This study examines the empirical feasibility of quantitatively integrating environmental value information into Strategic Environmental Assessment(SEA).An analytical framework was established to incorporate environme...This study examines the empirical feasibility of quantitatively integrating environmental value information into Strategic Environmental Assessment(SEA).An analytical framework was established to incorporate environmental cost estimates into the SEA process by utilizing ecosystem service unit values provided by the Environmental Valuation Information System(EVIS),a national platform developed to support the evaluation of policies and projects.The framework was applied to a case study involving a multipurpose rural water development project in South Korea.Ecosystem service losses resulting from the project were quantified using biophysical indicators,such as vegetation biomass,forest area,and hydrological functions,and subsequently monetized through the application of the market price method,replacement cost method,and contingent valuation method.The total annual environmental cost was estimated to be approximately KRW 56.18 billion,with the majority attributable to losses in forest conservation and climate regulation services.These findings demonstrate that quantified environmental data can serve as a robust basis for alternative comparison and site evaluation within SEA.The study provides empirical evidence supporting the advancement of SEA from a predominantly procedural tool focused on environmental protection to a more comprehensive sustainability assessment framework that integrates environmental,economic,and social considerations.Furthermore,the results suggest that EVIS-based quantitative information holds potential for broader application in other national evaluation systems,such as preliminary feasibility studies and regulatory impact assessments.展开更多
Enhanced mass concentrations of aromatic-derived secondary organic aerosol(SOA)are frequently observed during humid-haze events.However,the influencing mechanism of relative humidity(RH)in aromatic-derived SOA formati...Enhanced mass concentrations of aromatic-derived secondary organic aerosol(SOA)are frequently observed during humid-haze events.However,the influencing mechanism of relative humidity(RH)in aromatic-derived SOA formation remains incompletely understood.Here,the RH dependence of SOA formation in the presence of NOx was explored by a series of chamber experiments for toluene(TOL)and 1,3,5-trimethylbenzene(TMB)photooxidation.The yield of TOL SOA and TMB SOA increased by 221%and 52%with increasing RH from~8%to~70%,respectively.Analytical results from a high-resolution mass spectrometer showed that SOA constituents with high oxygen content(O/C>0.6)were more abundant in SOA formed in the~70%RH experiment.The elevated yields and O/C of SOA could be attributed to the promoted formation and particle-phase diffusivity of highly oxidized molecules.In addition,in comparison with TMB,TOL could produce more unsaturated aldehydes,which are oxidized into carboxylic acids with high O/C,leading to a more sensitive response of TOL SOA formation to the change in RH.Our work provides mechanistic insights into RH roles in aromatic SOA formation and is helpful for a better understanding of humid-haze events.展开更多
The increasing population and continuous urbanization make food security a key consideration in sustainable development.Efficient farming strategies with low environmental footprints are thus increasingly required to ...The increasing population and continuous urbanization make food security a key consideration in sustainable development.Efficient farming strategies with low environmental footprints are thus increasingly required to meet food demands.This study presents a design for environmentally friendly,economical,and modular vertical farming systems,in which vegetables are cultivated in a carbon dioxide(CO_(2))-enriched atmosphere enabled by direct air capture(DAC)and subjected to artificial light exposure.We established a vertical farming setup and conducted experiments to identify productive cultivation strategies by regulating lighting,CO_(2)concentration,biochar application,and plant species.Additionally,a self-developed DAC rotary adsorber was utilized to achieve stable and efficient CO_(2)enrichment.Compared with the control group,the fresh weight of the vegetables in the experimental groups increased by up to 57.5%.Furthermore,we performed a comprehensive evaluation of the design and demonstrated that integrating photovoltaic-thermal(PVT)and DAC units increased the system’s net present value(NPV)by 157%compared with a conventional design without these units.Importantly,we found it possible to maintain the low carbon footprint of the system(0.468 kg-CO_(2)equivalent·kg−1(CO_(2)eq·kg−1)-vegetable)in the production process.Parametric studies and an application analysis on a global scale reveal the wide adaptability of this strategy to diverse conditions.These findings,together with the modular characteristics of vertical farming systems,highlight the promising potential of this design to increase food security and foster sustainable agriculture.展开更多
Rare earth elements are highly applicable in photocatalysis due to their partially filled 4f orbitals,existing in electronic structures that facilitate the transfer of electrons during the reaction process.Among these...Rare earth elements are highly applicable in photocatalysis due to their partially filled 4f orbitals,existing in electronic structures that facilitate the transfer of electrons during the reaction process.Among these materials,CeO_(2)has a distinctive external electronic structure(4f^(1)5d^(1)6s^(2)),abundant oxygen vacancies,and strong conversion ability of Ce^(4+)/Ce^(3+),which makes it an attractive candidate in the field of photocatalysis.To broaden its practical applications in the visible region,the drawbacks of a wide band gap and a slow Ce^(4+)/Ce^(3+)cycle have been addressed through the modification of CeO_(2),thereby accelerating light absorption and self-circulation,and enhancing photocatalytic activity.This paper presents a review of the preparation of modified CeO_(2)catalysts and their application in the conversion of cerium valence state in the photocatalytic degradation of pollutants in water.Furthermore,this paper presents a summary of the most recent development and current challenges,as well as prospect for the application of modified CeO_(2)-based materials.展开更多
To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content ...To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced.展开更多
Identifying the provenance of aeolian sediments in the Hunshandake Sandy Land is of great importance for understanding the formation of the dune fields in the mid-latitudes and for deciphering information about desert...Identifying the provenance of aeolian sediments in the Hunshandake Sandy Land is of great importance for understanding the formation of the dune fields in the mid-latitudes and for deciphering information about desert＇s responses to global change. By determining the major and trace elements concentrations of aeolian sands in three grain size fractions from the central and western parts of the Hunshandake Sandy Land, we systematically study the provenance and the depositional history of aeolian sands in this desert environment. Our results show that aeolian sands from the Hunshandake Sandy Land are enriched in SiO2 and are depleted in many other elements compared to those of the Upper Continent Crust （UCC）. Variations of the immobile elements ratios like Zr/Hf, La/Yb, Th/Nb, La/Nb, LaN/YbN, GdN/YbN are relatively large in the coarse and medium fractions but minor in the fine fractions. Eu anomalies are quite different in the coarse fractions, but mostly positive in the medium fractions and all negative in the fine fractions. Decreasing tendency of Zr concentrations from the west to the east in the Hunshandake Sandy Land is evident in the coarse sands but rather weak in the fine grain size fractions. Our geochemical data indicate that the sources for the coarse and medium fractions of aeolian sands are diverse, influenced by local geology and geomorphology, while the fine sand fractions are more homogenous due to intensive mixture mainly by aeolian processes. Various ratios of immobile elements suggest that these sands should be sourced primarily from the surrounding mountains by fluvial/alluvial processes rather than from any remote territories. Aeolian sands with Ce negative anomalies are widely distributed in the Hunshandake Sandy Land, indicating that aquatic environments have occurred extensively prior to the occurrence of the dune field.展开更多
