Water supply is a global problem. A study was conducted on twelve (12) traditional wells water in Daba Dagnogo and Gnipi 2 to determine their physico-chemical quality. Two sampling campaigns (dry season and rainy seas...Water supply is a global problem. A study was conducted on twelve (12) traditional wells water in Daba Dagnogo and Gnipi 2 to determine their physico-chemical quality. Two sampling campaigns (dry season and rainy season), were performed on 16 physical and chemical parameters. The results show that the water is acidic with an average pH of 6.41 ± 0.4;moderately mineralized with an average conductivity of 731.14 ± 611.98 μS·cm-1;moderately saline with an average rate of 1.56 ± 1.22. The average temperature of 28.07 ± 0.86°C is above the norm for all wells. All major ions are consistent with WHO standards except calcium and potassium. 41.67% of wells exceed the standard ammonium ion whose average was 1.43 ± 2.79 mg·L-1 nitrate and 100% with an average of 492.42 ± 434.02 mg·L-1. The ion concentrations are highest in the urban area and are higher in the dry season. The quality of the water sampled wells deteriorated. Several factors affect the degradation, namely the shallow wells, their proximity to toilet, the lack of sanitation and poor management of household waste. It will carry out a campaign to educate people to protect the immediate environment of the water points, avoiding the deposit of garbage and to provide the appropriate wells lids.展开更多
Industrial activities have contributed so much to the pollution of water bodies and these pollutions have adversely affected the aquatic ecosystem.This study aimed to investigate the ecological risk evaluation of heav...Industrial activities have contributed so much to the pollution of water bodies and these pollutions have adversely affected the aquatic ecosystem.This study aimed to investigate the ecological risk evaluation of heavy metal accumulation in Aba River bottom sediments:implications for soap and detergent industry wastewater management.Varian AA240 Atomic absorption spectrometer was used to analyse heavy metals.Individual and complex ecological indices were used to evaluate heavy metal contamination in bottom sediments.According to the results,the heavy metal properties of the wastewater indicated that Fe,Pb,Cd,Cr and Cu mean concentration values were higher than the World Health Organization(WHO)and the National Environmental Standards and Regulations Enforcement Agency(NESREA)permissible limits.Heavy metal properties of the surface water in Aba River(dry seasons)showed that Pb,Cd,Cu,Mn,Fe,and Cr,mean concentrations were above the NESREA,WHO and U.S.Environmental Protection Agency(USEPA)permissible limits.Heavy metal properties of the bottom sediments of Aba River(wet and dry season)showed that Pb,Cd,and Fe mean concentrations were significantly higher than the NESREA,WHO and USEPA permissible limits.The heavy metal contamination factor(CF)of sediments obtained from Aba River during the wet and dry season was low and the CFs of each of the assayed heavy metals were less than 1(CD<1).This also signifies the existence of a low contamination in the sediments of the course streams of Aba River during wet and dry season.The pollution load index(PLI)values of Aba River(sediment)indicated that there is no metal pollution at PLI<1 in the sampled sediments.The potential ecological risk index(RI)of Aba River was less than 150(RI<150)indicating a low ecological RI.Abatement of pollutants in the wastewater to permissible concentrations required for natural environment protection is needed.展开更多
Urbanization in small-and medium-sized cities has often been overlooked in urban studies.Research on urbanization has predominantly focused on large metropolitan cities;however,urbanization in small-and medium-sized c...Urbanization in small-and medium-sized cities has often been overlooked in urban studies.Research on urbanization has predominantly focused on large metropolitan cities;however,urbanization in small-and medium-sized cities also contributes to the acceleration of urban sprawl.Urban growth boundary(UGB)is an ecological approach designed to limit urban development.This study aimedto analyze environmental protection priority zonesby combining ecological quality and sensitivity indices to identify the areas suitable for UGB implementation.Tegal City and its surrounding areas(including Tegal and Brebes regencies)of Indonesia were selected as the study area.The ecological quality index was calculated using the normalized difference vegetation index,humidity index,land surface temperature,and normalized difference bare soil index.These indices were subsequently subjected to principal component analysis(PCA)to extract orthogonal factors,which were summed to derive the final index value.In parallel,we mapped and evaluated ecological sensitivity based on spatial planning policies and regulations.The results revealed that ecological quality in Tegal and Brebes regencies was predominantly categorized as good and very good ecological quality,whereas TegalCity exhibited moderate and poor ecological quality.Additionally,over 45.00%of the area in Tegal and Brebes regencies demonstrated very high ecological sensitivity.Consequently,more than 50.00%of the area in Tegal and Brebes regencies,along with 27.00%of Tegal City,were classified as ecological constraint zone,making them potential regionsfor UGB development.The UGB is expected to curtail urban expansion,promote compact city planning,and preserve ecosystem services to achieve urban sustainability.This study implies that planningsmall-and medium-sized cities is important to prevent urban sprawl and maintain environmental health.Designing UGB to limit urban expansion should be enhanced by better knowledge about its ecological functions in supporting urban sustainability.展开更多
Wetland plants and their related environmental interfaces are colonized by a wide range of microbial communities,and the symbiotic system of plants and microorganisms can interact and cooperate with each other,playing...Wetland plants and their related environmental interfaces are colonized by a wide range of microbial communities,and the symbiotic system of plants and microorganisms can interact and cooperate with each other,playing an important role in environmental remediation of metal pollution,which has garnered significant attention.The dominant communities of wetland plants still have high treatment performance and survival rate under pollution conditions.Many studies show that hyperaccumulating metallophytes have the capacity to accumulate heavy metal up to several times higher than the plants in sterile soil,due to the interaction of microbes within the rhizosphere.Thus,biotechnological efforts are being explored to modify plants for heavy metal phytoremediation and to improve the adaptation of wetland plants,endophytes,and rhizospheric microorganisms to adverse environment.New phytoremediation techniques and enhanced symbiosis technique for endophytic bacteria inoculation with high efficiency are being pursued and utilized in heavy metal phytoremediation in wetland systems.Therefore,in this review,we systematically summarized the interface characteristics of wetland systems and the interaction of symbionts,with emphasis on the enhanced removal potential and regulation mechanisms of heavy metals by plant-microbe symbiosis in wetland systems,along with the applications of plant-microbiomes for heavy metal remediation in wetlands.Moreover,we explored the remediation mechanisms of combined endogenic-ecophytic microorganisms for wetland systems.In recent research,the exogeneous bacteria drastically remodeled the rhizospheric microbiome and further improved the activity of rhizospheric functional enzymes,with the metal removal at the rhizospheric region reaching up to 95%.In order to increase the effectiveness of plant-microbiome engineering in addressing wetland environmental pollution,the significance of incorporating synergistic techniques and taking a variety of environmental factors was discussed.展开更多
During emergency response to oil spills incident accurate information is required in order to reduce the risk associated with oil spill disasters. This study focuses on Environmental Sensitivity mapping for sustainabl...During emergency response to oil spills incident accurate information is required in order to reduce the risk associated with oil spill disasters. This study focuses on Environmental Sensitivity mapping for sustainable environmental clean-up and contingency planning along the 3.0 km of AGIP pipeline at Asemoku in Delta State, Nigeria. Geographic information systems (GIS) techniques were used to create an Environmental Sensitivity Index (ESI) map in the study area. A 2018 Google Earth Satellite imagery of the study area was downloaded, and landuse/cover classification scheme comprising of Vegetation, Farmland, Water Body, Wetland, built up area and Bare Surface was adopted. Existing categorization, ranking and classification of the inland habitat were adopted and used to create a Landuse/cover Environmental Sensitivity Index (ESI) map, while the buffer zones of 100 m, 200 m, 300 m and 400 m were adopted. In the ArcGIS 10.8 environment, the landuse/cover map was generated and buffer distances of 100 m, 200 m, 300 m and 400 m were created on the landuse/cover map to ascertain the features that are vulnerable and could be at risk in the event of oil spill. This study established that the Natural Vegetation areas are the most vulnerable and sensitive feature as a result of their size along the created buffer zones. Findings from this study thus provide insight into the most sensitive land-use/land-cover, in the event of a spill or emergency oil spill clean-up response.展开更多
