Herein,the association between the dynamic adsorption capacity of toluene and several important characteristic values on activated carbon(AC)samples was investigated by multidimensional linear regression.Among the cha...Herein,the association between the dynamic adsorption capacity of toluene and several important characteristic values on activated carbon(AC)samples was investigated by multidimensional linear regression.Among the characteristic values,the carbon tetrachloride(CTC)adsorption value has demonstrated relatively stronger correlation with the toluene adsorption capacity on AC sampleswith diverse sources and forms,particularly in exposure to high-concentration toluene.Notably,the relevance of the toluene adsorption capacity to the CTC value could also be extended to a series of other porous adsorbents,which proved the wide applicability of CTC value in characterizing the adsorption behaviors.Based on these results,a mathematical and visual model was then established to predict the toluene adsorption saturation under different conditions(inlet concentration,adsorption time,initial CTC value,etc.)on diverse AC samples,of which the accuracy has later been verified by experimental data.As such,a fast and accurate estimation of the adsorption behaviors over AC samples,and possibly other porous adsorbents,was realized.展开更多
CeO_(2),La_(2)O_(3),and CeO_(2)-Y_(2)O_(3) oxides were coated on the surface of spherical granular AI_(2)O_(3)(3-5 mm)through impregnation method,and proved as better supports of Pd and Pt catalysts.The influences of ...CeO_(2),La_(2)O_(3),and CeO_(2)-Y_(2)O_(3) oxides were coated on the surface of spherical granular AI_(2)O_(3)(3-5 mm)through impregnation method,and proved as better supports of Pd and Pt catalysts.The influences of rare earth metal doping on the adsorption rates of Pd and Pt ions,as well as the catalytic performance,were investigated.Results show that the H_(2)PtCl_(6)·6H_(2)O adsorption rates of the Al_(2)O_(3) carriers modified by Ce,La,and CeY increase significantly.These rare earth coatings can adsorb almost all H2PtCl_(6)·6H_(2)O in the solution.Compared with Pt/Al_(2)O_(3) catalyst,Pt/Ce-AI_(2)O_(3) and Pt/CeY-AI_(2)O_(3) catalysts have better degradation performance for toluene,and the T_(90) temperatures are both about 147℃.According to X-ray photoelectron spectroscopy(XPS)characterization,Pt^(0)is an important active species for catalytic oxidation reaction of toluene.After CeO_(2)modification to the conventional Pt/Al_(2)O_(3)catalyst,the proportion of Pt^(0)increases from 74.5%to 82.1%.When the Pt^(0)content in the metal state is improved,the redox activity of the catalyst is promoted correspondingly.展开更多
基金supported by the Key Research and Development Projects in Zhejiang Province(Nos.2023C03127,2024C03114,2024C03108)the Natural Science Foundation of China(Nos.22208300,22078294)+2 种基金the Natural Science Foundation of Zhejiang Province(No.LQ23B060007)the Fundamental Research Funds for the Provincial Universities of Zhejiang(No.RF-A2023004)Zhejiang Provincial Postdoctoral Science Foundation(No.ZJ2023145).
文摘Herein,the association between the dynamic adsorption capacity of toluene and several important characteristic values on activated carbon(AC)samples was investigated by multidimensional linear regression.Among the characteristic values,the carbon tetrachloride(CTC)adsorption value has demonstrated relatively stronger correlation with the toluene adsorption capacity on AC sampleswith diverse sources and forms,particularly in exposure to high-concentration toluene.Notably,the relevance of the toluene adsorption capacity to the CTC value could also be extended to a series of other porous adsorbents,which proved the wide applicability of CTC value in characterizing the adsorption behaviors.Based on these results,a mathematical and visual model was then established to predict the toluene adsorption saturation under different conditions(inlet concentration,adsorption time,initial CTC value,etc.)on diverse AC samples,of which the accuracy has later been verified by experimental data.As such,a fast and accurate estimation of the adsorption behaviors over AC samples,and possibly other porous adsorbents,was realized.
基金supported by the Scientific Research Fund of Zhejiang Provincial Education Department(Y202043197)the National Natural Science Foundation of China(22078294)+1 种基金the Natural Science Foundation of Zhejiang Province(LZ21E080001,LGF20E080018)the Key Laboratory of Environmental Pollution Control Technology Research of Zhejiang Province(2021ZEKL04)。
文摘CeO_(2),La_(2)O_(3),and CeO_(2)-Y_(2)O_(3) oxides were coated on the surface of spherical granular AI_(2)O_(3)(3-5 mm)through impregnation method,and proved as better supports of Pd and Pt catalysts.The influences of rare earth metal doping on the adsorption rates of Pd and Pt ions,as well as the catalytic performance,were investigated.Results show that the H_(2)PtCl_(6)·6H_(2)O adsorption rates of the Al_(2)O_(3) carriers modified by Ce,La,and CeY increase significantly.These rare earth coatings can adsorb almost all H2PtCl_(6)·6H_(2)O in the solution.Compared with Pt/Al_(2)O_(3) catalyst,Pt/Ce-AI_(2)O_(3) and Pt/CeY-AI_(2)O_(3) catalysts have better degradation performance for toluene,and the T_(90) temperatures are both about 147℃.According to X-ray photoelectron spectroscopy(XPS)characterization,Pt^(0)is an important active species for catalytic oxidation reaction of toluene.After CeO_(2)modification to the conventional Pt/Al_(2)O_(3)catalyst,the proportion of Pt^(0)increases from 74.5%to 82.1%.When the Pt^(0)content in the metal state is improved,the redox activity of the catalyst is promoted correspondingly.
