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ZIF-8/ZIF-67衍生钴氮共修饰碳的合成及电催化性能研究 被引量:3
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作者 孙梦龙 党姣娥 +2 位作者 张永伟 刘卓磊 云斯宁 《稀有金属》 EI CAS CSCD 北大核心 2024年第2期288-295,共8页
开发并利用高效廉价的电催化剂来代替传统的贵金属铂(Pt)基催化剂,对新能源材料与器件的开发和利用意义重大。以锌/钴基沸石咪唑酯骨架材料(ZIF-8/ZIF-67)为前驱体,通过不同的热解方式,合成表面原位生长碳纳米管的钴氮共修饰碳十二面体(... 开发并利用高效廉价的电催化剂来代替传统的贵金属铂(Pt)基催化剂,对新能源材料与器件的开发和利用意义重大。以锌/钴基沸石咪唑酯骨架材料(ZIF-8/ZIF-67)为前驱体,通过不同的热解方式,合成表面原位生长碳纳米管的钴氮共修饰碳十二面体(Co@NCD/CNT)和表面光滑的钴氮共修饰碳十二面体(Co@NCD)。采用X射线衍射仪(XRD)、拉曼光谱仪(Raman)、场发射扫描电镜(FESEM)对合成催化剂的组份和形貌进行表征。XRD图谱显示Co@NCD和Co@NCD/CNT为无定型碳结构,并存在Co金属物种。Raman图谱显示Co@NCD/CNT比Co@NCD具有更高的石墨化程度。FESEM图像显示Co@NCD呈表面光滑的十二面体状,Co@NCD/CNT呈十二面体状且表面长有碳纳米管。电化学测试结果显示,Co@NCD/CNT和Co@NCD催化剂在碘电解液体系中的的传荷电阻分别为0.79和0.91Ω·cm^(2),还原峰值电流密度分别为-6.43和-4.46 mA·cm^(2)。由光伏测试结果可知,Co@NCD/CNT对电极催化剂组装的染料敏化太阳能电池获得了8.05%的光电能量转化效率(PCE),优于Co@NCD(7.20%)和Pt(6.95%)对电极组装电池的PCE。50次连续循环伏安测试表明Co@NCD/CNT具有较好的电化学稳定性,可作为潜在类Pt催化剂使用。 展开更多
关键词 对电极 染料敏化太阳能电池 金属有机框架 碳材料
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氧化钼纳米杂化物的可控构筑及催化性能研究 被引量:2
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作者 张丽珊 张永伟 +2 位作者 后玉芝 张阳亮 云斯宁 《稀有金属》 EI CAS CSCD 北大核心 2024年第4期498-507,共10页
开发具有高催化活性的对电极(CE)材料对提升染料敏化太阳能电池(DSSC)的光电转换效率(PCE)具有重要意义。在这项研究中,采用两步水热法,以MoCl_(5)为前驱体,去离子水为氧源,通过添加不同含量的Ni(NO_(3))2·6H_(2)O来可控制备3种不... 开发具有高催化活性的对电极(CE)材料对提升染料敏化太阳能电池(DSSC)的光电转换效率(PCE)具有重要意义。在这项研究中,采用两步水热法,以MoCl_(5)为前驱体,去离子水为氧源,通过添加不同含量的Ni(NO_(3))2·6H_(2)O来可控制备3种不同形貌的氧化钼纳米催化剂(MoO_(2),MoO_(3)和MoO_(2)@MoO_(3))。采用X射线衍射仪(XRD)、X射线光电子能谱仪(XPS)和场发射扫描电镜(FESEM)对3种氧化钼纳米催化剂进行结构和形貌表征。由XRD结果可知:MoO_(2)和MoO_(3)分别为单斜相和正交晶相。由XPS结果可知:MoO_(2),MoO_(3)和MoO_(2)@MoO_(3)催化剂中都仅存在元素Mo和O的特征峰,无其余杂质存在。由FESEM结果可知:3种纳米催化剂的分别为球状MoO_(2),带状MoO_(3)以及带状上负载球状的MoO_(2)@MoO_(3)。由电化学和光伏性能测试结果可知:MoO_(2),MoO_(3)和MoO_(2)@MoO_(3)催化剂在I3-/I-电解液体系中的传荷电阻分别为85.09,16.33和3.66Ω·cm^(2)。使用MoO_(2),MoO_(3)和MoO_(2)@MoO_(3)对电极催化剂材料组装的DSSC,获得的PCE分别为7.13%,6.70%和7.28%,高于Pt电极的PCE(6.46%)。100次连续循环伏安测试结果表明:3种对电极材料具有较好的电化学稳定性可作为潜在催化剂材料使用。 展开更多
关键词 氧化钼 对电极(CE) 染料敏化太阳能电池(DSSC) 催化活性 纳米杂化物
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The Epidemiology of Tuberculosis in Western Sudan during the Sudan War 2023-2024
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作者 Amal Khalil Yousif Mohammed Maysa Khowgali Abd Alla Babker +12 位作者 Esraa Daffalla Mohamed Ahmed Hasabsidu Adam Dafea Tumadir Mohammed Adam Tasneem Alfaki Mohamedelnour Monwer Mirghani Kamal Eldin Mirghani Ahmed Eldisugi Hassan Mohammed Humida Mustafa Elnour Hussein Bahar Hikmat Siddig Elzain Elnour Tomadir Elfaki Mohamedelnour Monawer Gesmelseid Abdelgader Gesmelseid Saror Ahmed Amin Mohammed Ahmed Najla Adam Elsharef Salem Hussain Gadelkarim Ahmed 《Advances in Infectious Diseases》 2024年第4期691-701,共11页