Agriculture plays a crucial role in the economy,and there is an increasing global emphasis on automating agri-cultural processes.With the tremendous increase in population,the demand for food and employment has also i...Agriculture plays a crucial role in the economy,and there is an increasing global emphasis on automating agri-cultural processes.With the tremendous increase in population,the demand for food and employment has also increased significantly.Agricultural methods traditionally used to meet these requirements are no longer ade-quate,requiring solutions to issues such as excessive herbicide use and the use of chemical fertilizers.Integration of technologies such as the Internet of Things,wireless communication,machine learning,artificial intelligence(AI),and deep learning shows promise in addressing these challenges.However,there is a lack of comprehensive documentation on the application and potential of AI in improving agricultural input efficiency.To address this gap,a desk research approach was used by utilizing peer-reviewed electronic databases like PubMed,Scopus,Goo-gle Scholar,Web of Science,and Science Direct for relevant articles.Out of 327 initially identified articles,180 were deemed pertinent,focusing primarily on AI’s potential in enhancing yield through better management of nutrients,water,and weeds.Taking into account researchfindings worldwide,we found that AI technologies could assist farmers by providing recommendations on the optimal nutrients to enhance soil quality and deter-mine the best time for irrigation or herbicide application.The present status of AI-driven automation in agricul-ture holds significant promise for optimizing agricultural input utilization and reducing resource waste,particularly in the context of three pillars of crop management,i.e.,nutrient,irrigation,and weed management.展开更多
Nitrogen removal from domestic sewage is usually limited by insufficient carbon source and electron donor.An economical solid carbon source was developed by composition of polyvinyl alcohol,sodium alginate,and corncob...Nitrogen removal from domestic sewage is usually limited by insufficient carbon source and electron donor.An economical solid carbon source was developed by composition of polyvinyl alcohol,sodium alginate,and corncob,which was utilized as external carbon source in the anaerobic anoxic oxic(AAO)-biofilter for the treatment of low carbon-to-nitrogen ratio domestic sewage,and the nitrogen removal was remarkably improved from 63.2%to 96.5%.Furthermore,the effluent chemical oxygen demand maintained at 35 mg/L or even lower,and the total nitrogenwas reduced to less than 2mg/L.Metagenomic analysis demonstrated that the microbial communities responsible for potential denitrification and organic matter degradation in both AAO and the biofilter reactors were mainly composed of Proteobacteria and Bacteroides,respectively.The solid carbon source addition resulted in relatively high abundance of functional enzymes responsible for NO_(3)^(−)-N to NO_(2)^(−)-N con-version in both AAO and the biofilter reactors,thus enabled stable reaction.The carbon source addition during glycolysis primarily led to the increase of genes associated with the metabolic conversion of fructose 1.6P2 to glycerol-3P The reactor maintained high abun-dance of genes related to the tricarboxylic acid cycle,and then guaranteed efficient carbon metabolism.The results indicate that the composite carbon source is feasible for denitri-fication enhancement of AAO-biofilter,which contribute to the theoretical foundation for practical nitrogen removal application.展开更多
Carbon emissions resulting from energy consumption have become a pressing issue for governments worldwide.Accurate estimation of carbon emissions using satellite remote sensing data has become a crucial research probl...Carbon emissions resulting from energy consumption have become a pressing issue for governments worldwide.Accurate estimation of carbon emissions using satellite remote sensing data has become a crucial research problem.Previous studies relied on statistical regression models that failed to capture the complex nonlinear relationships between carbon emissions and characteristic variables.In this study,we propose a machine learning algorithm for carbon emissions,a Bayesian optimized XGboost regression model,using multi-year energy carbon emission data and nighttime lights(NTL)remote sensing data from Shaanxi Province,China.Our results demonstrate that the XGboost algorithm outperforms linear regression and four other machine learning models,with an R^(2)of 0.906 and RMSE of 5.687.We observe an annual increase in carbon emissions,with high-emission counties primarily concentrated in northern and central Shaanxi Province,displaying a shift from discrete,sporadic points to contiguous,extended spatial distribution.Spatial autocorrelation clustering reveals predominantly high-high and low-low clustering patterns,with economically developed counties showing high-emission clustering and economically relatively backward counties displaying low-emission clustering.Our findings show that the use of NTL data and the XGboost algorithm can estimate and predict carbon emissionsmore accurately and provide a complementary reference for satellite remote sensing image data to serve carbon emission monitoring and assessment.This research provides an important theoretical basis for formulating practical carbon emission reduction policies and contributes to the development of techniques for accurate carbon emission estimation using remote sensing data.展开更多
Hydroxyapatite nanoparticles(HAP NPs)were synthesized by a one‐step hydrothermal method.The surface of HAP NPs was grafted-SH and-COOH chelating groups via in situ surface‐modification with iminodiacetic acid(IDA)an...Hydroxyapatite nanoparticles(HAP NPs)were synthesized by a one‐step hydrothermal method.The surface of HAP NPs was grafted-SH and-COOH chelating groups via in situ surface‐modification with iminodiacetic acid(IDA)and 3‐mercaptopropyl trimethoxysilane(MPS)to afford dual surface‐capped nano‐amendment HAPIDA/MPS.The structure of HAP‐IDA/MPS was characterized,and its adsorption performance for Hg^(2+),Cu^(2+),Zn^(2+),Ni^(2+),Co^(2+),and Cd^(2+)was evaluated.The total adsorption capacity of 0.10 g HAP‐IDA/MPS nano‐amendment for Hg^(2+),Cu^(2+),Zn^(2+),Ni^(2+),Co^(2+),and Cd^(2+)with an initial mass concentration of 20 mg·L^(-1) reached 13.7 mg·g^(-1),about 4.3 times as much as that of HAP.Notably,HAP‐IDA/MPS nano‐amendment displayed the highest immobilization rate for Hg^(2+),possibly because of its chemical reaction with-SH to form sulfide,possessing the lowest solubility product constant among a variety of metal sulfides.展开更多
This study was carried out to evaluate the response of Nile tilapia(Oreochromis niloticus)fingerlings to acute copper sulphate and ferrocene toxicity.Nile tilapia fingerlings weighing 2.3±0.2 g were acclimated an...This study was carried out to evaluate the response of Nile tilapia(Oreochromis niloticus)fingerlings to acute copper sulphate and ferrocene toxicity.Nile tilapia fingerlings weighing 2.3±0.2 g were acclimated and randomly distributed at a rate of 10 fish per 30 L aquarium.Fish were exposed to a range of copper sulphate and ferrocene concentrations of 4 mg/L,8 mg/L,12 mg/L,16 mg/L and 2.5 mg/L,5 mg/L,7.5 mg/L,10 mg/L respectively.Fish not exposed to any toxicant served as control.Mortality was assessed and median lethal concentration(LC50)and median lethal time(LT50)were calculated.The 96-h LC50 values obtained for copper sulphate and ferrocene were 7.49 mg/L(confidence interval CI:6.35 to 8.57 mg/L)and 3.55 mg/L(CI:0.98 to 5.17 mg/L)respectively.The LC50 decreased with time of exposure implying that toxicity increased over time,however,LT50 decreased as concentration increased.The safe concentration for copper sulphate derived was 1.913 mg/L and 1.196 mg/L for ferrocene.Histological analyses were carried out on fish gills and skin.The skin histomorphology showed marked and widespread epidermal loss and widespread mycocytic degeneration in treatments with high concentration for both toxicants.The gill morphology showed moderate to severe hyperplasia of the primary gill epithelia leading to partial or complete loss of the secondary lamellae.展开更多
