AIM: To examine the relations of alcohol consumption to the prevalence of metabolic syndrome in Shanghai adults. METHODS: We performed a cross-sectional analysis of data from the randomized multistage stratified clust...AIM: To examine the relations of alcohol consumption to the prevalence of metabolic syndrome in Shanghai adults. METHODS: We performed a cross-sectional analysis of data from the randomized multistage stratified cluster sampling of Shanghai adults, who were evaluated for alcohol consumption and each component of metabolic syndrome, using the adapted U.S. National Cholesterol Education Program criteria. Current alcohol consumption was defined as more than once of alcohol drinking per month. RESULTS: The study population consisted of 3953 participants (1524 men) with a mean age of 54.3 ± 12.1 years. Among them, 448 subjects (11.3%) were current alcohol drinkers, including 405 males and 43 females. After adjustment for age and sex, the prevalence of current alcohol drinking and metabolic syndrome in the general population of Shanghai was 13.0% and 15.3%, respectively. Compared with nondrinkers, the prevalence of hypertriglyceridemia and hypertension was higher while the prevalence of abdominal obesity, low serum high-density-lipoprotein cholesterol (HDL-C) and diabetes mellitus was lower in subjects who consumed alcohol twice or more per month, with a trend toward reducing the prevalence of metabolic syndrome. Among the current alcohol drinkers, systolic blood pressure, HDL-C, fastingplasma glucose, and prevalence of hypertriglyceridemia tended to increase with increased alcohol consumption. However, low-density-lipoprotein cholesterol concentration, prevalence of abdominal obesity, low serum HDL-C and metabolic syndrome showed the tendency to decrease. Moreover, these statistically significant differences were independent of gender and age.CONCLUSION: Current alcohol consumption is associated with a lower prevalence of metabolic syndrome irrespe- ctive of alcohol intake (g/d), and has a favorable influence on HDL-C, waist circumference, and possible diabetes mellitus. However, alcohol intake increases the likelihood of hypertension, hypertriglyceridemia and hyperglycemia. The clinical significance of these findings needs further investigation.展开更多
The use of non-renewable resources by the construction industry has several environmental consequences, contributing to excessive energy consumption and loss of materials. So, the construction sector is always in sear...The use of non-renewable resources by the construction industry has several environmental consequences, contributing to excessive energy consumption and loss of materials. So, the construction sector is always in search of improvement and methods that innovate the existing techniques, aiming at the use of alternative and sustainable materials. Bamboo is a perennial plant with fast growth rate and low cost that has great physical and mechanical characteristics that assure its performance in the building environment. The use of beams with total or partial replacement of steel by bamboo has been well studied, due to the possibility of using the same design methods used in reinforced concrete beams, since the bamboo-reinforced beams meet the Bernoulli-Kirchoff bending theory. The objective of the work was to adapt a design procedure into an electronic spreadsheet for bamboo reinforced concrete beams subjected to four-point bending, with rectangular section, according to Brazilian Standard NBR 6118 (2014). The spreadsheet was tested based on other authors taking into consideration a steel double reinforcement. The resulting values were equivalents to those obtained by the authors, validating the efficiency of the worksheet. This methodology aims to optimize the design process of beams and enable the substitution of steel by bamboo, highlighting the validation, from the structural point of view, obtained by the authors.展开更多
Titanium dioxide(TiO2) has gained burgeoning attention for potassium-ion storage because of its large theoretical capacity,wide availability,and environmental benignity.Nevertheless,the inherently poor conductivity gi...Titanium dioxide(TiO2) has gained burgeoning attention for potassium-ion storage because of its large theoretical capacity,wide availability,and environmental benignity.Nevertheless,the inherently poor conductivity gives rise to its sluggish reaction kinetics and inferior rate capability.Here,we report the direct graphene growth over TiO2 nanotubes by virtue of chemical vapor deposition.Such conformal graphene coatings effectively enhance the conductive environment and well accommodate the volume change of TiO2 upon potassiation/depotassiation.When paired with an activated carbon cathode,the graphene-armored TiO2 nanotubes allow the potassium-ion hybrid capacitor full cells to harvest an energy/power density of 81.2 Wh kg-1/3746.6 W kg-1.We further employ in situ transmis sion electron microscopy and ope rando X-ray diffraction to probe the potassium-ion storage behavior.This work offers a viable and versatile solution to the anode design and in situ probing of potassium storage technologies that is readily promising for practical applications.展开更多
