Geothermal energy,a form of renewable energy,has been extensively utilized for building heating.However,there is a lack of detailed comparative studies on the use of shallow and medium-deep geothermal energy in buildi...Geothermal energy,a form of renewable energy,has been extensively utilized for building heating.However,there is a lack of detailed comparative studies on the use of shallow and medium-deep geothermal energy in building energy systems,which are essential for decision-making.Therefore,this paper presents a comparative study of the performance and economic analysis of shallow and medium-deep borehole heat exchanger heating systems.Based on the geological parameters of Xi’an,China and commonly used borehole heat exchanger structures,numerical simulationmethods are employed to analyze performance and economic efficiency.The results indicate that increasing the spacing between shallow borehole heat exchangers can effectively reduce thermal interference between the pipes and improve heat extraction performance.As the flow rate increases,the outlet water temperature ranges from 279.3 to 279.7 K,with heat extraction power varying between 595 and 609 W.For medium-deep borehole heat exchangers,performance predictions show that a higher flow rate results in greater heat extraction power.However,when the flow rate exceeds 30 m^(3)/h,further increases in flow rate have only a minor effect on enhancing heat extraction power.Additionally,the economic analysis reveals that the payback period for shallow geothermal heating systems ranges from 10 to 11 years,while for medium-deep geothermal heating systems,it varies more widely from 3 to 25 years.Therefore,the payback period for medium-deep geothermal heating systems is more significantly influenced by operational and installation parameters,and optimizing these parameters can considerably shorten the payback period.The results of this study are expected to provide valuable insights into the efficient and cost-effective utilization of geothermal energy for building heating.展开更多
Autograft or metal implants are routinely used in skeletal repair.However,they fail to provide long-term clinical resolution,necessitating a functional biomimetic tissue engineering alternative.The use of native human...Autograft or metal implants are routinely used in skeletal repair.However,they fail to provide long-term clinical resolution,necessitating a functional biomimetic tissue engineering alternative.The use of native human bone tissue for synthesizing a biomimeticmaterial inkfor three-dimensional(3D)bioprintingof skeletal tissueis anattractivestrategyfor tissueregeneration.Thus,human bone extracellular matrix(bone-ECM)offers an exciting potential for the development of an appropriate microenvironment for human bone marrow stromal cells(HBMSCs)to proliferate and differentiate along the osteogenic lineage.In this study,we engineered a novel material ink(LAB)by blending human bone-ECM(B)with nanoclay(L,Laponite®)and alginate(A)polymers using extrusion-based deposition.The inclusion of the nanofiller and polymeric material increased the rheology,printability,and drug retention properties and,critically,the preservation of HBMSCs viability upon printing.The composite of human bone-ECM-based 3D constructs containing vascular endothelial growth factor(VEGF)enhanced vascularization after implantation in an ex vivo chick chorioallantoic membrane(CAM)model.The inclusion of bone morphogenetic protein-2(BMP-2)with the HBMSCs further enhanced vascularization and mineralization after only seven days.This study demonstrates the synergistic combination of nanoclay with biomimetic materials(alginate and bone-ECM)to support the formation of osteogenic tissue both in vitro and ex vivo and offers a promising novel 3D bioprinting approach to personalized skeletal tissue repair.展开更多
The influence of Mo and ZrO_(2)nanoparticles addition on the interfacial properties and shear strength of Sn58Bi solder joint was investigated.The interfacial microstructures of Sn58Bi/Cu,Sn58Bi+Mo/Cu and Sn58Bi+ZrO_(...The influence of Mo and ZrO_(2)nanoparticles addition on the interfacial properties and shear strength of Sn58Bi solder joint was investigated.The interfacial microstructures of Sn58Bi/Cu,Sn58Bi+Mo/Cu and Sn58Bi+ZrO_(2)/Cu solder joints were analysed using a scanning electron microscope(SEM)coupled with energy dispersive X-ray(EDX)and the X-ray diffraction(XRD).Intermetallic compounds(IMCs)of MoSn_(2)are detected in the Sn58Bi+Mo/Cu solder joint,while SnZr,Zr_(5)Sn_(3),ZrCu and ZrSn_(2)are detected in Sn58Bi+ZrO_(2)/Cu solder joint.IMC layers for both composite solders comprise of Cu_(6)Sn_(5) and Cu_(3)Sn.The SEM images of these layers were used to measure the IMC layer’s thickness.The average IMC layer’s thickness is 1.4431μm for Sn58Bi+Mo/Cu and 0.9112μm for Sn58Bi+ZrO_(2)/Cu solder joints.Shear strength of the solder joints was investigated via the single shear lap test method.The average maximum load and shear stress of the Sn58Bi+Mo/Cu and Sn58Bi+ZrO_(2)/Cu solder joints are increased by 33%and 69%,respectively,as compared to those of the Sn58Bi/Cu solder joint.By comparing both composite solder joints,the latter prevails better as adding smaller sized ZrO_(2)nanoparticles improves the interfacial properties granting a stronger solder joint.展开更多
Phenol-containing wastewater is typical organic wastewater,and its treatment is arduous.An advanced method to treat this type of wastewater is persulfate activation.Environmentally friendly ceriummanganese composite o...Phenol-containing wastewater is typical organic wastewater,and its treatment is arduous.An advanced method to treat this type of wastewater is persulfate activation.Environmentally friendly ceriummanganese composite oxide materials were synthesized by hydrothermal method and applied to the phenol degradation process.Various ratios of cerium and manganese,as well as the amount of sodium hydroxide,were investigated.The solid solutions of cerium and manganese were formed and confirmed by X-ray diffraction(XRD) and transmission electron microscopy(TEM).H_(2)-temperature programmed reduction(H_(2)-TPR) and X-ray photoelectron spectroscopy(XPS) were utilized to analyze the synergistic effect of cerium and manganese.It is found that there is a transformation between Ce^(4+)/Ce^(3+) and Mn^(2+)/Mn^(3+),which makes the material more trivalent manganese and thereby increases the catalytic activity.The effect of materials in catalyzing phenol degradation by peroxodisulfate(PDS) under various preparation conditions is discussed and high-effciency removal of phenol can be achieved and the removal rate at 180 min is close to 100%.The kinetic of this process was investigated and activation energy of phenol degradation is 62,35 kJ/mol.The degradation pathway of phenol was studied and it is found that PDS can be activated by low metal ions and the OH and SO_(4·)^(-)radicals play crucial roles according to the quenching experiments.展开更多
The DNS over HTTPS(Hypertext Transfer Protocol Secure)(DoH)is a new technology that encrypts DNS traffic,enhancing the privacy and security of end-users.However,the adoption of DoH is still facing several research cha...The DNS over HTTPS(Hypertext Transfer Protocol Secure)(DoH)is a new technology that encrypts DNS traffic,enhancing the privacy and security of end-users.However,the adoption of DoH is still facing several research challenges,such as ensuring security,compatibility,standardization,performance,privacy,and increasing user awareness.DoH significantly impacts network security,including better end-user privacy and security,challenges for network security professionals,increasing usage of encrypted malware communication,and difficulty adapting DNS-based security measures.Therefore,it is important to understand the impact of DoH on network security and develop newprivacy-preserving techniques to allowthe analysis of DoH traffic without compromising user privacy.This paper provides an in-depth analysis of the effects of DoH on cybersecurity.We discuss various techniques for detecting DoH tunneling and identify essential research challenges that need to be addressed in future security studies.Overall,this paper highlights the need for continued research and development to ensure the effectiveness of DoH as a tool for improving privacy and security.展开更多