The histopathological effect of pentachlor,an organochlorine pesticide,on the gill and liver tissues of the African catfish(Clarias gariepinus)juvenile was carried out to investigate the toxicity of pentachlor when ad...The histopathological effect of pentachlor,an organochlorine pesticide,on the gill and liver tissues of the African catfish(Clarias gariepinus)juvenile was carried out to investigate the toxicity of pentachlor when administered on the test sample within concentrations of 0.073 mg/L,0.036 mg/L,0.024 mg/L and 0.018 mg/L and a control in those replicates was used.The fish were acclimatized for 7 days under laboratory conditions before exposure.Sixteen(16)troughs,each of seven(7)juvenile samples of length 2.3 cm and average weight of 10-15 g,were used for the study.Twelve(12)troughs exposed to varying concentrations of pentachlor were used as treatment samples while four(4)troughs served as control.The juveniles were exposed to sub-lethal concentrations for 21 days with a break at every 48 h.The gills and livers were collected for histological examination.Histological data revealed that at 0.1 m/L pentachlor concentration,the gills showed epithelial hyperplasia with heamorrhage in the central venous of the cartilaginous core with the lifting of the epithelia and hypertrophy at 0.2 mg/L.At 0.3 mg/L exposure,epithelia hyperplasia,dilation of the secondary lamellae occurred and severe deformation of the secondary gill lamellae at 0.4 mg/L.However,the control presented normal mucous and epithelial cells with normal secondary and primary gill lamellae.The liver sample treated with 0.1 mg/L showed complete vascular degeneration.Control sample revealed normal blood vessels,sinusoid vessels and hypatocystes.This showed that pentachlor can accumulate in the liver and potentially cause damage to tissue over time.展开更多
1.Introduction As global temperatures increase and weather patterns grow more er-ratic,the urgency of adopting climate-smart conservation strategies has intensified(Manyakaidze et al.,2024).Climate-smart conservation ...1.Introduction As global temperatures increase and weather patterns grow more er-ratic,the urgency of adopting climate-smart conservation strategies has intensified(Manyakaidze et al.,2024).Climate-smart conservation com-prises adaptive management practices aimed at bolstering the resilience of ecosystems and species amid climate variability(Birchall et al.,2021;Gabriel-Campos et al.,2021).展开更多
This study examined gender differences in modal choice among residents of coastal communities of Yenagoa metropolis in Bayelsa State, Nigeria. The Four-Step model of transportation planning and modal choice provided t...This study examined gender differences in modal choice among residents of coastal communities of Yenagoa metropolis in Bayelsa State, Nigeria. The Four-Step model of transportation planning and modal choice provided the theoretical basis for this study. A survey research design involving a stratified sampling technique was adopted. The descriptives on transport modes, amount and time spent revealed that 10 (76.9%) males and 3 (23.1%) females preferred bicycle as means of transportation, 7 (58.3%) males and 5 (41.7%) females preferred motorcycle, while a significant proportion 90 (53.9%) males and 77 (46.1%) females preferred tricycle, 80 (63.0%) males and 47 (37.0%) females preferred cars/taxis, and 12 (46.2%) males and 14 (53.8%) females preferred mass transit bus. However, 14 (46.7%) males and 16 (53.3%) females in marshy terrain and coastal locations preferred canoes and boats. The result of the logistic regression model revealed that gender modal preference is more likely to be influenced by mode of transportation with a beta weight of 1.140, safety considerations 1.139, ownership of transport 1.135 and distance to place of work 1.073. Hence, this study recommends that a combination of these factors should be incorporated into transport planning to achieve effective transport planning and sustainable development in the Yenagoa metropolis.展开更多
Constructed Wetlands (CWs) are currently one of the most promising techniques for wastewater treatment, having demonstrated their effectiveness. However, the choice of substrate particle size is critical to the smooth...Constructed Wetlands (CWs) are currently one of the most promising techniques for wastewater treatment, having demonstrated their effectiveness. However, the choice of substrate particle size is critical to the smooth operation of the process, as hydrodynamic constraints require a coarse particle size, whereas wastewater treatment recommends a fine particle size. This study investigates the suitability of laterite and shale as substrates of different sizes (1 - 3, 3 - 5 and 5 - 8 mm) in CWs for domestic wastewater treatment. The study was carried out in an experimental pilot plant consisting of 12 parallelepiped beds (C × C = 0.4 × 0.4 m2;H = 0.6 m) filled from bottom to top with 0.1 m of gravel and 0.4 m of shale or laterite of different grain sizes with two replications. During the six months of operation, plant biomass and stem diameter of Pennisetum purpureum used as vegetation in the CWs were determined. Raw and treated water were also sampled and analyzed for pollutants, including chemical oxygen demand (COD), biochemical oxygen demand (BOD5), total Kjedahl nitrogen (TKN), total phosphorus (TP), and total suspended solids (TSS), using International Organization for Standardization (ISO) analytical methods. P. purpureum developed much better in the CW beds lined with shale;plant biomass ranged from 13.8 to 14.7 kg/m2 and from 11.2 to 12.5 kg/m2 in the beds lined with shale and laterite, respectively, as did stump diameter, which ranged from 15.5 to 16.1 cm and from 11.10 to 12.7 cm, respectively. However, the highest values for biomass and stump diameter for each material were obtained in the beds lined with 1 - 3 mm geomaterials. Pollutant removal efficiencies were highest in the CWs lined with laterite and shale of 1 - 3 mm grain size (76.9% - 83% COD, 78% - 84.7% BOD5, 55.5% - 72.2% TKN, 58.4% - 72.4% TP, 78.1% - 80.2% TSS), with the highest values recorded in the shale-lined beds. However, the 3 - 5 mm grain size of both materials provided quality filtrates (140 - 174 mg/L COD, 78.5 - 94.8 mg/L BOD5, 4.6 - 5.7 mg/L TP) in line with local wastewater discharge levels. This size of geomaterials appears to be suitable for optimization purposes, although further work with these materials, such as increasing the depth of the wetland, is required to improve the level of NTK and TSS discharge.展开更多
Coastal tourism holds substantial development potential.However,coastal ecosystems are affected by tourism development,which limits the supply of ecosystem services(ES).This study aims to conduct a systematic literatu...Coastal tourism holds substantial development potential.However,coastal ecosystems are affected by tourism development,which limits the supply of ecosystem services(ES).This study aims to conduct a systematic literature review on the impacts of tourism on coastal and marine ES using the Preferred Reporting Items for Systematic Reviews and Meta-alpha Methods.We initially identified 640 studies by searching titles,abstracts,and keywords.After screening,only 50 studies met the criteria for inclusion in the review.The results showed a significant increase in publications between 2011 and 2023.Most studies were conducted in Europe,Asia,and North and Central America.The most used ES classifications were MEA and CICES.Most studies concentrated on the ES supply dimension(43 studies;86%).Cultural ES(47 studies;94%)were researched more than provisioning(28 studies;56%)and regulating&maintenance(29 studies;58%)sections.Regarding cultural ES,most studies were focused on“Physical and experiential interactions with the natural environment”(34 studies;68%)and on provisioning ES on“Wild animals(terrestrial and aquatic)for nutrition,materials or energy”(18 studies;36%).Quantitative and mixed methods were the most used in the reviewed studies.Most studies identified pressures from“Tourism,urbanisation,and population increase”(27 studies;54%)and focused on“Integrative/common management strategies”(20 studies;40%).Only a few of the studies’results have been validated by external data(10 studies;20%).This study provides an overview of the most assessed marine and coastal ES,where studies are needed with more comprehensive geographic coverage.展开更多
Methane’s complete catalytic oxidation process has been widely studied,but efficient catalytic oxidation of low-concentration methane(≤0.75%)remains a crucial problem in the coal chemical industry.How to prevent the...Methane’s complete catalytic oxidation process has been widely studied,but efficient catalytic oxidation of low-concentration methane(≤0.75%)remains a crucial problem in the coal chemical industry.How to prevent the sintering deactivation of the active component in Pd-based catalysts and achieve efficient and stable operation of sub-nanometer catalysts remains challenging.Here,we utilize the interaction between amine ligands and Pd nanoparticles to stabilize and encapsulate the Pd particles within the pores of a molecular sieve carrier,effectively promoting the high dispersion of Pd particles.By leveraging the low acidity,high hydrophobicity,and high hydrothermal stability of the zeolite carrier,the Pd@S-1 catalyst exhibits excellent activity and stability in the catalytic oxidation of methane at lowconcentrations.Finally,density functional theory is employed to investigate the reaction mechanism of low-concentration methane during the catalytic process.Encapsulating the active metal component in zeolite to improve catalytic activity and stability provides a theoretical basis and direction for preparing complete oxidation catalysts for low-concentration methane.展开更多
