Top-down environmental policies aim to mitigate environmental risks but inevitably lead to economic losses due to the market entry or exit of enterprises.This study developed a universal dynamic agent-based supply cha...Top-down environmental policies aim to mitigate environmental risks but inevitably lead to economic losses due to the market entry or exit of enterprises.This study developed a universal dynamic agent-based supply chain model to achieve tradeoffs between environmental risk reduction and economic sus-tainability.The model was used to conduct high-resolution daily simulations of the dynamic shifts in enterprise operations and their cascading effects on supply chain networks.It includes production,con-sumption,and transportation agents,attributing economic features to supply chain components and cap-turing their interactions.It also accounts for adaptive responses to daily external shocks and replicates realistic firm behaviors.By coupling high spatial-temporal resolution firm-level data from 18916 chemical enterprises,this study investigates the economic and environmental impacts of an environmen-tal policy resulting in the closure of 1800 chemical enterprises over three years.The results revealed a significant economic loss of 25.8 billion USD,ranging from 23.8 billion to 31.8 billion USD.Notably,over 80%of this loss was attributed to supply chain propagation.Counterfactual analyses indicated that imple-menting a staggered shutdown strategy prevented 18.8%of supply chain losses,highlighting the impor-tance of a gradual policy implementation to prevent abrupt supply chain disruptions.Furthermore,the study highlights the effectiveness of a multi-objective policy design in reducing economic losses(about 29%)and environmental risks(about 40%),substantially enhancing the efficiency of the environmental policy.The high-resolution simulations provide valuable insights for policy designers to formulate strategies with staggered implementation and multiple objectives to mitigate supply chain losses and environmental risks and ensure a sustainable future.展开更多
Abandoned mines,especially pyrite-rich ones,release acid mine drainage(AMD)with high acidity and excessive amounts of heavy metals,threatening regional ecosystems.Six samples of mine drainage,nine samples of surface w...Abandoned mines,especially pyrite-rich ones,release acid mine drainage(AMD)with high acidity and excessive amounts of heavy metals,threatening regional ecosystems.Six samples of mine drainage,nine samples of surface water,and twelve samples of sediment were analyzed in this case study of the Dashu pyrite mine in southwest China.A comprehensive analysis of the pollution levels,pollution sources,and potential hazards of eight metals(Ni,Cd,Cu,Zn,Fe,Al,Pb,and Mn)that exceeded regulatory standardswas conducted bymonitoring 24 conventional and characteristic indicators.Ultimately,this research evaluated the environmental hazards associated with abandonedmine water using the"pressure-response"model,thereby providing valuable insights for the effective protection of the environment in mining regions.The primary pollutants in mine water were determined to be SO_(4)^(2−),Fe,and Mn,with concentrations of 7700,1450,and 6.78mg/L,respectively.A clear"source-sink"dynamic was observed between themine water and the surrounding water system.surface water was primarily polluted by Ni and Mn,while water system sediments were primarily polluted by Cu and Hg.Ion ratio and Pearson correlation analyses indicated heavy metals in surface water and sediments originated from the same AMD source.The"pressureresponse"model was used to assess the environmental hazards of water from abandoned mines.Mines W1,W2,W5,and W6 were classified as high-risk,while W3 and W4 were medium-risk.This study offers a novel approach and valuable reference for identifying and classifying environmental risks in abandoned mines and targeting AMD treatment.展开更多
Polycyclic aromatic hydrocarbons(PAHs)are of great concern because they threaten pri-mary productivity,but their specific effects on ecosystem functioning are scarce,hindering a comprehensive understanding of their ec...Polycyclic aromatic hydrocarbons(PAHs)are of great concern because they threaten pri-mary productivity,but their specific effects on ecosystem functioning are scarce,hindering a comprehensive understanding of their ecological risks,especially in eutrophicwaters.The present study was conducted by adding PAHs to four marine phytoplankton species and showed that naphthalene(Nap)and phenanthrene(Phe)induced both stimulatory and in-hibitory effects(>50%)on urea and NO_(3)−uptake by phytoplankton species.In addition,the apparent stimulative effects(>50%)for NH_(4)^(+)were also observed.Overall,38.9%of the sam-ples exhibited stimulation effects after 24 h exposure,which increased to 61.1%after 96 h exposure.This suggested the existence of a lag period,during which a tolerant cell popula-tion could adapt to PAHs.Significant positive correlations(P<0.01)between low and high concentrations of PAH individuals demonstrated that the mode of action for both pollutants on nitrogen uptake by phytoplankton was the same.Species-specific responses were also observed,with 19.0%of Thalassiosira sp.and 24.0%of Tetraselmis sp.exhibited inhibition effects greater than 50%,while 40.9%of Karlodinium veneficum and 27.3%of Rhodomonas salina demonstrated stimulation effects exceeding 50%,providing a unique perspective for exploring the harmful algal bloom of the mixotrophic K.veneficum,in addition to the original consideration of nutrients.The internal mechanisms may lie in differences in energy consumption between N-forms,exposure time and chemical concentrations,aswell as mor-phological characteristics and biochemical structures of the species,which require further investigation.展开更多
Located in northern China,the Hetao Plain is an important agro-economic zone and population centre.The deterioration of local groundwater quality has had a serious impact on human health and economic development.Nowad...Located in northern China,the Hetao Plain is an important agro-economic zone and population centre.The deterioration of local groundwater quality has had a serious impact on human health and economic development.Nowadays,the groundwater vulnerability assessment(GVA)has become an essential task to identify the current status and development trend of groundwater quality.In this study,the Convolutional Neural Network(CNN)and Long Short-Term Memory(LSTM)models are integrated to realize the spatio-temporal prediction of regional groundwater vulnerability by introducing the Self-attention mechanism.The study firstly builds the CNN-LSTM modelwith self-attention(SA)mechanism and evaluates the prediction accuracy of the model for groundwater vulnerability compared to other common machine learning models such as Support Vector Machine(SVM),Random Forest(RF),and Extreme Gradient Boosting(XGBoost).The results indicate that the CNNLSTM model outperforms thesemodels,demonstrating its significance in groundwater vulnerability assessment.It can be posited that the predictions indicate an increased risk of groundwater vulnerability in the study area over the coming years.This increase can be attributed to the synergistic impact of global climate anomalies and intensified local human activities.Moreover,the overall groundwater vulnerability risk in the entire region has increased,evident fromboth the notably high value and standard deviation.This suggests that the spatial variability of groundwater vulnerability in the area is expected to expand in the future due to the sustained progression of climate change and human activities.The model can be optimized for diverse applications across regional environmental assessment,pollution prediction,and risk statistics.This study holds particular significance for ecological protection and groundwater resource management.展开更多
The large-scale exploitation of vanadium(Ⅴ) bearing minerals has led to a massive accumulation of Ⅴ tailings, of which Ⅴ pollution poses severe ecological risks. Although the mechanisms of Ⅴ stress to the microbia...The large-scale exploitation of vanadium(Ⅴ) bearing minerals has led to a massive accumulation of Ⅴ tailings, of which Ⅴ pollution poses severe ecological risks. Although the mechanisms of Ⅴ stress to the microbial community have been reported, the influential pathways in a multi-medium-containing system, for example, the soil-tailings-groundwater system,are unknown. The dynamic redox conditions and substance exchange within the system exhibited complex Ⅴ stress on the local microbial communities. In this study, the influence pathways of Ⅴ stress to the microbial community in the soil-tailings-groundwater system were first investigated. High Ⅴ contents were observed in groundwater(139.2 ± 0.15 μg/L) and soil(98.0–323.8 ± 0.02 mg/kg), respectively. Distinct microbial composition was observed for soil and groundwater, where soil showed the highest level of diversity and richness. Firmicutes, Proteobacteria, Actinobacteria, and Acidobacteria were dominant in soil and groundwater with a sum relative abundance of around 80 %. Based on redundancy analysis and structural equation models, Ⅴ was one of the vital driving factors affecting microbial communities. Groundwater microbial communities were influenced by Ⅴ via Cr, dissolved oxygen, and total nitrogen, while Fe, Mn, and total phosphorus were the key mediators for Ⅴ to affect soil microbial communities. Ⅴ affected the microbial community via metabolic pathways related to carbonaceous matter, which was involved in the establishment of survival strategies for metal stress. This study provides novel insights into the influence pathways of Ⅴ on the microorganisms in tailings reservoir for pollution bioremediation.展开更多
