote Sensing with GIS. Firstly, land use types were divided into 6 classes （farmland, mountain, forestland, water body, urban land and unused land） according to national classification standard of land use, comprehensible ability of TM image and purpose of this study. Secondly, following the theory of landscape ecology analysis, 11 typical landscape indices were abstracted to evaluate the environmental effects and spatial feature changes of land use. Research results indicated that land use has grown more and more diversified and unbalanced, human activities have disturbed the landscape more seriously. Finally, transfer matrix of Markov was applied to forecast change process of land use in the future different periods, and then potential land use changes were also simulated from 2010 to 2050. Results showed that conversion tendency for all types of land use in Kitakyushu into urban construction land were enhanced. The study was anticipated to help local authorities better understand and address a complex land use system, and develop improved land use management strategies that could better balance urban expansion and ecological conservation.
基金supported by the National Research Program for key issues in air pollution control(No.DQGG0304-05)the Fundamental Research Funds for Central Public Welfare Scientific Research Institutes of China(No.2016YSKY-025)+7 种基金the National Department Public Benefit Research Foundation(No.201109005)the National Natural Science Foundation of China(Nos.41205093,41305124,and 21976106)the Opening Project of Shanghai Key Laboratory of Atmospheric Particle Pollution and Prevention(No.FDLAP18005)the National Key Research and Development Program of Ministry of Science and Technology of China(No.2016YFE0112200)supported by Science Foundation of Shandong Jianzhu University(No.XNBS1824)Shandong Key Research and Development Program(No.2019GSF109064)the supports from the Co-Innovation Center for Green Building of Shandong Province(No.X18027Z)the Introduction and Cultivation Plan for Young Innovative Talents of Colleges and Universities by the Education Department of Shandong Province(Serial No.142,2019)
文摘To investigate the secondary formation and pollution sources of atmospheric particles in urban Beijing,PM2.5 and its chemical components were collected and determined by URG-9000 D ambient ion monitor(AIM) from March 2016 to January 2017.Among water-soluble ions(WSIs), NO3-,SO42- and NH4+(SNA) had the largest proportion(77.8%) with the total concentration of 23.8 μg/m3.Moreover,as fine particle pollution worsened,the NO3-,SO4<sup>2- and NH4+ concentrations increased basically,which revealed that secondary aerosols were the main cause of particle pollution in Beijing.Furthermore,the particle neutralization ratio(1.1),the ammonia to sulfate molar ratio(3.4) and the nitrate to sulfate molar ratio(2.2) showed that secondary aerosols are under ammonium-rich conditions with the main chemical forms of NH4 NO3 and(NH4)2 SO4,and vehicle emission could be the main anthropogenic source of secondary aerosols in Beijing.Source analysis further indicated that secondary aerosols,solid fuel combustion,dust and marine aerosol were the principal pollution sources of PM2.5,accounting for about 46.1%,22.4% and 13.0%,respectively,and Inner Mongolia and Hebei Provinces could be considered as the main potential sources of PM2.5 in urban Beijing.In addition,secondary formation process was closely related with gaseous precursor emission amounts(SO2,NO2,NH3 and HONG),atmospheric ozone concentration(O3),meteorological conditions(temperature and relative humidity) and particle components.Sensitive analysis of the thermodynamic equilibrium model(ISORROPIA Ⅱ)revealed that controlling total nitrate(TN) is the effective measure to mitigate fine particle pollution in Beijing.
基金supported by the National Natural Science Foundation of China(Nos.41205093,42075182)the National Department Public Benefit Research Foundation(No.201109005)。
文摘Zhuzhou was one of the most polluted cities in China with the serious acid rain.Due to the implementation of air pollution control measures from 2016 to 2018,the acid rain pollution in this city has reduced.In order to understand the recent situation,a comprehensive study on the acid rain was carried out from January 2011 to December 2020.The pH values during the study period varied from 3.3 to 7.5,with a volume-weighted mean value of 4.7.The predominant acidic components of the precipitation were SO_(4)^(2-)and NO_(3)^(-),accounting for 89.3% of the total anions.The ratio of non-sea-salt SO_(4)^(2-)to NO_(3)^(-)showed a decreasing trend,revealing that the pollution type of acid rain changed from sulfuric acid type to sulfuric acid and nitric acid compound type.The correlation analysis(p<0.05)showed that SO_(4)^(2-)was positively correlated with NH_(4)^(+),Ca^(2+),and Mg^(2+);hence,it predominated in precipitation as(NH_(4))_(2)SO_(4),NH_(4)HSO_(4),CaSO_(4),and MgSO_(4).Significant positive correlation of Ca^(2+)with Mg^(2+)shows that they may originated mainly from crust.Significant positive correlation between SO_(4)^(2-)and F^(-)and Cl^(-)indicate that their source may be related to the non-ferrous metal smelting industry in Zhuzhou.Further correlation analysis shows that emissions from the non-ferrous metal smelting industry in the area have a large significant on SO_(4)^(2-)and F^(-)in precipitation,while Cl^(-)may still be emitted from other anthropogenic sources.
