An attempt study of fine course construction strategy of modern education technology, Starting from the modern education technology professional career goals, while, in curriculum setting, highlights the profession＇...An attempt study of fine course construction strategy of modern education technology, Starting from the modern education technology professional career goals, while, in curriculum setting, highlights the profession＇ s ＂Normal＂ , and ＂technical＂ and ＂managerial＂ character. And fully reflect the characteristics of higher vocational college and strengthen the ability of students to achieve a to job competency-based, employment-oriented training model. Through the construction of the core curriculum system, cultivating high-quality skilled training objectives Normal talents.展开更多
With more educational business absorbed into information management system at universities, traditional information management platform seems unable to provide efficient service for teaching and research. Some univers...With more educational business absorbed into information management system at universities, traditional information management platform seems unable to provide efficient service for teaching and research. Some universities then resort to cloud computing platform. In view of the problems existing in the traditional information platform, this study presented an information management framework designed with cloud technology, and introduced the security techniques for its protection.展开更多
Elaborated the multimedia technologies in the teaching characteristic, definitely multimedia technical superiority at the same time, the union managed by the people university have used the question which in the multi...Elaborated the multimedia technologies in the teaching characteristic, definitely multimedia technical superiority at the same time, the union managed by the people university have used the question which in the multimedia technologies appears to propose some improvement method as well as in the multimedia technologies the question which should pay attention in the teaching. Proposed in the modem education media, the teacher reasonably chooses and utilizes the science teaching process through the teaching design which multimedia technical and the traditional teaching method organic synthesis forms, all played to the curriculum and the teaching method reform the positive role. The science uses the multimedia technologies, may avoid the multimedia technologies in classroom instruction application some erroneous zones, the realization teaching effect optimization.展开更多
To overcome the problem that soft sensor models cannot be updated with the process changes, a soft sensor modeling algorithm based on hybrid fuzzy c-means （FCM） algorithm and incremental support vector machines （I...To overcome the problem that soft sensor models cannot be updated with the process changes, a soft sensor modeling algorithm based on hybrid fuzzy c-means （FCM） algorithm and incremental support vector machines （ISVM） is proposed. This hybrid algorithm FCMISVM includes three parts： samples clustering based on FCM algorithm, learning algorithm based on ISVM, and heuristic sample displacement method. In the training process, the training samples are first clustered by the FCM algorithm, and then by training each clustering with the SVM algorithm, a sub-model is built to each clustering. In the predicting process, when an incremental sample that represents new operation information is introduced in the model, the fuzzy membership function of the sample to each clustering is first computed by the FCM algorithm. Then, a corresponding SVM sub-model of the clustering with the largest fuzzy membership function is used to predict and perform incremental learning so the model can be updated on-line. An old sample chosen by heuristic sample displacement method is then discarded from the sub-model to control the size of the working set. The proposed method is applied to predict the p-xylene （PX） purity in the adsorption separation process. Simulation results indicate that the proposed method actually increases the model＇s adaptive abilities to various operation conditions and improves its generalization capability.展开更多
Motivated by the widely used ans¨atz method and starting from the modified Riemann–Liouville derivative together with a fractional complex transformation that can be utilized to transform nonlinear fractional pa...Motivated by the widely used ans¨atz method and starting from the modified Riemann–Liouville derivative together with a fractional complex transformation that can be utilized to transform nonlinear fractional partial differential equations to nonlinear ordinary differential equations, new types of exact traveling wave solutions to three important nonlinear space- and time-fractional partial differential equations are obtained simultaneously in terms of solutions of a Riccati equation. The results are new and first reported in this paper.展开更多