This study is an extension of the previous work done with ARS-680 Environmental Chamber. Drying is a complex operation that demands much energy and time. Drying is essentially important for preservation of ginger rhiz...This study is an extension of the previous work done with ARS-680 Environmental Chamber. Drying is a complex operation that demands much energy and time. Drying is essentially important for preservation of ginger rhizome. Drying of ginger was modeled, and then the effective diffusion coefficient and activation energy were determined. For this purpose, the experiments were done at six levels of varied temperatures: 10°C, 20°C, 30°C, 40°C, 50°C and 60°C. The values of effective diffusion coefficients obtained in this work for the variously treated ginger rhizomes closely agreed with the average effective diffusion coefficients of other notable authors who determined the drying kinetics and convective heat transfer coefficients of ginger slices.展开更多
This paper studies motor joint control of a 4-degree-of-freedom(DoF)robotic manipulator using learning-based Adaptive Dynamic Programming(ADP)approach.The manipulator’s dynamics are modelled as an open-loop 4-link se...This paper studies motor joint control of a 4-degree-of-freedom(DoF)robotic manipulator using learning-based Adaptive Dynamic Programming(ADP)approach.The manipulator’s dynamics are modelled as an open-loop 4-link serial kinematic chain with 4 Degrees of Freedom(DoF).Decentralised optimal controllers are designed for each link using ADP approach based on a set of cost matrices and data collected from exploration trajectories.The proposed control strategy employs an off-line,off-policy iterative approach to derive four optimal control policies,one for each joint,under exploration strategies.The objective of the controller is to control the position of each joint.Simulation and experimental results show that four independent optimal controllers are found,each under similar exploration strategies,and the proposed ADP approach successfully yields optimal linear control policies despite the presence of these complexities.The experimental results conducted on the Quanser Qarm robotic platform demonstrate the effectiveness of the proposed ADP controllers in handling significant dynamic nonlinearities,such as actuation limitations,output saturation,and filter delays.展开更多
Objective: Heavy ion beam, which has emerged as a new mutagen in the mutation breeding of crops and ornamental plants, is expected to result in the induction of novel mutations. This study investigates the morphologic...Objective: Heavy ion beam, which has emerged as a new mutagen in the mutation breeding of crops and ornamental plants, is expected to result in the induction of novel mutations. This study investigates the morphological and biochemical responses of Oryza sativa toward different doses of carbon ion beam irradiation. Methods: In this study, the dry seeds of O. sativa were irradiated at 0, 20, 40, 60, 80, 100, and 120 Gy, followed by in-vitro germination under controlled conditions. Morphological and biochemical studies were conducted to investigate the morphological and physiological responses of O. sativa towards ion beam irradiation. Results: The study demonstrated that low doses(10 Gy) of ion beam have a stimulating effect on the height, root length, and fresh weight of the plantlets but not on the number of leaves. Meanwhile, doses higher than 10 Gy caused reductions in all the morphological parameters studied as compared to the control samples. The highest total soluble protein content [(2.11±0.47) mg/g FW] was observed in plantlets irradiated at 20 Gy. All irradiated plantlets were found to have 0.85% to 58.32% higher specific activity of peroxidase as compared to the control samples. The present study also revealed that low doses of ion beam(10 and 20 Gy) had negligible effect on the total chlorophyll content of O. sativa plantlets while 40 Gy had a stimulating effect on the chlorophyll content. Plantlets irradiated between 40 to 120 Gy were shown to be 0.38% to 9.98% higher in total soluble nitrogen content which, however, was not significantly different from the control samples. Conclusions: Carbon ion beam irradiation administered at low to moderate doses of 10 to 40 Gy may induce O. sativa mutants with superior characteristics.展开更多
In this study,a quantitative performance of three commercial polyamide nanofiltration(NF) membranes(i.e.,NF,NF90,and NF270) for phosphorus removal under different feed conditions was investigated.The experiments were ...In this study,a quantitative performance of three commercial polyamide nanofiltration(NF) membranes(i.e.,NF,NF90,and NF270) for phosphorus removal under different feed conditions was investigated.The experiments were conducted at different feed phosphorus concentrations(2.5,5,10,and 15 mg·L^-1) and elevated pHs(pH 1.5,5,10,and 13.5) at a constant feed pressure of 1 MPa using a dead-end filtration cell.Membrane rejection against total phosphorus generally increased with increasing phosphorus concentration regardless of membrane type.In contrast,the permeate flux for all the membranes only decreased slightly with increasing phosphorus concentration.The results also showed that the phosphorus rejections improved while water flux remained almost unchanged with increasing feed solution pH.When the three membranes were exposed to strong pHs(pH 1.5 and 13.5) for a longer duration(up to 6 weeks)it was found that the rejection capability and water flux of the membranes remained very similar throughout the duration,except for NF membrane with marginal decrement in phosphorus rejection.Adsorption study also revealed that more phosphorus was adsorbed onto the membrane structure at alkaline conditions(pH 10 and 13.5) compared to the same membranes tested at lower pHs(pH 1.5 and 5).In eonelusion,NF270 membrane outperformed Nf and NF90 membranes owing to its desirable performance of water flux and phosphorus rejection particularly under strong alkali solution.The NF270 membrane achieved 14.0 L·m^-2·h^-1 and 96.5% rejection against 10 mg·L^-1 phosphorus solution with a pH value of 13.5 at the applied pressure of 1 MPa.展开更多
Nowadays,Multi Robotic System(MRS)consisting of different robot shapes,sizes and capabilities has received significant attention from researchers and are being deployed in a variety of real-world applications.From sen...Nowadays,Multi Robotic System(MRS)consisting of different robot shapes,sizes and capabilities has received significant attention from researchers and are being deployed in a variety of real-world applications.From sensors and actuators improved by communication technologies to powerful computing systems utilizing advanced Artificial Intelligence(AI)algorithms have rapidly driven the development of MRS,so the Internet of Things(IoT)in MRS has become a new topic,namely the Internet of Robotic Things(IoRT).This paper summarizes a comprehensive survey of state-of-the-art technologies for mobile robots,including general architecture,benefits,challenges,practical applications,and future research directions.In addition,remarkable research of i)multirobot navigation,ii)network architecture,routing protocols and communications,and iii)coordination among robots as well as data analysis via external computing(cloud,fog,edge,edge-cloud)are merged with the IoRT architecture according to their applicability.Moreover,security is a long-term challenge for IoRT because of various attack vectors,security flaws,and vulnerabilities.Security threats,attacks,and existing solutions based on IoRT architectures are also under scrutiny.Moreover,the identification of environmental situations that are crucial for all types of IoRT applications,such as the detection of objects,human,and obstacles,is also critically reviewed.Finally,future research directions are given by analyzing the challenges of IoRT in mobile robots.展开更多