In this study,the three dimensional nanoscale organization in the photoactive layers of poly(3-hexylthiophene) (P3HT) and a methanofullerene derivative (PCBM) is revealed by transmission electron tomography.After anne...In this study,the three dimensional nanoscale organization in the photoactive layers of poly(3-hexylthiophene) (P3HT) and a methanofullerene derivative (PCBM) is revealed by transmission electron tomography.After annealing treatment,either at elevated temperature or during slow solvent evaporation,nanoscale interpenetrating networks are formed with high crystalline order and favorable concentration gradients of both components through the thickness of the photoactive layer.Such a tailored morphology account...展开更多
Electrocatalytic nitrate reduction reaction has attracted increasing attention due to its goal of low carbon emission and environmental protection.Here,we report an efficient NitRR catalyst composed of single Mn sites...Electrocatalytic nitrate reduction reaction has attracted increasing attention due to its goal of low carbon emission and environmental protection.Here,we report an efficient NitRR catalyst composed of single Mn sites with atomically dispersed oxygen(O)coordination on bacterial cellulose-converted graphitic carbon(Mn-O-C).Evidence of the atomically dispersed Mn-(O-C_(2))_(4)moieties embedding in the exposed basal plane of carbon surface is confirmed by X-ray absorption spectroscopy.As a result,the as-synthesized Mn-O-C catalyst exhibits superior NitRR activity with an NH_(3)yield rate(RNH_(3))of 1476.9±62.6μg h^(−1)cm^(−2)at−0.7 V(vs.reversible hydrogen electrode,RHE)and a faradaic efficiency(FE)of 89.0±3.8%at−0.5 V(vs.RHE)under ambient conditions.Further,when evaluated with a practical flow cell,Mn-O-C shows a high RNH_(3)of 3706.7±552.0μg h^(−1)cm^(−2)at a current density of 100 mA cm−2,2.5 times of that in the H cell.The in situ FT-IR and Raman spectroscopic studies combined with theoretical calculations indicate that the Mn-(O-C_(2))_(4)sites not only effectively inhibit the competitive hydrogen evolution reaction,but also greatly promote the adsorption and activation of nitrate(NO_(3)^(−)),thus boosting both the FE and selectivity of NH_(3)over Mn-(O-C_(2))_(4)sites.展开更多
Porites coral in the nearshore waters off Hainan Island can give off yellowish\|green fluorescence under UV laser induction. After fitting the data between rainfall and fluorescent intensity, it can be found that both...Porites coral in the nearshore waters off Hainan Island can give off yellowish\|green fluorescence under UV laser induction. After fitting the data between rainfall and fluorescent intensity, it can be found that both appear in a simply linear equation with a correlation coefficient of 0.78. The model equation can be used to reconstruct the rainfall in the past time by means of the determined fluorescent intensity. The correlation diagram of the determined and calculated or hindcast rainfall shows a synchronous change from 1982 to 1997. The peak positions of the variant curve are usually related to the El’nino year. That means the drought and flood recycles are restrained to some extent by globally environmental changes. Therefore, the coral fluorescent intensity acts as a geochemical proxy for reconstructing the rainfall series in the past hundreds of years and predicting the drought\|flood variant tendency in the future time.展开更多
We realize a coherent transfer of mechanical excitation in a finely controlled artificial nanomechanical lattice.We also realize strong dynamic coupling between adjacent high-Q mechanical resonators,via modulated diel...We realize a coherent transfer of mechanical excitation in a finely controlled artificial nanomechanical lattice.We also realize strong dynamic coupling between adjacent high-Q mechanical resonators,via modulated dielectric force at the frequency difference between them.An excitation transfer across a lattice consisting of 7 nanobeams is observed by applying a design sequence of switching for couplings,with the final effective population reaching 0.94.This work not only demonstrates the ability to fully control an artificial lattice but also provides an efficient platform for studying complicated dynamics in one-dimensional systems.展开更多
This study shows that submicron/nanoparticles found in bacterial cells (S. aureus) incubated with polyurethane (a material commonly used for prostheses in odontostomatology) are a consequence of biodestruction. The pr...This study shows that submicron/nanoparticles found in bacterial cells (S. aureus) incubated with polyurethane (a material commonly used for prostheses in odontostomatology) are a consequence of biodestruction. The presence of polyurethane nanoparticles into bacterial vesicles suggests that the internalization process occurs through endocytosis. TEM and FIB/SEM are a suitable set of correlated instruments and techniques for this multi facet investigation: polyurethane particles influence the properties of S. aureus from the morpho-functional standpoint that may have undesirable effects on the human body. S. aureus and C. albicans are symbiotic microorganisms;it was observed that C. albicans has a similar interaction with polyurethane and an increment of the biodestruction capacity is expected by its mutual work with S. aureus.展开更多
