This paper studies motor joint control of a 4-degree-of-freedom(DoF)robotic manipulator using learning-based Adaptive Dynamic Programming(ADP)approach.The manipulator’s dynamics are modelled as an open-loop 4-link se...This paper studies motor joint control of a 4-degree-of-freedom(DoF)robotic manipulator using learning-based Adaptive Dynamic Programming(ADP)approach.The manipulator’s dynamics are modelled as an open-loop 4-link serial kinematic chain with 4 Degrees of Freedom(DoF).Decentralised optimal controllers are designed for each link using ADP approach based on a set of cost matrices and data collected from exploration trajectories.The proposed control strategy employs an off-line,off-policy iterative approach to derive four optimal control policies,one for each joint,under exploration strategies.The objective of the controller is to control the position of each joint.Simulation and experimental results show that four independent optimal controllers are found,each under similar exploration strategies,and the proposed ADP approach successfully yields optimal linear control policies despite the presence of these complexities.The experimental results conducted on the Quanser Qarm robotic platform demonstrate the effectiveness of the proposed ADP controllers in handling significant dynamic nonlinearities,such as actuation limitations,output saturation,and filter delays.展开更多
Geothermal energy,a form of renewable energy,has been extensively utilized for building heating.However,there is a lack of detailed comparative studies on the use of shallow and medium-deep geothermal energy in buildi...Geothermal energy,a form of renewable energy,has been extensively utilized for building heating.However,there is a lack of detailed comparative studies on the use of shallow and medium-deep geothermal energy in building energy systems,which are essential for decision-making.Therefore,this paper presents a comparative study of the performance and economic analysis of shallow and medium-deep borehole heat exchanger heating systems.Based on the geological parameters of Xi’an,China and commonly used borehole heat exchanger structures,numerical simulationmethods are employed to analyze performance and economic efficiency.The results indicate that increasing the spacing between shallow borehole heat exchangers can effectively reduce thermal interference between the pipes and improve heat extraction performance.As the flow rate increases,the outlet water temperature ranges from 279.3 to 279.7 K,with heat extraction power varying between 595 and 609 W.For medium-deep borehole heat exchangers,performance predictions show that a higher flow rate results in greater heat extraction power.However,when the flow rate exceeds 30 m^(3)/h,further increases in flow rate have only a minor effect on enhancing heat extraction power.Additionally,the economic analysis reveals that the payback period for shallow geothermal heating systems ranges from 10 to 11 years,while for medium-deep geothermal heating systems,it varies more widely from 3 to 25 years.Therefore,the payback period for medium-deep geothermal heating systems is more significantly influenced by operational and installation parameters,and optimizing these parameters can considerably shorten the payback period.The results of this study are expected to provide valuable insights into the efficient and cost-effective utilization of geothermal energy for building heating.展开更多
Creep and anelastic backflow behaviors of pure copper （4N Cu） with grain size dg=40 μm were investigated at low temperatures of T〈0.3Tm （Tm is melting point） and ultra-low creep rates of ε≤1×10^-10 s^-1 b...Creep and anelastic backflow behaviors of pure copper （4N Cu） with grain size dg=40 μm were investigated at low temperatures of T〈0.3Tm （Tm is melting point） and ultra-low creep rates of ε≤1×10^-10 s^-1 by a high strain-resolution measurement （the helicoid spring specimen technique）. Analysis of creep data was based on the scaling factors of creep curves instead of the conventional extrapolated steady-state creep rate. Power-law creep equation is suggested to be the best for describing the primary transient creep behavior, because the pre-parameter does not apparently change with elapsed time. The observed anelastic strains are 1/6 of the calculated elastic strains, and linear viscous behavior was identified from the logarithm plot of the anelastic strain rate versus anelastic strain （slope equals 1）. Therefore, the creep anelasticity is suggested to be due to the unbowing of there-dimensional network of dislocations.展开更多
Two types of cyanobacteria of the genus Arthrospira（commonly known as Spirulina） were tested for biosorption of cerium（III） ions from aqueous solutions. An endemic type（ES） found in the northern Negev desert, Is...Two types of cyanobacteria of the genus Arthrospira（commonly known as Spirulina） were tested for biosorption of cerium（III） ions from aqueous solutions. An endemic type（ES） found in the northern Negev desert, Israel, and a commercial powder（CS） were used in this study. Biosorption was evaluated as a function of p H, contact time, initial metal concentration, number of sorption-desorption cycles, and salt concentration. The optimum p H range for biosorption was found to be 5.0–5.5. The kinetic characteristics of both Spirulina types were found to be highly compatible with a pseudo-second order kinetic model. The adsorption isotherms of both types were found to be well-suited to Langmuir and Freundlich adsorption isotherms. Maximum biosorption uptakes, according to the Langmuir model, were 18.1 and 38.2 mg/g, for ES and CS, respectively. Sodium chloride concentrations of up to 5 g/L had a minor effect on cerium biosorption. Desorption efficiency was found to be greater than 97% with 0.1 mol/L HNO_3 after three sorption-desorption cycles, without significant loss in the biosorption capacity. The results indicated the feasibility of cerium recovery from industrial wastes using Spirulina biomass.展开更多
Novel characteristics of graphene have captured great attention of researchers for energy technology applications.Incorporation of graphene related hybrid and composite materials have demonstrated high performance and...Novel characteristics of graphene have captured great attention of researchers for energy technology applications.Incorporation of graphene related hybrid and composite materials have demonstrated high performance and durability for fuel cell energy conversion devices.This article overviews graphene based materials for fuel cell technology applications such as electrodes additives,bipolar plates and proton conducting electrolyte membrane.The graphene dispersion over electrodes has revealed enhanced exposure of electrochemically active surface area for improved electro-catalytic activity towards fuel oxidation and oxidant reduction reactions.The issue of device stack durability and degraded performance due to corrosion of bipolar plates is discussed by incorporating graphene based materials.In proton exchange membrane devices,graphene as an electrolyte has shown an excellent performance towards high ionic conductivity and power density.The graphene incorporation in fuel cell devices has exhibited commendable performance and has bright future for commercial applications.展开更多