Rationale: The contamination of soil with crude oil poses significant environmental and ecological threats. Bioremediation, particularly through the use of organisms like Pleurotus ostreatus (mushroom) and Eisenia fet...Rationale: The contamination of soil with crude oil poses significant environmental and ecological threats. Bioremediation, particularly through the use of organisms like Pleurotus ostreatus (mushroom) and Eisenia fetida (earthworm), has emerged as a promising approach to mitigate crude oil pollution. Understanding the effectiveness of these organisms in reducing hydrocarbon levels in contaminated soil is crucial for devising sustainable remediation strategies. Objectives: This study aimed to evaluate the efficacy of Pleurotus ostreatus and Eisenia fetida in remediating crude oil-polluted soil. Specifically, it sought to assess the hydrocarbon profiles in soil treated with these organisms across varying concentrations of crude oil pollution. Method: Crude oil concentration levels ranging from 0% to 10% were applied to soil samples alongside control treatments, including soil only, soil with earthworms, and soil with mushrooms. Each treatment was replicated five times using a randomized complete block design. Standard methods were employed to determine the hydrocarbon contents of the soil. Results: The results indicated a significant increase (P Pleurotus ostreatus and Eisenia fetida exhibited noteworthy reductions in these hydrocarbon levels. At the three-month mark, mushrooms demonstrated a remarkable ability to reduce hydrocarbon content by 70% - 90% compared to the pollution treatment. In contrast, earthworms exhibited minimal potential for hydrocarbon reduction, particularly at both three and six-month intervals. For instance, TOC reduction reached a maximum of 96% with mushroom treatment and 85% with earthworm treatment at 5% crude oil pollution over six months. Conclusion: The findings highlight the effectiveness of Pleurotus ostreatus in significantly reducing hydrocarbon levels in crude oil-polluted soil compared to Eisenia fetida. Mushroom-treated soils consistently exhibited substantial reductions in TOC, TPH, TOG, PAH, and THC over the study period, suggesting their potential as a viable bioremediation agent. In contrast, while earthworms showed some capability in reducing hydrocarbon content, their effectiveness was comparatively limited. Recommendation: Based on the results, it is recommended to utilize Pleurotus ostreatus for the bioremediation of crude oil-polluted soils. Further research could explore optimizing remediation protocols involving mushroom-based treatments for enhanced efficiency. Statement of Significance: This study contributes valuable insights into the application of bioremediation techniques for mitigating crude oil contamination in soil. The demonstrated efficacy of Pleurotus ostreatus underscores its potential as a sustainable and eco-friendly solution for remediating hydrocarbon-polluted environments, offering a promising avenue for environmental restoration and conservation efforts.展开更多
Amid ongoing global environmental change and the critical pursuit of sustainable development,human-environment systems are exhibiting increasingly complex dynamic evolutions and spatial relationships,underscoring an u...Amid ongoing global environmental change and the critical pursuit of sustainable development,human-environment systems are exhibiting increasingly complex dynamic evolutions and spatial relationships,underscoring an urgent need for innovative research frameworks.Integrated geography synthesizes physical geography,human geography,and geographic information science,providing key frameworks for understanding complex human-environment systems.This editorial proposes an emerging research framework for integrated geography—“Composite driving-System evolution-Coupling mechanism-Synergistic regulation(CSCS)”—based on key issues such as climate change,biodiversity loss,resource scarcity,and social-ecological interactions,which have been highlighted in both recent critical literature on human-environment systems and UN assessment reports.The framework starts with diverse composite driving forces,extends to the evolution of human-environment system structures,processes,and functions that these drivers induce,explores couplings within human-environment systems,and calls for regulation aimed at sustainable development in synergies.Major research frontiers include understanding the cascading“evolution-coupling”effects of shocks;measuring system resilience,thresholds,and safe and just operating space boundaries;clarifying linkage mechanisms across scales;and achieving synergistic outcomes for multi-objective sustainability.This framework will help promote the interdisciplinary integration and development of integrated geography,and provide geographical solutions for the global sustainable development agenda.展开更多
The impact of different global and local variables in urban development processes requires a systematic study to fully comprehend the underlying complexities in them.The interplay between such variables is crucial for...The impact of different global and local variables in urban development processes requires a systematic study to fully comprehend the underlying complexities in them.The interplay between such variables is crucial for modelling urban growth to closely reflects reality.Despite extensive research,ambiguity remains about how variations in these input variables influence urban densification.In this study,we conduct a global sensitivity analysis(SA)using a multinomial logistic regression(MNL)model to assess the model’s explanatory and predictive power.We examine the influence of global variables,including spatial resolution,neighborhood size,and density classes,under different input combinations at a provincial scale to understand their impact on densification.Additionally,we perform a stepwise regression to identify the significant explanatory variables that are important for understanding densification in the Brussels Metropolitan Area(BMA).Our results indicate that a finer spatial resolution of 50 m and 100 m,smaller neighborhood size of 5×5 and 3×3,and specific density classes—namely 3(non-built-up,low and high built-up)and 4(non-built-up,low,medium and high built-up)—optimally explain and predict urban densification.In line with the same,the stepwise regression reveals that models with a coarser resolution of 300 m lack significant variables,reflecting a lower explanatory power for densification.This approach aids in identifying optimal and significant global variables with higher explanatory power for understanding and predicting urban densification.Furthermore,these findings are reproducible in a global urban context,offering valuable insights for planners,modelers and geographers in managing future urban growth and minimizing modelling.展开更多
Chemical leaching techniques have been proven effective in removing heavymetal contaminants fromsoil using various leaching agents.Previous research has shown that both singleagent and composite leaching systems have ...Chemical leaching techniques have been proven effective in removing heavymetal contaminants fromsoil using various leaching agents.Previous research has shown that both singleagent and composite leaching systems have been applied for the remediation of chromiumcontaminated soils,with varying degrees of success depending on soil type and contaminant form.However,the removal rate of total chromium(Cr)and hexavalent chromium(Cr(Ⅵ))often fluctuates based on the chemical composition of the leaching agents,as well as the soil’s physicochemical properties,such as pH and Cr speciation stability.Therefore,this study investigates the effectiveness of 20 composite leaching systems,including deionized water,lime water,calcium chloride,sodium carbonate,and sodium phosphate,through soil column leaching tests.The aim was to evaluate their impact on soil pH,total Cr,and Cr(Ⅵ)removal,and to examine the transformation of various Cr species during the leaching process.Results reveal that lime water and sodium phosphate were particularly effective in stabilizing Cr(Ⅵ)and neutralizing soil pH,while total Cr removal amount ranged from 197.4 mg/kg to 1671.6 mg/kg and Cr(Ⅵ)removal amount ranged from 113.2mg/kg to 316.8mg/kg.We also find that using 0.2 mol/L citric acid,0.1 mol/L hydrochloric acid,and 1.2 mL/g lime solution adjusted soil pH to 7.37,with average removal efficiencies of 34.6%.for total Cr and 72.7%for Cr(Ⅵ).Overall,our results suggest that the combined use of lime water and sodium phosphate is an effective strategy for remediating chromium-contaminated soil,particularly for stabilizing unleached Cr and adjusting soil pH.展开更多
文摘Water supply is a global problem. A study was conducted on twelve (12) traditional wells water in Daba Dagnogo and Gnipi 2 to determine their physico-chemical quality. Two sampling campaigns (dry season and rainy season), were performed on 16 physical and chemical parameters. The results show that the water is acidic with an average pH of 6.41 ± 0.4;moderately mineralized with an average conductivity of 731.14 ± 611.98 μS·cm-1;moderately saline with an average rate of 1.56 ± 1.22. The average temperature of 28.07 ± 0.86°C is above the norm for all wells. All major ions are consistent with WHO standards except calcium and potassium. 41.67% of wells exceed the standard ammonium ion whose average was 1.43 ± 2.79 mg·L-1 nitrate and 100% with an average of 492.42 ± 434.02 mg·L-1. The ion concentrations are highest in the urban area and are higher in the dry season. The quality of the water sampled wells deteriorated. Several factors affect the degradation, namely the shallow wells, their proximity to toilet, the lack of sanitation and poor management of household waste. It will carry out a campaign to educate people to protect the immediate environment of the water points, avoiding the deposit of garbage and to provide the appropriate wells lids.