基金supported by the National Natural Science Foundation of China(Nos.51208466 and 51238011)the Science and Technology Research Program of Chinese Ministry of Housing and Urban-Rural Development(No.2014R2-036)+2 种基金the Humanities and Social Sciences Research Foundation of the Ministry of Education(No.17YJAZH136)the Natural Science Foundation of Zhejiang Province(No.LY16E0 80011)the Social Sciences Planning Project of Zhejiang Province(No.12JCSH02YB),China
文摘The effect of wind environment is becoming increasingly important in analyzing and selecting sites for better naturalventilation of residential buildings, external comfort, and pollution dispersion. The mainpurpose of this study was to develop a setof methods for wind environment assessment in coastal concave terrains. This set of methods can be used to provide quantifiableindicators of preferable wind conditions and help site analysis. Firstly, a total of 20 types of coastal bays with concave terrains inEast Asia were characterized to find ideal locations. The selected areas were divided into five categories according to the mainterrain features. Then a sample database for the concave terrains was compiled for modelling comparisons. Secondly, a number ofkey wind variables were identified. Computational fluid dynamics （CFD） models of the typical coastal concave terrains identifiedas a result of the study were created, and the local wind environments were simulated with input from geographic informationsystem （GIS） and statistic package for social science （SPSS） analysis. A measure of wind suitability was proposed that takes windvelocity and wind direction into account using GIS. Finally, SPSS was used to find the relationship between wind suitability andkey terrain factors. The results showed that wind suitability was significantly associated with terrain factors, especially altitude.The results suggest that residential building sites should be selected such that their bay openings face the direction of the prevailingwind and that the opposite direction should be avoided.
文摘There is an abrupt boundary between two well-developed wetland forests, a stand consisting of a broad-leaved, nitrogen-fixer Alnusjaponica and a stand of the needle-leaved Picea glehnii Masters, in eastern Hokkaido, Japan. To clarify maintenance mechanisms, we studied the forest profile, water level, groundwater and precipitation chemistry, seedling establishment patterns in relation to microhabitats, and seed migration. The profile of groundwater level insufficiently explained the abrupt boundary formation, while the groundwater chemistry differed significantly between the two forests ; i.e., EC, Na^＋, K^＋, Mg^2＋, Ca^2＋ and Cl^- were higher in P. glehnii forest and pH was lower. Precipitation in P. glehnii forest contained richer Na＋, Ca^2＋ and Cl^-, indicating that the differences in surface-water chemistry were mostly derived from precipitation. Solar radiation was less than 2.2 MJ.m^-2.d^-1 on P. glehnii forest in late June, while that was patchily distributed in A.japonica forest with a range from 1.0 to 3.7 MJ＇m^-2＇d^-1. Moss cover on the soil surface, most of which were made of Sphagnum spp., was 60% in P. glehnii forest, but was 10% in A. japonica forest. Surface water chemistry represented by pH was considered to determine the development of Sphagnum moss. About 70% of P. glehnii seedlings 〈 1.3 m in height established on moss cover. Seed-sowing experiments suggested that seed germination and seedling survival for both species were significantly higher in P. glehnii forest. Therefore, the regeneration of P. glehnii in A. japonica forest was negligible, owing to the paucity of favorable microhabitats and low seedling establishment. A. japonica regenerated only by resprouting, and the seedlings were few in both forests. In addition, A. japonica seed migration into the P. glehnii forests was greatly restricted, and low solar radiation in the P. glehnii forest contributed to low seedling survival. Based on those results, we concluded that Picea glehnii and Alnusjaponica could develop distinct and selfish environments being unsuitable for the other species and inhibit natural afforestation of another species each other by excluding invasion.