Background: Tuberculosis is endemic in Sudan and has witnessed a major surge amid the country’s continuous conflict. The goal of this study is to analyze the epidemiological aspects of tuberculosis in Western Sudan f... Background: Tuberculosis is endemic in Sudan and has witnessed a major surge amid the country’s continuous conflict. The goal of this study is to analyze the epidemiological aspects of tuberculosis in Western Sudan from 2023 to 2024, during the Sudan War. Methodology: This is a retrospective descriptive study that was carried out at El-Obeid Teaching Hospital in North Kordofan State, Sudan, during August and September 2024. All information on tuberculosis patients diagnosed between 15 April 2023, and 15 April 2024, was obtained from the hospital. Results: The results showed that 71% of the 751 tuberculosis patients had pulmonary tuberculosis, while 29% had extrapulmonary tuberculosis. Among the 533 patients with pulmonary tuberculosis, 74.3% were male and 62% were female. Among the 218 patients with extrapulmonary tuberculosis, 19% were males and 37.9% were females. The predominant age group for pulmonary tuberculosis was 19 - 25 years, followed by ≥46 and 26 - 35 years, with incidence rates of 25.3%, 25%, and 24.6%, respectively. Extrapulmonary tuberculosis was most prevalent in those aged ≥ 46 years, followed by those aged ≤ 18 years and 26 - 35 years, representing 38%, 18.3%, and 16%, respectively. Conclusion: Tuberculosis is prevalent in western Sudan and has seen a significant rise during the region’s conflict. Tuberculosis predominantly impacts individuals in their younger years. The heightened operations of conventional gold mining, coupled with the escalating urban air pollution, have markedly influenced the elevated epidemiological rates of the disease in Sudan. A significant number of individuals receive diagnoses and treatment at a delayed stage, potentially facilitating the propagation of infection. 展开更多
关键词 TUBERCULOSIS Pulmonary TB Extra Pulmonary TB SUDAN Mycobacterium Tuberculosis
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Emerging semiconductor ionic materials tailored by mixed ionic-electronic conductors for advanced fuel cells
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作者 Bushra Bibi Atif Nazar +10 位作者 Bin Zhu Fan Yang Muhammad Yousaf Rizwan Raza M.A.K.Yousaf Shah Jung-Sik Kim Muhammad Afzal Yongpeng Lei Yifu Jing Peter Lund Sining Yun 《Advanced Powder Materials》 2024年第6期1-25,共25页
Mixed ionic-electronic conductors(MIECs)play a crucial role in the landscape of energy conversion and storage technologies,with a pronounced focus on electrode materials’application in solid oxide fuel cells(SOFCs)an... Mixed ionic-electronic conductors(MIECs)play a crucial role in the landscape of energy conversion and storage technologies,with a pronounced focus on electrode materials’application in solid oxide fuel cells(SOFCs)and proton-conducting ceramic fuel cells(PCFCs).In parallel,the emergence of semiconductor ionic materials(SIMs)has introduced a new paradigm in the field of functional materials,particularly for both