The East China Sea continental shelf is a unique area for the study of land-sea interactions and paleoenvironmental change because it receives a large amount of terrestrial material inputs. In recent decades, human ac...The East China Sea continental shelf is a unique area for the study of land-sea interactions and paleoenvironmental change because it receives a large amount of terrestrial material inputs. In recent decades, human activities and global climate change have greatly aff ected river discharges into the sea. However, changes in the deposition process caused by these factors in the East China Sea continental shelf are unclear. We collected eight short sediment cores from the East China Sea inner shelf(ECSIS) using a box core sampler in 2012 and 2015. The grainsize, 2 10 Pb, and 1 37 Cs of these cores were analyzed in order to reconstruct the deposition history since the 1950 s, and to reveal human activity and climate change influences on sediment deposition in the ECSIS. Results indicated that sediment grain size became finer after 1969, turned coarser after 1987, and then further coarser since 2003, corresponding well to the three steps of sediment load drop in the Changjiang(Yangtze) River, which are mainly caused by human activities(particularly the closure of the Three Gorges Dam). Simultaneously, the East Asian Monsoon influenced the deposition process in the ECSIS by changing the intensity of coastal currents. Mean grain size variations in the fine-grained population(divided by grain size vs. standard deviation method) coincided with that of the East Asian Winter Monsoon strength and reflected its weakness in 1987. Abrupt changes in sediment grain size over a short time scale in these sediment cores were generally caused by floods and typhoons. Spectral analyses of the sediment cores showed periodicities of 10–11 and 20–22 years, corresponding to the periodicity of solar activity(Schwabe cycle and Hale cycle). Mean grain size time series also displayed a 3–8 year periodicity corresponding to El Ni?o Southern Oscillation periodic change.展开更多
Holocene palaeoweathering conditions and environmental changes of Loulan （楼兰） Stupa Sec-tion were reconstructed by major elements analysis results and optical stimulated luminescence dating results. Major element ...Holocene palaeoweathering conditions and environmental changes of Loulan （楼兰） Stupa Sec-tion were reconstructed by major elements analysis results and optical stimulated luminescence dating results. Major element results show source rock change little, with the composition equivalent to granodiorite. The low R value and high CIA （chemical index of alteration） value indicating the section at primary weathering phases. The muddy silt and silty clay have low R value and high CIA value and total iron content. In contrast, the sandy clay silt and sandy silt have high R value and low CIA and total iron value. Deglaciation time climate was relatively humid. In comparison to previous and posterior hiatus, the Middle-Holocene climate was relatively wet but still displayed high-frequency and high-amplitude fluctuations.展开更多
The imbalance between supply and demand of Artemia cysts in China and around the world is increasing now.Salt lakes in Tibet may contribute to the solution of the problem.In Northern Tibet there are 26 saline lakes wh...The imbalance between supply and demand of Artemia cysts in China and around the world is increasing now.Salt lakes in Tibet may contribute to the solution of the problem.In Northern Tibet there are 26 saline lakes whose salinity and temperature may support Artemia survival at an altitude of 4 000–5 100 m.We found Artemia in 15 of these lakes.The saline lakes with Artemia populations mainly belong to the shallow basin lakes,and the majority of these lakes are small in area.The total area of lakes without Artemia is more than 1 000 km 2.Lake Dangxiong Co(Co means lake in Tibet) was chosen for the intentional introduction of Artemia sinica.In 2004,850 g of A.sinica cysts,originating from Qinghai,were introduced in the lake.Surveys in 2006–2014 showed that the average abundance of Artemia adults in the lake gradually increased from 20 ind./m 3 in 2006 to 1950 ind./m 3 in 2013.We assume that two subpopulations of A.sinica,separated by depth,may exist in the lake.The new Artemia population caused an increase in the number of species of phytoplankton and heterotrophic protozoa with a decrease of their total abundance.Water transparency also increased.Dominance in phytoplankton passed from cyanobacteria to diatoms.Changes occurred not only in the lake ecosystem;the number of water birds using the lakes also dramatically increased.Preliminary calculations showed that is it possible to harvest at least about 150 t cysts per year from the lake as well as 3.2 thousand tons of frozen or 350 t of dried biomass of adult Artemia.展开更多
103 surface sediment samples in 71 water bodies,such as lakes with different salinity,swamps,shallow puddles and rivers on the Qinghai-Tibetan Plateau(QTP),were collected to study the ecological distribution of living...103 surface sediment samples in 71 water bodies,such as lakes with different salinity,swamps,shallow puddles and rivers on the Qinghai-Tibetan Plateau(QTP),were collected to study the ecological distribution of living ostracods and their environmental implications.Total of 12 genus and 45 species living ostracods are identified.According to the frequencies and abundance of ostracods occurrence,Limnocythere dubiosa,Limnocytherellina kunlunensis,llyocypris bradyi,Candona candida,Eucypris rischtanica and Leucocythere dilatata are the common species on the QTP,with occurrence frequency of more than 8 and abundance of more than 570 in the 71 water bodies.Among them,L.dubiosa,occurring in 28 water bodies with 2177 shells,is the most widely distributed ostracod in this research.Canonical Correspondence Analysis(CCA)indicates high correlation between species and environmental variables,suggesting that the occurrence of species is strongly related to the changes in ecological conditions of habitats.Among eight environmental factors,salinity and pH value are the most affective variables that influence the species occurrence.L.kunlunensis is positively correlated with salinity while E.rischtanica is negatively correlated with salinity.C.candida has a positive correlation with salinity,as does I.bradyi although there is not such a strong correlation.L.dubiosa displays a positive correlation with pH value.Consequently,we discuss the environmental implications of the common living ostracods on the QTP based on the CCA as well as the distribution of ostracod species in different salinity and pH values water.L.dubiosa,L.kunlunensis and E.rischtanica are euryhaline species,among which,L.dubiosa is the most adaptable species on the QTP with large occurrence in sundry salinity water and the most widely adaptive range for pH values.L.kunlunensis prefers to saline water while E.rischtanica prefers to fresh water.Both L.kunlunensis and E.rischtanica can live in water from faintly acid to alkaline,in contrast,L.dubiosa only appears in neutral and alkaline water bodies.L bradyi only occurs in fresh water and oligohaline water with a large pH tolerance range tolerance range from weakly acidic water to alkaline water weakly acidic water to alkaline water.C.Candida lives in freshwater,with pH value above eight.The six common species reach maximum abundance in alkaline water(pH 8-10)except for llyocypris bradyi.展开更多