Various manganese oxides(MnOx) prepared via citric acid solution combustion synthesis were applied for catalytic oxidation of benzene. The results showed the ratios of citric acid/manganese nitrate in synthesizing pro...Various manganese oxides(MnOx) prepared via citric acid solution combustion synthesis were applied for catalytic oxidation of benzene. The results showed the ratios of citric acid/manganese nitrate in synthesizing process positively affected the physicochemical properties of MnOx, e.g., BET(Brunauer-Emmett-Teller) surface area, porous structure, reducibility and so on, which were in close relationship with their catalytic performance. Of all the catalysts, the sample prepared at a citric acid/manganese nitrate ratio of 2:1(C2M1) displayed the best catalytic activity with T(90)(the temperature when 90% of benzene was catalytically oxidized) of 212 ℃. Further investigation showed that C2M1 was Mn2O3 with abundant nano-pores, the largest surface area and the proper ratio of surface Mn^4+/Mn^3+, resulting in preferable low-temperature reducibility and abundant surface active adsorbed oxygen species. The analysis results of the in-situ Fourier transform infrared spectroscopy(in-situ FTIR) revealed that the benzene was successively oxidized to phenolate, o-benzoquinone, small molecules(such as maleates, acetates, and vinyl), and finally transformed to CO2 and H2O.展开更多
A pplication o f m echanical excavators is one o f th e m o st com m only used excavation m eth o d s because itcan bring th e p ro ject m ore productivity, accuracy and safety. A m ong th e m echanical excavators, ro...A pplication o f m echanical excavators is one o f th e m o st com m only used excavation m eth o d s because itcan bring th e p ro ject m ore productivity, accuracy and safety. A m ong th e m echanical excavators, roadhead ers are m echanical m iners w h ich have b een extensively u se d in tu n n elin g , m ining an d civil indu stries. Perform ance pred ictio n is an im p o rta n t issue for successful ro a d h e a d e r application andgenerally deals w ith m achine selection, p ro d u ctio n rate an d b it consu m p tio n . The m ain aim o f thisresearch is to investigate th e c u ttin g p erfo rm an ce （in stan tan eo u s c u ttin g rates （ICRs）） o f m ed iu m -d u tyro ad h ead ers by using artificial neural n etw o rk （ANN） approach. T here are d ifferent categories forANNs, b u t based o n train in g alg o rith m th e re are tw o m ain k in d s： supervised and u n su p erv ised . Them u lti-lay er p ercep tro n （MLP） an d K ohonen self-organizing feature m ap （KSOFM） are th e m o st w idelyused neu ral netw o rk s for supervised an d u n su p erv ised ones, respectively. For gaining this goal, ad atab ase w as prim arily provided from ro ad h e a d e rs＇ p erfo rm an ce an d geom echanical characteristics o frock form ations in tu n n els and d rift galleries in Tabas coal m ine, th e larg est an d th e only fullymech an ized coal m ine in Iran. T hen th e datab ase w as analyzed in o rd e r to yield th e m ost im p o rtan tfactor for ICR by using relatively im p o rta n t factor in w hich G arson eq u atio n w as utilized. The MLPn etw o rk w as train ed by 3 in p u t p ara m e te rs including rock m ass pro p erties, rock quality d esignation（RQD）, in tact rock p ro p erties such as uniaxial com pressive stre n g th （UCS） an d Brazilian ten sile stren g th（BTS）, and o n e o u tp u t p a ra m e te r （ICR）. In o rd e r to have m ore v alidation o n MLP o u tp u ts, KSOFM visualizationw as applied. The m ean square e rro r （MSE） an d regression coefficient （R ） o f MLP w e re found tobe 5.49 an d 0.97, respectively. M oreover, KSOFM n etw o rk has a m ap size o f 8 x 5 and final qu an tizatio nan d topographic erro rs w e re 0.383 an d 0.032, respectively. The results show th a t MLP neural n etw orkshave a strong capability to p red ict an d ev alu ate th e perfo rm an ce o f m ed iu m -d u ty ro ad h ead ers in coalm easu re rocks. Furtherm ore, it is concluded th a t KSOFM neural n etw o rk is an efficient w ay for u n d e rstand in g system beh av io r an d know ledge extraction. Finally, it is indicated th a t UCS has m ore influenceo n ICR b y applying th e b e st train ed MLP n etw o rk w eig h ts in G arson eq u atio n w h ich is also confirm ed byKSOFM.展开更多
Pt supported on mesoporous silica SBA-15 was investigated as a catalyst for low temperature selective catalytic reduction（SCR） of NO by C 3 H 6 in the presence of excess oxygen.The prepared catalysts were characteri...Pt supported on mesoporous silica SBA-15 was investigated as a catalyst for low temperature selective catalytic reduction（SCR） of NO by C 3 H 6 in the presence of excess oxygen.The prepared catalysts were characterized by means of XRD,BET surface area,TEM,NO-TPD,NO/C 3 H 6-TPO,NH 3-TPD,XPS and 27 Al MAS NMR.The effects of Pt loading amount,O 2 /C 3 H 6 concentration,and incorporation of Al into SBA-15 have been studied.It was found that the removal efficiency increased significantly after Pt loading,but an optimal loading amount was observed.In particular,under an atmosphere of 150 ppm NO,150 ppm C 3 H 6,and 18 vol.% O 2,0.5% Pt/SBA-15 showed remarkably high catalytic performance giving 80.1% NOx reduction and 87.04% C 3 H 6 conversion simultaneously at 140°C.The enhanced SCR activity of Pt/SBA-15 is associated with its outstanding oxidation activities of NO to NO 2 and C 3 H 6 to CO 2 in low temperature range.The research results also suggested that higher concentration of O 2 and higher concentration of C 3 H 6 favored NO removal.The incorporation of Al into SBA-15 improved catalytic performance,which could be ascribed to the enhancement of catalyst surface acidity caused by tetrahedrally coordinated AlO 4.Moreover,the catalysts could be easily reused and possessed good stability.展开更多
The Norwegian Public Roads Administration(NPRA) is planning for an upgrade of the E39 highway route at the westcoast of Norway. Fixed links shall replace ferries at seven fjord crossings. Wide spans and large depths a...The Norwegian Public Roads Administration(NPRA) is planning for an upgrade of the E39 highway route at the westcoast of Norway. Fixed links shall replace ferries at seven fjord crossings. Wide spans and large depths at the crossings combined with challenging subsea topography and environmental loads call for an extension of existing practice. A variety of bridge concepts are evaluated in the feasibility study. The structures will experience significant loads from deadweight, traffic and environment. Anchoring of these forces is thus one of the challenges met in the project. Large-size subsea rock anchors are considered a viable alternative. These can be used for anchoring of floating structures but also with the purpose of increasing capacity of fixed structures. This paper presents first a thorough study of factors affecting rock anchor bond capacity. Laboratory testing of rock anchors subjected to cyclic loading is thereafter presented. Finally, the paper presents a model predicting the capacity of a rock anchor segment, in terms of a ribbed bar, subjected to a cyclic load history. The research assumes a failure mode occurring in the interface between the rock anchor and the surrounding grout. The constitutive behavior of the bonding interface is investigated for anchors subjected to cyclic one-way tensile loads. The model utilizes the static bond capacity curve as a basis, defining the ultimate bond sbuand the slip s1 at τ. A limited number of input parameters are required to apply the model. The model defines the bond-slip behavior with the belonging rock anchor capacity depending on the cyclic load level(τcy/τ), the cyclic load ratio(R= τcy/τcy), and the number of load cycles(N). The constitutive model is intended to model short anchor lengths representing an incremental length of a complete rock anchor.展开更多