Objective: Labisia pumila var. alata, commonly known as 'Kacip Fatimah' or 'Selusuh Fatimah' in Southeast Asia, is traditionally used by members of the Malay community because of its post-partum medici...Objective: Labisia pumila var. alata, commonly known as 'Kacip Fatimah' or 'Selusuh Fatimah' in Southeast Asia, is traditionally used by members of the Malay community because of its post-partum medicinal properties. Its various pharmaceutical applications cause an excessive harvesting and lead to serious shortage in natural habitat. Thus, this in vitro propagation study investigated the effects of different plant growth regulators (PGRs) on in vitro leaf and stem explants of L. pumila. Methods: The capabilities of callus, shoot, and root formation were evaluated by culturing both explants on Murashige and Skoog (MS) medium supplemented with various PGRs at the concentrations of 0, 1, 3, 5, and 7 mg/L. Results: Medium supplemented with 3 mg/L indole-3-butyric acid (IBA) showed the optimal callogenesis from both leaf and stem explants with (72.34±19.55)% and (70.40±14.14)% efficacy, respectively. IBA was also found to be the most efficient PGR for root induction. A total of (50.00±7.07)% and (77.78±16.47)% of root formation were obtained from the in vitro stem and leaf explants after being cultured for (26.5±5.0) and (30.0±8.5) d in the medium supplemented with 1 and 3 mg/L of IBA, respectively. Shoot formation was only observed in stem explant, with the maximum percentage of formation ((100.00±0.00)%) that was obtained in 1 mg/L zeatin after (11.0±2.8) d of culture. Conclusions: Callus, roots, and shoots can be induced from in vitro leaf and stem explants of L. pumila through the manipulation of types and concentrations of PGRs.展开更多
Graphene oxide is a very high capacity adsorbent due to its functional groups and π-π interactions with other compounds. Adsorption capacity of graphene oxide, however, can be further enhanced by having synergistic ...Graphene oxide is a very high capacity adsorbent due to its functional groups and π-π interactions with other compounds. Adsorption capacity of graphene oxide, however, can be further enhanced by having synergistic effects through the use of mixed-matrix composite. In this study, silica-decorated graphene oxide(SGO) was used as a high-efficiency adsorbent to remove Congo red(CR) and Cadmium(Ⅱ) from aqueous solutions. The effects of solution initial concentration(20 to 120 mg/l), solution pH(pH 2 to 7), adsorption duration(0 to 140 min) and temperature(298 to 323 K) were measured in order to optimize the adsorption conditions using the SGO adsorbent. Morphological analysis indicated that the silica nanoparticles could be dispersed uniformly on the graphene oxide surfaces. The maximum capacities of adsorbent for effective removal of Cd(Ⅱ) and CR were 43.45 and 333.33 mg/g based on Freundlich and Langmuir isotherms, respectively. Langmuir and Freundlich isotherms displayed the highest values of Q max for CR and Cd(Ⅱ) adsorption in this study, which indicated monolayer adsorption of CR and multilayer adsorption of Cd(II) onto the SGO, respectively. Thermodynamic study showed that the enthalpy( H) and Gibbs free energy( G) values of the adsorption process for both pollutants were negative, suggesting that the process was spontaneous and exothermic in nature. This study showed active sites of SGO( π-π, hydroxyl, carboxyl, ketone, silane-based functional groups) contributed to an enormous enhancement in simultaneous removal of CR and Cd(Ⅱ) from an aqueous solu-tion, Therefore, SGO can be considered as a promising adsorbent for future water pollution control and removal of hazardous materials from aqueous solutions.展开更多
Polylactic acid(PLA)bioplastic is a common material used in Fused Deposition Modeling(FDM)3D printing.It is biodegradable and environmentally friendly biopolymer which made out of corn.However,it exhibits weak mechani...Polylactic acid(PLA)bioplastic is a common material used in Fused Deposition Modeling(FDM)3D printing.It is biodegradable and environmentally friendly biopolymer which made out of corn.However,it exhibits weak mechanical properties which reduced its usability as a functional prototype in a real-world application.In the present study,two PLA composites are created through coextruded with 3K carbon fibres and twisted Kevlar string(as core fibre)to form a fibre reinforced parts(FRP).The mechanical strength of printed parts was examined using ASTM D638 standard with a strain rate of 1 mm/min.It has been demonstrated that the FRPs coextruded with 3K carbon fibres had achieved significant improvement in Young’s modulus(+180.6%,9.205 GPa),ultimate tensile strength(+175.3%,103 MPa)and maximum tensile strain(+21.6%,1.833%).Although the Young’s modulus of Kevlar FRP was found to be similar to as compared to unreinforced PLA(~3.29 GPa),it has gained significant increment in terms of maximum tensile strain(+179.7%,104.64 MPa),and maximum tensile strain(+257%,5.384%).Thus,this study revealed two unique composite materials,in which the 3K carbon FRP can offer stiff and high strength structure while Kevlar FRP offers similar strength but at a higher elasticity.展开更多
The rising production of produced water from oilfields had been proven to bring detrimental environmental effects.In this study,an efficient,recyclable,and environmental-friendly reduced graphene oxide immobilizedκ-C...The rising production of produced water from oilfields had been proven to bring detrimental environmental effects.In this study,an efficient,recyclable,and environmental-friendly reduced graphene oxide immobilizedκ-Carrageenan hydrogel composite(κCaGO)was fabricated as an alternative sorbent for crude oil-in-water demulsification.Polyethyleneimine(PEI)was employed to form a stable hydrogel composite.The conditions for the immobilization of graphene oxide(GO)on PEI-modifiedκ-Carrageenan(κC)beads were optimized appropriately.An immobilization yield of 77%was attained at 2%PEI,2 h immobilization activation time,and pH 6.5.Moreover,the synthesizedκCaGO is capable of demulsification with an average demulsification efficiency of 70%.It was found that the demulsification efficiency increases with salinity andκCaGO dosage,and it deteriorates under alkaline condition.These phenomena can be attributed to the interfacial interactions betweenκCaGO and the emulsion.Furthermore,theκCaGO can be recycled to use for up to six cycles without significant leaching and degradation.As such,the synthesizedκCaGO could be further developed as a potential sorbent substitute for the separation of crude oil from produced water.展开更多
To determine the effect of dissolution on pore network development in carbonate rocks, dissolution experiments, X-Ray microtomography, and thin section analysis were conducted on argillaceous limestone and grain limes...To determine the effect of dissolution on pore network development in carbonate rocks, dissolution experiments, X-Ray microtomography, and thin section analysis were conducted on argillaceous limestone and grain limestone samples at different temperatures and constant pH, HCl concentration. The relationship between Ca^(2+) concentration and time was revealed through the experiments; pore size distribution before and after dissolution indicate that there is no correlation between the temperature and pore size variation, but pore size variation in grain limestone is more significant, indicating that the variation is mainly controlled by the heterogeneity of the rock itself(initial porosity and permeability) and the abundance of unstable minerals(related to crystal shape, size and mineral type). At different temperatures, the two kinds of carbonate rocks had very small variation in pore throat radius from 0.003 mm to 0.040 mm, which is 1.3 to 3.5 times more, 1.7 on average of the original pore throat radius. Their pore throat length varied from 0.05 mm to 0.35 mm. The minor changes in the pore throat radius, length and connectivity brought big changes to permeability of up to 1 000×10^(-3) μm^2.展开更多