To reconstruct the productivity changes for the last 10 500 a in the northeastern East China Sea （ECS）, biogenic compounds （such as carbonate, organic carbon and opal）, marine micropaleontological fossils （plankt...To reconstruct the productivity changes for the last 10 500 a in the northeastern East China Sea （ECS）, biogenic compounds （such as carbonate, organic carbon and opal）, marine micropaleontological fossils （planktonic foraminifera, benthic foraminifera, radiolarian and silicoflagellate） and the compositional characters of benthic foraminifera fauna analyses were carried out on a sediment core DOC082 obtained from the western slope of Okinawa Trough （29°13.93′N, 128°08.53′E; 1 128 m water depth）. The long-term changes of biogenic and micropaleontological proxies display some similarities through the last 10 500 a, which show three different phases： lower values are recorded during the early and middle ttolocene （before about 4 000 a BP）, followed by an abrupt and remarkable increase at about 4 000 a BP, the late Holocene （after about 3 000 a BP） is characterized by continuously high values. The multi-proxy data of paleoproductivity and percents of benthic foraminifera genera （Uvigerina and Bulimina） show that during the early and middle Holocene （10 500-4 000 a BP） productivity was relatively low with a sudden and distinct increase at about 4 000 a BP, and the late Holocene （3 400-0 a BP） is marked by significantly higher productivity. Also, the radiolarian-based sea surface temperature （SST） records reveal a distinct decline in SST in the late Holocene after 3 200 a BP, very different from the early and middle Holocene. For the last 3 000 a, the enhanced biological productivity and distinctly lower SST indicate a major change of oceanographic conditions in the northeastern ECS. These marine environmental anomalies are consistent with other paleoclimatic records for the late Holocene in the Chinese continent and its surrounding regions. After analyzing the mechanisms of modern productivity and SST changes in the northeastern ECS, and based on the climatic anomalies in the Chinese continent and variations in the Kuroshio Current during modern El Nino periods, we suggest that the anomalous environmental conditions in the northeastern ECS may imply intensified El Nino activity during the late Holocene.展开更多
Rare earth elements （REE） compositions and discriminant function were successfully used to examine high resolution sediment source changes in the northern Okinawa Trough over the last 24.1 ka, especially for the inf...Rare earth elements （REE） compositions and discriminant function were successfully used to examine high resolution sediment source changes in the northern Okinawa Trough over the last 24.1 ka, especially for the influence from the Yellow River and the Tsushima Warm Current （TWC） that has not been well solved. Variations of these parameters were clearly divided into three distinct depositional units. During Interval 1 （24.1-16.0 ka BP）, the paleo-Yellow River and the paleo-Yangtze River mouths were situated near the studied area and could have played major roles in the sedimentation therein. In Interval 2 （16.0-7.3 ka BP）, these river mouths gradually retreated with global sea-level rise, leading to less fluvial inputs from them to the northern Okinawa Trough. Meanwhile, formation of the TWC could carry some sediment loads of Taiwan to the studied core, especially during its late phase （8.0-7.3 ka BP）. Modem oceanographic conditions, with a predominance of the TWC, were finally established since the beginning of Interval 3, causing more ten＇igenous contribution from Taiwan to the studied area. Subsequently, modem depositional environments mainly influenced by the Yellow River, the Yangtze River, and the TWC were finally formed.展开更多
Paleoenvironmental changes in the northern Okinawa trough covering the last 25 ka were synthetically reconstructed using REE and organic carbon indices of core CSH1.Variations of these parameters revealed three distin...Paleoenvironmental changes in the northern Okinawa trough covering the last 25 ka were synthetically reconstructed using REE and organic carbon indices of core CSH1.Variations of these parameters revealed three distinct intervals of major sediment provenance changes that can be related to sea-level fluctuation and Tsushima Warm Current evolution.Interval 1（16-24.7 ka BP） is characterized by dominantly fluvial discharge from the Changjiang（Yangtze River） and Huanghe（Yellow River） as well as high primary productivity.In Interval 2（7.3-16 ka BP）,the Changjiang and Huanghe mouths regressed with sea-level rising.The newly formed Tsushima Warm Current could carry some sediment loads of Taiwan to the study core,especially during its late phase（7.3-8.2 ka BP）.Modern oceanographic conditions were finally established since the beginning of Interval 3,leading to more terrigenous contribution from Taiwan,whereas low sea-surface productivity in the study area.展开更多
Diatom data of 192 surface sediment samples from the marginal seas in the western Pacific together with modern summer and winter sea surface temperature and salinity data were analyzed.The results of canonical corresp...Diatom data of 192 surface sediment samples from the marginal seas in the western Pacific together with modern summer and winter sea surface temperature and salinity data were analyzed.The results of canonical correspondence analysis show that summer sea-surface salinity(SSS) is highly positively correlated with winter SSS and so is summer sea-surface temperature(SST) with winter SST.The correlations between SSSs and SSTs are less positively correlated,which may be due to interactions of regional current pattern and monsoon climate.The correlations between diatom species,sample sites and environmental variables concur with known diatom ecology and regional oceanographic characters.The results of forward selection of the environmental variables and associated Monte Carlo permutation tests of the statistical significance of each variable suggest that summer SSS and winter SST are the main environmental factors affecting the diatom distribution in the area and therefore preserved diatom data from down core could be used for reconstructions of summer SSS and winter SST in the region.展开更多
Controlled by climate changes, there were three large-scale transgressions and regressions around the Bohai Sea during the late Quaternary, which were accepted by most geologists. However, a big controversy still exis...Controlled by climate changes, there were three large-scale transgressions and regressions around the Bohai Sea during the late Quaternary, which were accepted by most geologists. However, a big controversy still exists about the time when the transgressions occurred separately. In order to find out the process of the paleoenvironmental changes around the Bohai Sea in the late Quaternary, the foraminifera assemblages from a new borehole Lz908 in the southern coast of the Laizhou Bay were studied, and then the transgressive strata were indentified. Combined with accelerator mass spectrometry radiocarbon 14C（AMS14C） and optically stimulated luminescence（OSL） ages, the occurrence time of these transgressions were re-determined. The result showed that three major large-scale transgressions occurred separately at the beginning of marine isotopic stage 7（MIS7）, the last interglacial period（MIS5） and the Holocene. In addition, a small-scale transgression occurred in the mid-MIS6, and the corresponding transgressive stratum was deposited. The transgressive deposition of MIS3 was also discovered in this study. However, the characteristics of the foraminifera indicated the environment during this period was colder than that in the MIS5. By comparison with the global sea-level changes, the paleoenvironmental changes around the Bohai Sea in the late Quaternary can be consistent with the global climate changes.展开更多