Establishing structural load spectrum under actual operating conditions is a major problem in structural fatigue life analysis. This study introduces the load measuring method for the bogie frame structure. The load-m...Establishing structural load spectrum under actual operating conditions is a major problem in structural fatigue life analysis. This study introduces the load measuring method for the bogie frame structure. The load-measuring frame based on quasi-static can measure different load systems synchronously. The t-test method is employed to evaluate the least test time of deducing the parent distribution. In order to fit the load spectrum distribution accurately, the kernel density estimation method is employed which is based on the sample characteristics. The expansion factor method is used to deduce the maximum load. The formula of standardized load spectrum derives from the deduced maximum load, the linear factor between operating condition length and cumulative frequency and the parent distribution of each load system. The damage consistency criterion is performed by solving the objective function with constraint conditions. The calibrated damage provides a suitable representation of the real damage under actual operating conditions. By processing and analyzing the load spectrum and stress spectrum data of the measured lines, it is verified that the standardized load spectrum established in this paper is superior to the European specification and the Japanese specification in evaluating the fatigue reliability of the structure.展开更多
Traveling wave solutions have been well studied for various nonlinear systems.However,for high order nonlinear physical models,there still exist various open problems.Here,travelling wave solutions to the well-known f...Traveling wave solutions have been well studied for various nonlinear systems.However,for high order nonlinear physical models,there still exist various open problems.Here,travelling wave solutions to the well-known fifth-order nonlinear physical model,the Sawada–Kotera equation,are revisited.Abundant travelling wave structures including soliton molecules,soliton lattice,kink-antikink molecules,peak-plateau soliton molecules,few-cycle-pulse solitons,double-peaked and triple-peaked solitons are unearthed.展开更多
A new method for discretization of continuous attributes is put forward to overcome the limitation of the traditional rough sets, which cannot deal with continuous attributes.The method is based on an improved algorit...A new method for discretization of continuous attributes is put forward to overcome the limitation of the traditional rough sets, which cannot deal with continuous attributes.The method is based on an improved algorithm to produce candidate cut points and an algorithm of reduction based on variable precision rough information entropy. With the guarantee of consistency of decision system, the method can reduce the number of cut points and im- prove efficiency of reduction. Adopting variable precision rough information entropy as measure criterion, it has a good tolerance to noise. Experiments show that the algorithm yields satisfying reduction results.展开更多
A new knowledge measure with parameter of intuitionistic fuzzy sets (IFSs) is presented based on the membership degree and the non-membership degree of IFSs, which complies with the extended form of Szmidt-Kacprzyk ax...A new knowledge measure with parameter of intuitionistic fuzzy sets (IFSs) is presented based on the membership degree and the non-membership degree of IFSs, which complies with the extended form of Szmidt-Kacprzyk axioms for intuitionistic fuzzy entropy. And a sufficient and necessary condition of order property in the Szmidt-Kacprzyk axioms is discussed. Additionally, some numerical examples are given to illustrate the applications of the proposed knowledge measure and some conventional entropies and knowledge measures of IFSs. The experimental results show that the results of the parametric model proposed in this paper are more accurate than those of most of the classic models.展开更多
Due to lack of strictly defined formal semantics, an UML activity diagram is unsuitable for the tasks of formal analysis, verification and assertion on the system it describes. In this paper, Petri net is used to defi...Due to lack of strictly defined formal semantics, an UML activity diagram is unsuitable for the tasks of formal analysis, verification and assertion on the system it describes. In this paper, Petri net is used to define the formal semantics of an UML activity diagram containing object flow states, laying a foundation for the precise description and analysis of a workflow system.展开更多