electrode and electrolyte development for low-temperature,300–550℃,SOFCs,and PCFCs.This review article critically delves into the intricate mechanisms underpinning the synergistic relationship between MIECs and SIMs,with a particular emphasis on elucidating the fundamental working principles of semiconductor ionic membrane fuel cells(SIMFCs).By exploring critical facets such as ion-coupled electron transfer/transport,junction effect,energy bands alignment,and theoretical computations,it casts an illuminating spotlight on the transformative potential of MIECs,also involving triple charge conducting oxides(TCOs)in the context of SIMs and advanced fuel cells(FCs).The insights and findings articulated herein contribute substantially to the advancement of SIMs and SIMFCs by tailoring MIECs(TCOs)as promising avenues toward the emergence of high-performance SIMFCs.This scientific quest not only addresses the insistent challenges surrounding efficient charge transfer,ionic transport and power output but also unlocks the profound potential for the widespread commercialization of FC technology. 展开更多
关键词 MIEC SIM e-i coupling SIMFC TCO Surface and interface HETEROSTRUCTURES
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基于光学和扫描显微平台的微尺度实验力学检测技术和装置研究 被引量:6
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作者 李喜德 杨燕 +2 位作者 魏成 彭云 张钊 《实验力学》 CSCD 北大核心 2006年第4期427-438,共12页
本文基于光学和扫描显微平台,介绍了本研究组在微尺度实验力学检测技术和设备方面的最新研究成果。在检测技术方面涉及显微散斑干涉技术、微标记阵列检测技术、晶粒变形分析技术、光学探针动静态变形分析技术;在检测系统和装置方面介绍... 本文基于光学和扫描显微平台,介绍了本研究组在微尺度实验力学检测技术和设备方面的最新研究成果。在检测技术方面涉及显微散斑干涉技术、微标记阵列检测技术、晶粒变形分析技术、光学探针动静态变形分析技术;在检测系统和装置方面介绍了新近开发的双视场薄膜检测系统、散斑微干涉系统、微标记检测平台、AFM和SEM单轴拉伸装置、三维微定位与加载系统、微力传感器及其标定装置、微动平台驱动装置等。探讨了微尺度实验力学检测中的问题和新的检测技术,给出了一些典型的应用和相关装置。 展开更多
关键词 微光学干涉 扫描显微镜 变形测量 微尺度对象 动态测试 力学性能
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摩擦因素对微压痕实验的影响 被引量:6
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作者 张帆 黄克智 +1 位作者 黄永刚 秦江 《工程力学》 EI CSCD 北大核心 2006年第A01期1-6,共6页
材料在发生微米亚微米尺度不均匀变形时表现出尺度效应,微压痕问题是典型代表。目前的微压痕研究中普遍采用无摩擦假设,而相对缺少对摩擦因素的深入研究。基于CMSG低阶应变梯度塑性理论,通过有限元分析研究了摩擦因素对微压痕实验的影... 材料在发生微米亚微米尺度不均匀变形时表现出尺度效应,微压痕问题是典型代表。目前的微压痕研究中普遍采用无摩擦假设,而相对缺少对摩擦因素的深入研究。基于CMSG低阶应变梯度塑性理论,通过有限元分析研究了摩擦因素对微压痕实验的影响。结果表明对于目前普遍采用的较钝的Berkovich压头(简化为圆锥后顶角为140.6?),摩擦的影响并不重要,可以简化为无摩擦情况。 展开更多
关键词 固体力学 压痕 应变梯度 摩擦 尺度效应
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相干梯度敏感(CGS)干涉测量技术及其应用研究 被引量:3
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作者 姚学锋 许蔚 +1 位作者 刘栋梁 金观昌 《实验力学》 CSCD 北大核心 2006年第5期559-566,共8页
首先介绍了相干梯度敏感(CGS:Coherent Gradient Sensing)光学干涉测量技术的最新研究进展;其次,详细介绍了透射CGS方法和反射CGS方法的基本原理及实验技术;最后给出了CGS技术在各种断裂力学研究中的应用,不仅给出了各向同性均匀聚合物... 首先介绍了相干梯度敏感(CGS:Coherent Gradient Sensing)光学干涉测量技术的最新研究进展;其次,详细介绍了透射CGS方法和反射CGS方法的基本原理及实验技术;最后给出了CGS技术在各种断裂力学研究中的应用,不仅给出了各向同性均匀聚合物材料I型、混合型、V型裂纹及梯度材料I型裂纹尖端奇异场的控制方程,而且给出了对应各自情况下的CGS光学条纹模拟与实验图像。研究结果将为实验断裂力学研究提供基础性理论和实验应力分析手段。 展开更多
关键词 相干梯度敏感干涉技术 断裂力学 条纹模式 应力强度因子
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基于余能原理的有限变形问题有限元列式 被引量:3