In this study,Al–Zn and Al–Mg coatings were deposited on steel substrates by an arc thermal spray process.X-ray diffraction and scanning electron microscopy were used to characterize the deposited coatings and corro...In this study,Al–Zn and Al–Mg coatings were deposited on steel substrates by an arc thermal spray process.X-ray diffraction and scanning electron microscopy were used to characterize the deposited coatings and corrosion products.Open circuit potential（OCP）,electrochemical impedance spectroscopy,and potentiodynamic studies were used to assess the corrosion characteristics of these coatings after exposure according to the Society of Automotive Engineers（SAE）J2334 solution of varying durations.This solution simulates an industrial environment and contains chloride and carbonate ions that induce corrosion of the deposited coatings.However,the Al–Mg alloy coating maintained an OCP of approximately-0.911 V versus Ag/Ag Cl in the SAE J2334 solution even after 792 h of exposure.This indicates that it protects the steel sacrificially,whereas the Al–Zn coating provides only barrier-type protection through the deposition of corrosion products.The Al–Mg coating acts as a self-healing coating and provides protection by forming Mg_6Al_2（OH）_（16）CO_3（Al–Mg layered double hydroxides）.Mg_6Al_2（OH）_（16）CO_3has interlocking characteristics with a morphology of plate-like nanostructures and an ion-exchange ability that can improve the corrosion resistance properties of the coating.The presence of Zn in the corrosion products of the Al–Zn coating allows dissolution,but,at the same time,Zn_5（OH）_6（CO_3）_2and Zn_6Al_2（OH）_（16）CO_3are formed and act to reduce the corrosion rate.展开更多
Black locust(Robinia pseudoacacia L.),a species native to the eastern North America,was introduced to Europe probably in 1601 and currently extends over2.3×10~6 ha.It has become naturalized in all sub-Mediterrane...Black locust(Robinia pseudoacacia L.),a species native to the eastern North America,was introduced to Europe probably in 1601 and currently extends over2.3×10~6 ha.It has become naturalized in all sub-Mediterranean and temperate regions rivaling Populus spp.as the second most planted broadleaved tree species worldwide after Eucalyptus spp.This wide-spreading planting is because black locust is an important multipurpose species,producing wood,fodder,and a source of honey as well as bio-oil and biomass.It is also important for carbon sequestration,soil stabilization and re-vegetation of landfills,mining areas and wastelands,in biotherapy and landscaping.In Europe,black locust is drought tolerant so grows in areas with annual precipitation as low as 500-550 mm.It tolerates dry,nutrient poor soils but grows best on deep,nutrient-rich,well-drained soils.It is a fast-growing tree and the height,diameter and volume growth peak before the age of 20.It mostly regenerates vegetatively by root suckers under a simple coppice system,which is considered the most cost-effective management system.It also regenerates,but less frequently,by stool sprouts.Its early silviculture in production forests includes release cutting to promote root suckers rather than stool shoots,and cleaning-respacing to remove low-quality stems,reduce the number of shoots per stool,and adjust spacing between root suckers.In addition,early,moderate and frequent thinning as well as limited pruning are carried out focusing on crop trees.The species is regarded as invasive in several European countries and its range here is expected to expand under predicted climate changes.展开更多
According to the New Energy and Industry Technology Development Organization(NEDO)road map 2017 of Japan,polymer electrolyte fuel cell(PEFC)system is required to be operated at 90°C and 100°C for stationary ...According to the New Energy and Industry Technology Development Organization(NEDO)road map 2017 of Japan,polymer electrolyte fuel cell(PEFC)system is required to be operated at 90°C and 100°C for stationary and mobility applications,respectively.However,the general PEFC,which has Nafion membrane is operated within the temperature range between 60°C and 80°C.It is important to understand the temperature distribution in a PEFC cell for analyzing performance on working life span of PEFC.This study focuses on the combination of thin polymer electrolyte membrane(PEM)and thin gas diffusion layer(GDL)to improve power generation performance under relatively higher temperature operation conditions.In addition,this study also focuses on effect of micro porous layer(MPL),which can promote the mass transfer,over temperature distribution.The key aim of this study is to analyze impact of MPL of temperature distribution on the reaction surface(Treact)of a cell of PEFC using thin PEM and GDL with variations of H2 and O2 supply flow rates and their relative humidity(RH)with changing the initial operating temperature(Tini)from 80°C to 100°C.As a result,the distribution of Treact without MPL,for anode and cathode at 80%RH and Tini at 80°C and 90°C,is higher than normal conditions.There is a small difference in temperature distribution among different RH conditions with MPL.The distributions of Treact are relatively flat and almost the same among different RH conditions without MPL at Tini=100°C,while the distributions of Treact with MPL are almost the same among different RH conditions.This study is revealed that more even temperature distribution and higher power generation performance can be obtained in the case without MPL compared to the case with MPL.展开更多
Border Gateway Protocol(BGP)is a standard inter-domain routing protocol for the Internet that conveys network layer reachability information and establishes routes to different destinations.The BGP protocol exhibits s...Border Gateway Protocol(BGP)is a standard inter-domain routing protocol for the Internet that conveys network layer reachability information and establishes routes to different destinations.The BGP protocol exhibits security design defects,such as an unconditional trust mechanism and the default acceptance of BGP route announcements from peers by BGP neighboring nodes,easily triggering prefix hijacking,path forgery,route leakage,and other BGP security threats.Meanwhile,the traditional BGP security mechanism,relying on a public key infrastructure,faces issues like a single point of failure and a single point of trust.The decentralization,anti-tampering,and traceability advantages of blockchain offer new solution ideas for constructing secure and trusted inter-domain routing mechanisms.In this paper,we summarize the characteristics of BGP protocol in detail,sort out the BGP security threats and their causes.Additionally,we analyze the shortcomings of the traditional BGP security mechanism and comprehensively evaluate existing blockchain-based solutions to address the above problems and validate the reliability and effectiveness of blockchain-based BGP security methods in mitigating BGP security threats.Finally,we discuss the challenges posed by BGP security problems and outline prospects for future research.展开更多
A study was conducted by collecting eight seepage water samples that drain through the sedimentary rocks, mainly sandstone and shale, to evaluate the hydro- geochemical characteristics. The collected samples were anal...A study was conducted by collecting eight seepage water samples that drain through the sedimentary rocks, mainly sandstone and shale, to evaluate the hydro- geochemical characteristics. The collected samples were analyzed for physico-chemical parameters using standard procedures. Three water types were identified in the Piper plot and the hydrogeochemical evolution starts from a Ca- C1 facies （type 1） via mixed Ca-Mg-C1 and Ca-Na-HCO3 facies （type 2） to Na-C1 facies （type 3）. Increasing trend of electrical conductivity （EC） values were observed from type 1 water to type 3 water. Lower ionic concentrations with an average EC value of 35.7 kts/cm in Ca-C1 facies indicate the recharge water by monsoonal rainfall, and ion exchange/weathering process is reflected in the mixing zone. Higher ionic concentration with an average EC value of 399 kts/cm is noted in Na-C1 facies, which indicates the ion exchange during water-rock interaction. Higher log pCO2 values are also found in this facies, revealing the longer residence time of seepage water in the rock matrix, which release more ions into the water. The relative mobility of elements during weathering suggest that the order of mobility in both sandstone and shale is Na 〉 Ca 〉 Mg 〉 K. It was observed that thehydrogeochemistry of seepage water is mainly controlled by the bedrock geology.展开更多
基金support by the Shanghai Engineering Research Center for Shallow Geothermal Energy(DRZX-202306)Shaanxi Coal Geology Group Co.,Ltd.(SMDZ-ZD2024-23)+4 种基金Key Laboratory of Coal Resources Exploration and Comprehensive Utilization,Ministry of Natural Resources,China(ZP2020-1)Shaanxi Investment Group Co.,Ltd.(SIGC2023-KY-05)Key Research and Development Projects of Shaanxi Province(2023-GHZD-54)Shaanxi Qinchuangyuan Scientist+Engineer Team Construction Project(2022KXJ-049)China Postdoctoral Science Foundation(2023M742802,2024T170721).