Current research on heterogeneous advanced oxidation processes(HAOPs)predominantly emphasizes catalyst iteration and innovation.Significant efforts have been made to regulate the electron structure and optimize the el...Current research on heterogeneous advanced oxidation processes(HAOPs)predominantly emphasizes catalyst iteration and innovation.Significant efforts have been made to regulate the electron structure and optimize the electron distribution,thereby increasing the catalytic activity.However,this focus often overshadows an equally essential aspect of HAOPs:the adsorption effect.Adsorption is a critical initiator for triggering the interaction of oxidants and contaminants with heterogeneous catalysts.The efficacy of these interactions is influenced by a variety of physicochemical properties,including surface chemistry and pore sizes,which determine the affinities between contaminants and material surfaces.This dispar ity in affinity is pivotal because it underpins the selective removal of contaminants,especially in complex waste streams containing diverse contaminants and competing matrices.Consequently,understanding and mastering these interfacial interactions is fundamentally indispensable not only for improving pro cess efficiency but also for enhancing the selectivity of contaminant removal.Herein,we highlight the importance of adsorption-driven interfacial interactions for fundamentally elucidating the catalytic mechanisms of HAOPs.Such interactions dictate the overall performance of the treatment processes by balancing the adsorption,reaction,and desorption rates on the catalyst surfaces.Elucidating the adsorption effect not only shifts the paradigm in understanding HAOPs but also improves their practical ity in water treatment and wastewater decontamination.Overall,we propose that revisiting adsorption driven interfacial interactions holds great promise for optimizing catalytic processes to develop effective HAOP strategies.展开更多
Although air pollutant emissions have sharply reduced in recent years,the occurrence of PM_(2.5) pollution events remains an intractable environmental problem in Beijing,and regional transport is the key influence fac...Although air pollutant emissions have sharply reduced in recent years,the occurrence of PM_(2.5) pollution events remains an intractable environmental problem in Beijing,and regional transport is the key influence factor.However,it has been difficult to identify regional transport characteristics and the main contributors to pollution events in recent years.In this study,the relative contribution of regional transport was quantified(61.3%)in PM_(2.5) pollution events during 2018-2021 by the Community Multiscale Air Quality model embedded with the Integrated Source Apportionment Model(CMAQ-ISAM).The four regions with the largest fractional contributions to Beijing for all events were Shandong(7.7%),South Hebei(7.3%),Baoding(6.2%),and Langfang(5.8%).Pollution events were classified into the following types based on regional transport directions:local,southwest(SW),southeast(SE),south-mixed(SM),and others.Based on the transport distance,the SW,SE,and SM types can be subdivided into SW-short,SW-long,SE-short,SE-long,SM-short,SM-long distance from southwest,SM-long distance from southeast,and SM-long distance from southwest and southeast.SE-long was regarded as the most important type,with the highest relative frequency(20%).The transport directions were related to the southwest wind at 925 hPa and southeast wind at 1000 hPa in the south of the Beijing–Tianjin–Hebei(BTH)region,and the distance was mainly controlled by wind strength.The wind-field difference can be attributed to the low-pressure and high-pressure systems that control the BTH region.The results suggest that regional joint pollution control should be optimized based on the transport type.展开更多
Rapid screening of inorganic arsenic(iAs)in groundwater used for drinking by hundreds of millions of mostly rural residents worldwide is crucial for health protection.Most commercial field test kits are based on the G...Rapid screening of inorganic arsenic(iAs)in groundwater used for drinking by hundreds of millions of mostly rural residents worldwide is crucial for health protection.Most commercial field test kits are based on the Gutzeit reaction that uses mercury-based reagents for color development,an environmental concern that increasingly limits its utilization.This study further improves the Molybdenum Blue(MB)colorimetric method to allow for faster screening with more stable reagents.More importantly,a portable three-channel colorimeter is developed for screening iAs relative to the WHO drinking water guideline value(10μg/L).Adding the reducing reagents in sequence not only prolongs the storage time to>7 days,but also accelerates the color development time to 6 min in conjunction with lowering the H_(2)SO_(4) concentration in chromogenic reagents.The optimal pH ranges from 1.2 to 1.3 and is achieved by acidifying groundwater to 1%(V/V)HCl.With detection limits of 3.7μg/L for inorganic arsenate(iAs(V))and 3.8μg/L for inorganic arsenite(iAs(Ⅲ)),testing groundwater with-10μg/L of As has a precision<20%.The method works well for a range of phosphate concentrations of 48-950μg/L(0.5-10μmol/L).Concentrations of total_iAs(6-300μg/L),iAs(V)(6-230μg/L)and iAs(Ⅲ)(0-170μg/L)for 14 groundwater samples from Yinchuan Plain,Pearl River Delta,and Jianghan Plain,are in excellent agreements(linear regression slope:0.969-1.029)with the benchmark methods.The improved chemistry here lays the foundation for the MB colorimetric method to become a commercially viable screening tool,with further engineering and design improvement of the colorimeter.展开更多
The copper complexing of dissolved organic matter released from hydrochar(HDOM)affects the former’s environmental behavior.In this study,how hydrothermal temperatures(180,220 and 260℃)influence the molecular-level c...The copper complexing of dissolved organic matter released from hydrochar(HDOM)affects the former’s environmental behavior.In this study,how hydrothermal temperatures(180,220 and 260℃)influence the molecular-level constitutions and Cu(II)binding features of HDOM were elucidated via fourier transform ion cyclotron resonance mass spectrometry and multi-spectroscopic analysis.The findings demonstrated that the almost HDOM molecules had the traits of lower polarity and higher hydrophobicity.As the hydrothermal temperature increased,the molecules with particularly high relative strength gradually disappeared,average molecular weight,percentages of CHON and aliphatic compounds of HDOM reduced while the percentages of CHO and aromatic compounds increased.In general,the fluorescence quenching of Cu(II)weakened as hydrothermal temperature rose and the Cu(II)binding stability constants of fluorophores in HDOM were 4.50–5.31.In addition,the Cu(II) binding order of fluorophores in HDOM showed temperature heterogeneities, andpolysaccharides or aromatic rings of non-fluorescent substances had the fastest responsesto Cu(II) binding. Generally, fluorescent components tend to bind Cu(II) at relatively traceconcentrations (0–40 μmol/L), whereas non-fluorescent substances tend to the bind Cu(II)at relatively higher concentrations (50–100 μmol/L). This study contributed to the predictionof the potential environmental behaviors and risks of Cu(II) at the molecular level afterhydrochar application.展开更多
Hydroxyapatite nanoparticles(HAP NPs)were synthesized by a one‐step hydrothermal method.The surface of HAP NPs was grafted-SH and-COOH chelating groups via in situ surface‐modification with iminodiacetic acid(IDA)an...Hydroxyapatite nanoparticles(HAP NPs)were synthesized by a one‐step hydrothermal method.The surface of HAP NPs was grafted-SH and-COOH chelating groups via in situ surface‐modification with iminodiacetic acid(IDA)and 3‐mercaptopropyl trimethoxysilane(MPS)to afford dual surface‐capped nano‐amendment HAPIDA/MPS.The structure of HAP‐IDA/MPS was characterized,and its adsorption performance for Hg^(2+),Cu^(2+),Zn^(2+),Ni^(2+),Co^(2+),and Cd^(2+)was evaluated.The total adsorption capacity of 0.10 g HAP‐IDA/MPS nano‐amendment for Hg^(2+),Cu^(2+),Zn^(2+),Ni^(2+),Co^(2+),and Cd^(2+)with an initial mass concentration of 20 mg·L^(-1) reached 13.7 mg·g^(-1),about 4.3 times as much as that of HAP.Notably,HAP‐IDA/MPS nano‐amendment displayed the highest immobilization rate for Hg^(2+),possibly because of its chemical reaction with-SH to form sulfide,possessing the lowest solubility product constant among a variety of metal sulfides.展开更多