Organic-inorganic lead halide based perovskite solar cells(PSCs)have attracted unprecedented research interest over last decade.The high performance,combined with merits of low fabrication costs and ease of synthesis ...Organic-inorganic lead halide based perovskite solar cells(PSCs)have attracted unprecedented research interest over last decade.The high performance,combined with merits of low fabrication costs and ease of synthesis make PSCs promising alternate to state of the art silicon(Si)based solar cells.Howeve r,some inherent shortcomings of PSCs are hindering their market dominance over conventional photovoltaic technologies such as transmission loss of sub-bandgap photons,poor stability and hysteresis effects.Recently,use of rare earth(RE)ions doped nanomaterials in PSCs,has been identified as an effective means to address the aforementioned issues by expanding the range of absorption spectra minimizing the non-absorption loss of solar photons,enhancing light scattering and improving operational stability.This article reviews the recent progress in doping rare-earth(RE)ions in the building blocks of PSCs such as semiconductor electrodes and photoactive perovskite layers,and its use as a separate spectral conversion layer in PSCs.The effect of size,shape,constitution and concentration of RE-nanoparticles on the overall performance and device stability will be analyzed in detail.Moreover,we provide an outlook on the opportunities this newly developed field offers and the critical challenges faced in rationally and effectively using RE-ion-doped nanomaterials in PSCs for better operational stability and enhanced performance.展开更多
In view of the fact that large scale vortices play the substantial role of momentum transport in turbulent flows, large eddy simulation （LES） is considered as a better simulation model. However, the sub-grid scale ...In view of the fact that large scale vortices play the substantial role of momentum transport in turbulent flows, large eddy simulation （LES） is considered as a better simulation model. However, the sub-grid scale （SGS） models reported so far have not ascertained under what flow conditions the LES can lapse into the direct nu-merical simulation. To overcome this discrepancy, this paper develops a swirling strength based the SGS model to properly model the turbulence intermittency, with the primary characteristics that when the local swirling strength is zero, the local sub-grid viscosity will be vanished. In this paper, the model is used to investigate the flow characteris-tics of zero-incident incompressible turbulent flows around a single square cylinder （SC） at a low Reynolds number range Re ∈ [103, 104]. The flow characteristics investigated include the Reynolds number dependence of lift and drag coefficients, the distributions of time-spanwise averaged variables such as the sub-grid viscosity and the logarithm of Kolmogorov micro-scale to the base of 10 at Re=2 500 and 104, the contours of spanwise and streamwise vorticity components at t = 170. It is revealed that the peak value of sub-grid viscosity ratio and its root mean square （RMS） values grow with the Reynolds number. The dissipation rate of turbulent kinetic energy is larger near the SC solid walls. The instantaneous factor of swirling strength intermittency （FSI） exhibits some laminated structure involved with vortex shedding.展开更多
Non-thermal plasma(NTP)has been demonstrated as one of the promising technologies that can degrade volatile organic compounds(VOCs)under ambient condition.However,one of the key challenges of VOCs degradation in NTP i...Non-thermal plasma(NTP)has been demonstrated as one of the promising technologies that can degrade volatile organic compounds(VOCs)under ambient condition.However,one of the key challenges of VOCs degradation in NTP is its relatively low mineralization rate,which needs to be addressed by introducing catalysts.Therefore,the design and optimization of catalysts have become the focus of NTP coupling catalysis research.In thiswork,a series of two-dimensional nanosheet Co-Ni metal oxides were synthesized by microwave method and investigated for the catalytic oxidation of benzene in an NTP-catalysis coupling system.Among them,Co_(2)Ni_(1)O_(x)achieves 60%carbon dioxide(CO_(2))selectivity(SCO_(2))when the benzene removal efficiency(REbenzene)reaches more than 99%,which is a significant enhancement compared with the CO_(2)selectivity obtained without any catalysts(38%)under the same input power.More intriguingly,this SCO_(2)is also significantly higher than that of single metal oxides,NiO or Co_(3)O_(4),which is only around 40%.Such improved performance of this binary metal oxide catalyst is uniquely attributed to the synergistic effects of Co and Ni in Co_(2)Ni_(1)O_(x)catalyst.The introduction of Co_(2)Ni_(1)O_(x)was found to promote the generation of acrolein significantly,one of the key intermediates found in NTP alone system reported previously,suggest the benzene ring open reaction is promoted.Compared with monometallic oxides NiO and Co_(3)O_(4),Co_(2)Ni_(1)O_(x)also shows higher active oxygen proportion,better oxygenmobility,and stronger low-temperature redox capability.The above factors result in the improved catalytic performance of Co_(2)Ni_(1)O_(x)in the NTP coupling removal of benzene.展开更多
The alumina composite coatings reinforced with 25% ZrO2 （denoted as AZ-25） and 3% TiO2 （denoted as AT-3） were deposited on low carbon steel using a thermal flame spraying. The microstructure, phase composition, mi...The alumina composite coatings reinforced with 25% ZrO2 （denoted as AZ-25） and 3% TiO2 （denoted as AT-3） were deposited on low carbon steel using a thermal flame spraying. The microstructure, phase composition, microhardness and tribological properties of the coatings were investigated. The XRD results of the coatings reinforced by TiO2 （AT-3） revealed the presence of α-Al2O3 phase as matrix and new metastable phases of α-Al2O3 and α-Al2O3. However, the coatings reinforced by ZrO2 （AZ-25） consist of α-Al2O3 as matrix, q-ZrO2 and m-ZrO2. In most studied conditions, the AT-3 coating displays a better tribological performance, i.e., lower coefficient of frictions and wear rates, than the AZ-25 coating. It was also found that the microhardness of the coatings was decreased with the reinforcement of ZrO2 and increased with TiO2.展开更多
Graphene oxide （GO） ultrathin flat lenses have provided a new and viable solution to achieve high resolution, high efficiency, ultra-light weight, integratable and flexible optical systems. Current GO lenses are des...Graphene oxide （GO） ultrathin flat lenses have provided a new and viable solution to achieve high resolution, high efficiency, ultra-light weight, integratable and flexible optical systems. Current GO lenses are designed based on the Fresnel diffraction model, which uses a paraxial approximation for low numerical aperture （NA） focusing process. Herein we develop a lens design method based on the Rayleigh-Sommerfeld （RS） diffraction theory that is able to unambiguously determine the radii of each ring without the optimization process for the first time. More importantly, the RS design method is able to accurately design GO lenses with arbitrary NA and focal length. Our design is experimentally confirmed by fabricating high NA GO lenses with both short and long focal lengths. Compared with the conventional Fresnel design methods, the differences in ring positions and the resulted focal length are up to 13.9% and 9.1%, respectively. Our method can be further applied to design high performance flat lenses of arbitrary materials given the NA and focal length requirements, including metasurfaces or other two-dimensional materials.展开更多
An initiation study is presented in which we examine the effect of the normal and the tangential velocity components of a fragment that impacts a covered and a bare Comp-B explosive. The study is based on calibrated n...An initiation study is presented in which we examine the effect of the normal and the tangential velocity components of a fragment that impacts a covered and a bare Comp-B explosive. The study is based on calibrated numerical Lagrangian simulations using the LS-Dyna hydrocode. A special procedure was developed to present the estimated initiation point and the shock wave transition into detonation for various impact angles. The influence of the fragment strength and the steel cover thickness on the detonation threshold were also examined. The velocity threshold results are presented and used to modify the Jacobs-Roslund initiation model.展开更多