文摘Industrial activities have contributed so much to the pollution of water bodies and these pollutions have adversely affected the aquatic ecosystem.This study aimed to investigate the ecological risk evaluation of heavy metal accumulation in Aba River bottom sediments:implications for soap and detergent industry wastewater management.Varian AA240 Atomic absorption spectrometer was used to analyse heavy metals.Individual and complex ecological indices were used to evaluate heavy metal contamination in bottom sediments.According to the results,the heavy metal properties of the wastewater indicated that Fe,Pb,Cd,Cr and Cu mean concentration values were higher than the World Health Organization(WHO)and the National Environmental Standards and Regulations Enforcement Agency(NESREA)permissible limits.Heavy metal properties of the surface water in Aba River(dry seasons)showed that Pb,Cd,Cu,Mn,Fe,and Cr,mean concentrations were above the NESREA,WHO and U.S.Environmental Protection Agency(USEPA)permissible limits.Heavy metal properties of the bottom sediments of Aba River(wet and dry season)showed that Pb,Cd,and Fe mean concentrations were significantly higher than the NESREA,WHO and USEPA permissible limits.The heavy metal contamination factor(CF)of sediments obtained from Aba River during the wet and dry season was low and the CFs of each of the assayed heavy metals were less than 1(CD<1).This also signifies the existence of a low contamination in the sediments of the course streams of Aba River during wet and dry season.The pollution load index(PLI)values of Aba River(sediment)indicated that there is no metal pollution at PLI<1 in the sampled sediments.The potential ecological risk index(RI)of Aba River was less than 150(RI<150)indicating a low ecological RI.Abatement of pollutants in the wastewater to permissible concentrations required for natural environment protection is needed.
基金funded by the Directorate of Research and Community Service, Ministry of Education, Culture, Research, and Technology, Indonesia (027/E5/PG.02.00.PL/2024)Bogor Agricultural University for their invaluable support and resources that made this research possibleDirectorate of Research and Community Service, Ministry of Education, Culture, Research, and Technology, Indonesia, for their financial and administrative support
文摘Urbanization in small-and medium-sized cities has often been overlooked in urban studies.Research on urbanization has predominantly focused on large metropolitan cities;however,urbanization in small-and medium-sized cities also contributes to the acceleration of urban sprawl.Urban growth boundary(UGB)is an ecological approach designed to limit urban development.This study aimedto analyze environmental protection priority zonesby combining ecological quality and sensitivity indices to identify the areas suitable for UGB implementation.Tegal City and its surrounding areas(including Tegal and Brebes regencies)of Indonesia were selected as the study area.The ecological quality index was calculated using the normalized difference vegetation index,humidity index,land surface temperature,and normalized difference bare soil index.These indices were subsequently subjected to principal component analysis(PCA)to extract orthogonal factors,which were summed to derive the final index value.In parallel,we mapped and evaluated ecological sensitivity based on spatial planning policies and regulations.The results revealed that ecological quality in Tegal and Brebes regencies was predominantly categorized as good and very good ecological quality,whereas TegalCity exhibited moderate and poor ecological quality.Additionally,over 45.00%of the area in Tegal and Brebes regencies demonstrated very high ecological sensitivity.Consequently,more than 50.00%of the area in Tegal and Brebes regencies,along with 27.00%of Tegal City,were classified as ecological constraint zone,making them potential regionsfor UGB development.The UGB is expected to curtail urban expansion,promote compact city planning,and preserve ecosystem services to achieve urban sustainability.This study implies that planningsmall-and medium-sized cities is important to prevent urban sprawl and maintain environmental health.Designing UGB to limit urban expansion should be enhanced by better knowledge about its ecological functions in supporting urban sustainability.
基金financially supported by the Natural Science Foundation of Hebei Province for Youth,China(No.D2021201003)the Key Research and Development(R&D)Project of Hebei Province,China(No.21373601D)+3 种基金the Science and Technology Planning Project of Shijiazhuang,China(No.221240223A)the Natural Science Interdisciplinary Research Program of Hebei University,China(No.DXK202106)the Hebei Provincial 3-3-3 Talent Project,China(No.A202101120)the Collaborative Innovation Center for Baiyangdian Basin Ecological Protection and Beijing-Tianjin-Hebei Sustainable Development,China。
文摘Wetland plants and their related environmental interfaces are colonized by a wide range of microbial communities,and the symbiotic system of plants and microorganisms can interact and cooperate with each other,playing an important role in environmental remediation of metal pollution,which has garnered significant attention.The dominant communities of wetland plants still have high treatment performance and survival rate under pollution conditions.Many studies show that hyperaccumulating metallophytes have the capacity to accumulate heavy metal up to several times higher than the plants in sterile soil,due to the interaction of microbes within the rhizosphere.Thus,biotechnological efforts are being explored to modify plants for heavy metal phytoremediation and to improve the adaptation of wetland plants,endophytes,and rhizospheric microorganisms to adverse environment.New phytoremediation techniques and enhanced symbiosis technique for endophytic bacteria inoculation with high efficiency are being pursued and utilized in heavy metal phytoremediation in wetland systems.Therefore,in this review,we systematically summarized the interface characteristics of wetland systems and the interaction of symbionts,with emphasis on the enhanced removal potential and regulation mechanisms of heavy metals by plant-microbe symbiosis in wetland systems,along with the applications of plant-microbiomes for heavy metal remediation in wetlands.Moreover,we explored the remediation mechanisms of combined endogenic-ecophytic microorganisms for wetland systems.In recent research,the exogeneous bacteria drastically remodeled the rhizospheric microbiome and further improved the activity of rhizospheric functional enzymes,with the metal removal at the rhizospheric region reaching up to 95%.In order to increase the effectiveness of plant-microbiome engineering in addressing wetland environmental pollution,the significance of incorporating synergistic techniques and taking a variety of environmental factors was discussed.