文摘Geothermal energy,a form of renewable energy,has been extensively utilized for building heating.However,there is a lack of detailed comparative studies on the use of shallow and medium-deep geothermal energy in building energy systems,which are essential for decision-making.Therefore,this paper presents a comparative study of the performance and economic analysis of shallow and medium-deep borehole heat exchanger heating systems.Based on the geological parameters of Xi’an,China and commonly used borehole heat exchanger structures,numerical simulationmethods are employed to analyze performance and economic efficiency.The results indicate that increasing the spacing between shallow borehole heat exchangers can effectively reduce thermal interference between the pipes and improve heat extraction performance.As the flow rate increases,the outlet water temperature ranges from 279.3 to 279.7 K,with heat extraction power varying between 595 and 609 W.For medium-deep borehole heat exchangers,performance predictions show that a higher flow rate results in greater heat extraction power.However,when the flow rate exceeds 30 m^(3)/h,further increases in flow rate have only a minor effect on enhancing heat extraction power.Additionally,the economic analysis reveals that the payback period for shallow geothermal heating systems ranges from 10 to 11 years,while for medium-deep geothermal heating systems,it varies more widely from 3 to 25 years.Therefore,the payback period for medium-deep geothermal heating systems is more significantly influenced by operational and installation parameters,and optimizing these parameters can considerably shorten the payback period.The results of this study are expected to provide valuable insights into the efficient and cost-effective utilization of geothermal energy for building heating.
基金supported by grants from the Biotechnology and Biological Sciences Research Council(Nos.BBSRC LO21071/and BB/L00609X/1)UK Regenerative Medicine Platform Hub Acellular Approaches for Therapeutic Delivery(No.MR/K026682/1)+3 种基金Acellular Hub,SMART Materials 3D Architecture(No.MR/R015651/1)the UK Regenerative Medicine Platform(No.MR/L012626/1 Southampton Imaging)to ROCOMRCAMED Regenerative Medicine and Stem Cell Research Initiative(No.MR/V00543X/1)to JID,ROCO and YHKGC acknowledges funding from AIRC Aldi Fellowship under grant agreement No.25412.
文摘Autograft or metal implants are routinely used in skeletal repair.However,they fail to provide long-term clinical resolution,necessitating a functional biomimetic tissue engineering alternative.The use of native human bone tissue for synthesizing a biomimeticmaterial inkfor three-dimensional(3D)bioprintingof skeletal tissueis anattractivestrategyfor tissueregeneration.Thus,human bone extracellular matrix(bone-ECM)offers an exciting potential for the development of an appropriate microenvironment for human bone marrow stromal cells(HBMSCs)to proliferate and differentiate along the osteogenic lineage.In this study,we engineered a novel material ink(LAB)by blending human bone-ECM(B)with nanoclay(L,Laponite®)and alginate(A)polymers using extrusion-based deposition.The inclusion of the nanofiller and polymeric material increased the rheology,printability,and drug retention properties and,critically,the preservation of HBMSCs viability upon printing.The composite of human bone-ECM-based 3D constructs containing vascular endothelial growth factor(VEGF)enhanced vascularization after implantation in an ex vivo chick chorioallantoic membrane(CAM)model.The inclusion of bone morphogenetic protein-2(BMP-2)with the HBMSCs further enhanced vascularization and mineralization after only seven days.This study demonstrates the synergistic combination of nanoclay with biomimetic materials(alginate and bone-ECM)to support the formation of osteogenic tissue both in vitro and ex vivo and offers a promising novel 3D bioprinting approach to personalized skeletal tissue repair.
文摘The influence of Mo and ZrO_(2)nanoparticles addition on the interfacial properties and shear strength of Sn58Bi solder joint was investigated.The interfacial microstructures of Sn58Bi/Cu,Sn58Bi+Mo/Cu and Sn58Bi+ZrO_(2)/Cu solder joints were analysed using a scanning electron microscope(SEM)coupled with energy dispersive X-ray(EDX)and the X-ray diffraction(XRD).Intermetallic compounds(IMCs)of MoSn_(2)are detected in the Sn58Bi+Mo/Cu solder joint,while SnZr,Zr_(5)Sn_(3),ZrCu and ZrSn_(2)are detected in Sn58Bi+ZrO_(2)/Cu solder joint.IMC layers for both composite solders comprise of Cu_(6)Sn_(5) and Cu_(3)Sn.The SEM images of these layers were used to measure the IMC layer’s thickness.The average IMC layer’s thickness is 1.4431μm for Sn58Bi+Mo/Cu and 0.9112μm for Sn58Bi+ZrO_(2)/Cu solder joints.Shear strength of the solder joints was investigated via the single shear lap test method.The average maximum load and shear stress of the Sn58Bi+Mo/Cu and Sn58Bi+ZrO_(2)/Cu solder joints are increased by 33%and 69%,respectively,as compared to those of the Sn58Bi/Cu solder joint.By comparing both composite solder joints,the latter prevails better as adding smaller sized ZrO_(2)nanoparticles improves the interfacial properties granting a stronger solder joint.
基金supported by the National Natural Science Foundation of China (21908132)。
文摘Phenol-containing wastewater is typical organic wastewater,and its treatment is arduous.An advanced method to treat this type of wastewater is persulfate activation.Environmentally friendly ceriummanganese composite oxide materials were synthesized by hydrothermal method and applied to the phenol degradation process.Various ratios of cerium and manganese,as well as the amount of sodium hydroxide,were investigated.The solid solutions of cerium and manganese were formed and confirmed by X-ray diffraction(XRD) and transmission electron microscopy(TEM).H_(2)-temperature programmed reduction(H_(2)-TPR) and X-ray photoelectron spectroscopy(XPS) were utilized to analyze the synergistic effect of cerium and manganese.It is found that there is a transformation between Ce^(4+)/Ce^(3+) and Mn^(2+)/Mn^(3+),which makes the material more trivalent manganese and thereby increases the catalytic activity.The effect of materials in catalyzing phenol degradation by peroxodisulfate(PDS) under various preparation conditions is discussed and high-effciency removal of phenol can be achieved and the removal rate at 180 min is close to 100%.The kinetic of this process was investigated and activation energy of phenol degradation is 62,35 kJ/mol.The degradation pathway of phenol was studied and it is found that PDS can be activated by low metal ions and the OH and SO_(4·)^(-)radicals play crucial roles according to the quenching experiments.
基金Deanship of Scientific Research at King Khalid University for funding this work through a large group Research Project under Grant Number RGP.2/373/45.