Nowadays,Multi Robotic System(MRS)consisting of different robot shapes,sizes and capabilities has received significant attention from researchers and are being deployed in a variety of real-world applications.From sen...Nowadays,Multi Robotic System(MRS)consisting of different robot shapes,sizes and capabilities has received significant attention from researchers and are being deployed in a variety of real-world applications.From sensors and actuators improved by communication technologies to powerful computing systems utilizing advanced Artificial Intelligence(AI)algorithms have rapidly driven the development of MRS,so the Internet of Things(IoT)in MRS has become a new topic,namely the Internet of Robotic Things(IoRT).This paper summarizes a comprehensive survey of state-of-the-art technologies for mobile robots,including general architecture,benefits,challenges,practical applications,and future research directions.In addition,remarkable research of i)multirobot navigation,ii)network architecture,routing protocols and communications,and iii)coordination among robots as well as data analysis via external computing(cloud,fog,edge,edge-cloud)are merged with the IoRT architecture according to their applicability.Moreover,security is a long-term challenge for IoRT because of various attack vectors,security flaws,and vulnerabilities.Security threats,attacks,and existing solutions based on IoRT architectures are also under scrutiny.Moreover,the identification of environmental situations that are crucial for all types of IoRT applications,such as the detection of objects,human,and obstacles,is also critically reviewed.Finally,future research directions are given by analyzing the challenges of IoRT in mobile robots.展开更多
Objective: Labisia pumila var. alata, commonly known as 'Kacip Fatimah' or 'Selusuh Fatimah' in Southeast Asia, is traditionally used by members of the Malay community because of its post-partum medici...Objective: Labisia pumila var. alata, commonly known as 'Kacip Fatimah' or 'Selusuh Fatimah' in Southeast Asia, is traditionally used by members of the Malay community because of its post-partum medicinal properties. Its various pharmaceutical applications cause an excessive harvesting and lead to serious shortage in natural habitat. Thus, this in vitro propagation study investigated the effects of different plant growth regulators (PGRs) on in vitro leaf and stem explants of L. pumila. Methods: The capabilities of callus, shoot, and root formation were evaluated by culturing both explants on Murashige and Skoog (MS) medium supplemented with various PGRs at the concentrations of 0, 1, 3, 5, and 7 mg/L. Results: Medium supplemented with 3 mg/L indole-3-butyric acid (IBA) showed the optimal callogenesis from both leaf and stem explants with (72.34±19.55)% and (70.40±14.14)% efficacy, respectively. IBA was also found to be the most efficient PGR for root induction. A total of (50.00±7.07)% and (77.78±16.47)% of root formation were obtained from the in vitro stem and leaf explants after being cultured for (26.5±5.0) and (30.0±8.5) d in the medium supplemented with 1 and 3 mg/L of IBA, respectively. Shoot formation was only observed in stem explant, with the maximum percentage of formation ((100.00±0.00)%) that was obtained in 1 mg/L zeatin after (11.0±2.8) d of culture. Conclusions: Callus, roots, and shoots can be induced from in vitro leaf and stem explants of L. pumila through the manipulation of types and concentrations of PGRs.展开更多
In this study,a quantitative performance of three commercial polyamide nanofiltration(NF) membranes(i.e.,NF,NF90,and NF270) for phosphorus removal under different feed conditions was investigated.The experiments were ...In this study,a quantitative performance of three commercial polyamide nanofiltration(NF) membranes(i.e.,NF,NF90,and NF270) for phosphorus removal under different feed conditions was investigated.The experiments were conducted at different feed phosphorus concentrations(2.5,5,10,and 15 mg·L^-1) and elevated pHs(pH 1.5,5,10,and 13.5) at a constant feed pressure of 1 MPa using a dead-end filtration cell.Membrane rejection against total phosphorus generally increased with increasing phosphorus concentration regardless of membrane type.In contrast,the permeate flux for all the membranes only decreased slightly with increasing phosphorus concentration.The results also showed that the phosphorus rejections improved while water flux remained almost unchanged with increasing feed solution pH.When the three membranes were exposed to strong pHs(pH 1.5 and 13.5) for a longer duration(up to 6 weeks)it was found that the rejection capability and water flux of the membranes remained very similar throughout the duration,except for NF membrane with marginal decrement in phosphorus rejection.Adsorption study also revealed that more phosphorus was adsorbed onto the membrane structure at alkaline conditions(pH 10 and 13.5) compared to the same membranes tested at lower pHs(pH 1.5 and 5).In eonelusion,NF270 membrane outperformed Nf and NF90 membranes owing to its desirable performance of water flux and phosphorus rejection particularly under strong alkali solution.The NF270 membrane achieved 14.0 L·m^-2·h^-1 and 96.5% rejection against 10 mg·L^-1 phosphorus solution with a pH value of 13.5 at the applied pressure of 1 MPa.展开更多
The present study initially investigates the kinetics of microwave-assisted grinding and flotation in a porphyry copper deposit.Kinetic tests were conducted on untreated and microwave-irradiated samples by varying the...The present study initially investigates the kinetics of microwave-assisted grinding and flotation in a porphyry copper deposit.Kinetic tests were conducted on untreated and microwave-irradiated samples by varying the exposure time from 15 to 150 s.Optical microscopy,energy-dispersive X-ray spectroscopy,and scanning electron microscopy were conducted to determine the mineral liberation and particle surface properties,and to perform mineralogical analyses.Results showed that the ore breakage rate constant monotonically increased by increasing the exposure time,particularly for the coarsest fraction size(400μm)due to the creation of thermal stress fractures alongside grain boundaries.Excessive irradiation time(>60 s)led to the creation of oxidized and porous surfaces along with a dramatic change in particle morphologies that result in a substantial reduction of chalcopyrite and pyrite flotation rate constants and ultimate recoveries.We concluded that MW-pretreated copper ore was ground faster than the untreated variety,but the two types have slightly similar floatabilities.展开更多
The adsorption/plasma decomposition with the combination of adsorption honeycomb-sheets and a plasma element is a new technology for small-sized apparatuses to decompose volatile organic compounds （VOCs） at concentr...The adsorption/plasma decomposition with the combination of adsorption honeycomb-sheets and a plasma element is a new technology for small-sized apparatuses to decompose volatile organic compounds （VOCs） at concentrations lower than about 100 ppm. The feasibility of the prototype adsorption/plasma decomposition apparatus was evaluated with the simulated exhausts containing one VOC component and with real exhausts from a painting booth and an adhesion factory. The apparatus decomposed VOCs effectively at the painting booth exhaust but not always satisfactorily at the adhesion factory exhaust. The performance test results with real exhausts were discussed with respect to the concentration and discharge pattern of the exhausts and the basic properties of the system such as cooperation of adsorption and plasma reaction and the concentration dependence of the performance.展开更多
基金supported by the DEEPCOBOT project under Grant 306640/O70 funded by the Research Council of Norway.