The limitations of swirl separation in removing microfine oil droplets in water have driven the development of hydrocyclone technology coupled with multiphase or multifield techniques.To enhance microfine oil droplets...The limitations of swirl separation in removing microfine oil droplets in water have driven the development of hydrocyclone technology coupled with multiphase or multifield techniques.To enhance microfine oil droplets separation,a novel hydrocyclone separation coupled with fiber coalescence(HCCFC) was designed.The interaction between fiber balls and oil droplets inside the hydrocyclone,including droplet coalescence and breakage,was investigated.The influence of different operating parameters on separation efficiency was discussed.The results showed that fiber balls promoted oil droplet coalescence when the inlet droplet size(D_(43)) was below 22.37 μm but caused droplet breakage above this threshold.The coalescence performance of HCCFC improved with increasing inlet oil content but declined beyond 450 mg·L^(-1).Separation experiments confirmed that HCCFC outperformed conventional hydrocyclone,with separation efficiency increasing by 2.9% to 20.0%.As the fiber ball content and inlet flow rate increased,the separation efficiency showed a trend of first increasing and then decreasing.Additionally,HCCFC's separation efficiency varied with inlet oil droplet size distribution,showing the most significant enhancement when D_(43) was 22.37 μm,where separation efficiency increased by 14.4%.These findings offer insights into the development and application of multiphase coupled with hydrocyclone technology.展开更多
In this study,a Fe,N-decorated carbocatalyst(FeCN@X)based on Fe-MOFs was synthesized to activate peroxydisulfate(PDS)for removing sulfadiazine(SDZ)from water.The surface morphology and structure of FeCN@X was characte...In this study,a Fe,N-decorated carbocatalyst(FeCN@X)based on Fe-MOFs was synthesized to activate peroxydisulfate(PDS)for removing sulfadiazine(SDZ)from water.The surface morphology and structure of FeCN@X was characterized by scanning electron microscopy,X-ray diffraction,and X-ray photoelectron spec troscopy.FeCN@1000,formed at the pyrolysis temperature of 1000℃,exhibited the best catalytic performance for degrade SDZ in the presence of 0.15 g·L^(-1)catalyst and 0.5 mmol·L^(-1)PDS,and the reaction conversion rate was 0.199 L·mmol^(-1).Moreover,the effects of experimental conditions,coexisting anions and fulvic acid on catalytic performance of FeCN@1000 were investigated.The excellent potential of FeCN@1000 as a PDS activator in environmental applications was also suggested by the results of its reusability and adaptability experiments.The result of XPS,ROS quenching,EPR and electrochemical experiments showed the degradation of SDZ was primarily driven by an electron transfer process(ETP).Furthermore,Fe(Ⅲ)instead of Fe(Ⅱ)plays a major role in ETP,as Fe(Ⅲ)sites can interact with PDS and form the low-spin surface complexes(Fe(Ⅲ)/CN-PDS).Meanwhile,the small number of~1O_(2) and O_(2)~-·generated by the activation of PDS will promote the system degradation of SDZ activity by accelerating the conversion of Fe(Ⅱ)to Fe(Ⅲ).This study provides new insights for the design of novel PDS activator for efficient degradation of emerging pollutants by ETP.展开更多
Arsenic(As)pollution in coastal wetlands has been receiving growing attention.However,the exact mechanism of As mobility driven by tidal action is still not completely understood.The results reveal that lower total As...Arsenic(As)pollution in coastal wetlands has been receiving growing attention.However,the exact mechanism of As mobility driven by tidal action is still not completely understood.The results reveal that lower total As concentrations in solution were observed in the flood-ebb treatment(FE),with the highest concentration being 7.1μg/L,and As(V)was the predominant species.However,elevated levels of total As in solution were found in the flooded treatment(FL),with a maximum value of 14.5μg/L after 30 days,and As(III)was the predominant form.The results of dissolved organicmatter(DOM)suggest that in the early to mid-stages of the incubation,fulvic acid-like substances might be utilized by microorganisms as electron donors or shuttle bodies,facilitating the reductive release of As/Fe from sediments.Both flood-ebb and flooded treatments promoted the transformation of crystalline iron hydrous oxides-bound As into residual forms.However,prolonged flooded conditions more readily facilitated the formation of specific adsorption forms of As and the reduction of crystalline iron hydrous oxides-bound As,increasing As mobility.In addition,the flood-ebb tides have been found to increase the diversity ofmicrobial populations.The main microbial genera in the flood-ebb treatment included Salinimicrobium,Erythrobacter,Yangia,Sulfitobacter,and Marinobacter.Bacillus,Psychrobacter,and Yangia showed a significant correlation with As(V).In flooded treatment,Bacillus,Pseudomonas,and Geothermobacter played a major role in the reduction and release of As.This study significantly contributes to the current understanding of how As behaves in diverse natural environments.展开更多
CO_(2) emissions(CEs)pose a growing threat to environmental changes and global warming,attracting extensive attention.Here,we leveraged near-real-time monitoring data spanning 2019 to 2022 to investigate spatiotempora...CO_(2) emissions(CEs)pose a growing threat to environmental changes and global warming,attracting extensive attention.Here,we leveraged near-real-time monitoring data spanning 2019 to 2022 to investigate spatiotemporal heterogeneity,sectoral contributions,provincial spatial correlation,and driving factors influencing CEs at the provincial level in China.Our analysis,integrating Moran’s Index analysis,Spearman correlation analysis,and the Geographically Weighted Regression model,unveiled China’s consistent world-leading CEs,surpassing 10,000 Mt over the study period.Spatially,CEs exhibited a heterogeneous distribution,with markedly higher emissions in eastern and northern regions compared to western and southern areas.Temporally,CEs displayed significant fluctuations,peaking in the fourth quarter before declining in subsequent quarters.Chinese NewYear and COVID-19 had the biggest effects on CEs,with average daily reductions of-20.8%and-18.9%,respectively,compared to the four-year average and the same period in 2019.Sectoral analysis highlighted the power and industry sectors as primary contributors to CEs in China,jointly accounting for 37.9%-40.2%and 43.5%-46.4%of total CEs,respectively.Spatial clustering analysis identified a distinct High-High agglomeration region,predominantly encompassing provinces such as Inner Mongolia,Shandong and Jiangsu.Furthermore,total energy consumption and electricity consumption emerged as significant drivers of CEs,exhibiting correlation coefficients exceeding 0.9,followed by exhaust emissions,population size,and gross domestic product.Moreover,the influence of drivers on provincial CEs exhibited notable spatial heterogeneity,with regression coefficients displaying a decreasing gradient from north to south.These findings provide scientific and technological support to realize the provincial dual-carbon goals in China.展开更多
The North China Plain(NCP)frequently experiences ozone pollution events,which are generally related to cross-border transport at multiple scales.However,current methods of calculating ozone transport are insufficient ...The North China Plain(NCP)frequently experiences ozone pollution events,which are generally related to cross-border transport at multiple scales.However,current methods of calculating ozone transport are insufficient to account for ozone transport at different altitudes.To further understand the characteristics of ozone transport,we applied theWeather Research and Forecasting(WRF)model and the Comprehensive Air Quality Model with Extensions(CAMx)based on flux calculation method.The results showed that the simulated flux calculation method was suitable for revealing the evolutionary trend of ozone fluxes.Monthly inflows,outflows,and total net fluxes ranged from-32985.45 to 37361.46 t/d and indicated strong transport and significant spatial and temporal variations of ozone in the urban boundary segments.Vertical distribution analysis of the net ozone fluxes demonstrated that the net fluxes varied with the altitude,and the altitude at which the corresponding peaks were located had a strong correlation with the neighborhood and season.It was noteworthy that there were three main transport directions throughout the year,namely northwest-southeast(NW-SE),southeast-northwest(SE-NW),and southwestnortheast(SW-NE).Additionally,the ozone flux was mainly affected by temperature,wind speed,and ozone concentration,with the correlation coefficient varying by season and altitude,up to 0.78.Moreover,the correlation analysis of ozone flux and wind direction in each city further verified the accuracy of the transport direction.This paper can provide scientific and technological support for the study of ozone generation mechanisms and the solution of urban/interregional ozone pollution problems.展开更多