文摘During emergency response to oil spills incident accurate information is required in order to reduce the risk associated with oil spill disasters. This study focuses on Environmental Sensitivity mapping for sustainable environmental clean-up and contingency planning along the 3.0 km of AGIP pipeline at Asemoku in Delta State, Nigeria. Geographic information systems (GIS) techniques were used to create an Environmental Sensitivity Index (ESI) map in the study area. A 2018 Google Earth Satellite imagery of the study area was downloaded, and landuse/cover classification scheme comprising of Vegetation, Farmland, Water Body, Wetland, built up area and Bare Surface was adopted. Existing categorization, ranking and classification of the inland habitat were adopted and used to create a Landuse/cover Environmental Sensitivity Index (ESI) map, while the buffer zones of 100 m, 200 m, 300 m and 400 m were adopted. In the ArcGIS 10.8 environment, the landuse/cover map was generated and buffer distances of 100 m, 200 m, 300 m and 400 m were created on the landuse/cover map to ascertain the features that are vulnerable and could be at risk in the event of oil spill. This study established that the Natural Vegetation areas are the most vulnerable and sensitive feature as a result of their size along the created buffer zones. Findings from this study thus provide insight into the most sensitive land-use/land-cover, in the event of a spill or emergency oil spill clean-up response.
文摘Agriculture plays a crucial role in the economy,and there is an increasing global emphasis on automating agri-cultural processes.With the tremendous increase in population,the demand for food and employment has also increased significantly.Agricultural methods traditionally used to meet these requirements are no longer ade-quate,requiring solutions to issues such as excessive herbicide use and the use of chemical fertilizers.Integration of technologies such as the Internet of Things,wireless communication,machine learning,artificial intelligence(AI),and deep learning shows promise in addressing these challenges.However,there is a lack of comprehensive documentation on the application and potential of AI in improving agricultural input efficiency.To address this gap,a desk research approach was used by utilizing peer-reviewed electronic databases like PubMed,Scopus,Goo-gle Scholar,Web of Science,and Science Direct for relevant articles.Out of 327 initially identified articles,180 were deemed pertinent,focusing primarily on AI’s potential in enhancing yield through better management of nutrients,water,and weeds.Taking into account researchfindings worldwide,we found that AI technologies could assist farmers by providing recommendations on the optimal nutrients to enhance soil quality and deter-mine the best time for irrigation or herbicide application.The present status of AI-driven automation in agricul-ture holds significant promise for optimizing agricultural input utilization and reducing resource waste,particularly in the context of three pillars of crop management,i.e.,nutrient,irrigation,and weed management.
基金supported by the Special Funds for Chengde national innovation demonstration area construction of science and technology special project sustainable development agenda(No.202104F001)the National Basic Research Program of China(No.2019YFC0408602).
文摘Nitrogen removal from domestic sewage is usually limited by insufficient carbon source and electron donor.An economical solid carbon source was developed by composition of polyvinyl alcohol,sodium alginate,and corncob,which was utilized as external carbon source in the anaerobic anoxic oxic(AAO)-biofilter for the treatment of low carbon-to-nitrogen ratio domestic sewage,and the nitrogen removal was remarkably improved from 63.2%to 96.5%.Furthermore,the effluent chemical oxygen demand maintained at 35 mg/L or even lower,and the total nitrogenwas reduced to less than 2mg/L.Metagenomic analysis demonstrated that the microbial communities responsible for potential denitrification and organic matter degradation in both AAO and the biofilter reactors were mainly composed of Proteobacteria and Bacteroides,respectively.The solid carbon source addition resulted in relatively high abundance of functional enzymes responsible for NO_(3)^(−)-N to NO_(2)^(−)-N con-version in both AAO and the biofilter reactors,thus enabled stable reaction.The carbon source addition during glycolysis primarily led to the increase of genes associated with the metabolic conversion of fructose 1.6P2 to glycerol-3P The reactor maintained high abun-dance of genes related to the tricarboxylic acid cycle,and then guaranteed efficient carbon metabolism.The results indicate that the composite carbon source is feasible for denitri-fication enhancement of AAO-biofilter,which contribute to the theoretical foundation for practical nitrogen removal application.
基金supported by the Key Research and Development Program in Shaanxi Province,China(No.2022ZDLSF07-05)the Fundamental Research Funds for the Central Universities,CHD(No.300102352901)。
文摘Carbon emissions resulting from energy consumption have become a pressing issue for governments worldwide.Accurate estimation of carbon emissions using satellite remote sensing data has become a crucial research problem.Previous studies relied on statistical regression models that failed to capture the complex nonlinear relationships between carbon emissions and characteristic variables.In this study,we propose a machine learning algorithm for carbon emissions,a Bayesian optimized XGboost regression model,using multi-year energy carbon emission data and nighttime lights(NTL)remote sensing data from Shaanxi Province,China.Our results demonstrate that the XGboost algorithm outperforms linear regression and four other machine learning models,with an R^(2)of 0.906 and RMSE of 5.687.We observe an annual increase in carbon emissions,with high-emission counties primarily concentrated in northern and central Shaanxi Province,displaying a shift from discrete,sporadic points to contiguous,extended spatial distribution.Spatial autocorrelation clustering reveals predominantly high-high and low-low clustering patterns,with economically developed counties showing high-emission clustering and economically relatively backward counties displaying low-emission clustering.Our findings show that the use of NTL data and the XGboost algorithm can estimate and predict carbon emissionsmore accurately and provide a complementary reference for satellite remote sensing image data to serve carbon emission monitoring and assessment.This research provides an important theoretical basis for formulating practical carbon emission reduction policies and contributes to the development of techniques for accurate carbon emission estimation using remote sensing data.
文摘Hydroxyapatite nanoparticles(HAP NPs)were synthesized by a one‐step hydrothermal method.The surface of HAP NPs was grafted-SH and-COOH chelating groups via in situ surface‐modification with iminodiacetic acid(IDA)and 3‐mercaptopropyl trimethoxysilane(MPS)to afford dual surface‐capped nano‐amendment HAPIDA/MPS.The structure of HAP‐IDA/MPS was characterized,and its adsorption performance for Hg^(2+),Cu^(2+),Zn^(2+),Ni^(2+),Co^(2+),and Cd^(2+)was evaluated.The total adsorption capacity of 0.10 g HAP‐IDA/MPS nano‐amendment for Hg^(2+),Cu^(2+),Zn^(2+),Ni^(2+),Co^(2+),and Cd^(2+)with an initial mass concentration of 20 mg·L^(-1) reached 13.7 mg·g^(-1),about 4.3 times as much as that of HAP.Notably,HAP‐IDA/MPS nano‐amendment displayed the highest immobilization rate for Hg^(2+),possibly because of its chemical reaction with-SH to form sulfide,possessing the lowest solubility product constant among a variety of metal sulfides.
文摘This study was carried out to evaluate the response of Nile tilapia(Oreochromis niloticus)fingerlings to acute copper sulphate and ferrocene toxicity.Nile tilapia fingerlings weighing 2.3±0.2 g were acclimated and randomly distributed at a rate of 10 fish per 30 L aquarium.Fish were exposed to a range of copper sulphate and ferrocene concentrations of 4 mg/L,8 mg/L,12 mg/L,16 mg/L and 2.5 mg/L,5 mg/L,7.5 mg/L,10 mg/L respectively.Fish not exposed to any toxicant served as control.Mortality was assessed and median lethal concentration(LC50)and median lethal time(LT50)were calculated.The 96-h LC50 values obtained for copper sulphate and ferrocene were 7.49 mg/L(confidence interval CI:6.35 to 8.57 mg/L)and 3.55 mg/L(CI:0.98 to 5.17 mg/L)respectively.The LC50 decreased with time of exposure implying that toxicity increased over time,however,LT50 decreased as concentration increased.The safe concentration for copper sulphate derived was 1.913 mg/L and 1.196 mg/L for ferrocene.Histological analyses were carried out on fish gills and skin.The skin histomorphology showed marked and widespread epidermal loss and widespread mycocytic degeneration in treatments with high concentration for both toxicants.The gill morphology showed moderate to severe hyperplasia of the primary gill epithelia leading to partial or complete loss of the secondary lamellae.