文摘The DNS over HTTPS(Hypertext Transfer Protocol Secure)(DoH)is a new technology that encrypts DNS traffic,enhancing the privacy and security of end-users.However,the adoption of DoH is still facing several research challenges,such as ensuring security,compatibility,standardization,performance,privacy,and increasing user awareness.DoH significantly impacts network security,including better end-user privacy and security,challenges for network security professionals,increasing usage of encrypted malware communication,and difficulty adapting DNS-based security measures.Therefore,it is important to understand the impact of DoH on network security and develop newprivacy-preserving techniques to allowthe analysis of DoH traffic without compromising user privacy.This paper provides an in-depth analysis of the effects of DoH on cybersecurity.We discuss various techniques for detecting DoH tunneling and identify essential research challenges that need to be addressed in future security studies.Overall,this paper highlights the need for continued research and development to ensure the effectiveness of DoH as a tool for improving privacy and security.
文摘This study is an extension of the previous work done with ARS-680 Environmental Chamber. Drying is a complex operation that demands much energy and time. Drying is essentially important for preservation of ginger rhizome. Drying of ginger was modeled, and then the effective diffusion coefficient and activation energy were determined. For this purpose, the experiments were done at six levels of varied temperatures: 10°C, 20°C, 30°C, 40°C, 50°C and 60°C. The values of effective diffusion coefficients obtained in this work for the variously treated ginger rhizomes closely agreed with the average effective diffusion coefficients of other notable authors who determined the drying kinetics and convective heat transfer coefficients of ginger slices.
基金supported by the DEEPCOBOT project under Grant 306640/O70 funded by the Research Council of Norway.
文摘This paper studies motor joint control of a 4-degree-of-freedom(DoF)robotic manipulator using learning-based Adaptive Dynamic Programming(ADP)approach.The manipulator’s dynamics are modelled as an open-loop 4-link serial kinematic chain with 4 Degrees of Freedom(DoF).Decentralised optimal controllers are designed for each link using ADP approach based on a set of cost matrices and data collected from exploration trajectories.The proposed control strategy employs an off-line,off-policy iterative approach to derive four optimal control policies,one for each joint,under exploration strategies.The objective of the controller is to control the position of each joint.Simulation and experimental results show that four independent optimal controllers are found,each under similar exploration strategies,and the proposed ADP approach successfully yields optimal linear control policies despite the presence of these complexities.The experimental results conducted on the Quanser Qarm robotic platform demonstrate the effectiveness of the proposed ADP controllers in handling significant dynamic nonlinearities,such as actuation limitations,output saturation,and filter delays.
基金supported by the Nuclear Safety Research Association(NSRA),Japan
文摘Objective: Heavy ion beam, which has emerged as a new mutagen in the mutation breeding of crops and ornamental plants, is expected to result in the induction of novel mutations. This study investigates the morphological and biochemical responses of Oryza sativa toward different doses of carbon ion beam irradiation. Methods: In this study, the dry seeds of O. sativa were irradiated at 0, 20, 40, 60, 80, 100, and 120 Gy, followed by in-vitro germination under controlled conditions. Morphological and biochemical studies were conducted to investigate the morphological and physiological responses of O. sativa towards ion beam irradiation. Results: The study demonstrated that low doses(10 Gy) of ion beam have a stimulating effect on the height, root length, and fresh weight of the plantlets but not on the number of leaves. Meanwhile, doses higher than 10 Gy caused reductions in all the morphological parameters studied as compared to the control samples. The highest total soluble protein content [(2.11±0.47) mg/g FW] was observed in plantlets irradiated at 20 Gy. All irradiated plantlets were found to have 0.85% to 58.32% higher specific activity of peroxidase as compared to the control samples. The present study also revealed that low doses of ion beam(10 and 20 Gy) had negligible effect on the total chlorophyll content of O. sativa plantlets while 40 Gy had a stimulating effect on the chlorophyll content. Plantlets irradiated between 40 to 120 Gy were shown to be 0.38% to 9.98% higher in total soluble nitrogen content which, however, was not significantly different from the control samples. Conclusions: Carbon ion beam irradiation administered at low to moderate doses of 10 to 40 Gy may induce O. sativa mutants with superior characteristics.
基金Supported by the Ministry of Education(MoE)Malaysia to Universiti Teknologi Malaysia(UTM)under the grant of Higher Institution Centre of Excellence(HICoE)(R.J090301.7846.4J175)Universiti Tunku Abdul Rahman(UTAR)under the research publication scheme(6251/K02)
文摘In this study,a quantitative performance of three commercial polyamide nanofiltration(NF) membranes(i.e.,NF,NF90,and NF270) for phosphorus removal under different feed conditions was investigated.The experiments were conducted at different feed phosphorus concentrations(2.5,5,10,and 15 mg·L^-1) and elevated pHs(pH 1.5,5,10,and 13.5) at a constant feed pressure of 1 MPa using a dead-end filtration cell.Membrane rejection against total phosphorus generally increased with increasing phosphorus concentration regardless of membrane type.In contrast,the permeate flux for all the membranes only decreased slightly with increasing phosphorus concentration.The results also showed that the phosphorus rejections improved while water flux remained almost unchanged with increasing feed solution pH.When the three membranes were exposed to strong pHs(pH 1.5 and 13.5) for a longer duration(up to 6 weeks)it was found that the rejection capability and water flux of the membranes remained very similar throughout the duration,except for NF membrane with marginal decrement in phosphorus rejection.Adsorption study also revealed that more phosphorus was adsorbed onto the membrane structure at alkaline conditions(pH 10 and 13.5) compared to the same membranes tested at lower pHs(pH 1.5 and 5).In eonelusion,NF270 membrane outperformed Nf and NF90 membranes owing to its desirable performance of water flux and phosphorus rejection particularly under strong alkali solution.The NF270 membrane achieved 14.0 L·m^-2·h^-1 and 96.5% rejection against 10 mg·L^-1 phosphorus solution with a pH value of 13.5 at the applied pressure of 1 MPa.
基金This research was supported by the Ministry of Higher Education,Malaysia(MoHE)through Fundamental Research Grant Scheme(FRGS/1/2021/TK0/UTAR/02/9)The work was also supported by the Universiti Tunku Abdul Rahman(UTAR),Malaysia,under UTAR Research Fund(UTARRF)(IPSR/RMC/UTARRF/2021C1/T05).
文摘Nowadays,Multi Robotic System(MRS)consisting of different robot shapes,sizes and capabilities has received significant attention from researchers and are being deployed in a variety of real-world applications.From sensors and actuators improved by communication technologies to powerful computing systems utilizing advanced Artificial Intelligence(AI)algorithms have rapidly driven the development of MRS,so the Internet of Things(IoT)in MRS has become a new topic,namely the Internet of Robotic Things(IoRT).This paper summarizes a comprehensive survey of state-of-the-art technologies for mobile robots,including general architecture,benefits,challenges,practical applications,and future research directions.In addition,remarkable research of i)multirobot navigation,ii)network architecture,routing protocols and communications,and iii)coordination among robots as well as data analysis via external computing(cloud,fog,edge,edge-cloud)are merged with the IoRT architecture according to their applicability.Moreover,security is a long-term challenge for IoRT because of various attack vectors,security flaws,and vulnerabilities.Security threats,attacks,and existing solutions based on IoRT architectures are also under scrutiny.Moreover,the identification of environmental situations that are crucial for all types of IoRT applications,such as the detection of objects,human,and obstacles,is also critically reviewed.Finally,future research directions are given by analyzing the challenges of IoRT in mobile robots.