By analyzing the correlation between courses in students’grades,we can provide a decision-making basis for the revision of courses and syllabi,rationally optimize courses,and further improve teaching effects.With the...By analyzing the correlation between courses in students’grades,we can provide a decision-making basis for the revision of courses and syllabi,rationally optimize courses,and further improve teaching effects.With the help of IBM SPSS Modeler data mining software,this paper uses Apriori algorithm for association rule mining to conduct an in-depth analysis of the grades of nursing students in Shandong College of Traditional Chinese Medicine,and to explore the correlation between professional basic courses and professional core courses.Lastly,according to the detailed analysis of the mining results,valuable curriculum information will be found from the actual teaching data.展开更多
The thermal behaviors of five proteins in hydrophobic interaction chromatography （HIC） were investigated in the temperature range from 0 to 50℃. The thermodynamic parameters （△H°,△S°, △Cp°and △G...The thermal behaviors of five proteins in hydrophobic interaction chromatography （HIC） were investigated in the temperature range from 0 to 50℃. The thermodynamic parameters （△H°,△S°, △Cp°and △G°） of these proteins in the process of retention and unfolding were determined. The existence of enthalpy and entropy convergence with temperature was confirmed. The differences of the isoentropic and isoenthalpic temperatures for protein unfolding in HIC system from the traditional solution were elucidated.展开更多
To determine CDN cache servers'placement reasonably,an idea that using graph partitioning to solve the problem was put forward through theoretical analysis and the specific algorithm of partitioning was researched...To determine CDN cache servers'placement reasonably,an idea that using graph partitioning to solve the problem was put forward through theoretical analysis and the specific algorithm of partitioning was researched. The concept of graph partitioning for CDN was defined. The conditions of graph partitioning for CDN were demonstrated: the sum of the weights of the nodes in each subarea is as close as possible; edge cut between the subareas is as large as possible; internal nodes in each subarea are connected as far as possible. By reference to light vertex matching algorithm of graph partitioning for network simulation,a multilevel k-way algorithm of graph partitioning for CDN was proposed. The maximized edge cut k-way KL refinement algorithm was discussed. Graph partitioning is a feasible way to solve the problem of CDN servers'placement. Multilevel k-way algorithm is a feasible algorithm for CDN graph partitioning.展开更多
A novel method is proposed for treating cylindrical probe characteristics to obtain plasma density. The method consists of exponential extrapolation of the transitional part of the I -V curve to the floating potential...A novel method is proposed for treating cylindrical probe characteristics to obtain plasma density. The method consists of exponential extrapolation of the transitional part of the I -V curve to the floating potential for the ion saturation current, other than the existing theories which use the ion branch, and an iterative sheath thickness correction procedure for improved accuracy. The method was tested by treating Langmuir probe I-V characteristics obtained from inductively coupled Ar discharges at various pressures, and comparing the present results with those deduced by existing theories. It was shown that the plasma densities obtained by the present method are in good agreement with those calculated by the Allen-Boyd-Reynolds （ABR） theory, suggesting the effectiveness of the proposed method. Without need of manual setting and adjustment of fitting parameters, the method may be suitable for automatic and real time processing of probe characteristics.展开更多
A new parallel architecture for quantified boolean formula(QBF)solving was proposed,and the prediction model based on machine learning technology was proposed for how sharing knowledge affects the solving performance ...A new parallel architecture for quantified boolean formula(QBF)solving was proposed,and the prediction model based on machine learning technology was proposed for how sharing knowledge affects the solving performance in QBF parallel solving system,and the experimental evaluation scheme was also designed.It shows that the characterization factor of clause and cube influence the solving performance markedly in our experiment.At the same time,the heuristic machine learning algorithm was applied,support vector machine was chosen to predict the performance of QBF parallel solving system based on clause sharing and cube sharing.The relative error of accuracy for prediction can be controlled in a reasonable range of 20%30%.The results show the important and complex role that knowledge sharing plays in any modern parallel solver.It shows that the parallel solver with machine learning reduces the quantity of knowledge sharing about 30%and saving computational resource but does not reduce the performance of solving system.展开更多