Air quality monitoring is effective for timely understanding of the current air quality status of a region or city.Currently,the huge volume of environmental monitoring data,which has reasonable real-time performance,...Air quality monitoring is effective for timely understanding of the current air quality status of a region or city.Currently,the huge volume of environmental monitoring data,which has reasonable real-time performance,provides strong support for in-depth analysis of air pollution characteristics and causes.However,in the era of big data,to meet current demands for fine management of the atmospheric environment,it is important to explore the characteristics and causes of air pollution from multiple aspects for comprehensive and scientific evaluation of air quality.This study reviewed and summarized air quality evaluation methods on the basis of environmental monitoring data statistics during the 13th Five-Year Plan period,and evaluated the level of air pollution in the Beijing-Tianjin-Hebei region and its surrounding areas(i.e.,the“2+26”region)during the period of the three-year action plan to fight air pollution.We suggest that air quality should be comprehensively,deeply,and scientifically evaluated from the aspects of air pollution characteristics,causes,and influences of meteorological conditions and anthropogenic emissions.It is also suggested that a threeyear moving average be introduced as one of the evaluation indexes of long-term change of pollutants.Additionally,both temporal and spatial differences should be considered when removing confounding meteorological factors.展开更多
1 Introduction Ostracodes are good materials for studying palaeoenvironmental evolution because of their sensitive response to environment changes.At present,the environmental implications of ostracodes are mainly based
The fate of riverine sulfate ion (SO_(4)^(2-)) and its environmental effects in arid environment are difficult to evaluate due to its complicated sources and strongly coupled behaviors with water cycle which is signif...The fate of riverine sulfate ion (SO_(4)^(2-)) and its environmental effects in arid environment are difficult to evaluate due to its complicated sources and strongly coupled behaviors with water cycle which is significantly modified by humans.To understand the sulfur cycle in aquatic systems in arid environment,the chemical and sulfur and oxygen isotopic compositions (δ^(34)S_(SO4)and δ^(18)O_(SO4)) of major rivers around the Badain Jaran Desert,northwestern China,were investigated.These rivers had averaged SO_(4)^(2-)content at 1336μmol/L,over 10times higher than the global average.The δ^(34)S_(SO4)and δ^(18)O_(SO4)values ranged from-5.3‰to+11.8‰and+1.6‰to+12.8‰,respectively.The end-member analysis and the inverse model showed that riverine sulfate was mainly derived from evaporites dissolution (0-87%),sulfide oxidation (13%-100%) and precipitation (0-33%),indicating heterogeneity in sulfur sources and behaviors along the river drainage with the lithology variations and climate gradients.Multiple isotopic tools combining with hydro-chemistry compositions could be applied to reveal sulfur cycle in arid environment.Based on the calculation,sulfide oxidation plays the primary role in the headwater and upstream in the Qilian-Mountains area,where sulfide is widely exposed.While the proportion of evaporites dissolution contributing to riverine sulfate is much higher in downstream in a drier environment.Besides,less precipitation and higher temperature can lead to more intensive evaporation,affecting the process of sulfide oxidation and enhancing the rates of evaporites dissolution and sulfate precipitation in the basin.展开更多
As an anticonvulsant,oxcarbazepine(OXC)has attracted considerable attention for its potential threat to aquatic organisms.Density functional theory has been used to study the mechanisms and kinetics of OXC degradation...As an anticonvulsant,oxcarbazepine(OXC)has attracted considerable attention for its potential threat to aquatic organisms.Density functional theory has been used to study the mechanisms and kinetics of OXC degradation initiated by OH radicals in aqueous environment.A total of fourteen OH-addition pathways were investigated,and the addition to the C8 position of the right benzene ringwas themost vulnerable pathway,resulting in the intermediate IM8.The H-abstraction reactions initiated by OH radicalswere also explored,where the extraction site of the methylene group(C14)on the seven-member carbon heterocyclic ring was found to be the optimal path.The calculations show that the total rate constant of OXC with OH radicals is 9.47×10^(9)(mol/L)^(−1)sec^(−1),and the half-life time is 7.32 s at 298 K with the[·OH]of 10^(−11) mol/L.Moreover,the branch ratio values revealed that OH-addition(89.58%)shows more advantageous than H-abstraction(10.42%).To further understand the potential eco-toxicity of OXC and its transformation products to aquatic organisms,acute toxicity and chronic toxicity were evaluated using ECOSAR software.The toxicity assessment revealed that most degradation products such as OXC-2OH,OXC-4OH,OXC-1O-1OOH,and OXC-1OH’are innoxious to fish and daphnia.Conversely,green algae are more sensitive to these compounds.This study can provide an extensive investigation into the degradation of OXC by OH radicals and enrich the understanding of the aquatic oxidation processes of pharmaceuticals and personal care products(PPCPs).展开更多
A pool of dormant stages of planktonic organisms in saline lakes is a substantial component in the plankton communities;we need to take it into account to understand plankton dynamics.Hypersaline water bodies in Crime...A pool of dormant stages of planktonic organisms in saline lakes is a substantial component in the plankton communities;we need to take it into account to understand plankton dynamics.Hypersaline water bodies in Crimea,the largest peninsula in the Black Sea,constitute a very characteristic and peculiar habitat type in the region.We examined the presence of crustacean resting stages in sediments of dried up sites of the Crimean hypersaline lakes.Sediment samples were taken in 9 different lakes.Experiments performed on the hatching of these resting stages showed the presence of Moina salina(Cladocera),parthenogenetic Artemia and Artemia urmiana(Anostraca),Eucypris mareotica( inflata)(Ostracoda),and Cletocamptus retrogressus(Harpacticoida).Comparing the experimental results obtained with clean dried brine shrimp cysts and those kept in sediment samples,it was noted that clean cysts hatched much faster than those from sediments did.Some components in bottom sediments slow down and desynchronize hatching from resting eggs in different groups of crustaceans.The sediments of different lakes inhibited the nauplii output from Artemia and ostracod resting eggs to different degrees.More data are needed before we can discuss the reasons of this inhibition.The nonsynchronous output of active stages from the bottom resting ones may be an adaptation that allows crustacean species to exist in extreme and unpredictably changing environments,avoiding the risk that all may emerge at once under unsuitable conditions.展开更多
基金funded by Korea Environmental Industry&Technology Institute(KEITI)through“Development of Aquatic Ecosystem Service Evaluation Indicators and Valuation Technology”of the Korea Ministry of Environment(MOE)(RS-2025-02214985).
文摘This study examines the empirical feasibility of quantitatively integrating environmental value information into Strategic Environmental Assessment(SEA).An analytical framework was established to incorporate environmental cost estimates into the SEA process by utilizing ecosystem service unit values provided by the Environmental Valuation Information System(EVIS),a national platform developed to support the evaluation of policies and projects.The framework was applied to a case study involving a multipurpose rural water development project in South Korea.Ecosystem service losses resulting from the project were quantified using biophysical indicators,such as vegetation biomass,forest area,and hydrological functions,and subsequently monetized through the application of the market price method,replacement cost method,and contingent valuation method.The total annual environmental cost was estimated to be approximately KRW 56.18 billion,with the majority attributable to losses in forest conservation and climate regulation services.These findings demonstrate that quantified environmental data can serve as a robust basis for alternative comparison and site evaluation within SEA.The study provides empirical evidence supporting the advancement of SEA from a predominantly procedural tool focused on environmental protection to a more comprehensive sustainability assessment framework that integrates environmental,economic,and social considerations.Furthermore,the results suggest that EVIS-based quantitative information holds potential for broader application in other national evaluation systems,such as preliminary feasibility studies and regulatory impact assessments.