文摘The histopathological effect of pentachlor,an organochlorine pesticide,on the gill and liver tissues of the African catfish(Clarias gariepinus)juvenile was carried out to investigate the toxicity of pentachlor when administered on the test sample within concentrations of 0.073 mg/L,0.036 mg/L,0.024 mg/L and 0.018 mg/L and a control in those replicates was used.The fish were acclimatized for 7 days under laboratory conditions before exposure.Sixteen(16)troughs,each of seven(7)juvenile samples of length 2.3 cm and average weight of 10-15 g,were used for the study.Twelve(12)troughs exposed to varying concentrations of pentachlor were used as treatment samples while four(4)troughs served as control.The juveniles were exposed to sub-lethal concentrations for 21 days with a break at every 48 h.The gills and livers were collected for histological examination.Histological data revealed that at 0.1 m/L pentachlor concentration,the gills showed epithelial hyperplasia with heamorrhage in the central venous of the cartilaginous core with the lifting of the epithelia and hypertrophy at 0.2 mg/L.At 0.3 mg/L exposure,epithelia hyperplasia,dilation of the secondary lamellae occurred and severe deformation of the secondary gill lamellae at 0.4 mg/L.However,the control presented normal mucous and epithelial cells with normal secondary and primary gill lamellae.The liver sample treated with 0.1 mg/L showed complete vascular degeneration.Control sample revealed normal blood vessels,sinusoid vessels and hypatocystes.This showed that pentachlor can accumulate in the liver and potentially cause damage to tissue over time.
文摘1.Introduction As global temperatures increase and weather patterns grow more er-ratic,the urgency of adopting climate-smart conservation strategies has intensified(Manyakaidze et al.,2024).Climate-smart conservation com-prises adaptive management practices aimed at bolstering the resilience of ecosystems and species amid climate variability(Birchall et al.,2021;Gabriel-Campos et al.,2021).
文摘This study examined gender differences in modal choice among residents of coastal communities of Yenagoa metropolis in Bayelsa State, Nigeria. The Four-Step model of transportation planning and modal choice provided the theoretical basis for this study. A survey research design involving a stratified sampling technique was adopted. The descriptives on transport modes, amount and time spent revealed that 10 (76.9%) males and 3 (23.1%) females preferred bicycle as means of transportation, 7 (58.3%) males and 5 (41.7%) females preferred motorcycle, while a significant proportion 90 (53.9%) males and 77 (46.1%) females preferred tricycle, 80 (63.0%) males and 47 (37.0%) females preferred cars/taxis, and 12 (46.2%) males and 14 (53.8%) females preferred mass transit bus. However, 14 (46.7%) males and 16 (53.3%) females in marshy terrain and coastal locations preferred canoes and boats. The result of the logistic regression model revealed that gender modal preference is more likely to be influenced by mode of transportation with a beta weight of 1.140, safety considerations 1.139, ownership of transport 1.135 and distance to place of work 1.073. Hence, this study recommends that a combination of these factors should be incorporated into transport planning to achieve effective transport planning and sustainable development in the Yenagoa metropolis.
文摘Constructed Wetlands (CWs) are currently one of the most promising techniques for wastewater treatment, having demonstrated their effectiveness. However, the choice of substrate particle size is critical to the smooth operation of the process, as hydrodynamic constraints require a coarse particle size, whereas wastewater treatment recommends a fine particle size. This study investigates the suitability of laterite and shale as substrates of different sizes (1 - 3, 3 - 5 and 5 - 8 mm) in CWs for domestic wastewater treatment. The study was carried out in an experimental pilot plant consisting of 12 parallelepiped beds (C × C = 0.4 × 0.4 m2;H = 0.6 m) filled from bottom to top with 0.1 m of gravel and 0.4 m of shale or laterite of different grain sizes with two replications. During the six months of operation, plant biomass and stem diameter of Pennisetum purpureum used as vegetation in the CWs were determined. Raw and treated water were also sampled and analyzed for pollutants, including chemical oxygen demand (COD), biochemical oxygen demand (BOD5), total Kjedahl nitrogen (TKN), total phosphorus (TP), and total suspended solids (TSS), using International Organization for Standardization (ISO) analytical methods. P. purpureum developed much better in the CW beds lined with shale;plant biomass ranged from 13.8 to 14.7 kg/m2 and from 11.2 to 12.5 kg/m2 in the beds lined with shale and laterite, respectively, as did stump diameter, which ranged from 15.5 to 16.1 cm and from 11.10 to 12.7 cm, respectively. However, the highest values for biomass and stump diameter for each material were obtained in the beds lined with 1 - 3 mm geomaterials. Pollutant removal efficiencies were highest in the CWs lined with laterite and shale of 1 - 3 mm grain size (76.9% - 83% COD, 78% - 84.7% BOD5, 55.5% - 72.2% TKN, 58.4% - 72.4% TP, 78.1% - 80.2% TSS), with the highest values recorded in the shale-lined beds. However, the 3 - 5 mm grain size of both materials provided quality filtrates (140 - 174 mg/L COD, 78.5 - 94.8 mg/L BOD5, 4.6 - 5.7 mg/L TP) in line with local wastewater discharge levels. This size of geomaterials appears to be suitable for optimization purposes, although further work with these materials, such as increasing the depth of the wetland, is required to improve the level of NTK and TSS discharge.
基金supported by the project MApping and Forecasting Ecosystem Services in Urban Areas(MAFESUR)funded by the Lithuanian Research Council(Contract:Nr.P-MIP-23-426).
文摘Coastal tourism holds substantial development potential.However,coastal ecosystems are affected by tourism development,which limits the supply of ecosystem services(ES).This study aims to conduct a systematic literature review on the impacts of tourism on coastal and marine ES using the Preferred Reporting Items for Systematic Reviews and Meta-alpha Methods.We initially identified 640 studies by searching titles,abstracts,and keywords.After screening,only 50 studies met the criteria for inclusion in the review.The results showed a significant increase in publications between 2011 and 2023.Most studies were conducted in Europe,Asia,and North and Central America.The most used ES classifications were MEA and CICES.Most studies concentrated on the ES supply dimension(43 studies;86%).Cultural ES(47 studies;94%)were researched more than provisioning(28 studies;56%)and regulating&maintenance(29 studies;58%)sections.Regarding cultural ES,most studies were focused on“Physical and experiential interactions with the natural environment”(34 studies;68%)and on provisioning ES on“Wild animals(terrestrial and aquatic)for nutrition,materials or energy”(18 studies;36%).Quantitative and mixed methods were the most used in the reviewed studies.Most studies identified pressures from“Tourism,urbanisation,and population increase”(27 studies;54%)and focused on“Integrative/common management strategies”(20 studies;40%).Only a few of the studies’results have been validated by external data(10 studies;20%).This study provides an overview of the most assessed marine and coastal ES,where studies are needed with more comprehensive geographic coverage.
基金supported by the National Natural Science Foundation of China(No.52270114)the State key laboratory of coal mine disaster dynamics and control(No.2011DA105827-FW202210).