文摘Objective: Labisia pumila var. alata, commonly known as 'Kacip Fatimah' or 'Selusuh Fatimah' in Southeast Asia, is traditionally used by members of the Malay community because of its post-partum medicinal properties. Its various pharmaceutical applications cause an excessive harvesting and lead to serious shortage in natural habitat. Thus, this in vitro propagation study investigated the effects of different plant growth regulators (PGRs) on in vitro leaf and stem explants of L. pumila. Methods: The capabilities of callus, shoot, and root formation were evaluated by culturing both explants on Murashige and Skoog (MS) medium supplemented with various PGRs at the concentrations of 0, 1, 3, 5, and 7 mg/L. Results: Medium supplemented with 3 mg/L indole-3-butyric acid (IBA) showed the optimal callogenesis from both leaf and stem explants with (72.34±19.55)% and (70.40±14.14)% efficacy, respectively. IBA was also found to be the most efficient PGR for root induction. A total of (50.00±7.07)% and (77.78±16.47)% of root formation were obtained from the in vitro stem and leaf explants after being cultured for (26.5±5.0) and (30.0±8.5) d in the medium supplemented with 1 and 3 mg/L of IBA, respectively. Shoot formation was only observed in stem explant, with the maximum percentage of formation ((100.00±0.00)%) that was obtained in 1 mg/L zeatin after (11.0±2.8) d of culture. Conclusions: Callus, roots, and shoots can be induced from in vitro leaf and stem explants of L. pumila through the manipulation of types and concentrations of PGRs.
基金NPRP Grant # 10-0127-170270 from Qatar National Research FundMI-2017-002 grant from Universiti Kebangsaan Malaysia。
文摘Graphene oxide is a very high capacity adsorbent due to its functional groups and π-π interactions with other compounds. Adsorption capacity of graphene oxide, however, can be further enhanced by having synergistic effects through the use of mixed-matrix composite. In this study, silica-decorated graphene oxide(SGO) was used as a high-efficiency adsorbent to remove Congo red(CR) and Cadmium(Ⅱ) from aqueous solutions. The effects of solution initial concentration(20 to 120 mg/l), solution pH(pH 2 to 7), adsorption duration(0 to 140 min) and temperature(298 to 323 K) were measured in order to optimize the adsorption conditions using the SGO adsorbent. Morphological analysis indicated that the silica nanoparticles could be dispersed uniformly on the graphene oxide surfaces. The maximum capacities of adsorbent for effective removal of Cd(Ⅱ) and CR were 43.45 and 333.33 mg/g based on Freundlich and Langmuir isotherms, respectively. Langmuir and Freundlich isotherms displayed the highest values of Q max for CR and Cd(Ⅱ) adsorption in this study, which indicated monolayer adsorption of CR and multilayer adsorption of Cd(II) onto the SGO, respectively. Thermodynamic study showed that the enthalpy( H) and Gibbs free energy( G) values of the adsorption process for both pollutants were negative, suggesting that the process was spontaneous and exothermic in nature. This study showed active sites of SGO( π-π, hydroxyl, carboxyl, ketone, silane-based functional groups) contributed to an enormous enhancement in simultaneous removal of CR and Cd(Ⅱ) from an aqueous solu-tion, Therefore, SGO can be considered as a promising adsorbent for future water pollution control and removal of hazardous materials from aqueous solutions.
基金This project is funded by Universiti Tunku Abdul Rahman through the grant number IPSR/RMC/UTARRF/2018-C2/T02.
文摘Polylactic acid(PLA)bioplastic is a common material used in Fused Deposition Modeling(FDM)3D printing.It is biodegradable and environmentally friendly biopolymer which made out of corn.However,it exhibits weak mechanical properties which reduced its usability as a functional prototype in a real-world application.In the present study,two PLA composites are created through coextruded with 3K carbon fibres and twisted Kevlar string(as core fibre)to form a fibre reinforced parts(FRP).The mechanical strength of printed parts was examined using ASTM D638 standard with a strain rate of 1 mm/min.It has been demonstrated that the FRPs coextruded with 3K carbon fibres had achieved significant improvement in Young’s modulus(+180.6%,9.205 GPa),ultimate tensile strength(+175.3%,103 MPa)and maximum tensile strain(+21.6%,1.833%).Although the Young’s modulus of Kevlar FRP was found to be similar to as compared to unreinforced PLA(~3.29 GPa),it has gained significant increment in terms of maximum tensile strain(+179.7%,104.64 MPa),and maximum tensile strain(+257%,5.384%).Thus,this study revealed two unique composite materials,in which the 3K carbon FRP can offer stiff and high strength structure while Kevlar FRP offers similar strength but at a higher elasticity.
基金The authors would like to acknowledge for the financial supports given by Fundamental Research Grant Scheme (FRGS/1/2019/TK02/CURTIN/03/2) from Ministry of Higher Education (MOHE),Malaysia.
文摘The rising production of produced water from oilfields had been proven to bring detrimental environmental effects.In this study,an efficient,recyclable,and environmental-friendly reduced graphene oxide immobilizedκ-Carrageenan hydrogel composite(κCaGO)was fabricated as an alternative sorbent for crude oil-in-water demulsification.Polyethyleneimine(PEI)was employed to form a stable hydrogel composite.The conditions for the immobilization of graphene oxide(GO)on PEI-modifiedκ-Carrageenan(κC)beads were optimized appropriately.An immobilization yield of 77%was attained at 2%PEI,2 h immobilization activation time,and pH 6.5.Moreover,the synthesizedκCaGO is capable of demulsification with an average demulsification efficiency of 70%.It was found that the demulsification efficiency increases with salinity andκCaGO dosage,and it deteriorates under alkaline condition.These phenomena can be attributed to the interfacial interactions betweenκCaGO and the emulsion.Furthermore,theκCaGO can be recycled to use for up to six cycles without significant leaching and degradation.As such,the synthesizedκCaGO could be further developed as a potential sorbent substitute for the separation of crude oil from produced water.
基金sponsored by PETRONAS and YUTP (Yayasan Universiti Teknologi PETRONAS)
文摘To determine the effect of dissolution on pore network development in carbonate rocks, dissolution experiments, X-Ray microtomography, and thin section analysis were conducted on argillaceous limestone and grain limestone samples at different temperatures and constant pH, HCl concentration. The relationship between Ca^(2+) concentration and time was revealed through the experiments; pore size distribution before and after dissolution indicate that there is no correlation between the temperature and pore size variation, but pore size variation in grain limestone is more significant, indicating that the variation is mainly controlled by the heterogeneity of the rock itself(initial porosity and permeability) and the abundance of unstable minerals(related to crystal shape, size and mineral type). At different temperatures, the two kinds of carbonate rocks had very small variation in pore throat radius from 0.003 mm to 0.040 mm, which is 1.3 to 3.5 times more, 1.7 on average of the original pore throat radius. Their pore throat length varied from 0.05 mm to 0.35 mm. The minor changes in the pore throat radius, length and connectivity brought big changes to permeability of up to 1 000×10^(-3) μm^2.