文摘In order to determine the contribution of aquatic macrophyte communities on nutrition to sustain the high primary productivity of an estuary aquatic community, we analyzed the process of phosphorus release from sediments in aquatic macrophyte community in the estuary of the Chikugogawa River, South-Western Japan. Vertical profile of PD3-4 concentration and redox potential (Eh) of pore water in sediments were investigated within and outside the Phragmites australis community. Sediment horizon lower than 23 cm layer from the surface showed anaerobic (Eh australis community, whereas sediment was constantly oxic (Eh > 0 mV) up to 50 cm depth outside the P. australis community without organic matter accumulation. Non-vegetated sediment with organic matter accumulation showed anoxic profile as vegetated site. PD3-4 concentration in anaerobic parts of sediment showed higher than oxic parts, and higher PD3-4 concentration in sediment pore water corresponded to sulfur deposition in sediment. Sulfate ion supplied from the sea water is reduced under the anoxic condition and S2- reacts with water-insoluble phosphorus salts e.g. Fe3(PO4)2 or AlPO4 and Fe2S3 or Al2S3 precipitates. Thus PD3-4 was mobilized and released under anoxic sediments. P. australis supply organic litter to sediment and the sediment within the P. australis community showed anoxic after aerobic decomposition of organic substances in sediment. Incubation of sediments under N2 atmosphere accumulated PD3-4 in the medium corresponding to low Eh (3-4 was released under anaerobic condition. Estuary P. australis community has function for supplying PD3-4 to river water.
文摘The gully region of Loess Plateau is one of the earliest human settlement areas and the most ecologically sensitive areas in China. It has been facing challenges for future development. Gully village is the smallest social units on Loess Plateau that owns large amount of agricultural population. However, due to inappropriate development planning and lack of developing directions, they are gradually disappearing. Based on the practical investigations of the Gully Regions of Loess Plateau, this paper aims to explore a new way for the future development of gully villages. Firstly, it classifies the gully villages by the distribution of location. Secondly, selecting ecological construction evaluation factors of gully village and completing the quantitative evaluation are applied on the suitability and sensitivity of ecological sustainable development classification. Thirdly, according to the comprehensive evaluation, the developing condition of each gully village is divided into “Good”, “General” and “Poor”. Finally, this paper figures out the future developing direction for gully villages in different developing conditions.
文摘In the present study reduction of nitrogen oxides using reburning technology, during combustion of sewage sludge (fuel I) and the mixture of sewage sludge, wasted bleaching earth and CaO (fuel II), was carried out. The experimental works were conducted in a laboratory-scale fluidized bed reactor (power up to 10 kW) with application of two types of beds: chemically inert bed (sand) and chemically active bed (CaO). The second combustion (reburning) zone in the reactor was formed by dosing into an area above the bed, additional gaseous fuel (propane). Obtained reduction in emissions of nitrogen oxides in both types of beds was at a level 70% - 79%. Additionally bed of CaO has the desulfurizing effect and also reduces the CO concentration in the exhaust fumes. A significant drawback of active bed is the adverse effect on increase of the primary NO which enters the second combustion zone. The result of this fact is higher NOx emission during combustion of the same fuel in bed of CaO in comparison to the combustion of this fuel in the sand bed, when the same maximum degree of reduction of NOx will be obtained for both types of beds.
文摘In order to clarify the effect of condensate inundation on steam condensation in a large tube bundle, condensation heat transfer and the condensate flow pattern in the tube bundle have been experimentally investigated. Test tube bundle consists of 36 cooling tubes, 12 condensate supply tubes and 24 un-cooled dummy tubes. Cooling test tubes are made of copper and have an outer diameter of 19.1 mm and condensing length of 150 mm, Steam flows horizontally through the test tube bundle at gap velocities 15-27 m/s at pressures of 8.8 kPa. In this study, experimental data about condensate flow pattern and condensation heat transfer in a tube bundle were collected for the optimization of tube arrangement in large power plant condensers.
基金supported by the grants from Ministry of Education, Science, and Culture of Japan.
文摘There is an abrupt boundary between two well-developed wetland forests, a stand consisting of a broad-leaved, nitrogen-fixer Alnus japonica and a stand of the needle-leaved Picea glehnii Masters, in eastern Hokkaido, Japan.To clarify maintenance mechanisms, we studied the forest profile, water level, groundwater and precipitation chemistry, seedling establishment patterns in relation to microhabitats, and seed migration.The profile of groundwater level insufficiently explained the abrupt boundary formation, while the groundwater che-mistry differed significantly between the two forests;i.e., EC, Na+, K+, Mg2+, Ca2+ and Cl-were higher in P.glehnii forest and pH was lower.Precipitation in P.glehnii forest contained richer Na+, Ca2+ and Cl-, indicating that the differences in surface-water chemistry were mostly derived from precipitation.Solar radiation was less than 2.2 MJ·m-2·d-1 on P.glehnii forest in late June, while that was patchily distributed in A.japonica forest with a range from 1.0 to 3.7 MJ·m-2·d-1.Moss cover on the soil surface, most of which were made of Sphagnum spp., was 60% in P.glehnii forest, but was 10% in A.japonica forest.Surface water chemistry represented by pH was considered to determine the development of Sphagnum moss.About 70% of P.glehnii seedlings < 1.3 m in height established on moss cover.Seed-sowing experiments suggested that seed germination and seedling survival for both species were significantly higher in P.glehnii forest.Therefore, the regeneration of P.glehnii in A.japonica forest was negligible, owing to the paucity of favorable microhabitats and low seedling establishment.A.japonica regenerated only by resprouting, and the seedlings were few in both forests.In addition, A.japonica seed migration into the P.glehnii forests was greatly restricted, and low solar radiation in the P.glehnii forest contributed to low seedling survival.Based on those results, we concluded that Picea glehnii and Alnus japonica could develop distinct and selfish environments being unsuitable for the other species and inhibit natural afforestation of another species each other by excluding invasion.