文摘Methane’s complete catalytic oxidation process has been widely studied,but efficient catalytic oxidation of low-concentration methane(≤0.75%)remains a crucial problem in the coal chemical industry.How to prevent the sintering deactivation of the active component in Pd-based catalysts and achieve efficient and stable operation of sub-nanometer catalysts remains challenging.Here,we utilize the interaction between amine ligands and Pd nanoparticles to stabilize and encapsulate the Pd particles within the pores of a molecular sieve carrier,effectively promoting the high dispersion of Pd particles.By leveraging the low acidity,high hydrophobicity,and high hydrothermal stability of the zeolite carrier,the Pd@S-1 catalyst exhibits excellent activity and stability in the catalytic oxidation of methane at lowconcentrations.Finally,density functional theory is employed to investigate the reaction mechanism of low-concentration methane during the catalytic process.Encapsulating the active metal component in zeolite to improve catalytic activity and stability provides a theoretical basis and direction for preparing complete oxidation catalysts for low-concentration methane.
文摘Rationale: The contamination of soil with crude oil poses significant environmental and ecological threats. Bioremediation, particularly through the use of organisms like Pleurotus ostreatus (mushroom) and Eisenia fetida (earthworm), has emerged as a promising approach to mitigate crude oil pollution. Understanding the effectiveness of these organisms in reducing hydrocarbon levels in contaminated soil is crucial for devising sustainable remediation strategies. Objectives: This study aimed to evaluate the efficacy of Pleurotus ostreatus and Eisenia fetida in remediating crude oil-polluted soil. Specifically, it sought to assess the hydrocarbon profiles in soil treated with these organisms across varying concentrations of crude oil pollution. Method: Crude oil concentration levels ranging from 0% to 10% were applied to soil samples alongside control treatments, including soil only, soil with earthworms, and soil with mushrooms. Each treatment was replicated five times using a randomized complete block design. Standard methods were employed to determine the hydrocarbon contents of the soil. Results: The results indicated a significant increase (P Pleurotus ostreatus and Eisenia fetida exhibited noteworthy reductions in these hydrocarbon levels. At the three-month mark, mushrooms demonstrated a remarkable ability to reduce hydrocarbon content by 70% - 90% compared to the pollution treatment. In contrast, earthworms exhibited minimal potential for hydrocarbon reduction, particularly at both three and six-month intervals. For instance, TOC reduction reached a maximum of 96% with mushroom treatment and 85% with earthworm treatment at 5% crude oil pollution over six months. Conclusion: The findings highlight the effectiveness of Pleurotus ostreatus in significantly reducing hydrocarbon levels in crude oil-polluted soil compared to Eisenia fetida. Mushroom-treated soils consistently exhibited substantial reductions in TOC, TPH, TOG, PAH, and THC over the study period, suggesting their potential as a viable bioremediation agent. In contrast, while earthworms showed some capability in reducing hydrocarbon content, their effectiveness was comparatively limited. Recommendation: Based on the results, it is recommended to utilize Pleurotus ostreatus for the bioremediation of crude oil-polluted soils. Further research could explore optimizing remediation protocols involving mushroom-based treatments for enhanced efficiency. Statement of Significance: This study contributes valuable insights into the application of bioremediation techniques for mitigating crude oil contamination in soil. The demonstrated efficacy of Pleurotus ostreatus underscores its potential as a sustainable and eco-friendly solution for remediating hydrocarbon-polluted environments, offering a promising avenue for environmental restoration and conservation efforts.
基金supported by the National Natural Science Foundation of China(Grants No.W2412144,42271292)the 111 project,and the Fundamental Research Funds for the Central Universities of China.
文摘Amid ongoing global environmental change and the critical pursuit of sustainable development,human-environment systems are exhibiting increasingly complex dynamic evolutions and spatial relationships,underscoring an urgent need for innovative research frameworks.Integrated geography synthesizes physical geography,human geography,and geographic information science,providing key frameworks for understanding complex human-environment systems.This editorial proposes an emerging research framework for integrated geography—“Composite driving-System evolution-Coupling mechanism-Synergistic regulation(CSCS)”—based on key issues such as climate change,biodiversity loss,resource scarcity,and social-ecological interactions,which have been highlighted in both recent critical literature on human-environment systems and UN assessment reports.The framework starts with diverse composite driving forces,extends to the evolution of human-environment system structures,processes,and functions that these drivers induce,explores couplings within human-environment systems,and calls for regulation aimed at sustainable development in synergies.Major research frontiers include understanding the cascading“evolution-coupling”effects of shocks;measuring system resilience,thresholds,and safe and just operating space boundaries;clarifying linkage mechanisms across scales;and achieving synergistic outcomes for multi-objective sustainability.This framework will help promote the interdisciplinary integration and development of integrated geography,and provide geographical solutions for the global sustainable development agenda.
基金funded by the INTER program and cofunded by the Fond National de la Recherche,Luxembourg(FNR)and the Fund for Scientific Research-FNRS,Belgium(F.R.S-FNRS),T.0233.20-‘Sustainable Residential Densification’project(SusDens,2020–2024).
文摘The impact of different global and local variables in urban development processes requires a systematic study to fully comprehend the underlying complexities in them.The interplay between such variables is crucial for modelling urban growth to closely reflects reality.Despite extensive research,ambiguity remains about how variations in these input variables influence urban densification.In this study,we conduct a global sensitivity analysis(SA)using a multinomial logistic regression(MNL)model to assess the model’s explanatory and predictive power.We examine the influence of global variables,including spatial resolution,neighborhood size,and density classes,under different input combinations at a provincial scale to understand their impact on densification.Additionally,we perform a stepwise regression to identify the significant explanatory variables that are important for understanding densification in the Brussels Metropolitan Area(BMA).Our results indicate that a finer spatial resolution of 50 m and 100 m,smaller neighborhood size of 5×5 and 3×3,and specific density classes—namely 3(non-built-up,low and high built-up)and 4(non-built-up,low,medium and high built-up)—optimally explain and predict urban densification.In line with the same,the stepwise regression reveals that models with a coarser resolution of 300 m lack significant variables,reflecting a lower explanatory power for densification.This approach aids in identifying optimal and significant global variables with higher explanatory power for understanding and predicting urban densification.Furthermore,these findings are reproducible in a global urban context,offering valuable insights for planners,modelers and geographers in managing future urban growth and minimizing modelling.
基金supported by the National Key Research and Development Program of China(No.2023YFC3707902)China Postdoctoral Science Foundation(No.2024M752168)+1 种基金Jiangsu Funding Programfor Excellent Postdoctoral Talent(No.2024ZB393)the National Natural Science Foundation of China(No.42407126).
文摘Chemical leaching techniques have been proven effective in removing heavymetal contaminants fromsoil using various leaching agents.Previous research has shown that both singleagent and composite leaching systems have been applied for the remediation of chromiumcontaminated soils,with varying degrees of success depending on soil type and contaminant form.However,the removal rate of total chromium(Cr)and hexavalent chromium(Cr(Ⅵ))often fluctuates based on the chemical composition of the leaching agents,as well as the soil’s physicochemical properties,such as pH and Cr speciation stability.Therefore,this study investigates the effectiveness of 20 composite leaching systems,including deionized water,lime water,calcium chloride,sodium carbonate,and sodium phosphate,through soil column leaching tests.The aim was to evaluate their impact on soil pH,total Cr,and Cr(Ⅵ)removal,and to examine the transformation of various Cr species during the leaching process.Results reveal that lime water and sodium phosphate were particularly effective in stabilizing Cr(Ⅵ)and neutralizing soil pH,while total Cr removal amount ranged from 197.4 mg/kg to 1671.6 mg/kg and Cr(Ⅵ)removal amount ranged from 113.2mg/kg to 316.8mg/kg.We also find that using 0.2 mol/L citric acid,0.1 mol/L hydrochloric acid,and 1.2 mL/g lime solution adjusted soil pH to 7.37,with average removal efficiencies of 34.6%.for total Cr and 72.7%for Cr(Ⅵ).Overall,our results suggest that the combined use of lime water and sodium phosphate is an effective strategy for remediating chromium-contaminated soil,particularly for stabilizing unleached Cr and adjusting soil pH.