The double row layout problem(DRLP)is to assign facilities on two rows in parallel so that the total cost of material handling among facilities is minimized.Since it is vital to save cost and enhance productivity,the ...The double row layout problem(DRLP)is to assign facilities on two rows in parallel so that the total cost of material handling among facilities is minimized.Since it is vital to save cost and enhance productivity,the DRLP plays an important role in many application fields.Nevertheless,it is very hard to handle the DRLP because of its complex model.In this paper,we consider a new simplified model for the DRLP(SM-DRLP)and provide a mixed integer programming(MIP)formulation for it.The continuous decision variables of the DRLP are divided into two parts:start points of double rows and adjustable clearances between adjacent facilities.The former one is considered in the new simplified model for the DRLP with the purpose of maintaining solution quality,while the latter one is not taken into account with the purpose of reducing computational time.To evaluate its performance,our SM-DRLP is compared with the model of a general DRLP and the model of another simplified DRLP.The experimental results show the efficiency of our proposed model.展开更多
Reactions of Cd（OAC）2·2H2O with m-thioacetatebenzoic acid（H2L） and 1,10-phenanthroline（phen） give rise to a metal-organic framework,[CdL（phen）]n（1）.X-ray single-crystal diffraction reveals that 1 crysta...Reactions of Cd（OAC）2·2H2O with m-thioacetatebenzoic acid（H2L） and 1,10-phenanthroline（phen） give rise to a metal-organic framework,[CdL（phen）]n（1）.X-ray single-crystal diffraction reveals that 1 crystallizes in the monoclinic system,space group C2/c,with a= 25.7099（5）,b=10.3872（2）,c=19.1820（4）,β=131.114（1）°,V=3859.4（1）3,Mr=502.80,Z= 8,F（000）=2000,μ=1.271 mm-1,Dc=1.731 g·cm-3,the final R=0.0226 and wR=0.0559 for 3817 observed reflections（Ⅰ〉 2σ（Ⅰ））.1 displays a 1D double-strand chain structure with crab-like dinuclear subunits,and extends into a 3D network by π-π interactions and C-H···O hydrogen bonds.Photoluminescence studies reveal that it displays intense structure-related fluorescent emission bands（λex=342 nm） at 370.5 and 389 nm in the solid state at room temperature.展开更多
We have investigated the electronic and magnetic properties of zigzag phosphorene nanoribbons(ZPNRs)with transition metal(TM)passivated atoms,it can be found that the ZPNRs with TM passivated atoms exhibit different m...We have investigated the electronic and magnetic properties of zigzag phosphorene nanoribbons(ZPNRs)with transition metal(TM)passivated atoms,it can be found that the ZPNRs with TM passivated atoms exhibit different magnetisms except for the Ni-passivated system.Meanwhile,the results show that the magnetic moments of ZPNRs with TM passivated atoms are larger than that of ZPNRs with other passivated non-metals/groups.Interestingly,it can be found that Fe-passivated ZPNR exhibits magnetic semiconducting character,which provides the possbility for the application of phosphorene in information storage.For Mn-passivated ZPNRs,it exhibits the half-metallicity.These results may be useful for potential applications of phosphorene in electronic and high-performance spintronic devices.展开更多
文摘An attempt study of fine course construction strategy of modern education technology, Starting from the modern education technology professional career goals, while, in curriculum setting, highlights the profession＇ s ＂Normal＂ , and ＂technical＂ and ＂managerial＂ character. And fully reflect the characteristics of higher vocational college and strengthen the ability of students to achieve a to job competency-based, employment-oriented training model. Through the construction of the core curriculum system, cultivating high-quality skilled training objectives Normal talents.
文摘With more educational business absorbed into information management system at universities, traditional information management platform seems unable to provide efficient service for teaching and research. Some universities then resort to cloud computing platform. In view of the problems existing in the traditional information platform, this study presented an information management framework designed with cloud technology, and introduced the security techniques for its protection.