基金supported by the National Key Research and Development Program of China (Grant No. 2023YFC3706203)the National Natural Science Foundation of China (Grant Nos. 91644214, 22361162668, and 22406109)+1 种基金the China Postdoctoral Science Foundation (Grant No. 2024M751797)Shandong Postdoctoral Science Foundation (SDCX-ZG-202400178)
文摘Enhanced mass concentrations of aromatic-derived secondary organic aerosol(SOA)are frequently observed during humid-haze events.However,the influencing mechanism of relative humidity(RH)in aromatic-derived SOA formation remains incompletely understood.Here,the RH dependence of SOA formation in the presence of NOx was explored by a series of chamber experiments for toluene(TOL)and 1,3,5-trimethylbenzene(TMB)photooxidation.The yield of TOL SOA and TMB SOA increased by 221%and 52%with increasing RH from~8%to~70%,respectively.Analytical results from a high-resolution mass spectrometer showed that SOA constituents with high oxygen content(O/C>0.6)were more abundant in SOA formed in the~70%RH experiment.The elevated yields and O/C of SOA could be attributed to the promoted formation and particle-phase diffusivity of highly oxidized molecules.In addition,in comparison with TMB,TOL could produce more unsaturated aldehydes,which are oxidized into carboxylic acids with high O/C,leading to a more sensitive response of TOL SOA formation to the change in RH.Our work provides mechanistic insights into RH roles in aromatic SOA formation and is helpful for a better understanding of humid-haze events.
基金the National Research Foundation(NRF),Prime Minister’s Office,Singapore,under its Campus for Research Excellence and Technological Enterprise(CREATE)program(A-0001032-01-00)the National Natural Science Foundation of China(52376011).
文摘The increasing population and continuous urbanization make food security a key consideration in sustainable development.Efficient farming strategies with low environmental footprints are thus increasingly required to meet food demands.This study presents a design for environmentally friendly,economical,and modular vertical farming systems,in which vegetables are cultivated in a carbon dioxide(CO_(2))-enriched atmosphere enabled by direct air capture(DAC)and subjected to artificial light exposure.We established a vertical farming setup and conducted experiments to identify productive cultivation strategies by regulating lighting,CO_(2)concentration,biochar application,and plant species.Additionally,a self-developed DAC rotary adsorber was utilized to achieve stable and efficient CO_(2)enrichment.Compared with the control group,the fresh weight of the vegetables in the experimental groups increased by up to 57.5%.Furthermore,we performed a comprehensive evaluation of the design and demonstrated that integrating photovoltaic-thermal(PVT)and DAC units increased the system’s net present value(NPV)by 157%compared with a conventional design without these units.Importantly,we found it possible to maintain the low carbon footprint of the system(0.468 kg-CO_(2)equivalent·kg−1(CO_(2)eq·kg−1)-vegetable)in the production process.Parametric studies and an application analysis on a global scale reveal the wide adaptability of this strategy to diverse conditions.These findings,together with the modular characteristics of vertical farming systems,highlight the promising potential of this design to increase food security and foster sustainable agriculture.
基金Project supported by National Key Research and Development Program of China(2022YFB3504100,2021YFB3500600)National Natural Science Foundation of China(22208170)+4 种基金Basic Scientific Research Expenses Program of Universities directly under Inner Mongolia Autonomous Region(JY20220286)Cooperation Foundation for the Chunhui Plan Program of Ministry of Education of China(202200554)Open Project Program of Key Laboratory of Opticelectric Sensing and Analytical Chemistry for Life Science,MOE(M2024-7)Open Project Program of Anhui Province Key Laboratory of Pollutant Sensitive Materials and Environmental RemediatiSon(PSMER2023008)the Open Foundation of State Environmental Protection Key Laboratory of Soil Environmental Management and Pollution Control(SEMPC2023004)。
文摘Rare earth elements are highly applicable in photocatalysis due to their partially filled 4f orbitals,existing in electronic structures that facilitate the transfer of electrons during the reaction process.Among these materials,CeO_(2)has a distinctive external electronic structure(4f^(1)5d^(1)6s^(2)),abundant oxygen vacancies,and strong conversion ability of Ce^(4+)/Ce^(3+),which makes it an attractive candidate in the field of photocatalysis.To broaden its practical applications in the visible region,the drawbacks of a wide band gap and a slow Ce^(4+)/Ce^(3+)cycle have been addressed through the modification of CeO_(2),thereby accelerating light absorption and self-circulation,and enhancing photocatalytic activity.This paper presents a review of the preparation of modified CeO_(2)catalysts and their application in the conversion of cerium valence state in the photocatalytic degradation of pollutants in water.Furthermore,this paper presents a summary of the most recent development and current challenges,as well as prospect for the application of modified CeO_(2)-based materials.
基金Supported by the Science and Technology Cooperation and Exchange special project of Cooperation of Shanxi Province(202404041101014)the Fundamental Research Program of Shanxi Province(202403021212333)+3 种基金the Joint Funds of the National Natural Science Foundation of China(U24A20555)the Lvliang Key R&D of University-Local Cooperation(2023XDHZ10)the Initiation Fund for Doctoral Research of Taiyuan University of Science and Technology(20242026)the Outstanding Doctor Funding Award of Shanxi Province(20242080).
文摘To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced.
基金supported by the National Natural Science Foundation of China (Grant nos.: 40930105, 41172325)the Chinese Academy of Sciences (CAS) Strategic Priority Research Program (grant no. XDA05120502)
文摘Identifying the provenance of aeolian sediments in the Hunshandake Sandy Land is of great importance for understanding the formation of the dune fields in the mid-latitudes and for deciphering information about desert＇s responses to global change. By determining the major and trace elements concentrations of aeolian sands in three grain size fractions from the central and western parts of the Hunshandake Sandy Land, we systematically study the provenance and the depositional history of aeolian sands in this desert environment. Our results show that aeolian sands from the Hunshandake Sandy Land are enriched in SiO2 and are depleted in many other elements compared to those of the Upper Continent Crust （UCC）. Variations of the immobile elements ratios like Zr/Hf, La/Yb, Th/Nb, La/Nb, LaN/YbN, GdN/YbN are relatively large in the coarse and medium fractions but minor in the fine fractions. Eu anomalies are quite different in the coarse fractions, but mostly positive in the medium fractions and all negative in the fine fractions. Decreasing tendency of Zr concentrations from the west to the east in the Hunshandake Sandy Land is evident in the coarse sands but rather weak in the fine grain size fractions. Our geochemical data indicate that the sources for the coarse and medium fractions of aeolian sands are diverse, influenced by local geology and geomorphology, while the fine sand fractions are more homogenous due to intensive mixture mainly by aeolian processes. Various ratios of immobile elements suggest that these sands should be sourced primarily from the surrounding mountains by fluvial/alluvial processes rather than from any remote territories. Aeolian sands with Ce negative anomalies are widely distributed in the Hunshandake Sandy Land, indicating that aquatic environments have occurred extensively prior to the occurrence of the dune field.