文摘This paper studies motor joint control of a 4-degree-of-freedom(DoF)robotic manipulator using learning-based Adaptive Dynamic Programming(ADP)approach.The manipulator’s dynamics are modelled as an open-loop 4-link serial kinematic chain with 4 Degrees of Freedom(DoF).Decentralised optimal controllers are designed for each link using ADP approach based on a set of cost matrices and data collected from exploration trajectories.The proposed control strategy employs an off-line,off-policy iterative approach to derive four optimal control policies,one for each joint,under exploration strategies.The objective of the controller is to control the position of each joint.Simulation and experimental results show that four independent optimal controllers are found,each under similar exploration strategies,and the proposed ADP approach successfully yields optimal linear control policies despite the presence of these complexities.The experimental results conducted on the Quanser Qarm robotic platform demonstrate the effectiveness of the proposed ADP controllers in handling significant dynamic nonlinearities,such as actuation limitations,output saturation,and filter delays.
基金support by the Shanghai Engineering Research Center for Shallow Geothermal Energy(DRZX-202306)Shaanxi Coal Geology Group Co.,Ltd.(SMDZ-ZD2024-23)+4 种基金Key Laboratory of Coal Resources Exploration and Comprehensive Utilization,Ministry of Natural Resources,China(ZP2020-1)Shaanxi Investment Group Co.,Ltd.(SIGC2023-KY-05)Key Research and Development Projects of Shaanxi Province(2023-GHZD-54)Shaanxi Qinchuangyuan Scientist+Engineer Team Construction Project(2022KXJ-049)China Postdoctoral Science Foundation(2023M742802,2024T170721).
文摘Geothermal energy,a form of renewable energy,has been extensively utilized for building heating.However,there is a lack of detailed comparative studies on the use of shallow and medium-deep geothermal energy in building energy systems,which are essential for decision-making.Therefore,this paper presents a comparative study of the performance and economic analysis of shallow and medium-deep borehole heat exchanger heating systems.Based on the geological parameters of Xi’an,China and commonly used borehole heat exchanger structures,numerical simulationmethods are employed to analyze performance and economic efficiency.The results indicate that increasing the spacing between shallow borehole heat exchangers can effectively reduce thermal interference between the pipes and improve heat extraction performance.As the flow rate increases,the outlet water temperature ranges from 279.3 to 279.7 K,with heat extraction power varying between 595 and 609 W.For medium-deep borehole heat exchangers,performance predictions show that a higher flow rate results in greater heat extraction power.However,when the flow rate exceeds 30 m^(3)/h,further increases in flow rate have only a minor effect on enhancing heat extraction power.Additionally,the economic analysis reveals that the payback period for shallow geothermal heating systems ranges from 10 to 11 years,while for medium-deep geothermal heating systems,it varies more widely from 3 to 25 years.Therefore,the payback period for medium-deep geothermal heating systems is more significantly influenced by operational and installation parameters,and optimizing these parameters can considerably shorten the payback period.The results of this study are expected to provide valuable insights into the efficient and cost-effective utilization of geothermal energy for building heating.
基金Project(12JCYBJC32100)supported by the Tianjin Research Program of Application Foundation and Advanced Technology,ChinaProject([2013]693)supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry,China
文摘Creep and anelastic backflow behaviors of pure copper （4N Cu） with grain size dg=40 μm were investigated at low temperatures of T〈0.3Tm （Tm is melting point） and ultra-low creep rates of ε≤1×10^-10 s^-1 by a high strain-resolution measurement （the helicoid spring specimen technique）. Analysis of creep data was based on the scaling factors of creep curves instead of the conventional extrapolated steady-state creep rate. Power-law creep equation is suggested to be the best for describing the primary transient creep behavior, because the pre-parameter does not apparently change with elapsed time. The observed anelastic strains are 1/6 of the calculated elastic strains, and linear viscous behavior was identified from the logarithm plot of the anelastic strain rate versus anelastic strain （slope equals 1）. Therefore, the creep anelasticity is suggested to be due to the unbowing of there-dimensional network of dislocations.
基金Project supported by PAZY Foundation,Israel(244)
文摘Two types of cyanobacteria of the genus Arthrospira（commonly known as Spirulina） were tested for biosorption of cerium（III） ions from aqueous solutions. An endemic type（ES） found in the northern Negev desert, Israel, and a commercial powder（CS） were used in this study. Biosorption was evaluated as a function of p H, contact time, initial metal concentration, number of sorption-desorption cycles, and salt concentration. The optimum p H range for biosorption was found to be 5.0–5.5. The kinetic characteristics of both Spirulina types were found to be highly compatible with a pseudo-second order kinetic model. The adsorption isotherms of both types were found to be well-suited to Langmuir and Freundlich adsorption isotherms. Maximum biosorption uptakes, according to the Langmuir model, were 18.1 and 38.2 mg/g, for ES and CS, respectively. Sodium chloride concentrations of up to 5 g/L had a minor effect on cerium biosorption. Desorption efficiency was found to be greater than 97% with 0.1 mol/L HNO_3 after three sorption-desorption cycles, without significant loss in the biosorption capacity. The results indicated the feasibility of cerium recovery from industrial wastes using Spirulina biomass.
基金supported by Higher Education Commission(HEC)of Pakistan under the National Research Program for Universities(NRPU)with project No.5544/KPK/NRPU/R&D/HEC/2016
文摘Novel characteristics of graphene have captured great attention of researchers for energy technology applications.Incorporation of graphene related hybrid and composite materials have demonstrated high performance and durability for fuel cell energy conversion devices.This article overviews graphene based materials for fuel cell technology applications such as electrodes additives,bipolar plates and proton conducting electrolyte membrane.The graphene dispersion over electrodes has revealed enhanced exposure of electrochemically active surface area for improved electro-catalytic activity towards fuel oxidation and oxidant reduction reactions.The issue of device stack durability and degraded performance due to corrosion of bipolar plates is discussed by incorporating graphene based materials.In proton exchange membrane devices,graphene as an electrolyte has shown an excellent performance towards high ionic conductivity and power density.The graphene incorporation in fuel cell devices has exhibited commendable performance and has bright future for commercial applications.