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作者 彭一江 刘应华 《计算力学学报》 EI CAS CSCD 北大核心 2009年第4期460-465,共6页
利用基面力概念,推导了一种基于余能原理的有限变形问题显式有限元列式,可应用于结构的大位移、大转动问题。以基面力为状态变量来表达单元的余能,将有限变形情况下的单元余能分解为变形余能部分和转动余能部分,利用Lagrange乘子法推导... 利用基面力概念,推导了一种基于余能原理的有限变形问题显式有限元列式,可应用于结构的大位移、大转动问题。以基面力为状态变量来表达单元的余能,将有限变形情况下的单元余能分解为变形余能部分和转动余能部分,利用Lagrange乘子法推导出余能原理有限元的控制方程,编制了相应的非线性有限元程序。通过算例分析,说明该列式和程序的可靠性和精确性。 展开更多
关键词 有限变形 基面力 余能原理 有限元 大位移 大转动
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微梁与基底间的毛细粘附作用
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作者 彭云 李喜德 《实验力学》 CSCD 北大核心 2006年第5期553-558,共6页
在表面微型机械结构的制造过程中,强的毛细相互作用常常使得组成这些结构的微桥、微梁与基底粘附而导致失效。而在微尺度实验中,微桥与微梁又是微尺度材料常数和性能检测的常用的试件样式,如果实验中加载端与被检测的微尺度试件发生毛... 在表面微型机械结构的制造过程中,强的毛细相互作用常常使得组成这些结构的微桥、微梁与基底粘附而导致失效。而在微尺度实验中,微桥与微梁又是微尺度材料常数和性能检测的常用的试件样式,如果实验中加载端与被检测的微尺度试件发生毛细粘附,将直接影响检测数据的准确性。本文应用微悬臂梁试件,讨论微梁与基底间的毛细粘附作用,并通过能量原理计算其粘附力的大小和试件几何尺寸、粘附面距离、粘附液体特性之间的关系。最后应用微散斑干涉,检测粘附平衡态时微桥和微梁的粘附力以及由毛细粘附所导致的弯曲变形,并与理论计算结果进行比较。 展开更多
关键词 毛细粘附 MEMS器件 微尺度实验 变形
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MNbO_(4)/生物质碳复合催化剂的制备和催化性能研究 被引量:1
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作者 王曦 张永伟 +2 位作者 司艺铭 王银号 云斯宁 《功能材料》 CAS CSCD 北大核心 2021年第10期10008-10015,共8页
开发一种适用于非碘体系染料敏化太阳能电池(DSSC)的对电极(CE)催化剂对太阳能的开发利用具有重要的意义。在这项工作中,通过共沉淀法合成了铌基双金属氧化物(MNbO_(4),M=Al,Fe)以及相应的与生物质衍生碳(BC)复合催化剂(MNbO_(4)/BC,M=A... 开发一种适用于非碘体系染料敏化太阳能电池(DSSC)的对电极(CE)催化剂对太阳能的开发利用具有重要的意义。在这项工作中,通过共沉淀法合成了铌基双金属氧化物(MNbO_(4),M=Al,Fe)以及相应的与生物质衍生碳(BC)复合催化剂(MNbO_(4)/BC,M=Al,Fe)。采用X射线衍射仪和场发射扫描电子显微镜对制备的四种材料进行结构和形貌的表征。结果表明,AlNbO_(4)和FeNbO_(4)为高结晶度的单斜相;AlNbO_(4)/BC和FeNbO_(4)/BC是AlNbO_(4)和FeNbO_(4)与三维多孔BC骨架的复合材料。由电催化性能测试和光伏性能测试可知,AlNbO_(4)/BC和FeNbO_(4)/BC催化剂与Cu^(2+)/Cu^(+)电解液界面的电荷转移电阻(R_(ct))比AlNbO_(4)和FeNbO_(4)小,分别为4.27和11.21Ω·cm^(2)。此外,AlNbO_(4)/BC组装的DSSC获得了3.94%的光电能量转换效率,优于Pt基的DSSC(3.29%)。MNbO_(4)/BC复合催化剂在非碘体系的DSSC中被首次探究。 展开更多
关键词 染料敏化太阳能电池 铜氧化还原电对 铌基双金属氧化物 对电极催化剂 生物质衍生碳
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Directional Motion of Droplets in a Conical Tube or on a Conical Fibre 被引量:9
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作者 刘建林 夏热 +1 位作者 李炳蔚 冯西桥 《Chinese Physics Letters》 SCIE CAS CSCD 2007年第11期3210-3213,共4页
Manipulating the directional movement of liquid droplets is of significance for design and fabrication of some microfluidic devices, An energy-based method is adopted to analyse the directional movement of a droplet d... Manipulating the directional movement of liquid droplets is of significance for design and fabrication of some microfluidic devices, An energy-based method is adopted to analyse the directional movement of a droplet deposited in a conical tube or on a conical fibre. We perform an experiment to investigate the directional motion of a droplet in an open conical tube. Our theoretical analysis and experimental observations both demonstrate that surface tension can drive the droplet to move in the conical tube. The critical condition of the liquid moving in the conical tube is presented. We also analyse a droplet on a conical hydrophilic fibre, which can move from the thinner to the thicker end. 展开更多