基金Supported by the National Natural Science Foundation of China(No.41430965)the Open Fund of the Key Laboratory of Marine Geology and Environment,Chinese Academy of Sciences(No.MGE2015KG08)
文摘The East China Sea continental shelf is a unique area for the study of land-sea interactions and paleoenvironmental change because it receives a large amount of terrestrial material inputs. In recent decades, human activities and global climate change have greatly aff ected river discharges into the sea. However, changes in the deposition process caused by these factors in the East China Sea continental shelf are unclear. We collected eight short sediment cores from the East China Sea inner shelf(ECSIS) using a box core sampler in 2012 and 2015. The grainsize, 2 10 Pb, and 1 37 Cs of these cores were analyzed in order to reconstruct the deposition history since the 1950 s, and to reveal human activity and climate change influences on sediment deposition in the ECSIS. Results indicated that sediment grain size became finer after 1969, turned coarser after 1987, and then further coarser since 2003, corresponding well to the three steps of sediment load drop in the Changjiang(Yangtze) River, which are mainly caused by human activities(particularly the closure of the Three Gorges Dam). Simultaneously, the East Asian Monsoon influenced the deposition process in the ECSIS by changing the intensity of coastal currents. Mean grain size variations in the fine-grained population(divided by grain size vs. standard deviation method) coincided with that of the East Asian Winter Monsoon strength and reflected its weakness in 1987. Abrupt changes in sediment grain size over a short time scale in these sediment cores were generally caused by floods and typhoons. Spectral analyses of the sediment cores showed periodicities of 10–11 and 20–22 years, corresponding to the periodicity of solar activity(Schwabe cycle and Hale cycle). Mean grain size time series also displayed a 3–8 year periodicity corresponding to El Ni?o Southern Oscillation periodic change.
基金supported by the Key Consultation Project (No. 2008-ZD-05)of Chinese Academy of Engineeringthe National Natural Science Foundation of China (Nos. 40472094, 40772212)National Project (No. NP2010-033)
文摘Holocene palaeoweathering conditions and environmental changes of Loulan （楼兰） Stupa Sec-tion were reconstructed by major elements analysis results and optical stimulated luminescence dating results. Major element results show source rock change little, with the composition equivalent to granodiorite. The low R value and high CIA （chemical index of alteration） value indicating the section at primary weathering phases. The muddy silt and silty clay have low R value and high CIA value and total iron content. In contrast, the sandy clay silt and sandy silt have high R value and low CIA and total iron value. Deglaciation time climate was relatively humid. In comparison to previous and posterior hiatus, the Middle-Holocene climate was relatively wet but still displayed high-frequency and high-amplitude fluctuations.
基金Supported by the Special Fund for Public Welfare Land and Resources(No.201011001-4)the Project of China Geological Survey(No.1212011120982)
文摘The imbalance between supply and demand of Artemia cysts in China and around the world is increasing now.Salt lakes in Tibet may contribute to the solution of the problem.In Northern Tibet there are 26 saline lakes whose salinity and temperature may support Artemia survival at an altitude of 4 000–5 100 m.We found Artemia in 15 of these lakes.The saline lakes with Artemia populations mainly belong to the shallow basin lakes,and the majority of these lakes are small in area.The total area of lakes without Artemia is more than 1 000 km 2.Lake Dangxiong Co(Co means lake in Tibet) was chosen for the intentional introduction of Artemia sinica.In 2004,850 g of A.sinica cysts,originating from Qinghai,were introduced in the lake.Surveys in 2006–2014 showed that the average abundance of Artemia adults in the lake gradually increased from 20 ind./m 3 in 2006 to 1950 ind./m 3 in 2013.We assume that two subpopulations of A.sinica,separated by depth,may exist in the lake.The new Artemia population caused an increase in the number of species of phytoplankton and heterotrophic protozoa with a decrease of their total abundance.Water transparency also increased.Dominance in phytoplankton passed from cyanobacteria to diatoms.Changes occurred not only in the lake ecosystem;the number of water birds using the lakes also dramatically increased.Preliminary calculations showed that is it possible to harvest at least about 150 t cysts per year from the lake as well as 3.2 thousand tons of frozen or 350 t of dried biomass of adult Artemia.
基金supported by the National Natural Science Foundation of China(41372179)the Special Funds for Public Welfare Land and Resources Scientific Project(201311140)China Geological Survey(12120114048501)
文摘103 surface sediment samples in 71 water bodies,such as lakes with different salinity,swamps,shallow puddles and rivers on the Qinghai-Tibetan Plateau(QTP),were collected to study the ecological distribution of living ostracods and their environmental implications.Total of 12 genus and 45 species living ostracods are identified.According to the frequencies and abundance of ostracods occurrence,Limnocythere dubiosa,Limnocytherellina kunlunensis,llyocypris bradyi,Candona candida,Eucypris rischtanica and Leucocythere dilatata are the common species on the QTP,with occurrence frequency of more than 8 and abundance of more than 570 in the 71 water bodies.Among them,L.dubiosa,occurring in 28 water bodies with 2177 shells,is the most widely distributed ostracod in this research.Canonical Correspondence Analysis(CCA)indicates high correlation between species and environmental variables,suggesting that the occurrence of species is strongly related to the changes in ecological conditions of habitats.Among eight environmental factors,salinity and pH value are the most affective variables that influence the species occurrence.L.kunlunensis is positively correlated with salinity while E.rischtanica is negatively correlated with salinity.C.candida has a positive correlation with salinity,as does I.bradyi although there is not such a strong correlation.L.dubiosa displays a positive correlation with pH value.Consequently,we discuss the environmental implications of the common living ostracods on the QTP based on the CCA as well as the distribution of ostracod species in different salinity and pH values water.L.dubiosa,L.kunlunensis and E.rischtanica are euryhaline species,among which,L.dubiosa is the most adaptable species on the QTP with large occurrence in sundry salinity water and the most widely adaptive range for pH values.L.kunlunensis prefers to saline water while E.rischtanica prefers to fresh water.Both L.kunlunensis and E.rischtanica can live in water from faintly acid to alkaline,in contrast,L.dubiosa only appears in neutral and alkaline water bodies.L bradyi only occurs in fresh water and oligohaline water with a large pH tolerance range tolerance range from weakly acidic water to alkaline water weakly acidic water to alkaline water.C.Candida lives in freshwater,with pH value above eight.The six common species reach maximum abundance in alkaline water(pH 8-10)except for llyocypris bradyi.