基金financially supported by the National Key Re-search and Development Plan (No. 2017YFC0211804)。
文摘Various manganese oxides(MnOx) prepared via citric acid solution combustion synthesis were applied for catalytic oxidation of benzene. The results showed the ratios of citric acid/manganese nitrate in synthesizing process positively affected the physicochemical properties of MnOx, e.g., BET(Brunauer-Emmett-Teller) surface area, porous structure, reducibility and so on, which were in close relationship with their catalytic performance. Of all the catalysts, the sample prepared at a citric acid/manganese nitrate ratio of 2:1(C2M1) displayed the best catalytic activity with T(90)(the temperature when 90% of benzene was catalytically oxidized) of 212 ℃. Further investigation showed that C2M1 was Mn2O3 with abundant nano-pores, the largest surface area and the proper ratio of surface Mn^4+/Mn^3+, resulting in preferable low-temperature reducibility and abundant surface active adsorbed oxygen species. The analysis results of the in-situ Fourier transform infrared spectroscopy(in-situ FTIR) revealed that the benzene was successively oxidized to phenolate, o-benzoquinone, small molecules(such as maleates, acetates, and vinyl), and finally transformed to CO2 and H2O.
文摘A pplication o f m echanical excavators is one o f th e m o st com m only used excavation m eth o d s because itcan bring th e p ro ject m ore productivity, accuracy and safety. A m ong th e m echanical excavators, roadhead ers are m echanical m iners w h ich have b een extensively u se d in tu n n elin g , m ining an d civil indu stries. Perform ance pred ictio n is an im p o rta n t issue for successful ro a d h e a d e r application andgenerally deals w ith m achine selection, p ro d u ctio n rate an d b it consu m p tio n . The m ain aim o f thisresearch is to investigate th e c u ttin g p erfo rm an ce （in stan tan eo u s c u ttin g rates （ICRs）） o f m ed iu m -d u tyro ad h ead ers by using artificial neural n etw o rk （ANN） approach. T here are d ifferent categories forANNs, b u t based o n train in g alg o rith m th e re are tw o m ain k in d s： supervised and u n su p erv ised . Them u lti-lay er p ercep tro n （MLP） an d K ohonen self-organizing feature m ap （KSOFM） are th e m o st w idelyused neu ral netw o rk s for supervised an d u n su p erv ised ones, respectively. For gaining this goal, ad atab ase w as prim arily provided from ro ad h e a d e rs＇ p erfo rm an ce an d geom echanical characteristics o frock form ations in tu n n els and d rift galleries in Tabas coal m ine, th e larg est an d th e only fullymech an ized coal m ine in Iran. T hen th e datab ase w as analyzed in o rd e r to yield th e m ost im p o rtan tfactor for ICR by using relatively im p o rta n t factor in w hich G arson eq u atio n w as utilized. The MLPn etw o rk w as train ed by 3 in p u t p ara m e te rs including rock m ass pro p erties, rock quality d esignation（RQD）, in tact rock p ro p erties such as uniaxial com pressive stre n g th （UCS） an d Brazilian ten sile stren g th（BTS）, and o n e o u tp u t p a ra m e te r （ICR）. In o rd e r to have m ore v alidation o n MLP o u tp u ts, KSOFM visualizationw as applied. The m ean square e rro r （MSE） an d regression coefficient （R ） o f MLP w e re found tobe 5.49 an d 0.97, respectively. M oreover, KSOFM n etw o rk has a m ap size o f 8 x 5 and final qu an tizatio nan d topographic erro rs w e re 0.383 an d 0.032, respectively. The results show th a t MLP neural n etw orkshave a strong capability to p red ict an d ev alu ate th e perfo rm an ce o f m ed iu m -d u ty ro ad h ead ers in coalm easu re rocks. Furtherm ore, it is concluded th a t KSOFM neural n etw o rk is an efficient w ay for u n d e rstand in g system beh av io r an d know ledge extraction. Finally, it is indicated th a t UCS has m ore influenceo n ICR b y applying th e b e st train ed MLP n etw o rk w eig h ts in G arson eq u atio n w h ich is also confirm ed byKSOFM.
基金supported by the National Natural Science Foundation of China (No. 20807027)the National High-Tech Research and Development Program (863) of China (No. 2010AA064907)
文摘Pt supported on mesoporous silica SBA-15 was investigated as a catalyst for low temperature selective catalytic reduction（SCR） of NO by C 3 H 6 in the presence of excess oxygen.The prepared catalysts were characterized by means of XRD,BET surface area,TEM,NO-TPD,NO/C 3 H 6-TPO,NH 3-TPD,XPS and 27 Al MAS NMR.The effects of Pt loading amount,O 2 /C 3 H 6 concentration,and incorporation of Al into SBA-15 have been studied.It was found that the removal efficiency increased significantly after Pt loading,but an optimal loading amount was observed.In particular,under an atmosphere of 150 ppm NO,150 ppm C 3 H 6,and 18 vol.% O 2,0.5% Pt/SBA-15 showed remarkably high catalytic performance giving 80.1% NOx reduction and 87.04% C 3 H 6 conversion simultaneously at 140°C.The enhanced SCR activity of Pt/SBA-15 is associated with its outstanding oxidation activities of NO to NO 2 and C 3 H 6 to CO 2 in low temperature range.The research results also suggested that higher concentration of O 2 and higher concentration of C 3 H 6 favored NO removal.The incorporation of Al into SBA-15 improved catalytic performance,which could be ascribed to the enhancement of catalyst surface acidity caused by tetrahedrally coordinated AlO 4.Moreover,the catalysts could be easily reused and possessed good stability.
基金sponsored by the Norwegian Public Roads Administration(NPRA)
文摘The Norwegian Public Roads Administration(NPRA) is planning for an upgrade of the E39 highway route at the westcoast of Norway. Fixed links shall replace ferries at seven fjord crossings. Wide spans and large depths at the crossings combined with challenging subsea topography and environmental loads call for an extension of existing practice. A variety of bridge concepts are evaluated in the feasibility study. The structures will experience significant loads from deadweight, traffic and environment. Anchoring of these forces is thus one of the challenges met in the project. Large-size subsea rock anchors are considered a viable alternative. These can be used for anchoring of floating structures but also with the purpose of increasing capacity of fixed structures. This paper presents first a thorough study of factors affecting rock anchor bond capacity. Laboratory testing of rock anchors subjected to cyclic loading is thereafter presented. Finally, the paper presents a model predicting the capacity of a rock anchor segment, in terms of a ribbed bar, subjected to a cyclic load history. The research assumes a failure mode occurring in the interface between the rock anchor and the surrounding grout. The constitutive behavior of the bonding interface is investigated for anchors subjected to cyclic one-way tensile loads. The model utilizes the static bond capacity curve as a basis, defining the ultimate bond sbuand the slip s1 at τ. A limited number of input parameters are required to apply the model. The model defines the bond-slip behavior with the belonging rock anchor capacity depending on the cyclic load level(τcy/τ), the cyclic load ratio(R= τcy/τcy), and the number of load cycles(N). The constitutive model is intended to model short anchor lengths representing an incremental length of a complete rock anchor.