基金supported by the research fund of Hanyang University (No. HY-2014-P)
文摘In this study,Al–Zn and Al–Mg coatings were deposited on steel substrates by an arc thermal spray process.X-ray diffraction and scanning electron microscopy were used to characterize the deposited coatings and corrosion products.Open circuit potential（OCP）,electrochemical impedance spectroscopy,and potentiodynamic studies were used to assess the corrosion characteristics of these coatings after exposure according to the Society of Automotive Engineers（SAE）J2334 solution of varying durations.This solution simulates an industrial environment and contains chloride and carbonate ions that induce corrosion of the deposited coatings.However,the Al–Mg alloy coating maintained an OCP of approximately-0.911 V versus Ag/Ag Cl in the SAE J2334 solution even after 792 h of exposure.This indicates that it protects the steel sacrificially,whereas the Al–Zn coating provides only barrier-type protection through the deposition of corrosion products.The Al–Mg coating acts as a self-healing coating and provides protection by forming Mg_6Al_2（OH）_（16）CO_3（Al–Mg layered double hydroxides）.Mg_6Al_2（OH）_（16）CO_3has interlocking characteristics with a morphology of plate-like nanostructures and an ion-exchange ability that can improve the corrosion resistance properties of the coating.The presence of Zn in the corrosion products of the Al–Zn coating allows dissolution,but,at the same time,Zn_5（OH）_6（CO_3）_2and Zn_6Al_2（OH）_（16）CO_3are formed and act to reduce the corrosion rate.
基金funded by any source but carried out voluntarily by a group of people (university staff,researchers,practitioners) interested in the ecology,growth and yield and management of black locust
文摘Black locust(Robinia pseudoacacia L.),a species native to the eastern North America,was introduced to Europe probably in 1601 and currently extends over2.3×10~6 ha.It has become naturalized in all sub-Mediterranean and temperate regions rivaling Populus spp.as the second most planted broadleaved tree species worldwide after Eucalyptus spp.This wide-spreading planting is because black locust is an important multipurpose species,producing wood,fodder,and a source of honey as well as bio-oil and biomass.It is also important for carbon sequestration,soil stabilization and re-vegetation of landfills,mining areas and wastelands,in biotherapy and landscaping.In Europe,black locust is drought tolerant so grows in areas with annual precipitation as low as 500-550 mm.It tolerates dry,nutrient poor soils but grows best on deep,nutrient-rich,well-drained soils.It is a fast-growing tree and the height,diameter and volume growth peak before the age of 20.It mostly regenerates vegetatively by root suckers under a simple coppice system,which is considered the most cost-effective management system.It also regenerates,but less frequently,by stool sprouts.Its early silviculture in production forests includes release cutting to promote root suckers rather than stool shoots,and cleaning-respacing to remove low-quality stems,reduce the number of shoots per stool,and adjust spacing between root suckers.In addition,early,moderate and frequent thinning as well as limited pruning are carried out focusing on crop trees.The species is regarded as invasive in several European countries and its range here is expected to expand under predicted climate changes.
基金This work is supported by Mie Prefecture IndustrialResearch Institute and the authors gratefullyacknowledge.
文摘According to the New Energy and Industry Technology Development Organization(NEDO)road map 2017 of Japan,polymer electrolyte fuel cell(PEFC)system is required to be operated at 90°C and 100°C for stationary and mobility applications,respectively.However,the general PEFC,which has Nafion membrane is operated within the temperature range between 60°C and 80°C.It is important to understand the temperature distribution in a PEFC cell for analyzing performance on working life span of PEFC.This study focuses on the combination of thin polymer electrolyte membrane(PEM)and thin gas diffusion layer(GDL)to improve power generation performance under relatively higher temperature operation conditions.In addition,this study also focuses on effect of micro porous layer(MPL),which can promote the mass transfer,over temperature distribution.The key aim of this study is to analyze impact of MPL of temperature distribution on the reaction surface(Treact)of a cell of PEFC using thin PEM and GDL with variations of H2 and O2 supply flow rates and their relative humidity(RH)with changing the initial operating temperature(Tini)from 80°C to 100°C.As a result,the distribution of Treact without MPL,for anode and cathode at 80%RH and Tini at 80°C and 90°C,is higher than normal conditions.There is a small difference in temperature distribution among different RH conditions with MPL.The distributions of Treact are relatively flat and almost the same among different RH conditions without MPL at Tini=100°C,while the distributions of Treact with MPL are almost the same among different RH conditions.This study is revealed that more even temperature distribution and higher power generation performance can be obtained in the case without MPL compared to the case with MPL.
基金the National Natural Science Foundation of China,GrantNumbers(62272007,62001007)the Natural Science Foundation of Beijing,GrantNumbers(4234083,4212018)The authors also acknowledge the support from King Khalid University for funding this research through the Large Group Project under Grant Number RGP.2/373/45.
文摘Border Gateway Protocol(BGP)is a standard inter-domain routing protocol for the Internet that conveys network layer reachability information and establishes routes to different destinations.The BGP protocol exhibits security design defects,such as an unconditional trust mechanism and the default acceptance of BGP route announcements from peers by BGP neighboring nodes,easily triggering prefix hijacking,path forgery,route leakage,and other BGP security threats.Meanwhile,the traditional BGP security mechanism,relying on a public key infrastructure,faces issues like a single point of failure and a single point of trust.The decentralization,anti-tampering,and traceability advantages of blockchain offer new solution ideas for constructing secure and trusted inter-domain routing mechanisms.In this paper,we summarize the characteristics of BGP protocol in detail,sort out the BGP security threats and their causes.Additionally,we analyze the shortcomings of the traditional BGP security mechanism and comprehensively evaluate existing blockchain-based solutions to address the above problems and validate the reliability and effectiveness of blockchain-based BGP security methods in mitigating BGP security threats.Finally,we discuss the challenges posed by BGP security problems and outline prospects for future research.
基金University of Malaya for the rock analysis by payment basis through RPI fund
文摘A study was conducted by collecting eight seepage water samples that drain through the sedimentary rocks, mainly sandstone and shale, to evaluate the hydro- geochemical characteristics. The collected samples were analyzed for physico-chemical parameters using standard procedures. Three water types were identified in the Piper plot and the hydrogeochemical evolution starts from a Ca- C1 facies （type 1） via mixed Ca-Mg-C1 and Ca-Na-HCO3 facies （type 2） to Na-C1 facies （type 3）. Increasing trend of electrical conductivity （EC） values were observed from type 1 water to type 3 water. Lower ionic concentrations with an average EC value of 35.7 kts/cm in Ca-C1 facies indicate the recharge water by monsoonal rainfall, and ion exchange/weathering process is reflected in the mixing zone. Higher ionic concentration with an average EC value of 399 kts/cm is noted in Na-C1 facies, which indicates the ion exchange during water-rock interaction. Higher log pCO2 values are also found in this facies, revealing the longer residence time of seepage water in the rock matrix, which release more ions into the water. The relative mobility of elements during weathering suggest that the order of mobility in both sandstone and shale is Na 〉 Ca 〉 Mg 〉 K. It was observed that thehydrogeochemistry of seepage water is mainly controlled by the bedrock geology.