文摘We investigated the chemical properties of stemflow of Picea glehnii,Abies sachalinensis and Alnus japonica as well as peat pore water chemistry,including the distance and depth profiles of pore water chemistry,in an ombrogenous mire.The effect of stemflow on the peat pore water chemistry was clear at the stem base in the peat forest in the mire,and the peat pore water around the stem base of a tree had its own chemical properties specific to each species.P.glehnii showed the highest concentration of salts both in stemflow and peat-pore water,whereas A.japonica showed the lowest concentrations;however,the gradient of the chemical environment from the stem base to outside of the canopy is formed.The peat pore water chemistry under the canopy was mainly controlled by the chemical processes diluted by the abundant peat pore water;the stemflow movement in the high water content of the peat was more slowly because of the flat topography（〈 1o）.This would be due to the fact that the chemicals in stemflow would be diluted by the abundant peat pore water.The spatial heterogeneity of chemical environment between microsites within forested peatland would be also contributed indirectly through the control of microorganism activity,and nutrient regeneration mediated the surface water and the stemflow of the dominant canopy trees.
文摘In the suburbs of Kitakyushu,Japan,the inorganic aerosol mass concentration(IAM)was about 32.7μg/m^(3),with the aerosol pH of 3.3.To study the thermodynamics of aerosol when its individual components'concentration is reduced,sensitive tests were performed using the ISORROPIAⅡmodel,in which the seven control species—TNaCl,TNH_(4)^(+),TSO_(4)^(2-),TNO_(3)^(-),TMg^(2+),TK^(+),and TCa^(2+)—were taken into account.IAM and inorganic aerosol pH after reducing TNaCl,TNO_(3)^(-),TMg^(2+),TK^(+),and TCa^(2+)responded linearly(0%≤concentration reduction ratio(CRR)≤100%,with the exception of 100%in TNaCl);the nonlinear variations of these two parameters could be observed by controlling TNH_(4)^(+)and TSO_(4)^(2-).Unexpected aerosol behavior occurred at 100%reduction of TNaCl,which was caused by the sudden increase of NO_(3)^(-),NH_(4)^(+),and aerosol liquid water content(ALWC);the increase of IAM was also observed after controlling TSO_(4)^(2-)(60%≤CRR≤100%)and TCa^(2+)(0%≤CRR≤100%),which was mainly related to the variation of ALWC driven by the response of CaSO_(4).Multiple regression analysis showed that ALWC was statistically and strongly related to the variations of NO_(3)^(-),Cl-,SO_(4)^(2-),HSO_(4)^(-),HNO_(3),and NH_(3)(P<0.05),with regression coefficients of 1.68,5.23,1.83,2.81,0.34,and 0.57,respectively.The highest coefficient(5.23)was found for Cl^(-),revealing that sea salts significantly influenced particle responses.Overall,this study comprehensively investigated aerosol characteristics and inner responses for the reduction of components,which is of great significance for a better understanding of atmospheric chemistry in Kitakyushu,Japan.
基金Dean of the Faculty of Environmental Engineering and Land Surveying, University of Agriculture in Krakow, for financial support
文摘The aim of this study was to assess the runoff amount from a catchment characterized by diverse land uses by using the Soil Conservation Service Curve Number(SCS-CN) method based on Curve Number(CN) defined for dominant homogeneous elementary sub-regions.The calculations employed the SCS-CN method,involving the division of the catchment in two homogeneous parts and determining the runoff amount.The obtained results were compared with the results provided by three other CN determination methods,i.e.the Hawkins function,the kinetics equation,and a complementary error function peak.The catchment is located in a mountain dominated by forest land cover.Empirical CN-Precipitation(CN_(emp)-P) data pairs were analyzed using the mentioned methods,and the highest quality score was achieved from model 1.The results suggest that dividing a catchment into two homogeneous areas and determining their separate CN parameters,used later on to calculate the runoff by means of the presented approach,could be an alternative to the standard methods.The described method is relatively easy,and as it does not require an adoption of numerous parameters,and it can be employed for designing hydraulic facilities.