基金Supported by the Knowledge Innovation Program of Chinese Academy of Sciences (Project No. KZCX2-YW-221)the State Key Basic Research and Development Plan of China (Project No2007CB815903)the National Natural Science Foundation of China (Project No. 40506015)
文摘To reconstruct the productivity changes for the last 10 500 a in the northeastern East China Sea （ECS）, biogenic compounds （such as carbonate, organic carbon and opal）, marine micropaleontological fossils （planktonic foraminifera, benthic foraminifera, radiolarian and silicoflagellate） and the compositional characters of benthic foraminifera fauna analyses were carried out on a sediment core DOC082 obtained from the western slope of Okinawa Trough （29°13.93′N, 128°08.53′E; 1 128 m water depth）. The long-term changes of biogenic and micropaleontological proxies display some similarities through the last 10 500 a, which show three different phases： lower values are recorded during the early and middle ttolocene （before about 4 000 a BP）, followed by an abrupt and remarkable increase at about 4 000 a BP, the late Holocene （after about 3 000 a BP） is characterized by continuously high values. The multi-proxy data of paleoproductivity and percents of benthic foraminifera genera （Uvigerina and Bulimina） show that during the early and middle Holocene （10 500-4 000 a BP） productivity was relatively low with a sudden and distinct increase at about 4 000 a BP, and the late Holocene （3 400-0 a BP） is marked by significantly higher productivity. Also, the radiolarian-based sea surface temperature （SST） records reveal a distinct decline in SST in the late Holocene after 3 200 a BP, very different from the early and middle Holocene. For the last 3 000 a, the enhanced biological productivity and distinctly lower SST indicate a major change of oceanographic conditions in the northeastern ECS. These marine environmental anomalies are consistent with other paleoclimatic records for the late Holocene in the Chinese continent and its surrounding regions. After analyzing the mechanisms of modern productivity and SST changes in the northeastern ECS, and based on the climatic anomalies in the Chinese continent and variations in the Kuroshio Current during modern El Nino periods, we suggest that the anomalous environmental conditions in the northeastern ECS may imply intensified El Nino activity during the late Holocene.
基金supported by the Public Science and Technology Research Funds Projects of Ocean,State Oceanic Administration of the People’s Republic of China (201005003)the National Natural Science Foundation of China (41230959,41106043,41076030)the National Basic Research Program of China (2007CB815903)
文摘Rare earth elements （REE） compositions and discriminant function were successfully used to examine high resolution sediment source changes in the northern Okinawa Trough over the last 24.1 ka, especially for the influence from the Yellow River and the Tsushima Warm Current （TWC） that has not been well solved. Variations of these parameters were clearly divided into three distinct depositional units. During Interval 1 （24.1-16.0 ka BP）, the paleo-Yellow River and the paleo-Yangtze River mouths were situated near the studied area and could have played major roles in the sedimentation therein. In Interval 2 （16.0-7.3 ka BP）, these river mouths gradually retreated with global sea-level rise, leading to less fluvial inputs from them to the northern Okinawa Trough. Meanwhile, formation of the TWC could carry some sediment loads of Taiwan to the studied core, especially during its late phase （8.0-7.3 ka BP）. Modem oceanographic conditions, with a predominance of the TWC, were finally established since the beginning of Interval 3, causing more ten＇igenous contribution from Taiwan to the studied area. Subsequently, modem depositional environments mainly influenced by the Yellow River, the Yangtze River, and the TWC were finally formed.
基金supported by the Open Fund of the Key Laboratory of Marine Geology and Environment,Chinese Academy of Sciences,the Innovative Program of Chinese Academy of Sciences(No.KZCX2-YW-221)the National Basic Research Program of China(No.2007CB815903)the National Natural Science Foundation of China(Nos. 41106043 and 40906038)
文摘Paleoenvironmental changes in the northern Okinawa trough covering the last 25 ka were synthetically reconstructed using REE and organic carbon indices of core CSH1.Variations of these parameters revealed three distinct intervals of major sediment provenance changes that can be related to sea-level fluctuation and Tsushima Warm Current evolution.Interval 1（16-24.7 ka BP） is characterized by dominantly fluvial discharge from the Changjiang（Yangtze River） and Huanghe（Yellow River） as well as high primary productivity.In Interval 2（7.3-16 ka BP）,the Changjiang and Huanghe mouths regressed with sea-level rising.The newly formed Tsushima Warm Current could carry some sediment loads of Taiwan to the study core,especially during its late phase（7.3-8.2 ka BP）.Modern oceanographic conditions were finally established since the beginning of Interval 3,leading to more terrigenous contribution from Taiwan,whereas low sea-surface productivity in the study area.
基金Supported by the support by the NSFC (No 40676027)the Fund for Creative Research Groups of China (No 40721004)the 111 Project (No B08022)
文摘Diatom data of 192 surface sediment samples from the marginal seas in the western Pacific together with modern summer and winter sea surface temperature and salinity data were analyzed.The results of canonical correspondence analysis show that summer sea-surface salinity(SSS) is highly positively correlated with winter SSS and so is summer sea-surface temperature(SST) with winter SST.The correlations between SSSs and SSTs are less positively correlated,which may be due to interactions of regional current pattern and monsoon climate.The correlations between diatom species,sample sites and environmental variables concur with known diatom ecology and regional oceanographic characters.The results of forward selection of the environmental variables and associated Monte Carlo permutation tests of the statistical significance of each variable suggest that summer SSS and winter SST are the main environmental factors affecting the diatom distribution in the area and therefore preserved diatom data from down core could be used for reconstructions of summer SSS and winter SST in the region.
基金The National Basic Research Program of China(973 Program)under contract No.2010CB951200the Marine Public Service Specific Research under contract No.201105020
文摘Controlled by climate changes, there were three large-scale transgressions and regressions around the Bohai Sea during the late Quaternary, which were accepted by most geologists. However, a big controversy still exists about the time when the transgressions occurred separately. In order to find out the process of the paleoenvironmental changes around the Bohai Sea in the late Quaternary, the foraminifera assemblages from a new borehole Lz908 in the southern coast of the Laizhou Bay were studied, and then the transgressive strata were indentified. Combined with accelerator mass spectrometry radiocarbon 14C（AMS14C） and optically stimulated luminescence（OSL） ages, the occurrence time of these transgressions were re-determined. The result showed that three major large-scale transgressions occurred separately at the beginning of marine isotopic stage 7（MIS7）, the last interglacial period（MIS5） and the Holocene. In addition, a small-scale transgression occurred in the mid-MIS6, and the corresponding transgressive stratum was deposited. The transgressive deposition of MIS3 was also discovered in this study. However, the characteristics of the foraminifera indicated the environment during this period was colder than that in the MIS5. By comparison with the global sea-level changes, the paleoenvironmental changes around the Bohai Sea in the late Quaternary can be consistent with the global climate changes.