文摘Elaborated the multimedia technologies in the teaching characteristic, definitely multimedia technical superiority at the same time, the union managed by the people university have used the question which in the multimedia technologies appears to propose some improvement method as well as in the multimedia technologies the question which should pay attention in the teaching. Proposed in the modem education media, the teacher reasonably chooses and utilizes the science teaching process through the teaching design which multimedia technical and the traditional teaching method organic synthesis forms, all played to the curriculum and the teaching method reform the positive role. The science uses the multimedia technologies, may avoid the multimedia technologies in classroom instruction application some erroneous zones, the realization teaching effect optimization.
基金Supported by the National Natural Science Foundation of China （60421002） and priority supported financially by ＂the New Century 151 Talent Project＂ of Zhejiang Province.
文摘To overcome the problem that soft sensor models cannot be updated with the process changes, a soft sensor modeling algorithm based on hybrid fuzzy c-means （FCM） algorithm and incremental support vector machines （ISVM） is proposed. This hybrid algorithm FCMISVM includes three parts： samples clustering based on FCM algorithm, learning algorithm based on ISVM, and heuristic sample displacement method. In the training process, the training samples are first clustered by the FCM algorithm, and then by training each clustering with the SVM algorithm, a sub-model is built to each clustering. In the predicting process, when an incremental sample that represents new operation information is introduced in the model, the fuzzy membership function of the sample to each clustering is first computed by the FCM algorithm. Then, a corresponding SVM sub-model of the clustering with the largest fuzzy membership function is used to predict and perform incremental learning so the model can be updated on-line. An old sample chosen by heuristic sample displacement method is then discarded from the sub-model to control the size of the working set. The proposed method is applied to predict the p-xylene （PX） purity in the adsorption separation process. Simulation results indicate that the proposed method actually increases the model＇s adaptive abilities to various operation conditions and improves its generalization capability.
基金Supported by National Natural Science Foundation of China under Grant Nos.11071278,111471004the Fundamental Research Funds for the Central Universities of GK201302026 and GK201102007
文摘Motivated by the widely used ans¨atz method and starting from the modified Riemann–Liouville derivative together with a fractional complex transformation that can be utilized to transform nonlinear fractional partial differential equations to nonlinear ordinary differential equations, new types of exact traveling wave solutions to three important nonlinear space- and time-fractional partial differential equations are obtained simultaneously in terms of solutions of a Riccati equation. The results are new and first reported in this paper.
基金This work was supported by the National Natural Science Foundation of China (Grant 51565013).
文摘Establishing structural load spectrum under actual operating conditions is a major problem in structural fatigue life analysis. This study introduces the load measuring method for the bogie frame structure. The load-measuring frame based on quasi-static can measure different load systems synchronously. The t-test method is employed to evaluate the least test time of deducing the parent distribution. In order to fit the load spectrum distribution accurately, the kernel density estimation method is employed which is based on the sample characteristics. The expansion factor method is used to deduce the maximum load. The formula of standardized load spectrum derives from the deduced maximum load, the linear factor between operating condition length and cumulative frequency and the parent distribution of each load system. The damage consistency criterion is performed by solving the objective function with constraint conditions. The calibrated damage provides a suitable representation of the real damage under actual operating conditions. By processing and analyzing the load spectrum and stress spectrum data of the measured lines, it is verified that the standardized load spectrum established in this paper is superior to the European specification and the Japanese specification in evaluating the fatigue reliability of the structure.
基金Supported by the National Natural Science Foundation of China(Grant Nos.11975131, 11435005 and 11471004)K.C.Wong Magna Fund in Ningbo University
文摘Traveling wave solutions have been well studied for various nonlinear systems.However,for high order nonlinear physical models,there still exist various open problems.Here,travelling wave solutions to the well-known fifth-order nonlinear physical model,the Sawada–Kotera equation,are revisited.Abundant travelling wave structures including soliton molecules,soliton lattice,kink-antikink molecules,peak-plateau soliton molecules,few-cycle-pulse solitons,double-peaked and triple-peaked solitons are unearthed.