基金the financial support provided by Dongguan University of Technology to carry out this extensive research work。
文摘Organic-inorganic lead halide based perovskite solar cells(PSCs)have attracted unprecedented research interest over last decade.The high performance,combined with merits of low fabrication costs and ease of synthesis make PSCs promising alternate to state of the art silicon(Si)based solar cells.Howeve r,some inherent shortcomings of PSCs are hindering their market dominance over conventional photovoltaic technologies such as transmission loss of sub-bandgap photons,poor stability and hysteresis effects.Recently,use of rare earth(RE)ions doped nanomaterials in PSCs,has been identified as an effective means to address the aforementioned issues by expanding the range of absorption spectra minimizing the non-absorption loss of solar photons,enhancing light scattering and improving operational stability.This article reviews the recent progress in doping rare-earth(RE)ions in the building blocks of PSCs such as semiconductor electrodes and photoactive perovskite layers,and its use as a separate spectral conversion layer in PSCs.The effect of size,shape,constitution and concentration of RE-nanoparticles on the overall performance and device stability will be analyzed in detail.Moreover,we provide an outlook on the opportunities this newly developed field offers and the critical challenges faced in rationally and effectively using RE-ion-doped nanomaterials in PSCs for better operational stability and enhanced performance.
基金Project supported by the National Natural Science Foundation of China(No.11372303)
文摘In view of the fact that large scale vortices play the substantial role of momentum transport in turbulent flows, large eddy simulation （LES） is considered as a better simulation model. However, the sub-grid scale （SGS） models reported so far have not ascertained under what flow conditions the LES can lapse into the direct nu-merical simulation. To overcome this discrepancy, this paper develops a swirling strength based the SGS model to properly model the turbulence intermittency, with the primary characteristics that when the local swirling strength is zero, the local sub-grid viscosity will be vanished. In this paper, the model is used to investigate the flow characteris-tics of zero-incident incompressible turbulent flows around a single square cylinder （SC） at a low Reynolds number range Re ∈ [103, 104]. The flow characteristics investigated include the Reynolds number dependence of lift and drag coefficients, the distributions of time-spanwise averaged variables such as the sub-grid viscosity and the logarithm of Kolmogorov micro-scale to the base of 10 at Re=2 500 and 104, the contours of spanwise and streamwise vorticity components at t = 170. It is revealed that the peak value of sub-grid viscosity ratio and its root mean square （RMS） values grow with the Reynolds number. The dissipation rate of turbulent kinetic energy is larger near the SC solid walls. The instantaneous factor of swirling strength intermittency （FSI） exhibits some laminated structure involved with vortex shedding.
基金supported by the National Key Research and Development Program of China(No.2017YFE0127500)National Natural Science Foundation of China(No.U1832155).
文摘Non-thermal plasma(NTP)has been demonstrated as one of the promising technologies that can degrade volatile organic compounds(VOCs)under ambient condition.However,one of the key challenges of VOCs degradation in NTP is its relatively low mineralization rate,which needs to be addressed by introducing catalysts.Therefore,the design and optimization of catalysts have become the focus of NTP coupling catalysis research.In thiswork,a series of two-dimensional nanosheet Co-Ni metal oxides were synthesized by microwave method and investigated for the catalytic oxidation of benzene in an NTP-catalysis coupling system.Among them,Co_(2)Ni_(1)O_(x)achieves 60%carbon dioxide(CO_(2))selectivity(SCO_(2))when the benzene removal efficiency(REbenzene)reaches more than 99%,which is a significant enhancement compared with the CO_(2)selectivity obtained without any catalysts(38%)under the same input power.More intriguingly,this SCO_(2)is also significantly higher than that of single metal oxides,NiO or Co_(3)O_(4),which is only around 40%.Such improved performance of this binary metal oxide catalyst is uniquely attributed to the synergistic effects of Co and Ni in Co_(2)Ni_(1)O_(x)catalyst.The introduction of Co_(2)Ni_(1)O_(x)was found to promote the generation of acrolein significantly,one of the key intermediates found in NTP alone system reported previously,suggest the benzene ring open reaction is promoted.Compared with monometallic oxides NiO and Co_(3)O_(4),Co_(2)Ni_(1)O_(x)also shows higher active oxygen proportion,better oxygenmobility,and stronger low-temperature redox capability.The above factors result in the improved catalytic performance of Co_(2)Ni_(1)O_(x)in the NTP coupling removal of benzene.
文摘The alumina composite coatings reinforced with 25% ZrO2 （denoted as AZ-25） and 3% TiO2 （denoted as AT-3） were deposited on low carbon steel using a thermal flame spraying. The microstructure, phase composition, microhardness and tribological properties of the coatings were investigated. The XRD results of the coatings reinforced by TiO2 （AT-3） revealed the presence of α-Al2O3 phase as matrix and new metastable phases of α-Al2O3 and α-Al2O3. However, the coatings reinforced by ZrO2 （AZ-25） consist of α-Al2O3 as matrix, q-ZrO2 and m-ZrO2. In most studied conditions, the AT-3 coating displays a better tribological performance, i.e., lower coefficient of frictions and wear rates, than the AZ-25 coating. It was also found that the microhardness of the coatings was decreased with the reinforcement of ZrO2 and increased with TiO2.
文摘Graphene oxide （GO） ultrathin flat lenses have provided a new and viable solution to achieve high resolution, high efficiency, ultra-light weight, integratable and flexible optical systems. Current GO lenses are designed based on the Fresnel diffraction model, which uses a paraxial approximation for low numerical aperture （NA） focusing process. Herein we develop a lens design method based on the Rayleigh-Sommerfeld （RS） diffraction theory that is able to unambiguously determine the radii of each ring without the optimization process for the first time. More importantly, the RS design method is able to accurately design GO lenses with arbitrary NA and focal length. Our design is experimentally confirmed by fabricating high NA GO lenses with both short and long focal lengths. Compared with the conventional Fresnel design methods, the differences in ring positions and the resulted focal length are up to 13.9% and 9.1%, respectively. Our method can be further applied to design high performance flat lenses of arbitrary materials given the NA and focal length requirements, including metasurfaces or other two-dimensional materials.
文摘An initiation study is presented in which we examine the effect of the normal and the tangential velocity components of a fragment that impacts a covered and a bare Comp-B explosive. The study is based on calibrated numerical Lagrangian simulations using the LS-Dyna hydrocode. A special procedure was developed to present the estimated initiation point and the shock wave transition into detonation for various impact angles. The influence of the fragment strength and the steel cover thickness on the detonation threshold were also examined. The velocity threshold results are presented and used to modify the Jacobs-Roslund initiation model.