In this study,an efficient stabilizer material for cadmium(Cd^(2+))treatment was successfully prepared by simply co-milling olivine with magnesite.Several analyticalmethods including XRD,TEM,SEM and FTIR,combined with...In this study,an efficient stabilizer material for cadmium(Cd^(2+))treatment was successfully prepared by simply co-milling olivine with magnesite.Several analyticalmethods including XRD,TEM,SEM and FTIR,combined with theoretical calculations(DFT),were used to investigate mechanochemical interfacial reaction between twominerals,and the reaction mechanism of Cd removal,with ion exchange between Cd^(2+)and Mg^(2+)as the main pathway.A fixation capacity of Cd^(2+)as high as 270.61 mg/g,much higher than that of the pristine minerals and even the individual/physical mixture of milled olivine and magnesite,has been obtained at optimized conditions,with a neutral pH value of the solution after treatment to allow its direct discharge.The as-proposed Mg-based stabilizer with various advantages such as cost benefits,green feature etc.,will boosts the utilization efficiency of naturalminerals over the elaborately prepared adsorbents.展开更多
In the current era of renewable energy prominence,the wide operational capacity of coal-fired boilers has emerged as crucial for ensuring the sustainability of power plants.However,attaining ultra-low nitrogen oxides(...In the current era of renewable energy prominence,the wide operational capacity of coal-fired boilers has emerged as crucial for ensuring the sustainability of power plants.However,attaining ultra-low nitrogen oxides(NO_x)emissions during periods of low-load operations presents a significant and persistent challenge for coal power enterprises.While techniques such as biomass re-burning and advanced re-burning have shown promise in enhancing NO reduction effciency above 800℃,their elevated levels of chlorine(Cl)and alkali metals pose potential risks to boiler equipment integrity.Therefore,this study proposes the utilization of biomass char derived from pyrolysis as a dual-purpose solution to enhance NO reduction efficiency while safeguarding boiler integrity during low-load operations.Findings indicate that pyrolysis treatment effectively reduces the Cl and alkali metal content of biomass.Specifically,it was determined that biomass char produced through deeply pyrolysis at 300℃achieves the highest NO reduction efficiency while minimizing the presence of harmful components.At a reduction temperature of 700℃,both re-burning and advanced re-burning techniques exhibit NO reduction efficiencies of 55.90%and 62.22%,which is already an ideal deficiency at low temperatures.The addition of water vapor at 700-800℃obviously avoids the oxidation of ammonia to NO in advanced reburning.Upon further analysis,denitrification efficiency in biomass char re-burning and advanced reburning is influenced not only by volatile content but also by physicochemical properties such as porosity and surface functional group distribution under certain reaction conditions.This study provides a theoretical framework for the industrial implementation of biomass char for NO control in coal-fired power plants,offering insights into optimizing NO reduction efficiency while mitigating potential risks to boiler equipment.展开更多
Poly(butylene succinate-co-furandicarboxylate)(PBSF)and poly(butylene adipateco-furandicarboxylate)(PBAF)are novel furandicarboxylic acid-based biodegradable copolyesters with great potential to replace fossil-derived...Poly(butylene succinate-co-furandicarboxylate)(PBSF)and poly(butylene adipateco-furandicarboxylate)(PBAF)are novel furandicarboxylic acid-based biodegradable copolyesters with great potential to replace fossil-derived terephthalic acid-based copolyesters such as poly(butylene succinate-co-terephthalate)(PBST)and poly(butylene adipate-co-terephthalate)(PBAT).In this study,quantum chemistry techniques after molecular dynamics simulations are employed to investigate the degradationmechanism of PBSF and PBAF catalyzed by Candida antarctica lipase B(CALB).Computational analysis indicates that the catalytic reaction follows a four-step mechanism resembling the ping-pong bibi mechanism,with the initial two steps being acylation reactions and the subsequent two being hydrolysis reactions.Notably,the first step of the hydrolysis is identified as the rate-determining step.Moreover,by introducing single-point mutations to expand the substrate entrance tunnel,the catalytic distance of the first acylation step decreases.Additionally,energy barrier of the rate-determining step is decreased in the PBSF system by site-directed mutations on key residues increasing hydrophobicity of the enzyme’s active site.This study unprecedently show the substrate binding pocket and hydrophobicity of the enzyme’s active site have the potential to be engineered to enhance the degradation of copolyesters catalyzed by CALB.展开更多
Chinese diesel trucks are the main contributors to NOx and particulate matter(PM)vehicle emissions.An increase in diesel trucks could aggravate air pollution and damage human health.The Chinese government has recently...Chinese diesel trucks are the main contributors to NOx and particulate matter(PM)vehicle emissions.An increase in diesel trucks could aggravate air pollution and damage human health.The Chinese government has recently implemented a series of emission control technologies andmeasures for air quality improvement.This paper summarizes recent control technologies and measures for diesel truck emissions in China and introduces the comprehensive application of control technologies and measures in Beijing-Tianjin-Hebei and surrounding regions.Remote onlinemonitoring technology has been adopted according to the China VI standard for heavy-duty diesel trucks,and control measures such as transportation structure adjustment and heavy pollution enterprise classification control continue to support the battle action plan for pollution control.Perspectives and suggestions are provided for promoting pollution control and supervision of diesel truck emissions:adhere to the concept of overall management and control,vigorously promote the application of systematic and technological means in emission monitoring,continuously facilitate cargo transportation structure adjustment and promote new energy freight vehicles.This paper aims to accelerate the implementation of control technologies and measures throughout China.China is endeavouring to control diesel truck exhaust pollution.China is willing to cooperate with the world to protect the global ecological environment.展开更多
Wastewater contains various high-risk trace organic pollutants,such as antibiotics and endocrine disruptors,which seriously restrict wastewater reuse.Cyclodextrin-based functional materials show great potential in the...Wastewater contains various high-risk trace organic pollutants,such as antibiotics and endocrine disruptors,which seriously restrict wastewater reuse.Cyclodextrin-based functional materials show great potential in the removal of trace pollutants because of their adsorption catalytic synergy.Clarifying the synergistic mechanism of cyclodextrin in oxidation is the key issue in confined catalytic oxidation process design.In this work,we fabricated a BiOIO_(3)@BiOBr/β-CD heterojunction photocatalyst to study the synergistic mechanism of cyclodextrin in the photocatalytic oxidation process.The synergistic mechanism of cyclodextrin was investigated by combining radical chemistry,electrochemistry,spectroscopy,and timedependent density functional theory.Results showed that the excited intermediate free radicals played an important role in promoting the photocatalytic degradation process.The heterojunction photocatalyst loaded withβ-cyclodextrin(β-CD)at the electronic end(C[Cat.]=0.2mg/mL)removed about 97%of bisphenol A(BPA)within 30min,and the first-order kinetic constant(k_(CDBIB)=0.112 min^(−1))was about twice that of the unloadedβ-CD(k_(BIB)=0.057 min^(−1)).Cyclodextrin loading improved the photocatalytic performance of the heterojunction and stimulated the intermediate to increase the free radical yield and regulate the reaction path.展开更多
基金supported by the National Natural Science Foundation of China(52200228 and 72022004)the China Postdoctoral Science Foundation(2022M721817)the National Key Scientific Research Project(2021YFC3200200).