文摘A new method for discretization of continuous attributes is put forward to overcome the limitation of the traditional rough sets, which cannot deal with continuous attributes.The method is based on an improved algorithm to produce candidate cut points and an algorithm of reduction based on variable precision rough information entropy. With the guarantee of consistency of decision system, the method can reduce the number of cut points and im- prove efficiency of reduction. Adopting variable precision rough information entropy as measure criterion, it has a good tolerance to noise. Experiments show that the algorithm yields satisfying reduction results.
文摘A new knowledge measure with parameter of intuitionistic fuzzy sets (IFSs) is presented based on the membership degree and the non-membership degree of IFSs, which complies with the extended form of Szmidt-Kacprzyk axioms for intuitionistic fuzzy entropy. And a sufficient and necessary condition of order property in the Szmidt-Kacprzyk axioms is discussed. Additionally, some numerical examples are given to illustrate the applications of the proposed knowledge measure and some conventional entropies and knowledge measures of IFSs. The experimental results show that the results of the parametric model proposed in this paper are more accurate than those of most of the classic models.
文摘Due to lack of strictly defined formal semantics, an UML activity diagram is unsuitable for the tasks of formal analysis, verification and assertion on the system it describes. In this paper, Petri net is used to define the formal semantics of an UML activity diagram containing object flow states, laying a foundation for the precise description and analysis of a workflow system.
文摘By analyzing the correlation between courses in students’grades,we can provide a decision-making basis for the revision of courses and syllabi,rationally optimize courses,and further improve teaching effects.With the help of IBM SPSS Modeler data mining software,this paper uses Apriori algorithm for association rule mining to conduct an in-depth analysis of the grades of nursing students in Shandong College of Traditional Chinese Medicine,and to explore the correlation between professional basic courses and professional core courses.Lastly,according to the detailed analysis of the mining results,valuable curriculum information will be found from the actual teaching data.
文摘The thermal behaviors of five proteins in hydrophobic interaction chromatography （HIC） were investigated in the temperature range from 0 to 50℃. The thermodynamic parameters （△H°,△S°, △Cp°and △G°） of these proteins in the process of retention and unfolding were determined. The existence of enthalpy and entropy convergence with temperature was confirmed. The differences of the isoentropic and isoenthalpic temperatures for protein unfolding in HIC system from the traditional solution were elucidated.
基金Sponsored by the National Natural Science Foundation of China(Grant No.60973027)Science Projects of China National Ministry of Information Industry(Grant No.01XK230009)
文摘To determine CDN cache servers'placement reasonably,an idea that using graph partitioning to solve the problem was put forward through theoretical analysis and the specific algorithm of partitioning was researched. The concept of graph partitioning for CDN was defined. The conditions of graph partitioning for CDN were demonstrated: the sum of the weights of the nodes in each subarea is as close as possible; edge cut between the subareas is as large as possible; internal nodes in each subarea are connected as far as possible. By reference to light vertex matching algorithm of graph partitioning for network simulation,a multilevel k-way algorithm of graph partitioning for CDN was proposed. The maximized edge cut k-way KL refinement algorithm was discussed. Graph partitioning is a feasible way to solve the problem of CDN servers'placement. Multilevel k-way algorithm is a feasible algorithm for CDN graph partitioning.
文摘A novel method is proposed for treating cylindrical probe characteristics to obtain plasma density. The method consists of exponential extrapolation of the transitional part of the I -V curve to the floating potential for the ion saturation current, other than the existing theories which use the ion branch, and an iterative sheath thickness correction procedure for improved accuracy. The method was tested by treating Langmuir probe I-V characteristics obtained from inductively coupled Ar discharges at various pressures, and comparing the present results with those deduced by existing theories. It was shown that the plasma densities obtained by the present method are in good agreement with those calculated by the Allen-Boyd-Reynolds （ABR） theory, suggesting the effectiveness of the proposed method. Without need of manual setting and adjustment of fitting parameters, the method may be suitable for automatic and real time processing of probe characteristics.