Poor cycling stability in lithium–sulfur(Li–S)batteries necessitates advanced electrode/electrolyte design and innovative interlayer architectures.Heterogeneous catalysis has emerged as a promising approach,leveragi...Poor cycling stability in lithium–sulfur(Li–S)batteries necessitates advanced electrode/electrolyte design and innovative interlayer architectures.Heterogeneous catalysis has emerged as a promising approach,leveraging the adsorption and catalytic performance on lithium polysulfides(LiPSs)to inhibit LiPSs shuttling and improve redox kinetics.In this study,we report an ultrathin and laminar SnO_(2)@MXene heterostructure interlayer(SnO_(2)@MX),where SnO_(2) quantum dots(QDs)are uniformly distributed across the MXene layer.The combined structure of SnO_(2) QDs and MXene,along with the creation of numerous active boundary sites with coordination electron environments,plays a critical role in manipulating the catalytic kinetics of sulfur species.The Li–S cell with the SnO_(2)@MX-modified separator not only demonstrates superior electrochemical performance compared to cells with a bare separator but also induces homogeneous Li deposition during cycling.As a result,an areal capacity of 7.6 mAh cm^(-2) under a sulfur loading of 7.5 mg cm^(-2) and a high stability over 500 cycles are achieved.Our work demonstrates a feasible strategy of utilizing a laminar separator interlayer for advanced Li–S batteries awaiting commercialization and may shed light on the understanding of heterostructure catalysis with enhanced reaction kinetics.展开更多
A mathematical model capable of providing a forecast of future consumption and import of natural gas is essential for the planning of the Brazilian energy matrix. The aim of this study is to compare three mathematical...A mathematical model capable of providing a forecast of future consumption and import of natural gas is essential for the planning of the Brazilian energy matrix. The aim of this study is to compare three mathematical models, logistic model or model of Verhulst, exponential model or the model of Malthus and the model of von Bertalanffy to analyze the possibilities of these models to describe the evolution of production, import and consumption of natural gas in Brazil, from data provided by the energy balance of the Ministry of Mines and Energy (MME) from 1970 to 2009. A projection of the production and the import of natural gas up to 2017 is made with the models studied in this article and compared with the Brazilian Ten-Year Plan for Expansion of Energy (PDE). At the end of this paper a comparison with the Hubbert model for Brazilian natural gas production is made. These data were adjusted to use the differential equations which describe the models of population growth. All the computer work used in this article: graphics, resolution of differential equations, calculations of linearization and the least squares fitting was prepared in the software MatLab. The results obtained by means of graphs show that the population dynamics models (logistic, exponential and von Bertalanffy) can be applied in modeling the production, import and consumption of natural gas in Brazil.展开更多
基金The Grant-in-Aid from Shanghai Science and Technology Community Fund, No. 01ZD001
文摘AIM: To examine the relations of alcohol consumption to the prevalence of metabolic syndrome in Shanghai adults. METHODS: We performed a cross-sectional analysis of data from the randomized multistage stratified cluster sampling of Shanghai adults, who were evaluated for alcohol consumption and each component of metabolic syndrome, using the adapted U.S. National Cholesterol Education Program criteria. Current alcohol consumption was defined as more than once of alcohol drinking per month. RESULTS: The study population consisted of 3953 participants (1524 men) with a mean age of 54.3 ± 12.1 years. Among them, 448 subjects (11.3%) were current alcohol drinkers, including 405 males and 43 females. After adjustment for age and sex, the prevalence of current alcohol drinking and metabolic syndrome in the general population of Shanghai was 13.0% and 15.3%, respectively. Compared with nondrinkers, the prevalence of hypertriglyceridemia and hypertension was higher while the prevalence of abdominal obesity, low serum high-density-lipoprotein cholesterol (HDL-C) and diabetes mellitus was lower in subjects who consumed alcohol twice or more per month, with a trend toward reducing the prevalence of metabolic syndrome. Among the current alcohol drinkers, systolic blood pressure, HDL-C, fastingplasma glucose, and prevalence of hypertriglyceridemia tended to increase with increased alcohol consumption. However, low-density-lipoprotein cholesterol concentration, prevalence of abdominal obesity, low serum HDL-C and metabolic syndrome showed the tendency to decrease. Moreover, these statistically significant differences were independent of gender and age.CONCLUSION: Current alcohol consumption is associated with a lower prevalence of metabolic syndrome irrespe- ctive of alcohol intake (g/d), and has a favorable influence on HDL-C, waist circumference, and possible diabetes mellitus. However, alcohol intake increases the likelihood of hypertension, hypertriglyceridemia and hyperglycemia. The clinical significance of these findings needs further investigation.