文摘Top-down environmental policies aim to mitigate environmental risks but inevitably lead to economic losses due to the market entry or exit of enterprises.This study developed a universal dynamic agent-based supply chain model to achieve tradeoffs between environmental risk reduction and economic sus-tainability.The model was used to conduct high-resolution daily simulations of the dynamic shifts in enterprise operations and their cascading effects on supply chain networks.It includes production,con-sumption,and transportation agents,attributing economic features to supply chain components and cap-turing their interactions.It also accounts for adaptive responses to daily external shocks and replicates realistic firm behaviors.By coupling high spatial-temporal resolution firm-level data from 18916 chemical enterprises,this study investigates the economic and environmental impacts of an environmen-tal policy resulting in the closure of 1800 chemical enterprises over three years.The results revealed a significant economic loss of 25.8 billion USD,ranging from 23.8 billion to 31.8 billion USD.Notably,over 80%of this loss was attributed to supply chain propagation.Counterfactual analyses indicated that imple-menting a staggered shutdown strategy prevented 18.8%of supply chain losses,highlighting the impor-tance of a gradual policy implementation to prevent abrupt supply chain disruptions.Furthermore,the study highlights the effectiveness of a multi-objective policy design in reducing economic losses(about 29%)and environmental risks(about 40%),substantially enhancing the efficiency of the environmental policy.The high-resolution simulations provide valuable insights for policy designers to formulate strategies with staggered implementation and multiple objectives to mitigate supply chain losses and environmental risks and ensure a sustainable future.
基金supported by the National Key Research and Development Program of China(No.2023YFC3710000)the National Natural Science Foundation of China(Nos.42277078 and 42307118).
文摘Abandoned mines,especially pyrite-rich ones,release acid mine drainage(AMD)with high acidity and excessive amounts of heavy metals,threatening regional ecosystems.Six samples of mine drainage,nine samples of surface water,and twelve samples of sediment were analyzed in this case study of the Dashu pyrite mine in southwest China.A comprehensive analysis of the pollution levels,pollution sources,and potential hazards of eight metals(Ni,Cd,Cu,Zn,Fe,Al,Pb,and Mn)that exceeded regulatory standardswas conducted bymonitoring 24 conventional and characteristic indicators.Ultimately,this research evaluated the environmental hazards associated with abandonedmine water using the"pressure-response"model,thereby providing valuable insights for the effective protection of the environment in mining regions.The primary pollutants in mine water were determined to be SO_(4)^(2−),Fe,and Mn,with concentrations of 7700,1450,and 6.78mg/L,respectively.A clear"source-sink"dynamic was observed between themine water and the surrounding water system.surface water was primarily polluted by Ni and Mn,while water system sediments were primarily polluted by Cu and Hg.Ion ratio and Pearson correlation analyses indicated heavy metals in surface water and sediments originated from the same AMD source.The"pressureresponse"model was used to assess the environmental hazards of water from abandoned mines.Mines W1,W2,W5,and W6 were classified as high-risk,while W3 and W4 were medium-risk.This study offers a novel approach and valuable reference for identifying and classifying environmental risks in abandoned mines and targeting AMD treatment.
基金supported by the National Natural Science Foundation of China(No.42277404)the State Environmental Protection Key Laboratory of Aquatic Ecosystem Health in the Middle and Lower Reaches of Yangtze River(No.AEHKF2023004)+2 种基金the National Key Research and Development Programof China(No.2022YFC3202703)the International Collaboration Program of Chinese Academy of Sciences(Nos.SAJC202403,067GJHZ2023034MI)the Autonomous Deployment Project of Key Laboratory of Lake andWatershed Science for Water Security(No.NKL2023-KP01).
文摘Polycyclic aromatic hydrocarbons(PAHs)are of great concern because they threaten pri-mary productivity,but their specific effects on ecosystem functioning are scarce,hindering a comprehensive understanding of their ecological risks,especially in eutrophicwaters.The present study was conducted by adding PAHs to four marine phytoplankton species and showed that naphthalene(Nap)and phenanthrene(Phe)induced both stimulatory and in-hibitory effects(>50%)on urea and NO_(3)−uptake by phytoplankton species.In addition,the apparent stimulative effects(>50%)for NH_(4)^(+)were also observed.Overall,38.9%of the sam-ples exhibited stimulation effects after 24 h exposure,which increased to 61.1%after 96 h exposure.This suggested the existence of a lag period,during which a tolerant cell popula-tion could adapt to PAHs.Significant positive correlations(P<0.01)between low and high concentrations of PAH individuals demonstrated that the mode of action for both pollutants on nitrogen uptake by phytoplankton was the same.Species-specific responses were also observed,with 19.0%of Thalassiosira sp.and 24.0%of Tetraselmis sp.exhibited inhibition effects greater than 50%,while 40.9%of Karlodinium veneficum and 27.3%of Rhodomonas salina demonstrated stimulation effects exceeding 50%,providing a unique perspective for exploring the harmful algal bloom of the mixotrophic K.veneficum,in addition to the original consideration of nutrients.The internal mechanisms may lie in differences in energy consumption between N-forms,exposure time and chemical concentrations,aswell as mor-phological characteristics and biochemical structures of the species,which require further investigation.
基金supported by the National Key Research and Development Program of China(No.2021YFA0715900).
文摘Located in northern China,the Hetao Plain is an important agro-economic zone and population centre.The deterioration of local groundwater quality has had a serious impact on human health and economic development.Nowadays,the groundwater vulnerability assessment(GVA)has become an essential task to identify the current status and development trend of groundwater quality.In this study,the Convolutional Neural Network(CNN)and Long Short-Term Memory(LSTM)models are integrated to realize the spatio-temporal prediction of regional groundwater vulnerability by introducing the Self-attention mechanism.The study firstly builds the CNN-LSTM modelwith self-attention(SA)mechanism and evaluates the prediction accuracy of the model for groundwater vulnerability compared to other common machine learning models such as Support Vector Machine(SVM),Random Forest(RF),and Extreme Gradient Boosting(XGBoost).The results indicate that the CNNLSTM model outperforms thesemodels,demonstrating its significance in groundwater vulnerability assessment.It can be posited that the predictions indicate an increased risk of groundwater vulnerability in the study area over the coming years.This increase can be attributed to the synergistic impact of global climate anomalies and intensified local human activities.Moreover,the overall groundwater vulnerability risk in the entire region has increased,evident fromboth the notably high value and standard deviation.This suggests that the spatial variability of groundwater vulnerability in the area is expected to expand in the future due to the sustained progression of climate change and human activities.The model can be optimized for diverse applications across regional environmental assessment,pollution prediction,and risk statistics.This study holds particular significance for ecological protection and groundwater resource management.
基金supported by the National Natural Science Foundation of China(No.42377415)the Natural Science Foundation of Sichuan Province(No.2023NSFSC0811),Sichuan Science and Technology Program(Nos.2021JDTD0013 and 2021YFQ0066)+1 种基金the Science and Technology Major Project of Xizhang Autonomous Region of China(No.XZ202201ZD0004G06)the Everest Scientific Research Program(No.80000-2023ZF11405).