基金Project(61171141)supported by the National Natural Science Foundation of China
文摘A new parallel architecture for quantified boolean formula(QBF)solving was proposed,and the prediction model based on machine learning technology was proposed for how sharing knowledge affects the solving performance in QBF parallel solving system,and the experimental evaluation scheme was also designed.It shows that the characterization factor of clause and cube influence the solving performance markedly in our experiment.At the same time,the heuristic machine learning algorithm was applied,support vector machine was chosen to predict the performance of QBF parallel solving system based on clause sharing and cube sharing.The relative error of accuracy for prediction can be controlled in a reasonable range of 20%30%.The results show the important and complex role that knowledge sharing plays in any modern parallel solver.It shows that the parallel solver with machine learning reduces the quantity of knowledge sharing about 30%and saving computational resource but does not reduce the performance of solving system.
基金Supported by the National Natural Science Foundation of China(61871204,62174033)the Natural Science Foundation of Fujian Province(2017J01767,2020J01843)+1 种基金the Program for New Century Excellent Talents in Fujian Province Universitythe Science and Technology Project of Minjiang University(MYK19017)。
文摘The double row layout problem(DRLP)is to assign facilities on two rows in parallel so that the total cost of material handling among facilities is minimized.Since it is vital to save cost and enhance productivity,the DRLP plays an important role in many application fields.Nevertheless,it is very hard to handle the DRLP because of its complex model.In this paper,we consider a new simplified model for the DRLP(SM-DRLP)and provide a mixed integer programming(MIP)formulation for it.The continuous decision variables of the DRLP are divided into two parts:start points of double rows and adjustable clearances between adjacent facilities.The former one is considered in the new simplified model for the DRLP with the purpose of maintaining solution quality,while the latter one is not taken into account with the purpose of reducing computational time.To evaluate its performance,our SM-DRLP is compared with the model of a general DRLP and the model of another simplified DRLP.The experimental results show the efficiency of our proposed model.
文摘Reactions of Cd（OAC）2·2H2O with m-thioacetatebenzoic acid（H2L） and 1,10-phenanthroline（phen） give rise to a metal-organic framework,[CdL（phen）]n（1）.X-ray single-crystal diffraction reveals that 1 crystallizes in the monoclinic system,space group C2/c,with a= 25.7099（5）,b=10.3872（2）,c=19.1820（4）,β=131.114（1）°,V=3859.4（1）3,Mr=502.80,Z= 8,F（000）=2000,μ=1.271 mm-1,Dc=1.731 g·cm-3,the final R=0.0226 and wR=0.0559 for 3817 observed reflections（Ⅰ〉 2σ（Ⅰ））.1 displays a 1D double-strand chain structure with crab-like dinuclear subunits,and extends into a 3D network by π-π interactions and C-H···O hydrogen bonds.Photoluminescence studies reveal that it displays intense structure-related fluorescent emission bands（λex=342 nm） at 370.5 and 389 nm in the solid state at room temperature.
基金Project supported by the National Natural Science Foundation of China(Grant No.11564008)the Natural Science Foundation of Guangxi Zhuang Autonomous Region,China(Grant No.2017GXNSFAA198195)the Shanghai Supercomputer Center。
文摘We have investigated the electronic and magnetic properties of zigzag phosphorene nanoribbons(ZPNRs)with transition metal(TM)passivated atoms,it can be found that the ZPNRs with TM passivated atoms exhibit different magnetisms except for the Ni-passivated system.Meanwhile,the results show that the magnetic moments of ZPNRs with TM passivated atoms are larger than that of ZPNRs with other passivated non-metals/groups.Interestingly,it can be found that Fe-passivated ZPNR exhibits magnetic semiconducting character,which provides the possbility for the application of phosphorene in information storage.For Mn-passivated ZPNRs,it exhibits the half-metallicity.These results may be useful for potential applications of phosphorene in electronic and high-performance spintronic devices.