文摘The use of non-renewable resources by the construction industry has several environmental consequences, contributing to excessive energy consumption and loss of materials. So, the construction sector is always in search of improvement and methods that innovate the existing techniques, aiming at the use of alternative and sustainable materials. Bamboo is a perennial plant with fast growth rate and low cost that has great physical and mechanical characteristics that assure its performance in the building environment. The use of beams with total or partial replacement of steel by bamboo has been well studied, due to the possibility of using the same design methods used in reinforced concrete beams, since the bamboo-reinforced beams meet the Bernoulli-Kirchoff bending theory. The objective of the work was to adapt a design procedure into an electronic spreadsheet for bamboo reinforced concrete beams subjected to four-point bending, with rectangular section, according to Brazilian Standard NBR 6118 (2014). The spreadsheet was tested based on other authors taking into consideration a steel double reinforcement. The resulting values were equivalents to those obtained by the authors, validating the efficiency of the worksheet. This methodology aims to optimize the design process of beams and enable the substitution of steel by bamboo, highlighting the validation, from the structural point of view, obtained by the authors.
基金financially supported by the National Natural Science Foundation of China(51702225,11774051,61574034,51672007)the National Basic Research Program of China(No.2016YFA0200103)the Natural Science Foundation of Jiangsu Province(BK20170336)。
文摘Titanium dioxide(TiO2) has gained burgeoning attention for potassium-ion storage because of its large theoretical capacity,wide availability,and environmental benignity.Nevertheless,the inherently poor conductivity gives rise to its sluggish reaction kinetics and inferior rate capability.Here,we report the direct graphene growth over TiO2 nanotubes by virtue of chemical vapor deposition.Such conformal graphene coatings effectively enhance the conductive environment and well accommodate the volume change of TiO2 upon potassiation/depotassiation.When paired with an activated carbon cathode,the graphene-armored TiO2 nanotubes allow the potassium-ion hybrid capacitor full cells to harvest an energy/power density of 81.2 Wh kg-1/3746.6 W kg-1.We further employ in situ transmis sion electron microscopy and ope rando X-ray diffraction to probe the potassium-ion storage behavior.This work offers a viable and versatile solution to the anode design and in situ probing of potassium storage technologies that is readily promising for practical applications.
基金the research program of the Dutch Polymer Institute (DPI),project # 524.Additional financial support was provided by the Dutch Science Organization (NWO).
文摘In this study,the three dimensional nanoscale organization in the photoactive layers of poly(3-hexylthiophene) (P3HT) and a methanofullerene derivative (PCBM) is revealed by transmission electron tomography.After annealing treatment,either at elevated temperature or during slow solvent evaporation,nanoscale interpenetrating networks are formed with high crystalline order and favorable concentration gradients of both components through the thickness of the photoactive layer.Such a tailored morphology account...
基金the financial support from the Natural Science Foundation of China(Grant No.52172106)Anhui Provincial Natural Science Foundation(Grant Nos.2108085QB60 and 2108085QB61)China Postdoctoral Science Foundation(Grant Nos.2020M682057 and 2023T160651).
文摘Electrocatalytic nitrate reduction reaction has attracted increasing attention due to its goal of low carbon emission and environmental protection.Here,we report an efficient NitRR catalyst composed of single Mn sites with atomically dispersed oxygen(O)coordination on bacterial cellulose-converted graphitic carbon(Mn-O-C).Evidence of the atomically dispersed Mn-(O-C_(2))_(4)moieties embedding in the exposed basal plane of carbon surface is confirmed by X-ray absorption spectroscopy.As a result,the as-synthesized Mn-O-C catalyst exhibits superior NitRR activity with an NH_(3)yield rate(RNH_(3))of 1476.9±62.6μg h^(−1)cm^(−2)at−0.7 V(vs.reversible hydrogen electrode,RHE)and a faradaic efficiency(FE)of 89.0±3.8%at−0.5 V(vs.RHE)under ambient conditions.Further,when evaluated with a practical flow cell,Mn-O-C shows a high RNH_(3)of 3706.7±552.0μg h^(−1)cm^(−2)at a current density of 100 mA cm−2,2.5 times of that in the H cell.The in situ FT-IR and Raman spectroscopic studies combined with theoretical calculations indicate that the Mn-(O-C_(2))_(4)sites not only effectively inhibit the competitive hydrogen evolution reaction,but also greatly promote the adsorption and activation of nitrate(NO_(3)^(−)),thus boosting both the FE and selectivity of NH_(3)over Mn-(O-C_(2))_(4)sites.