文摘The large-scale exploitation of vanadium(Ⅴ) bearing minerals has led to a massive accumulation of Ⅴ tailings, of which Ⅴ pollution poses severe ecological risks. Although the mechanisms of Ⅴ stress to the microbial community have been reported, the influential pathways in a multi-medium-containing system, for example, the soil-tailings-groundwater system,are unknown. The dynamic redox conditions and substance exchange within the system exhibited complex Ⅴ stress on the local microbial communities. In this study, the influence pathways of Ⅴ stress to the microbial community in the soil-tailings-groundwater system were first investigated. High Ⅴ contents were observed in groundwater(139.2 ± 0.15 μg/L) and soil(98.0–323.8 ± 0.02 mg/kg), respectively. Distinct microbial composition was observed for soil and groundwater, where soil showed the highest level of diversity and richness. Firmicutes, Proteobacteria, Actinobacteria, and Acidobacteria were dominant in soil and groundwater with a sum relative abundance of around 80 %. Based on redundancy analysis and structural equation models, Ⅴ was one of the vital driving factors affecting microbial communities. Groundwater microbial communities were influenced by Ⅴ via Cr, dissolved oxygen, and total nitrogen, while Fe, Mn, and total phosphorus were the key mediators for Ⅴ to affect soil microbial communities. Ⅴ affected the microbial community via metabolic pathways related to carbonaceous matter, which was involved in the establishment of survival strategies for metal stress. This study provides novel insights into the influence pathways of Ⅴ on the microorganisms in tailings reservoir for pollution bioremediation.
基金supported by the National Key Research and Development Program of China(2022YFC3205300)the National Natural Science Foundation of China(22176124).
文摘Current research on heterogeneous advanced oxidation processes(HAOPs)predominantly emphasizes catalyst iteration and innovation.Significant efforts have been made to regulate the electron structure and optimize the electron distribution,thereby increasing the catalytic activity.However,this focus often overshadows an equally essential aspect of HAOPs:the adsorption effect.Adsorption is a critical initiator for triggering the interaction of oxidants and contaminants with heterogeneous catalysts.The efficacy of these interactions is influenced by a variety of physicochemical properties,including surface chemistry and pore sizes,which determine the affinities between contaminants and material surfaces.This dispar ity in affinity is pivotal because it underpins the selective removal of contaminants,especially in complex waste streams containing diverse contaminants and competing matrices.Consequently,understanding and mastering these interfacial interactions is fundamentally indispensable not only for improving pro cess efficiency but also for enhancing the selectivity of contaminant removal.Herein,we highlight the importance of adsorption-driven interfacial interactions for fundamentally elucidating the catalytic mechanisms of HAOPs.Such interactions dictate the overall performance of the treatment processes by balancing the adsorption,reaction,and desorption rates on the catalyst surfaces.Elucidating the adsorption effect not only shifts the paradigm in understanding HAOPs but also improves their practical ity in water treatment and wastewater decontamination.Overall,we propose that revisiting adsorption driven interfacial interactions holds great promise for optimizing catalytic processes to develop effective HAOP strategies.
基金supported by the National Key R&D program of China(No.2022YFC3703404)the National Natural Science Foundation of China(No.22188102)the Samsung Advanced Institute of Technology.
文摘Although air pollutant emissions have sharply reduced in recent years,the occurrence of PM_(2.5) pollution events remains an intractable environmental problem in Beijing,and regional transport is the key influence factor.However,it has been difficult to identify regional transport characteristics and the main contributors to pollution events in recent years.In this study,the relative contribution of regional transport was quantified(61.3%)in PM_(2.5) pollution events during 2018-2021 by the Community Multiscale Air Quality model embedded with the Integrated Source Apportionment Model(CMAQ-ISAM).The four regions with the largest fractional contributions to Beijing for all events were Shandong(7.7%),South Hebei(7.3%),Baoding(6.2%),and Langfang(5.8%).Pollution events were classified into the following types based on regional transport directions:local,southwest(SW),southeast(SE),south-mixed(SM),and others.Based on the transport distance,the SW,SE,and SM types can be subdivided into SW-short,SW-long,SE-short,SE-long,SM-short,SM-long distance from southwest,SM-long distance from southeast,and SM-long distance from southwest and southeast.SE-long was regarded as the most important type,with the highest relative frequency(20%).The transport directions were related to the southwest wind at 925 hPa and southeast wind at 1000 hPa in the south of the Beijing–Tianjin–Hebei(BTH)region,and the distance was mainly controlled by wind strength.The wind-field difference can be attributed to the low-pressure and high-pressure systems that control the BTH region.The results suggest that regional joint pollution control should be optimized based on the transport type.
基金the National Key R&D Program of China(No.2021YFA0715900)the National Natural Science Foundation of China(No.41831279)+2 种基金the Shenzhen Key Laboratory of Precision Measurement and Early Warning Technology for Urban Environmental Health Risks(No.ZDSYS20220606100604008)the Guangdong Province Bureau of Education(No.2020KCXTD006)the Guangdong Provincial Key Laboratory of Soil and Groundwater Pollution Control(No.2023B1212060002).
文摘Rapid screening of inorganic arsenic(iAs)in groundwater used for drinking by hundreds of millions of mostly rural residents worldwide is crucial for health protection.Most commercial field test kits are based on the Gutzeit reaction that uses mercury-based reagents for color development,an environmental concern that increasingly limits its utilization.This study further improves the Molybdenum Blue(MB)colorimetric method to allow for faster screening with more stable reagents.More importantly,a portable three-channel colorimeter is developed for screening iAs relative to the WHO drinking water guideline value(10μg/L).Adding the reducing reagents in sequence not only prolongs the storage time to>7 days,but also accelerates the color development time to 6 min in conjunction with lowering the H_(2)SO_(4) concentration in chromogenic reagents.The optimal pH ranges from 1.2 to 1.3 and is achieved by acidifying groundwater to 1%(V/V)HCl.With detection limits of 3.7μg/L for inorganic arsenate(iAs(V))and 3.8μg/L for inorganic arsenite(iAs(Ⅲ)),testing groundwater with-10μg/L of As has a precision<20%.The method works well for a range of phosphate concentrations of 48-950μg/L(0.5-10μmol/L).Concentrations of total_iAs(6-300μg/L),iAs(V)(6-230μg/L)and iAs(Ⅲ)(0-170μg/L)for 14 groundwater samples from Yinchuan Plain,Pearl River Delta,and Jianghan Plain,are in excellent agreements(linear regression slope:0.969-1.029)with the benchmark methods.The improved chemistry here lays the foundation for the MB colorimetric method to become a commercially viable screening tool,with further engineering and design improvement of the colorimeter.
基金supported by the National Natural Science Foundation of China(No.42307090)the Open Subject from State Environmental Protection Key Laboratory of Aquatic Ecosystem Health in theMiddle and Lower Reaches of Yangtze River(No.AEHKF2023008).
文摘The copper complexing of dissolved organic matter released from hydrochar(HDOM)affects the former’s environmental behavior.In this study,how hydrothermal temperatures(180,220 and 260℃)influence the molecular-level constitutions and Cu(II)binding features of HDOM were elucidated via fourier transform ion cyclotron resonance mass spectrometry and multi-spectroscopic analysis.The findings demonstrated that the almost HDOM molecules had the traits of lower polarity and higher hydrophobicity.As the hydrothermal temperature increased,the molecules with particularly high relative strength gradually disappeared,average molecular weight,percentages of CHON and aliphatic compounds of HDOM reduced while the percentages of CHO and aromatic compounds increased.In general,the fluorescence quenching of Cu(II)weakened as hydrothermal temperature rose and the Cu(II)binding stability constants of fluorophores in HDOM were 4.50–5.31.In addition,the Cu(II) binding order of fluorophores in HDOM showed temperature heterogeneities, andpolysaccharides or aromatic rings of non-fluorescent substances had the fastest responsesto Cu(II) binding. Generally, fluorescent components tend to bind Cu(II) at relatively traceconcentrations (0–40 μmol/L), whereas non-fluorescent substances tend to the bind Cu(II)at relatively higher concentrations (50–100 μmol/L). This study contributed to the predictionof the potential environmental behaviors and risks of Cu(II) at the molecular level afterhydrochar application.