关键词 coated conductor buffer layer self-epitaxy CEO2
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Base force element method of complementary energy principle for large rotation problems 被引量:9
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作者 Yijiang Peng Yinghua Liu 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2009年第4期507-515,共9页
Using the concept of the base forces, a new finite element method (base force element method, BFEM) based on the complementary energy principle is presented for accurate modeling of structures with large displacemen... Using the concept of the base forces, a new finite element method (base force element method, BFEM) based on the complementary energy principle is presented for accurate modeling of structures with large displacements and large rotations. First, the complementary energy of an element is described by taking the base forces as state variables, and is then separated into deformation and rotation parts for the case of large deformation. Second, the control equations of the BFEM based on the complementary energy principle are derived using the Lagrange multiplier method. Nonlinear procedure of the BFEM is then developed. Finally, several examples are analyzed to illustrate the reliability and accuracy of the BFEM. 展开更多
关键词 Base force element method (BFEM) Complementary energy principle Lagrange multiplier method Geometrically nonlinear Large rotation
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PROPAGATION BEHAVIORS OF SHEAR HORIZONTAL WAVES IN PIEZOELECTRIC-PIEZOMAGNETIC PERIODICALLY LAYERED STRUCTURES 被引量:5
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作者 Jinxi Liu Weiyi Wei Daining Fang 《Acta Mechanica Solida Sinica》 SCIE EI 2010年第1期77-84,共8页
This paper investigates shear horizontal (SH) waves propagating in a periodically layered structure that consists of piezoelectric (PE) layers perfectly bonded with piezomagnetic (PM) layers alternately. The exp... This paper investigates shear horizontal (SH) waves propagating in a periodically layered structure that consists of piezoelectric (PE) layers perfectly bonded with piezomagnetic (PM) layers alternately. The explicit dispersion relations are derived for the two cases when the propagation directions of SH waves are normal to the interface and parallel to the interface, respectively. The asymptotic expressions for dispersion relations are also given when the wave number is extremely small. Numerical results for stop band effect and phase velocity are presented for a periodic system of alternating BaTiO3 and Terfenol-D layers. The influence of volume fraction on stop band effect and dispersion behaviors is discussed and revealed. 展开更多