文摘Porites coral in the nearshore waters off Hainan Island can give off yellowish\|green fluorescence under UV laser induction. After fitting the data between rainfall and fluorescent intensity, it can be found that both appear in a simply linear equation with a correlation coefficient of 0.78. The model equation can be used to reconstruct the rainfall in the past time by means of the determined fluorescent intensity. The correlation diagram of the determined and calculated or hindcast rainfall shows a synchronous change from 1982 to 1997. The peak positions of the variant curve are usually related to the El’nino year. That means the drought and flood recycles are restrained to some extent by globally environmental changes. Therefore, the coral fluorescent intensity acts as a geochemical proxy for reconstructing the rainfall series in the past hundreds of years and predicting the drought\|flood variant tendency in the future time.
文摘We realize a coherent transfer of mechanical excitation in a finely controlled artificial nanomechanical lattice.We also realize strong dynamic coupling between adjacent high-Q mechanical resonators,via modulated dielectric force at the frequency difference between them.An excitation transfer across a lattice consisting of 7 nanobeams is observed by applying a design sequence of switching for couplings,with the final effective population reaching 0.94.This work not only demonstrates the ability to fully control an artificial lattice but also provides an efficient platform for studying complicated dynamics in one-dimensional systems.
文摘This study shows that submicron/nanoparticles found in bacterial cells (S. aureus) incubated with polyurethane (a material commonly used for prostheses in odontostomatology) are a consequence of biodestruction. The presence of polyurethane nanoparticles into bacterial vesicles suggests that the internalization process occurs through endocytosis. TEM and FIB/SEM are a suitable set of correlated instruments and techniques for this multi facet investigation: polyurethane particles influence the properties of S. aureus from the morpho-functional standpoint that may have undesirable effects on the human body. S. aureus and C. albicans are symbiotic microorganisms;it was observed that C. albicans has a similar interaction with polyurethane and an increment of the biodestruction capacity is expected by its mutual work with S. aureus.
基金financial support from the Swiss National Science Foundation via the Southeast Asia–Europe Joint Funding Scheme 2020(Grant No.IZJFZ2_202476)funding from the National Natural Science Foundation of China(Grant Nos.22209118 and 00301054A1073)the Fundamental Research Funds for the Central Universities(Grant Nos.1082204112A26,20826044D3083,and 20822041G4080)。
文摘Poor cycling stability in lithium–sulfur(Li–S)batteries necessitates advanced electrode/electrolyte design and innovative interlayer architectures.Heterogeneous catalysis has emerged as a promising approach,leveraging the adsorption and catalytic performance on lithium polysulfides(LiPSs)to inhibit LiPSs shuttling and improve redox kinetics.In this study,we report an ultrathin and laminar SnO_(2)@MXene heterostructure interlayer(SnO_(2)@MX),where SnO_(2) quantum dots(QDs)are uniformly distributed across the MXene layer.The combined structure of SnO_(2) QDs and MXene,along with the creation of numerous active boundary sites with coordination electron environments,plays a critical role in manipulating the catalytic kinetics of sulfur species.The Li–S cell with the SnO_(2)@MX-modified separator not only demonstrates superior electrochemical performance compared to cells with a bare separator but also induces homogeneous Li deposition during cycling.As a result,an areal capacity of 7.6 mAh cm^(-2) under a sulfur loading of 7.5 mg cm^(-2) and a high stability over 500 cycles are achieved.Our work demonstrates a feasible strategy of utilizing a laminar separator interlayer for advanced Li–S batteries awaiting commercialization and may shed light on the understanding of heterostructure catalysis with enhanced reaction kinetics.
文摘A mathematical model capable of providing a forecast of future consumption and import of natural gas is essential for the planning of the Brazilian energy matrix. The aim of this study is to compare three mathematical models, logistic model or model of Verhulst, exponential model or the model of Malthus and the model of von Bertalanffy to analyze the possibilities of these models to describe the evolution of production, import and consumption of natural gas in Brazil, from data provided by the energy balance of the Ministry of Mines and Energy (MME) from 1970 to 2009. A projection of the production and the import of natural gas up to 2017 is made with the models studied in this article and compared with the Brazilian Ten-Year Plan for Expansion of Energy (PDE). At the end of this paper a comparison with the Hubbert model for Brazilian natural gas production is made. These data were adjusted to use the differential equations which describe the models of population growth. All the computer work used in this article: graphics, resolution of differential equations, calculations of linearization and the least squares fitting was prepared in the software MatLab. The results obtained by means of graphs show that the population dynamics models (logistic, exponential and von Bertalanffy) can be applied in modeling the production, import and consumption of natural gas in Brazil.