文摘Hydroxyapatite nanoparticles(HAP NPs)were synthesized by a one‐step hydrothermal method.The surface of HAP NPs was grafted-SH and-COOH chelating groups via in situ surface‐modification with iminodiacetic acid(IDA)and 3‐mercaptopropyl trimethoxysilane(MPS)to afford dual surface‐capped nano‐amendment HAPIDA/MPS.The structure of HAP‐IDA/MPS was characterized,and its adsorption performance for Hg^(2+),Cu^(2+),Zn^(2+),Ni^(2+),Co^(2+),and Cd^(2+)was evaluated.The total adsorption capacity of 0.10 g HAP‐IDA/MPS nano‐amendment for Hg^(2+),Cu^(2+),Zn^(2+),Ni^(2+),Co^(2+),and Cd^(2+)with an initial mass concentration of 20 mg·L^(-1) reached 13.7 mg·g^(-1),about 4.3 times as much as that of HAP.Notably,HAP‐IDA/MPS nano‐amendment displayed the highest immobilization rate for Hg^(2+),possibly because of its chemical reaction with-SH to form sulfide,possessing the lowest solubility product constant among a variety of metal sulfides.
基金sponsored by the National Science Fund for Distinguished Young Scholars,China(22225804)the National Natural Science Foundation of China(22078102,22408101,22308105)。
文摘The limitations of swirl separation in removing microfine oil droplets in water have driven the development of hydrocyclone technology coupled with multiphase or multifield techniques.To enhance microfine oil droplets separation,a novel hydrocyclone separation coupled with fiber coalescence(HCCFC) was designed.The interaction between fiber balls and oil droplets inside the hydrocyclone,including droplet coalescence and breakage,was investigated.The influence of different operating parameters on separation efficiency was discussed.The results showed that fiber balls promoted oil droplet coalescence when the inlet droplet size(D_(43)) was below 22.37 μm but caused droplet breakage above this threshold.The coalescence performance of HCCFC improved with increasing inlet oil content but declined beyond 450 mg·L^(-1).Separation experiments confirmed that HCCFC outperformed conventional hydrocyclone,with separation efficiency increasing by 2.9% to 20.0%.As the fiber ball content and inlet flow rate increased,the separation efficiency showed a trend of first increasing and then decreasing.Additionally,HCCFC's separation efficiency varied with inlet oil droplet size distribution,showing the most significant enhancement when D_(43) was 22.37 μm,where separation efficiency increased by 14.4%.These findings offer insights into the development and application of multiphase coupled with hydrocyclone technology.
基金supported by Key Research and Development Projects of Shanghai Municipal Commission of Science and Technology(20dz1204000)。
文摘In this study,a Fe,N-decorated carbocatalyst(FeCN@X)based on Fe-MOFs was synthesized to activate peroxydisulfate(PDS)for removing sulfadiazine(SDZ)from water.The surface morphology and structure of FeCN@X was characterized by scanning electron microscopy,X-ray diffraction,and X-ray photoelectron spec troscopy.FeCN@1000,formed at the pyrolysis temperature of 1000℃,exhibited the best catalytic performance for degrade SDZ in the presence of 0.15 g·L^(-1)catalyst and 0.5 mmol·L^(-1)PDS,and the reaction conversion rate was 0.199 L·mmol^(-1).Moreover,the effects of experimental conditions,coexisting anions and fulvic acid on catalytic performance of FeCN@1000 were investigated.The excellent potential of FeCN@1000 as a PDS activator in environmental applications was also suggested by the results of its reusability and adaptability experiments.The result of XPS,ROS quenching,EPR and electrochemical experiments showed the degradation of SDZ was primarily driven by an electron transfer process(ETP).Furthermore,Fe(Ⅲ)instead of Fe(Ⅱ)plays a major role in ETP,as Fe(Ⅲ)sites can interact with PDS and form the low-spin surface complexes(Fe(Ⅲ)/CN-PDS).Meanwhile,the small number of~1O_(2) and O_(2)~-·generated by the activation of PDS will promote the system degradation of SDZ activity by accelerating the conversion of Fe(Ⅱ)to Fe(Ⅲ).This study provides new insights for the design of novel PDS activator for efficient degradation of emerging pollutants by ETP.
基金supported by the National Natural Science Foundation of China(No.41977283)the Qing Lan Project of Jiangsu Province of China.
文摘Arsenic(As)pollution in coastal wetlands has been receiving growing attention.However,the exact mechanism of As mobility driven by tidal action is still not completely understood.The results reveal that lower total As concentrations in solution were observed in the flood-ebb treatment(FE),with the highest concentration being 7.1μg/L,and As(V)was the predominant species.However,elevated levels of total As in solution were found in the flooded treatment(FL),with a maximum value of 14.5μg/L after 30 days,and As(III)was the predominant form.The results of dissolved organicmatter(DOM)suggest that in the early to mid-stages of the incubation,fulvic acid-like substances might be utilized by microorganisms as electron donors or shuttle bodies,facilitating the reductive release of As/Fe from sediments.Both flood-ebb and flooded treatments promoted the transformation of crystalline iron hydrous oxides-bound As into residual forms.However,prolonged flooded conditions more readily facilitated the formation of specific adsorption forms of As and the reduction of crystalline iron hydrous oxides-bound As,increasing As mobility.In addition,the flood-ebb tides have been found to increase the diversity ofmicrobial populations.The main microbial genera in the flood-ebb treatment included Salinimicrobium,Erythrobacter,Yangia,Sulfitobacter,and Marinobacter.Bacillus,Psychrobacter,and Yangia showed a significant correlation with As(V).In flooded treatment,Bacillus,Pseudomonas,and Geothermobacter played a major role in the reduction and release of As.This study significantly contributes to the current understanding of how As behaves in diverse natural environments.
基金supported by the National Natural Science Foundation of China(No.52200120)the R&D Program of Beijing Municipal Education Commission(No.KM202310011003).
文摘CO_(2) emissions(CEs)pose a growing threat to environmental changes and global warming,attracting extensive attention.Here,we leveraged near-real-time monitoring data spanning 2019 to 2022 to investigate spatiotemporal heterogeneity,sectoral contributions,provincial spatial correlation,and driving factors influencing CEs at the provincial level in China.Our analysis,integrating Moran’s Index analysis,Spearman correlation analysis,and the Geographically Weighted Regression model,unveiled China’s consistent world-leading CEs,surpassing 10,000 Mt over the study period.Spatially,CEs exhibited a heterogeneous distribution,with markedly higher emissions in eastern and northern regions compared to western and southern areas.Temporally,CEs displayed significant fluctuations,peaking in the fourth quarter before declining in subsequent quarters.Chinese NewYear and COVID-19 had the biggest effects on CEs,with average daily reductions of-20.8%and-18.9%,respectively,compared to the four-year average and the same period in 2019.Sectoral analysis highlighted the power and industry sectors as primary contributors to CEs in China,jointly accounting for 37.9%-40.2%and 43.5%-46.4%of total CEs,respectively.Spatial clustering analysis identified a distinct High-High agglomeration region,predominantly encompassing provinces such as Inner Mongolia,Shandong and Jiangsu.Furthermore,total energy consumption and electricity consumption emerged as significant drivers of CEs,exhibiting correlation coefficients exceeding 0.9,followed by exhaust emissions,population size,and gross domestic product.Moreover,the influence of drivers on provincial CEs exhibited notable spatial heterogeneity,with regression coefficients displaying a decreasing gradient from north to south.These findings provide scientific and technological support to realize the provincial dual-carbon goals in China.