关键词 piezoelectric material piezomagnetic material periodically layered structure SH waves stop band effect dispersion relation
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Experimental Investigation of Polycrystalline Material Deformation Based on a Grain Scale 被引量:3
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作者 李喜德 杨燕 魏成 《Chinese Physics Letters》 SCIE CAS CSCD 2005年第10期2553-2556,共4页
We propose an experimental approach for investigation of the polycrystalline deformation behaviour at a grain scale. The technique is characterized by the joint application of micro material testing systems and the in... We propose an experimental approach for investigation of the polycrystalline deformation behaviour at a grain scale. The technique is characterized by the joint application of micro material testing systems and the intragranular deformation analysis methods, It is attempting to map the deformation evolution at grain scale during the elastic and plastic deformations of polycrystalline specimens. 展开更多
关键词 SPECKLE PATTERN INTERFEROMETRY MICRO-RAMAN SPECTROSCOPY MULTICRYSTAL
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The indenter tip radius effect in micro- and nanoindentation hardness experiments 被引量:6
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作者 Fan Zhang Yonggang Huang Keh-Chih Hwang 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2006年第1期1-8,共8页
Nix and Gao established an important relation between the microindentation hardness and indentation depth. Such a relation has been verified by many microindentation experiments (indentation depths in the micrometer ... Nix and Gao established an important relation between the microindentation hardness and indentation depth. Such a relation has been verified by many microindentation experiments (indentation depths in the micrometer range), but it does not always hold in nanoindentation experiments (indentation depths approaching the nanometer range). Indenter tip radius effect has been proposed by Qu et al. and others as possibly the main factor that causes the deviation from Nix and Gao's relationship. We have developed an indentation model for micro- and nanoindentation, which accounts for two indenter shapes, a sharp, conical indenter and a conical indenter with a spherical tip. The analysis is based on the conventional theory of mechanism-based strain gradient plasticity established from the Taylor dislocation model to account for the effect of geometrically necessary dislocations. The comparison between numerical result and Feng and Nix's experimental data shows that the indenter tip radius effect indeed causes the deviation from Nix-Gao relation, but it seems not be the main factor. 展开更多
关键词 Taylor dislocation model Strain gradient plasticity Indentation Nix-Gao relation
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ZnMoO_(4)/芦荟衍生多孔碳的化学共沉淀法制备及催化性能 被引量:3
