The surface acidity of synthetic amorphous AI hydroxide was determined by acid/base titration with several complementary methods including solution analyses of the reacted solutions and XRD characterization of the rea...The surface acidity of synthetic amorphous AI hydroxide was determined by acid/base titration with several complementary methods including solution analyses of the reacted solutions and XRD characterization of the reacted solids. The synthetic specimen was characterized to be the amorphous material showing four broad peaks in XRD pattern. XRD analyses of reacted solids after the titration experiments showed that amorphous AI hydroxide rapidly transformed to crystalline bayerite at the alkaline condition （pH〉10）. The solution analyses after and during the titration Ksp=^aAl^3＋/aH^＋^3 ,was 10^10.3. The amount of consumption of added acid or base during the titration experiment was attributed to both the protonation/deprotonation of dissolved AI species and surface hydroxyl group. The surface acidity constants, surface hydroxyl density and specific surface area were estimated by FITEQL 4.0.展开更多
Hybrid atomization is a new powder-making method and can produce economically very fine, clean, spherical tin alloy powders with average particle size about 10μm and narrow size distributions. The key concept of hybr...Hybrid atomization is a new powder-making method and can produce economically very fine, clean, spherical tin alloy powders with average particle size about 10μm and narrow size distributions. The key concept of hybrid atomization is to control the liquid film formation on disk for fine powder production. Low-pressure gas atomization was utilized to promote the formation of a very thin stable liquid film before centrifugal breakup and give a better preparation for the final disintegration of melts. Besides the breakup ability of the rotating atomizer, the characteristics of liquid film on rotating disk affect the atomization mechanism and results remarkably. The main disintegration mode of melt is the breakup type of liquid film, which depends on the film instability and the atomization ability of the rotating disk. On the other hand, the mean powder size relates closely to the film thickness. The powder size distribution is mainly controlled by the atomization mode and the stability, flow type of liquid film on the rotating disk. A very thin, stable liquid film with long ligaments and a small pitch in LF mode results in very fine uniform tin alloy powders.展开更多
Lath-shaped and highly crystalline trioctahedral smectites were synthesized under hydrothermal conditions. The quenched glasses with stoichiometrically dehydrated Na-smectite compositions were treated at （a） 500℃ a...Lath-shaped and highly crystalline trioctahedral smectites were synthesized under hydrothermal conditions. The quenched glasses with stoichiometrically dehydrated Na-smectite compositions were treated at （a） 500℃ and 100 MPa for 1 and 11 days; and （b） 300℃ and 100 MPa for 7 days. The crystallinity and particle size of products were dependent on the chemical composition of the starting glass, synthetic temperature and duration of hydrothermal treatment. The high structural ordering and large dimensions of the products were confirmed from the sharpness of XRD peaks; and hydration behavior under controlled relative humidity. Transmission electron microscopy was also performed for the characterization of the particle size of product. Particle sizes vary from ca. 10 nm to a few pm by changing the chemical compositions of the starting materials. The product with the highest structural ordering and largest dimension was obtained from Nao.33（Mg1.83Al0.67）Si4O11 glass treated at 500℃ and 100 MPa for 1 day. The obtained results also confirmed the metastability and compositional dependency in the formation of highly crystalline trioctahedral smectite at hydrothermal conditions.展开更多
文摘The surface acidity of synthetic amorphous AI hydroxide was determined by acid/base titration with several complementary methods including solution analyses of the reacted solutions and XRD characterization of the reacted solids. The synthetic specimen was characterized to be the amorphous material showing four broad peaks in XRD pattern. XRD analyses of reacted solids after the titration experiments showed that amorphous AI hydroxide rapidly transformed to crystalline bayerite at the alkaline condition （pH〉10）. The solution analyses after and during the titration Ksp=^aAl^3＋/aH^＋^3 ,was 10^10.3. The amount of consumption of added acid or base during the titration experiment was attributed to both the protonation/deprotonation of dissolved AI species and surface hydroxyl group. The surface acidity constants, surface hydroxyl density and specific surface area were estimated by FITEQL 4.0.
基金Project(NCET-05-0737) supported by the Program for New Century Excellent Talents in University, ChinaProject(50774035) supported by the National Natural Science Foundation of China
文摘Hybrid atomization is a new powder-making method and can produce economically very fine, clean, spherical tin alloy powders with average particle size about 10μm and narrow size distributions. The key concept of hybrid atomization is to control the liquid film formation on disk for fine powder production. Low-pressure gas atomization was utilized to promote the formation of a very thin stable liquid film before centrifugal breakup and give a better preparation for the final disintegration of melts. Besides the breakup ability of the rotating atomizer, the characteristics of liquid film on rotating disk affect the atomization mechanism and results remarkably. The main disintegration mode of melt is the breakup type of liquid film, which depends on the film instability and the atomization ability of the rotating disk. On the other hand, the mean powder size relates closely to the film thickness. The powder size distribution is mainly controlled by the atomization mode and the stability, flow type of liquid film on the rotating disk. A very thin, stable liquid film with long ligaments and a small pitch in LF mode results in very fine uniform tin alloy powders.
文摘Lath-shaped and highly crystalline trioctahedral smectites were synthesized under hydrothermal conditions. The quenched glasses with stoichiometrically dehydrated Na-smectite compositions were treated at （a） 500℃ and 100 MPa for 1 and 11 days; and （b） 300℃ and 100 MPa for 7 days. The crystallinity and particle size of products were dependent on the chemical composition of the starting glass, synthetic temperature and duration of hydrothermal treatment. The high structural ordering and large dimensions of the products were confirmed from the sharpness of XRD peaks; and hydration behavior under controlled relative humidity. Transmission electron microscopy was also performed for the characterization of the particle size of product. Particle sizes vary from ca. 10 nm to a few pm by changing the chemical compositions of the starting materials. The product with the highest structural ordering and largest dimension was obtained from Nao.33（Mg1.83Al0.67）Si4O11 glass treated at 500℃ and 100 MPa for 1 day. The obtained results also confirmed the metastability and compositional dependency in the formation of highly crystalline trioctahedral smectite at hydrothermal conditions.