基金supported by the National Key Research and Development Program of China(No.2019YFC0214800)。
文摘Air quality monitoring is effective for timely understanding of the current air quality status of a region or city.Currently,the huge volume of environmental monitoring data,which has reasonable real-time performance,provides strong support for in-depth analysis of air pollution characteristics and causes.However,in the era of big data,to meet current demands for fine management of the atmospheric environment,it is important to explore the characteristics and causes of air pollution from multiple aspects for comprehensive and scientific evaluation of air quality.This study reviewed and summarized air quality evaluation methods on the basis of environmental monitoring data statistics during the 13th Five-Year Plan period,and evaluated the level of air pollution in the Beijing-Tianjin-Hebei region and its surrounding areas(i.e.,the“2+26”region)during the period of the three-year action plan to fight air pollution.We suggest that air quality should be comprehensively,deeply,and scientifically evaluated from the aspects of air pollution characteristics,causes,and influences of meteorological conditions and anthropogenic emissions.It is also suggested that a threeyear moving average be introduced as one of the evaluation indexes of long-term change of pollutants.Additionally,both temporal and spatial differences should be considered when removing confounding meteorological factors.
基金supported by the National Natural Science Foundation of China (41372179)the Special Funds for Public Welfare Land and Resources Scientific Project (201311140)
文摘1 Introduction Ostracodes are good materials for studying palaeoenvironmental evolution because of their sensitive response to environment changes.At present,the environmental implications of ostracodes are mainly based
基金supported by the Strategic Priority Research Program of Chinese Academy of Sciences (No. XDB26000000)the National Key Research and Development Program of China (No. 2020YFA0607700)+2 种基金the National Natural Science Foundation of China (Nos. 41730857 and 42273050)the Key Research Program of the Institute of Geology&Geophysics,CAS (No. IGGCAS-202204)support from the Youth Innovation Promotion Association CAS (No.2019067)。
文摘The fate of riverine sulfate ion (SO_(4)^(2-)) and its environmental effects in arid environment are difficult to evaluate due to its complicated sources and strongly coupled behaviors with water cycle which is significantly modified by humans.To understand the sulfur cycle in aquatic systems in arid environment,the chemical and sulfur and oxygen isotopic compositions (δ^(34)S_(SO4)and δ^(18)O_(SO4)) of major rivers around the Badain Jaran Desert,northwestern China,were investigated.These rivers had averaged SO_(4)^(2-)content at 1336μmol/L,over 10times higher than the global average.The δ^(34)S_(SO4)and δ^(18)O_(SO4)values ranged from-5.3‰to+11.8‰and+1.6‰to+12.8‰,respectively.The end-member analysis and the inverse model showed that riverine sulfate was mainly derived from evaporites dissolution (0-87%),sulfide oxidation (13%-100%) and precipitation (0-33%),indicating heterogeneity in sulfur sources and behaviors along the river drainage with the lithology variations and climate gradients.Multiple isotopic tools combining with hydro-chemistry compositions could be applied to reveal sulfur cycle in arid environment.Based on the calculation,sulfide oxidation plays the primary role in the headwater and upstream in the Qilian-Mountains area,where sulfide is widely exposed.While the proportion of evaporites dissolution contributing to riverine sulfate is much higher in downstream in a drier environment.Besides,less precipitation and higher temperature can lead to more intensive evaporation,affecting the process of sulfide oxidation and enhancing the rates of evaporites dissolution and sulfate precipitation in the basin.
基金This work was supported by the Shandong Provincial Natural Science Foundation of China(No.ZR2021MB039)the National Natural Science Foundation of China(No.21607089)the Shandong Provincial Key Research and Development Program(Major Scientific and Technological Innovation Project)(No.2020CXGC011402).
文摘As an anticonvulsant,oxcarbazepine(OXC)has attracted considerable attention for its potential threat to aquatic organisms.Density functional theory has been used to study the mechanisms and kinetics of OXC degradation initiated by OH radicals in aqueous environment.A total of fourteen OH-addition pathways were investigated,and the addition to the C8 position of the right benzene ringwas themost vulnerable pathway,resulting in the intermediate IM8.The H-abstraction reactions initiated by OH radicalswere also explored,where the extraction site of the methylene group(C14)on the seven-member carbon heterocyclic ring was found to be the optimal path.The calculations show that the total rate constant of OXC with OH radicals is 9.47×10^(9)(mol/L)^(−1)sec^(−1),and the half-life time is 7.32 s at 298 K with the[·OH]of 10^(−11) mol/L.Moreover,the branch ratio values revealed that OH-addition(89.58%)shows more advantageous than H-abstraction(10.42%).To further understand the potential eco-toxicity of OXC and its transformation products to aquatic organisms,acute toxicity and chronic toxicity were evaluated using ECOSAR software.The toxicity assessment revealed that most degradation products such as OXC-2OH,OXC-4OH,OXC-1O-1OOH,and OXC-1OH’are innoxious to fish and daphnia.Conversely,green algae are more sensitive to these compounds.This study can provide an extensive investigation into the degradation of OXC by OH radicals and enrich the understanding of the aquatic oxidation processes of pharmaceuticals and personal care products(PPCPs).
文摘A pool of dormant stages of planktonic organisms in saline lakes is a substantial component in the plankton communities;we need to take it into account to understand plankton dynamics.Hypersaline water bodies in Crimea,the largest peninsula in the Black Sea,constitute a very characteristic and peculiar habitat type in the region.We examined the presence of crustacean resting stages in sediments of dried up sites of the Crimean hypersaline lakes.Sediment samples were taken in 9 different lakes.Experiments performed on the hatching of these resting stages showed the presence of Moina salina(Cladocera),parthenogenetic Artemia and Artemia urmiana(Anostraca),Eucypris mareotica( inflata)(Ostracoda),and Cletocamptus retrogressus(Harpacticoida).Comparing the experimental results obtained with clean dried brine shrimp cysts and those kept in sediment samples,it was noted that clean cysts hatched much faster than those from sediments did.Some components in bottom sediments slow down and desynchronize hatching from resting eggs in different groups of crustaceans.The sediments of different lakes inhibited the nauplii output from Artemia and ostracod resting eggs to different degrees.More data are needed before we can discuss the reasons of this inhibition.The nonsynchronous output of active stages from the bottom resting ones may be an adaptation that allows crustacean species to exist in extreme and unpredictably changing environments,avoiding the risk that all may emerge at once under unsuitable conditions.