基金This research was supported by the Ministry of Higher Education,Malaysia(MoHE)through Fundamental Research Grant Scheme(FRGS/1/2021/TK0/UTAR/02/9)The work was also supported by the Universiti Tunku Abdul Rahman(UTAR),Malaysia,under UTAR Research Fund(UTARRF)(IPSR/RMC/UTARRF/2021C1/T05).
文摘Nowadays,Multi Robotic System(MRS)consisting of different robot shapes,sizes and capabilities has received significant attention from researchers and are being deployed in a variety of real-world applications.From sensors and actuators improved by communication technologies to powerful computing systems utilizing advanced Artificial Intelligence(AI)algorithms have rapidly driven the development of MRS,so the Internet of Things(IoT)in MRS has become a new topic,namely the Internet of Robotic Things(IoRT).This paper summarizes a comprehensive survey of state-of-the-art technologies for mobile robots,including general architecture,benefits,challenges,practical applications,and future research directions.In addition,remarkable research of i)multirobot navigation,ii)network architecture,routing protocols and communications,and iii)coordination among robots as well as data analysis via external computing(cloud,fog,edge,edge-cloud)are merged with the IoRT architecture according to their applicability.Moreover,security is a long-term challenge for IoRT because of various attack vectors,security flaws,and vulnerabilities.Security threats,attacks,and existing solutions based on IoRT architectures are also under scrutiny.Moreover,the identification of environmental situations that are crucial for all types of IoRT applications,such as the detection of objects,human,and obstacles,is also critically reviewed.Finally,future research directions are given by analyzing the challenges of IoRT in mobile robots.
文摘Objective: Labisia pumila var. alata, commonly known as 'Kacip Fatimah' or 'Selusuh Fatimah' in Southeast Asia, is traditionally used by members of the Malay community because of its post-partum medicinal properties. Its various pharmaceutical applications cause an excessive harvesting and lead to serious shortage in natural habitat. Thus, this in vitro propagation study investigated the effects of different plant growth regulators (PGRs) on in vitro leaf and stem explants of L. pumila. Methods: The capabilities of callus, shoot, and root formation were evaluated by culturing both explants on Murashige and Skoog (MS) medium supplemented with various PGRs at the concentrations of 0, 1, 3, 5, and 7 mg/L. Results: Medium supplemented with 3 mg/L indole-3-butyric acid (IBA) showed the optimal callogenesis from both leaf and stem explants with (72.34±19.55)% and (70.40±14.14)% efficacy, respectively. IBA was also found to be the most efficient PGR for root induction. A total of (50.00±7.07)% and (77.78±16.47)% of root formation were obtained from the in vitro stem and leaf explants after being cultured for (26.5±5.0) and (30.0±8.5) d in the medium supplemented with 1 and 3 mg/L of IBA, respectively. Shoot formation was only observed in stem explant, with the maximum percentage of formation ((100.00±0.00)%) that was obtained in 1 mg/L zeatin after (11.0±2.8) d of culture. Conclusions: Callus, roots, and shoots can be induced from in vitro leaf and stem explants of L. pumila through the manipulation of types and concentrations of PGRs.
基金Supported by the Ministry of Education(MoE)Malaysia to Universiti Teknologi Malaysia(UTM)under the grant of Higher Institution Centre of Excellence(HICoE)(R.J090301.7846.4J175)Universiti Tunku Abdul Rahman(UTAR)under the research publication scheme(6251/K02)
文摘In this study,a quantitative performance of three commercial polyamide nanofiltration(NF) membranes(i.e.,NF,NF90,and NF270) for phosphorus removal under different feed conditions was investigated.The experiments were conducted at different feed phosphorus concentrations(2.5,5,10,and 15 mg·L^-1) and elevated pHs(pH 1.5,5,10,and 13.5) at a constant feed pressure of 1 MPa using a dead-end filtration cell.Membrane rejection against total phosphorus generally increased with increasing phosphorus concentration regardless of membrane type.In contrast,the permeate flux for all the membranes only decreased slightly with increasing phosphorus concentration.The results also showed that the phosphorus rejections improved while water flux remained almost unchanged with increasing feed solution pH.When the three membranes were exposed to strong pHs(pH 1.5 and 13.5) for a longer duration(up to 6 weeks)it was found that the rejection capability and water flux of the membranes remained very similar throughout the duration,except for NF membrane with marginal decrement in phosphorus rejection.Adsorption study also revealed that more phosphorus was adsorbed onto the membrane structure at alkaline conditions(pH 10 and 13.5) compared to the same membranes tested at lower pHs(pH 1.5 and 5).In eonelusion,NF270 membrane outperformed Nf and NF90 membranes owing to its desirable performance of water flux and phosphorus rejection particularly under strong alkali solution.The NF270 membrane achieved 14.0 L·m^-2·h^-1 and 96.5% rejection against 10 mg·L^-1 phosphorus solution with a pH value of 13.5 at the applied pressure of 1 MPa.
基金Amirkabir University of Technology(Iran)and Helmholtz Institute Freiberg for Research Technology(Germany)for supporting this research work。
文摘The present study initially investigates the kinetics of microwave-assisted grinding and flotation in a porphyry copper deposit.Kinetic tests were conducted on untreated and microwave-irradiated samples by varying the exposure time from 15 to 150 s.Optical microscopy,energy-dispersive X-ray spectroscopy,and scanning electron microscopy were conducted to determine the mineral liberation and particle surface properties,and to perform mineralogical analyses.Results showed that the ore breakage rate constant monotonically increased by increasing the exposure time,particularly for the coarsest fraction size(400μm)due to the creation of thermal stress fractures alongside grain boundaries.Excessive irradiation time(>60 s)led to the creation of oxidized and porous surfaces along with a dramatic change in particle morphologies that result in a substantial reduction of chalcopyrite and pyrite flotation rate constants and ultimate recoveries.We concluded that MW-pretreated copper ore was ground faster than the untreated variety,but the two types have slightly similar floatabilities.
基金supported by Okabe MicaCo.,Ltd.and NEDO (New Energy and Industrial Technology Development Organization) of Japan
文摘The adsorption/plasma decomposition with the combination of adsorption honeycomb-sheets and a plasma element is a new technology for small-sized apparatuses to decompose volatile organic compounds （VOCs） at concentrations lower than about 100 ppm. The feasibility of the prototype adsorption/plasma decomposition apparatus was evaluated with the simulated exhausts containing one VOC component and with real exhausts from a painting booth and an adhesion factory. The apparatus decomposed VOCs effectively at the painting booth exhaust but not always satisfactorily at the adhesion factory exhaust. The performance test results with real exhausts were discussed with respect to the concentration and discharge pattern of the exhausts and the basic properties of the system such as cooperation of adsorption and plasma reaction and the concentration dependence of the performance.