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作者 党长伟 张永伟 +5 位作者 韩凤 党姣娥 刘卓磊 王银号 邓莹莹 云斯宁 《无机化学学报》 SCIE CAS CSCD 北大核心 2022年第3期489-500,共12页
通过两步活化和化学共沉淀法分别制备了芦荟衍生多孔碳(aloe-derived porous carbon,APC)、ZnMoO_(4)和ZnMoO_(4)/APC催化剂,并研究了3种催化剂作为染料敏化太阳能电池(dye-sensitized solar cells,DSSCs)对电极时在D35/Y123染料和Cu^(2... 通过两步活化和化学共沉淀法分别制备了芦荟衍生多孔碳(aloe-derived porous carbon,APC)、ZnMoO_(4)和ZnMoO_(4)/APC催化剂,并研究了3种催化剂作为染料敏化太阳能电池(dye-sensitized solar cells,DSSCs)对电极时在D35/Y123染料和Cu^(2+)/Cu^(+)体系中的电化学特性和光伏性能。通过场发射扫描电子显微镜(FESEM)、X射线光电子能谱(XPS)和N_(2)吸附-脱附测试表征了APC、ZnMoO_(4)和ZnMoO_(4)/APC的微观结构、化学成分、比表面积和孔结构。结果表明:APC为多孔网络结构,比表面积为1439 m^(2)·g^(-1),ZnMoO_(4)纳米颗粒均匀嵌入或分散在APC表面。ZnMoO_(4)/APC在D35或Y123染料和Cu^(2+)/Cu^(+)电解液的DSSC中,分别获得了3.97%和3.72%的光电能量转化效率(power conversion efficiency,PCE),高于同等条件下的APC(2.72%,2.61%)、ZnMoO_(4)(1.24%,1.08%)和Pt电极(2.86%,2.80%)的PCE。 展开更多
关键词 染料敏化太阳能电池 对电极催化剂 Cu^(2+)/Cu^(+)氧化还原电对 D35/Y123染料 生物碳
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A LOWER BOUND LIMIT ANALYSIS OF DUCTILE COMPOSITE MATERIALS 被引量:2
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作者 Zhang Hongtao Liu Yinghua Xu Bingye 《Acta Mechanica Solida Sinica》 SCIE EI 2005年第3期215-224,共10页
The plastic load-bearing capacity of ductile composites such as metal matrix composites is studied with an insight into the microstructures. The macroscopic strength of a composite is obtained by combining the homogen... The plastic load-bearing capacity of ductile composites such as metal matrix composites is studied with an insight into the microstructures. The macroscopic strength of a composite is obtained by combining the homogenization theory with static limit analysis, where the temperature parameter method is used to construct the self-equilibrium stress field. An interface failure model is proposed to account for the effects of the interface on the failure of composites. The static limit analysis with the finite-element method is then formulated as a constrained nonlinear programming problem, which is solved by the Sequential Quadratic Programming (SQP) method. Finally, the macroscopic transverse strength of perforated materials, the macroscopic transverse and off-axis strength of fiber-reinforced composites are obtained through numerical calculation. The computational results are in good agreement with the experimental data. 展开更多
关键词 limit analysis homogenization theory interface failure temperature parameter method
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MnWO_(4)/生物质衍生碳纳米复合催化剂的制备及催化性能 被引量:2
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作者 刘卓磊 李静文 +3 位作者 孙梦龙 张永伟 党长伟 云斯宁 《无机化学学报》 SCIE CAS CSCD 北大核心 2021年第12期2219-2226,共8页
通过共沉淀法合成了双金属氧化物MnWO_(4)镶嵌生物质衍生碳(MnWO_(4)/BC)纳米复合催化剂,并将其作为对电极(counter electrode,CE)催化剂组装了染料敏化太阳能电池(dye-sensitized solar cell,DSSC),探究了MnWO_(4)/BC在非碘体系中的催... 通过共沉淀法合成了双金属氧化物MnWO_(4)镶嵌生物质衍生碳(MnWO_(4)/BC)纳米复合催化剂,并将其作为对电极(counter electrode,CE)催化剂组装了染料敏化太阳能电池(dye-sensitized solar cell,DSSC),探究了MnWO_(4)/BC在非碘体系中的催化性能和光伏性能。结果表明:在铜氧化还原(Cu^(2+)/Cu^(+))电对DSSC中获得的光电能量转换效率(power conversion efficiency,PCE)为3.57%(D35)和1.59%(Y123),高于Pt电极的PCE(3.12%,1.16%);50次连续循环伏安测试表明,MnWO_(4)/BC催化剂具有较好的电化学稳定性。 展开更多