基金supported by the National Natural Science Foundation of China(No.52200120)the R&D Program of Beijing Municipal Education Commission(No.KM202310011003)。
文摘The North China Plain(NCP)frequently experiences ozone pollution events,which are generally related to cross-border transport at multiple scales.However,current methods of calculating ozone transport are insufficient to account for ozone transport at different altitudes.To further understand the characteristics of ozone transport,we applied theWeather Research and Forecasting(WRF)model and the Comprehensive Air Quality Model with Extensions(CAMx)based on flux calculation method.The results showed that the simulated flux calculation method was suitable for revealing the evolutionary trend of ozone fluxes.Monthly inflows,outflows,and total net fluxes ranged from-32985.45 to 37361.46 t/d and indicated strong transport and significant spatial and temporal variations of ozone in the urban boundary segments.Vertical distribution analysis of the net ozone fluxes demonstrated that the net fluxes varied with the altitude,and the altitude at which the corresponding peaks were located had a strong correlation with the neighborhood and season.It was noteworthy that there were three main transport directions throughout the year,namely northwest-southeast(NW-SE),southeast-northwest(SE-NW),and southwestnortheast(SW-NE).Additionally,the ozone flux was mainly affected by temperature,wind speed,and ozone concentration,with the correlation coefficient varying by season and altitude,up to 0.78.Moreover,the correlation analysis of ozone flux and wind direction in each city further verified the accuracy of the transport direction.This paper can provide scientific and technological support for the study of ozone generation mechanisms and the solution of urban/interregional ozone pollution problems.
基金supported by the Key 491 R&D Programof Hubei Province(No.2022BCA083).
文摘In this study,an efficient stabilizer material for cadmium(Cd^(2+))treatment was successfully prepared by simply co-milling olivine with magnesite.Several analyticalmethods including XRD,TEM,SEM and FTIR,combined with theoretical calculations(DFT),were used to investigate mechanochemical interfacial reaction between twominerals,and the reaction mechanism of Cd removal,with ion exchange between Cd^(2+)and Mg^(2+)as the main pathway.A fixation capacity of Cd^(2+)as high as 270.61 mg/g,much higher than that of the pristine minerals and even the individual/physical mixture of milled olivine and magnesite,has been obtained at optimized conditions,with a neutral pH value of the solution after treatment to allow its direct discharge.The as-proposed Mg-based stabilizer with various advantages such as cost benefits,green feature etc.,will boosts the utilization efficiency of naturalminerals over the elaborately prepared adsorbents.
基金supported by the Open Topics of State Key Laboratory of Clean and Efficient Coal-Fired Power Generation and Pollution Control(D2022FK103)National Natural Science Foundation of China(22278250)+1 种基金the Shanxi Province Science and Technology Cooperation and Exchange Special Program(202104041101014)the Shanxi Province Scholarship Council。
文摘In the current era of renewable energy prominence,the wide operational capacity of coal-fired boilers has emerged as crucial for ensuring the sustainability of power plants.However,attaining ultra-low nitrogen oxides(NO_x)emissions during periods of low-load operations presents a significant and persistent challenge for coal power enterprises.While techniques such as biomass re-burning and advanced re-burning have shown promise in enhancing NO reduction effciency above 800℃,their elevated levels of chlorine(Cl)and alkali metals pose potential risks to boiler equipment integrity.Therefore,this study proposes the utilization of biomass char derived from pyrolysis as a dual-purpose solution to enhance NO reduction efficiency while safeguarding boiler integrity during low-load operations.Findings indicate that pyrolysis treatment effectively reduces the Cl and alkali metal content of biomass.Specifically,it was determined that biomass char produced through deeply pyrolysis at 300℃achieves the highest NO reduction efficiency while minimizing the presence of harmful components.At a reduction temperature of 700℃,both re-burning and advanced re-burning techniques exhibit NO reduction efficiencies of 55.90%and 62.22%,which is already an ideal deficiency at low temperatures.The addition of water vapor at 700-800℃obviously avoids the oxidation of ammonia to NO in advanced reburning.Upon further analysis,denitrification efficiency in biomass char re-burning and advanced reburning is influenced not only by volatile content but also by physicochemical properties such as porosity and surface functional group distribution under certain reaction conditions.This study provides a theoretical framework for the industrial implementation of biomass char for NO control in coal-fired power plants,offering insights into optimizing NO reduction efficiency while mitigating potential risks to boiler equipment.
基金supported by the Joint Funds of the National Natural Science Foundation of China(No.U21A20320)the National Natural Science Foundation of China(No.22106102)was also sponsored by the special fund of State Environmental Protection Key Laboratory of Environmental Health Impact Assessment of Emerging Contaminants(No.SEPKLEHIAEC-202203).
文摘Poly(butylene succinate-co-furandicarboxylate)(PBSF)and poly(butylene adipateco-furandicarboxylate)(PBAF)are novel furandicarboxylic acid-based biodegradable copolyesters with great potential to replace fossil-derived terephthalic acid-based copolyesters such as poly(butylene succinate-co-terephthalate)(PBST)and poly(butylene adipate-co-terephthalate)(PBAT).In this study,quantum chemistry techniques after molecular dynamics simulations are employed to investigate the degradationmechanism of PBSF and PBAF catalyzed by Candida antarctica lipase B(CALB).Computational analysis indicates that the catalytic reaction follows a four-step mechanism resembling the ping-pong bibi mechanism,with the initial two steps being acylation reactions and the subsequent two being hydrolysis reactions.Notably,the first step of the hydrolysis is identified as the rate-determining step.Moreover,by introducing single-point mutations to expand the substrate entrance tunnel,the catalytic distance of the first acylation step decreases.Additionally,energy barrier of the rate-determining step is decreased in the PBSF system by site-directed mutations on key residues increasing hydrophobicity of the enzyme’s active site.This study unprecedently show the substrate binding pocket and hydrophobicity of the enzyme’s active site have the potential to be engineered to enhance the degradation of copolyesters catalyzed by CALB.
基金supported by the National Key Research and Development Project (No.2022YFB2602001)the National Research Program for Key Issues in Air Pollution Control (No.DQGG0207).
文摘Chinese diesel trucks are the main contributors to NOx and particulate matter(PM)vehicle emissions.An increase in diesel trucks could aggravate air pollution and damage human health.The Chinese government has recently implemented a series of emission control technologies andmeasures for air quality improvement.This paper summarizes recent control technologies and measures for diesel truck emissions in China and introduces the comprehensive application of control technologies and measures in Beijing-Tianjin-Hebei and surrounding regions.Remote onlinemonitoring technology has been adopted according to the China VI standard for heavy-duty diesel trucks,and control measures such as transportation structure adjustment and heavy pollution enterprise classification control continue to support the battle action plan for pollution control.Perspectives and suggestions are provided for promoting pollution control and supervision of diesel truck emissions:adhere to the concept of overall management and control,vigorously promote the application of systematic and technological means in emission monitoring,continuously facilitate cargo transportation structure adjustment and promote new energy freight vehicles.This paper aims to accelerate the implementation of control technologies and measures throughout China.China is endeavouring to control diesel truck exhaust pollution.China is willing to cooperate with the world to protect the global ecological environment.
基金supported by Program of Shanghai Outstanding Technology Leaders(No.20XD1433900)the National Natural Science Foundation of China(No.52370168).
文摘Wastewater contains various high-risk trace organic pollutants,such as antibiotics and endocrine disruptors,which seriously restrict wastewater reuse.Cyclodextrin-based functional materials show great potential in the removal of trace pollutants because of their adsorption catalytic synergy.Clarifying the synergistic mechanism of cyclodextrin in oxidation is the key issue in confined catalytic oxidation process design.In this work,we fabricated a BiOIO_(3)@BiOBr/β-CD heterojunction photocatalyst to study the synergistic mechanism of cyclodextrin in the photocatalytic oxidation process.The synergistic mechanism of cyclodextrin was investigated by combining radical chemistry,electrochemistry,spectroscopy,and timedependent density functional theory.Results showed that the excited intermediate free radicals played an important role in promoting the photocatalytic degradation process.The heterojunction photocatalyst loaded withβ-cyclodextrin(β-CD)at the electronic end(C[Cat.]=0.2mg/mL)removed about 97%of bisphenol A(BPA)within 30min,and the first-order kinetic constant(k_(CDBIB)=0.112 min^(−1))was about twice that of the unloadedβ-CD(k_(BIB)=0.057 min^(−1)).Cyclodextrin loading improved the photocatalytic performance of the heterojunction and stimulated the intermediate to increase the free radical yield and regulate the reaction path.