基金supported by the National Natural Science Foundation of China(No.42075182)the Science and Technology Pre-research Project for Collaborative Prevention and Control on O3 and PM2.5 Compound Pollution(No.DQGG202026)the Three-dimensional Comprehensive Observation Research Program for O3and PM2.5Compound Pollution in Key Areas in Summer 2021(No.DQGG2021101)
文摘Over the past few decades,the metal elements(MEs)in atmospheric particles have aroused great attention.Some well-established techniques have been used to measure particlebound MEs.However,each method has its own advantages and disadvantages in terms of complexity,accuracy,and specific elements of interest.In this study,the performances of inductively coupled plasma-optical emission spectrometry(ICP-OES)and total reflection X-ray fluorescence spectroscopy(TXRF)were evaluated for quality control to analyze data accuracy and precision.The statistic methods(Deming regression and significance testing)were applied for intercomparison between ICP-OES and TXRF measurements for same lowloading PM_(2.5)samples in Weizhou Island.The results from the replicate analysis of standard filters(SRM 2783)and field filters samples indicated that 10 MEs(K,Ca,V,Cr,Mn,Fe,Ni,Cu,Zn,and Pb)showed good accuracies and precision for both techniques.The higher accuracy tended to the higher precision in the MEs analysis process.In addition,the interlab comparisons illustrated that V and Mn all had good agreements between ICP-OES and TXRF.The measurements of K,Cu and Zn were more reliable by TXRF analysis for low-loading PM_(2.5).ICP-OES was more accurate for the determinations for Ca,Cr,Ni and Pb,owing to the overlapping spectral lines and low sensitivity during TXRF analysis.The measurements of Fe,influenced by low-loading PM_(2.5),were not able to determine which instrument could obtain more reliable results.These conclusions could provide reference information to choose suitable instrument for the determination of MEs in low-loading PM_(2.5)samples.
基金supported by the CAPES(Coordenação de Aperfeiçoamento de Pessoal de Nível Superior,Coordination for the Improvement of Higher Education Personnel)CNPq(Conselho Nacional de Desenvolvimento Científi co e Tecnológico,National Council for Scientifi c and Technological Development)+1 种基金FAPEMIG(Fundação de Amparo à Pesquisa do Estado de Minas Gerais,Foundation for Supporting Research of the State of Minas Gerais)scholarship grant of the Federal University of Lavras(Universidade Federal de Lavras).
文摘Shifts in hydrological regimes alter river flow rates and flood pulses, decrease environmental heterogeneity and the floristic-structural complexity of associated plant communities. We tested the hypothesis that drought events affect plant community composition and structure at a small-scale within a riparian fragment towards a reduction in floristic-structural complexity. The tree community was sampled in three habitats (wet, transitional and dry) and monitored in seven inventories carried out between 1991 and 2018. Hydrological variations were evaluated through annual rainfalls, river flow rates and water level data. The species richness and the detrended correspondence analysis axes were used to characterise the temporal modifications in floristic composition. Community structure was described in terms of biomass: accumulated, growth of survivors, mortality and recruitment. Generalised linear mixed models were fitted to evaluate the effects of time and environment in community. It was concluded that the climate has become drier in recent years due to declining precipitation that has affected flow rates and water levels. The floristic-structural complexity of the study fragment was maintained during the monitoring period. However, prolonged and extreme drought events displayed the potential to impact floristic-structural patterns.
文摘Energy consumption is increasing every year in building sector, utilization and development of alternative energy sources and technologies to support the requirements of every house. The hydrogen fuel cell is one of the latest technologies for distributed energy systems. This research is aim to grasp the energy saving performance of the hydrogen co-generation system in the detached house. First, it investigated on the demand-side energy consumption including electricity, cooling, heating and hot water. Second, it introduced a distributed energy resources (DER) system and set six cases to analyze the energy utilization. Different options for changing the heating, cooling, electricity and hot water systems were compared for this type of detached house, assuming basiccase as a reference. Changes in the fuel used, energy operation machines and also demand side and supply side were analyzed. Except past case, every case will be operated under the electricitytracking mode and heat-tracking mode. The comparisons and evaluations of the energy consumption between cases can suggest the environmental performance of the hydrogen co-generation system.