关键词 染料敏化太阳能电池 双金属氧化物 生物质衍生碳 铜氧化还原电对 对电极催化剂
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氮掺杂芦荟碳和磁场对厌氧共发酵系统产甲烷的协同作用 被引量:2
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作者 安锦航 李冰洁 +2 位作者 王凯君 柯腾 云斯宁 《太阳能学报》 EI CAS CSCD 北大核心 2023年第6期532-540,共9页
采用氮掺杂芦荟碳(N-C)作为厌氧共发酵的添加剂,研究其和磁场的协同作用对厌氧共发酵系统的甲烷产量、总化学需氧量(TCOD)去除率、pH值、总固体(TS)和挥发性固体(VS)去除率的影响。结果表明:与对照组CK相比,添加N-C可使发酵系统的产气... 采用氮掺杂芦荟碳(N-C)作为厌氧共发酵的添加剂,研究其和磁场的协同作用对厌氧共发酵系统的甲烷产量、总化学需氧量(TCOD)去除率、pH值、总固体(TS)和挥发性固体(VS)去除率的影响。结果表明:与对照组CK相比,添加N-C可使发酵系统的产气高峰提前、沼气产量增加。给发酵系统施加5 mT的磁场,添加N-C可进一步提升共发酵系统性能。N-C添加剂和磁场协同作用可使产沼气高峰比CK组提前2~3 d,累计沼气产量提高48.4%~101.6%。质量分数为0.30%N-C的添加量使发酵系统获得最高的沼气产量(537.6 mL/g VS)、最高的甲烷含量(59.3%)和甲烷产量(318.8 mL/g VS)、最高的TCOD去除率(79.02%)、最高的TS去除率(44.1%)和VS去除率(55.7%)。最后,解释N-C作为添加剂和磁场在增强厌氧共发酵甲烷产量的协同作用。 展开更多
关键词 磁场 厌氧发酵 甲烷 沼气 氮掺杂芦荟碳 表面官能团
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Mechanical properties of cocoons constructed consecutively by a single silkworm caterpillar,Bombyx mori 被引量:3
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作者 S.Q.Huang H.P.Zhao +3 位作者 X.Q.Feng W.Cui Z.Lin M.Q.Xu 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2008年第2期151-160,共10页
Most animals have the ability to adapt, to some extends and in different ways, the variation or disturbance of environment. In our experiments, we forced a silkworm caterpillar to spin two, three or four thin cocoons ... Most animals have the ability to adapt, to some extends and in different ways, the variation or disturbance of environment. In our experiments, we forced a silkworm caterpillar to spin two, three or four thin cocoons by taking it out from the cocoon being constructed. The mechanical properties of these cocoons were studied by static tensile tests and dynamic mechanical thermal analysis. Though external disturbances may cause the decrease in the total weight of silk spun by the silkworm, a gradual enhancement was interestingly found in the mechanical properties of these thin cocoons. Scanning electron microscopy observations of the fractured specimens of the cocoons showed that there exist several different energy dissipation mechanisms occurred simultaneously at macro-, meso-, and micro-scales, yielding a superior capacity of cocoons to adsorb the energy of possible attacks from the outside and to protect efficiently its pupa against damage. Through evolution of millions of years, therefore, the silkworm Bombyx mori seems to have gained the ability to adapt external disturbances and to redesign a new cocoon with optimized protective function when its first cocoon has been damaged for some reasons. 展开更多
关键词 SILK Silkworm cocoon Mechanical property Biomimetics
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